#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/39/4503978.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4503978
loop_
_publ_author_name
'Chen, Huan-Ching'
'Hu, Hui-Ling'
'Chan, Zhi-Kai'
'Yeh, Chun-Wei'
'Jia, Hsi-Wei'
'Wu, Chi-Phi'
'Chen, Jhy-Der'
'Wang, Ju-Chun'
_publ_section_title
;
 Ag(I) Complexes Containing FlexibleN,N‘-Di(2-pyridyl)adipoamide
 Ligands:  Syntheses, Structures, and Ligand Conformations
;
_journal_issue                   4
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              698
_journal_paper_doi               10.1021/cg060619y
_journal_volume                  7
_journal_year                    2007
_chemical_formula_sum            'C18 H22 Ag B F4 N5 O2.5'
_chemical_formula_weight         543.09
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           1
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  'P 1'
_symmetry_space_group_name_H-M   'P 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                111.007(8)
_cell_angle_beta                 93.701(12)
_cell_angle_gamma                93.778(10)
_cell_formula_units_Z            2
_cell_length_a                   9.8724(18)
_cell_length_b                   10.2111(11)
_cell_length_c                   11.5477(12)
_cell_measurement_reflns_used    25
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      12.36
_cell_measurement_theta_min      6.36
_cell_volume                     1079.5(3)
_computing_cell_refinement       'Bruker XSCANS'
_computing_data_collection       'Bruker XSCANS'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      295(2)
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Bruker P4'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0283
_diffrn_reflns_limit_h_max       1
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            4402
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.90
_diffrn_standards_interval_count 100
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    0.995
_exptl_absorpt_correction_T_max  0.4129
_exptl_absorpt_correction_T_min  0.3924
_exptl_absorpt_correction_type   empirical
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.671
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             546
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.3
_exptl_crystal_size_min          0.2
_refine_diff_density_max         0.698
_refine_diff_density_min         -0.399
_refine_diff_density_rms         0.072
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.11(6)
_refine_ls_extinction_coef       0.0003(2)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     553
_refine_ls_number_reflns         4402
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.0639
_refine_ls_R_factor_gt           0.0421
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+3.6358P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0750
_refine_ls_wR_factor_ref         0.0846
_reflns_number_gt                3301
_reflns_number_total             4402
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg060619ysi20061229_020634.cif
_cod_data_source_block           5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P1
_cod_original_formula_sum        'C18 H22 Ag B F4 N5 O2.50'
_cod_database_code               4503978
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag -0.49675(8) 0.76258(8) 1.03391(7) 0.0535(5) Uani 1 1 d .
Ag2 Ag 0.01545(8) 0.75291(8) 0.02628(7) 0.0527(5) Uani 1 1 d .
O1 O -0.1150(14) 0.6202(17) 0.7557(14) 0.059(4) Uani 1 1 d .
O2 O -0.3739(13) 0.8938(15) 0.3012(14) 0.050(4) Uani 1 1 d .
O3 O 0.3919(13) 0.6371(17) -0.2307(14) 0.056(4) Uani 1 1 d .
O4 O 0.1198(14) 0.8706(17) -0.7107(14) 0.056(4) Uani 1 1 d .
N1 N -0.3560(14) 0.6046(15) 1.0152(15) 0.039(4) Uani 1 1 d .
N2 N -0.3237(15) 0.5965(16) 0.8219(14) 0.040(4) Uani 1 1 d .
H2N H -0.4199 0.6027 0.8038 0.048 Uiso 1 1 d R
N3 N -0.1605(15) 0.9088(17) 0.2416(13) 0.039(4) Uani 1 1 d .
H3N H -0.0711 0.9065 0.2641 0.047 Uiso 1 1 d R
N4 N -0.1169(14) 0.9071(16) 0.0430(15) 0.043(4) Uani 1 1 d .
N5 N 0.1522(17) 0.5969(17) 0.0081(14) 0.043(4) Uani 1 1 d .
N6 N 0.1804(12) 0.5796(16) -0.1881(14) 0.041(4) Uani 1 1 d .
H6N H 0.0834 0.5936 -0.1950 0.049 Uiso 1 1 d R
N7 N 0.3334(15) 0.9237(17) -0.7460(14) 0.044(4) Uani 1 1 d .
H7N H 0.4165 0.9298 -0.7092 0.053 Uiso 1 1 d R
N8 N 0.3667(16) 0.9232(16) -0.9488(15) 0.042(4) Uani 1 1 d .
C1 C -0.3420(17) 0.5610(17) 1.1110(14) 0.040(4) Uani 1 1 d .
H1A H -0.3980 0.5919 1.1753 0.048 Uiso 1 1 calc R
C2 C -0.245(2) 0.470(2) 1.116(2) 0.066(6) Uani 1 1 d .
H2B H -0.2296 0.4412 1.1826 0.079 Uiso 1 1 calc R
C3 C -0.171(2) 0.426(2) 1.007(2) 0.067(6) Uani 1 1 d .
H3B H -0.1005 0.3709 1.0083 0.080 Uiso 1 1 calc R
C4 C -0.1922(19) 0.455(2) 0.907(2) 0.055(5) Uani 1 1 d .
H4A H -0.1493 0.4142 0.8348 0.066 Uiso 1 1 calc R
C5 C -0.2807(19) 0.548(2) 0.9186(16) 0.046(5) Uani 1 1 d .
C6 C -0.2390(15) 0.6284(17) 0.7462(15) 0.034(4) Uani 1 1 d .
C7 C -0.3062(18) 0.6880(19) 0.6532(15) 0.044(4) Uani 1 1 d .
H7B H -0.3523 0.7692 0.6992 0.053 Uiso 1 1 calc R
H7C H -0.3746 0.6172 0.5973 0.053 Uiso 1 1 calc R
C8 C -0.2013(19) 0.733(2) 0.5731(16) 0.050(5) Uani 1 1 d .
H8B H -0.1325 0.8047 0.6281 0.060 Uiso 1 1 calc R
H8C H -0.1559 0.6527 0.5252 0.060 Uiso 1 1 calc R
C9 C -0.2751(16) 0.7913(19) 0.4863(16) 0.041(4) Uani 1 1 d .
H9A H -0.3434 0.7191 0.4319 0.049 Uiso 1 1 calc R
H9B H -0.3222 0.8702 0.5352 0.049 Uiso 1 1 calc R
C10 C -0.1861(17) 0.838(2) 0.4099(17) 0.053(5) Uani 1 1 d .
H10A H -0.1252 0.9179 0.4645 0.064 Uiso 1 1 calc R
H10B H -0.1302 0.7628 0.3701 0.064 Uiso 1 1 calc R
C11 C -0.2531(19) 0.878(2) 0.3140(15) 0.047(5) Uani 1 1 d .
C12 C -0.1892(16) 0.9572(15) 0.1419(16) 0.028(4) Uani 1 1 d .
C13 C -0.2919(19) 1.0504(17) 0.1436(17) 0.041(4) Uani 1 1 d .
H13A H -0.3434 1.0797 0.2114 0.050 Uiso 1 1 calc R
C14 C -0.317(2) 1.100(2) 0.0434(18) 0.053(5) Uani 1 1 d .
H14A H -0.3817 1.1622 0.0441 0.064 Uiso 1 1 calc R
C15 C -0.240(2) 1.048(2) -0.0517(16) 0.059(6) Uani 1 1 d .
H15A H -0.2516 1.0763 -0.1197 0.071 Uiso 1 1 calc R
C16 C -0.149(2) 0.960(2) -0.0517(19) 0.064(6) Uani 1 1 d .
H16A H -0.1011 0.9289 -0.1216 0.077 Uiso 1 1 calc R
C17 C 0.175(2) 0.553(2) 0.1048(17) 0.061(6) Uani 1 1 d .
H17A H 0.1272 0.5860 0.1745 0.073 Uiso 1 1 calc R
C18 C 0.275(2) 0.453(2) 0.099(2) 0.072(7) Uani 1 1 d .
H18A H 0.2943 0.4214 0.1635 0.087 Uiso 1 1 calc R
C19 C 0.338(2) 0.4096(19) -0.0081(19) 0.060(5) Uani 1 1 d .
H19A H 0.4055 0.3490 -0.0108 0.072 Uiso 1 1 calc R
C20 C 0.3167(15) 0.4427(17) -0.1100(18) 0.043(4) Uani 1 1 d .
H20A H 0.3614 0.4068 -0.1817 0.051 Uiso 1 1 calc R
C21 C 0.2194(16) 0.5371(18) -0.0941(17) 0.037(4) Uani 1 1 d .
C22 C 0.2657(13) 0.6224(17) -0.2580(14) 0.027(3) Uani 1 1 d .
C23 C 0.1967(17) 0.667(2) -0.3606(16) 0.070(6) Uani 1 1 d .
H23A H 0.1244 0.7255 -0.3263 0.084 Uiso 1 1 calc R
H23B H 0.1552 0.5838 -0.4282 0.084 Uiso 1 1 calc R
C24 C 0.2996(18) 0.7530(18) -0.4155(14) 0.050(4) Uani 1 1 d .
H24A H 0.3299 0.8441 -0.3517 0.060 Uiso 1 1 calc R
H24B H 0.3791 0.7019 -0.4387 0.060 Uiso 1 1 calc R
C25 C 0.2323(15) 0.774(2) -0.5282(16) 0.052(5) Uani 1 1 d .
H25A H 0.2207 0.6837 -0.5967 0.063 Uiso 1 1 calc R
H25B H 0.1420 0.8027 -0.5096 0.063 Uiso 1 1 calc R
C26 C 0.2974(17) 0.869(2) -0.5676(17) 0.064(5) Uani 1 1 d .
H26A H 0.3897 0.8439 -0.5815 0.077 Uiso 1 1 calc R
H26B H 0.3035 0.9607 -0.5014 0.077 Uiso 1 1 calc R
C27 C 0.233(2) 0.880(2) -0.6827(19) 0.058(5) Uani 1 1 d .
C28 C 0.3034(18) 0.9680(18) -0.8500(17) 0.040(5) Uani 1 1 d .
C29 C 0.207(2) 1.060(2) -0.8471(18) 0.056(5) Uani 1 1 d .
H29A H 0.1591 1.0921 -0.7769 0.067 Uiso 1 1 calc R
C30 C 0.1754(19) 1.110(2) -0.947(2) 0.063(6) Uani 1 1 d .
H30A H 0.1119 1.1736 -0.9445 0.076 Uiso 1 1 calc R
C31 C 0.249(2) 1.052(2) -1.0445(14) 0.055(5) Uani 1 1 d .
H31A H 0.2342 1.0749 -1.1152 0.066 Uiso 1 1 calc R
C32 C 0.338(2) 0.9679(18) -1.0419(18) 0.050(5) Uani 1 1 d .
H32A H 0.3871 0.9349 -1.1111 0.060 Uiso 1 1 calc R
N9 N -0.495(2) 0.1399(19) 0.7923(18) 0.116(6) Uani 1 1 d .
C33 C -0.417(3) 0.218(2) 0.623(2) 0.164(13) Uani 1 1 d .
H33A H -0.4575 0.1688 0.5397 0.247 Uiso 1 1 calc R
H33B H -0.3194 0.2224 0.6242 0.247 Uiso 1 1 calc R
H33C H -0.4443 0.3123 0.6532 0.247 Uiso 1 1 calc R
C34 C -0.462(3) 0.144(2) 0.7043(17) 0.094(7) Uani 1 1 d .
N10 N 0.001(2) 1.393(3) 0.295(2) 0.194(13) Uani 1 1 d .
C35 C -0.083(2) 1.320(2) 0.4556(15) 0.105(7) Uani 1 1 d .
H35A H -0.1703 1.2661 0.4306 0.157 Uiso 1 1 calc R
H35B H -0.0917 1.4090 0.5193 0.157 Uiso 1 1 calc R
H35C H -0.0211 1.2688 0.4873 0.157 Uiso 1 1 calc R
C36 C -0.033(2) 1.340(2) 0.356(2) 0.093(7) Uani 1 1 d .
B1 B 0.0048(8) 0.1713(7) 0.7286(7) 0.074(6) Uani 1 1 d G
F1 F 0.0987(13) 0.0822(13) 0.6721(10) 0.221(8) Uani 1 1 d G
F2 F 0.0187(13) 0.2903(9) 0.7002(8) 0.154(4) Uani 1 1 d G
F3 F -0.1239(10) 0.1052(12) 0.6873(12) 0.195(7) Uani 1 1 d G
F4 F 0.0256(12) 0.2074(11) 0.8551(7) 0.125(4) Uani 1 1 d G
B2 B -0.4993(10) 1.3779(8) 0.3520(8) 0.068(5) Uani 1 1 d G
F5 F -0.5969(17) 1.3663(15) 0.4279(14) 0.306(13) Uani 1 1 d G
F6 F -0.3735(13) 1.3700(15) 0.4051(15) 0.237(9) Uani 1 1 d G
F7 F -0.5250(13) 1.2706(10) 0.2384(11) 0.177(6) Uani 1 1 d G
F8 F -0.5019(13) 1.5047(9) 0.3368(10) 0.164(5) Uani 1 1 d G
O5 O -0.741(6) 1.251(7) 0.512(5) 0.437(17) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N8 Ag1 N1 178.6(7) 1_457 .
N4 Ag2 N5 179.3(7) . .
C1 N1 C5 117.8(14) . .
C1 N1 Ag1 115.3(12) . .
C5 N1 Ag1 126.9(12) . .
C6 N2 C5 124.2(14) . .
C6 N2 H2N 115.8 . .
C5 N2 H2N 119.9 . .
C11 N3 C12 126.5(14) . .
C11 N3 H3N 116.8 . .
C12 N3 H3N 116.4 . .
C12 N4 C16 113.5(16) . .
C12 N4 Ag2 122.5(11) . .
C16 N4 Ag2 123.7(13) . .
C21 N5 C17 117.0(17) . .
C21 N5 Ag2 124.6(11) . .
C17 N5 Ag2 118.4(14) . .
C21 N6 C22 125.5(12) . .
C21 N6 H6N 114.4 . .
C22 N6 H6N 119.4 . .
C27 N7 C28 124.0(15) . .
C27 N7 H7N 111.6 . .
C28 N7 H7N 124.1 . .
C28 N8 C32 119.6(16) . .
C28 N8 Ag1 118.7(12) . 1_653
C32 N8 Ag1 121.4(14) . 1_653
N1 C1 C2 120.8(16) . .
N1 C1 H1A 119.6 . .
C2 C1 H1A 119.6 . .
C1 C2 C3 113.2(17) . .
C1 C2 H2B 123.4 . .
C3 C2 H2B 123.4 . .
C4 C3 C2 127(2) . .
C4 C3 H3B 116.4 . .
C2 C3 H3B 116.4 . .
C3 C4 C5 112(2) . .
C3 C4 H4A 123.8 . .
C5 C4 H4A 123.8 . .
C4 C5 N1 127.8(17) . .
C4 C5 N2 123.8(19) . .
N1 C5 N2 108.1(17) . .
O1 C6 N2 122.7(14) . .
O1 C6 C7 121.7(17) . .
N2 C6 C7 115.5(13) . .
C6 C7 C8 113.6(14) . .
C6 C7 H7B 108.9 . .
C8 C7 H7B 108.9 . .
C6 C7 H7C 108.9 . .
C8 C7 H7C 108.9 . .
H7B C7 H7C 107.7 . .
C9 C8 C7 109.9(10) . .
C9 C8 H8B 109.7 . .
C7 C8 H8B 109.7 . .
C9 C8 H8C 109.7 . .
C7 C8 H8C 109.7 . .
H8B C8 H8C 108.2 . .
C10 C9 C8 113.9(10) . .
C10 C9 H9A 108.8 . .
C8 C9 H9A 108.8 . .
C10 C9 H9B 108.8 . .
C8 C9 H9B 108.8 . .
H9A C9 H9B 107.7 . .
C11 C10 C9 116.2(15) . .
C11 C10 H10A 108.2 . .
C9 C10 H10A 108.2 . .
C11 C10 H10B 108.2 . .
C9 C10 H10B 108.2 . .
H10A C10 H10B 107.4 . .
O2 C11 N3 122.4(16) . .
O2 C11 C10 126.4(16) . .
N3 C11 C10 111.0(15) . .
N4 C12 N3 116.3(14) . .
N4 C12 C13 121.1(15) . .
N3 C12 C13 122.6(16) . .
C14 C13 C12 121.5(17) . .
C14 C13 H13A 119.2 . .
C12 C13 H13A 119.2 . .
C15 C14 C13 114.7(18) . .
C15 C14 H14A 122.6 . .
C13 C14 H14A 122.6 . .
C16 C15 C14 122.1(15) . .
C16 C15 H15A 119.0 . .
C14 C15 H15A 119.0 . .
C15 C16 N4 127.0(19) . .
C15 C16 H16A 116.5 . .
N4 C16 H16A 116.5 . .
N5 C17 C18 119.8(19) . .
N5 C17 H17A 120.1 . .
C18 C17 H17A 120.1 . .
C19 C18 C17 115.4(16) . .
C19 C18 H18A 122.3 . .
C17 C18 H18A 122.3 . .
C20 C19 C18 128.4(17) . .
C20 C19 H19A 115.8 . .
C18 C19 H19A 115.8 . .
C19 C20 C21 111.0(17) . .
C19 C20 H20A 124.5 . .
C21 C20 H20A 124.5 . .
N6 C21 N5 112.1(15) . .
N6 C21 C20 119.8(16) . .
N5 C21 C20 128.1(16) . .
O3 C22 N6 120.3(13) . .
O3 C22 C23 123.3(15) . .
N6 C22 C23 116.0(12) . .
C22 C23 C24 113.6(13) . .
C22 C23 H23A 108.8 . .
C24 C23 H23A 108.8 . .
C22 C23 H23B 108.8 . .
C24 C23 H23B 108.8 . .
H23A C23 H23B 107.7 . .
C25 C24 C23 111.2(11) . .
C25 C24 H24A 109.4 . .
C23 C24 H24A 109.4 . .
C25 C24 H24B 109.4 . .
C23 C24 H24B 109.4 . .
H24A C24 H24B 108.0 . .
C26 C25 C24 116.9(11) . .
C26 C25 H25A 108.1 . .
C24 C25 H25A 108.1 . .
C26 C25 H25B 108.1 . .
C24 C25 H25B 108.1 . .
H25A C25 H25B 107.3 . .
C25 C26 C27 115.4(16) . .
C25 C26 H26A 108.4 . .
C27 C26 H26A 108.4 . .
C25 C26 H26B 108.4 . .
C27 C26 H26B 108.4 . .
H26A C26 H26B 107.5 . .
O4 C27 N7 123.5(19) . .
O4 C27 C26 126(2) . .
N7 C27 C26 109.8(17) . .
N8 C28 C29 117.3(15) . .
N8 C28 N7 121.2(17) . .
C29 C28 N7 121.5(18) . .
C28 C29 C30 123.5(19) . .
C28 C29 H29A 118.2 . .
C30 C29 H29A 118.2 . .
C31 C30 C29 112.3(18) . .
C31 C30 H30A 123.9 . .
C29 C30 H30A 123.9 . .
C32 C31 C30 121.6(15) . .
C32 C31 H31A 119.2 . .
C30 C31 H31A 119.2 . .
C31 C32 N8 125.7(18) . .
C31 C32 H32A 117.2 . .
N8 C32 H32A 117.2 . .
C34 C33 H33A 109.5 . .
C34 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
C34 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
N9 C34 C33 153(2) . .
C36 C35 H35A 109.5 . .
C36 C35 H35B 109.5 . .
H35A C35 H35B 109.5 . .
C36 C35 H35C 109.5 . .
H35A C35 H35C 109.5 . .
H35B C35 H35C 109.5 . .
N10 C36 C35 161(3) . .
F2 B1 F1 109.5 . .
F2 B1 F4 109.4 . .
F1 B1 F4 109.5 . .
F2 B1 F3 109.5 . .
F1 B1 F3 109.5 . .
F4 B1 F3 109.4 . .
F8 B2 F5 109.4 . .
F8 B2 F6 109.5 . .
F5 B2 F6 109.5 . .
F8 B2 F7 109.5 . .
F5 B2 F7 109.5 . .
F6 B2 F7 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N8 2.154(15) 1_457
Ag1 N1 2.159(13) .
Ag2 N4 2.076(16) .
Ag2 N5 2.118(16) .
O1 C6 1.23(2) .
O2 C11 1.22(2) .
O3 C22 1.250(18) .
O4 C27 1.13(2) .
N1 C1 1.34(2) .
N1 C5 1.35(2) .
N2 C6 1.35(2) .
N2 C5 1.42(2) .
N2 H2N 0.9704 .
N3 C11 1.37(2) .
N3 C12 1.426(19) .
N3 H3N 0.9084 .
N4 C12 1.34(2) .
N4 C16 1.41(2) .
N5 C21 1.36(2) .
N5 C17 1.36(2) .
N6 C21 1.35(2) .
N6 C22 1.358(19) .
N6 H6N 0.9798 .
N7 C27 1.41(2) .
N7 C28 1.447(19) .
N7 H7N 0.8870 .
N8 C28 1.29(2) .
N8 C32 1.33(2) .
N8 Ag1 2.154(15) 1_653
C1 C2 1.38(3) .
C1 H1A 0.9300 .
C2 C3 1.44(3) .
C2 H2B 0.9300 .
C3 C4 1.30(3) .
C3 H3B 0.9300 .
C4 C5 1.31(3) .
C4 H4A 0.9300 .
C6 C7 1.546(17) .
C7 C8 1.58(2) .
C7 H7B 0.9700 .
C7 H7C 0.9700 .
C8 C9 1.508(10) .
C8 H8B 0.9700 .
C8 H8C 0.9700 .
C9 C10 1.46(2) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 C11 1.45(2) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C12 C13 1.43(2) .
C13 C14 1.43(2) .
C13 H13A 0.9300 .
C14 C15 1.34(3) .
C14 H14A 0.9300 .
C15 C16 1.31(3) .
C15 H15A 0.9300 .
C16 H16A 0.9300 .
C17 C18 1.45(3) .
C17 H17A 0.9300 .
C18 C19 1.36(3) .
C18 H18A 0.9300 .
C19 C20 1.35(2) .
C19 H19A 0.9300 .
C20 C21 1.38(2) .
C20 H20A 0.9300 .
C22 C23 1.552(16) .
C23 C24 1.60(2) .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C24 C25 1.513(10) .
C24 H24A 0.9700 .
C24 H24B 0.9700 .
C25 C26 1.35(2) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C26 C27 1.48(2) .
C26 H26A 0.9700 .
C26 H26B 0.9700 .
C28 C29 1.38(3) .
C29 C30 1.44(3) .
C29 H29A 0.9300 .
C30 C31 1.35(3) .
C30 H30A 0.9300 .
C31 C32 1.28(3) .
C31 H31A 0.9300 .
C32 H32A 0.9300 .
N9 C34 1.10(2) .
C33 C34 1.47(3) .
C33 H33A 0.9600 .
C33 H33B 0.9600 .
C33 H33C 0.9600 .
N10 C36 1.08(3) .
C35 C36 1.36(3) .
C35 H35A 0.9600 .
C35 H35B 0.9600 .
C35 H35C 0.9600 .
B1 F2 1.3696 .
B1 F1 1.3696 .
B1 F4 1.3697 .
B1 F3 1.3697 .
B2 F8 1.3696 .
B2 F5 1.3697 .
B2 F6 1.3697 .
B2 F7 1.3697 .
