#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:48:13 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179597 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/61/4506100.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4506100
loop_
_publ_author_name
'Zhu, Yan'
'Luo, Feng'
'Song, Yu-mei'
'Feng, Xue-feng'
'Luo, Ming-biao'
'Liao, Zhen-wei'
'Sun, Gong-ming'
'Tian, Xiao-zhao'
'Yuan, Zi-Jun'
_publ_section_title
;
 The First One-Pot Synthesis of Multinuclear 3d-4f Metal--Organic
 Compounds Involving a Polytopic N,O-Donor Ligand Formed in Situ
;
_journal_issue                   5
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              2158
_journal_paper_doi               10.1021/cg3002509
_journal_volume                  12
_journal_year                    2012
_chemical_formula_sum            'C120 H86 Co4 Gd2 N12 O14'
_chemical_formula_weight         2470.23
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           176
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  '-P 6c'
_symmetry_space_group_name_H-M   'P 63/m'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            1
_cell_length_a                   13.40490(10)
_cell_length_b                   13.40490(10)
_cell_length_c                   18.4479(2)
_cell_measurement_reflns_used    3876
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.37
_cell_measurement_theta_min      2.82
_cell_volume                     2870.81(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0385
_diffrn_reflns_av_sigmaI/netI    0.0223
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            13677
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.75
_exptl_absorpt_coefficient_mu    1.768
_exptl_absorpt_correction_T_max  0.7187
_exptl_absorpt_correction_T_min  0.6763
_exptl_absorpt_correction_type   none
_exptl_crystal_density_diffrn    1.429
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1238
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.563
_refine_diff_density_min         -1.129
_refine_diff_density_rms         0.071
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.097
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     132
_refine_ls_number_reflns         1749
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      1.096
_refine_ls_R_factor_all          0.0482
_refine_ls_R_factor_gt           0.0411
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0405P)²+3.9888P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0996
_refine_ls_wR_factor_ref         0.1046
_reflns_number_gt                1517
_reflns_number_total             1749
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg3002509_si_002.cif
_cod_data_source_block           12
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Hexagonal' changed to 'hexagonal'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P6(3)/m
_cod_database_code               4506100
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'x, y, -z-1/2'
'-y, x-y, -z-1/2'
'-x+y, -x, -z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.4278(4) 0.2804(4) 0.4274(2) 0.0529(10) Uani 1 1 d .
C2 C 0.4313(4) 0.2314(3) 0.3595(2) 0.0491(9) Uani 1 1 d .
C3 C 0.5255(5) 0.3768(4) 0.5318(3) 0.0774(15) Uani 1 1 d .
H3 H 0.5928 0.4127 0.5590 0.093 Uiso 1 1 calc R
C4 C 0.4252(6) 0.3708(5) 0.5599(3) 0.0894(18) Uani 1 1 d .
H4 H 0.4271 0.4034 0.6048 0.107 Uiso 1 1 calc R
C5 C 0.3270(6) 0.3178(5) 0.5220(3) 0.0848(16) Uani 1 1 d .
H5 H 0.2601 0.3116 0.5414 0.102 Uiso 1 1 calc R
C6 C 0.3241(5) 0.2715(4) 0.4531(3) 0.0682(13) Uani 1 1 d .
C7 C 0.2253(5) 0.2129(6) 0.4103(3) 0.0856(17) Uani 1 1 d .
H7 H 0.1564 0.2067 0.4257 0.103 Uiso 1 1 calc R
C8 C 0.2294(5) 0.1645(6) 0.3457(3) 0.0805(16) Uani 1 1 d .
H8 H 0.1624 0.1254 0.3184 0.097 Uiso 1 1 calc R
C9 C 0.3309(3) 0.1719(4) 0.3192(2) 0.0564(11) Uani 1 1 d .
C10 C 0.3318(5) 0.1101(6) 0.2500 0.0591(15) Uani 1 2 d SD
C11 C 0.2328(8) -0.0172(8) 0.2500 0.089(2) Uani 1 2 d SD
Co1 Co 0.6667 0.3333 0.41548(5) 0.0482(3) Uani 1 3 d S
Gd1 Gd 0.6667 0.3333 0.2500 0.0589(2) Uani 1 6 d S
H1A H 0.9664(12) 0.521(15) 0.2500 0.071 Uiso 0.33 2 d SPD
H2A H 0.401(3) 0.100(6) 0.2500 0.071 Uiso 1 2 d SD
H3A H 0.166(4) -0.004(6) 0.2500 0.071 Uiso 1 2 d SD
H4A H 0.248(4) -0.054(4) 0.2925(18) 0.071 Uiso 1 1 d D
N1 N 0.5273(3) 0.3330(3) 0.46742(18) 0.0598(9) Uani 1 1 d .
O1 O 0.5311(2) 0.2415(2) 0.34001(13) 0.0463(6) Uani 1 1 d .
O2 O 0.8933(7) 0.4836(7) 0.2500 0.0275(19) Uani 0.33 2 d SPD
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 C1 C6 121.6(4) . .
N1 C1 C2 117.5(4) . .
C6 C1 C2 120.8(4) . .
O1 C2 C9 123.5(4) . .
O1 C2 C1 117.1(4) . .
C9 C2 C1 119.3(4) . .
N1 C3 C4 122.2(5) . .
N1 C3 H3 118.9 . .
C4 C3 H3 118.9 . .
C5 C4 C3 119.8(5) . .
C5 C4 H4 120.1 . .
C3 C4 H4 120.1 . .
C4 C5 C6 120.6(5) . .
C4 C5 H5 119.7 . .
C6 C5 H5 119.7 . .
C7 C6 C5 124.6(5) . .
C7 C6 C1 118.2(4) . .
C5 C6 C1 117.1(5) . .
C8 C7 C6 120.4(5) . .
C8 C7 H7 119.8 . .
C6 C7 H7 119.8 . .
C7 C8 C9 122.5(5) . .
C7 C8 H8 118.8 . .
C9 C8 H8 118.8 . .
C2 C9 C8 118.8(4) . .
C2 C9 C10 119.4(4) . .
C8 C9 C10 121.6(5) . .
C9 C10 C9 113.7(5) . 10_556
C9 C10 C11 111.2(3) . .
C9 C10 C11 111.2(3) 10_556 .
C9 C10 H2A 109.5(18) . .
C9 C10 H2A 109.5(18) 10_556 .
C11 C10 H2A 101(4) . .
C10 C11 H3A 99(4) . .
C10 C11 H4A 106(3) . .
H3A C11 H4A 121(3) . .
N1 Co1 N1 100.78(13) 2_655 3_665
N1 Co1 N1 100.78(13) 2_655 .
N1 Co1 N1 100.78(13) 3_665 .
N1 Co1 O1 78.18(12) 2_655 2_655
N1 Co1 O1 99.54(12) 3_665 2_655
N1 Co1 O1 159.47(13) . 2_655
N1 Co1 O1 99.54(12) 2_655 .
N1 Co1 O1 159.47(13) 3_665 .
N1 Co1 O1 78.18(12) . .
O1 Co1 O1 81.76(10) 2_655 .
N1 Co1 O1 159.47(13) 2_655 3_665
N1 Co1 O1 78.18(12) 3_665 3_665
N1 Co1 O1 99.54(12) . 3_665
O1 Co1 O1 81.76(10) 2_655 3_665
O1 Co1 O1 81.76(10) . 3_665
N1 Co1 Gd1 117.18(10) 2_655 .
N1 Co1 Gd1 117.18(10) 3_665 .
N1 Co1 Gd1 117.18(10) . .
O1 Co1 Gd1 49.09(7) 2_655 .
O1 Co1 Gd1 49.09(7) . .
O1 Co1 Gd1 49.09(7) 3_665 .
O1 Gd1 O1 91.89(13) 2_655 11_656
O1 Gd1 O1 139.31(5) 2_655 10_556
O1 Gd1 O1 74.06(10) 11_656 10_556
O1 Gd1 O1 74.06(10) 2_655 3_665
O1 Gd1 O1 139.31(5) 11_656 3_665
O1 Gd1 O1 139.31(5) 10_556 3_665
O1 Gd1 O1 74.06(10) 2_655 .
O1 Gd1 O1 139.31(5) 11_656 .
O1 Gd1 O1 91.89(13) 10_556 .
O1 Gd1 O1 74.06(10) 3_665 .
O1 Gd1 O1 139.31(5) 2_655 12_666
O1 Gd1 O1 74.06(10) 11_656 12_666
O1 Gd1 O1 74.06(10) 10_556 12_666
O1 Gd1 O1 91.89(13) 3_665 12_666
O1 Gd1 O1 139.31(5) . 12_666
O1 Gd1 O2 70.24(14) 2_655 3_665
O1 Gd1 O2 70.24(14) 11_656 3_665
O1 Gd1 O2 69.07(14) 10_556 3_665
O1 Gd1 O2 134.05(6) 3_665 3_665
O1 Gd1 O2 69.07(14) . 3_665
O1 Gd1 O2 134.05(6) 12_666 3_665
O1 Gd1 O2 69.07(14) 2_655 .
O1 Gd1 O2 69.07(14) 11_656 .
O1 Gd1 O2 134.05(6) 10_556 .
O1 Gd1 O2 70.24(14) 3_665 .
O1 Gd1 O2 134.05(6) . .
O1 Gd1 O2 70.24(14) 12_666 .
O2 Gd1 O2 120.0 3_665 .
O1 Gd1 O2 134.05(6) 2_655 2_655
O1 Gd1 O2 134.05(6) 11_656 2_655
O1 Gd1 O2 70.24(14) 10_556 2_655
O1 Gd1 O2 69.07(14) 3_665 2_655
O1 Gd1 O2 70.24(14) . 2_655
O1 Gd1 O2 69.07(14) 12_666 2_655
O2 Gd1 O2 120.000(2) 3_665 2_655
O2 Gd1 O2 120.000(1) . 2_655
O1 Gd1 Co1 44.06(6) 2_655 .
O1 Gd1 Co1 135.94(6) 11_656 .
O1 Gd1 Co1 135.94(6) 10_556 .
O1 Gd1 Co1 44.06(6) 3_665 .
O1 Gd1 Co1 44.06(6) . .
O1 Gd1 Co1 135.94(6) 12_666 .
O2 Gd1 Co1 90.0 3_665 .
O2 Gd1 Co1 90.0 . .
O2 Gd1 Co1 90.0 2_655 .
O1 Gd1 Co1 135.94(6) 2_655 10_556
O1 Gd1 Co1 44.06(6) 11_656 10_556
O1 Gd1 Co1 44.06(6) 10_556 10_556
O1 Gd1 Co1 135.94(6) 3_665 10_556
O1 Gd1 Co1 135.94(6) . 10_556
O1 Gd1 Co1 44.06(6) 12_666 10_556
O2 Gd1 Co1 90.0 3_665 10_556
O2 Gd1 Co1 90.0 . 10_556
O2 Gd1 Co1 90.0 2_655 10_556
Co1 Gd1 Co1 180.0 . 10_556
C3 N1 C1 118.7(4) . .
C3 N1 Co1 128.3(4) . .
C1 N1 Co1 113.1(3) . .
C2 O1 Co1 114.1(2) . .
C2 O1 Gd1 137.2(2) . .
Co1 O1 Gd1 86.85(9) . .
Gd1 O2 H1A 170(10) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N1 1.371(6) .
C1 C6 1.417(6) .
C1 C2 1.426(6) .
C2 O1 1.325(5) .
C2 C9 1.389(6) .
C3 N1 1.331(5) .
C3 C4 1.404(8) .
C3 H3 0.9300 .
C4 C5 1.339(8) .
C4 H4 0.9300 .
C5 C6 1.407(7) .
C5 H5 0.9300 .
C6 C7 1.398(8) .
C7 C8 1.370(7) .
C7 H7 0.9300 .
C8 C9 1.401(6) .
C8 H8 0.9300 .
C9 C10 1.526(6) .
C10 C9 1.526(6) 10_556
C10 C11 1.551(11) .
C10 H2A 1.002(10) .
C11 H3A 1.000(10) .
C11 H4A 1.007(10) .
Co1 N1 2.098(4) 2_655
Co1 N1 2.098(4) 3_665
Co1 N1 2.098(4) .
Co1 O1 2.126(3) 2_655
Co1 O1 2.126(3) .
Co1 O1 2.126(3) 3_665
Co1 Gd1 3.0528(8) .
Gd1 O1 2.311(2) 2_655
Gd1 O1 2.311(2) 11_656
Gd1 O1 2.311(2) 10_556
Gd1 O1 2.311(2) 3_665
Gd1 O1 2.311(2) .
Gd1 O1 2.311(2) 12_666
Gd1 O2 2.678(8) 3_665
Gd1 O2 2.678(8) .
Gd1 O2 2.678(8) 2_655
Gd1 Co1 3.0528(8) 10_556
O2 H1A 0.848(11) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C1 C2 O1 -0.6(5) . .
C6 C1 C2 O1 -178.7(4) . .
N1 C1 C2 C9 176.5(4) . .
C6 C1 C2 C9 -1.7(6) . .
N1 C3 C4 C5 1.0(9) . .
C3 C4 C5 C6 -2.1(9) . .
C4 C5 C6 C7 178.6(6) . .
C4 C5 C6 C1 2.0(8) . .
N1 C1 C6 C7 -177.7(4) . .
C2 C1 C6 C7 0.4(7) . .
N1 C1 C6 C5 -0.8(7) . .
C2 C1 C6 C5 177.3(4) . .
C5 C6 C7 C8 -175.9(5) . .
C1 C6 C7 C8 0.7(8) . .
C6 C7 C8 C9 -0.6(9) . .
O1 C2 C9 C8 178.6(4) . .
C1 C2 C9 C8 1.8(6) . .
O1 C2 C9 C10 2.3(6) . .
C1 C2 C9 C10 -174.5(4) . .
C7 C8 C9 C2 -0.7(8) . .
C7 C8 C9 C10 175.5(5) . .
C2 C9 C10 C9 -105.0(5) . 10_556
C8 C9 C10 C9 78.8(7) . 10_556
C2 C9 C10 C11 128.4(6) . .
C8 C9 C10 C11 -47.8(7) . .
N1 Co1 Gd1 O1 -41.45(14) 2_655 2_655
N1 Co1 Gd1 O1 78.55(14) 3_665 2_655
N1 Co1 Gd1 O1 -161.45(14) . 2_655
O1 Co1 Gd1 O1 -120.0 . 2_655
O1 Co1 Gd1 O1 120.0 3_665 2_655
N1 Co1 Gd1 O1 -41.45(14) 2_655 11_656
N1 Co1 Gd1 O1 78.55(14) 3_665 11_656
N1 Co1 Gd1 O1 -161.45(14) . 11_656
O1 Co1 Gd1 O1 0.0 2_655 11_656
O1 Co1 Gd1 O1 -120.0 . 11_656
O1 Co1 Gd1 O1 120.0 3_665 11_656
N1 Co1 Gd1 O1 78.55(14) 2_655 10_556
N1 Co1 Gd1 O1 -161.45(14) 3_665 10_556
N1 Co1 Gd1 O1 -41.45(14) . 10_556
O1 Co1 Gd1 O1 120.0 2_655 10_556
O1 Co1 Gd1 O1 0.0 . 10_556
O1 Co1 Gd1 O1 -120.0 3_665 10_556
N1 Co1 Gd1 O1 -161.45(14) 2_655 3_665
N1 Co1 Gd1 O1 -41.45(14) 3_665 3_665
N1 Co1 Gd1 O1 78.55(14) . 3_665
O1 Co1 Gd1 O1 -120.0 2_655 3_665
O1 Co1 Gd1 O1 120.0 . 3_665
N1 Co1 Gd1 O1 78.55(14) 2_655 .
N1 Co1 Gd1 O1 -161.45(14) 3_665 .
N1 Co1 Gd1 O1 -41.45(14) . .
O1 Co1 Gd1 O1 120.0 2_655 .
O1 Co1 Gd1 O1 -120.0 3_665 .
N1 Co1 Gd1 O1 -161.45(14) 2_655 12_666
N1 Co1 Gd1 O1 -41.45(14) 3_665 12_666
N1 Co1 Gd1 O1 78.55(14) . 12_666
O1 Co1 Gd1 O1 -120.0 2_655 12_666
O1 Co1 Gd1 O1 120.0 . 12_666
O1 Co1 Gd1 O1 0.0 3_665 12_666
N1 Co1 Gd1 O2 19.5(2) 2_655 3_665
N1 Co1 Gd1 O2 139.5(2) 3_665 3_665
N1 Co1 Gd1 O2 -100.5(2) . 3_665
O1 Co1 Gd1 O2 60.9(2) 2_655 3_665
O1 Co1 Gd1 O2 -59.1(2) . 3_665
O1 Co1 Gd1 O2 -179.1(2) 3_665 3_665
N1 Co1 Gd1 O2 -100.5(2) 2_655 .
N1 Co1 Gd1 O2 19.5(2) 3_665 .
N1 Co1 Gd1 O2 139.5(2) . .
O1 Co1 Gd1 O2 -59.1(2) 2_655 .
O1 Co1 Gd1 O2 -179.1(2) . .
O1 Co1 Gd1 O2 60.9(2) 3_665 .
N1 Co1 Gd1 O2 139.5(2) 2_655 2_655
N1 Co1 Gd1 O2 -100.5(2) 3_665 2_655
N1 Co1 Gd1 O2 19.5(2) . 2_655
O1 Co1 Gd1 O2 -179.1(2) 2_655 2_655
O1 Co1 Gd1 O2 60.9(2) . 2_655
O1 Co1 Gd1 O2 -59.1(2) 3_665 2_655
N1 Co1 Gd1 Co1 120(44) 2_655 10_556
N1 Co1 Gd1 Co1 -120(24) 3_665 10_556
N1 Co1 Gd1 Co1 0(24) . 10_556
O1 Co1 Gd1 Co1 162(44) 2_655 10_556
O1 Co1 Gd1 Co1 42(24) . 10_556
O1 Co1 Gd1 Co1 -78(24) 3_665 10_556
C4 C3 N1 C1 0.1(7) . .
C4 C3 N1 Co1 179.7(4) . .
C6 C1 N1 C3 -0.3(6) . .
C2 C1 N1 C3 -178.4(4) . .
C6 C1 N1 Co1 -179.9(3) . .
C2 C1 N1 Co1 2.0(5) . .
N1 Co1 N1 C3 80.9(4) 2_655 .
N1 Co1 N1 C3 -22.4(4) 3_665 .
O1 Co1 N1 C3 166.0(4) 2_655 .
O1 Co1 N1 C3 178.5(4) . .
O1 Co1 N1 C3 -102.1(4) 3_665 .
Gd1 Co1 N1 C3 -150.8(4) . .
N1 Co1 N1 C1 -99.5(3) 2_655 .
N1 Co1 N1 C1 157.2(3) 3_665 .
O1 Co1 N1 C1 -14.5(5) 2_655 .
O1 Co1 N1 C1 -1.9(3) . .
O1 Co1 N1 C1 77.5(3) 3_665 .
Gd1 Co1 N1 C1 28.8(3) . .
C9 C2 O1 Co1 -178.0(3) . .
C1 C2 O1 Co1 -1.2(4) . .
C9 C2 O1 Gd1 68.7(5) . .
C1 C2 O1 Gd1 -114.4(4) . .
N1 Co1 O1 C2 100.8(3) 2_655 .
N1 Co1 O1 C2 -87.5(4) 3_665 .
N1 Co1 O1 C2 1.7(2) . .
O1 Co1 O1 C2 177.3(3) 2_655 .
O1 Co1 O1 C2 -99.9(3) 3_665 .
Gd1 Co1 O1 C2 -141.3(3) . .
N1 Co1 O1 Gd1 -117.86(12) 2_655 .
N1 Co1 O1 Gd1 53.8(4) 3_665 .
N1 Co1 O1 Gd1 143.01(12) . .
O1 Co1 O1 Gd1 -41.40(4) 2_655 .
O1 Co1 O1 Gd1 41.40(4) 3_665 .
O1 Gd1 O1 C2 161.6(4) 2_655 .
O1 Gd1 O1 C2 -124.6(4) 11_656 .
O1 Gd1 O1 C2 -57.2(4) 10_556 .
O1 Gd1 O1 C2 84.1(4) 3_665 .
O1 Gd1 O1 C2 10.3(4) 12_666 .
O2 Gd1 O1 C2 -123.9(4) 3_665 .
O2 Gd1 O1 C2 124.1(4) . .
O2 Gd1 O1 C2 11.1(4) 2_655 .
Co1 Gd1 O1 C2 122.8(4) . .
Co1 Gd1 O1 C2 -57.2(4) 10_556 .
O1 Gd1 O1 Co1 38.78(3) 2_655 .
O1 Gd1 O1 Co1 112.53(2) 11_656 .
O1 Gd1 O1 Co1 180.0 10_556 .
O1 Gd1 O1 Co1 -38.78(3) 3_665 .
O1 Gd1 O1 Co1 -112.53(2) 12_666 .
O2 Gd1 O1 Co1 113.29(18) 3_665 .
O2 Gd1 O1 Co1 1.3(3) . .
O2 Gd1 O1 Co1 -111.79(18) 2_655 .
Co1 Gd1 O1 Co1 180.0 10_556 .
