#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:53:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179602 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/66/4506667.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4506667
loop_
_publ_author_name
'Gotthardt, Jan M.'
'White, Keith F.'
'Abrahams, Brendan F.'
'Ritchie, Chris'
'Boskovic, Colette'
_publ_section_title
;
 Fluorite Topology in Lanthanoid Coordination Polymers with Di- and
 Trimetallic Building Blocks
;
_journal_issue                   9
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              4425
_journal_paper_doi               10.1021/cg3006103
_journal_volume                  12
_journal_year                    2012
_chemical_formula_sum            'C70 H66 Eu3 N6 O25 Si2'
_chemical_formula_weight         1903.35
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                118.055(5)
_cell_angle_beta                 105.125(5)
_cell_angle_gamma                96.417(5)
_cell_formula_units_Z            1
_cell_length_a                   11.919(5)
_cell_length_b                   14.010(5)
_cell_length_c                   14.792(5)
_cell_measurement_reflns_used    5198
_cell_measurement_temperature    130(2)
_cell_measurement_theta_max      62.9890
_cell_measurement_theta_min      3.5933
_cell_volume                     2023.0(13)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      130(2)
_diffrn_detector_area_resol_mean 10.2273
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'SuperNova, dual, Cu at zero, Atlas'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0374
_diffrn_reflns_av_sigmaI/netI    0.0523
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            11740
_diffrn_reflns_theta_full        24.27
_diffrn_reflns_theta_max         24.27
_diffrn_reflns_theta_min         1.66
_exptl_absorpt_coefficient_mu    2.402
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.52063
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.35.11 (release 16-05-2011 CrysAlis171 .NET)
(compiled May 16 2011,17:55:39)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.562
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Rod
_exptl_crystal_F_000             945
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.049
_refine_diff_density_min         -0.818
_refine_diff_density_rms         0.175
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.269
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     493
_refine_ls_number_reflns         6393
_refine_ls_number_restraints     10
_refine_ls_restrained_S_all      1.274
_refine_ls_R_factor_all          0.0822
_refine_ls_R_factor_gt           0.0641
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0642P)²+30.1670P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2104
_refine_ls_wR_factor_ref         0.2180
_reflns_number_gt                5408
_reflns_number_total             6393
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg3006103_si_002.cif
_cod_data_source_block           jgo1_24eub
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4506667
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
O13 O 0.861(4) 0.302(3) 0.240(4) 0.079(13) Uiso 0.25 1 d PD A 1
N4 N 0.739(4) 0.127(4) 0.111(4) 0.065(14) Uiso 0.25 1 d PD A 1
C38 C 0.760(5) 0.229(4) 0.179(4) 0.044(12) Uiso 0.25 1 d P A 1
H38 H 0.6929 0.2556 0.1864 0.053 Uiso 0.35 1 calc PR A 1
C37 C 0.620(5) 0.054(5) 0.047(5) 0.055(14) Uiso 0.25 1 d P A 1
H37A H 0.6234 -0.0211 0.0015 0.083 Uiso 0.35 1 calc PR A 1
H37B H 0.5771 0.0794 0.0018 0.083 Uiso 0.35 1 calc PR A 1
H37C H 0.5777 0.0542 0.0945 0.083 Uiso 0.35 1 calc PR A 1
C36 C 0.833(7) 0.081(7) 0.100(7) 0.10(2) Uiso 0.25 1 d P A 1
H36A H 0.8026 0.0020 0.0461 0.144 Uiso 0.35 1 calc PR A 1
H36B H 0.8812 0.0920 0.1688 0.144 Uiso 0.35 1 calc PR A 1
H36C H 0.8821 0.1170 0.0762 0.144 Uiso 0.35 1 calc PR A 1
Si1 Si 0.2125(2) 0.4632(2) 0.9114(2) 0.0226(6) Uani 1 1 d . . .
O12 O 0.3814(7) -0.1779(6) 0.3928(6) 0.0362(19) Uani 1 1 d . . .
O3 O 0.4675(8) 0.2164(7) 0.1859(6) 0.045(2) Uani 1 1 d . . .
O7 O 0.6591(7) 0.2617(8) 0.5193(7) 0.051(2) Uani 1 1 d . . .
O1 O 0.3847(8) 0.1958(8) 0.4645(7) 0.055(3) Uani 1 1 d . . .
O2 O 0.4665(8) 0.3699(8) 0.5190(7) 0.051(2) Uani 1 1 d . . .
O4 O 0.3479(8) 0.2840(7) 0.2775(7) 0.042(2) Uani 1 1 d . . .
O6 O 0.6629(9) 0.1512(10) 0.2992(9) 0.066(3) Uani 1 1 d . . .
C17 C 0.0457(9) 0.4195(9) 0.8370(8) 0.028(2) Uani 1 1 d . . .
C11 C 0.3707(10) 0.4863(9) 0.7997(9) 0.032(3) Uani 1 1 d . . .
H12 H 0.4050 0.5597 0.8590 0.038 Uiso 1 1 calc R . .
C13 C 0.2523(9) 0.3914(8) 0.9898(8) 0.025(2) Uani 1 1 d . . .
C15 C 0.2785(9) 0.4172(9) 0.8013(8) 0.027(2) Uani 1 1 d . . .
C12 C 0.2188(5) 0.4166(5) 1.0798(5) 0.030(2) Uani 1 1 d . . .
H3 H 0.1691 0.4642 1.0965 0.036 Uiso 1 1 calc R . .
C18 C 0.2776(5) -0.3812(5) 0.0115(5) 0.027(2) Uani 1 1 d R . .
C14 C 0.3256(5) 0.3180(5) 0.9658(5) 0.028(2) Uani 1 1 d R . .
H1 H 0.3482 0.2982 0.9051 0.034 Uiso 1 1 d R . .
C6 C 0.0013(10) -0.4453(9) 0.2446(9) 0.034(3) Uani 1 1 d . . .
H7 H -0.0476 -0.4990 0.2482 0.040 Uiso 1 1 calc R . .
C9 C 0.2743(11) 0.2675(10) 0.6259(9) 0.040(3) Uani 1 1 d . . .
H10 H 0.2430 0.1930 0.5684 0.048 Uiso 1 1 calc R . .
C4 C 0.0345(10) -0.3460(9) 0.1556(8) 0.030(2) Uani 1 1 d . . .
H6 H 0.0078 -0.3306 0.1002 0.036 Uiso 1 1 calc R . .
C8 C 0.3636(10) 0.3382(10) 0.6253(8) 0.032(3) Uani 1 1 d . . .
C16 C 0.2305(10) 0.3058(9) 0.7111(8) 0.032(3) Uani 1 1 d . . .
H9 H 0.1683 0.2572 0.7087 0.039 Uiso 1 1 calc R . .
C2 C 0.1929(9) -0.3150(8) 0.3122(8) 0.026(2) Uani 1 1 d . . .
C29 C 0.2575(10) 0.3728(9) 0.1459(9) 0.032(2) Uani 1 1 d . . .
H14 H 0.2334 0.3907 0.2055 0.039 Uiso 1 1 calc R . .
C28 C 0.3651(10) 0.2741(9) 0.0316(8) 0.031(2) Uani 1 1 d . . .
H13 H 0.4138 0.2257 0.0147 0.037 Uiso 1 1 calc R . .
C3 C 0.1529(6) -0.2947(5) 0.2282(5) 0.032(2) Uani 1 1 d . . .
H15 H 0.2050 -0.2468 0.2205 0.038 Uiso 1 1 calc R . .
C19 C 0.3851(6) -0.3429(5) 0.0991(5) 0.033(3) Uani 1 1 d R . .
H19 H 0.4239 -0.3943 0.1063 0.039 Uiso 1 1 d R . .
C5 C 0.1168(6) -0.3927(5) 0.3179(5) 0.029(2) Uani 1 1 d R . .
H17 H 0.1447 -0.4091 0.3725 0.035 Uiso 1 1 d R . .
C10 C 0.4130(10) 0.4510(9) 0.7149(9) 0.033(3) Uani 1 1 d . . .
H23 H 0.4732 0.5002 0.7160 0.039 Uiso 1 1 calc R . .
C7 C 0.4088(11) 0.3000(12) 0.5309(9) 0.042(3) Uani 1 1 d . . .
C20 C 0.2228(13) -0.3017(11) 0.0029(11) 0.048(3) Uani 1 1 d . . .
H20 H 0.1506 -0.3245 -0.0544 0.058 Uiso 1 1 calc R . .
C23 C 0.3792(12) -0.1510(10) 0.1681(12) 0.063(5) Uani 1 1 d D . .
C22 C 0.4353(11) -0.2286(9) 0.1759(9) 0.044(3) Uani 1 1 d D . .
H22 H 0.5079 -0.2044 0.2334 0.052 Uiso 1 1 calc R . .
C21 C 0.2756(14) -0.1903(10) 0.0789(13) 0.069(5) Uani 1 1 d D . .
H21 H 0.2396 -0.1382 0.0699 0.082 Uiso 1 1 calc R . .
O5 O 0.6402(9) 0.3945(8) 0.4089(7) 0.055(3) Uani 1 1 d . . .
C27 C 0.3318(10) 0.3026(9) 0.1227(9) 0.030(2) Uani 1 1 d . . .
C26 C 0.3844(11) 0.2647(9) 0.1996(9) 0.035(3) Uani 1 1 d . . .
C1 C 0.3152(9) -0.2465(9) 0.4016(9) 0.032(3) Uani 1 1 d . . .
N2 N 0.7973(11) 0.5521(10) 0.5108(9) 0.062(3) Uani 1 1 d D . .
C32 C 0.8552(15) 0.5184(17) 0.4307(13) 0.077(5) Uani 1 1 d D . .
H31A H 0.9278 0.5761 0.4577 0.115 Uiso 1 1 calc R . .
H31B H 0.8014 0.5071 0.3635 0.115 Uiso 1 1 calc R . .
H31C H 0.8749 0.4496 0.4177 0.115 Uiso 1 1 calc R . .
C31 C 0.8524(15) 0.6634(12) 0.6105(11) 0.068(4) Uani 1 1 d D . .
H32A H 0.9256 0.6987 0.6095 0.102 Uiso 1 1 calc R . .
H32B H 0.8706 0.6558 0.6735 0.102 Uiso 1 1 calc R . .
H32C H 0.7972 0.7088 0.6139 0.102 Uiso 1 1 calc R . .
C30 C 0.6928(14) 0.4814(14) 0.4892(14) 0.059(4) Uani 1 1 d . . .
H30 H 0.6598 0.5048 0.5440 0.071 Uiso 1 1 calc R . .
O8 O 0.3721(15) 0.0479(15) 0.5145(14) 0.042(4) Uani 0.50 1 d P . .
N3 N 0.833(2) 0.107(2) 0.366(2) 0.059(6) Uani 0.50 1 d P . .
C33 C 0.768(2) 0.179(3) 0.370(2) 0.050(7) Uani 0.50 1 d P . .
C34 C 0.951(2) 0.141(3) 0.444(3) 0.065(9) Uani 0.50 1 d P . .
H41A H 0.9833 0.0775 0.4274 0.098 Uiso 0.50 1 calc PR . .
H41B H 0.9477 0.1724 0.5166 0.098 Uiso 0.50 1 calc PR . .
H41C H 1.0027 0.1971 0.4420 0.098 Uiso 0.50 1 calc PR . .
C35 C 0.775(3) -0.008(3) 0.290(3) 0.114(19) Uani 0.50 1 d P . .
H42A H 0.8312 -0.0514 0.2954 0.172 Uiso 0.50 1 calc PR . .
H42B H 0.7491 -0.0208 0.2169 0.172 Uiso 0.50 1 calc PR . .
H42C H 0.7067 -0.0315 0.3044 0.172 Uiso 0.50 1 calc PR . .
O9 O 0.2375(17) -0.0382(15) 0.3303(15) 0.053(5) Uani 0.50 1 d P . .
O10 O 0.2409(16) -0.0154(14) 0.4856(15) 0.048(4) Uani 0.50 1 d P . .
N1 N 0.175(2) -0.0380(15) 0.3913(19) 0.046(6) Uani 0.50 1 d P . .
O11 O 0.071(2) -0.0612(19) 0.362(2) 0.077(7) Uani 0.50 1 d P . .
Eu1 Eu 0.50797(6) 0.22523(6) 0.36162(5) 0.0432(2) Uani 1 1 d . . .
Eu2 Eu 0.44517(11) 0.01800(10) 0.47781(10) 0.0371(3) Uani 0.50 1 d P . .
O14A O 0.4848(12) 0.0146(12) 0.3279(12) 0.018(3) Uiso 0.50 1 d P . 1
O14 O 0.3683(16) 0.0401(15) 0.2034(15) 0.045(4) Uiso 0.50 1 d P . 1
C24 C 0.414(2) -0.0261(14) 0.232(2) 0.038(6) Uiso 0.50 1 d PD . 1
C24A C 0.447(2) -0.035(2) 0.276(2) 0.044(7) Uiso 0.50 1 d PD . 2
O15 O 0.4115(16) 0.0372(16) 0.2618(16) 0.045(4) Uiso 0.50 1 d P . 2
O15A O 0.5261(15) -0.0141(14) 0.3630(14) 0.042(4) Uiso 0.50 1 d P . 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C38 N4 C36 119(6) . .
C38 N4 C37 123(5) . .
C36 N4 C37 118(5) . .
N4 C38 O13 129(5) . .
N4 C38 H38 115.6 . .
O13 C38 H38 115.6 . .
N4 C37 H37A 109.5 . .
N4 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
N4 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
N4 C36 H36A 109.5 . .
N4 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
N4 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
C15 Si1 C17 104.8(5) . .
C15 Si1 C13 110.1(5) . .
C17 Si1 C13 110.8(5) . .
C15 Si1 C18 110.0(4) . 1_566
C17 Si1 C18 113.9(4) . 1_566
C13 Si1 C18 107.3(4) . 1_566
C1 O12 Eu2 136.3(8) . .
C1 O12 Eu2 133.1(7) . 2_656
Eu2 O12 Eu2 38.04(13) . 2_656
C26 O3 Eu1 91.5(7) . .
C1 O7 Eu1 145.8(7) 2_656 .
C7 O1 Eu1 92.4(8) . .
C7 O1 Eu2 135.1(8) . .
Eu1 O1 Eu2 102.6(3) . .
C7 O2 Eu1 94.0(8) . .
C26 O4 Eu1 92.6(7) . .
C33 O6 Eu1 118.8(15) . .
C4 C17 C6 116.7(9) 2_556 2_556
C4 C17 Si1 122.6(8) 2_556 .
C6 C17 Si1 119.8(8) 2_556 .
C10 C11 C15 123.0(10) . .
C10 C11 H12 118.5 . .
C15 C11 H12 118.5 . .
C12 C13 C14 117.6(9) . .
C12 C13 Si1 120.8(7) . .
C14 C13 Si1 121.3(7) . .
C11 C15 C16 116.8(10) . .
C11 C15 Si1 124.6(8) . .
C16 C15 Si1 118.5(8) . .
C13 C12 C29 121.8(8) . 1_556
C13 C12 H3 119.1 . .
C29 C12 H3 119.1 1_556 .
C19 C18 C20 118.0(8) . .
C19 C18 Si1 118.9(5) . 1_544
C20 C18 Si1 123.1(7) . 1_544
C28 C14 C13 121.0(8) 1_556 .
C28 C14 H1 119.3 1_556 .
C13 C14 H1 119.7 . .
C5 C6 C17 121.2(10) . 2_556
C5 C6 H7 119.4 . .
C17 C6 H7 119.4 2_556 .
C8 C9 C16 120.9(10) . .
C8 C9 H10 119.6 . .
C16 C9 H10 119.6 . .
C3 C4 C17 122.1(9) . 2_556
C3 C4 H6 119.0 . .
C17 C4 H6 119.0 2_556 .
C9 C8 C10 119.1(10) . .
C9 C8 C7 121.9(10) . .
C10 C8 C7 119.0(10) . .
C9 C16 C15 121.1(10) . .
C9 C16 H9 119.4 . .
C15 C16 H9 119.4 . .
C3 C2 C5 119.5(8) . .
C3 C2 C1 119.9(9) . .
C5 C2 C1 120.5(9) . .
C27 C29 C12 119.9(10) . 1_554
C27 C29 H14 120.0 . .
C12 C29 H14 120.0 1_554 .
C14 C28 C27 120.2(9) 1_554 .
C14 C28 H13 119.9 1_554 .
C27 C28 H13 119.9 . .
C2 C3 C4 119.5(8) . .
C2 C3 H15 120.2 . .
C4 C3 H15 120.2 . .
C18 C19 C22 120.7(8) . .
C18 C19 H19 119.7 . .
C22 C19 H19 119.6 . .
C6 C5 C2 120.7(8) . .
C6 C5 H17 119.6 . .
C2 C5 H17 119.7 . .
C11 C10 C8 119.1(10) . .
C11 C10 H23 120.4 . .
C8 C10 H23 120.4 . .
O2 C7 O1 121.4(12) . .
O2 C7 C8 120.5(12) . .
O1 C7 C8 118.1(12) . .
O2 C7 Eu1 60.3(7) . .
O1 C7 Eu1 61.3(6) . .
C8 C7 Eu1 176.0(8) . .
C21 C20 C18 119.6(12) . .
C21 C20 H20 120.2 . .
C18 C20 H20 120.2 . .
C21 C23 C22 117.4(11) . .
C21 C23 C24 109.3(14) . .
C22 C23 C24 132.9(15) . .
C21 C23 C24A 134.6(15) . .
C22 C23 C24A 107.6(14) . .
C24 C23 C24A 28.0(11) . .
C23 C22 C19 120.8(11) . .
C23 C22 H22 119.6 . .
C19 C22 H22 119.6 . .
C20 C21 C23 123.3(13) . .
C20 C21 H21 118.3 . .
C23 C21 H21 118.3 . .
C30 O5 Eu1 136.2(10) . .
C29 C27 C28 119.5(10) . .
C29 C27 C26 120.3(10) . .
C28 C27 C26 120.0(10) . .
O4 C26 O3 121.7(10) . .
O4 C26 C27 119.7(11) . .
O3 C26 C27 118.5(11) . .
O4 C26 Eu1 60.7(6) . .
O3 C26 Eu1 61.5(6) . .
C27 C26 Eu1 171.5(8) . .
O12 C1 O7 125.1(10) . 2_656
O12 C1 C2 118.3(10) . .
O7 C1 C2 116.5(10) 2_656 .
C30 N2 C32 119.1(14) . .
C30 N2 C31 123.1(13) . .
C32 N2 C31 117.8(14) . .
N2 C32 H31A 109.5 . .
N2 C32 H31B 109.5 . .
H31A C32 H31B 109.5 . .
N2 C32 H31C 109.5 . .
H31A C32 H31C 109.5 . .
H31B C32 H31C 109.5 . .
N2 C31 H32A 109.5 . .
N2 C31 H32B 109.5 . .
H32A C31 H32B 109.5 . .
N2 C31 H32C 109.5 . .
H32A C31 H32C 109.5 . .
H32B C31 H32C 109.5 . .
O5 C30 N2 126.8(15) . .
O5 C30 H30 116.6 . .
N2 C30 H30 116.6 . .
Eu2 O8 O10 131.1(15) . .
Eu2 O8 Eu2 29.2(5) . 2_656
O10 O8 Eu2 129.7(11) . 2_656
C33 N3 C35 118(3) . .
C33 N3 C34 122(3) . .
C35 N3 C34 120(3) . .
O6 C33 N3 123(3) . .
O6 C33 Eu1 40.7(10) . .
N3 C33 Eu1 145.1(19) . .
N3 C34 H41A 109.5 . .
N3 C34 H41B 109.5 . .
H41A C34 H41B 109.5 . .
N3 C34 H41C 109.5 . .
H41A C34 H41C 109.5 . .
H41B C34 H41C 109.5 . .
N3 C35 H42A 109.5 . .
N3 C35 H42B 109.5 . .
H42A C35 H42B 109.5 . .
N3 C35 H42C 109.5 . .
H42A C35 H42C 109.5 . .
H42B C35 H42C 109.5 . .
N1 O9 Eu2 95.3(13) . .
N1 O10 O8 110.0(18) . .
N1 O10 Eu2 101.6(16) . .
O8 O10 Eu2 20.7(7) . .
O11 N1 O10 123(3) . .
O11 N1 O9 124(3) . .
O10 N1 O9 113(2) . .
O11 N1 Eu2 177(2) . .
O10 N1 Eu2 53.8(12) . .
O9 N1 Eu2 58.9(11) . .
O15 Eu1 O7 107.8(5) . .
O15 Eu1 O5 157.1(5) . .
O7 Eu1 O5 79.0(3) . .
O15 Eu1 O6 80.0(5) . .
O7 Eu1 O6 75.3(4) . .
O5 Eu1 O6 80.8(4) . .
O15 Eu1 O4 96.9(5) . .
O7 Eu1 O4 148.3(3) . .
O5 Eu1 O4 85.9(3) . .
O6 Eu1 O4 129.6(3) . .
O15 Eu1 O3 87.1(5) . .
O7 Eu1 O3 144.6(3) . .
O5 Eu1 O3 76.4(3) . .
O6 Eu1 O3 76.1(3) . .
O4 Eu1 O3 53.6(3) . .
O15 Eu1 O2 125.5(5) . .
O7 Eu1 O2 73.7(3) . .
O5 Eu1 O2 77.2(3) . .
O6 Eu1 O2 144.8(4) . .
O4 Eu1 O2 75.9(3) . .
O3 Eu1 O2 123.8(3) . .
O15 Eu1 O1 74.5(5) . .
O7 Eu1 O1 78.9(3) . .
O5 Eu1 O1 128.4(3) . .
O6 Eu1 O1 135.7(4) . .
O4 Eu1 O1 89.3(3) . .
O3 Eu1 O1 136.5(3) . .
O2 Eu1 O1 51.9(3) . .
O15 Eu1 O14 21.2(5) . .
O7 Eu1 O14 128.7(5) . .
O5 Eu1 O14 143.7(5) . .
O6 Eu1 O14 84.5(5) . .
O4 Eu1 O14 78.3(5) . .
O3 Eu1 O14 67.9(5) . .
O2 Eu1 O14 128.5(4) . .
O1 Eu1 O14 84.4(4) . .
O15 Eu1 O14A 28.8(6) . .
O7 Eu1 O14A 79.1(4) . .
O5 Eu1 O14A 147.0(4) . .
O6 Eu1 O14A 70.0(4) . .
O4 Eu1 O14A 124.5(4) . .
O3 Eu1 O14A 109.7(4) . .
O2 Eu1 O14A 119.2(4) . .
O1 Eu1 O14A 70.2(4) . .
O14 Eu1 O14A 49.6(5) . .
O15 Eu1 C26 94.1(5) . .
O7 Eu1 C26 157.1(3) . .
O5 Eu1 C26 78.2(3) . .
O6 Eu1 C26 102.9(4) . .
O4 Eu1 C26 26.8(3) . .
O3 Eu1 C26 27.0(3) . .
O2 Eu1 C26 99.1(3) . .
O1 Eu1 C26 114.3(4) . .
O14 Eu1 C26 73.0(5) . .
O14A Eu1 C26 122.3(4) . .
O15 Eu1 C7 100.5(5) . .
O7 Eu1 C7 73.4(3) . .
O5 Eu1 C7 102.4(4) . .
O6 Eu1 C7 147.2(4) . .
O4 Eu1 C7 83.0(3) . .
O3 Eu1 C7 136.6(3) . .
O2 Eu1 C7 25.7(3) . .
O1 Eu1 C7 26.2(3) . .
O14 Eu1 C7 107.8(5) . .
O14A Eu1 C7 94.6(4) . .
C26 Eu1 C7 109.7(4) . .
O8 Eu2 Eu2 129.4(9) . 2_656
O8 Eu2 O15A 152.1(10) . .
Eu2 Eu2 O15A 78.4(5) 2_656 .
O8 Eu2 O15A 68.8(10) . 2_656
Eu2 Eu2 O15A 60.7(4) 2_656 2_656
O15A Eu2 O15A 139.0(3) . 2_656
O8 Eu2 O12 103.5(9) . .
Eu2 Eu2 O12 73.5(2) 2_656 .
O15A Eu2 O12 85.1(5) . .
O15A Eu2 O12 83.5(5) 2_656 .
O8 Eu2 O14A 130.5(9) . .
Eu2 Eu2 O14A 99.7(3) 2_656 .
O15A Eu2 O14A 21.7(5) . .
O15A Eu2 O14A 160.0(5) 2_656 .
O12 Eu2 O14A 94.9(4) . .
O8 Eu2 O12 100.5(9) . 2_656
Eu2 Eu2 O12 68.5(2) 2_656 2_656
O15A Eu2 O12 87.4(5) . 2_656
O15A Eu2 O12 78.2(5) 2_656 2_656
O12 Eu2 O12 141.96(13) . 2_656
O14A Eu2 O12 91.4(4) . 2_656
O8 Eu2 O8 150.8(5) . 2_656
Eu2 Eu2 O8 21.4(4) 2_656 2_656
O15A Eu2 O8 57.0(6) . 2_656
O15A Eu2 O8 82.0(6) 2_656 2_656
O12 Eu2 O8 73.2(5) . 2_656
O14A Eu2 O8 78.4(5) . 2_656
O12 Eu2 O8 71.5(5) 2_656 2_656
O8 Eu2 O10 28.2(10) . .
Eu2 Eu2 O10 128.6(5) 2_656 .
O15A Eu2 O10 139.3(7) . .
O15A Eu2 O10 75.1(6) 2_656 .
O12 Eu2 O10 77.0(4) . .
O14A Eu2 O10 124.1(6) . .
O12 Eu2 O10 128.3(5) 2_656 .
O8 Eu2 O10 144.1(6) 2_656 .
O8 Eu2 O9 67.0(10) . .
Eu2 Eu2 O9 148.3(4) 2_656 .
O15A Eu2 O9 90.1(7) . .
O15A Eu2 O9 124.7(6) 2_656 .
O12 Eu2 O9 76.2(4) . .
O14A Eu2 O9 73.8(6) . .
O12 Eu2 O9 141.1(4) 2_656 .
O8 Eu2 O9 136.2(6) 2_656 .
O10 Eu2 O9 50.5(6) . .
O8 Eu2 C24A 127.5(10) . .
Eu2 Eu2 C24A 102.6(6) 2_656 .
O15A Eu2 C24A 26.2(7) . .
O15A Eu2 C24A 160.8(7) 2_656 .
O12 Eu2 C24A 82.5(6) . .
O14A Eu2 C24A 14.2(5) . .
O12 Eu2 C24A 105.4(6) 2_656 .
O8 Eu2 C24A 81.4(7) 2_656 .
O10 Eu2 C24A 114.2(7) . .
O9 Eu2 C24A 64.1(8) . .
O8 Eu2 O1 65.9(9) . .
Eu2 Eu2 O1 142.0(2) 2_656 .
O15A Eu2 O1 91.1(5) . .
O15A Eu2 O1 120.7(5) 2_656 .
O12 Eu2 O1 142.5(3) . .
O14A Eu2 O1 71.7(4) . .
O12 Eu2 O1 74.7(3) 2_656 .
O8 Eu2 O1 133.7(5) 2_656 .
O10 Eu2 O1 82.2(4) . .
O9 Eu2 O1 66.5(4) . .
C24A Eu2 O1 78.1(6) . .
C24 O14A Eu2 129.3(14) . .
C24 O14A Eu1 90.1(12) . .
Eu2 O14A Eu1 107.4(5) . .
C24 O14A Eu2 145.1(13) . 2_656
Eu2 O14A Eu2 30.21(18) . 2_656
Eu1 O14A Eu2 120.1(5) . 2_656
C24 O14 Eu1 99.0(14) . .
O14A C24 O14 119.1(17) . .
O14A C24 C23 112.4(19) . .
O14 C24 C23 128(2) . .
O14A C24 Eu1 65.2(9) . .
O14 C24 Eu1 55.6(10) . .
C23 C24 Eu1 174.7(15) . .
O15 C24A O15A 124(2) . .
O15 C24A C23 108(2) . .
O15A C24A C23 128(2) . .
O15 C24A Eu2 104.9(17) . .
O15A C24A Eu2 46.1(12) . .
C23 C24A Eu2 124.7(15) . .
O15 C24A Eu1 35.7(12) . .
O15A C24A Eu1 89.6(15) . .
C23 C24A Eu1 140.6(16) . .
Eu2 C24A Eu1 88.1(7) . .
C24A O15 Eu1 126.2(18) . .
C24A O15A Eu2 107.7(16) . .
C24A O15A Eu2 143.6(17) . 2_656
Eu2 O15A Eu2 41.0(3) . 2_656
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
O13 C38 1.26(6) .
N4 C38 1.25(6) .
N4 C36 1.37(9) .
N4 C37 1.42(7) .
C38 H38 0.9300 .
C37 H37A 0.9600 .
C37 H37B 0.9600 .
C37 H37C 0.9600 .
C36 H36A 0.9600 .
C36 H36B 0.9600 .
C36 H36C 0.9600 .
Si1 C15 1.866(11) .
Si1 C17 1.869(11) .
Si1 C13 1.870(11) .
Si1 C18 1.880(7) 1_566
O12 C1 1.251(13) .
O12 Eu2 2.341(8) .
O12 Eu2 2.413(7) 2_656
O3 C26 1.267(14) .
O3 Eu1 2.456(8) .
O7 C1 1.253(14) 2_656
O7 Eu1 2.329(7) .
O1 C7 1.261(16) .
O1 Eu1 2.502(9) .
O1 Eu2 2.748(11) .
O2 C7 1.240(15) .
O2 Eu1 2.481(9) .
O4 C26 1.259(14) .
O4 Eu1 2.438(8) .
O6 C33 1.29(3) .
O6 Eu1 2.399(10) .
C17 C4 1.388(15) 2_556
C17 C6 1.415(15) 2_556
C11 C10 1.370(16) .
C11 C15 1.393(15) .
C11 H12 0.9300 .
C13 C12 1.387(12) .
C13 C14 1.402(12) .
C15 C16 1.410(15) .
C12 C29 1.393(12) 1_556
C12 H3 0.9300 .
C18 C19 1.391(8) .
C18 C20 1.391(14) .
C18 Si1 1.880(6) 1_544
C14 C28 1.391(12) 1_556
C14 H1 0.9300 .
C6 C5 1.363(12) .
C6 C17 1.415(15) 2_556
C6 H7 0.9300 .
C9 C8 1.375(16) .
C9 C16 1.385(16) .
C9 H10 0.9300 .
C4 C3 1.385(12) .
C4 C17 1.388(15) 2_556
C4 H6 0.9300 .
C8 C10 1.419(16) .
C8 C7 1.510(16) .
C16 H9 0.9300 .
C2 C3 1.381(12) .
C2 C5 1.386(12) .
C2 C1 1.511(14) .
C29 C27 1.380(16) .
C29 C12 1.393(12) 1_554
C29 H14 0.9300 .
C28 C14 1.391(12) 1_554
C28 C27 1.394(16) .
C28 H13 0.9300 .
C3 H15 0.9300 .
C19 C22 1.391(12) .
C19 H19 0.9300 .
C5 H17 0.9300 .
C10 H23 0.9300 .
C7 Eu1 2.850(13) .
C20 C21 1.363(18) .
C20 H20 0.9300 .
C23 C21 1.372(15) .
C23 C22 1.372(14) .
C23 C24 1.485(16) .
C23 C24A 1.56(3) .
C22 H22 0.9300 .
C21 H21 0.9300 .
O5 C30 1.169(18) .
O5 Eu1 2.371(9) .
C27 C26 1.496(15) .
C26 Eu1 2.793(11) .
C1 O7 1.253(14) 2_656
N2 C30 1.361(19) .
N2 C32 1.440(14) .
N2 C31 1.464(14) .
C32 H31A 0.9600 .
C32 H31B 0.9600 .
C32 H31C 0.9600 .
C31 H32A 0.9600 .
C31 H32B 0.9600 .
C31 H32C 0.9600 .
C30 H30 0.9300 .
O8 Eu2 1.159(15) .
O8 O10 1.55(2) .
O8 Eu2 2.455(15) 2_656
N3 C33 1.32(4) .
N3 C35 1.41(4) .
N3 C34 1.43(3) .
C33 Eu1 3.22(3) .
C34 H41A 0.9600 .
C34 H41B 0.9600 .
C34 H41C 0.9600 .
C35 H42A 0.9600 .
C35 H42B 0.9600 .
C35 H42C 0.9600 .
O9 N1 1.31(3) .
O9 Eu2 2.576(17) .
O10 N1 1.27(3) .
O10 Eu2 2.470(18) .
N1 O11 1.14(3) .
N1 Eu2 3.00(2) .
Eu1 O15 2.284(19) .
Eu1 O14 2.503(18) .
Eu1 O14A 2.719(14) .
Eu2 Eu2 1.551(3) 2_656
Eu2 O15A 2.062(17) .
Eu2 O15A 2.317(18) 2_656
Eu2 O14A 2.365(13) .
Eu2 O12 2.413(7) 2_656
Eu2 O8 2.455(15) 2_656
Eu2 C24A 2.73(3) .
O14A C24 1.25(3) .
O14A Eu2 3.038(14) 2_656
O14 C24 1.30(3) .
C24A O15 1.22(3) .
C24A O15A 1.26(3) .
O15A Eu2 2.317(18) 2_656
