#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:19:26 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179572 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/37/4503710.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4503710
loop_
_publ_author_name
'Ye, Junwei'
'Zhang, Jingying'
'Ning, Guiling'
'Tian, Ge'
'Chen, Yan'
'Wang, Yue'
_publ_section_title
;
 Lanthanide Coordination Polymers Constructed from Dinuclear Building
 Blocks: Novel Structure Evolution from One-Dimensional Chains to
 Three-Dimensional Architectures
;
_journal_issue                   8
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              3098
_journal_paper_doi               10.1021/cg800310j
_journal_volume                  8
_journal_year                    2008
_chemical_formula_sum            'C48 H25 Eu2 N7 O18'
_chemical_formula_weight         1291.67
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                105.50(3)
_cell_angle_beta                 115.10(3)
_cell_angle_gamma                90.68(3)
_cell_formula_units_Z            2
_cell_length_a                   13.104(3)
_cell_length_b                   14.325(3)
_cell_length_c                   14.761(3)
_cell_measurement_reflns_used    20481
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.52
_cell_measurement_theta_min      3.09
_cell_volume                     2392.9(12)
_computing_cell_refinement       PROCESS-AUTO
_computing_data_collection       PROCESS-AUTO
_computing_data_reduction        PROCESS-AUTO
_computing_molecular_graphics    'SHELXL-97 (Sheldrick, 1997)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.0
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Rigaku RAXIS-RAPID'
_diffrn_measurement_method       'Omega scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0220
_diffrn_reflns_av_sigmaI/netI    0.0301
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            23118
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.09
_diffrn_standards_decay_%        none
_diffrn_standards_interval_count none
_diffrn_standards_interval_time  none
_diffrn_standards_number         none
_exptl_absorpt_coefficient_mu    2.682
_exptl_absorpt_correction_T_max  0.6242
_exptl_absorpt_correction_T_min  0.4826
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Higashi, T. (1995) Progrom for Absorption Correcttion.
Rigaku Corporation, Tokyo, Japan. 
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.793
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1264
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.19
_refine_diff_density_max         1.711
_refine_diff_density_min         -0.682
_refine_diff_density_rms         0.189
_refine_ls_extinction_coef       0
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.128
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     676
_refine_ls_number_reflns         10785
_refine_ls_number_restraints     36
_refine_ls_restrained_S_all      1.127
_refine_ls_R_factor_all          0.0376
_refine_ls_R_factor_gt           0.0279
_refine_ls_shift/su_max          0.190
_refine_ls_shift/su_mean         0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0566P)²+1.0449P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0845
_refine_ls_wR_factor_ref         0.0930
_reflns_number_gt                9063
_reflns_number_total             10785
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg800310j-file003.cif
_cod_data_source_block           8
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        2393.0(8)
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               4503710
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu -0.004594(7) 0.561325(7) 0.135704(6) 0.01654(2) Uani 1 1 d .
Eu2 Eu 0.424101(7) 1.036165(7) 0.854246(7) 0.01696(2) Uani 1 1 d .
O1 O 0.17132(12) 0.49793(12) 0.16608(11) 0.0262(4) Uani 1 1 d .
O2 O 0.16542(12) 0.41732(11) 0.01122(10) 0.0236(4) Uani 1 1 d .
O3 O 0.38396(14) 0.14830(12) -0.01891(11) 0.0318(4) Uani 1 1 d .
O4 O 0.47047(14) 0.09186(12) 0.11783(13) 0.0353(5) Uani 1 1 d .
O5 O 0.5842(2) 0.3482(2) 0.46712(16) 0.0722(9) Uani 1 1 d .
O6 O 0.43709(19) 0.40777(18) 0.47811(13) 0.0596(7) Uani 1 1 d .
O7 O -0.07942(13) 0.67213(13) 0.23464(11) 0.0326(5) Uani 1 1 d .
O8 O 0.10706(13) 0.68259(13) 0.31324(11) 0.0305(4) Uani 1 1 d .
O9 O 0.31880(15) 0.91568(15) 0.68259(12) 0.0394(5) Uani 1 1 d .
O10 O 0.22912(15) 1.03539(12) 0.72848(13) 0.0368(5) Uani 1 1 d .
O11 O -0.19301(17) 0.97862(16) 0.54552(16) 0.0543(6) Uani 1 1 d .
O12 O -0.27367(17) 0.8371(2) 0.43815(17) 0.0701(9) Uani 1 1 d .
O13 O 0.30889(13) 0.93663(13) 0.89059(12) 0.0356(4) Uani 1 1 d .
O14 O 0.39437(13) 0.87645(13) 1.02380(13) 0.0344(5) Uani 1 1 d .
O15 O 0.06664(17) 0.71958(13) 1.12249(12) 0.0472(5) Uani 1 1 d .
O16 O 0.05182(12) 0.59074(11) 0.99808(10) 0.0241(4) Uani 1 1 d .
O17 O -0.2009(2) 0.7849(3) 0.7340(2) 0.1273(10) Uani 1 1 d U
O18 O -0.1022(2) 0.8533(2) 0.68274(19) 0.1103(9) Uani 1 1 d U
N1 N 0.4880(2) 0.36742(17) 0.42818(15) 0.0416(7) Uani 1 1 d .
N2 N -0.19082(18) 0.89897(18) 0.49245(15) 0.0381(6) Uani 1 1 d .
N3 N -0.1105(2) 0.8161(2) 0.7427(2) 0.0710(8) Uani 1 1 d .
N4 N -0.17845(16) 0.45783(15) 0.12847(14) 0.0306(5) Uani 1 1 d .
N5 N 0.03616(18) 0.48193(16) 0.28571(14) 0.0365(6) Uani 1 1 d .
N6 N 0.41773(15) 1.19795(14) 0.80703(13) 0.0237(5) Uani 1 1 d .
N7 N 0.53995(18) 1.05959(16) 0.75488(15) 0.0382(5) Uani 1 1 d .
C1 C 0.29267(16) 0.37790(15) 0.16074(14) 0.0200(5) Uani 1 1 d .
C2 C 0.31758(17) 0.29844(15) 0.09919(15) 0.0223(5) Uani 1 1 d .
H2A H 0.2812 0.2841 0.0266 0.027 Uiso 1 1 calc R
C3 C 0.39585(16) 0.24020(15) 0.14438(14) 0.0204(5) Uani 1 1 d .
C4 C 0.45384(18) 0.26396(16) 0.25283(15) 0.0243(5) Uani 1 1 d .
H4A H 0.5083 0.2271 0.2845 0.029 Uiso 1 1 calc R
C5 C 0.42866(19) 0.34352(17) 0.31233(15) 0.0261(6) Uani 1 1 d .
C6 C 0.34883(17) 0.40059(16) 0.26959(15) 0.0230(5) Uani 1 1 d .
H6A H 0.3328 0.4529 0.3123 0.028 Uiso 1 1 calc R
C7 C 0.20326(16) 0.43659(15) 0.10913(14) 0.0196(5) Uani 1 1 d .
C8 C 0.41884(17) 0.15328(16) 0.07659(15) 0.0231(5) Uani 1 1 d .
C9 C 0.01809(18) 0.78492(16) 0.40566(14) 0.0236(5) Uani 1 1 d .
C10 C 0.12057(18) 0.83157(17) 0.49074(15) 0.0249(5) Uani 1 1 d .
H10A H 0.1893 0.8154 0.4912 0.030 Uiso 1 1 calc R
C11 C 0.11938(19) 0.90335(17) 0.57615(15) 0.0263(6) Uani 1 1 d .
C12 C 0.01807(19) 0.92746(17) 0.57593(15) 0.0260(6) Uani 1 1 d .
H12A H 0.0171 0.9768 0.6311 0.031 Uiso 1 1 calc R
C13 C -0.08224(18) 0.87678(17) 0.49185(15) 0.0255(5) Uani 1 1 d .
C14 C -0.08403(18) 0.80644(18) 0.40714(16) 0.0280(6) Uani 1 1 d .
H14A H -0.1529 0.7736 0.3514 0.034 Uiso 1 1 calc R
C15 C 0.01711(18) 0.70898(16) 0.31251(15) 0.0239(5) Uani 1 1 d .
C16 C 0.23034(19) 0.95525(17) 0.66799(16) 0.0280(6) Uani 1 1 d .
C17 C 0.19459(17) 0.84298(15) 0.93152(15) 0.0230(5) Uani 1 1 d .
C18 C 0.18568(17) 0.78974(15) 0.99472(15) 0.0223(5) Uani 1 1 d .
H18A H 0.2509 0.7846 1.0514 0.027 Uiso 1 1 calc R
C19 C 0.08168(18) 0.74463(15) 0.97447(15) 0.0237(5) Uani 1 1 d .
C20 C -0.01526(19) 0.75308(19) 0.89166(19) 0.0382(6) Uani 1 1 d .
H20A H -0.0860 0.7233 0.8777 0.046 Uiso 1 1 calc R
C21 C -0.0061(2) 0.8064(2) 0.8295(2) 0.0418(7) Uani 1 1 d .
C22 C 0.0970(2) 0.85169(18) 0.84820(18) 0.0339(6) Uani 1 1 d .
H22A H 0.1011 0.8876 0.8056 0.041 Uiso 1 1 calc R
C23 C 0.30809(17) 0.88902(16) 0.95021(16) 0.0248(5) Uani 1 1 d .
C24 C 0.06695(17) 0.68237(16) 1.03696(15) 0.0229(5) Uani 1 1 d .
C25 C -0.2819(2) 0.4415(2) 0.0513(2) 0.0443(8) Uani 1 1 d .
H25A H -0.2935 0.4664 -0.0038 0.053 Uiso 1 1 calc R
C26 C -0.3753(3) 0.3895(3) 0.0466(2) 0.0635(10) Uani 1 1 d .
H26A H -0.4469 0.3813 -0.0094 0.076 Uiso 1 1 calc R
C27 C -0.3599(3) 0.3515(3) 0.1242(3) 0.0761(10) Uani 1 1 d .
H27A H -0.4213 0.3162 0.1222 0.091 Uiso 1 1 calc R
C28 C -0.2520(3) 0.3646(2) 0.2082(2) 0.0600(8) Uani 1 1 d .
C29 C -0.2255(3) 0.3236(3) 0.2954(3) 0.0923(11) Uani 1 1 d U
H29A H -0.2834 0.2877 0.2979 0.111 Uiso 1 1 calc R
C30 C -0.1216(4) 0.3368(3) 0.3697(3) 0.0958(13) Uani 1 1 d U
H30A H -0.1080 0.3104 0.4243 0.115 Uiso 1 1 calc R
C31 C -0.0292(3) 0.3895(3) 0.3706(2) 0.0694(10) Uani 1 1 d .
C32 C 0.0832(4) 0.4038(3) 0.4495(3) 0.0926(13) Uani 1 1 d U
H32A H 0.0997 0.3778 0.5047 0.111 Uiso 1 1 calc R
C33 C 0.1659(3) 0.4545(3) 0.4453(2) 0.0813(12) Uani 1 1 d .
H33A H 0.2403 0.4629 0.4971 0.098 Uiso 1 1 calc R
C34 C 0.1416(3) 0.4956(3) 0.3631(2) 0.0519(9) Uani 1 1 d .
H34A H 0.1998 0.5328 0.3625 0.062 Uiso 1 1 calc R
C35 C -0.0495(2) 0.43092(19) 0.28897(18) 0.0408(6) Uani 1 1 d .
C36 C -0.1619(2) 0.41872(18) 0.20676(18) 0.0380(6) Uani 1 1 d .
C37 C 0.3506(2) 1.26182(18) 0.82291(18) 0.0312(6) Uani 1 1 d .
H37A H 0.3027 1.2467 0.8504 0.037 Uiso 1 1 calc R
C38 C 0.3477(2) 1.3506(2) 0.8007(2) 0.0420(8) Uani 1 1 d .
H38A H 0.2967 1.3921 0.8101 0.050 Uiso 1 1 calc R
C39 C 0.4214(2) 1.3751(2) 0.7651(2) 0.0464(8) Uani 1 1 d .
H39A H 0.4232 1.4355 0.7530 0.056 Uiso 1 1 calc R
C40 C 0.4946(2) 1.31022(18) 0.7463(2) 0.0372(7) Uani 1 1 d .
C41 C 0.5719(2) 1.3302(2) 0.7076(2) 0.0531(8) Uani 1 1 d .
H41A H 0.5777 1.3905 0.6963 0.064 Uiso 1 1 calc R
C42 C 0.6369(3) 1.2642(2) 0.6868(2) 0.0558(8) Uani 1 1 d .
H42A H 0.6875 1.2792 0.6620 0.067 Uiso 1 1 calc R
C43 C 0.6285(2) 1.1708(2) 0.7028(2) 0.0459(7) Uani 1 1 d .
C44 C 0.6906(3) 1.0993(3) 0.6773(3) 0.0739(10) Uani 1 1 d .
H44A H 0.7417 1.1119 0.6521 0.089 Uiso 1 1 calc R
C45 C 0.6752(3) 1.0099(3) 0.6901(3) 0.0950(10) Uani 1 1 d U
H45A H 0.7141 0.9600 0.6719 0.114 Uiso 1 1 calc R
C46 C 0.6010(3) 0.9949(2) 0.7305(2) 0.0727(8) Uani 1 1 d .
H46A H 0.5939 0.9345 0.7411 0.087 Uiso 1 1 calc R
C47 C 0.55302(19) 1.14840(18) 0.74090(16) 0.0304(6) Uani 1 1 d .
C48 C 0.48683(18) 1.22045(16) 0.76628(15) 0.0248(5) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Eu1 O16 142.86(6) . 2_566
O7 Eu1 O2 83.61(6) . 2_565
O16 Eu1 O2 75.43(6) 2_566 2_565
O7 Eu1 O1 137.38(5) . .
O16 Eu1 O1 74.21(6) 2_566 .
O2 Eu1 O1 136.85(6) 2_565 .
O7 Eu1 O8 53.49(6) . .
O16 Eu1 O8 156.28(6) 2_566 .
O2 Eu1 O8 128.28(6) 2_565 .
O1 Eu1 O8 84.98(6) . .
O7 Eu1 O15 80.93(7) . 1_554
O16 Eu1 O15 123.01(6) 2_566 1_554
O2 Eu1 O15 78.40(7) 2_565 1_554
O1 Eu1 O15 93.34(7) . 1_554
O8 Eu1 O15 68.51(6) . 1_554
O7 Eu1 O16 126.73(6) . 1_554
O16 Eu1 O16 73.00(6) 2_566 1_554
O2 Eu1 O16 68.41(6) 2_565 1_554
O1 Eu1 O16 73.83(6) . 1_554
O8 Eu1 O16 112.37(6) . 1_554
O15 Eu1 O16 50.35(6) 1_554 1_554
O7 Eu1 N5 80.95(7) . .
O16 Eu1 N5 94.63(6) 2_566 .
O2 Eu1 N5 138.32(7) 2_565 .
O1 Eu1 N5 74.24(7) . .
O8 Eu1 N5 68.35(6) . .
O15 Eu1 N5 135.90(6) 1_554 .
O16 Eu1 N5 147.83(6) 1_554 .
O7 Eu1 N4 73.92(7) . .
O16 Eu1 N4 71.52(7) 2_566 .
O2 Eu1 N4 76.25(7) 2_565 .
O1 Eu1 N4 120.78(6) . .
O8 Eu1 N4 111.44(7) . .
O15 Eu1 N4 145.88(7) 1_554 .
O16 Eu1 N4 134.81(5) 1_554 .
N5 Eu1 N4 62.32(7) . .
O7 Eu1 C15 27.11(6) . .
O16 Eu1 C15 163.39(7) 2_566 .
O2 Eu1 C15 107.02(7) 2_565 .
O1 Eu1 C15 110.86(6) . .
O8 Eu1 C15 26.38(6) . .
O15 Eu1 C15 73.17(7) 1_554 .
O16 Eu1 C15 123.44(6) 1_554 .
N5 Eu1 C15 72.45(7) . .
N4 Eu1 C15 92.87(7) . .
O7 Eu1 C24 102.87(7) . 1_554
O16 Eu1 C24 98.07(6) 2_566 1_554
O2 Eu1 C24 69.52(6) 2_565 1_554
O1 Eu1 C24 85.22(7) . 1_554
O8 Eu1 C24 91.26(6) . 1_554
O15 Eu1 C24 24.96(6) 1_554 1_554
O16 Eu1 C24 25.59(5) 1_554 1_554
N5 Eu1 C24 151.87(6) . 1_554
N4 Eu1 C24 145.75(6) . 1_554
C15 Eu1 C24 98.12(7) . 1_554
O7 Eu1 Eu1 149.63(4) . 2_565
O16 Eu1 Eu1 38.09(4) 2_566 2_565
O2 Eu1 Eu1 67.18(5) 2_565 2_565
O1 Eu1 Eu1 69.97(5) . 2_565
O8 Eu1 Eu1 142.50(5) . 2_565
O15 Eu1 Eu1 85.09(5) 1_554 2_565
O16 Eu1 Eu1 34.91(3) 1_554 2_565
N5 Eu1 Eu1 126.47(5) . 2_565
N4 Eu1 Eu1 105.36(5) . 2_565
C15 Eu1 Eu1 158.27(5) . 2_565
C24 Eu1 Eu1 60.15(5) 1_554 2_565
O4 Eu2 O14 79.11(7) 2_666 2_677
O4 Eu2 O3 125.50(7) 2_666 1_566
O14 Eu2 O3 77.53(7) 2_677 1_566
O4 Eu2 O13 78.42(7) 2_666 .
O14 Eu2 O13 125.21(6) 2_677 .
O3 Eu2 O13 76.33(7) 1_566 .
O4 Eu2 O10 130.75(6) 2_666 .
O14 Eu2 O10 149.39(6) 2_677 .
O3 Eu2 O10 86.85(7) 1_566 .
O13 Eu2 O10 74.77(7) . .
O4 Eu2 O9 81.01(7) 2_666 .
O14 Eu2 O9 143.95(7) 2_677 .
O3 Eu2 O9 138.03(6) 1_566 .
O13 Eu2 O9 79.01(7) . .
O10 Eu2 O9 53.91(7) . .
O4 Eu2 N6 143.94(7) 2_666 .
O14 Eu2 N6 77.98(7) 2_677 .
O3 Eu2 N6 75.55(7) 1_566 .
O13 Eu2 N6 137.63(6) . .
O10 Eu2 N6 72.65(7) . .
O9 Eu2 N6 102.21(7) . .
O4 Eu2 N7 82.93(8) 2_666 .
O14 Eu2 N7 70.79(7) 2_677 .
O3 Eu2 N7 131.98(7) 1_566 .
O13 Eu2 N7 151.68(6) . .
O10 Eu2 N7 102.64(7) . .
O9 Eu2 N7 77.16(7) . .
N6 Eu2 N7 63.38(7) . .
O4 Eu2 C16 105.45(7) 2_666 .
O14 Eu2 C16 161.33(8) 2_677 .
O3 Eu2 C16 112.14(7) 1_566 .
O13 Eu2 C16 73.35(7) . .
O10 Eu2 C16 27.02(7) . .
O9 Eu2 C16 27.02(7) . .
N6 Eu2 C16 88.81(7) . .
N7 Eu2 C16 91.58(7) . .
O4 Eu2 Eu2 54.60(5) 2_666 2_677
O14 Eu2 Eu2 64.58(6) 2_677 2_677
O3 Eu2 Eu2 70.90(5) 1_566 2_677
O13 Eu2 Eu2 61.60(5) . 2_677
O10 Eu2 Eu2 134.28(6) . 2_677
O9 Eu2 Eu2 123.99(6) . 2_677
N6 Eu2 Eu2 133.80(4) . 2_677
N7 Eu2 Eu2 122.10(5) . 2_677
C16 Eu2 Eu2 132.96(6) . 2_677
C7 O1 Eu1 133.39(12) . .
C7 O2 Eu1 139.71(15) . 2_565
C8 O3 Eu2 127.31(15) . 1_544
C8 O4 Eu2 161.26(18) . 2_666
C15 O7 Eu1 94.91(14) . .
C15 O8 Eu1 89.61(11) . .
C16 O9 Eu2 91.22(13) . .
C16 O10 Eu2 91.26(14) . .
C23 O13 Eu2 145.33(13) . .
C23 O14 Eu2 137.55(16) . 2_677
C24 O15 Eu1 95.24(14) . 1_556
C24 O16 Eu1 156.95(15) . 2_566
C24 O16 Eu1 92.85(14) . 1_556
Eu1 O16 Eu1 107.00(6) 2_566 1_556
O5 N1 O6 124.8(2) . .
O5 N1 C5 117.7(3) . .
O6 N1 C5 117.5(2) . .
O11 N2 O12 123.8(3) . .
O11 N2 C13 118.1(2) . .
O12 N2 C13 118.1(2) . .
O18 N3 O17 122.7(3) . .
O18 N3 C21 118.4(3) . .
O17 N3 C21 118.8(3) . .
C25 N4 C36 117.3(2) . .
C25 N4 Eu1 123.2(2) . .
C36 N4 Eu1 119.54(14) . .
C34 N5 C35 119.3(3) . .
C34 N5 Eu1 119.8(2) . .
C35 N5 Eu1 120.83(15) . .
C37 N6 C48 117.8(2) . .
C37 N6 Eu2 122.40(18) . .
C48 N6 Eu2 119.81(15) . .
C46 N7 C47 117.0(3) . .
C46 N7 Eu2 123.0(2) . .
C47 N7 Eu2 119.23(17) . .
C2 C1 C6 119.4(2) . .
C2 C1 C7 119.76(17) . .
C6 C1 C7 120.79(19) . .
C1 C2 C3 121.11(18) . .
C1 C2 H2A 119.4 . .
C3 C2 H2A 119.4 . .
C4 C3 C2 119.6(2) . .
C4 C3 C8 120.20(19) . .
C2 C3 C8 120.23(17) . .
C5 C4 C3 118.3(2) . .
C5 C4 H4A 120.8 . .
C3 C4 H4A 120.8 . .
C4 C5 C6 123.30(18) . .
C4 C5 N1 118.5(2) . .
C6 C5 N1 118.2(2) . .
C5 C6 C1 118.2(2) . .
C5 C6 H6A 120.9 . .
C1 C6 H6A 120.9 . .
O1 C7 O2 125.9(2) . .
O1 C7 C1 117.75(17) . .
O2 C7 C1 116.32(19) . .
O4 C8 O3 125.1(2) . .
O4 C8 C3 118.14(19) . .
O3 C8 C3 116.8(2) . .
C14 C9 C10 120.1(2) . .
C14 C9 C15 119.54(17) . .
C10 C9 C15 120.3(2) . .
C9 C10 C11 119.3(2) . .
C9 C10 H10A 120.4 . .
C11 C10 H10A 120.4 . .
C12 C11 C10 120.60(18) . .
C12 C11 C16 119.88(19) . .
C10 C11 C16 119.5(2) . .
C11 C12 C13 118.5(2) . .
C11 C12 H12A 120.8 . .
C13 C12 H12A 120.8 . .
C14 C13 C12 122.3(2) . .
C14 C13 N2 118.58(18) . .
C12 C13 N2 119.1(2) . .
C13 C14 C9 119.09(18) . .
C13 C14 H14A 120.5 . .
C9 C14 H14A 120.5 . .
O8 C15 O7 121.97(19) . .
O8 C15 C9 120.62(17) . .
O7 C15 C9 117.4(2) . .
O8 C15 Eu1 64.01(11) . .
O7 C15 Eu1 57.97(12) . .
C9 C15 Eu1 174.79(16) . .
O9 C16 O10 123.02(18) . .
O9 C16 C11 119.0(2) . .
O10 C16 C11 117.9(2) . .
O9 C16 Eu2 61.76(10) . .
O10 C16 Eu2 61.72(11) . .
C11 C16 Eu2 171.10(18) . .
C22 C17 C18 119.3(2) . .
C22 C17 C23 119.4(2) . .
C18 C17 C23 121.38(18) . .
C19 C18 C17 120.94(18) . .
C19 C18 H18A 119.5 . .
C17 C18 H18A 119.5 . .
C18 C19 C20 119.9(2) . .
C18 C19 C24 123.50(18) . .
C20 C19 C24 116.6(2) . .
C21 C20 C19 119.0(2) . .
C21 C20 H20A 120.5 . .
C19 C20 H20A 120.5 . .
C20 C21 C22 122.0(2) . .
C20 C21 N3 118.3(2) . .
C22 C21 N3 119.7(3) . .
C17 C22 C21 118.9(3) . .
C17 C22 H22A 120.5 . .
C21 C22 H22A 120.5 . .
O13 C23 O14 125.1(2) . .
O13 C23 C17 117.54(18) . .
O14 C23 C17 117.3(2) . .
O15 C24 O16 120.7(2) . .
O15 C24 C19 121.3(2) . .
O16 C24 C19 118.03(19) . .
O15 C24 Eu1 59.80(14) . 1_556
O16 C24 Eu1 61.57(13) . 1_556
C19 C24 Eu1 169.82(14) . 1_556
N4 C25 C26 124.5(3) . .
N4 C25 H25A 117.8 . .
C26 C25 H25A 117.8 . .
C27 C26 C25 118.6(3) . .
C27 C26 H26A 120.7 . .
C25 C26 H26A 120.7 . .
C26 C27 C28 120.2(3) . .
C26 C27 H27A 119.9 . .
C28 C27 H27A 119.9 . .
C27 C28 C36 117.3(3) . .
C27 C28 C29 124.5(3) . .
C36 C28 C29 118.2(3) . .
C30 C29 C28 120.9(4) . .
C30 C29 H29A 119.5 . .
C28 C29 H29A 119.5 . .
C29 C30 C31 122.7(4) . .
C29 C30 H30A 118.7 . .
C31 C30 H30A 118.7 . .
C32 C31 C30 123.5(3) . .
C32 C31 C35 117.5(3) . .
C30 C31 C35 119.0(3) . .
C33 C32 C31 120.2(4) . .
C33 C32 H32A 119.9 . .
C31 C32 H32A 119.9 . .
C32 C33 C34 120.4(3) . .
C32 C33 H33A 119.8 . .
C34 C33 H33A 119.8 . .
N5 C34 C33 121.1(3) . .
N5 C34 H34A 119.4 . .
C33 C34 H34A 119.4 . .
N5 C35 C31 121.5(3) . .
N5 C35 C36 118.5(2) . .
C31 C35 C36 120.0(3) . .
N4 C36 C35 118.7(2) . .
N4 C36 C28 122.0(2) . .
C35 C36 C28 119.3(3) . .
N6 C37 C38 123.5(3) . .
N6 C37 H37A 118.2 . .
C38 C37 H37A 118.2 . .
C39 C38 C37 118.5(3) . .
C39 C38 H38A 120.8 . .
C37 C38 H38A 120.8 . .
C38 C39 C40 120.6(3) . .
C38 C39 H39A 119.7 . .
C40 C39 H39A 119.7 . .
C48 C40 C39 116.4(3) . .
C48 C40 C41 120.0(3) . .
C39 C40 C41 123.7(3) . .
C42 C41 C40 121.5(3) . .
C42 C41 H41A 119.3 . .
C40 C41 H41A 119.3 . .
C41 C42 C43 120.1(3) . .
C41 C42 H42A 120.0 . .
C43 C42 H42A 120.0 . .
C47 C43 C44 118.4(3) . .
C47 C43 C42 120.1(3) . .
C44 C43 C42 121.4(3) . .
C45 C44 C43 118.8(4) . .
C45 C44 H44A 120.6 . .
C43 C44 H44A 120.6 . .
C44 C45 C46 118.9(4) . .
C44 C45 H45A 120.6 . .
C46 C45 H45A 120.6 . .
N7 C46 C45 124.7(3) . .
N7 C46 H46A 117.7 . .
C45 C46 H46A 117.7 . .
N7 C47 C43 122.2(3) . .
N7 C47 C48 118.3(2) . .
C43 C47 C48 119.5(2) . .
N6 C48 C40 123.0(2) . .
N6 C48 C47 118.2(2) . .
C40 C48 C47 118.8(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O7 2.3721(19) .
Eu1 O16 2.3790(17) 2_566
Eu1 O2 2.3938(17) 2_565
Eu1 O1 2.3938(17) .
Eu1 O8 2.5058(19) .
Eu1 O15 2.528(2) 1_554
Eu1 O16 2.5644(18) 1_554
Eu1 N5 2.615(2) .
Eu1 N4 2.651(2) .
Eu1 C15 2.788(2) .
Eu1 C24 2.913(3) 1_554
Eu1 Eu1 3.9754(12) 2_565
Eu2 O4 2.3288(19) 2_666
Eu2 O14 2.3575(19) 2_677
Eu2 O3 2.3687(18) 1_566
Eu2 O13 2.376(2) .
Eu2 O10 2.4369(19) .
Eu2 O9 2.438(2) .
Eu2 N6 2.585(2) .
Eu2 N7 2.590(3) .
Eu2 C16 2.766(2) .
Eu2 Eu2 4.3262(13) 2_677
O1 C7 1.252(3) .
O2 C7 1.259(2) .
O2 Eu1 2.3938(17) 2_565
O3 C8 1.265(3) .
O3 Eu2 2.3687(18) 1_544
O4 C8 1.246(3) .
O4 Eu2 2.3288(19) 2_666
O5 N1 1.214(3) .
O6 N1 1.234(4) .
O7 C15 1.275(2) .
O8 C15 1.239(3) .
O9 C16 1.257(3) .
O10 C16 1.257(3) .
O11 N2 1.208(3) .
O12 N2 1.211(3) .
O13 C23 1.252(3) .
O14 C23 1.248(3) .
O14 Eu2 2.3575(18) 2_677
O15 C24 1.234(3) .
O15 Eu1 2.528(2) 1_556
O16 C24 1.259(3) .
O16 Eu1 2.3790(17) 2_566
O16 Eu1 2.5644(18) 1_556
O17 N3 1.202(4) .
O18 N3 1.188(4) .
N1 C5 1.483(3) .
N2 C13 1.465(3) .
N3 C21 1.466(3) .
N4 C25 1.315(3) .
N4 C36 1.354(4) .
N5 C34 1.336(3) .
N5 C35 1.357(4) .
N6 C37 1.321(3) .
N6 C48 1.358(3) .
N7 C46 1.308(4) .
N7 C47 1.362(4) .
C1 C2 1.391(3) .
C1 C6 1.393(3) .
C1 C7 1.506(3) .
C2 C3 1.389(3) .
C2 H2A 0.9300 .
C3 C4 1.388(3) .
C3 C8 1.497(3) .
C4 C5 1.378(3) .
C4 H4A 0.9300 .
C5 C6 1.377(3) .
C6 H6A 0.9300 .
C9 C14 1.385(3) .
C9 C10 1.388(3) .
C9 C15 1.503(3) .
C10 C11 1.404(3) .
C10 H10A 0.9300 .
C11 C12 1.375(4) .
C11 C16 1.506(3) .
C12 C13 1.381(3) .
C12 H12A 0.9300 .
C13 C14 1.371(3) .
C14 H14A 0.9300 .
C17 C22 1.384(3) .
C17 C18 1.392(3) .
C17 C23 1.502(3) .
C18 C19 1.377(3) .
C18 H18A 0.9300 .
C19 C20 1.374(3) .
C19 C24 1.507(3) .
C20 C21 1.380(4) .
C20 H20A 0.9300 .
C21 C22 1.374(4) .
C22 H22A 0.9300 .
C24 Eu1 2.913(3) 1_556
C25 C26 1.391(4) .
C25 H25A 0.9300 .
C26 C27 1.337(6) .
C26 H26A 0.9300 .
C27 C28 1.399(4) .
C27 H27A 0.9300 .
C28 C36 1.416(4) .
C28 C29 1.467(5) .
C29 C30 1.307(5) .
C29 H29A 0.9300 .
C30 C31 1.413(6) .
C30 H30A 0.9300 .
C31 C32 1.406(5) .
C31 C35 1.410(4) .
C32 C33 1.330(6) .
C32 H32A 0.9300 .
C33 C34 1.406(5) .
C33 H33A 0.9300 .
C34 H34A 0.9300 .
C35 C36 1.427(3) .
C37 C38 1.392(4) .
C37 H37A 0.9300 .
C38 C39 1.362(5) .
C38 H38A 0.9300 .
C39 C40 1.404(4) .
C39 H39A 0.9300 .
C40 C48 1.406(4) .
C40 C41 1.417(5) .
C41 C42 1.342(5) .
C41 H41A 0.9300 .
C42 C43 1.429(5) .
C42 H42A 0.9300 .
C43 C47 1.400(4) .
C43 C44 1.388(5) .
C44 C45 1.368(6) .
C44 H44A 0.9300 .
C45 C46 1.379(6) .
C45 H45A 0.9300 .
C46 H46A 0.9300 .
C47 C48 1.431(4) .
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
C44 H44A O11 0.93 2.54 3.144(5) 123.4 1_655
C45 H45A O11 0.93 2.69 3.221(5) 117.4 1_655
C42 H42A O8 0.93 2.59 3.432(4) 151.0 2_676
