#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:38:42 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179590 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/55/4505584.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4505584
loop_
_publ_author_name
'Ahmad, Musheer'
'Sharma, Manish K.'
'Das, Raja'
'Poddar, Pankaj'
'Bharadwaj, Parimal K.'
_publ_section_title
;
 Syntheses, Crystal Structures, and Magnetic Properties of Metal--Organic
 Hybrid Materials of Co(II) Using Flexible and Rigid Nitrogen-Based
 Ditopic Ligands as Spacers
;
_journal_issue                   3
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1571
_journal_paper_doi               10.1021/cg201619x
_journal_volume                  12
_journal_year                    2012
_chemical_formula_moiety         'C22 H21 Co2 N O11'
_chemical_formula_sum            'C22 H21 Co2 N O11'
_chemical_formula_weight         593.26
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                97.640(3)
_cell_angle_beta                 91.050(5)
_cell_angle_gamma                109.285(2)
_cell_formula_units_Z            2
_cell_length_a                   8.005(2)
_cell_length_b                   10.744(5)
_cell_length_c                   14.402(5)
_cell_measurement_reflns_used    999
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      2500
_cell_measurement_theta_min      2.03
_cell_volume                     1156.2(7)
_computing_cell_refinement       'SAINT 6.45 ( Bruker, 2003)'
_computing_data_collection       'SMART 5.628 (Bruker, 2003)'
_computing_data_reduction        'SAINT 6.45 ( Bruker, 2003)'
_computing_molecular_graphics    'DIAMOND 2.1e'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    SIR-97
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'BRUKER SMART APEX'
_diffrn_measurement_method       /w-scans
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0222
_diffrn_reflns_av_sigmaI/netI    0.0442
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            6018
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.03
_exptl_absorpt_coefficient_mu    1.499
_exptl_absorpt_correction_T_max  0.8065
_exptl_absorpt_correction_T_min  0.7638
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            Pink
_exptl_crystal_density_diffrn    1.704
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             604
_exptl_crystal_size_max          0.19
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.790
_refine_diff_density_min         -0.425
_refine_diff_density_rms         0.091
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.060
_refine_ls_hydrogen_treatment    refU
_refine_ls_matrix_type           full
_refine_ls_number_parameters     347
_refine_ls_number_reflns         3989
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.060
_refine_ls_R_factor_all          0.0419
_refine_ls_R_factor_gt           0.0364
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0469P)²+1.1325P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0917
_refine_ls_wR_factor_ref         0.0974
_reflns_number_gt                3473
_reflns_number_total             3989
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg201619x_si_002.cif
_cod_data_source_block           Compound2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1156.2(8)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4505584
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Co1 Co 0.55185(5) 0.73855(4) 0.46103(3) 0.01018(13) Uani 1 1 d .
Co2 Co 0.50777(5) 1.01920(4) 0.61212(3) 0.00960(13) Uani 1 1 d .
O1 O 0.7811(3) 0.7191(2) 0.52977(17) 0.0143(5) Uani 1 1 d .
H1 H 0.8591 0.7255 0.4928 0.021 Uiso 1 1 calc R
O2 O 0.4584(3) 0.5273(2) 0.40181(16) 0.0165(5) Uani 1 1 d .
H2 H 0.3749 0.4868 0.4305 0.025 Uiso 1 1 calc R
O3 O 0.6244(3) 0.9381(2) 0.50343(15) 0.0112(5) Uani 1 1 d .
O4 O 0.6956(3) 0.7490(2) 0.34607(15) 0.0151(5) Uani 1 1 d .
O5 O 0.6118(3) 0.8962(2) 0.27756(15) 0.0142(5) Uani 1 1 d .
O6 O 0.3386(3) 0.77921(19) 0.38901(14) 0.0117(4) Uani 1 1 d .
O7 O 0.0800(3) 0.7935(2) 0.43465(15) 0.0162(5) Uani 1 1 d .
O8 O 0.9006(3) 0.6219(2) -0.12768(15) 0.0141(5) Uani 1 1 d .
O9 O -0.3874(3) 0.3297(2) 0.43417(14) 0.0126(4) Uani 1 1 d .
O10 O -0.3111(3) 0.1569(2) 0.36736(15) 0.0133(5) Uani 1 1 d .
O11 O 0.0090(4) 0.9591(3) 0.6223(2) 0.0278(6) Uani 1 1 d .
N1 N 0.6709(3) 1.0003(2) 0.72498(18) 0.0129(5) Uani 1 1 d .
C1 C 0.6633(4) 0.7975(3) 0.2752(2) 0.0118(6) Uani 1 1 d .
C2 C 0.6874(4) 0.7293(3) 0.1807(2) 0.0135(6) Uani 1 1 d .
C3 C 0.6313(4) 0.7637(3) 0.0982(2) 0.0157(7) Uani 1 1 d .
H3 H 0.5817 0.8311 0.1017 0.019 Uiso 1 1 calc R
C4 C 0.6487(4) 0.6986(3) 0.0120(2) 0.0175(7) Uani 1 1 d .
H4 H 0.6083 0.7211 -0.0421 0.021 Uiso 1 1 calc R
C5 C 0.7259(4) 0.5996(3) 0.0047(2) 0.0133(6) Uani 1 1 d .
C6 C 0.7818(4) 0.5650(3) 0.0870(2) 0.0158(7) Uani 1 1 d .
H6 H 0.8335 0.4988 0.0832 0.019 Uiso 1 1 calc R
C7 C 0.7610(4) 0.6283(3) 0.1742(2) 0.0153(7) Uani 1 1 d .
H7 H 0.7964 0.6030 0.2285 0.018 Uiso 1 1 calc R
C8 C 0.7495(4) 0.5320(3) -0.0900(2) 0.0169(7) Uani 1 1 d .
H8A H 0.7697 0.4491 -0.0840 0.020 Uiso 1 1 calc R
H8B H 0.6441 0.5120 -0.1314 0.020 Uiso 1 1 calc R
C9 C 0.1708(4) 0.7306(3) 0.3964(2) 0.0117(6) Uani 1 1 d .
C10 C 0.0837(4) 0.5889(3) 0.3497(2) 0.0119(6) Uani 1 1 d .
C11 C 0.1470(4) 0.5471(3) 0.2661(2) 0.0122(6) Uani 1 1 d .
H11 H 0.2488 0.6028 0.2438 0.015 Uiso 1 1 calc R
C12 C 0.0572(4) 0.4217(3) 0.2161(2) 0.0124(6) Uani 1 1 d .
C13 C -0.0840(4) 0.3322(3) 0.2543(2) 0.0124(6) Uani 1 1 d .
H13 H -0.1380 0.2458 0.2233 0.015 Uiso 1 1 calc R
C14 C -0.1426(4) 0.3738(3) 0.3390(2) 0.0125(6) Uani 1 1 d .
C15 C -0.0643(4) 0.5034(3) 0.3854(2) 0.0109(6) Uani 1 1 d .
H15 H -0.1103 0.5325 0.4396 0.013 Uiso 1 1 calc R
C16 C -0.2923(4) 0.2773(3) 0.3834(2) 0.0108(6) Uani 1 1 d .
C17 C 0.7527(4) 1.1044(3) 0.7921(2) 0.0184(7) Uani 1 1 d .
H17 H 0.7413 1.1864 0.7860 0.022 Uiso 1 1 calc R
C18 C 0.8517(4) 1.0971(3) 0.8689(2) 0.0199(7) Uani 1 1 d .
H18 H 0.9053 1.1727 0.9127 0.024 Uiso 1 1 calc R
C19 C 0.8713(4) 0.9756(3) 0.8808(2) 0.0159(7) Uani 1 1 d .
C20 C 0.7876(4) 0.8682(3) 0.8107(2) 0.0156(7) Uani 1 1 d .
H20 H 0.7986 0.7854 0.8141 0.019 Uiso 1 1 calc R
C21 C 0.6888(4) 0.8840(3) 0.7363(2) 0.0142(6) Uani 1 1 d .
H21 H 0.6318 0.8099 0.6920 0.017 Uiso 1 1 calc R
C22 C 0.9727(4) 0.9576(3) 0.9607(2) 0.0168(7) Uani 1 1 d .
H22 H 1.0011 0.8798 0.9556 0.020 Uiso 1 1 calc R
H23 H 0.020(9) 1.047(8) 0.627(5) 0.13(3) Uiso 1 1 d .
H24 H 0.092(6) 0.950(4) 0.641(3) 0.031(13) Uiso 1 1 d .
H25 H 0.522(6) 0.490(4) 0.405(3) 0.043(15) Uiso 1 1 d .
H12A H 0.816(6) 0.776(4) 0.558(3) 0.030(14) Uiso 1 1 d .
H11A H 0.708(5) 0.972(4) 0.506(3) 0.017(12) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Co1 O3 96.57(9) . .
O4 Co1 O9 163.63(9) . 2_566
O3 Co1 O9 99.78(9) . 2_566
O4 Co1 O1 84.29(9) . .
O3 Co1 O1 94.37(10) . .
O9 Co1 O1 93.90(9) 2_566 .
O4 Co1 O6 92.84(9) . .
O3 Co1 O6 80.52(9) . .
O9 Co1 O6 90.37(9) 2_566 .
O1 Co1 O6 173.84(8) . .
O4 Co1 O2 80.98(9) . .
O3 Co1 O2 173.63(9) . .
O9 Co1 O2 82.80(9) 2_566 .
O1 Co1 O2 91.25(10) . .
O6 Co1 O2 93.69(9) . .
O3 Co2 O10 97.47(9) . 2_566
O3 Co2 O6 97.13(9) . 2_676
O10 Co2 O6 164.57(8) 2_566 2_676
O3 Co2 O5 179.37(8) . 2_676
O10 Co2 O5 82.92(9) 2_566 2_676
O6 Co2 O5 82.43(8) 2_676 2_676
O3 Co2 O3 81.28(10) . 2_676
O10 Co2 O3 97.70(9) 2_566 2_676
O6 Co2 O3 79.66(9) 2_676 2_676
O5 Co2 O3 98.19(9) 2_676 2_676
O3 Co2 N1 97.17(10) . .
O10 Co2 N1 90.32(9) 2_566 .
O6 Co2 N1 92.76(9) 2_676 .
O5 Co2 N1 83.32(10) 2_676 .
O3 Co2 N1 171.96(10) 2_676 .
Co1 O3 Co2 122.32(12) . .
Co1 O3 Co2 96.38(10) . 2_676
Co2 O3 Co2 98.72(10) . 2_676
C1 O4 Co1 123.24(19) . .
C1 O5 Co2 128.42(19) . 2_676
C9 O6 Co2 127.46(19) . 2_676
C9 O6 Co1 128.95(18) . .
Co2 O6 Co1 92.88(8) 2_676 .
C12 O8 C8 116.4(2) 2_665 .
C16 O9 Co1 131.60(19) . 2_566
C16 O10 Co2 135.2(2) . 2_566
C21 N1 C17 116.3(3) . .
C21 N1 Co2 122.2(2) . .
C17 N1 Co2 121.4(2) . .
O5 C1 O4 125.4(3) . .
O5 C1 C2 118.0(3) . .
O4 C1 C2 116.6(3) . .
C7 C2 C3 119.0(3) . .
C7 C2 C1 120.4(3) . .
C3 C2 C1 120.6(3) . .
C4 C3 C2 120.5(3) . .
C3 C4 C5 121.0(3) . .
C4 C5 C6 118.6(3) . .
C4 C5 C8 120.5(3) . .
C6 C5 C8 120.9(3) . .
C7 C6 C5 120.7(3) . .
C6 C7 C2 120.2(3) . .
O8 C8 C5 107.5(2) . .
O7 C9 O6 124.6(3) . .
O7 C9 C10 120.1(3) . .
O6 C9 C10 115.3(3) . .
C11 C10 C15 120.2(3) . .
C11 C10 C9 118.5(3) . .
C15 C10 C9 121.2(3) . .
C12 C11 C10 119.7(3) . .
O8 C12 C11 123.4(3) 2_665 .
O8 C12 C13 116.4(3) 2_665 .
C11 C12 C13 120.3(3) . .
C14 C13 C12 119.1(3) . .
C13 C14 C15 121.0(3) . .
C13 C14 C16 120.2(3) . .
C15 C14 C16 118.8(3) . .
C14 C15 C10 119.2(3) . .
O10 C16 O9 126.4(3) . .
O10 C16 C14 118.0(3) . .
O9 C16 C14 115.7(3) . .
N1 C17 C18 124.2(3) . .
C17 C18 C19 119.6(3) . .
C18 C19 C20 116.0(3) . .
C18 C19 C22 123.6(3) . .
C20 C19 C22 120.4(3) . .
C21 C20 C19 120.6(3) . .
N1 C21 C20 123.3(3) . .
C22 C22 C19 125.6(4) 2_777 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 O4 2.028(2) .
Co1 O3 2.030(2) .
Co1 O9 2.068(2) 2_566
Co1 O1 2.152(3) .
Co1 O6 2.174(2) .
Co1 O2 2.186(2) .
Co2 O3 2.076(2) .
Co2 O10 2.084(2) 2_566
Co2 O6 2.111(2) 2_676
Co2 O5 2.124(2) 2_676
Co2 O3 2.135(2) 2_676
Co2 N1 2.139(3) .
O3 Co2 2.135(2) 2_676
O4 C1 1.266(4) .
O5 C1 1.254(4) .
O5 Co2 2.124(2) 2_676
O6 C9 1.283(4) .
O6 Co2 2.111(2) 2_676
O7 C9 1.237(4) .
O8 C12 1.385(4) 2_665
O8 C8 1.443(4) .
O9 C16 1.275(4) .
O9 Co1 2.068(2) 2_566
O10 C16 1.242(4) .
O10 Co2 2.084(2) 2_566
N1 C21 1.333(4) .
N1 C17 1.349(4) .
C1 C2 1.505(4) .
C2 C7 1.390(4) .
C2 C3 1.398(4) .
C3 C4 1.374(5) .
C4 C5 1.390(4) .
C5 C6 1.396(4) .
C5 C8 1.503(4) .
C6 C7 1.387(4) .
C9 C10 1.505(4) .
C10 C11 1.391(4) .
C10 C15 1.394(4) .
C11 C12 1.391(4) .
C12 O8 1.385(4) 2_665
C12 C13 1.396(4) .
C13 C14 1.386(4) .
C14 C15 1.393(4) .
C14 C16 1.518(4) .
C17 C18 1.374(4) .
C18 C19 1.398(5) .
C19 C20 1.398(4) .
C19 C22 1.466(4) .
C20 C21 1.381(4) .
C22 C22 1.323(6) 2_777
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O4 Co1 O3 Co2 172.01(12) . .
O9 Co1 O3 Co2 -8.52(14) 2_566 .
O1 Co1 O3 Co2 -103.25(14) . .
O6 Co1 O3 Co2 80.21(13) . .
O2 Co1 O3 Co2 105.0(8) . .
O4 Co1 O3 Co2 67.46(10) . 2_676
O9 Co1 O3 Co2 -113.07(10) 2_566 2_676
O1 Co1 O3 Co2 152.20(9) . 2_676
O6 Co1 O3 Co2 -24.34(9) . 2_676
O2 Co1 O3 Co2 0.4(9) . 2_676
O10 Co2 O3 Co1 -6.60(14) 2_566 .
O6 Co2 O3 Co1 178.37(12) 2_676 .
O5 Co2 O3 Co1 -135(8) 2_676 .
O3 Co2 O3 Co1 -103.30(16) 2_676 .
N1 Co2 O3 Co1 84.66(14) . .
O10 Co2 O3 Co2 96.70(10) 2_566 2_676
O6 Co2 O3 Co2 -78.33(10) 2_676 2_676
O5 Co2 O3 Co2 -32(8) 2_676 2_676
O3 Co2 O3 Co2 0.0 2_676 2_676
N1 Co2 O3 Co2 -172.04(9) . 2_676
O3 Co1 O4 C1 -66.5(2) . .
O9 Co1 O4 C1 115.3(3) 2_566 .
O1 Co1 O4 C1 -160.3(2) . .
O6 Co1 O4 C1 14.3(2) . .
O2 Co1 O4 C1 107.6(2) . .
O4 Co1 O6 C9 142.9(2) . .
O3 Co1 O6 C9 -121.0(3) . .
O9 Co1 O6 C9 -21.1(2) 2_566 .
O1 Co1 O6 C9 -155.1(7) . .
O2 Co1 O6 C9 61.7(2) . .
O4 Co1 O6 Co2 -71.68(9) . 2_676
O3 Co1 O6 Co2 24.51(9) . 2_676
O9 Co1 O6 Co2 124.37(8) 2_566 2_676
O1 Co1 O6 Co2 -9.6(8) . 2_676
O2 Co1 O6 Co2 -152.82(9) . 2_676
O3 Co2 N1 C21 -54.9(2) . .
O10 Co2 N1 C21 42.7(2) 2_566 .
O6 Co2 N1 C21 -152.4(2) 2_676 .
O5 Co2 N1 C21 125.5(2) 2_676 .
O3 Co2 N1 C21 -133.2(6) 2_676 .
O3 Co2 N1 C17 129.4(2) . .
O10 Co2 N1 C17 -133.1(2) 2_566 .
O6 Co2 N1 C17 31.8(2) 2_676 .
O5 Co2 N1 C17 -50.2(2) 2_676 .
O3 Co2 N1 C17 51.1(8) 2_676 .
Co2 O5 C1 O4 -19.1(4) 2_676 .
Co2 O5 C1 C2 160.21(19) 2_676 .
Co1 O4 C1 O5 36.9(4) . .
Co1 O4 C1 C2 -142.4(2) . .
O5 C1 C2 C7 173.5(3) . .
O4 C1 C2 C7 -7.1(4) . .
O5 C1 C2 C3 -8.5(4) . .
O4 C1 C2 C3 170.9(3) . .
C7 C2 C3 C4 -0.1(4) . .
C1 C2 C3 C4 -178.1(3) . .
C2 C3 C4 C5 -1.5(5) . .
C3 C4 C5 C6 1.5(4) . .
C3 C4 C5 C8 -178.1(3) . .
C4 C5 C6 C7 -0.1(4) . .
C8 C5 C6 C7 179.5(3) . .
C5 C6 C7 C2 -1.4(5) . .
C3 C2 C7 C6 1.5(4) . .
C1 C2 C7 C6 179.5(3) . .
C12 O8 C8 C5 -179.0(2) 2_665 .
C4 C5 C8 O8 77.5(3) . .
C6 C5 C8 O8 -102.1(3) . .
Co2 O6 C9 O7 -25.7(4) 2_676 .
Co1 O6 C9 O7 108.8(3) . .
Co2 O6 C9 C10 151.1(2) 2_676 .
Co1 O6 C9 C10 -74.4(3) . .
O7 C9 C10 C11 141.5(3) . .
O6 C9 C10 C11 -35.4(4) . .
O7 C9 C10 C15 -34.3(4) . .
O6 C9 C10 C15 148.8(3) . .
C15 C10 C11 C12 2.9(4) . .
C9 C10 C11 C12 -173.0(3) . .
C10 C11 C12 O8 172.7(3) . 2_665
C10 C11 C12 C13 -7.0(4) . .
O8 C12 C13 C14 -174.5(3) 2_665 .
C11 C12 C13 C14 5.2(4) . .
C12 C13 C14 C15 0.9(4) . .
C12 C13 C14 C16 -178.2(3) . .
C13 C14 C15 C10 -5.0(4) . .
C16 C14 C15 C10 174.1(3) . .
C11 C10 C15 C14 3.1(4) . .
C9 C10 C15 C14 178.9(3) . .
Co2 O10 C16 O9 12.3(5) 2_566 .
Co2 O10 C16 C14 -167.60(19) 2_566 .
Co1 O9 C16 O10 20.8(4) 2_566 .
Co1 O9 C16 C14 -159.26(19) 2_566 .
C13 C14 C16 O10 29.0(4) . .
C15 C14 C16 O10 -150.2(3) . .
C13 C14 C16 O9 -151.0(3) . .
C15 C14 C16 O9 29.9(4) . .
C21 N1 C17 C18 0.5(5) . .
Co2 N1 C17 C18 176.5(3) . .
N1 C17 C18 C19 -0.3(5) . .
C17 C18 C19 C20 0.8(5) . .
C17 C18 C19 C22 -179.4(3) . .
C18 C19 C20 C21 -1.6(5) . .
C22 C19 C20 C21 178.6(3) . .
C17 N1 C21 C20 -1.4(4) . .
Co2 N1 C21 C20 -177.3(2) . .
C19 C20 C21 N1 2.0(5) . .
C18 C19 C22 C22 14.3(6) . 2_777
C20 C19 C22 C22 -165.8(4) . 2_777
