#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:19:26 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179572 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/37/4503770.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4503770
loop_
_publ_author_name
'Yang, Yu-ting'
'Luo, Feng'
'Che, Yun-xia'
'Zheng, Ji-min'
_publ_section_title
;
 Employing An Unprecedented Ferromagnetic Molecular Building Block (MBB)
 of [Co2Ln(μ3-OH)(CO2)5(N3)]2(Ln = Tb, Gd, Dy, Eu, Sm) to Construct a
 6-Connected α-Po Net
;
_journal_issue                   10
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              3508
_journal_paper_doi               10.1021/cg800431b
_journal_volume                  8
_journal_year                    2008
_chemical_formula_sum            'C60 H42 Co4 Eu2 N16 O22'
_chemical_formula_weight         1878.74
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                107.99(3)
_cell_angle_beta                 107.35(3)
_cell_angle_gamma                101.79(3)
_cell_formula_units_Z            1
_cell_length_a                   10.948(2)
_cell_length_b                   11.997(2)
_cell_length_c                   14.689(3)
_cell_measurement_reflns_used    14675
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      3.03
_cell_volume                     1655.5(9)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.989
_diffrn_measured_fraction_theta_max 0.989
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0319
_diffrn_reflns_av_sigmaI/netI    0.0424
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            16323
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.03
_exptl_absorpt_coefficient_mu    2.935
_exptl_absorpt_correction_T_max  0.7442
_exptl_absorpt_correction_T_min  0.5724
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            Red
_exptl_crystal_density_diffrn    1.884
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             924
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.11
_refine_diff_density_max         0.757
_refine_diff_density_min         -1.020
_refine_diff_density_rms         0.141
_refine_ls_extinction_coef       0.0023(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.141
_refine_ls_hydrogen_treatment    refU
_refine_ls_matrix_type           full
_refine_ls_number_parameters     474
_refine_ls_number_reflns         7510
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.141
_refine_ls_R_factor_all          0.0297
_refine_ls_R_factor_gt           0.0265
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0399P)²+0.9397P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0743
_refine_ls_wR_factor_ref         0.0804
_reflns_number_gt                6932
_reflns_number_total             7510
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg800431b_si_004.cif
_cod_data_source_block           4
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'Multi-scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from
2010-06-29.

'_refine_ls_hydrogen_treatment' value 'refu' changed to
'refU' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1655.5(5)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4503770
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.6960(4) 0.1748(3) 0.2009(2) 0.0291(7) Uani 1 1 d .
H1 H 0.6840 0.1473 0.1313 0.035 Uiso 1 1 calc R
C2 C 1.2357(4) 0.5000(4) 0.8471(3) 0.0325(8) Uani 1 1 d .
H2 H 1.2146 0.5088 0.9052 0.039 Uiso 1 1 calc R
C3 C 0.8362(3) 0.2494(3) 0.3730(2) 0.0207(6) Uani 1 1 d .
H3 H 0.9217 0.2711 0.4238 0.025 Uiso 1 1 calc R
C4 C 0.6014(3) 0.2233(3) 0.3285(2) 0.0282(7) Uani 1 1 d .
H4 H 0.5279 0.2280 0.3470 0.034 Uiso 1 1 calc R
C5 C 0.7925(3) 0.8114(3) 0.6054(2) 0.0222(6) Uani 1 1 d .
C6 C 1.3262(3) 0.4674(3) 0.5834(2) 0.0189(6) Uani 1 1 d .
C7 C 0.7300(3) 0.2606(3) 0.4039(2) 0.0199(6) Uani 1 1 d .
C8 C 1.3000(3) 0.4784(3) 0.6796(2) 0.0200(6) Uani 1 1 d .
C9 C 0.7544(3) 0.3244(3) 0.5173(2) 0.0188(6) Uani 1 1 d .
C10 C 1.4007(3) 0.4996(4) 0.7725(3) 0.0345(8) Uani 1 1 d .
H10 H 1.4891 0.5074 0.7779 0.041 Uiso 1 1 calc R
C11 C 0.5841(4) 0.1790(4) 0.2252(3) 0.0338(8) Uani 1 1 d .
H11 H 0.4986 0.1525 0.1730 0.041 Uiso 1 1 calc R
C12 C 0.7868(3) 0.8254(3) 0.9745(2) 0.0229(6) Uani 1 1 d .
C13 C 1.1709(3) 0.4678(3) 0.6758(2) 0.0215(6) Uani 1 1 d .
H13 H 1.1034 0.4518 0.6127 0.026 Uiso 1 1 calc R
C14 C 0.8938(3) 0.2515(3) 0.9339(2) 0.0216(6) Uani 1 1 d .
C15 C 0.8593(3) 0.9492(3) 1.0367(2) 0.0211(6) Uani 1 1 d .
H15 H 0.8963 0.9979 1.0069 0.025 Uiso 1 1 calc R
C16 C 1.3664(4) 0.5088(5) 0.8570(3) 0.0425(10) Uani 1 1 d .
H16 H 1.4312 0.5209 0.9200 0.051 Uiso 1 1 calc R
C17 C 0.7806(3) 0.7739(3) 0.8651(2) 0.0224(6) Uani 1 1 d .
C18 C 0.6714(5) 0.9282(5) 0.3612(4) 0.0605(14) Uani 1 1 d .
H18 H 0.6460 0.9566 0.3085 0.073 Uiso 1 1 calc R
C19 C 0.7344(5) 0.7522(4) 1.0191(3) 0.0425(10) Uani 1 1 d .
H19 H 0.6836 0.6690 0.9800 0.051 Uiso 1 1 calc R
C20 C 0.8138(4) 0.1330(3) 0.8636(3) 0.0361(9) Uani 1 1 d .
H20 H 0.7778 0.0743 0.8860 0.043 Uiso 1 1 calc R
C21 C 0.7464(4) 0.8541(3) 0.5187(2) 0.0251(7) Uani 1 1 d .
C22 C 0.8319(4) 0.9306(3) 1.1796(3) 0.0352(9) Uani 1 1 d .
H22 H 0.8481 0.9653 1.2499 0.042 Uiso 1 1 calc R
C23 C 0.9442(3) 0.3351(3) 0.8957(2) 0.0226(6) Uani 1 1 d .
H23 H 1.0008 0.4143 0.9430 0.027 Uiso 1 1 calc R
C24 C 0.8399(4) 0.1918(3) 0.7279(2) 0.0345(8) Uani 1 1 d .
H24 H 0.8212 0.1703 0.6575 0.041 Uiso 1 1 calc R
C25 C 0.7595(5) 0.8065(4) 1.1242(3) 0.0497(12) Uani 1 1 d .
H25 H 0.7275 0.7590 1.1569 0.060 Uiso 1 1 calc R
C26 C 0.6101(4) 0.8260(4) 0.4625(3) 0.0397(9) Uani 1 1 d .
H26 H 0.5456 0.7834 0.4799 0.048 Uiso 1 1 calc R
C27 C 0.7878(5) 0.1026(4) 0.7595(3) 0.0454(11) Uani 1 1 d .
H27 H 0.7357 0.0227 0.7111 0.054 Uiso 1 1 calc R
C28 C 0.8384(4) 0.9191(5) 0.4910(3) 0.0493(11) Uani 1 1 d .
H28 H 0.9303 0.9393 0.5290 0.059 Uiso 1 1 calc R
C29 C 0.8009(4) 0.9541(5) 0.4123(4) 0.0547(13) Uani 1 1 d .
H29 H 0.8649 0.9958 0.3941 0.066 Uiso 1 1 calc R
C30 C 0.9244(3) 0.2964(3) 1.0485(2) 0.0206(6) Uani 1 1 d .
Co1 Co 0.93484(4) 0.46372(4) 0.74753(3) 0.01801(10) Uani 1 1 d .
Co2 Co 1.01568(4) 0.80143(4) 0.78050(3) 0.01796(10) Uani 1 1 d .
Eu1 Eu 0.678192(14) 0.559674(13) 0.634698(10) 0.01672(7) Uani 1 1 d .
N1 N 1.1371(3) 0.4793(3) 0.75764(19) 0.0233(6) Uani 1 1 d .
N2 N 0.9162(3) 0.3082(3) 0.79429(19) 0.0236(6) Uani 1 1 d .
N3 N 0.7320(3) 0.4464(3) 0.7484(2) 0.0253(6) Uani 1 1 d .
N4 N 0.7121(3) 0.4457(3) 0.8242(2) 0.0278(6) Uani 1 1 d .
N5 N 0.6915(4) 0.4420(4) 0.8953(3) 0.0521(10) Uani 1 1 d .
N6 N 0.8211(3) 0.2085(2) 0.27277(19) 0.0221(5) Uani 1 1 d .
N7 N 0.8798(3) 1.0035(2) 1.13683(19) 0.0224(5) Uani 1 1 d .
N8 N 0.5700(5) 0.8617(5) 0.3801(4) 0.0751(14) Uani 1 1 d .
O1 O 0.6576(2) 0.3561(2) 0.53316(16) 0.0245(5) Uani 1 1 d .
O2 O 0.8671(2) 0.3454(2) 0.58562(16) 0.0244(5) Uani 1 1 d .
O3 O 1.2263(2) 0.4379(2) 0.50116(15) 0.0241(5) Uani 1 1 d .
O4 O 1.4457(2) 0.4875(2) 0.58622(17) 0.0257(5) Uani 1 1 d .
O5 O 0.9157(2) 0.60932(19) 0.69943(15) 0.0176(4) Uani 1 1 d .
O6 O 0.6832(3) 0.6789(2) 0.79912(17) 0.0306(5) Uani 1 1 d .
O7 O 0.8762(3) 0.8311(3) 0.84953(18) 0.0360(6) Uani 1 1 d .
O8 O 0.7008(2) 0.7507(2) 0.62373(17) 0.0259(5) Uani 1 1 d .
O9 O 0.9177(2) 0.8377(2) 0.65233(16) 0.0259(5) Uani 1 1 d .
O10 O 0.9920(3) 0.4090(2) 1.10036(16) 0.0271(5) Uani 1 1 d .
O12 O 0.8798(3) 0.2196(2) 1.08227(16) 0.0281(5) Uani 1 1 d .
H5A H 0.931(4) 0.597(3) 0.643(3) 0.017(8) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N6 C1 C11 123.2(3) . .
N6 C1 H1 118.4 . .
C11 C1 H1 118.4 . .
N1 C2 C16 123.1(3) . .
N1 C2 H2 118.4 . .
C16 C2 H2 118.4 . .
N6 C3 C7 122.9(3) . .
N6 C3 H3 118.6 . .
C7 C3 H3 118.6 . .
C11 C4 C7 118.8(3) . .
C11 C4 H4 120.6 . .
C7 C4 H4 120.6 . .
O9 C5 O8 125.7(3) . .
O9 C5 C21 117.7(3) . .
O8 C5 C21 116.6(3) . .
O9 C5 Eu1 100.81(19) . .
O8 C5 Eu1 35.02(15) . .
C21 C5 Eu1 132.9(2) . .
O3 C6 O4 121.9(3) . .
O3 C6 C8 117.6(3) . .
O4 C6 C8 120.5(3) . .
O3 C6 Eu1 51.36(14) . 2_766
O4 C6 Eu1 70.56(16) . 2_766
C8 C6 Eu1 168.8(2) . 2_766
C3 C7 C4 118.8(3) . .
C3 C7 C9 121.2(3) . .
C4 C7 C9 119.7(3) . .
C13 C8 C10 118.6(3) . .
C13 C8 C6 118.7(3) . .
C10 C8 C6 122.7(3) . .
O2 C9 O1 125.9(3) . .
O2 C9 C7 119.2(3) . .
O1 C9 C7 114.8(3) . .
O2 C9 Eu1 99.22(19) . .
O1 C9 Eu1 37.28(15) . .
C7 C9 Eu1 130.83(19) . .
C16 C10 C8 118.2(3) . .
C16 C10 H10 120.9 . .
C8 C10 H10 120.9 . .
C1 C11 C4 118.9(3) . .
C1 C11 H11 120.6 . .
C4 C11 H11 120.6 . .
C19 C12 C15 117.9(3) . .
C19 C12 C17 122.8(3) . .
C15 C12 C17 118.9(3) . .
N1 C13 C8 123.6(3) . .
N1 C13 H13 118.2 . .
C8 C13 H13 118.2 . .
C20 C14 C23 117.8(3) . .
C20 C14 C30 123.7(3) . .
C23 C14 C30 118.5(3) . .
N7 C15 C12 124.4(3) . .
N7 C15 H15 117.8 . .
C12 C15 H15 117.8 . .
C2 C16 C10 119.4(3) . .
C2 C16 H16 120.3 . .
C10 C16 H16 120.3 . .
O7 C17 O6 126.1(3) . .
O7 C17 C12 115.4(3) . .
O6 C17 C12 118.5(3) . .
O7 C17 Eu1 89.13(18) . .
O6 C17 Eu1 37.67(15) . .
C12 C17 Eu1 154.2(2) . .
C29 C18 N8 124.5(4) . .
C29 C18 H18 117.8 . .
N8 C18 H18 117.8 . .
C12 C19 C25 118.1(3) . .
C12 C19 H19 120.9 . .
C25 C19 H19 120.9 . .
C14 C20 C27 119.0(3) . .
C14 C20 H20 120.5 . .
C27 C20 H20 120.5 . .
C28 C21 C26 118.2(3) . .
C28 C21 C5 121.2(3) . .
C26 C21 C5 120.6(3) . .
N7 C22 C25 122.8(3) . .
N7 C22 H22 118.6 . .
C25 C22 H22 118.6 . .
N2 C23 C14 123.9(3) . .
N2 C23 H23 118.0 . .
C14 C23 H23 118.0 . .
N2 C24 C27 122.8(3) . .
N2 C24 H24 118.6 . .
C27 C24 H24 118.6 . .
C22 C25 C19 119.8(3) . .
C22 C25 H25 120.1 . .
C19 C25 H25 120.1 . .
C21 C26 N8 119.6(4) . .
C21 C26 H26 120.2 . .
N8 C26 H26 120.2 . .
C24 C27 C20 119.5(4) . .
C24 C27 H27 120.3 . .
C20 C27 H27 120.3 . .
C29 C28 C21 122.6(4) . .
C29 C28 H28 118.7 . .
C21 C28 H28 118.7 . .
C18 C29 C28 118.2(4) . .
C18 C29 H29 120.9 . .
C28 C29 H29 120.9 . .
O10 C30 O12 126.8(3) . .
O10 C30 C14 115.4(3) . .
O12 C30 C14 117.9(3) . .
O10 Co1 O5 88.19(9) 2_767 .
O10 Co1 N1 90.52(11) 2_767 .
O5 Co1 N1 97.51(10) . .
O10 Co1 O2 174.52(9) 2_767 .
O5 Co1 O2 87.10(9) . .
N1 Co1 O2 87.31(10) . .
O10 Co1 N2 92.23(10) 2_767 .
O5 Co1 N2 169.45(10) . .
N1 Co1 N2 93.03(11) . .
O2 Co1 N2 92.92(10) . .
O10 Co1 N3 86.54(11) 2_767 .
O5 Co1 N3 85.56(10) . .
N1 Co1 N3 175.69(9) . .
O2 Co1 N3 95.89(10) . .
N2 Co1 N3 83.94(11) . .
O10 Co1 Eu1 100.18(8) 2_767 .
O5 Co1 Eu1 42.82(6) . .
N1 Co1 Eu1 137.64(7) . .
O2 Co1 Eu1 78.18(7) . .
N2 Co1 Eu1 126.92(8) . .
N3 Co1 Eu1 46.23(7) . .
O9 Co2 O7 94.77(10) . .
O9 Co2 O5 92.21(9) . .
O7 Co2 O5 94.61(10) . .
O9 Co2 O12 175.34(9) . 2_767
O7 Co2 O12 83.88(10) . 2_767
O5 Co2 O12 92.34(9) . 2_767
O9 Co2 N7 88.15(10) . 2_777
O7 Co2 N7 86.12(11) . 2_777
O5 Co2 N7 179.15(10) . 2_777
O12 Co2 N7 87.31(10) 2_767 2_777
O9 Co2 N6 88.62(10) . 2_766
O7 Co2 N6 172.48(10) . 2_766
O5 Co2 N6 91.95(10) . 2_766
O12 Co2 N6 92.20(10) 2_767 2_766
N7 Co2 N6 87.29(11) 2_777 2_766
O9 Co2 Eu1 72.98(7) . .
O7 Co2 Eu1 66.60(8) . .
O5 Co2 Eu1 36.19(6) . .
O12 Co2 Eu1 110.39(7) 2_767 .
N7 Co2 Eu1 144.66(8) 2_777 .
N6 Co2 Eu1 120.87(7) 2_766 .
O8 Eu1 O4 99.37(9) . 1_455
O8 Eu1 O5 89.79(8) . .
O4 Eu1 O5 169.90(8) 1_455 .
O8 Eu1 O1 139.46(8) . .
O4 Eu1 O1 86.59(9) 1_455 .
O5 Eu1 O1 89.20(9) . .
O8 Eu1 O6 79.62(9) . .
O4 Eu1 O6 85.21(9) 1_455 .
O5 Eu1 O6 92.33(9) . .
O1 Eu1 O6 140.90(8) . .
O8 Eu1 N3 146.69(9) . .
O4 Eu1 N3 95.74(9) 1_455 .
O5 Eu1 N3 74.19(9) . .
O1 Eu1 N3 70.66(9) . .
O6 Eu1 N3 72.25(9) . .
O8 Eu1 O3 72.35(8) . 2_766
O4 Eu1 O3 119.61(8) 1_455 2_766
O5 Eu1 O3 67.17(7) . 2_766
O1 Eu1 O3 70.01(8) . 2_766
O6 Eu1 O3 144.81(8) . 2_766
N3 Eu1 O3 124.09(9) . 2_766
O8 Eu1 O4 72.91(8) . 2_766
O4 Eu1 O4 73.12(8) 1_455 2_766
O5 Eu1 O4 114.03(7) . 2_766
O1 Eu1 O4 70.65(8) . 2_766
O6 Eu1 O4 141.22(8) . 2_766
N3 Eu1 O4 140.23(8) . 2_766
O3 Eu1 O4 46.87(7) 2_766 2_766
O8 Eu1 C6 71.45(8) . 2_766
O4 Eu1 C6 96.88(9) 1_455 2_766
O5 Eu1 C6 90.03(8) . 2_766
O1 Eu1 C6 68.02(8) . 2_766
O6 Eu1 C6 150.97(8) . 2_766
N3 Eu1 C6 135.78(9) . 2_766
O3 Eu1 C6 22.87(8) 2_766 2_766
O4 Eu1 C6 24.01(7) 2_766 2_766
O8 Eu1 C5 18.23(8) . .
O4 Eu1 C5 115.39(9) 1_455 .
O5 Eu1 C5 74.35(8) . .
O1 Eu1 C5 127.65(8) . .
O6 Eu1 C5 90.06(8) . .
N3 Eu1 C5 142.97(9) . .
O3 Eu1 C5 57.73(8) 2_766 .
O4 Eu1 C5 71.82(8) 2_766 .
C6 Eu1 C5 62.80(8) 2_766 .
O8 Eu1 C9 131.76(8) . .
O4 Eu1 C9 105.36(9) 1_455 .
O5 Eu1 C9 70.91(8) . .
O1 Eu1 C9 18.83(8) . .
O6 Eu1 C9 142.30(8) . .
N3 Eu1 C9 70.76(8) . .
O3 Eu1 C9 59.45(8) 2_766 .
O4 Eu1 C9 75.63(8) 2_766 .
C6 Eu1 C9 65.04(8) 2_766 .
C5 Eu1 C9 115.80(8) . .
O8 Eu1 C17 70.52(8) . .
O4 Eu1 C17 102.89(9) 1_455 .
O5 Eu1 C17 76.06(9) . .
O1 Eu1 C17 147.34(8) . .
O6 Eu1 C17 18.87(8) . .
N3 Eu1 C17 77.27(9) . .
O3 Eu1 C17 126.88(8) 2_766 .
O4 Eu1 C17 141.99(8) 2_766 .
C6 Eu1 C17 139.35(8) 2_766 .
C5 Eu1 C17 76.64(8) . .
C9 Eu1 C17 138.88(8) . .
O8 Eu1 H5A 86.1(7) . .
O4 Eu1 H5A 165.1(8) 1_455 .
O5 Eu1 H5A 18.6(7) . .
O1 Eu1 H5A 80.4(8) . .
O6 Eu1 H5A 109.4(8) . .
N3 Eu1 H5A 86.8(7) . .
O3 Eu1 H5A 48.8(8) 2_766 .
O4 Eu1 H5A 95.6(8) 2_766 .
C6 Eu1 H5A 71.6(8) 2_766 .
C5 Eu1 H5A 68.4(7) . .
C9 Eu1 H5A 61.6(8) . .
C17 Eu1 H5A 91.9(8) . .
C13 N1 C2 117.0(3) . .
C13 N1 Co1 122.0(2) . .
C2 N1 Co1 121.0(2) . .
C24 N2 C23 117.0(3) . .
C24 N2 Co1 122.8(2) . .
C23 N2 Co1 116.6(2) . .
N4 N3 Co1 119.6(2) . .
N4 N3 Eu1 134.2(2) . .
Co1 N3 Eu1 94.01(10) . .
N5 N4 N3 178.4(4) . .
C1 N6 C3 117.4(3) . .
C1 N6 Co2 117.8(2) . 2_766
C3 N6 Co2 124.8(2) . 2_766
C22 N7 C15 116.9(3) . .
C22 N7 Co2 123.5(2) . 2_777
C15 N7 Co2 119.6(2) . 2_777
C18 N8 C26 116.9(4) . .
C9 O1 Eu1 123.9(2) . .
C9 O2 Co1 124.8(2) . .
C6 O3 Eu1 105.77(18) . 2_766
C6 O4 Eu1 165.2(2) . 1_655
C6 O4 Eu1 85.44(17) . 2_766
Eu1 O4 Eu1 106.88(8) 1_655 2_766
Co1 O5 Co2 129.78(10) . .
Co1 O5 Eu1 99.91(9) . .
Co2 O5 Eu1 112.05(10) . .
Co1 O5 H5A 110(2) . .
Co2 O5 H5A 101(2) . .
Eu1 O5 H5A 101(2) . .
C17 O6 Eu1 123.5(2) . .
C17 O7 Co2 141.6(2) . .
C5 O8 Eu1 126.7(2) . .
C5 O9 Co2 127.6(2) . .
C30 O10 Co1 138.3(2) . 2_767
C30 O12 Co2 127.0(2) . 2_767
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N6 1.343(4) .
C1 C11 1.380(5) .
C1 H1 0.9300 .
C2 N1 1.340(4) .
C2 C16 1.372(5) .
C2 H2 0.9300 .
C3 N6 1.346(4) .
C3 C7 1.384(4) .
C3 H3 0.9300 .
C4 C11 1.382(4) .
C4 C7 1.384(4) .
C4 H4 0.9300 .
C5 O9 1.257(4) .
C5 O8 1.262(4) .
C5 C21 1.505(4) .
C5 Eu1 3.233(3) .
C6 O3 1.253(4) .
C6 O4 1.266(4) .
C6 C8 1.496(4) .
C6 Eu1 3.103(3) 2_766
C7 C9 1.515(4) .
C8 C13 1.376(4) .
C8 C10 1.385(4) .
C9 O2 1.254(4) .
C9 O1 1.257(4) .
C9 Eu1 3.233(3) .
C10 C16 1.379(5) .
C10 H10 0.9300 .
C11 H11 0.9300 .
C12 C19 1.380(5) .
C12 C15 1.385(4) .
C12 C17 1.507(4) .
C13 N1 1.336(4) .
C13 H13 0.9300 .
C14 C20 1.378(5) .
C14 C23 1.390(4) .
C14 C30 1.505(4) .
C15 N7 1.338(4) .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 O7 1.252(4) .
C17 O6 1.257(4) .
C17 Eu1 3.241(3) .
C18 C29 1.308(6) .
C18 N8 1.380(6) .
C18 H18 0.9300 .
C19 C25 1.391(5) .
C19 H19 0.9300 .
C20 C27 1.381(5) .
C20 H20 0.9300 .
C21 C28 1.381(5) .
C21 C26 1.382(5) .
C22 N7 1.335(4) .
C22 C25 1.376(5) .
C22 H22 0.9300 .
C23 N2 1.344(4) .
C23 H23 0.9300 .
C24 N2 1.340(5) .
C24 C27 1.378(5) .
C24 H24 0.9300 .
C25 H25 0.9300 .
C26 N8 1.386(5) .
C26 H26 0.9300 .
C27 H27 0.9300 .
C28 C29 1.330(5) .
C28 H28 0.9300 .
C29 H29 0.9300 .
C30 O10 1.253(4) .
C30 O12 1.256(4) .
Co1 O10 2.072(2) 2_767
Co1 O5 2.102(2) .
Co1 N1 2.140(3) .
Co1 O2 2.157(2) .
Co1 N2 2.171(3) .
Co1 N3 2.192(3) .
Co1 Eu1 3.4191(11) .
Co2 O9 2.092(2) .
Co2 O7 2.100(2) .
Co2 O5 2.103(2) .
Co2 O12 2.120(2) 2_767
Co2 N7 2.141(3) 2_777
Co2 N6 2.164(3) 2_766
Co2 Eu1 3.703(2) .
Eu1 O8 2.315(2) .
Eu1 O4 2.318(2) 1_455
Eu1 O5 2.359(2) .
Eu1 O1 2.359(2) .
Eu1 O6 2.374(2) .
Eu1 N3 2.475(3) .
Eu1 O3 2.519(2) 2_766
Eu1 O4 2.936(2) 2_766
Eu1 C6 3.103(3) 2_766
Eu1 H5A 2.67(4) .
N3 N4 1.198(4) .
N4 N5 1.145(4) .
N6 Co2 2.164(3) 2_766
N7 Co2 2.141(3) 2_777
O3 Eu1 2.519(2) 2_766
O4 Eu1 2.318(2) 1_655
O4 Eu1 2.936(2) 2_766
O5 H5A 0.87(4) .
O10 Co1 2.072(2) 2_767
O12 Co2 2.120(2) 2_767
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N6 C3 C7 C4 2.9(5) . .
N6 C3 C7 C9 -170.9(3) . .
C11 C4 C7 C3 -1.6(5) . .
C11 C4 C7 C9 172.3(3) . .
O3 C6 C8 C13 -6.3(4) . .
O4 C6 C8 C13 173.7(3) . .
Eu1 C6 C8 C13 3.1(13) 2_766 .
O3 C6 C8 C10 174.2(3) . .
O4 C6 C8 C10 -5.8(5) . .
Eu1 C6 C8 C10 -176.5(9) 2_766 .
C3 C7 C9 O2 -14.1(4) . .
C4 C7 C9 O2 172.1(3) . .
C3 C7 C9 O1 163.0(3) . .
C4 C7 C9 O1 -10.7(4) . .
C3 C7 C9 Eu1 122.4(3) . .
C4 C7 C9 Eu1 -51.3(4) . .
C13 C8 C10 C16 0.2(6) . .
C6 C8 C10 C16 179.7(4) . .
N6 C1 C11 C4 2.0(6) . .
C7 C4 C11 C1 -0.7(6) . .
C10 C8 C13 N1 1.3(5) . .
C6 C8 C13 N1 -178.2(3) . .
C19 C12 C15 N7 -1.4(5) . .
C17 C12 C15 N7 -175.3(3) . .
N1 C2 C16 C10 1.9(7) . .
C8 C10 C16 C2 -1.6(7) . .
C19 C12 C17 O7 -149.5(4) . .
C15 C12 C17 O7 24.1(5) . .
C19 C12 C17 O6 29.8(5) . .
C15 C12 C17 O6 -156.6(3) . .
C19 C12 C17 Eu1 11.0(7) . .
C15 C12 C17 Eu1 -175.4(4) . .
C15 C12 C19 C25 -1.2(6) . .
C17 C12 C19 C25 172.5(4) . .
C23 C14 C20 C27 0.2(6) . .
C30 C14 C20 C27 177.5(4) . .
O9 C5 C21 C28 0.5(5) . .
O8 C5 C21 C28 -178.8(4) . .
Eu1 C5 C21 C28 -140.5(3) . .
O9 C5 C21 C26 178.6(3) . .
O8 C5 C21 C26 -0.7(5) . .
Eu1 C5 C21 C26 37.5(5) . .
C20 C14 C23 N2 2.1(5) . .
C30 C14 C23 N2 -175.3(3) . .
N7 C22 C25 C19 0.3(8) . .
C12 C19 C25 C22 1.7(8) . .
C28 C21 C26 N8 0.9(6) . .
C5 C21 C26 N8 -177.2(4) . .
N2 C24 C27 C20 0.4(7) . .
C14 C20 C27 C24 -1.4(7) . .
C26 C21 C28 C29 -0.8(7) . .
C5 C21 C28 C29 177.4(5) . .
N8 C18 C29 C28 -3.2(9) . .
C21 C28 C29 C18 1.8(9) . .
C20 C14 C30 O10 -175.7(3) . .
C23 C14 C30 O10 1.6(5) . .
C20 C14 C30 O12 3.6(5) . .
C23 C14 C30 O12 -179.1(3) . .
O9 C5 Eu1 O8 139.7(4) . .
C21 C5 Eu1 O8 -74.8(4) . .
O9 C5 Eu1 O4 169.83(17) . 1_455
O8 C5 Eu1 O4 30.1(3) . 1_455
C21 C5 Eu1 O4 -44.7(3) . 1_455
O9 C5 Eu1 O5 -7.29(18) . .
O8 C5 Eu1 O5 -147.0(3) . .
C21 C5 Eu1 O5 138.2(3) . .
O9 C5 Eu1 O1 -83.7(2) . .
O8 C5 Eu1 O1 136.5(2) . .
C21 C5 Eu1 O1 61.8(3) . .
O9 C5 Eu1 O6 85.11(19) . .
O8 C5 Eu1 O6 -54.6(3) . .
C21 C5 Eu1 O6 -129.4(3) . .
O9 C5 Eu1 N3 25.4(3) . .
O8 C5 Eu1 N3 -114.3(3) . .
C21 C5 Eu1 N3 170.9(3) . .
O9 C5 Eu1 O3 -79.86(19) . 2_766
O8 C5 Eu1 O3 140.4(3) . 2_766
C21 C5 Eu1 O3 65.6(3) . 2_766
O9 C5 Eu1 O4 -129.8(2) . 2_766
O8 C5 Eu1 O4 90.5(2) . 2_766
C21 C5 Eu1 O4 15.7(3) . 2_766
O9 C5 Eu1 C6 -105.6(2) . 2_766
O8 C5 Eu1 C6 114.7(3) . 2_766
C21 C5 Eu1 C6 39.9(3) . 2_766
O9 C5 Eu1 C9 -66.5(2) . .
O8 C5 Eu1 C9 153.8(2) . .
C21 C5 Eu1 C9 79.0(3) . .
O9 C5 Eu1 C17 71.72(19) . .
O8 C5 Eu1 C17 -68.0(2) . .
C21 C5 Eu1 C17 -142.8(3) . .
O2 C9 Eu1 O8 97.27(19) . .
O1 C9 Eu1 O8 -122.6(2) . .
C7 C9 Eu1 O8 -45.3(3) . .
O2 C9 Eu1 O4 -144.59(18) . 1_455
O1 C9 Eu1 O4 -4.4(2) . 1_455
C7 C9 Eu1 O4 72.9(3) . 1_455
O2 C9 Eu1 O5 25.58(17) . .
O1 C9 Eu1 O5 165.7(2) . .
C7 C9 Eu1 O5 -117.0(3) . .
O2 C9 Eu1 O1 -140.2(3) . .
C7 C9 Eu1 O1 77.3(3) . .
O2 C9 Eu1 O6 -42.2(2) . .
O1 C9 Eu1 O6 97.9(3) . .
C7 C9 Eu1 O6 175.2(2) . .
O2 C9 Eu1 N3 -53.79(18) . .
O1 C9 Eu1 N3 86.4(2) . .
C7 C9 Eu1 N3 163.7(3) . .
O2 C9 Eu1 O3 99.76(19) . 2_766
O1 C9 Eu1 O3 -120.1(2) . 2_766
C7 C9 Eu1 O3 -42.8(2) . 2_766
O2 C9 Eu1 O4 147.82(19) . 2_766
O1 C9 Eu1 O4 -72.0(2) . 2_766
C7 C9 Eu1 O4 5.3(2) . 2_766
O2 C9 Eu1 C6 124.9(2) . 2_766
O1 C9 Eu1 C6 -95.0(2) . 2_766
C7 C9 Eu1 C6 -17.7(2) . 2_766
O2 C9 Eu1 C5 86.61(19) . .
O1 C9 Eu1 C5 -133.2(2) . .
C7 C9 Eu1 C5 -55.9(3) . .
O2 C9 Eu1 C17 -12.8(2) . .
O1 C9 Eu1 C17 127.4(2) . .
C7 C9 Eu1 C17 -155.3(2) . .
O7 C17 Eu1 O8 -53.5(2) . .
O6 C17 Eu1 O8 116.4(3) . .
C12 C17 Eu1 O8 144.0(5) . .
O7 C17 Eu1 O4 -149.1(2) . 1_455
O6 C17 Eu1 O4 20.9(3) . 1_455
C12 C17 Eu1 O4 48.5(5) . 1_455
O7 C17 Eu1 O5 41.3(2) . .
O6 C17 Eu1 O5 -148.8(3) . .
C12 C17 Eu1 O5 -121.2(5) . .
O7 C17 Eu1 O1 106.8(2) . .
O6 C17 Eu1 O1 -83.3(3) . .
C12 C17 Eu1 O1 -55.6(6) . .
O7 C17 Eu1 O6 -169.9(4) . .
C12 C17 Eu1 O6 27.6(4) . .
O7 C17 Eu1 N3 117.9(2) . .
O6 C17 Eu1 N3 -72.2(3) . .
C12 C17 Eu1 N3 -44.6(5) . .
O7 C17 Eu1 O3 -5.4(2) . 2_766
O6 C17 Eu1 O3 164.5(2) . 2_766
C12 C17 Eu1 O3 -167.9(5) . 2_766
O7 C17 Eu1 O4 -70.1(2) . 2_766
O6 C17 Eu1 O4 99.8(3) . 2_766
C12 C17 Eu1 O4 127.5(5) . 2_766
O7 C17 Eu1 C6 -32.0(3) . 2_766
O6 C17 Eu1 C6 137.9(3) . 2_766
C12 C17 Eu1 C6 165.6(5) . 2_766
O7 C17 Eu1 C5 -35.6(2) . .
O6 C17 Eu1 C5 134.3(3) . .
C12 C17 Eu1 C5 161.9(5) . .
O7 C17 Eu1 C9 78.4(2) . .
O6 C17 Eu1 C9 -111.6(3) . .
C12 C17 Eu1 C9 -84.0(5) . .
C8 C13 N1 C2 -1.2(5) . .
C8 C13 N1 Co1 179.4(2) . .
C16 C2 N1 C13 -0.4(6) . .
C16 C2 N1 Co1 179.0(3) . .
O10 Co1 N1 C13 -147.4(3) 2_767 .
O5 Co1 N1 C13 -59.1(3) . .
O2 Co1 N1 C13 27.6(3) . .
N2 Co1 N1 C13 120.4(3) . .
N3 Co1 N1 C13 165.6(14) . .
Eu1 Co1 N1 C13 -41.6(3) . .
O10 Co1 N1 C2 33.2(3) 2_767 .
O5 Co1 N1 C2 121.5(3) . .
O2 Co1 N1 C2 -151.8(3) . .
N2 Co1 N1 C2 -59.0(3) . .
N3 Co1 N1 C2 -13.8(16) . .
Eu1 Co1 N1 C2 139.0(3) . .
C27 C24 N2 C23 1.8(6) . .
C27 C24 N2 Co1 -155.9(3) . .
C14 C23 N2 C24 -3.1(5) . .
C14 C23 N2 Co1 156.0(3) . .
O10 Co1 N2 C24 162.3(3) 2_767 .
O5 Co1 N2 C24 70.2(6) . .
N1 Co1 N2 C24 -107.1(3) . .
O2 Co1 N2 C24 -19.6(3) . .
N3 Co1 N2 C24 76.0(3) . .
Eu1 Co1 N2 C24 57.7(3) . .
O10 Co1 N2 C23 4.4(2) 2_767 .
O5 Co1 N2 C23 -87.7(5) . .
N1 Co1 N2 C23 95.0(2) . .
O2 Co1 N2 C23 -177.5(2) . .
N3 Co1 N2 C23 -81.9(2) . .
Eu1 Co1 N2 C23 -100.1(2) . .
O10 Co1 N3 N4 -39.9(3) 2_767 .
O5 Co1 N3 N4 -128.3(3) . .
N1 Co1 N3 N4 7.2(16) . .
O2 Co1 N3 N4 145.0(3) . .
N2 Co1 N3 N4 52.7(3) . .
Eu1 Co1 N3 N4 -147.5(3) . .
O10 Co1 N3 Eu1 107.65(10) 2_767 .
O5 Co1 N3 Eu1 19.19(9) . .
N1 Co1 N3 Eu1 154.7(14) . .
O2 Co1 N3 Eu1 -67.42(10) . .
N2 Co1 N3 Eu1 -159.74(11) . .
O8 Eu1 N3 N4 57.7(4) . .
O4 Eu1 N3 N4 -59.2(3) 1_455 .
O5 Eu1 N3 N4 121.7(3) . .
O1 Eu1 N3 N4 -143.5(4) . .
O6 Eu1 N3 N4 23.9(3) . .
O3 Eu1 N3 N4 169.0(3) 2_766 .
O4 Eu1 N3 N4 -129.6(3) 2_766 .
C6 Eu1 N3 N4 -165.2(3) 2_766 .
C5 Eu1 N3 N4 88.9(4) . .
C9 Eu1 N3 N4 -163.4(4) . .
C17 Eu1 N3 N4 42.8(3) . .
O8 Eu1 N3 Co1 -81.70(17) . .
O4 Eu1 N3 Co1 161.48(10) 1_455 .
O5 Eu1 N3 Co1 -17.67(8) . .
O1 Eu1 N3 Co1 77.15(11) . .
O6 Eu1 N3 Co1 -115.43(12) . .
O3 Eu1 N3 Co1 29.60(14) 2_766 .
O4 Eu1 N3 Co1 91.08(14) 2_766 .
C6 Eu1 N3 Co1 55.46(16) 2_766 .
C5 Eu1 N3 Co1 -50.43(17) . .
C9 Eu1 N3 Co1 57.19(10) . .
C17 Eu1 N3 Co1 -96.56(11) . .
Co1 N3 N4 N5 -104(14) . .
Eu1 N3 N4 N5 124(14) . .
C11 C1 N6 C3 -0.7(5) . .
C11 C1 N6 Co2 -178.9(3) . 2_766
C7 C3 N6 C1 -1.7(5) . .
C7 C3 N6 Co2 176.3(2) . 2_766
C25 C22 N7 C15 -2.7(6) . .
C25 C22 N7 Co2 176.9(4) . 2_777
C12 C15 N7 C22 3.3(5) . .
C12 C15 N7 Co2 -176.3(3) . 2_777
C29 C18 N8 C26 3.4(9) . .
C21 C26 N8 C18 -2.1(8) . .
O2 C9 O1 Eu1 51.3(4) . .
C7 C9 O1 Eu1 -125.6(2) . .
O8 Eu1 O1 C9 75.3(3) . .
O4 Eu1 O1 C9 175.7(2) 1_455 .
O5 Eu1 O1 C9 -13.5(2) . .
O6 Eu1 O1 C9 -106.2(2) . .
N3 Eu1 O1 C9 -87.0(2) . .
O3 Eu1 O1 C9 52.5(2) 2_766 .
O4 Eu1 O1 C9 102.4(2) 2_766 .
C6 Eu1 O1 C9 76.9(2) 2_766 .
C5 Eu1 O1 C9 56.0(3) . .
C17 Eu1 O1 C9 -75.5(3) . .
O1 C9 O2 Co1 -8.8(4) . .
C7 C9 O2 Co1 168.0(2) . .
Eu1 C9 O2 Co1 19.8(2) . .
O10 Co1 O2 C9 -92.0(10) 2_767 .
O5 Co1 O2 C9 -61.2(2) . .
N1 Co1 O2 C9 -158.8(2) . .
N2 Co1 O2 C9 108.3(2) . .
N3 Co1 O2 C9 24.1(2) . .
Eu1 Co1 O2 C9 -18.9(2) . .
O4 C6 O3 Eu1 -2.3(3) . 2_766
C8 C6 O3 Eu1 177.7(2) . 2_766
O3 C6 O4 Eu1 148.8(7) . 1_655
C8 C6 O4 Eu1 -31.2(10) . 1_655
Eu1 C6 O4 Eu1 146.9(8) 2_766 1_655
O3 C6 O4 Eu1 1.9(3) . 2_766
C8 C6 O4 Eu1 -178.1(3) . 2_766
O10 Co1 O5 Co2 22.79(14) 2_767 .
N1 Co1 O5 Co2 -67.50(15) . .
O2 Co1 O5 Co2 -154.40(14) . .
N2 Co1 O5 Co2 115.2(5) . .
N3 Co1 O5 Co2 109.46(15) . .
Eu1 Co1 O5 Co2 129.90(17) . .
O10 Co1 O5 Eu1 -107.12(10) 2_767 .
N1 Co1 O5 Eu1 162.60(9) . .
O2 Co1 O5 Eu1 75.69(9) . .
N2 Co1 O5 Eu1 -14.7(5) . .
N3 Co1 O5 Eu1 -20.45(9) . .
O9 Co2 O5 Co1 177.92(14) . .
O7 Co2 O5 Co1 -87.11(15) . .
O12 Co2 O5 Co1 -3.06(15) 2_767 .
N7 Co2 O5 Co1 62(6) 2_777 .
N6 Co2 O5 Co1 89.23(14) 2_766 .
Eu1 Co2 O5 Co1 -125.38(18) . .
O9 Co2 O5 Eu1 -56.70(10) . .
O7 Co2 O5 Eu1 38.27(11) . .
O12 Co2 O5 Eu1 122.32(10) 2_767 .
N7 Co2 O5 Eu1 -172(40) 2_777 .
N6 Co2 O5 Eu1 -145.39(10) 2_766 .
O8 Eu1 O5 Co1 169.12(8) . .
O4 Eu1 O5 Co1 13.9(5) 1_455 .
O1 Eu1 O5 Co1 -51.41(8) . .
O6 Eu1 O5 Co1 89.51(9) . .
N3 Eu1 O5 Co1 18.70(9) . .
O3 Eu1 O5 Co1 -120.00(10) 2_766 .
O4 Eu1 O5 Co1 -119.75(8) 2_766 .
C6 Eu1 O5 Co1 -119.43(9) 2_766 .
C5 Eu1 O5 Co1 178.92(9) . .
C9 Eu1 O5 Co1 -55.97(8) . .
C17 Eu1 O5 Co1 99.16(9) . .
O8 Eu1 O5 Co2 28.61(9) . .
O4 Eu1 O5 Co2 -126.6(4) 1_455 .
O1 Eu1 O5 Co2 168.09(9) . .
O6 Eu1 O5 Co2 -50.99(10) . .
N3 Eu1 O5 Co2 -121.80(11) . .
O3 Eu1 O5 Co2 99.50(11) 2_766 .
O4 Eu1 O5 Co2 99.75(10) 2_766 .
C6 Eu1 O5 Co2 100.07(10) 2_766 .
C5 Eu1 O5 Co2 38.42(9) . .
C9 Eu1 O5 Co2 163.53(11) . .
C17 Eu1 O5 Co2 -41.34(9) . .
O7 C17 O6 Eu1 12.5(5) . .
C12 C17 O6 Eu1 -166.7(2) . .
O8 Eu1 O6 C17 -59.2(3) . .
O4 Eu1 O6 C17 -159.6(3) 1_455 .
O5 Eu1 O6 C17 30.2(3) . .
O1 Eu1 O6 C17 121.8(3) . .
N3 Eu1 O6 C17 102.8(3) . .
O3 Eu1 O6 C17 -21.8(3) 2_766 .
O4 Eu1 O6 C17 -104.3(3) 2_766 .
C6 Eu1 O6 C17 -64.1(3) 2_766 .
C5 Eu1 O6 C17 -44.1(3) . .
C9 Eu1 O6 C17 91.3(3) . .
O6 C17 O7 Co2 -46.3(6) . .
C12 C17 O7 Co2 133.0(3) . .
Eu1 C17 O7 Co2 -38.7(4) . .
O9 Co2 O7 C17 105.7(4) . .
O5 Co2 O7 C17 13.1(4) . .
O12 Co2 O7 C17 -78.8(4) 2_767 .
N7 Co2 O7 C17 -166.5(4) 2_777 .
N6 Co2 O7 C17 -137.7(7) 2_766 .
Eu1 Co2 O7 C17 36.6(3) . .
O9 C5 O8 Eu1 -51.4(4) . .
C21 C5 O8 Eu1 127.8(3) . .
O4 Eu1 O8 C5 -152.7(2) 1_455 .
O5 Eu1 O8 C5 31.6(2) . .
O1 Eu1 O8 C5 -56.9(3) . .
O6 Eu1 O8 C5 124.0(3) . .
N3 Eu1 O8 C5 91.5(3) . .
O3 Eu1 O8 C5 -34.4(2) 2_766 .
O4 Eu1 O8 C5 -83.7(2) 2_766 .
C6 Eu1 O8 C5 -58.5(2) 2_766 .
C9 Eu1 O8 C5 -32.2(3) . .
C17 Eu1 O8 C5 106.9(3) . .
O8 C5 O9 Co2 -4.4(5) . .
C21 C5 O9 Co2 176.3(2) . .
Eu1 C5 O9 Co2 -31.6(3) . .
O7 Co2 O9 C5 -35.7(3) . .
O5 Co2 O9 C5 59.1(3) . .
O12 Co2 O9 C5 -108.8(11) 2_767 .
N7 Co2 O9 C5 -121.7(3) 2_777 .
N6 Co2 O9 C5 151.0(3) 2_766 .
Eu1 Co2 O9 C5 28.0(2) . .
O12 C30 O10 Co1 -2.2(6) . 2_767
C14 C30 O10 Co1 177.1(2) . 2_767
O10 C30 O12 Co2 -43.5(5) . 2_767
C14 C30 O12 Co2 137.3(2) . 2_767
