#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/66/4506676.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4506676
loop_
_publ_author_name
'Cai, Song-Liang'
'Zheng, Sheng-Run'
'Wen, Zhen-Zhen'
'Fan, Jun'
'Wang, Ning'
'Zhang, Wei-Guang'
_publ_section_title
;
 Two Types of New Three-Dimensional d--f Heterometallic Coordination
 Polymers Based on 2-(Pyridin-3-yl)-1H-Imidazole-4,5-Dicarboxylate and
 Oxalate Ligands: Syntheses, Structures, Luminescence, and Magnetic
 Properties
;
_journal_issue                   9
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              4441
_journal_paper_doi               10.1021/cg300613t
_journal_volume                  12
_journal_year                    2012
_chemical_formula_moiety         'C24 H18 Co N6 O20 Eu2, 4(H2 O)'
_chemical_formula_sum            'C24 H26 Co Eu2 N6 O24'
_chemical_formula_weight         1145.36
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                91.8010(10)
_cell_angle_beta                 110.0120(10)
_cell_angle_gamma                102.8610(10)
_cell_formula_units_Z            2
_cell_length_a                   10.5406(9)
_cell_length_b                   12.7755(11)
_cell_length_c                   14.1480(13)
_cell_measurement_reflns_used    3545
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      27.90
_cell_measurement_theta_min      2.34
_cell_volume                     1733.2(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.941
_diffrn_measured_fraction_theta_max 0.941
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0267
_diffrn_reflns_av_sigmaI/netI    0.0728
_diffrn_reflns_limit_h_max       7
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            7561
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.54
_exptl_absorpt_coefficient_mu    4.154
_exptl_absorpt_correction_T_max  0.4904
_exptl_absorpt_correction_T_min  0.4232
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            pink
_exptl_crystal_density_diffrn    2.195
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1114
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.20
_refine_diff_density_max         8.130
_refine_diff_density_min         -7.494
_refine_diff_density_rms         0.571
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     514
_refine_ls_number_reflns         5742
_refine_ls_number_restraints     42
_refine_ls_restrained_S_all      1.034
_refine_ls_R_factor_all          0.1829
_refine_ls_R_factor_gt           0.1333
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0200P)²+300.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2754
_refine_ls_wR_factor_ref         0.3121
_reflns_number_gt                4038
_reflns_number_total             5742
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg300613t_si_001.cif
_cod_data_source_block           Eu-Co
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_Hall     '-P 1 '
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4506676
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.04207(4) 0.75135(3) 0.03259(3) 0.03163(11) Uani 1 1 d .
Eu2 Eu 0.41122(4) 0.74951(3) -0.02499(3) 0.03212(11) Uani 1 1 d .
Co1 Co 0.21597(11) 0.72575(10) 0.50275(8) 0.0415(3) Uani 1 1 d .
C13 C 0.3738(7) 0.6970(6) 0.2694(5) 0.035(2) Uani 1 1 d .
C14 C 0.3753(7) 0.7098(6) 0.1667(5) 0.035(2) Uani 1 1 d .
C12 C 0.2971(7) 0.7191(7) 0.3225(5) 0.032(2) Uani 1 1 d .
C11 C 0.1760(8) 0.7687(5) 0.2953(5) 0.035(2) Uani 1 1 d .
C15 C 0.4694(6) 0.6687(6) 0.4261(6) 0.031(2) Uani 1 1 d .
C16 C 0.5701(6) 0.6439(6) 0.5175(5) 0.027(2) Uani 1 1 d .
N4 N 0.3534(6) 0.7027(5) 0.4209(4) 0.0345(19) Uani 1 1 d .
N5 N 0.4809(6) 0.6650(5) 0.3359(4) 0.0358(19) Uani 1 1 d .
H5 H 0.5459 0.6453 0.3219 0.043 Uiso 1 1 calc R
O6 O 0.1227(5) 0.7990(5) 0.2107(4) 0.0431(17) Uani 1 1 d .
O8 O 0.4815(5) 0.6957(5) 0.1474(3) 0.0432(17) Uani 1 1 d .
O7 O 0.2717(4) 0.7265(4) 0.0941(3) 0.0283(12) Uani 1 1 d U
O5 O 0.1372(5) 0.7873(5) 0.3684(4) 0.0470(18) Uani 1 1 d .
O1 O 0.2910(5) 0.6649(5) 0.6407(4) 0.0465(18) Uani 1 1 d .
N1 N 0.0856(6) 0.7633(5) 0.5821(4) 0.0358(19) Uani 1 1 d .
O3 O 0.1840(4) 0.7824(4) 0.9126(3) 0.0264(12) Uani 1 1 d U
O16 O 0.5544(5) 1.0840(4) -0.0818(4) 0.0431(17) Uani 1 1 d .
O4 O -0.0251(5) 0.8132(5) 0.8595(4) 0.0417(16) Uani 1 1 d .
O14 O 0.0001(5) 0.4047(4) 0.0842(4) 0.0402(17) Uani 1 1 d .
N6 N 0.7652(7) 0.5643(6) 0.5903(5) 0.045(2) Uani 1 1 d .
C18 C 0.6751(9) 0.6496(8) 0.6990(6) 0.055(3) Uani 1 1 d .
H18 H 0.6790 0.6683 0.7641 0.066 Uiso 1 1 calc R
C19 C 0.7693(9) 0.5932(7) 0.6822(8) 0.058(3) Uani 1 1 d .
H19 H 0.8361 0.5761 0.7379 0.070 Uiso 1 1 calc R
C20 C 0.6668(8) 0.5866(8) 0.5119(6) 0.047(3) Uani 1 1 d .
H20 H 0.6613 0.5623 0.4477 0.056 Uiso 1 1 calc R
C17 C 0.5781(10) 0.6754(9) 0.6155(7) 0.061(3) Uani 1 1 d .
H17 H 0.5172 0.7142 0.6244 0.073 Uiso 1 1 calc R
C6 C -0.1079(7) 0.8415(6) 0.4806(6) 0.035(2) Uani 1 1 d .
C7 C -0.1352(8) 0.7846(9) 0.3855(7) 0.058(3) Uani 1 1 d .
H7 H -0.0984 0.7256 0.3818 0.070 Uiso 1 1 calc R
N2 N -0.0232(6) 0.8347(6) 0.6663(4) 0.038(2) Uani 1 1 d .
H2 H -0.0792 0.8683 0.6784 0.046 Uiso 1 1 calc R
C2 C 0.1447(8) 0.7507(7) 0.6860(5) 0.040(2) Uani 1 1 d .
C3 C 0.0778(7) 0.7956(6) 0.7385(5) 0.028(2) Uani 1 1 d .
C5 C -0.0182(6) 0.8114(6) 0.5770(6) 0.037(2) Uani 1 1 d .
O2 O 0.3225(4) 0.6861(4) 0.8013(4) 0.0418(17) Uani 1 1 d .
C1 C 0.2584(7) 0.6984(7) 0.7110(6) 0.042(2) Uani 1 1 d .
C8 C -0.2166(8) 0.8173(7) 0.2984(6) 0.042(3) Uani 1 1 d .
H8 H -0.2393 0.7794 0.2353 0.051 Uiso 1 1 calc R
N3 N -0.2404(8) 0.9639(7) 0.3981(6) 0.062(3) Uani 1 1 d .
C9 C -0.2613(10) 0.9045(8) 0.3077(6) 0.057(3) Uani 1 1 d .
H9 H -0.3114 0.9284 0.2481 0.069 Uiso 1 1 calc R
C10 C -0.1644(8) 0.9307(6) 0.4813(6) 0.050(2) Uani 1 1 d .
H10 H -0.1475 0.9686 0.5433 0.060 Uiso 1 1 calc R
O13 O 0.0326(5) 0.5845(4) 0.1113(3) 0.0350(16) Uani 1 1 d .
O15 O 0.4425(6) 0.9096(5) -0.1088(4) 0.046(2) Uani 1 1 d .
C4 C 0.0787(7) 0.7947(6) 0.8426(6) 0.033(2) Uani 1 1 d .
O9 O -0.1205(6) 0.8614(4) 0.0404(5) 0.0500(18) Uani 1 1 d .
O11 O -0.2017(5) 0.6522(5) -0.0165(5) 0.0549(18) Uani 1 1 d .
C21 C -0.2508(6) 0.8158(6) 0.0232(5) 0.0305(11) Uani 1 1 d U
C22 C -0.2919(6) 0.6943(6) -0.0126(5) 0.0253(13) Uani 1 1 d U
C24 C 0.5032(7) 0.9993(6) -0.0555(5) 0.033(2) Uani 1 1 d .
O10 O -0.3370(5) 0.8518(4) 0.0343(4) 0.0401(12) Uani 1 1 d U
O12 O -0.4226(6) 0.6493(5) -0.0376(5) 0.0495(19) Uani 1 1 d .
C23 C 0.0098(8) 0.4975(7) 0.0556(5) 0.041(3) Uani 1 1 d .
O2W O 0.0795(6) 0.5656(5) 0.4443(5) 0.054(2) Uani 1 1 d .
H2WA H 0.1083 0.5094 0.4404 0.081 Uiso 1 1 d R
H2WB H 0.0062 0.5604 0.3923 0.081 Uiso 1 1 d R
O1W O 0.3537(6) 0.8749(6) 0.5687(5) 0.067(3) Uani 1 1 d .
H1WA H 0.4326 0.9055 0.5672 0.101 Uiso 1 1 d R
H1WB H 0.3278 0.9217 0.5983 0.101 Uiso 1 1 d R
O3W O 0.1703(5) 0.9458(5) 0.0613(4) 0.0460(19) Uani 1 1 d .
H3WA H 0.2280 0.9673 0.1221 0.069 Uiso 1 1 d R
H3WB H 0.1612 1.0012 0.0314 0.069 Uiso 1 1 d R
O4W O 0.3057(6) 0.5550(5) -0.0424(4) 0.059(2) Uani 1 1 d .
H4WA H 0.2587 0.5131 -0.0151 0.088 Uiso 1 1 d R
H4WB H 0.3110 0.5179 -0.0918 0.088 Uiso 1 1 d R
O5W O 0.6136(7) 0.5247(6) 0.2573(6) 0.079(3) Uani 1 1 d .
H5WA H 0.5298 0.5287 0.2299 0.118 Uiso 1 1 d R
H5WB H 0.6138 0.4727 0.2935 0.118 Uiso 1 1 d R
O6W O 0.8921(9) 0.5613(8) 0.2479(6) 0.097(4) Uani 1 1 d .
H6WA H 0.9370 0.5682 0.2079 0.145 Uiso 1 1 d R
H6WB H 0.8472 0.6094 0.2401 0.145 Uiso 1 1 d R
O7W O 0.8461(7) 0.9751(5) 0.7345(5) 0.071(2) Uani 1 1 d .
H7WA H 0.8716 1.0434 0.7420 0.107 Uiso 1 1 d R
H7WB H 0.8967 0.9530 0.7874 0.107 Uiso 1 1 d R
O8W O 0.5829(10) 0.8876(9) 0.7543(8) 0.133(5) Uani 1 1 d .
H8WA H 0.5247 0.8854 0.7838 0.199 Uiso 1 1 d R
H8WB H 0.5405 0.8535 0.6958 0.199 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Eu1 O6 75.04(18) . .
O7 Eu1 O14 82.94(17) . 2_565
O6 Eu1 O14 138.2(2) . 2_565
O7 Eu1 O13 72.67(17) . .
O6 Eu1 O13 72.40(18) . .
O14 Eu1 O13 67.20(18) 2_565 .
O7 Eu1 O11 141.76(18) . .
O6 Eu1 O11 105.9(2) . .
O14 Eu1 O11 71.3(2) 2_565 .
O13 Eu1 O11 71.46(18) . .
O7 Eu1 O9 148.30(15) . .
O6 Eu1 O9 80.4(2) . .
O14 Eu1 O9 128.63(17) 2_565 .
O13 Eu1 O9 118.4(2) . .
O11 Eu1 O9 64.58(18) . .
O7 Eu1 O3W 82.32(17) . .
O6 Eu1 O3W 74.9(2) . .
O14 Eu1 O3W 137.0(2) 2_565 .
O13 Eu1 O3W 142.85(16) . .
O11 Eu1 O3W 135.6(2) . .
O9 Eu1 O3W 72.03(18) . .
O7 Eu1 O4 113.50(17) . 1_554
O6 Eu1 O4 147.6(2) . 1_554
O14 Eu1 O4 74.03(19) 2_565 1_554
O13 Eu1 O4 139.74(16) . 1_554
O11 Eu1 O4 86.55(18) . 1_554
O9 Eu1 O4 78.2(2) . 1_554
O3W Eu1 O4 75.43(17) . 1_554
O7 Eu1 O3 62.65(15) . 1_554
O6 Eu1 O3 128.27(15) . 1_554
O14 Eu1 O3 65.99(17) 2_565 1_554
O13 Eu1 O3 117.44(18) . 1_554
O11 Eu1 O3 125.71(17) . 1_554
O9 Eu1 O3 122.77(18) . 1_554
O3W Eu1 O3 71.38(18) . 1_554
O4 Eu1 O3 50.91(16) 1_554 1_554
O7 Eu1 C4 88.17(18) . 1_554
O6 Eu1 C4 147.52(17) . 1_554
O14 Eu1 C4 64.0(2) 2_565 1_554
O13 Eu1 C4 129.2(2) . 1_554
O11 Eu1 C4 104.49(19) . 1_554
O9 Eu1 C4 102.6(2) . 1_554
O3W Eu1 C4 75.44(19) . 1_554
O4 Eu1 C4 25.82(19) 1_554 1_554
O3 Eu1 C4 25.64(16) 1_554 1_554
O7 Eu1 C23 73.80(18) . .
O6 Eu1 C23 92.5(2) . .
O14 Eu1 C23 46.77(19) 2_565 .
O13 Eu1 C23 20.43(18) . .
O11 Eu1 C23 68.0(2) . .
O9 Eu1 C23 127.6(2) . .
O3W Eu1 C23 155.27(18) . .
O4 Eu1 C23 119.89(18) 1_554 .
O3 Eu1 C23 102.2(2) 1_554 .
C4 Eu1 C23 109.5(2) 1_554 .
O7 Eu1 C23 78.39(17) . 2_565
O6 Eu1 C23 119.3(2) . 2_565
O14 Eu1 C23 19.54(19) 2_565 2_565
O13 Eu1 C23 47.66(18) . 2_565
O11 Eu1 C23 67.9(2) . 2_565
O9 Eu1 C23 132.01(18) . 2_565
O3W Eu1 C23 151.4(2) . 2_565
O4 Eu1 C23 93.17(19) 1_554 2_565
O3 Eu1 C23 81.05(19) 1_554 2_565
C4 Eu1 C23 83.0(2) 1_554 2_565
C23 Eu1 C23 27.2(3) . 2_565
O2 Eu2 O3 75.19(17) 1_554 1_554
O2 Eu2 O15 75.13(18) 1_554 .
O3 Eu2 O15 76.18(19) 1_554 .
O2 Eu2 O12 77.92(19) 1_554 1_655
O3 Eu2 O12 150.55(16) 1_554 1_655
O15 Eu2 O12 108.2(2) . 1_655
O2 Eu2 O4W 72.57(19) 1_554 .
O3 Eu2 O4W 89.88(19) 1_554 .
O15 Eu2 O4W 147.15(17) . .
O12 Eu2 O4W 70.6(2) 1_655 .
O2 Eu2 O16 137.81(19) 1_554 2_675
O3 Eu2 O16 78.40(16) 1_554 2_675
O15 Eu2 O16 66.93(19) . 2_675
O12 Eu2 O16 130.65(17) 1_655 2_675
O4W Eu2 O16 139.8(2) . 2_675
O2 Eu2 O8 144.7(2) 1_554 .
O3 Eu2 O8 114.94(18) 1_554 .
O15 Eu2 O8 139.19(17) . .
O12 Eu2 O8 81.4(2) 1_655 .
O4W Eu2 O8 73.66(19) . .
O16 Eu2 O8 76.8(2) 2_675 .
O2 Eu2 O10 112.15(18) 1_554 1_655
O3 Eu2 O10 139.72(17) 1_554 1_655
O15 Eu2 O10 68.46(18) . 1_655
O12 Eu2 O10 63.07(18) 1_655 1_655
O4W Eu2 O10 130.4(2) . 1_655
O16 Eu2 O10 70.56(19) 2_675 1_655
O8 Eu2 O10 82.60(17) . 1_655
O2 Eu2 O7 125.67(15) 1_554 .
O3 Eu2 O7 62.95(15) 1_554 .
O15 Eu2 O7 122.1(2) . .
O12 Eu2 O7 127.74(19) 1_655 .
O4W Eu2 O7 74.3(2) . .
O16 Eu2 O7 66.08(17) 2_675 .
O8 Eu2 O7 51.99(16) . .
O10 Eu2 O7 122.14(16) 1_655 .
O2 Eu2 C14 143.41(18) 1_554 .
O3 Eu2 C14 89.00(18) 1_554 .
O15 Eu2 C14 133.4(2) . .
O12 Eu2 C14 106.0(2) 1_655 .
O4W Eu2 C14 74.6(2) . .
O16 Eu2 C14 66.9(2) 2_675 .
O8 Eu2 C14 26.1(2) . .
O10 Eu2 C14 101.31(18) 1_655 .
O7 Eu2 C14 26.14(16) . .
O2 Eu2 C24 122.31(19) 1_554 2_675
O3 Eu2 C24 81.79(16) 1_554 2_675
O15 Eu2 C24 48.02(19) . 2_675
O12 Eu2 C24 123.47(18) 1_655 2_675
O4W Eu2 C24 159.7(2) . 2_675
O16 Eu2 C24 20.1(2) 2_675 2_675
O8 Eu2 C24 93.01(19) . 2_675
O10 Eu2 C24 60.42(19) 1_655 2_675
O7 Eu2 C24 85.44(18) . 2_675
C14 Eu2 C24 86.6(2) . 2_675
O2 Eu2 C24 95.17(19) 1_554 .
O3 Eu2 C24 82.16(17) 1_554 .
O15 Eu2 C24 20.07(17) . .
O12 Eu2 C24 112.2(2) 1_655 .
O4W Eu2 C24 166.84(17) . .
O16 Eu2 C24 48.7(2) 2_675 .
O8 Eu2 C24 119.22(18) . .
O10 Eu2 C24 58.14(18) 1_655 .
O7 Eu2 C24 110.79(19) . .
C14 Eu2 C24 115.5(2) . .
C24 Eu2 C24 28.9(3) 2_675 .
O5 Co1 O1W 91.1(3) . .
O5 Co1 O1 178.1(3) . .
O1W Co1 O1 88.9(2) . .
O5 Co1 N1 101.1(2) . .
O1W Co1 N1 87.5(3) . .
O1 Co1 N1 76.9(2) . .
O5 Co1 O2W 93.1(2) . .
O1W Co1 O2W 175.8(3) . .
O1 Co1 O2W 87.0(2) . .
N1 Co1 O2W 91.9(3) . .
O5 Co1 N4 76.2(2) . .
O1W Co1 N4 88.3(3) . .
O1 Co1 N4 105.8(2) . .
N1 Co1 N4 175.0(3) . .
O2W Co1 N4 92.4(3) . .
C12 C13 N5 105.8(6) . .
C12 C13 C14 136.2(7) . .
N5 C13 C14 117.7(7) . .
O7 C14 O8 118.6(7) . .
O7 C14 C13 123.0(7) . .
O8 C14 C13 118.2(6) . .
O7 C14 Eu2 62.2(4) . .
O8 C14 Eu2 57.2(4) . .
C13 C14 Eu2 173.4(4) . .
C13 C12 N4 111.1(7) . .
C13 C12 C11 131.6(7) . .
N4 C12 C11 116.8(7) . .
O6 C11 O5 121.3(8) . .
O6 C11 C12 124.1(8) . .
O5 C11 C12 114.4(6) . .
N5 C15 N4 109.8(6) . .
N5 C15 C16 124.2(7) . .
N4 C15 C16 125.9(7) . .
C20 C16 C17 115.5(7) . .
C20 C16 C15 121.3(7) . .
C17 C16 C15 123.2(8) . .
C12 N4 C15 104.2(7) . .
C12 N4 Co1 110.3(5) . .
C15 N4 Co1 145.2(5) . .
C15 N5 C13 109.0(7) . .
C11 O6 Eu1 144.9(5) . .
C14 O8 Eu2 96.7(4) . .
C14 O7 Eu1 150.1(5) . .
C14 O7 Eu2 91.7(5) . .
Eu1 O7 Eu2 118.13(18) . .
C11 O5 Co1 120.1(5) . .
C1 O1 Co1 116.4(5) . .
C5 N1 C2 104.4(7) . .
C5 N1 Co1 144.6(5) . .
C2 N1 Co1 109.7(5) . .
C4 O3 Eu2 152.4(5) . 1_556
C4 O3 Eu1 90.2(5) . 1_556
Eu2 O3 Eu1 116.18(17) 1_556 1_556
C24 O16 Eu2 116.3(5) . 2_675
C4 O4 Eu1 94.4(4) . 1_556
C23 O14 Eu1 120.7(5) . 2_565
C20 N6 C19 117.9(9) . .
C17 C18 C19 117.8(9) . .
N6 C19 C18 122.5(8) . .
N6 C20 C16 125.6(8) . .
C18 C17 C16 120.7(10) . .
C10 C6 C7 117.6(8) . .
C10 C6 C5 120.4(7) . .
C7 C6 C5 122.0(8) . .
C8 C7 C6 119.6(9) . .
C5 N2 C3 108.4(7) . .
C3 C2 N1 108.8(7) . .
C3 C2 C1 136.1(7) . .
N1 C2 C1 115.0(7) . .
C2 C3 N2 105.8(6) . .
C2 C3 C4 134.0(7) . .
N2 C3 C4 119.4(7) . .
N2 C5 N1 112.4(6) . .
N2 C5 C6 124.7(8) . .
N1 C5 C6 122.7(7) . .
C1 O2 Eu2 149.8(6) . 1_556
O1 C1 O2 120.7(8) . .
O1 C1 C2 118.4(7) . .
O2 C1 C2 120.9(8) . .
C9 C8 C7 117.7(8) . .
C10 N3 C9 115.7(9) . .
C8 C9 N3 126.1(8) . .
N3 C10 C6 123.3(8) . .
C23 O13 Eu1 117.5(5) . .
C24 O15 Eu2 118.7(5) . .
O3 C4 O4 121.8(7) . .
O3 C4 C3 119.9(7) . .
O4 C4 C3 118.1(6) . .
O3 C4 Eu1 64.1(4) . 1_556
O4 C4 Eu1 59.8(4) . 1_556
C3 C4 Eu1 168.6(4) . 1_556
C21 O9 Eu1 120.6(5) . .
C22 O11 Eu1 122.9(4) . .
O10 C21 O9 130.1(7) . .
O10 C21 C22 116.3(6) . .
O9 C21 C22 113.5(6) . .
O11 C22 O12 127.4(7) . .
O11 C22 C21 118.1(5) . .
O12 C22 C21 114.5(6) . .
O12 C22 Eu1 166.4(5) . .
C21 C22 Eu1 79.1(3) . .
O16 C24 O15 127.8(7) . .
O16 C24 C24 118.7(8) . 2_675
O15 C24 C24 113.2(8) . 2_675
C24 C24 Eu2 76.2(5) 2_675 2_675
O16 C24 Eu2 163.6(6) . .
O15 C24 Eu2 41.2(4) . .
C24 C24 Eu2 74.9(5) 2_675 .
Eu2 C24 Eu2 151.1(3) 2_675 .
C21 O10 Eu2 123.1(5) . 1_455
C22 O12 Eu2 122.3(5) . 1_455
O14 C23 O13 125.4(7) . .
O14 C23 C23 115.7(9) . 2_565
O13 C23 C23 118.9(10) . 2_565
O14 C23 Eu1 167.4(6) . .
C23 C23 Eu1 76.8(7) 2_565 .
O13 C23 Eu1 165.2(6) . 2_565
C23 C23 Eu1 75.9(6) 2_565 2_565
Eu1 C23 Eu1 152.8(3) . 2_565
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O7 2.374(5) .
Eu1 O6 2.377(5) .
Eu1 O14 2.408(6) 2_565
Eu1 O13 2.434(5) .
Eu1 O11 2.442(5) .
Eu1 O9 2.473(6) .
Eu1 O3W 2.495(5) .
Eu1 O4 2.511(5) 1_554
Eu1 O3 2.607(5) 1_554
Eu1 C4 2.897(8) 1_554
Eu1 C23 3.224(9) .
Eu1 C23 3.236(9) 2_565
Eu2 O2 2.353(6) 1_554
Eu2 O3 2.391(5) 1_554
Eu2 O15 2.412(6) .
Eu2 O12 2.436(7) 1_655
Eu2 O4W 2.452(6) .
Eu2 O16 2.453(6) 2_675
Eu2 O8 2.462(5) .
Eu2 O10 2.513(4) 1_655
Eu2 O7 2.573(5) .
Eu2 C14 2.908(8) .
Eu2 C24 3.191(7) 2_675
Eu2 C24 3.211(8) .
Co1 O5 2.056(6) .
Co1 O1W 2.083(6) .
Co1 O1 2.087(6) .
Co1 N1 2.167(7) .
Co1 O2W 2.170(6) .
Co1 N4 2.201(7) .
C13 C12 1.342(12) .
C13 N5 1.352(9) .
C13 C14 1.472(11) .
C14 O7 1.282(8) .
C14 O8 1.288(10) .
C12 N4 1.358(8) .
C12 C11 1.490(12) .
C11 O6 1.251(9) .
C11 O5 1.269(11) .
C15 N5 1.323(10) .
C15 N4 1.365(10) .
C15 C16 1.462(9) .
C16 C20 1.401(13) .
C16 C17 1.401(13) .
O1 C1 1.250(11) .
N1 C5 1.351(11) .
N1 C2 1.416(8) .
O3 C4 1.254(8) .
O3 Eu2 2.391(5) 1_556
O3 Eu1 2.607(5) 1_556
O16 C24 1.226(9) .
O16 Eu2 2.453(6) 2_675
O4 C4 1.266(10) .
O4 Eu1 2.511(5) 1_556
O14 C23 1.258(11) .
O14 Eu1 2.408(6) 2_565
N6 C20 1.324(10) .
N6 C19 1.324(14) .
C18 C17 1.377(12) .
C18 C19 1.425(16) .
C6 C10 1.400(12) .
C6 C7 1.415(13) .
C6 C5 1.487(10) .
C7 C8 1.377(12) .
N2 C5 1.311(11) .
N2 C3 1.397(9) .
C2 C3 1.375(12) .
C2 C1 1.446(12) .
C3 C4 1.469(11) .
O2 C1 1.257(9) .
O2 Eu2 2.353(6) 1_556
C8 C9 1.321(15) .
N3 C10 1.320(11) .
N3 C9 1.390(13) .
O13 C23 1.269(10) .
O15 C24 1.257(9) .
C4 Eu1 2.897(8) 1_556
O9 C21 1.299(8) .
O11 C22 1.207(9) .
C21 O10 1.158(10) .
C21 C22 1.536(10) .
C22 O12 1.286(8) .
C24 C24 1.595(16) 2_675
C24 Eu2 3.191(7) 2_675
O10 Eu2 2.513(4) 1_455
O12 Eu2 2.436(7) 1_455
C23 C23 1.521(16) 2_565
C23 Eu1 3.236(9) 2_565
