#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:35:22 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179587 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/52/4505284.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4505284
loop_
_publ_author_name
'Zou, Ru-Qiang'
'Li, Jian-Rong'
'Xie, Ya-Bo'
'Zhang, Ruo-Hua'
'Bu, Xian-He'
_publ_section_title
;
 Tuning the Framework Formation of Silver(I) Complexes with Flexible
 Bis(benzothiazol-2-ylsulfanyl)alkanes by Varying the Ligand Spacers and
 Counteranions
;
_journal_issue                   1
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              79
_journal_paper_doi               10.1021/cg0341149
_journal_volume                  4
_journal_year                    2004
_chemical_formula_sum            'C38 H36 Ag2 Cl2 N4 O8 S8'
_chemical_formula_weight         1219.83
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                108.992(7)
_cell_angle_beta                 94.586(7)
_cell_angle_gamma                107.799(7)
_cell_formula_units_Z            2
_cell_length_a                   12.094(5)
_cell_length_b                   13.077(5)
_cell_length_c                   16.097(6)
_cell_measurement_reflns_used    788
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      22.71
_cell_measurement_theta_min      2.73
_cell_volume                     2246.0(15)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0296
_diffrn_reflns_av_sigmaI/netI    0.0720
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            13117
_diffrn_reflns_theta_full        26.42
_diffrn_reflns_theta_max         26.42
_diffrn_reflns_theta_min         1.37
_exptl_absorpt_coefficient_mu    1.419
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.062317
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_density_diffrn    1.804
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1224
_exptl_crystal_size_max          0.38
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.935
_refine_diff_density_min         -0.938
_refine_diff_density_rms         0.101
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.030
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     559
_refine_ls_number_reflns         9098
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.030
_refine_ls_R_factor_all          0.1165
_refine_ls_R_factor_gt           0.0597
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0867P)²+0.1599P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1480
_refine_ls_wR_factor_ref         0.1763
_reflns_number_gt                5244
_reflns_number_total             9098
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg0341149si20030703_092130.cif
_cod_data_source_block           complex_7
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        2245.9(16)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4505284
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.02264(5) 0.82490(5) 0.76838(3) 0.05496(18) Uani 1 1 d .
Ag2 Ag 0.40591(5) 1.17099(5) 0.74843(4) 0.0683(2) Uani 1 1 d .
S1 S -0.16866(18) 0.43594(14) 0.55317(12) 0.0597(5) Uani 1 1 d .
S2 S -0.0925(2) 0.54977(15) 0.75792(12) 0.0665(6) Uani 1 1 d .
S3 S -0.10176(18) 0.20339(17) 1.03099(12) 0.0610(5) Uani 1 1 d .
S4 S 0.11051(18) 0.15513(16) 0.95671(11) 0.0621(5) Uani 1 1 d .
S5 S 0.6419(2) 1.55930(19) 0.95155(15) 0.0818(7) Uani 1 1 d .
S6 S 0.4976(2) 1.45608(19) 0.75900(16) 0.0862(7) Uani 1 1 d .
S7 S 0.67280(17) 1.78131(17) 0.45732(14) 0.0643(5) Uani 1 1 d .
S8 S 0.45247(16) 1.82009(17) 0.52195(12) 0.0585(5) Uani 1 1 d .
N1 N -0.0590(5) 0.6560(4) 0.6423(3) 0.0471(13) Uani 1 1 d .
N2 N 0.0602(5) 0.1488(4) 1.1090(3) 0.0434(12) Uani 1 1 d .
N3 N 0.5307(5) 1.3404(5) 0.8614(4) 0.0640(16) Uani 1 1 d .
N4 N 0.5171(5) 1.8419(4) 0.3775(4) 0.0512(13) Uani 1 1 d .
C1 C -0.0765(6) 0.6410(5) 0.5520(4) 0.0462(15) Uani 1 1 d .
C2 C -0.0421(6) 0.7280(6) 0.5188(5) 0.0585(18) Uani 1 1 d .
H2 H -0.0027 0.8042 0.5573 0.070 Uiso 1 1 calc R
C3 C -0.0674(8) 0.6999(8) 0.4269(5) 0.076(2) Uani 1 1 d .
H3 H -0.0454 0.7580 0.4037 0.091 Uiso 1 1 calc R
C4 C -0.1253(8) 0.5858(8) 0.3691(5) 0.082(3) Uani 1 1 d .
H4 H -0.1404 0.5690 0.3076 0.099 Uiso 1 1 calc R
C5 C -0.1608(7) 0.4969(7) 0.4005(5) 0.070(2) Uani 1 1 d .
H5 H -0.1995 0.4208 0.3616 0.084 Uiso 1 1 calc R
C6 C -0.1361(6) 0.5260(6) 0.4932(4) 0.0525(16) Uani 1 1 d .
C7 C -0.1031(6) 0.5570(5) 0.6514(4) 0.0501(16) Uani 1 1 d .
C8 C -0.1842(7) 0.4013(6) 0.7350(4) 0.0606(19) Uani 1 1 d .
H8A H -0.2663 0.3885 0.7135 0.073 Uiso 1 1 calc R
H8B H -0.1585 0.3489 0.6896 0.073 Uiso 1 1 calc R
C9 C -0.1709(7) 0.3802(6) 0.8237(5) 0.0617(19) Uani 1 1 d .
H9A H -0.1825 0.4422 0.8710 0.074 Uiso 1 1 calc R
H9B H -0.2324 0.3085 0.8173 0.074 Uiso 1 1 calc R
C10 C -0.0533(7) 0.3738(7) 0.8507(5) 0.066(2) Uani 1 1 d .
H10A H 0.0082 0.4461 0.8586 0.079 Uiso 1 1 calc R
H10B H -0.0408 0.3130 0.8029 0.079 Uiso 1 1 calc R
C11 C -0.0412(8) 0.3498(6) 0.9380(5) 0.072(2) Uani 1 1 d .
H11A H 0.0416 0.3645 0.9591 0.087 Uiso 1 1 calc R
H11B H -0.0657 0.4036 0.9833 0.087 Uiso 1 1 calc R
C12 C -0.1120(7) 0.2303(6) 0.9284(4) 0.064(2) Uani 1 1 d .
H12A H -0.0858 0.1767 0.8845 0.077 Uiso 1 1 calc R
H12B H -0.1945 0.2148 0.9054 0.077 Uiso 1 1 calc R
C13 C 0.0251(6) 0.1700(5) 1.0388(4) 0.0470(15) Uani 1 1 d .
C14 C 0.2016(6) 0.1187(5) 1.0219(4) 0.0575(18) Uani 1 1 d .
C15 C 0.3026(7) 0.0937(7) 1.0047(6) 0.072(2) Uani 1 1 d .
H15 H 0.3311 0.0968 0.9532 0.087 Uiso 1 1 calc R
C16 C 0.3592(7) 0.0644(7) 1.0652(6) 0.080(2) Uani 1 1 d .
H16 H 0.4255 0.0446 1.0535 0.096 Uiso 1 1 calc R
C17 C 0.3200(7) 0.0634(6) 1.1444(6) 0.068(2) Uani 1 1 d .
H17 H 0.3618 0.0461 1.1858 0.082 Uiso 1 1 calc R
C18 C 0.2185(6) 0.0883(6) 1.1610(5) 0.0563(17) Uani 1 1 d .
H18 H 0.1901 0.0849 1.2124 0.068 Uiso 1 1 calc R
C19 C 0.1595(6) 0.1186(5) 1.1002(4) 0.0472(15) Uani 1 1 d .
C20 C 0.5882(6) 1.3483(7) 0.9434(5) 0.068(2) Uani 1 1 d .
C21 C 0.5875(7) 1.2568(8) 0.9687(6) 0.075(2) Uani 1 1 d .
H21 H 0.5453 1.1814 0.9298 0.090 Uiso 1 1 calc R
C22 C 0.6490(8) 1.2772(10) 1.0515(6) 0.095(3) Uani 1 1 d .
H22 H 0.6481 1.2160 1.0691 0.114 Uiso 1 1 calc R
C23 C 0.7122(9) 1.3896(11) 1.1080(6) 0.104(3) Uani 1 1 d .
H23 H 0.7543 1.4022 1.1635 0.125 Uiso 1 1 calc R
C24 C 0.7161(8) 1.4846(10) 1.0864(6) 0.092(3) Uani 1 1 d .
H24 H 0.7587 1.5597 1.1259 0.111 Uiso 1 1 calc R
C25 C 0.6526(6) 1.4617(7) 1.0019(5) 0.071(2) Uani 1 1 d .
C26 C 0.5524(6) 1.4420(7) 0.8567(5) 0.070(2) Uani 1 1 d .
C27 C 0.5582(9) 1.6100(7) 0.7834(6) 0.090(3) Uani 1 1 d .
H27A H 0.5179 1.6493 0.8255 0.108 Uiso 1 1 calc R
H27B H 0.6418 1.6398 0.8105 0.108 Uiso 1 1 calc R
C28 C 0.5421(8) 1.6337(9) 0.6946(6) 0.095(3) Uani 1 1 d .
H28A H 0.4622 1.5877 0.6607 0.114 Uiso 1 1 calc R
H28B H 0.5516 1.7144 0.7097 0.114 Uiso 1 1 calc R
C29 C 0.6233(9) 1.6079(8) 0.6404(6) 0.091(3) Uani 1 1 d .
H29A H 0.6111 1.5264 0.6233 0.109 Uiso 1 1 calc R
H29B H 0.7030 1.6510 0.6755 0.109 Uiso 1 1 calc R
C30 C 0.6133(7) 1.6361(7) 0.5533(5) 0.077(2) Uani 1 1 d .
H30A H 0.6431 1.5865 0.5091 0.093 Uiso 1 1 calc R
H30B H 0.5301 1.6162 0.5296 0.093 Uiso 1 1 calc R
C31 C 0.6785(6) 1.7610(6) 0.5635(5) 0.0620(19) Uani 1 1 d .
H31A H 0.7607 1.7841 0.5917 0.074 Uiso 1 1 calc R
H31B H 0.6437 1.8108 0.6026 0.074 Uiso 1 1 calc R
C32 C 0.5448(6) 1.8153(5) 0.4457(4) 0.0492(16) Uani 1 1 d .
C33 C 0.3669(6) 1.8616(6) 0.4574(4) 0.0554(17) Uani 1 1 d .
C34 C 0.2643(6) 1.8885(6) 0.4720(5) 0.065(2) Uani 1 1 d .
H34 H 0.2323 1.8845 0.5219 0.078 Uiso 1 1 calc R
C35 C 0.2132(7) 1.9205(7) 0.4108(6) 0.075(2) Uani 1 1 d .
H35 H 0.1455 1.9388 0.4199 0.089 Uiso 1 1 calc R
C36 C 0.2581(7) 1.9265(6) 0.3365(6) 0.067(2) Uani 1 1 d .
H36 H 0.2194 1.9475 0.2960 0.081 Uiso 1 1 calc R
C37 C 0.3600(6) 1.9022(6) 0.3202(5) 0.0600(18) Uani 1 1 d .
H37 H 0.3913 1.9081 0.2704 0.072 Uiso 1 1 calc R
C38 C 0.4139(6) 1.8683(5) 0.3817(4) 0.0504(16) Uani 1 1 d .
Cl1 Cl 0.10004(17) 1.07204(17) 0.71422(13) 0.0638(5) Uani 1 1 d .
Cl2 Cl 0.32455(16) 0.88998(17) 0.75746(12) 0.0625(5) Uani 1 1 d .
O1 O 0.0038(5) 0.9762(5) 0.7187(4) 0.0790(16) Uani 1 1 d .
O2 O 0.2182(5) 1.1179(7) 0.7675(5) 0.111(2) Uani 1 1 d .
O3 O 0.1052(6) 1.0498(5) 0.6153(3) 0.0894(18) Uani 1 1 d .
O4 O 0.0557(5) 1.1732(4) 0.7319(4) 0.0821(17) Uani 1 1 d .
O5 O 0.2278(6) 0.8587(6) 0.8017(5) 0.113(2) Uani 1 1 d .
O6 O 0.4190(5) 1.0014(5) 0.7868(5) 0.099(2) Uani 1 1 d .
O7 O 0.2716(7) 0.8571(7) 0.6600(4) 0.131(3) Uani 1 1 d .
O8 O 0.3832(5) 0.7986(5) 0.7410(5) 0.112(2) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N1 121.07(18) 2_567 .
N2 Ag1 O5 113.1(2) 2_567 .
N1 Ag1 O5 106.7(2) . .
N2 Ag1 O1 103.19(18) 2_567 .
N1 Ag1 O1 104.87(18) . .
O5 Ag1 O1 106.7(2) . .
O2 Ag2 N4 131.4(2) . 2_686
O2 Ag2 N3 113.4(2) . .
N4 Ag2 N3 106.9(2) 2_686 .
O2 Ag2 O6 86.6(2) . .
N4 Ag2 O6 105.5(2) 2_686 .
N3 Ag2 O6 108.5(2) . .
C6 S1 C7 88.5(3) . .
C7 S2 C8 102.4(3) . .
C13 S3 C12 104.5(3) . .
C14 S4 C13 89.1(3) . .
C26 S5 C25 88.6(4) . .
C26 S6 C27 103.8(4) . .
C32 S7 C31 103.3(3) . .
C32 S8 C33 88.7(3) . .
C7 N1 C1 110.1(5) . .
C7 N1 Ag1 120.0(4) . .
C1 N1 Ag1 129.7(4) . .
C13 N2 C19 110.7(5) . .
C13 N2 Ag1 123.8(4) . 2_567
C19 N2 Ag1 125.2(4) . 2_567
C26 N3 C20 111.3(6) . .
C26 N3 Ag2 123.1(5) . .
C20 N3 Ag2 125.5(5) . .
C32 N4 C38 110.6(6) . .
C32 N4 Ag2 130.7(5) . 2_686
C38 N4 Ag2 118.1(4) . 2_686
C2 C1 N1 125.3(6) . .
C2 C1 C6 120.2(6) . .
N1 C1 C6 114.5(5) . .
C1 C2 C3 118.7(7) . .
C1 C2 H2 120.6 . .
C3 C2 H2 120.6 . .
C2 C3 C4 120.7(7) . .
C2 C3 H3 119.6 . .
C4 C3 H3 119.6 . .
C5 C4 C3 121.7(7) . .
C5 C4 H4 119.1 . .
C3 C4 H4 119.1 . .
C4 C5 C6 117.2(7) . .
C4 C5 H5 121.4 . .
C6 C5 H5 121.4 . .
C5 C6 C1 121.3(6) . .
C5 C6 S1 128.5(6) . .
C1 C6 S1 110.1(5) . .
N1 C7 S1 116.7(5) . .
N1 C7 S2 120.1(5) . .
S1 C7 S2 123.2(4) . .
C9 C8 S2 107.3(5) . .
C9 C8 H8A 110.3 . .
S2 C8 H8A 110.3 . .
C9 C8 H8B 110.3 . .
S2 C8 H8B 110.3 . .
H8A C8 H8B 108.5 . .
C10 C9 C8 113.2(6) . .
C10 C9 H9A 108.9 . .
C8 C9 H9A 108.9 . .
C10 C9 H9B 108.9 . .
C8 C9 H9B 108.9 . .
H9A C9 H9B 107.7 . .
C9 C10 C11 113.1(6) . .
C9 C10 H10A 108.9 . .
C11 C10 H10A 108.9 . .
C9 C10 H10B 108.9 . .
C11 C10 H10B 108.9 . .
H10A C10 H10B 107.8 . .
C12 C11 C10 114.0(6) . .
C12 C11 H11A 108.7 . .
C10 C11 H11A 108.7 . .
C12 C11 H11B 108.7 . .
C10 C11 H11B 108.7 . .
H11A C11 H11B 107.6 . .
C11 C12 S3 114.1(5) . .
C11 C12 H12A 108.7 . .
S3 C12 H12A 108.7 . .
C11 C12 H12B 108.7 . .
S3 C12 H12B 108.7 . .
H12A C12 H12B 107.6 . .
N2 C13 S3 119.9(5) . .
N2 C13 S4 115.5(5) . .
S3 C13 S4 124.6(4) . .
C15 C14 C19 121.9(7) . .
C15 C14 S4 128.4(6) . .
C19 C14 S4 109.7(6) . .
C16 C15 C14 118.2(8) . .
C16 C15 H15 120.9 . .
C14 C15 H15 120.9 . .
C15 C16 C17 121.7(8) . .
C15 C16 H16 119.2 . .
C17 C16 H16 119.2 . .
C18 C17 C16 119.7(8) . .
C18 C17 H17 120.1 . .
C16 C17 H17 120.1 . .
C17 C18 C19 119.5(7) . .
C17 C18 H18 120.2 . .
C19 C18 H18 120.2 . .
N2 C19 C18 126.0(6) . .
N2 C19 C14 115.0(6) . .
C18 C19 C14 118.9(7) . .
C21 C20 N3 126.2(7) . .
C21 C20 C25 119.9(8) . .
N3 C20 C25 113.9(8) . .
C22 C21 C20 120.0(9) . .
C22 C21 H21 120.0 . .
C20 C21 H21 120.0 . .
C21 C22 C23 119.2(10) . .
C21 C22 H22 120.4 . .
C23 C22 H22 120.4 . .
C22 C23 C24 123.3(9) . .
C22 C23 H23 118.3 . .
C24 C23 H23 118.3 . .
C23 C24 C25 116.4(9) . .
C23 C24 H24 121.8 . .
C25 C24 H24 121.8 . .
C24 C25 C20 121.1(9) . .
C24 C25 S5 128.7(7) . .
C20 C25 S5 110.2(6) . .
N3 C26 S6 120.6(6) . .
N3 C26 S5 116.0(6) . .
S6 C26 S5 123.4(5) . .
C28 C27 S6 109.7(6) . .
C28 C27 H27A 109.7 . .
S6 C27 H27A 109.7 . .
C28 C27 H27B 109.7 . .
S6 C27 H27B 109.7 . .
H27A C27 H27B 108.2 . .
C29 C28 C27 113.1(8) . .
C29 C28 H28A 109.0 . .
C27 C28 H28A 109.0 . .
C29 C28 H28B 109.0 . .
C27 C28 H28B 109.0 . .
H28A C28 H28B 107.8 . .
C28 C29 C30 114.4(8) . .
C28 C29 H29A 108.7 . .
C30 C29 H29A 108.7 . .
C28 C29 H29B 108.7 . .
C30 C29 H29B 108.7 . .
H29A C29 H29B 107.6 . .
C31 C30 C29 116.4(7) . .
C31 C30 H30A 108.2 . .
C29 C30 H30A 108.2 . .
C31 C30 H30B 108.2 . .
C29 C30 H30B 108.2 . .
H30A C30 H30B 107.3 . .
C30 C31 S7 112.8(5) . .
C30 C31 H31A 109.0 . .
S7 C31 H31A 109.0 . .
C30 C31 H31B 109.0 . .
S7 C31 H31B 109.0 . .
H31A C31 H31B 107.8 . .
N4 C32 S8 116.6(5) . .
N4 C32 S7 119.7(5) . .
S8 C32 S7 123.7(4) . .
C38 C33 C34 120.1(7) . .
C38 C33 S8 110.5(5) . .
C34 C33 S8 129.4(6) . .
C35 C34 C33 118.1(8) . .
C35 C34 H34 120.9 . .
C33 C34 H34 120.9 . .
C34 C35 C36 122.2(8) . .
C34 C35 H35 118.9 . .
C36 C35 H35 118.9 . .
C35 C36 C37 121.5(8) . .
C35 C36 H36 119.2 . .
C37 C36 H36 119.2 . .
C36 C37 C38 117.4(7) . .
C36 C37 H37 121.3 . .
C38 C37 H37 121.3 . .
N4 C38 C37 125.8(6) . .
N4 C38 C33 113.5(6) . .
C37 C38 C33 120.6(7) . .
O2 Cl1 O1 124.4(4) . .
O2 Cl1 O4 106.6(4) . .
O1 Cl1 O4 106.6(3) . .
O2 Cl1 O3 110.3(4) . .
O1 Cl1 O3 108.1(3) . .
O4 Cl1 O3 97.4(3) . .
O5 Cl2 O6 126.1(5) . .
O5 Cl2 O7 107.2(4) . .
O6 Cl2 O7 108.2(4) . .
O5 Cl2 O8 108.4(4) . .
O6 Cl2 O8 107.0(4) . .
O7 Cl2 O8 95.9(4) . .
Cl1 O1 Ag1 126.6(3) . .
Cl1 O2 Ag2 138.5(4) . .
Cl2 O5 Ag1 133.8(4) . .
Cl2 O6 Ag2 124.3(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.259(5) 2_567
Ag1 N1 2.324(5) .
Ag1 O5 2.366(7) .
Ag1 O1 2.425(5) .
Ag2 O2 2.240(6) .
Ag2 N4 2.276(5) 2_686
Ag2 N3 2.321(6) .
Ag2 O6 2.533(6) .
S1 C6 1.729(7) .
S1 C7 1.743(7) .
S2 C7 1.745(6) .
S2 C8 1.813(7) .
S3 C13 1.725(7) .
S3 C12 1.799(6) .
S4 C14 1.733(8) .
S4 C13 1.739(7) .
S5 C26 1.746(7) .
S5 C25 1.749(9) .
S6 C26 1.745(9) .
S6 C27 1.812(9) .
S7 C32 1.748(7) .
S7 C31 1.812(7) .
S8 C32 1.724(7) .
S8 C33 1.728(7) .
N1 C7 1.302(8) .
N1 C1 1.392(7) .
N2 C13 1.316(7) .
N2 C19 1.378(8) .
N2 Ag1 2.259(5) 2_567
N3 C26 1.303(10) .
N3 C20 1.399(9) .
N4 C32 1.303(8) .
N4 C38 1.394(8) .
N4 Ag2 2.276(5) 2_686
C1 C2 1.376(9) .
C1 C6 1.406(9) .
C2 C3 1.386(10) .
C2 H2 0.9300 .
C3 C4 1.392(11) .
C3 H3 0.9300 .
C4 C5 1.379(11) .
C4 H4 0.9300 .
C5 C6 1.397(9) .
C5 H5 0.9300 .
C8 C9 1.546(9) .
C8 H8A 0.9700 .
C8 H8B 0.9700 .
C9 C10 1.489(10) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 C11 1.541(9) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 C12 1.485(10) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C14 C15 1.384(11) .
C14 C19 1.397(9) .
C15 C16 1.365(11) .
C15 H15 0.9300 .
C16 C17 1.397(11) .
C16 H16 0.9300 .
C17 C18 1.388(10) .
C17 H17 0.9300 .
C18 C19 1.392(9) .
C18 H18 0.9300 .
C20 C21 1.381(11) .
C20 C25 1.400(11) .
C21 C22 1.373(11) .
C21 H21 0.9300 .
C22 C23 1.380(14) .
C22 H22 0.9300 .
C23 C24 1.384(13) .
C23 H23 0.9300 .
C24 C25 1.399(11) .
C24 H24 0.9300 .
C27 C28 1.567(12) .
C27 H27A 0.9700 .
C27 H27B 0.9700 .
C28 C29 1.410(12) .
C28 H28A 0.9700 .
C28 H28B 0.9700 .
C29 C30 1.566(11) .
C29 H29A 0.9700 .
C29 H29B 0.9700 .
C30 C31 1.528(10) .
C30 H30A 0.9700 .
C30 H30B 0.9700 .
C31 H31A 0.9700 .
C31 H31B 0.9700 .
C33 C38 1.401(9) .
C33 C34 1.405(10) .
C34 C35 1.362(11) .
C34 H34 0.9300 .
C35 C36 1.367(11) .
C35 H35 0.9300 .
C36 C37 1.389(10) .
C36 H36 0.9300 .
C37 C38 1.400(9) .
C37 H37 0.9300 .
Cl1 O2 1.444(6) .
Cl1 O1 1.453(5) .
Cl1 O4 1.527(5) .
Cl1 O3 1.533(5) .
Cl2 O5 1.440(6) .
Cl2 O6 1.449(6) .
Cl2 O7 1.513(6) .
Cl2 O8 1.531(5) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
N2 Ag1 N1 C7 -38.5(6) 2_567
O5 Ag1 N1 C7 92.7(5) .
O1 Ag1 N1 C7 -154.3(5) .
N2 Ag1 N1 C1 137.2(5) 2_567
O5 Ag1 N1 C1 -91.6(5) .
O1 Ag1 N1 C1 21.4(6) .
O2 Ag2 N3 C26 -92.6(6) .
N4 Ag2 N3 C26 59.6(6) 2_686
O6 Ag2 N3 C26 173.0(6) .
O2 Ag2 N3 C20 84.9(6) .
N4 Ag2 N3 C20 -122.8(5) 2_686
O6 Ag2 N3 C20 -9.5(6) .
C7 N1 C1 C2 179.1(7) .
Ag1 N1 C1 C2 3.1(9) .
C7 N1 C1 C6 0.1(8) .
Ag1 N1 C1 C6 -175.9(4) .
N1 C1 C2 C3 -179.0(7) .
C6 C1 C2 C3 0.0(10) .
C1 C2 C3 C4 -0.7(12) .
C2 C3 C4 C5 0.8(14) .
C3 C4 C5 C6 -0.1(14) .
C4 C5 C6 C1 -0.6(12) .
C4 C5 C6 S1 179.9(7) .
C2 C1 C6 C5 0.7(11) .
N1 C1 C6 C5 179.8(6) .
C2 C1 C6 S1 -179.8(5) .
N1 C1 C6 S1 -0.7(7) .
C7 S1 C6 C5 -179.7(7) .
C7 S1 C6 C1 0.8(5) .
C1 N1 C7 S1 0.6(7) .
Ag1 N1 C7 S1 177.0(3) .
C1 N1 C7 S2 179.4(5) .
Ag1 N1 C7 S2 -4.2(8) .
C6 S1 C7 N1 -0.8(6) .
C6 S1 C7 S2 -179.6(5) .
C8 S2 C7 N1 172.0(6) .
C8 S2 C7 S1 -9.3(6) .
C7 S2 C8 C9 173.9(5) .
S2 C8 C9 C10 -72.1(7) .
C8 C9 C10 C11 -178.6(6) .
C9 C10 C11 C12 71.6(9) .
C10 C11 C12 S3 -178.2(6) .
C13 S3 C12 C11 -84.3(7) .
C19 N2 C13 S3 177.1(4) .
Ag1 N2 C13 S3 -8.1(7) 2_567
C19 N2 C13 S4 -0.2(7) .
Ag1 N2 C13 S4 174.6(3) 2_567
C12 S3 C13 N2 178.0(5) .
C12 S3 C13 S4 -5.0(5) .
C14 S4 C13 N2 -0.5(5) .
C14 S4 C13 S3 -177.6(4) .
C13 S4 C14 C15 -178.3(7) .
C13 S4 C14 C19 1.0(5) .
C19 C14 C15 C16 2.3(11) .
S4 C14 C15 C16 -178.5(6) .
C14 C15 C16 C17 -2.3(12) .
C15 C16 C17 C18 2.5(12) .
C16 C17 C18 C19 -2.5(11) .
C13 N2 C19 C18 -178.6(6) .
Ag1 N2 C19 C18 6.6(9) 2_567
C13 N2 C19 C14 1.0(7) .
Ag1 N2 C19 C14 -173.8(4) 2_567
C17 C18 C19 N2 -177.9(6) .
C17 C18 C19 C14 2.5(10) .
C15 C14 C19 N2 178.0(6) .
S4 C14 C19 N2 -1.3(7) .
C15 C14 C19 C18 -2.4(10) .
S4 C14 C19 C18 178.3(5) .
C26 N3 C20 C21 -177.5(7) .
Ag2 N3 C20 C21 4.7(10) .
C26 N3 C20 C25 1.6(9) .
Ag2 N3 C20 C25 -176.2(5) .
N3 C20 C21 C22 179.5(7) .
C25 C20 C21 C22 0.5(12) .
C20 C21 C22 C23 -0.7(13) .
C21 C22 C23 C24 0.8(16) .
C22 C23 C24 C25 -0.7(15) .
C23 C24 C25 C20 0.4(12) .
C23 C24 C25 S5 -177.7(7) .
C21 C20 C25 C24 -0.4(11) .
N3 C20 C25 C24 -179.5(7) .
C21 C20 C25 S5 178.1(6) .
N3 C20 C25 S5 -1.0(8) .
C26 S5 C25 C24 178.5(8) .
C26 S5 C25 C20 0.2(6) .
C20 N3 C26 S6 176.5(5) .
Ag2 N3 C26 S6 -5.6(9) .
C20 N3 C26 S5 -1.5(8) .
Ag2 N3 C26 S5 176.4(3) .
C27 S6 C26 N3 -176.7(6) .
C27 S6 C26 S5 1.2(6) .
C25 S5 C26 N3 0.8(6) .
C25 S5 C26 S6 -177.2(5) .
C26 S6 C27 C28 166.6(6) .
S6 C27 C28 C29 -76.0(10) .
C27 C28 C29 C30 -177.3(7) .
C28 C29 C30 C31 83.5(11) .
C29 C30 C31 S7 174.6(6) .
C32 S7 C31 C30 90.2(6) .
C38 N4 C32 S8 -0.5(7) .
Ag2 N4 C32 S8 -171.8(3) 2_686
C38 N4 C32 S7 -178.7(4) .
Ag2 N4 C32 S7 9.9(8) 2_686
C33 S8 C32 N4 0.0(5) .
C33 S8 C32 S7 178.2(4) .
C31 S7 C32 N4 176.3(5) .
C31 S7 C32 S8 -1.9(5) .
C32 S8 C33 C38 0.4(5) .
C32 S8 C33 C34 -178.9(7) .
C38 C33 C34 C35 0.1(10) .
S8 C33 C34 C35 179.3(6) .
C33 C34 C35 C36 0.3(11) .
C34 C35 C36 C37 -1.1(12) .
C35 C36 C37 C38 1.5(11) .
C32 N4 C38 C37 179.0(6) .
Ag2 N4 C38 C37 -8.4(8) 2_686
C32 N4 C38 C33 0.8(8) .
Ag2 N4 C38 C33 173.4(4) 2_686
C36 C37 C38 N4 -179.1(6) .
C36 C37 C38 C33 -1.1(10) .
C34 C33 C38 N4 178.6(6) .
S8 C33 C38 N4 -0.8(7) .
C34 C33 C38 C37 0.3(10) .
S8 C33 C38 C37 -179.0(5) .
O2 Cl1 O1 Ag1 -24.1(6) .
O4 Cl1 O1 Ag1 -148.5(4) .
O3 Cl1 O1 Ag1 107.7(4) .
N2 Ag1 O1 Cl1 116.8(4) 2_567
N1 Ag1 O1 Cl1 -115.6(4) .
O5 Ag1 O1 Cl1 -2.6(5) .
O1 Cl1 O2 Ag2 133.5(6) .
O4 Cl1 O2 Ag2 -102.1(7) .
O3 Cl1 O2 Ag2 2.6(8) .
N4 Ag2 O2 Cl1 -5.3(9) 2_686
N3 Ag2 O2 Cl1 138.2(7) .
O6 Ag2 O2 Cl1 -113.1(7) .
O6 Cl2 O5 Ag1 107.8(6) .
O7 Cl2 O5 Ag1 -21.3(7) .
O8 Cl2 O5 Ag1 -123.7(6) .
N2 Ag1 O5 Cl2 -156.2(6) 2_567
N1 Ag1 O5 Cl2 68.2(6) .
O1 Ag1 O5 Cl2 -43.5(7) .
O5 Cl2 O6 Ag2 -85.8(6) .
O7 Cl2 O6 Ag2 42.9(6) .
O8 Cl2 O6 Ag2 145.2(5) .
O2 Ag2 O6 Cl2 39.0(5) .
N4 Ag2 O6 Cl2 -93.2(5) 2_686
N3 Ag2 O6 Cl2 152.5(4) .
