#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:51:31 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179600 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/64/4506498.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4506498
loop_
_publ_author_name
'Zhang, Ying'
'Yang, Jin'
'Yang, Yan'
'Guo, Jiao'
'Ma, Jian-Fang'
_publ_section_title
;
 Syntheses, Structures, and Luminescent Properties of a Series of
 Coordination Compounds Based on (4-Carboxylphenyl)
 (4-(2′-Carboxylphenyl)benzyl) Ether and Different N-Donor Ligands
;
_journal_issue                   8
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              4060
_journal_paper_doi               10.1021/cg300540d
_journal_volume                  12
_journal_year                    2012
_chemical_formula_moiety         'C66 H52 Co N4 O13'
_chemical_formula_sum            'C66 H52 Co N4 O13'
_chemical_formula_weight         1168.05
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                84.130(3)
_cell_angle_beta                 87.014(3)
_cell_angle_gamma                78.248(3)
_cell_formula_units_Z            2
_cell_length_a                   12.2270(4)
_cell_length_b                   15.1410(5)
_cell_length_c                   15.2690(4)
_cell_measurement_reflns_used    7159
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.1515
_cell_measurement_theta_min      2.7548
_cell_volume                     2751.55(15)
_computing_cell_refinement       CrysAlis
_computing_data_collection       'CrysAlis (Oxford Diffraction, 2006)'
_computing_data_reduction        CrysAlis
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.0
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Oxford Diffraction Gemini R Ultra'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0232
_diffrn_reflns_av_sigmaI/netI    0.0419
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            17471
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         2.76
_exptl_absorpt_coefficient_mu    0.385
_exptl_absorpt_correction_T_max  0.9962
_exptl_absorpt_correction_T_min  0.9962
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis (Oxford Diffraction, 2006)
;
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    1.410
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1214
_exptl_crystal_size_max          0.01
_exptl_crystal_size_mid          0.01
_exptl_crystal_size_min          0.01
_refine_diff_density_max         0.694
_refine_diff_density_min         -0.564
_refine_diff_density_rms         0.048
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.980
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     757
_refine_ls_number_reflns         9649
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.980
_refine_ls_R_factor_all          0.0631
_refine_ls_R_factor_gt           0.0457
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0555P)²+1.8338P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1137
_refine_ls_wR_factor_ref         0.1249
_reflns_number_gt                7576
_reflns_number_total             9649
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            cg300540d_si_002.cif
_cod_data_source_block           Compound-9
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4506498
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Co1 Co 0.66523(3) 0.44450(2) 0.91947(2) 0.03378(11) Uani 1 1 d .
C1 C 0.9710(3) 0.2751(2) 0.45078(18) 0.0476(7) Uani 1 1 d .
C2 C 0.9215(2) 0.3579(2) 0.49552(18) 0.0437(7) Uani 1 1 d .
C3 C 0.8536(3) 0.4280(2) 0.4459(2) 0.0563(8) Uani 1 1 d .
H3 H 0.8333 0.4185 0.3903 0.068 Uiso 1 1 calc R
C4 C 0.8156(3) 0.5113(2) 0.4773(2) 0.0646(9) Uani 1 1 d .
H4 H 0.7708 0.5577 0.4432 0.078 Uiso 1 1 calc R
C5 C 0.8451(3) 0.5246(2) 0.5599(2) 0.0625(9) Uani 1 1 d .
H5 H 0.8222 0.5811 0.5811 0.075 Uiso 1 1 calc R
C6 C 0.9088(3) 0.4543(2) 0.6116(2) 0.0529(8) Uani 1 1 d .
H6 H 0.9261 0.4641 0.6680 0.063 Uiso 1 1 calc R
C7 C 0.9477(2) 0.3697(2) 0.58140(18) 0.0441(7) Uani 1 1 d .
C8 C 1.0055(2) 0.2945(2) 0.64308(18) 0.0436(7) Uani 1 1 d .
C9 C 1.0746(3) 0.3108(2) 0.70673(19) 0.0507(7) Uani 1 1 d .
H9 H 1.0890 0.3687 0.7076 0.061 Uiso 1 1 calc R
C10 C 1.1222(3) 0.2423(2) 0.76890(19) 0.0539(8) Uani 1 1 d .
H10 H 1.1683 0.2550 0.8105 0.065 Uiso 1 1 calc R
C11 C 1.1024(3) 0.1559(2) 0.77001(18) 0.0514(8) Uani 1 1 d .
C12 C 1.0328(3) 0.1391(2) 0.7075(2) 0.0545(8) Uani 1 1 d .
H12 H 1.0178 0.0813 0.7075 0.065 Uiso 1 1 calc R
C13 C 0.9853(2) 0.2070(2) 0.6451(2) 0.0493(7) Uani 1 1 d .
H13 H 0.9391 0.1939 0.6037 0.059 Uiso 1 1 calc R
C14 C 1.1603(3) 0.0785(2) 0.8311(2) 0.0657(10) Uani 1 1 d .
H14A H 1.1092 0.0380 0.8479 0.079 Uiso 1 1 calc R
H14B H 1.2237 0.0450 0.7995 0.079 Uiso 1 1 calc R
C15 C 1.1273(2) 0.11772(18) 0.98103(18) 0.0444(7) Uani 1 1 d .
C16 C 1.0149(3) 0.11675(19) 0.98209(18) 0.0481(7) Uani 1 1 d .
H16 H 0.9809 0.1100 0.9308 0.058 Uiso 1 1 calc R
C17 C 0.9526(3) 0.12608(19) 1.06099(18) 0.0456(7) Uani 1 1 d .
H17 H 0.8767 0.1254 1.0618 0.055 Uiso 1 1 calc R
C18 C 1.0016(2) 0.13631(17) 1.13804(17) 0.0400(6) Uani 1 1 d .
C19 C 1.1148(2) 0.14008(18) 1.13437(18) 0.0442(7) Uani 1 1 d .
H19 H 1.1490 0.1483 1.1851 0.053 Uiso 1 1 calc R
C20 C 1.1766(2) 0.13184(19) 1.05679(19) 0.0463(7) Uani 1 1 d .
H20 H 1.2516 0.1357 1.0551 0.056 Uiso 1 1 calc R
C21 C 0.9356(3) 0.14126(18) 1.22396(19) 0.0455(7) Uani 1 1 d .
C22 C 0.6473(3) 1.0391(2) 0.33801(19) 0.0496(7) Uani 1 1 d .
C23 C 0.6159(2) 0.95921(19) 0.38956(18) 0.0446(7) Uani 1 1 d .
C24 C 0.5036(3) 0.9556(2) 0.40184(19) 0.0489(7) Uani 1 1 d .
H24 H 0.4501 1.0028 0.3768 0.059 Uiso 1 1 calc R
C25 C 0.4696(3) 0.8833(2) 0.45042(19) 0.0497(7) Uani 1 1 d .
H25 H 0.3941 0.8818 0.4584 0.060 Uiso 1 1 calc R
C26 C 0.5497(3) 0.8132(2) 0.4869(2) 0.0512(7) Uani 1 1 d .
C27 C 0.6619(3) 0.8153(2) 0.4746(2) 0.0604(9) Uani 1 1 d .
H27 H 0.7154 0.7674 0.4985 0.073 Uiso 1 1 calc R
C28 C 0.6946(3) 0.8884(2) 0.4266(2) 0.0547(8) Uani 1 1 d .
H28 H 0.7702 0.8899 0.4192 0.066 Uiso 1 1 calc R
C29 C 0.4127(3) 0.7363(2) 0.5614(2) 0.0526(8) Uani 1 1 d .
H29A H 0.3687 0.7403 0.5095 0.063 Uiso 1 1 calc R
H29B H 0.3811 0.7870 0.5950 0.063 Uiso 1 1 calc R
C30 C 0.4115(2) 0.64844(19) 0.61643(18) 0.0429(7) Uani 1 1 d .
C31 C 0.3447(2) 0.64542(19) 0.69217(18) 0.0410(6) Uani 1 1 d .
H31 H 0.3006 0.6986 0.7100 0.049 Uiso 1 1 calc R
C32 C 0.3430(2) 0.56378(18) 0.74165(17) 0.0381(6) Uani 1 1 d .
H32 H 0.2981 0.5633 0.7927 0.046 Uiso 1 1 calc R
C33 C 0.4064(2) 0.48265(18) 0.71725(16) 0.0372(6) Uani 1 1 d .
C34 C 0.4723(3) 0.4869(2) 0.64011(18) 0.0482(7) Uani 1 1 d .
H34 H 0.5150 0.4337 0.6211 0.058 Uiso 1 1 calc R
C35 C 0.4754(3) 0.5679(2) 0.59167(18) 0.0523(8) Uani 1 1 d .
H35 H 0.5214 0.5687 0.5412 0.063 Uiso 1 1 calc R
C36 C 0.4044(2) 0.39446(18) 0.76901(17) 0.0371(6) Uani 1 1 d .
C37 C 0.3996(2) 0.38432(17) 0.86146(17) 0.0342(6) Uani 1 1 d .
C38 C 0.3928(2) 0.30050(19) 0.9056(2) 0.0446(7) Uani 1 1 d .
H38 H 0.3855 0.2949 0.9668 0.054 Uiso 1 1 calc R
C39 C 0.3966(3) 0.2253(2) 0.8602(2) 0.0559(8) Uani 1 1 d .
H39 H 0.3945 0.1692 0.8906 0.067 Uiso 1 1 calc R
C40 C 0.4035(3) 0.2341(2) 0.7695(2) 0.0594(9) Uani 1 1 d .
H40 H 0.4069 0.1838 0.7385 0.071 Uiso 1 1 calc R
C41 C 0.4055(3) 0.3176(2) 0.7248(2) 0.0519(8) Uani 1 1 d .
H41 H 0.4076 0.3230 0.6636 0.062 Uiso 1 1 calc R
C42 C 0.4112(2) 0.45880(16) 0.91601(16) 0.0318(5) Uani 1 1 d .
C43 C 0.9157(2) 0.3619(2) 0.9676(2) 0.0512(7) Uani 1 1 d .
H43 H 0.8879 0.3158 1.0007 0.061 Uiso 1 1 calc R
C44 C 1.0305(3) 0.3600(2) 0.9680(2) 0.0629(9) Uani 1 1 d .
H44 H 1.0776 0.3139 1.0008 0.075 Uiso 1 1 calc R
C45 C 1.0720(3) 0.4269(3) 0.9194(2) 0.0636(10) Uani 1 1 d .
H45 H 1.1482 0.4267 0.9186 0.076 Uiso 1 1 calc R
C46 C 1.0003(2) 0.4961(2) 0.8706(2) 0.0495(8) Uani 1 1 d .
C47 C 1.0353(3) 0.5696(3) 0.8184(2) 0.0670(10) Uani 1 1 d .
H47 H 1.1109 0.5717 0.8146 0.080 Uiso 1 1 calc R
C48 C 0.9634(3) 0.6354(3) 0.7749(2) 0.0656(10) Uani 1 1 d .
H48 H 0.9896 0.6826 0.7423 0.079 Uiso 1 1 calc R
C49 C 0.8467(3) 0.6346(2) 0.77756(19) 0.0466(7) Uani 1 1 d .
C50 C 0.7667(3) 0.7004(2) 0.7321(2) 0.0571(9) Uani 1 1 d .
H50 H 0.7883 0.7488 0.6980 0.069 Uiso 1 1 calc R
C51 C 0.6579(3) 0.6932(2) 0.7378(2) 0.0576(8) Uani 1 1 d .
H51 H 0.6043 0.7366 0.7079 0.069 Uiso 1 1 calc R
C52 C 0.6269(2) 0.6202(2) 0.78892(19) 0.0470(7) Uani 1 1 d .
H52 H 0.5521 0.6155 0.7915 0.056 Uiso 1 1 calc R
C53 C 0.8089(2) 0.56321(18) 0.82812(16) 0.0356(6) Uani 1 1 d .
C54 C 0.8865(2) 0.49277(18) 0.87509(17) 0.0369(6) Uani 1 1 d .
C55 C 0.7030(3) 0.3733(2) 0.7314(2) 0.0574(8) Uani 1 1 d .
H55 H 0.7060 0.4327 0.7104 0.069 Uiso 1 1 calc R
C56 C 0.7157(3) 0.3081(3) 0.6712(3) 0.0738(11) Uani 1 1 d .
H56 H 0.7264 0.3243 0.6114 0.089 Uiso 1 1 calc R
C57 C 0.7125(3) 0.2210(3) 0.7005(3) 0.0803(12) Uani 1 1 d .
H57 H 0.7214 0.1771 0.6610 0.096 Uiso 1 1 calc R
C58 C 0.6959(3) 0.1975(2) 0.7902(3) 0.0693(10) Uani 1 1 d .
C59 C 0.6904(4) 0.1077(3) 0.8287(4) 0.0971(15) Uani 1 1 d .
H59 H 0.7026 0.0603 0.7928 0.116 Uiso 1 1 calc R
C60 C 0.6684(4) 0.0906(3) 0.9146(4) 0.0954(15) Uani 1 1 d .
H60 H 0.6627 0.0320 0.9366 0.114 Uiso 1 1 calc R
C61 C 0.6533(3) 0.1596(2) 0.9732(3) 0.0653(10) Uani 1 1 d .
C62 C 0.6274(3) 0.1463(2) 1.0636(3) 0.0773(12) Uani 1 1 d .
H62 H 0.6196 0.0893 1.0889 0.093 Uiso 1 1 calc R
C63 C 0.6140(3) 0.2165(2) 1.1140(3) 0.0682(10) Uani 1 1 d .
H63 H 0.5976 0.2080 1.1740 0.082 Uiso 1 1 calc R
C64 C 0.6249(3) 0.3016(2) 1.0749(2) 0.0531(8) Uani 1 1 d .
H64 H 0.6151 0.3492 1.1104 0.064 Uiso 1 1 calc R
C65 C 0.6619(2) 0.24787(18) 0.9390(2) 0.0480(7) Uani 1 1 d .
C66 C 0.6827(2) 0.2669(2) 0.8467(2) 0.0487(7) Uani 1 1 d .
O1 O 1.06999(18) 0.24242(17) 0.44938(15) 0.0663(6) Uani 1 1 d .
O2 O 0.89662(18) 0.24567(15) 0.40823(14) 0.0597(6) Uani 1 1 d .
H2 H 0.9272 0.2003 0.3847 0.090 Uiso 1 1 calc R
O1W O 1.1996(4) 0.0659(3) 1.3574(3) 0.1647(17) Uani 1 1 d .
O3 O 1.19903(18) 0.10528(15) 0.90944(13) 0.0597(6) Uani 1 1 d .
O2W O 1.1669(7) -0.0736(5) 1.4736(4) 0.296(5) Uani 1 1 d .
O4 O 0.83235(19) 0.14576(16) 1.22270(14) 0.0622(6) Uani 1 1 d .
O3W O 0.3803(5) 1.0898(4) 0.2114(5) 0.219(3) Uani 1 1 d .
O5 O 0.98896(19) 0.13945(16) 1.29263(13) 0.0609(6) Uani 1 1 d .
O6 O 0.75288(18) 1.04421(14) 0.34454(14) 0.0584(6) Uani 1 1 d .
H6A H 0.7653 1.0895 0.3148 0.088 Uiso 1 1 calc R
O7 O 0.5823(2) 1.09553(17) 0.29479(17) 0.0761(7) Uani 1 1 d .
O8 O 0.52639(19) 0.73820(15) 0.53631(16) 0.0662(6) Uani 1 1 d .
O9 O 0.49682(13) 0.49247(11) 0.90392(11) 0.0348(4) Uani 1 1 d .
O10 O 0.33329(14) 0.48235(12) 0.97140(12) 0.0399(4) Uani 1 1 d .
N1 N 0.84474(17) 0.42568(14) 0.92291(14) 0.0377(5) Uani 1 1 d .
N2 N 0.68657(18) 0.35417(16) 0.81731(16) 0.0446(6) Uani 1 1 d .
N3 N 0.69954(17) 0.55694(15) 0.83414(14) 0.0372(5) Uani 1 1 d .
N4 N 0.64843(18) 0.31821(15) 0.98993(15) 0.0418(5) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O9 Co1 O9 0.00(3) 1 .
O9 Co1 O10 92.29(7) 1 2_667
O9 Co1 O10 92.29(7) . 2_667
O9 Co1 N3 89.65(7) 1 .
O9 Co1 N3 89.65(7) . .
O10 Co1 N3 89.99(8) 2_667 .
O9 Co1 N4 95.69(8) 1 .
O9 Co1 N4 95.69(8) . .
O10 Co1 N4 97.73(8) 2_667 .
N3 Co1 N4 170.40(8) . .
O9 Co1 N2 96.06(8) 1 .
O9 Co1 N2 96.06(8) . .
O10 Co1 N2 170.57(8) 2_667 .
N3 Co1 N2 94.43(9) . .
N4 Co1 N2 77.12(9) . .
O9 Co1 N1 166.58(8) 1 .
O9 Co1 N1 166.58(8) . .
O10 Co1 N1 84.24(7) 2_667 .
N3 Co1 N1 77.41(8) . .
N4 Co1 N1 97.62(8) . .
N2 Co1 N1 88.59(8) . .
O1 C1 O2 124.0(3) . .
O1 C1 C2 123.3(3) . .
O2 C1 C2 112.6(3) . .
C3 C2 C7 119.9(3) . .
C3 C2 C1 117.1(3) . .
C7 C2 C1 122.9(3) . .
C4 C3 C2 121.5(3) . .
C4 C3 H3 119.3 . .
C2 C3 H3 119.3 . .
C5 C4 C3 118.9(3) . .
C5 C4 H4 120.5 . .
C3 C4 H4 120.5 . .
C4 C5 C6 120.3(3) . .
C4 C5 H5 119.8 . .
C6 C5 H5 119.8 . .
C5 C6 C7 121.7(3) . .
C5 C6 H6 119.1 . .
C7 C6 H6 119.1 . .
C6 C7 C2 117.6(3) . .
C6 C7 C8 119.1(3) . .
C2 C7 C8 123.1(3) . .
C9 C8 C13 117.2(3) . .
C9 C8 C7 120.8(3) . .
C13 C8 C7 121.7(3) . .
C10 C9 C8 121.2(3) . .
C10 C9 H9 119.4 . .
C8 C9 H9 119.4 . .
C11 C10 C9 121.1(3) . .
C11 C10 H10 119.4 . .
C9 C10 H10 119.4 . .
C10 C11 C12 118.2(3) . .
C10 C11 C14 122.4(3) . .
C12 C11 C14 119.2(3) . .
C13 C12 C11 121.0(3) . .
C13 C12 H12 119.5 . .
C11 C12 H12 119.5 . .
C12 C13 C8 121.2(3) . .
C12 C13 H13 119.4 . .
C8 C13 H13 119.4 . .
O3 C14 C11 114.3(3) . .
O3 C14 H14A 108.7 . .
C11 C14 H14A 108.7 . .
O3 C14 H14B 108.7 . .
C11 C14 H14B 108.7 . .
H14A C14 H14B 107.6 . .
O3 C15 C16 125.3(3) . .
O3 C15 C20 114.6(3) . .
C16 C15 C20 120.1(3) . .
C15 C16 C17 119.2(3) . .
C15 C16 H16 120.4 . .
C17 C16 H16 120.4 . .
C18 C17 C16 121.3(3) . .
C18 C17 H17 119.3 . .
C16 C17 H17 119.3 . .
C17 C18 C19 118.2(2) . .
C17 C18 C21 121.2(3) . .
C19 C18 C21 120.7(3) . .
C20 C19 C18 120.9(3) . .
C20 C19 H19 119.5 . .
C18 C19 H19 119.5 . .
C19 C20 C15 120.2(3) . .
C19 C20 H20 119.9 . .
C15 C20 H20 119.9 . .
O4 C21 O5 124.5(3) . .
O4 C21 C18 118.3(3) . .
O5 C21 C18 117.2(3) . .
O7 C22 O6 122.6(3) . .
O7 C22 C23 123.5(3) . .
O6 C22 C23 113.9(3) . .
C28 C23 C24 118.7(3) . .
C28 C23 C22 122.3(3) . .
C24 C23 C22 119.0(3) . .
C25 C24 C23 121.4(3) . .
C25 C24 H24 119.3 . .
C23 C24 H24 119.3 . .
C24 C25 C26 118.9(3) . .
C24 C25 H25 120.5 . .
C26 C25 H25 120.5 . .
O8 C26 C27 115.3(3) . .
O8 C26 C25 124.3(3) . .
C27 C26 C25 120.4(3) . .
C26 C27 C28 120.0(3) . .
C26 C27 H27 120.0 . .
C28 C27 H27 120.0 . .
C27 C28 C23 120.5(3) . .
C27 C28 H28 119.8 . .
C23 C28 H28 119.8 . .
O8 C29 C30 107.4(2) . .
O8 C29 H29A 110.2 . .
C30 C29 H29A 110.2 . .
O8 C29 H29B 110.2 . .
C30 C29 H29B 110.2 . .
H29A C29 H29B 108.5 . .
C31 C30 C35 118.2(3) . .
C31 C30 C29 121.0(3) . .
C35 C30 C29 120.8(2) . .
C30 C31 C32 120.4(3) . .
C30 C31 H31 119.8 . .
C32 C31 H31 119.8 . .
C33 C32 C31 121.9(2) . .
C33 C32 H32 119.1 . .
C31 C32 H32 119.1 . .
C32 C33 C34 116.9(2) . .
C32 C33 C36 122.5(2) . .
C34 C33 C36 120.6(2) . .
C35 C34 C33 121.3(3) . .
C35 C34 H34 119.3 . .
C33 C34 H34 119.3 . .
C34 C35 C30 121.3(3) . .
C34 C35 H35 119.4 . .
C30 C35 H35 119.4 . .
C41 C36 C37 117.7(2) . .
C41 C36 C33 119.4(2) . .
C37 C36 C33 122.8(2) . .
C38 C37 C36 119.7(2) . .
C38 C37 C42 117.5(2) . .
C36 C37 C42 122.5(2) . .
C39 C38 C37 121.1(3) . .
C39 C38 H38 119.4 . .
C37 C38 H38 119.4 . .
C40 C39 C38 119.6(3) . .
C40 C39 H39 120.2 . .
C38 C39 H39 120.2 . .
C39 C40 C41 119.9(3) . .
C39 C40 H40 120.0 . .
C41 C40 H40 120.0 . .
C40 C41 C36 121.9(3) . .
C40 C41 H41 119.1 . .
C36 C41 H41 119.1 . .
O9 C42 O9 0.0(2) 1 .
O9 C42 O10 124.8(2) 1 .
O9 C42 O10 124.8(2) . .
O9 C42 C37 118.3(2) 1 .
O9 C42 C37 118.3(2) . .
O10 C42 C37 116.9(2) . .
N1 C43 C44 123.4(3) . .
N1 C43 H43 118.3 . .
C44 C43 H43 118.3 . .
C45 C44 C43 118.7(3) . .
C45 C44 H44 120.6 . .
C43 C44 H44 120.6 . .
C44 C45 C46 120.2(3) . .
C44 C45 H45 119.9 . .
C46 C45 H45 119.9 . .
C45 C46 C54 117.0(3) . .
C45 C46 C47 124.4(3) . .
C54 C46 C47 118.6(3) . .
C48 C47 C46 122.3(3) . .
C48 C47 H47 118.9 . .
C46 C47 H47 118.9 . .
C47 C48 C49 121.0(3) . .
C47 C48 H48 119.5 . .
C49 C48 H48 119.5 . .
C50 C49 C53 117.4(3) . .
C50 C49 C48 124.2(3) . .
C53 C49 C48 118.4(3) . .
C51 C50 C49 119.8(3) . .
C51 C50 H50 120.1 . .
C49 C50 H50 120.1 . .
C50 C51 C52 119.5(3) . .
C50 C51 H51 120.3 . .
C52 C51 H51 120.3 . .
N3 C52 C51 122.8(3) . .
N3 C52 H52 118.6 . .
C51 C52 H52 118.6 . .
N3 C53 C49 122.4(3) . .
N3 C53 C54 117.3(2) . .
C49 C53 C54 120.3(2) . .
N1 C54 C46 123.1(3) . .
N1 C54 C53 117.5(2) . .
C46 C54 C53 119.4(3) . .
N2 C55 C56 122.8(3) . .
N2 C55 H55 118.6 . .
C56 C55 H55 118.6 . .
C57 C56 C55 119.5(4) . .
C57 C56 H56 120.2 . .
C55 C56 H56 120.2 . .
C56 C57 C58 119.8(3) . .
C56 C57 H57 120.1 . .
C58 C57 H57 120.1 . .
C57 C58 C66 117.5(4) . .
C57 C58 C59 124.6(4) . .
C66 C58 C59 117.9(4) . .
C60 C59 C58 121.7(4) . .
C60 C59 H59 119.2 . .
C58 C59 H59 119.2 . .
C59 C60 C61 121.7(4) . .
C59 C60 H60 119.2 . .
C61 C60 H60 119.2 . .
C62 C61 C65 117.1(3) . .
C62 C61 C60 124.3(4) . .
C65 C61 C60 118.6(4) . .
C63 C62 C61 119.9(3) . .
C63 C62 H62 120.0 . .
C61 C62 H62 120.0 . .
C62 C63 C64 119.3(4) . .
C62 C63 H63 120.3 . .
C64 C63 H63 120.3 . .
N4 C64 C63 123.4(3) . .
N4 C64 H64 118.3 . .
C63 C64 H64 118.3 . .
N4 C65 C61 122.8(3) . .
N4 C65 C66 117.4(2) . .
C61 C65 C66 119.9(3) . .
N2 C66 C58 122.8(3) . .
N2 C66 C65 117.0(2) . .
C58 C66 C65 120.2(3) . .
C1 O2 H2 109.5 . .
C15 O3 C14 119.1(3) . .
C22 O6 H6A 109.5 . .
C26 O8 C29 118.5(2) . .
O9 O9 C42 0(10) 1 .
O9 O9 Co1 0(7) 1 .
C42 O9 Co1 134.95(16) . .
C42 O10 Co1 128.59(16) . 2_667
C43 N1 C54 117.6(2) . .
C43 N1 Co1 129.0(2) . .
C54 N1 Co1 113.36(17) . .
C55 N2 C66 117.7(3) . .
C55 N2 Co1 128.2(2) . .
C66 N2 Co1 114.13(19) . .
C52 N3 C53 118.1(2) . .
C52 N3 Co1 127.57(18) . .
C53 N3 Co1 114.32(18) . .
C64 N4 C65 117.5(2) . .
C64 N4 Co1 128.1(2) . .
C65 N4 Co1 114.34(19) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Co1 O9 2.0569(17) 1
Co1 O9 2.0569(17) .
Co1 O10 2.0957(18) 2_667
Co1 N3 2.134(2) .
Co1 N4 2.138(2) .
Co1 N2 2.150(2) .
Co1 N1 2.158(2) .
C1 O1 1.211(3) .
C1 O2 1.317(3) .
C1 C2 1.492(4) .
C2 C3 1.390(4) .
C2 C7 1.403(4) .
C3 C4 1.377(5) .
C3 H3 0.9300 .
C4 C5 1.375(5) .
C4 H4 0.9300 .
C5 C6 1.384(5) .
C5 H5 0.9300 .
C6 C7 1.390(4) .
C6 H6 0.9300 .
C7 C8 1.484(4) .
C8 C9 1.392(4) .
C8 C13 1.394(4) .
C9 C10 1.388(4) .
C9 H9 0.9300 .
C10 C11 1.377(4) .
C10 H10 0.9300 .
C11 C12 1.386(4) .
C11 C14 1.500(4) .
C12 C13 1.384(4) .
C12 H12 0.9300 .
C13 H13 0.9300 .
C14 O3 1.434(4) .
C14 H14A 0.9700 .
C14 H14B 0.9700 .
C15 O3 1.369(3) .
C15 C16 1.377(4) .
C15 C20 1.386(4) .
C16 C17 1.395(4) .
C16 H16 0.9300 .
C17 C18 1.384(4) .
C17 H17 0.9300 .
C18 C19 1.395(4) .
C18 C21 1.504(4) .
C19 C20 1.374(4) .
C19 H19 0.9300 .
C20 H20 0.9300 .
C21 O4 1.251(4) .
C21 O5 1.259(4) .
C22 O7 1.208(4) .
C22 O6 1.319(4) .
C22 C23 1.481(4) .
C23 C28 1.382(4) .
C23 C24 1.388(4) .
C24 C25 1.381(4) .
C24 H24 0.9300 .
C25 C26 1.382(4) .
C25 H25 0.9300 .
C26 O8 1.369(3) .
C26 C27 1.381(4) .
C27 C28 1.380(4) .
C27 H27 0.9300 .
C28 H28 0.9300 .
C29 O8 1.428(4) .
C29 C30 1.501(4) .
C29 H29A 0.9700 .
C29 H29B 0.9700 .
C30 C31 1.383(4) .
C30 C35 1.384(4) .
C31 C32 1.385(4) .
C31 H31 0.9300 .
C32 C33 1.387(4) .
C32 H32 0.9300 .
C33 C34 1.396(4) .
C33 C36 1.484(4) .
C34 C35 1.373(4) .
C34 H34 0.9300 .
C35 H35 0.9300 .
C36 C41 1.402(4) .
C36 C37 1.404(4) .
C37 C38 1.391(4) .
C37 C42 1.502(3) .
C38 C39 1.385(4) .
C38 H38 0.9300 .
C39 C40 1.376(5) .
C39 H39 0.9300 .
C40 C41 1.377(4) .
C40 H40 0.9300 .
C41 H41 0.9300 .
C42 O9 1.252(3) 1
C42 O9 1.252(3) .
C42 O10 1.261(3) .
C43 N1 1.318(4) .
C43 C44 1.399(4) .
C43 H43 0.9300 .
C44 C45 1.360(5) .
C44 H44 0.9300 .
C45 C46 1.398(5) .
C45 H45 0.9300 .
C46 C54 1.401(4) .
C46 C47 1.426(5) .
C47 C48 1.332(5) .
C47 H47 0.9300 .
C48 C49 1.428(4) .
C48 H48 0.9300 .
C49 C50 1.401(5) .
C49 C53 1.405(4) .
C50 C51 1.354(5) .
C50 H50 0.9300 .
C51 C52 1.392(4) .
C51 H51 0.9300 .
C52 N3 1.328(4) .
C52 H52 0.9300 .
C53 N3 1.357(3) .
C53 C54 1.434(4) .
C54 N1 1.359(3) .
C55 N2 1.328(4) .
C55 C56 1.397(5) .
C55 H55 0.9300 .
C56 C57 1.357(6) .
C56 H56 0.9300 .
C57 C58 1.394(6) .
C57 H57 0.9300 .
C58 C66 1.406(4) .
C58 C59 1.438(6) .
C59 C60 1.335(7) .
C59 H59 0.9300 .
C60 C61 1.423(6) .
C60 H60 0.9300 .
C61 C62 1.403(6) .
C61 C65 1.407(4) .
C62 C63 1.354(5) .
C62 H62 0.9300 .
C63 C64 1.391(4) .
C63 H63 0.9300 .
C64 N4 1.325(4) .
C64 H64 0.9300 .
C65 N4 1.360(4) .
C65 C66 1.430(4) .
C66 N2 1.361(4) .
O2 H2 0.8200 .
O6 H6A 0.8200 .
O9 O9 0.000(3) 1
O10 Co1 2.0957(17) 2_667
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
O2 H2 O5 0.82 1.81 2.571(3) 154.3 1_554
O6 H6A O4 0.82 1.81 2.570(3) 152.5 1_564
C52 H52 O9 0.93 2.57 3.101(3) 116.6 1
C63 H63 O7 0.93 2.41 3.205(4) 144.0 1_546
C64 H64 O9 0.93 2.50 3.211(4) 133.3 2_667
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C1 C2 C3 127.3(3) . .
O2 C1 C2 C3 -48.3(4) . .
O1 C1 C2 C7 -47.6(4) . .
O2 C1 C2 C7 136.8(3) . .
C7 C2 C3 C4 3.5(5) . .
C1 C2 C3 C4 -171.6(3) . .
C2 C3 C4 C5 -0.6(5) . .
C3 C4 C5 C6 -2.1(5) . .
C4 C5 C6 C7 1.9(5) . .
C5 C6 C7 C2 1.0(4) . .
C5 C6 C7 C8 -173.7(3) . .
C3 C2 C7 C6 -3.6(4) . .
C1 C2 C7 C6 171.2(3) . .
C3 C2 C7 C8 170.9(3) . .
C1 C2 C7 C8 -14.3(4) . .
C6 C7 C8 C9 -35.9(4) . .
C2 C7 C8 C9 149.7(3) . .
C6 C7 C8 C13 138.3(3) . .
C2 C7 C8 C13 -36.1(4) . .
C13 C8 C9 C10 0.7(4) . .
C7 C8 C9 C10 175.1(3) . .
C8 C9 C10 C11 -0.3(5) . .
C9 C10 C11 C12 -0.4(4) . .
C9 C10 C11 C14 174.5(3) . .
C10 C11 C12 C13 0.6(4) . .
C14 C11 C12 C13 -174.4(3) . .
C11 C12 C13 C8 -0.2(4) . .
C9 C8 C13 C12 -0.5(4) . .
C7 C8 C13 C12 -174.8(3) . .
C10 C11 C14 O3 24.7(4) . .
C12 C11 C14 O3 -160.5(3) . .
O3 C15 C16 C17 176.9(3) . .
C20 C15 C16 C17 -2.8(4) . .
C15 C16 C17 C18 0.0(4) . .
C16 C17 C18 C19 2.1(4) . .
C16 C17 C18 C21 -176.6(3) . .
C17 C18 C19 C20 -1.4(4) . .
C21 C18 C19 C20 177.3(3) . .
C18 C19 C20 C15 -1.3(4) . .
O3 C15 C20 C19 -176.3(3) . .
C16 C15 C20 C19 3.5(4) . .
C17 C18 C21 O4 -7.6(4) . .
C19 C18 C21 O4 173.7(3) . .
C17 C18 C21 O5 171.6(3) . .
C19 C18 C21 O5 -7.1(4) . .
O7 C22 C23 C28 169.3(3) . .
O6 C22 C23 C28 -11.8(4) . .
O7 C22 C23 C24 -11.3(4) . .
O6 C22 C23 C24 167.6(2) . .
C28 C23 C24 C25 0.4(4) . .
C22 C23 C24 C25 -179.0(3) . .
C23 C24 C25 C26 -0.3(4) . .
C24 C25 C26 O8 180.0(3) . .
C24 C25 C26 C27 -0.4(5) . .
O8 C26 C27 C28 -179.2(3) . .
C25 C26 C27 C28 1.0(5) . .
C26 C27 C28 C23 -1.0(5) . .
C24 C23 C28 C27 0.3(5) . .
C22 C23 C28 C27 179.7(3) . .
O8 C29 C30 C31 137.3(3) . .
O8 C29 C30 C35 -44.1(4) . .
C35 C30 C31 C32 0.4(4) . .
C29 C30 C31 C32 179.0(3) . .
C30 C31 C32 C33 -0.7(4) . .
C31 C32 C33 C34 0.0(4) . .
C31 C32 C33 C36 -179.2(2) . .
C32 C33 C34 C35 1.1(4) . .
C36 C33 C34 C35 -179.7(3) . .
C33 C34 C35 C30 -1.4(5) . .
C31 C30 C35 C34 0.6(4) . .
C29 C30 C35 C34 -178.0(3) . .
C32 C33 C36 C41 139.9(3) . .
C34 C33 C36 C41 -39.2(4) . .
C32 C33 C36 C37 -38.9(4) . .
C34 C33 C36 C37 141.9(3) . .
C41 C36 C37 C38 -1.9(4) . .
C33 C36 C37 C38 177.0(2) . .
C41 C36 C37 C42 172.8(2) . .
C33 C36 C37 C42 -8.3(4) . .
C36 C37 C38 C39 3.4(4) . .
C42 C37 C38 C39 -171.5(3) . .
C37 C38 C39 C40 -2.2(5) . .
C38 C39 C40 C41 -0.6(5) . .
C39 C40 C41 C36 2.2(5) . .
C37 C36 C41 C40 -0.9(4) . .
C33 C36 C41 C40 -179.9(3) . .
C38 C37 C42 O9 119.0(3) . 1
C36 C37 C42 O9 -55.8(3) . 1
C38 C37 C42 O9 119.0(3) . .
C36 C37 C42 O9 -55.8(3) . .
C38 C37 C42 O10 -60.6(3) . .
C36 C37 C42 O10 124.6(3) . .
N1 C43 C44 C45 -0.4(5) . .
C43 C44 C45 C46 0.3(5) . .
C44 C45 C46 C54 0.4(4) . .
C44 C45 C46 C47 179.3(3) . .
C45 C46 C47 C48 -178.1(3) . .
C54 C46 C47 C48 0.8(5) . .
C46 C47 C48 C49 -0.9(5) . .
C47 C48 C49 C50 -178.6(3) . .
C47 C48 C49 C53 0.8(5) . .
C53 C49 C50 C51 -0.2(4) . .
C48 C49 C50 C51 179.2(3) . .
C49 C50 C51 C52 -0.2(5) . .
C50 C51 C52 N3 1.1(5) . .
C50 C49 C53 N3 -0.4(4) . .
C48 C49 C53 N3 -179.8(2) . .
C50 C49 C53 C54 178.9(2) . .
C48 C49 C53 C54 -0.5(4) . .
C45 C46 C54 N1 -1.0(4) . .
C47 C46 C54 N1 -180.0(3) . .
C45 C46 C54 C53 178.5(2) . .
C47 C46 C54 C53 -0.6(4) . .
N3 C53 C54 N1 -0.8(3) . .
C49 C53 C54 N1 179.9(2) . .
N3 C53 C54 C46 179.8(2) . .
C49 C53 C54 C46 0.4(4) . .
N2 C55 C56 C57 -0.6(5) . .
C55 C56 C57 C58 0.4(5) . .
C56 C57 C58 C66 0.2(5) . .
C56 C57 C58 C59 179.7(4) . .
C57 C58 C59 C60 -176.4(4) . .
C66 C58 C59 C60 3.1(6) . .
C58 C59 C60 C61 -2.4(7) . .
C59 C60 C61 C62 178.5(4) . .
C59 C60 C61 C65 0.1(6) . .
C65 C61 C62 C63 -1.2(5) . .
C60 C61 C62 C63 -179.6(4) . .
C61 C62 C63 C64 0.7(5) . .
C62 C63 C64 N4 -0.2(5) . .
C62 C61 C65 N4 1.3(5) . .
C60 C61 C65 N4 179.8(3) . .
C62 C61 C65 C66 -177.0(3) . .
C60 C61 C65 C66 1.5(5) . .
C57 C58 C66 N2 -0.6(5) . .
C59 C58 C66 N2 179.9(3) . .
C57 C58 C66 C65 178.1(3) . .
C59 C58 C66 C65 -1.4(5) . .
N4 C65 C66 N2 -0.4(4) . .
C61 C65 C66 N2 178.0(3) . .
N4 C65 C66 C58 -179.2(3) . .
C61 C65 C66 C58 -0.8(4) . .
C16 C15 O3 C14 -7.8(4) . .
C20 C15 O3 C14 172.0(3) . .
C11 C14 O3 C15 86.0(3) . .
C27 C26 O8 C29 172.2(3) . .
C25 C26 O8 C29 -8.1(5) . .
C30 C29 O8 C26 -178.5(3) . .
O10 C42 O9 O9 0.00(10) . 1
C37 C42 O9 O9 0.00(4) . 1
O9 C42 O9 Co1 0(100) 1 .
O10 C42 O9 Co1 115.9(3) . .
C37 C42 O9 Co1 -63.6(3) . .
O10 Co1 O9 O9 0.00(10) 2_667 1
N3 Co1 O9 O9 0.00(10) . 1
N4 Co1 O9 O9 0.00(10) . 1
N2 Co1 O9 O9 0.00(10) . 1
N1 Co1 O9 O9 0.0(3) . 1
O9 Co1 O9 C42 0.0(13) 1 .
O10 Co1 O9 C42 -108.8(2) 2_667 .
N3 Co1 O9 C42 161.3(2) . .
N4 Co1 O9 C42 -10.8(2) . .
N2 Co1 O9 C42 66.8(2) . .
N1 Co1 O9 C42 176.6(3) . .
O9 C42 O10 Co1 -17.5(4) 1 2_667
O9 C42 O10 Co1 -17.5(4) . 2_667
C37 C42 O10 Co1 162.09(16) . 2_667
C44 C43 N1 C54 -0.2(4) . .
C44 C43 N1 Co1 -176.3(2) . .
C46 C54 N1 C43 0.8(4) . .
C53 C54 N1 C43 -178.6(2) . .
C46 C54 N1 Co1 177.6(2) . .
C53 C54 N1 Co1 -1.8(3) . .
O9 Co1 N1 C43 163.1(3) 1 .
O9 Co1 N1 C43 163.1(3) . .
O10 Co1 N1 C43 87.6(2) 2_667 .
N3 Co1 N1 C43 178.8(2) . .
N4 Co1 N1 C43 -9.5(2) . .
N2 Co1 N1 C43 -86.3(2) . .
O9 Co1 N1 C54 -13.2(4) 1 .
O9 Co1 N1 C54 -13.2(4) . .
O10 Co1 N1 C54 -88.74(17) 2_667 .
N3 Co1 N1 C54 2.54(16) . .
N4 Co1 N1 C54 174.20(17) . .
N2 Co1 N1 C54 97.40(17) . .
C56 C55 N2 C66 0.2(4) . .
C56 C55 N2 Co1 180.0(2) . .
C58 C66 N2 C55 0.4(4) . .
C65 C66 N2 C55 -178.3(3) . .
C58 C66 N2 Co1 -179.4(2) . .
C65 C66 N2 Co1 1.9(3) . .
O9 Co1 N2 C55 83.8(2) 1 .
O9 Co1 N2 C55 83.8(2) . .
O10 Co1 N2 C55 -124.0(5) 2_667 .
N3 Co1 N2 C55 -6.3(3) . .
N4 Co1 N2 C55 178.3(3) . .
N1 Co1 N2 C55 -83.6(2) . .
O9 Co1 N2 C66 -96.37(19) 1 .
O9 Co1 N2 C66 -96.37(19) . .
O10 Co1 N2 C66 55.8(5) 2_667 .
N3 Co1 N2 C66 173.51(19) . .
N4 Co1 N2 C66 -1.90(18) . .
N1 Co1 N2 C66 96.25(19) . .
C51 C52 N3 C53 -1.7(4) . .
C51 C52 N3 Co1 177.2(2) . .
C49 C53 N3 C52 1.3(4) . .
C54 C53 N3 C52 -178.0(2) . .
C49 C53 N3 Co1 -177.67(19) . .
C54 C53 N3 Co1 3.0(3) . .
O9 Co1 N3 C52 -5.4(2) 1 .
O9 Co1 N3 C52 -5.4(2) . .
O10 Co1 N3 C52 -97.7(2) 2_667 .
N4 Co1 N3 C52 118.6(5) . .
N2 Co1 N3 C52 90.6(2) . .
N1 Co1 N3 C52 178.2(2) . .
O9 Co1 N3 C53 173.42(17) 1 .
O9 Co1 N3 C53 173.42(17) . .
O10 Co1 N3 C53 81.13(17) 2_667 .
N4 Co1 N3 C53 -62.6(6) . .
N2 Co1 N3 C53 -90.53(17) . .
N1 Co1 N3 C53 -2.97(16) . .
C63 C64 N4 C65 0.3(4) . .
C63 C64 N4 Co1 178.9(2) . .
C61 C65 N4 C64 -0.9(4) . .
C66 C65 N4 C64 177.5(3) . .
C61 C65 N4 Co1 -179.6(2) . .
C66 C65 N4 Co1 -1.3(3) . .
O9 Co1 N4 C64 -82.0(2) 1 .
O9 Co1 N4 C64 -82.0(2) . .
O10 Co1 N4 C64 11.1(3) 2_667 .
N3 Co1 N4 C64 154.5(5) . .
N2 Co1 N4 C64 -176.9(3) . .
N1 Co1 N4 C64 96.3(2) . .
O9 Co1 N4 C65 96.63(19) 1 .
O9 Co1 N4 C65 96.63(19) . .
O10 Co1 N4 C65 -170.27(18) 2_667 .
N3 Co1 N4 C65 -26.9(6) . .
N2 Co1 N4 C65 1.69(18) . .
N1 Co1 N4 C65 -85.09(19) . .
