#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:25:46 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179578 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/43/4504396.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4504396
loop_
_publ_author_name
'Akhbari, Kamran'
'Morsali, Ali'
_publ_section_title
;
 One-Dimensional Corrugated Tape AgICoordination Polymers Constructed of
 Ag−C Bonds
;
_journal_issue                   10
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              2024
_journal_paper_doi               10.1021/cg0704652
_journal_volume                  7
_journal_year                    2007
_chemical_formula_moiety         'C28 H16 Ag2 F6 O4, N C2 H3'
_chemical_formula_sum            'C30 H19 Ag2 F6 N O4'
_chemical_formula_weight         787.20
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.428(5)
_cell_angle_beta                 103.912(5)
_cell_angle_gamma                108.466(5)
_cell_formula_units_Z            2
_cell_length_a                   10.1623(6)
_cell_length_b                   11.6994(7)
_cell_length_c                   13.3822(12)
_cell_measurement_reflns_used    793
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      30
_cell_measurement_theta_min      3
_cell_volume                     1370.37(19)
_computing_cell_refinement       'APEX2 (Bruker, 2005)'
_computing_data_collection       'APEX2 (Bruker, 2005)'
_computing_data_reduction        'APEX2 (Bruker, 2005)'
_computing_molecular_graphics    'SHELXTL ver. 5.1 (Sheldrick, 1998b)'
_computing_publication_material  'SHELXTL ver. 5.1 (Sheldrick, 1998b)'
_computing_structure_refinement  'SHELXTL ver. 5.1 (Sheldrick, 1998b)'
_computing_structure_solution    'SHELXTL ver. 5.1 (Sheldrick, 1998b)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Bruker SMART APEX2 CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0211
_diffrn_reflns_av_sigmaI/netI    0.0292
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            15802
_diffrn_reflns_theta_full        29.00
_diffrn_reflns_theta_max         29.00
_diffrn_reflns_theta_min         1.68
_exptl_absorpt_coefficient_mu    1.508
_exptl_absorpt_correction_T_max  0.690
_exptl_absorpt_correction_T_min  0.645
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'APEX2 (Bruker, 2005)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.908
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             772
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.25
_refine_diff_density_max         1.383
_refine_diff_density_min         -0.907
_refine_diff_density_rms         0.094
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.992
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     430
_refine_ls_number_reflns         7189
_refine_ls_number_restraints     27
_refine_ls_restrained_S_all      1.004
_refine_ls_R_factor_all          0.0377
_refine_ls_R_factor_gt           0.0294
_refine_ls_shift/su_max          0.046
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0396P)²+1.4843P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0711
_refine_ls_wR_factor_ref         0.0767
_reflns_number_gt                6118
_reflns_number_total             7189
_reflns_threshold_expression     I>2/s(I)
_cod_data_source_file            cg0704652-file002.cif
_cod_data_source_block           29_a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               4504396
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.73195(2) 0.217849(17) 0.055667(16) 0.02001(6) Uani 1 1 d . . .
Ag2 Ag 0.78242(2) -0.080223(18) -0.057254(16) 0.02294(6) Uani 1 1 d . . .
O1 O 0.5648(2) -0.26265(18) -0.11910(17) 0.0273(4) Uani 1 1 d . . .
O2 O 0.5957(2) 0.00311(17) -0.07838(15) 0.0211(4) Uani 1 1 d . . .
C1 C 0.2112(4) -0.4739(3) -0.3186(2) 0.0176(6) Uani 0.80 1 d PD A 1
H1A H 0.1596 -0.4211 -0.3114 0.021 Uiso 0.80 1 calc PR A 1
C2 C 0.1356(3) -0.6028(3) -0.3917(3) 0.0164(6) Uani 0.80 1 d PD A 1
C3 C -0.0167(3) -0.6559(3) -0.4577(2) 0.0199(6) Uani 0.80 1 d PD A 1
H3A H -0.0709 -0.6054 -0.4518 0.024 Uiso 0.80 1 calc PR A 1
C4 C -0.0844(4) -0.7804(3) -0.5297(3) 0.0227(6) Uani 0.80 1 d PD A 1
H4A H -0.1842 -0.8138 -0.5721 0.027 Uiso 0.80 1 calc PR A 1
C5 C -0.0039(4) -0.8581(3) -0.5401(3) 0.0228(7) Uani 0.80 1 d PD A 1
H5A H -0.0508 -0.9420 -0.5906 0.027 Uiso 0.80 1 calc PR A 1
C6 C 0.1421(4) -0.8124(3) -0.4772(3) 0.0197(6) Uani 0.80 1 d PD A 1
H6A H 0.1931 -0.8656 -0.4841 0.024 Uiso 0.80 1 calc PR A 1
C7 C 0.2168(3) -0.6823(3) -0.4004(3) 0.0150(5) Uani 0.80 1 d PD A 1
C8 C 0.3672(3) -0.6316(3) -0.3355(2) 0.0174(6) Uani 0.80 1 d PD A 1
H8A H 0.4197 -0.6838 -0.3399 0.021 Uiso 0.80 1 calc PR A 1
C9 C 0.4372(3) -0.5058(3) -0.2658(2) 0.0153(5) Uani 0.80 1 d PD A 1
H9A H 0.5368 -0.4730 -0.2231 0.018 Uiso 0.80 1 calc PR A 1
C10 C 0.3578(3) -0.4253(3) -0.2586(2) 0.0150(6) Uani 0.80 1 d PD A 1
C11 C 0.4421(3) -0.2862(2) -0.1840(2) 0.0237(5) Uani 1 1 d D . .
C12 C 0.3827(3) -0.1907(2) -0.1945(2) 0.0217(5) Uani 1 1 d . . .
H12A H 0.2831 -0.2194 -0.2355 0.026 Uiso 1 1 calc R . .
C13 C 0.4669(3) -0.0573(2) -0.1463(2) 0.0193(5) Uani 1 1 d . . .
C14 C 0.3963(3) 0.0288(3) -0.1887(2) 0.0231(5) Uani 1 1 d . A .
F1 F 0.4373(2) 0.0499(2) -0.27227(18) 0.0466(5) Uani 1 1 d . . .
F2 F 0.24940(19) -0.02341(17) -0.22628(15) 0.0335(4) Uani 1 1 d . . .
F3 F 0.4378(2) 0.14149(18) -0.11128(17) 0.0482(6) Uani 1 1 d . . .
O1A O 0.9135(2) 0.13669(17) 0.08260(15) 0.0207(4) Uani 1 1 d . . .
O2A O 0.9148(2) -0.10969(17) 0.09653(16) 0.0251(4) Uani 1 1 d . . .
C1A C 1.2048(3) 0.3819(2) 0.3231(2) 0.0180(5) Uani 1 1 d . . .
H1AA H 1.2166 0.3306 0.3647 0.022 Uiso 1 1 calc R . .
C2A C 1.2781(3) 0.5176(2) 0.3731(2) 0.0182(5) Uani 1 1 d . . .
C3A C 1.3706(3) 0.5786(2) 0.4854(2) 0.0205(5) Uani 1 1 d . . .
H3AA H 1.3847 0.5284 0.5277 0.025 Uiso 1 1 calc R . .
C4A C 1.4395(3) 0.7100(3) 0.5324(2) 0.0244(5) Uani 1 1 d . . .
H4AA H 1.4988 0.7482 0.6064 0.029 Uiso 1 1 calc R . .
C5A C 1.4208(3) 0.7878(3) 0.4691(2) 0.0256(5) Uani 1 1 d . . .
H5AA H 1.4681 0.8770 0.5013 0.031 Uiso 1 1 calc R . .
C6A C 1.3327(3) 0.7315(2) 0.3596(2) 0.0224(5) Uani 1 1 d . . .
H6AA H 1.3212 0.7831 0.3183 0.027 Uiso 1 1 calc R . .
C7A C 1.2592(3) 0.5958(2) 0.3093(2) 0.0188(5) Uani 1 1 d . . .
C8A C 1.1668(3) 0.5348(2) 0.1969(2) 0.0205(5) Uani 1 1 d . . .
H8AA H 1.1532 0.5848 0.1543 0.025 Uiso 1 1 calc R . .
C9A C 1.0974(3) 0.4031(2) 0.1503(2) 0.0205(5) Uani 1 1 d . . .
H9AA H 1.0374 0.3648 0.0765 0.025 Uiso 1 1 calc R . .
C10A C 1.1160(3) 0.3246(2) 0.2134(2) 0.0176(5) Uani 1 1 d . . .
C11A C 1.0363(3) 0.1811(2) 0.1584(2) 0.0179(5) Uani 1 1 d . . .
C12A C 1.1066(3) 0.1032(2) 0.1955(2) 0.0197(5) Uani 1 1 d . . .
H12B H 1.2046 0.1443 0.2428 0.024 Uiso 1 1 calc R . .
C13A C 1.0368(3) -0.0314(2) 0.1650(2) 0.0217(5) Uani 1 1 d . . .
C14A C 1.1231(3) -0.0942(3) 0.2278(2) 0.0281(6) Uani 1 1 d . . .
F1A F 1.0514(3) -0.1466(2) 0.28616(19) 0.0534(6) Uani 1 1 d . . .
F2A F 1.2607(2) -0.01536(18) 0.29584(17) 0.0458(5) Uani 1 1 d . . .
F3A F 1.1363(2) -0.18990(18) 0.15681(15) 0.0407(5) Uani 1 1 d . . .
N1S N 0.7357(3) 0.3972(2) 0.0266(2) 0.0268(5) Uani 1 1 d . . .
C1S C 0.7204(3) 0.4909(3) 0.0382(2) 0.0234(5) Uani 1 1 d . . .
C2S C 0.7000(4) 0.6113(3) 0.0547(3) 0.0342(7) Uani 1 1 d . . .
H2SA H 0.6535 0.6228 0.1088 0.041 Uiso 1 1 calc R . .
H2SB H 0.6387 0.6085 -0.0135 0.041 Uiso 1 1 calc R . .
H2SC H 0.7945 0.6819 0.0797 0.041 Uiso 1 1 calc R . .
C1' C 0.3547(8) -0.5109(8) -0.2925(9) 0.027(3) Uiso 0.20 1 d PD A 2
H1'A H 0.4522 -0.4972 -0.2576 0.033 Uiso 0.20 1 calc PR A 2
C2' C 0.2572(9) -0.6344(8) -0.3697(12) 0.034(5) Uiso 0.20 1 d PD A 2
C3' C 0.3016(10) -0.7382(9) -0.3982(10) 0.033(3) Uiso 0.20 1 d PD A 2
H3'A H 0.3970 -0.7276 -0.3609 0.039 Uiso 0.20 1 calc PR A 2
C4' C 0.2065(12) -0.8534(9) -0.4793(10) 0.034(3) Uiso 0.20 1 d PD A 2
H4'A H 0.2395 -0.9183 -0.4996 0.041 Uiso 0.20 1 calc PR A 2
C5' C 0.0591(11) -0.8743(8) -0.5323(10) 0.031(3) Uiso 0.20 1 d PD A 2
H5'A H -0.0048 -0.9534 -0.5868 0.037 Uiso 0.20 1 calc PR A 2
C6' C 0.0081(9) -0.7800(7) -0.5050(9) 0.027(3) Uiso 0.20 1 d PD A 2
H6'A H -0.0898 -0.7954 -0.5405 0.033 Uiso 0.20 1 calc PR A 2
C7' C 0.1062(9) -0.6573(8) -0.4214(11) 0.030(4) Uiso 0.20 1 d PD A 2
C8' C 0.0621(8) -0.5547(7) -0.3953(10) 0.031(3) Uiso 0.20 1 d PD A 2
H8'A H -0.0348 -0.5668 -0.4300 0.038 Uiso 0.20 1 calc PR A 2
C9' C 0.1605(9) -0.4369(7) -0.3192(10) 0.030(3) Uiso 0.20 1 d PD A 2
H9'A H 0.1272 -0.3718 -0.3010 0.035 Uiso 0.20 1 calc PR A 2
C10' C 0.3129(8) -0.4103(7) -0.2666(11) 0.026(4) Uiso 0.20 1 d PD A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1S Ag1 O1A 131.14(8) . .
N1S Ag1 O2 125.39(8) . .
O1A Ag1 O2 80.20(6) . .
N1S Ag1 C12 109.14(9) . 2_655
O1A Ag1 C12 106.30(8) . 2_655
O2 Ag1 C12 98.28(7) . 2_655
O1 Ag2 O2A 99.43(7) . .
O1 Ag2 O2 76.69(6) . .
O2A Ag2 O2 130.00(6) . .
O1 Ag2 C12A 106.91(8) . 2_755
O2A Ag2 C12A 110.28(8) . 2_755
O2 Ag2 C12A 118.58(7) . 2_755
O1 Ag2 O1A 141.55(6) . .
O2A Ag2 O1A 75.60(6) . .
O2 Ag2 O1A 78.15(6) . .
C12A Ag2 O1A 110.55(8) 2_755 .
C11 O1 Ag2 128.88(17) . .
C13 O2 Ag2 124.76(16) . .
C13 O2 Ag1 134.67(16) . .
Ag2 O2 Ag1 100.54(7) . .
C10 C1 C2 121.3(3) . .
C10 C1 H1A 119.3 . .
C2 C1 H1A 119.3 . .
C1 C2 C3 122.8(3) . .
C1 C2 C7 118.3(3) . .
C3 C2 C7 118.9(3) . .
C4 C3 C2 120.9(3) . .
C4 C3 H3A 119.6 . .
C2 C3 H3A 119.6 . .
C3 C4 C5 120.3(3) . .
C3 C4 H4A 119.8 . .
C5 C4 H4A 119.8 . .
C6 C5 C4 121.1(3) . .
C6 C5 H5A 119.5 . .
C4 C5 H5A 119.5 . .
C5 C6 C7 120.1(3) . .
C5 C6 H6A 119.9 . .
C7 C6 H6A 119.9 . .
C8 C7 C2 119.6(3) . .
C8 C7 C6 121.7(3) . .
C2 C7 C6 118.6(3) . .
C9 C8 C7 120.5(3) . .
C9 C8 H8A 119.7 . .
C7 C8 H8A 119.7 . .
C8 C9 C10 120.1(3) . .
C8 C9 H9A 120.0 . .
C10 C9 H9A 120.0 . .
C1 C10 C9 120.1(3) . .
C1 C10 C11 122.2(3) . .
C9 C10 C11 117.7(3) . .
O1 C11 C12 124.7(2) . .
O1 C11 C10 114.3(2) . .
C12 C11 C10 120.9(3) . .
O1 C11 C10' 133.9(4) . .
C12 C11 C10' 101.3(4) . .
C13 C12 C11 123.8(2) . .
C13 C12 Ag1 98.43(16) . 2_655
C11 C12 Ag1 92.32(15) . 2_655
C13 C12 H12A 118.1 . .
C11 C12 H12A 118.1 . .
Ag1 C12 H12A 78.6 2_655 .
O2 C13 C12 129.4(2) . .
O2 C13 C14 114.2(2) . .
C12 C13 C14 116.2(2) . .
F3 C14 F2 106.7(2) . .
F3 C14 F1 108.2(2) . .
F2 C14 F1 106.5(2) . .
F3 C14 C13 111.9(2) . .
F2 C14 C13 113.8(2) . .
F1 C14 C13 109.4(2) . .
C11A O1A Ag1 130.22(16) . .
C11A O1A Ag2 127.82(15) . .
Ag1 O1A Ag2 101.05(7) . .
C13A O2A Ag2 125.50(16) . .
C10A C1A C2A 121.0(2) . .
C10A C1A H1AA 119.5 . .
C2A C1A H1AA 119.5 . .
C3A C2A C1A 122.0(2) . .
C3A C2A C7A 118.7(2) . .
C1A C2A C7A 119.3(2) . .
C4A C3A C2A 121.0(2) . .
C4A C3A H3AA 119.5 . .
C2A C3A H3AA 119.5 . .
C3A C4A C5A 120.3(2) . .
C3A C4A H4AA 119.8 . .
C5A C4A H4AA 119.8 . .
C6A C5A C4A 120.0(2) . .
C6A C5A H5AA 120.0 . .
C4A C5A H5AA 120.0 . .
C5A C6A C7A 120.8(2) . .
C5A C6A H6AA 119.6 . .
C7A C6A H6AA 119.6 . .
C6A C7A C8A 122.2(2) . .
C6A C7A C2A 119.1(2) . .
C8A C7A C2A 118.7(2) . .
C9A C8A C7A 120.8(2) . .
C9A C8A H8AA 119.6 . .
C7A C8A H8AA 119.6 . .
C8A C9A C10A 120.8(2) . .
C8A C9A H9AA 119.6 . .
C10A C9A H9AA 119.6 . .
C1A C10A C9A 119.4(2) . .
C1A C10A C11A 122.1(2) . .
C9A C10A C11A 118.5(2) . .
O1A C11A C12A 124.1(2) . .
O1A C11A C10A 118.3(2) . .
C12A C11A C10A 117.6(2) . .
C13A C12A C11A 124.2(2) . .
C13A C12A Ag2 91.29(16) . 2_755
C11A C12A Ag2 95.28(15) . 2_755
C13A C12A H12B 117.9 . .
C11A C12A H12B 117.9 . .
Ag2 C12A H12B 83.0 2_755 .
O2A C13A C12A 130.9(2) . .
O2A C13A C14A 113.2(2) . .
C12A C13A C14A 115.9(2) . .
F1A C14A F2A 107.5(2) . .
F1A C14A F3A 106.5(2) . .
F2A C14A F3A 105.9(2) . .
F1A C14A C13A 110.8(2) . .
F2A C14A C13A 115.3(2) . .
F3A C14A C13A 110.3(2) . .
C1S N1S Ag1 158.1(2) . .
N1S C1S C2S 179.1(3) . .
C1S C2S H2SA 109.5 . .
C1S C2S H2SB 109.5 . .
H2SA C2S H2SB 109.5 . .
C1S C2S H2SC 109.5 . .
H2SA C2S H2SC 109.5 . .
H2SB C2S H2SC 109.5 . .
C10' C1' C2' 123.2(4) . .
C10' C1' H1'A 118.4 . .
C2' C1' H1'A 118.4 . .
C1' C2' C3' 123.1(4) . .
C1' C2' C7' 118.8(4) . .
C3' C2' C7' 118.1(4) . .
C4' C3' C2' 121.2(5) . .
C4' C3' H3'A 119.4 . .
C2' C3' H3'A 119.4 . .
C3' C4' C5' 120.4(5) . .
C3' C4' H4'A 119.8 . .
C5' C4' H4'A 119.8 . .
C6' C5' C4' 121.0(5) . .
C6' C5' H5'A 119.5 . .
C4' C5' H5'A 119.5 . .
C5' C6' C7' 119.9(4) . .
C5' C6' H6'A 120.1 . .
C7' C6' H6'A 120.1 . .
C8' C7' C2' 118.4(4) . .
C8' C7' C6' 122.1(5) . .
C2' C7' C6' 119.3(4) . .
C9' C8' C7' 120.6(5) . .
C9' C8' H8'A 119.7 . .
C7' C8' H8'A 119.7 . .
C8' C9' C10' 122.4(4) . .
C8' C9' H9'A 118.8 . .
C10' C9' H9'A 118.8 . .
C1' C10' C9' 116.5(4) . .
C1' C10' C11 112.3(5) . .
C9' C10' C11 131.3(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1S 2.218(2) .
Ag1 O1A 2.3226(17) .
Ag1 O2 2.4089(18) .
Ag1 C12 2.451(2) 2_655
Ag2 O1 2.3197(19) .
Ag2 O2A 2.3410(19) .
Ag2 O2 2.3840(18) .
Ag2 C12A 2.391(2) 2_755
Ag2 O1A 2.4516(18) .
O1 C11 1.236(4) .
O2 C13 1.249(3) .
C1 C10 1.359(4) .
C1 C2 1.412(4) .
C1 H1A 0.9300 .
C2 C3 1.422(4) .
C2 C7 1.428(4) .
C3 C4 1.367(4) .
C3 H3A 0.9300 .
C4 C5 1.407(5) .
C4 H4A 0.9300 .
C5 C6 1.367(4) .
C5 H5A 0.9300 .
C6 C7 1.435(4) .
C6 H6A 0.9300 .
C7 C8 1.405(4) .
C8 C9 1.369(4) .
C8 H8A 0.9300 .
C9 C10 1.422(4) .
C9 H9A 0.9300 .
C10 C11 1.508(4) .
C11 C12 1.448(4) .
C11 C10' 1.533(4) .
C12 C13 1.404(4) .
C12 Ag1 2.451(2) 2_655
C12 H12A 0.9300 .
C13 C14 1.549(4) .
C14 F3 1.322(3) .
C14 F2 1.327(3) .
C14 F1 1.335(3) .
O1A C11A 1.255(3) .
O2A C13A 1.238(3) .
C1A C10A 1.381(3) .
C1A C2A 1.416(3) .
C1A H1AA 0.9300 .
C2A C3A 1.419(4) .
C2A C7A 1.423(3) .
C3A C4A 1.369(4) .
C3A H3AA 0.9300 .
C4A C5A 1.415(4) .
C4A H4AA 0.9300 .
C5A C6A 1.377(4) .
C5A H5AA 0.9300 .
C6A C7A 1.416(3) .
C6A H6AA 0.9300 .
C7A C8A 1.419(4) .
C8A C9A 1.372(4) .
C8A H8AA 0.9300 .
C9A C10A 1.418(3) .
C9A H9AA 0.9300 .
C10A C11A 1.501(3) .
C11A C12A 1.433(3) .
C12A C13A 1.408(4) .
C12A Ag2 2.391(2) 2_755
C12A H12B 0.9300 .
C13A C14A 1.541(4) .
C14A F1A 1.322(3) .
C14A F2A 1.337(4) .
C14A F3A 1.341(3) .
N1S C1S 1.134(3) .
C1S C2S 1.458(4) .
C2S H2SA 0.9600 .
C2S H2SB 0.9600 .
C2S H2SC 0.9600 .
C1' C10' 1.367(5) .
C1' C2' 1.412(5) .
C1' H1'A 0.9300 .
C2' C3' 1.423(5) .
C2' C7' 1.429(5) .
C3' C4' 1.368(5) .
C3' H3'A 0.9300 .
C4' C5' 1.407(5) .
C4' H4'A 0.9300 .
C5' C6' 1.367(5) .
C5' H5'A 0.9300 .
C6' C7' 1.437(5) .
C6' H6'A 0.9300 .
C7' C8' 1.403(5) .
C8' C9' 1.368(5) .
C8' H8'A 0.9300 .
C9' C10' 1.433(5) .
C9' H9'A 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O2A Ag2 O1 C11 163.2(2) . .
O2 Ag2 O1 C11 34.2(2) . .
C12A Ag2 O1 C11 -82.1(2) 2_755 .
O1A Ag2 O1 C11 84.6(2) . .
O1 Ag2 O2 C13 -29.2(2) . .
O2A Ag2 O2 C13 -120.38(19) . .
C12A Ag2 O2 C13 73.0(2) 2_755 .
O1A Ag2 O2 C13 -179.9(2) . .
O1 Ag2 O2 Ag1 152.62(8) . .
O2A Ag2 O2 Ag1 61.40(10) . .
C12A Ag2 O2 Ag1 -105.17(9) 2_755 .
O1A Ag2 O2 Ag1 1.93(6) . .
N1S Ag1 O2 C13 -45.8(3) . .
O1A Ag1 O2 C13 -180.0(2) . .
C12 Ag1 O2 C13 74.8(2) 2_655 .
N1S Ag1 O2 Ag2 132.10(9) . .
O1A Ag1 O2 Ag2 -2.02(6) . .
C12 Ag1 O2 Ag2 -107.25(8) 2_655 .
C10 C1 C2 C3 -178.4(3) . .
C10 C1 C2 C7 0.7(4) . .
C1 C2 C3 C4 178.1(3) . .
C7 C2 C3 C4 -1.0(5) . .
C2 C3 C4 C5 -0.3(5) . .
C3 C4 C5 C6 1.4(5) . .
C4 C5 C6 C7 -1.3(5) . .
C1 C2 C7 C8 1.1(4) . .
C3 C2 C7 C8 -179.7(3) . .
C1 C2 C7 C6 -178.0(3) . .
C3 C2 C7 C6 1.1(4) . .
C5 C6 C7 C8 -179.2(3) . .
C5 C6 C7 C2 0.0(5) . .
C2 C7 C8 C9 -1.5(4) . .
C6 C7 C8 C9 177.6(3) . .
C7 C8 C9 C10 0.0(4) . .
C2 C1 C10 C9 -2.1(5) . .
C2 C1 C10 C11 177.1(3) . .
C8 C9 C10 C1 1.8(5) . .
C8 C9 C10 C11 -177.5(3) . .
Ag2 O1 C11 C12 -33.2(4) . .
Ag2 O1 C11 C10 143.85(19) . .
Ag2 O1 C11 C10' 150.1(9) . .
C1 C10 C11 O1 166.2(3) . .
C9 C10 C11 O1 -14.5(4) . .
C1 C10 C11 C12 -16.6(4) . .
C9 C10 C11 C12 162.7(3) . .
C1 C10 C11 C10' -0.6(19) . .
C9 C10 C11 C10' 179(2) . .
O1 C11 C12 C13 11.7(4) . .
C10 C11 C12 C13 -165.2(2) . .
C10' C11 C12 C13 -170.8(7) . .
O1 C11 C12 Ag1 -90.0(3) . 2_655
C10 C11 C12 Ag1 93.1(2) . 2_655
C10' C11 C12 Ag1 87.5(7) . 2_655
Ag2 O2 C13 C12 26.1(4) . .
Ag1 O2 C13 C12 -156.4(2) . .
Ag2 O2 C13 C14 -148.92(16) . .
Ag1 O2 C13 C14 28.6(3) . .
C11 C12 C13 O2 -9.3(4) . .
Ag1 C12 C13 O2 89.3(3) 2_655 .
C11 C12 C13 C14 165.6(2) . .
Ag1 C12 C13 C14 -95.8(2) 2_655 .
O2 C13 C14 F3 -35.4(3) . .
C12 C13 C14 F3 148.9(2) . .
O2 C13 C14 F2 -156.5(2) . .
C12 C13 C14 F2 27.8(3) . .
O2 C13 C14 F1 84.5(3) . .
C12 C13 C14 F1 -91.2(3) . .
N1S Ag1 O1A C11A 63.4(2) . .
O2 Ag1 O1A C11A -167.6(2) . .
C12 Ag1 O1A C11A -71.7(2) 2_655 .
N1S Ag1 O1A Ag2 -127.04(9) . .
O2 Ag1 O1A Ag2 1.97(6) . .
C12 Ag1 O1A Ag2 97.81(8) 2_655 .
O1 Ag2 O1A C11A 117.9(2) . .
O2A Ag2 O1A C11A 30.8(2) . .
O2 Ag2 O1A C11A 167.9(2) . .
C12A Ag2 O1A C11A -75.8(2) 2_755 .
O1 Ag2 O1A Ag1 -52.01(13) . .
O2A Ag2 O1A Ag1 -139.06(8) . .
O2 Ag2 O1A Ag1 -2.00(6) . .
C12A Ag2 O1A Ag1 114.32(8) 2_755 .
O1 Ag2 O2A C13A -173.8(2) . .
O2 Ag2 O2A C13A -93.3(2) . .
C12A Ag2 O2A C13A 74.2(2) 2_755 .
O1A Ag2 O2A C13A -32.8(2) . .
C10A C1A C2A C3A -179.6(2) . .
C10A C1A C2A C7A 0.2(4) . .
C1A C2A C3A C4A -179.4(2) . .
C7A C2A C3A C4A 0.8(4) . .
C2A C3A C4A C5A -0.8(4) . .
C3A C4A C5A C6A 0.2(4) . .
C4A C5A C6A C7A 0.3(4) . .
C5A C6A C7A C8A 179.6(2) . .
C5A C6A C7A C2A -0.3(4) . .
C3A C2A C7A C6A -0.2(3) . .
C1A C2A C7A C6A 180.0(2) . .
C3A C2A C7A C8A 179.9(2) . .
C1A C2A C7A C8A 0.1(3) . .
C6A C7A C8A C9A 179.8(2) . .
C2A C7A C8A C9A -0.3(4) . .
C7A C8A C9A C10A 0.1(4) . .
C2A C1A C10A C9A -0.4(4) . .
C2A C1A C10A C11A -179.6(2) . .
C8A C9A C10A C1A 0.2(4) . .
C8A C9A C10A C11A 179.5(2) . .
Ag1 O1A C11A C12A 149.92(19) . .
Ag2 O1A C11A C12A -17.0(3) . .
Ag1 O1A C11A C10A -30.7(3) . .
Ag2 O1A C11A C10A 162.33(15) . .
C1A C10A C11A O1A 147.8(2) . .
C9A C10A C11A O1A -31.5(3) . .
C1A C10A C11A C12A -32.8(3) . .
C9A C10A C11A C12A 147.9(2) . .
O1A C11A C12A C13A -11.1(4) . .
C10A C11A C12A C13A 169.5(2) . .
O1A C11A C12A Ag2 84.1(2) . 2_755
C10A C11A C12A Ag2 -95.3(2) . 2_755
Ag2 O2A C13A C12A 24.2(4) . .
Ag2 O2A C13A C14A -157.17(17) . .
C11A C12A C13A O2A 7.8(5) . .
Ag2 C12A C13A O2A -89.4(3) 2_755 .
C11A C12A C13A C14A -170.8(2) . .
Ag2 C12A C13A C14A 92.0(2) 2_755 .
O2A C13A C14A F1A -63.1(3) . .
C12A C13A C14A F1A 115.7(3) . .
O2A C13A C14A F2A 174.5(2) . .
C12A C13A C14A F2A -6.7(4) . .
O2A C13A C14A F3A 54.5(3) . .
C12A C13A C14A F3A -126.6(3) . .
O1A Ag1 N1S C1S -129.4(6) . .
O2 Ag1 N1S C1S 120.5(6) . .
C12 Ag1 N1S C1S 4.8(7) 2_655 .
C10' C1' C2' C3' 178.7(16) . .
C10' C1' C2' C7' -2(3) . .
C1' C2' C3' C4' -175.0(16) . .
C7' C2' C3' C4' 6(3) . .
C2' C3' C4' C5' -4(2) . .
C3' C4' C5' C6' 1(2) . .
C4' C5' C6' C7' 0(2) . .
C1' C2' C7' C8' 2(3) . .
C3' C2' C7' C8' -178.8(15) . .
C1' C2' C7' C6' 176.1(15) . .
C3' C2' C7' C6' -4(2) . .
C5' C6' C7' C8' 175.8(16) . .
C5' C6' C7' C2' 2(2) . .
C2' C7' C8' C9' -2(2) . .
C6' C7' C8' C9' -176.6(15) . .
C7' C8' C9' C10' 3(2) . .
C2' C1' C10' C9' 2(2) . .
C2' C1' C10' C11 -177.7(14) . .
C8' C9' C10' C1' -3(2) . .
C8' C9' C10' C11 177.2(14) . .
O1 C11 C10' C1' -18.3(18) . .
C12 C11 C10' C1' 164.5(12) . .
C10 C11 C10' C1' -1.6(11) . .
O1 C11 C10' C9' 161.7(12) . .
C12 C11 C10' C9' -15.5(19) . .
C10 C11 C10' C9' 178(4) . .
