#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:38:42 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179590 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/55/4505519.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4505519
loop_
_publ_author_name
'Chen, Shuo'
'Fan, Rui-Qing'
'Sun, Cun-Fa'
'Wang, Ping'
'Yang, Yu-Lin'
'Su, Qing'
'Mu, Ying'
_publ_section_title
;
 Synthesis, Structure, and Luminescent Properties of Lanthanide-Based
 Two-Dimensional and Three-Dimensional Metal--Organic Frameworks with
 2,4′-Biphenyldicarboxylic Acid
;
_journal_issue                   3
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1337
_journal_paper_doi               10.1021/cg201411b
_journal_volume                  12
_journal_year                    2012
_chemical_formula_sum            'C28 H23 Eu2 N O15'
_chemical_formula_weight         917.39
_chemical_name_common            Eu1
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.68(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   19.239(4)
_cell_length_b                   16.373(3)
_cell_length_c                   9.3961(19)
_cell_measurement_reflns_used    26991
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      3.01
_cell_volume                     2887.6(10)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    SHELXP-97
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Bruker Smart APEX CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0507
_diffrn_reflns_av_sigmaI/netI    0.0471
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            26991
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.01
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.383
_exptl_absorpt_correction_T_max  0.4428
_exptl_absorpt_correction_T_min  0.3570
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.110
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1776
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.22
_refine_diff_density_max         1.762
_refine_diff_density_min         -2.129
_refine_diff_density_rms         0.168
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.197
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     415
_refine_ls_number_reflns         6534
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.197
_refine_ls_R_factor_all          0.0561
_refine_ls_R_factor_gt           0.0436
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+23.0073P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0932
_refine_ls_wR_factor_ref         0.0968
_reflns_number_gt                5437
_reflns_number_total             6534
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg201411b_si_002.cif
_cod_data_source_block           1-833808
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               4505519
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu -0.365548(17) 0.247448(18) -0.54536(3) 0.01958(9) Uani 1 1 d .
Eu2 Eu -0.126988(17) 0.262616(17) -0.43140(3) 0.01824(9) Uani 1 1 d .
O1 O -0.4558(3) 0.1987(4) -0.4404(6) 0.0471(15) Uani 1 1 d .
O2 O -0.4669(3) 0.2858(4) -0.7153(6) 0.0448(14) Uani 1 1 d .
O3 O -0.3976(3) 0.3894(3) -0.4716(5) 0.0329(12) Uani 1 1 d .
O4 O -0.3346(3) 0.3839(3) -0.6405(5) 0.0263(10) Uani 1 1 d .
O5 O -0.0328(3) 0.3165(3) -0.5227(6) 0.0434(14) Uani 1 1 d .
O6 O -0.0322(3) 0.2313(3) -0.2427(6) 0.0416(13) Uani 1 1 d .
O7 O -0.0819(3) 0.1200(3) -0.4921(5) 0.0281(11) Uani 1 1 d .
O8 O -0.1621(3) 0.1248(3) -0.3579(5) 0.0245(10) Uani 1 1 d .
O9 O -0.2467(3) 0.2853(3) -0.4048(5) 0.0276(10) Uani 1 1 d .
O10 O -0.1823(3) 0.2811(3) -0.1814(6) 0.0403(14) Uani 1 1 d .
O11 O -0.3044(3) 0.2808(3) -0.2281(7) 0.0474(15) Uani 1 1 d .
O12 O -0.0798(3) 0.3891(3) -0.2908(5) 0.0358(12) Uani 1 1 d .
H12A H -0.0345 0.3885 -0.2725 0.054 Uiso 1 1 d R
H12C H -0.0939 0.3903 -0.2112 0.054 Uiso 1 1 d R
O13 O -0.1816(3) 0.3815(3) -0.5760(5) 0.0257(10) Uani 1 1 d .
H13A H -0.1488 0.4135 -0.5895 0.039 Uiso 1 1 d R
H13C H -0.2057 0.3653 -0.6580 0.039 Uiso 1 1 d R
O14 O -0.4230(3) 0.1236(3) -0.6885(5) 0.0350(12) Uani 1 1 d .
H14A H -0.4680 0.1279 -0.7032 0.042 Uiso 1 1 d R
H14B H -0.4106 0.1215 -0.7699 0.053 Uiso 1 1 d R
O15 O -0.3109(3) 0.1242(3) -0.4180(5) 0.0247(10) Uani 1 1 d .
H15A H -0.3185 0.1230 -0.3356 0.037 Uiso 1 1 calc R
N1 N -0.2453(4) 0.2851(4) -0.2635(7) 0.0386(16) Uani 1 1 d .
C1 C -0.4909(4) 0.1971(4) -0.3457(7) 0.0231(13) Uani 1 1 d .
C2 C -0.5665(3) 0.1685(4) -0.3822(6) 0.0202(13) Uani 1 1 d .
C3 C -0.5796(4) 0.0852(4) -0.3970(7) 0.0279(15) Uani 1 1 d .
H3A H -0.5421 0.0496 -0.3986 0.033 Uiso 1 1 calc R
C4 C -0.6481(4) 0.0544(4) -0.4094(8) 0.0334(17) Uani 1 1 d .
H4A H -0.6564 -0.0014 -0.4215 0.040 Uiso 1 1 calc R
C5 C -0.7030(4) 0.1062(4) -0.4039(8) 0.0348(17) Uani 1 1 d .
H5A H -0.7486 0.0857 -0.4094 0.042 Uiso 1 1 calc R
C6 C -0.6905(4) 0.1899(4) -0.3901(8) 0.0300(15) Uani 1 1 d .
H6B H -0.7284 0.2247 -0.3868 0.036 Uiso 1 1 calc R
C7 C -0.6234(3) 0.2231(4) -0.3811(7) 0.0216(13) Uani 1 1 d .
C8 C -0.6161(4) 0.3136(4) -0.3820(7) 0.0224(13) Uani 1 1 d .
C9 C -0.6478(4) 0.3627(4) -0.2906(7) 0.0295(16) Uani 1 1 d .
H9A H -0.6671 0.3382 -0.2187 0.035 Uiso 1 1 calc R
C10 C -0.6506(4) 0.4466(4) -0.3065(8) 0.0328(17) Uani 1 1 d .
H10A H -0.6724 0.4778 -0.2460 0.039 Uiso 1 1 calc R
C11 C -0.6216(4) 0.4850(4) -0.4110(7) 0.0220(13) Uani 1 1 d .
C12 C -0.5866(4) 0.4369(4) -0.4975(7) 0.0242(14) Uani 1 1 d .
H12B H -0.5647 0.4619 -0.5651 0.029 Uiso 1 1 calc R
C13 C -0.5843(4) 0.3526(4) -0.4831(7) 0.0256(14) Uani 1 1 d .
H13B H -0.5611 0.3217 -0.5417 0.031 Uiso 1 1 calc R
C14 C -0.3705(4) 0.4245(4) -0.5650(7) 0.0231(13) Uani 1 1 d .
C15 C -0.0029(4) 0.3013(4) -0.6252(7) 0.0232(14) Uani 1 1 d .
C16 C 0.0731(3) 0.3261(4) -0.6113(6) 0.0189(12) Uani 1 1 d .
C17 C 0.0888(4) 0.4093(4) -0.5989(7) 0.0259(14) Uani 1 1 d .
H17A H 0.0538 0.4461 -0.5865 0.031 Uiso 1 1 calc R
C18 C 0.1559(4) 0.4381(4) -0.6050(8) 0.0317(16) Uani 1 1 d .
H18A H 0.1655 0.4938 -0.5985 0.038 Uiso 1 1 calc R
C19 C 0.2080(4) 0.3836(4) -0.6206(8) 0.0331(16) Uani 1 1 d .
H19A H 0.2532 0.4025 -0.6238 0.040 Uiso 1 1 calc R
C20 C 0.1934(4) 0.3003(4) -0.6316(7) 0.0272(14) Uani 1 1 d .
H20A H 0.2291 0.2641 -0.6427 0.033 Uiso 1 1 calc R
C21 C 0.1261(4) 0.2701(4) -0.6262(6) 0.0214(13) Uani 1 1 d .
C22 C 0.1170(3) 0.1791(4) -0.6244(6) 0.0193(12) Uani 1 1 d .
C23 C 0.1451(4) 0.1301(4) -0.7188(7) 0.0264(15) Uani 1 1 d .
H23A H 0.1639 0.1541 -0.7917 0.032 Uiso 1 1 calc R
C24 C 0.1454(4) 0.0448(4) -0.7052(7) 0.0296(16) Uani 1 1 d .
H24A H 0.1656 0.0130 -0.7676 0.036 Uiso 1 1 calc R
C25 C 0.1162(3) 0.0074(4) -0.6003(6) 0.0203(13) Uani 1 1 d .
C26 C 0.0855(4) 0.0563(4) -0.5085(7) 0.0225(13) Uani 1 1 d .
H26A H 0.0645 0.0320 -0.4390 0.027 Uiso 1 1 calc R
C27 C 0.0862(4) 0.1411(4) -0.5203(7) 0.0228(13) Uani 1 1 d .
H27A H 0.0660 0.1728 -0.4580 0.027 Uiso 1 1 calc R
C28 C -0.1194(4) 0.0837(3) -0.4188(7) 0.0201(13) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 O2 77.9(2) . .
O1 Eu1 O11 142.3(2) . 4_565
O2 Eu1 O11 91.7(2) . 4_565
O1 Eu1 O9 123.63(18) . .
O2 Eu1 O9 147.66(19) . .
O11 Eu1 O9 83.40(19) 4_565 .
O1 Eu1 O15 77.93(19) . .
O2 Eu1 O15 139.58(19) . .
O11 Eu1 O15 87.98(19) 4_565 .
O9 Eu1 O15 72.39(15) . .
O1 Eu1 O4 135.36(19) . .
O2 Eu1 O4 75.22(19) . .
O11 Eu1 O4 73.64(17) 4_565 .
O9 Eu1 O4 72.74(15) . .
O15 Eu1 O4 142.07(16) . .
O1 Eu1 O3 87.1(2) . .
O2 Eu1 O3 73.9(2) . .
O11 Eu1 O3 125.06(17) 4_565 .
O9 Eu1 O3 82.85(17) . .
O15 Eu1 O3 136.15(15) . .
O4 Eu1 O3 51.47(15) . .
O1 Eu1 O14 70.9(2) . .
O2 Eu1 O14 69.5(2) . .
O11 Eu1 O14 71.56(18) 4_565 .
O9 Eu1 O14 136.83(16) . .
O15 Eu1 O14 72.14(16) . .
O4 Eu1 O14 128.74(15) . .
O3 Eu1 O14 140.32(18) . .
O1 Eu1 C14 110.7(2) . .
O2 Eu1 C14 71.0(2) . .
O11 Eu1 C14 99.56(19) 4_565 .
O9 Eu1 C14 78.26(17) . .
O15 Eu1 C14 148.63(16) . .
O4 Eu1 C14 26.08(17) . .
O3 Eu1 C14 25.50(17) . .
O14 Eu1 C14 139.14(17) . .
O1 Eu1 O11 78.88(18) . .
O2 Eu1 O11 136.13(18) . .
O11 Eu1 O11 128.0(2) 4_565 .
O9 Eu1 O11 45.98(15) . .
O15 Eu1 O11 68.54(14) . .
O4 Eu1 O11 96.83(14) . .
O3 Eu1 O11 68.20(15) . .
O14 Eu1 O11 134.31(15) . .
C14 Eu1 O11 83.23(16) . .
O6 Eu2 O5 79.7(2) . .
O6 Eu2 O9 124.72(19) . .
O5 Eu2 O9 144.86(18) . .
O6 Eu2 O10 140.57(19) . 4_565
O5 Eu2 O10 88.1(2) . 4_565
O9 Eu2 O10 85.46(18) . 4_565
O6 Eu2 O13 140.08(18) . .
O5 Eu2 O13 76.77(19) . .
O9 Eu2 O13 68.53(16) . .
O10 Eu2 O13 70.23(16) 4_565 .
O6 Eu2 O8 78.60(17) . .
O5 Eu2 O8 136.08(18) . .
O9 Eu2 O8 77.70(16) . .
O10 Eu2 O8 85.12(16) 4_565 .
O13 Eu2 O8 139.11(16) . .
O6 Eu2 O12 69.25(18) . .
O5 Eu2 O12 70.32(19) . .
O9 Eu2 O12 93.56(18) . .
O10 Eu2 O12 140.39(16) 4_565 .
O13 Eu2 O12 72.63(15) . .
O8 Eu2 O12 133.41(15) . .
O6 Eu2 O7 73.93(18) . .
O5 Eu2 O7 86.32(18) . .
O9 Eu2 O7 122.42(16) . .
O10 Eu2 O7 67.94(16) 4_565 .
O13 Eu2 O7 135.15(14) . .
O8 Eu2 O7 51.06(14) . .
O12 Eu2 O7 139.09(17) . .
O6 Eu2 O10 76.15(19) . .
O5 Eu2 O10 137.22(17) . .
O9 Eu2 O10 49.14(15) . .
O10 Eu2 O10 131.9(2) 4_565 .
O13 Eu2 O10 100.52(15) . .
O8 Eu2 O10 71.93(14) . .
O12 Eu2 O10 68.30(16) . .
O7 Eu2 O10 119.21(14) . .
O6 Eu2 C28 73.91(18) . .
O5 Eu2 C28 110.8(2) . .
O9 Eu2 C28 100.99(17) . .
O10 Eu2 C28 75.87(17) 4_565 .
O13 Eu2 C28 145.05(16) . .
O8 Eu2 C28 25.87(17) . .
O12 Eu2 C28 142.32(16) . .
O7 Eu2 C28 25.21(16) . .
O10 Eu2 C28 95.66(16) . .
O6 Eu2 N1 100.51(19) . .
O5 Eu2 N1 149.99(19) . .
O9 Eu2 N1 24.35(15) . .
O10 Eu2 N1 108.18(19) 4_565 .
O13 Eu2 N1 85.10(16) . .
O8 Eu2 N1 71.91(16) . .
O12 Eu2 N1 81.60(19) . .
O7 Eu2 N1 122.88(16) . .
O10 Eu2 N1 24.87(15) . .
C28 Eu2 N1 97.78(18) . .
C1 O1 Eu1 153.7(5) . .
C1 O2 Eu1 144.5(5) 4_565 .
C14 O3 Eu1 93.8(4) . .
C14 O4 Eu1 93.7(4) . .
C15 O5 Eu2 137.0(5) . .
C15 O6 Eu2 154.9(5) 4_566 .
C28 O7 Eu2 92.6(4) . .
C28 O8 Eu2 96.4(4) . .
N1 O9 Eu2 107.2(4) . .
N1 O9 Eu1 110.5(4) . .
Eu2 O9 Eu1 135.0(2) . .
N1 O10 Eu2 137.6(5) . 4_566
N1 O10 Eu2 89.1(4) . .
Eu2 O10 Eu2 127.2(2) 4_566 .
N1 O11 Eu1 147.1(5) . 4_566
N1 O11 Eu1 85.8(4) . .
Eu1 O11 Eu1 122.9(2) 4_566 .
Eu2 O12 H12A 109.4 . .
Eu2 O12 H12C 109.5 . .
H12A O12 H12C 109.5 . .
Eu2 O13 H13A 109.2 . .
Eu2 O13 H13C 109.6 . .
H13A O13 H13C 109.5 . .
Eu1 O14 H14A 109.2 . .
Eu1 O14 H14B 109.5 . .
H14A O14 H14B 109.6 . .
Eu1 O15 H15A 109.5 . .
O11 N1 O10 128.8(7) . .
O11 N1 O9 116.5(6) . .
O10 N1 O9 114.2(6) . .
O11 N1 Eu2 161.6(5) . .
O10 N1 Eu2 66.0(4) . .
O9 N1 Eu2 48.4(3) . .
O1 C1 O2 124.3(7) . 4_566
O1 C1 C2 120.2(6) . .
O2 C1 C2 115.4(6) 4_566 .
C3 C2 C7 119.9(6) . .
C3 C2 C1 118.4(6) . .
C7 C2 C1 121.1(5) . .
C2 C3 C4 120.7(6) . .
C2 C3 H3A 119.6 . .
C4 C3 H3A 119.6 . .
C5 C4 C3 119.9(6) . .
C5 C4 H4A 120.1 . .
C3 C4 H4A 120.1 . .
C4 C5 C6 119.7(7) . .
C4 C5 H5A 120.1 . .
C6 C5 H5A 120.1 . .
C7 C6 C5 122.0(7) . .
C7 C6 H6B 119.0 . .
C5 C6 H6B 119.0 . .
C6 C7 C2 117.6(6) . .
C6 C7 C8 118.5(6) . .
C2 C7 C8 123.7(6) . .
C13 C8 C9 118.0(6) . .
C13 C8 C7 121.1(6) . .
C9 C8 C7 120.6(6) . .
C10 C9 C8 120.8(6) . .
C10 C9 H9A 119.6 . .
C8 C9 H9A 119.6 . .
C11 C10 C9 121.1(6) . .
C11 C10 H10A 119.5 . .
C9 C10 H10A 119.5 . .
C10 C11 C12 118.4(6) . .
C10 C11 C14 120.8(6) . 3_464
C12 C11 C14 120.8(6) . 3_464
C13 C12 C11 120.7(6) . .
C13 C12 H12B 119.6 . .
C11 C12 H12B 119.6 . .
C12 C13 C8 120.8(6) . .
C12 C13 H13B 119.6 . .
C8 C13 H13B 119.6 . .
O3 C14 O4 120.5(6) . .
O3 C14 C11 121.0(6) . 3_464
O4 C14 C11 118.5(6) . 3_464
O3 C14 Eu1 60.7(3) . .
O4 C14 Eu1 60.2(3) . .
C11 C14 Eu1 174.3(4) 3_464 .
O6 C15 O5 124.9(7) 4_565 .
O6 C15 C16 116.0(6) 4_565 .
O5 C15 C16 119.0(6) . .
C17 C16 C21 119.8(6) . .
C17 C16 C15 117.6(6) . .
C21 C16 C15 122.3(5) . .
C18 C17 C16 121.1(6) . .
C18 C17 H17A 119.5 . .
C16 C17 H17A 119.5 . .
C19 C18 C17 119.4(6) . .
C19 C18 H18A 120.3 . .
C17 C18 H18A 120.3 . .
C18 C19 C20 120.3(7) . .
C18 C19 H19A 119.8 . .
C20 C19 H19A 119.8 . .
C19 C20 C21 121.1(7) . .
C19 C20 H20A 119.4 . .
C21 C20 H20A 119.4 . .
C20 C21 C16 118.3(6) . .
C20 C21 C22 117.6(6) . .
C16 C21 C22 123.9(6) . .
C23 C22 C27 118.3(6) . .
C23 C22 C21 120.2(6) . .
C27 C22 C21 121.3(6) . .
C22 C23 C24 120.7(6) . .
C22 C23 H23A 119.6 . .
C24 C23 H23A 119.6 . .
C25 C24 C23 120.9(6) . .
C25 C24 H24A 119.6 . .
C23 C24 H24A 119.6 . .
C24 C25 C26 118.6(6) . .
C24 C25 C28 121.0(6) . 3_554
C26 C25 C28 120.4(6) . 3_554
C27 C26 C25 120.6(6) . .
C27 C26 H26A 119.7 . .
C25 C26 H26A 119.7 . .
C26 C27 C22 120.9(6) . .
C26 C27 H27A 119.6 . .
C22 C27 H27A 119.6 . .
O7 C28 O8 119.8(5) . .
O7 C28 C25 121.7(6) . 3_554
O8 C28 C25 118.6(6) . 3_554
O7 C28 Eu2 62.2(3) . .
O8 C28 Eu2 57.7(3) . .
C25 C28 Eu2 175.3(4) 3_554 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O1 2.318(5) .
Eu1 O2 2.318(5) .
Eu1 O11 2.331(5) 4_565
Eu1 O9 2.456(5) .
Eu1 O15 2.461(4) .
Eu1 O4 2.526(4) .
Eu1 O3 2.539(5) .
Eu1 O14 2.547(5) .
Eu1 C14 2.905(6) .
Eu1 O11 3.005(7) .
Eu2 O6 2.305(5) .
Eu2 O5 2.341(5) .
Eu2 O9 2.399(5) .
Eu2 O10 2.463(5) 4_565
Eu2 O13 2.472(4) .
Eu2 O8 2.496(4) .
Eu2 O12 2.516(5) .
Eu2 O7 2.598(5) .
Eu2 O10 2.799(6) .
Eu2 C28 2.934(6) .
Eu2 N1 3.063(7) .
O1 C1 1.230(8) .
O2 C1 1.244(8) 4_565
O3 C14 1.253(8) .
O4 C14 1.280(8) .
O5 C15 1.250(8) .
O6 C15 1.244(8) 4_566
O7 C28 1.251(8) .
O8 C28 1.289(8) .
O9 N1 1.322(7) .
O10 N1 1.288(8) .
O10 Eu2 2.463(5) 4_566
O11 N1 1.255(8) .
O11 Eu1 2.331(5) 4_566
O12 H12A 0.8500 .
O12 H12C 0.8500 .
O13 H13A 0.8500 .
O13 H13C 0.8500 .
O14 H14A 0.8501 .
O14 H14B 0.8501 .
O15 H15A 0.8200 .
C1 O2 1.244(8) 4_566
C1 C2 1.495(9) .
C2 C3 1.388(9) .
C2 C7 1.414(9) .
C3 C4 1.393(10) .
C3 H3A 0.9300 .
C4 C5 1.365(11) .
C4 H4A 0.9300 .
C5 C6 1.393(10) .
C5 H5A 0.9300 .
C6 C7 1.387(9) .
C6 H6B 0.9300 .
C7 C8 1.490(8) .
C8 C13 1.393(9) .
C8 C9 1.409(9) .
C9 C10 1.383(9) .
C9 H9A 0.9300 .
C10 C11 1.383(9) .
C10 H10A 0.9300 .
C11 C12 1.405(9) .
C11 C14 1.501(8) 3_464
C12 C13 1.386(9) .
C12 H12B 0.9300 .
C13 H13B 0.9300 .
C14 C11 1.501(8) 3_464
C15 O6 1.244(8) 4_565
C15 C16 1.494(9) .
C16 C17 1.396(8) .
C16 C21 1.402(9) .
C17 C18 1.386(10) .
C17 H17A 0.9300 .
C18 C19 1.373(10) .
C18 H18A 0.9300 .
C19 C20 1.392(9) .
C19 H19A 0.9300 .
C20 C21 1.397(9) .
C20 H20A 0.9300 .
C21 C22 1.501(8) .
C22 C23 1.390(9) .
C22 C27 1.396(9) .
C23 C24 1.402(9) .
C23 H23A 0.9300 .
C24 C25 1.380(9) .
C24 H24A 0.9300 .
C25 C26 1.400(9) .
C25 C28 1.501(8) 3_554
C26 C27 1.392(8) .
C26 H26A 0.9300 .
C27 H27A 0.9300 .
C28 C25 1.501(8) 3_554
