#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/66/4506677.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4506677
loop_
_publ_author_name
'Cai, Song-Liang'
'Zheng, Sheng-Run'
'Wen, Zhen-Zhen'
'Fan, Jun'
'Wang, Ning'
'Zhang, Wei-Guang'
_publ_section_title
;
 Two Types of New Three-Dimensional d--f Heterometallic Coordination
 Polymers Based on 2-(Pyridin-3-yl)-1H-Imidazole-4,5-Dicarboxylate and
 Oxalate Ligands: Syntheses, Structures, Luminescence, and Magnetic
 Properties
;
_journal_issue                   9
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              4441
_journal_paper_doi               10.1021/cg300613t
_journal_volume                  12
_journal_year                    2012
_chemical_formula_moiety         'C24 H18 Fe N6 O20 Eu2, 4(H2 O)'
_chemical_formula_sum            'C24 H26 Eu2 Fe N6 O24'
_chemical_formula_weight         1142.28
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                91.875(2)
_cell_angle_beta                 110.438(2)
_cell_angle_gamma                103.068(2)
_cell_formula_units_Z            2
_cell_length_a                   10.5283(16)
_cell_length_b                   12.771(2)
_cell_length_c                   14.211(2)
_cell_measurement_reflns_used    3383
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      27.56
_cell_measurement_theta_min      2.34
_cell_volume                     1731.0(5)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.929
_diffrn_measured_fraction_theta_max 0.929
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0246
_diffrn_reflns_av_sigmaI/netI    0.0655
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            7218
_diffrn_reflns_theta_full        24.75
_diffrn_reflns_theta_max         24.75
_diffrn_reflns_theta_min         1.54
_exptl_absorpt_coefficient_mu    4.099
_exptl_absorpt_correction_T_max  0.5097
_exptl_absorpt_correction_T_min  0.4524
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.192
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1112
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.19
_refine_diff_density_max         7.446
_refine_diff_density_min         -8.438
_refine_diff_density_rms         0.639
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     514
_refine_ls_number_reflns         5501
_refine_ls_number_restraints     30
_refine_ls_restrained_S_all      1.081
_refine_ls_R_factor_all          0.2360
_refine_ls_R_factor_gt           0.1722
_refine_ls_shift/su_max          0.009
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0200P)²+400.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.3379
_refine_ls_wR_factor_ref         0.3777
_reflns_number_gt                3654
_reflns_number_total             5501
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg300613t_si_001.cif
_cod_data_source_block           Eu-Fe
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_Hall     '-P 1 '
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4506677
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.04284(5) 0.75177(4) 0.03176(4) 0.03869(15) Uani 1 1 d .
Eu2 Eu 0.41221(5) 0.74924(4) -0.02405(4) 0.03939(16) Uani 1 1 d .
Fe1 Fe 0.21670(16) 0.72414(13) 0.50315(10) 0.0469(5) Uani 1 1 d .
C13 C 0.3762(8) 0.6981(7) 0.2687(6) 0.0292(18) Uani 1 1 d U
C14 C 0.3718(11) 0.7039(8) 0.1674(8) 0.053(3) Uani 1 1 d .
C12 C 0.2988(10) 0.7239(8) 0.3247(7) 0.041(3) Uani 1 1 d .
C11 C 0.1808(10) 0.7729(7) 0.2956(7) 0.040(3) Uani 1 1 d .
C15 C 0.4706(9) 0.6696(9) 0.4238(8) 0.043(3) Uani 1 1 d .
C16 C 0.5741(9) 0.6418(8) 0.5185(8) 0.043(3) Uani 1 1 d .
N4 N 0.3612(9) 0.7052(8) 0.4223(6) 0.052(3) Uani 1 1 d .
N5 N 0.4830(8) 0.6654(7) 0.3363(6) 0.046(3) Uani 1 1 d .
H5 H 0.5481 0.6451 0.3231 0.055 Uiso 1 1 calc R
O6 O 0.1233(7) 0.7957(6) 0.2072(5) 0.047(2) Uani 1 1 d .
O8 O 0.4820(6) 0.6961(6) 0.1481(5) 0.046(2) Uani 1 1 d .
O7 O 0.2771(9) 0.7267(5) 0.0956(5) 0.062(3) Uani 1 1 d .
O5 O 0.1389(7) 0.7891(6) 0.3661(5) 0.051(2) Uani 1 1 d .
O1 O 0.2837(7) 0.6594(6) 0.6411(5) 0.050(2) Uani 1 1 d .
N1 N 0.0836(9) 0.7621(7) 0.5833(6) 0.048(3) Uani 1 1 d .
O3 O 0.1814(9) 0.7816(6) 0.9136(5) 0.057(3) Uani 1 1 d .
O16 O 0.5503(7) 1.0811(5) -0.0797(5) 0.042(2) Uani 1 1 d .
O4 O -0.0256(6) 0.8139(6) 0.8601(5) 0.048(2) Uani 1 1 d .
O14 O -0.0001(8) 0.4076(6) 0.0834(5) 0.052(3) Uani 1 1 d .
N6 N 0.7720(8) 0.5635(7) 0.5917(6) 0.046(3) Uani 1 1 d .
C18 C 0.6757(12) 0.6451(10) 0.6930(10) 0.064(4) Uani 1 1 d .
H18 H 0.6802 0.6635 0.7582 0.077 Uiso 1 1 calc R
C19 C 0.7651(11) 0.5906(8) 0.6829(8) 0.050(4) Uani 1 1 d .
H19 H 0.8253 0.5703 0.7404 0.060 Uiso 1 1 calc R
C20 C 0.6751(10) 0.5906(9) 0.5129(8) 0.051(4) Uani 1 1 d .
H20 H 0.6755 0.5736 0.4489 0.062 Uiso 1 1 calc R
C17 C 0.5780(11) 0.6756(9) 0.6148(8) 0.047(2) Uani 1 1 d U
H17 H 0.5189 0.7156 0.6243 0.057 Uiso 1 1 calc R
C6 C -0.1104(12) 0.8461(10) 0.4804(8) 0.058(4) Uani 1 1 d .
C7 C -0.1331(11) 0.7880(10) 0.3853(8) 0.053(4) Uani 1 1 d .
H7 H -0.0950 0.7298 0.3811 0.064 Uiso 1 1 calc R
N2 N -0.0252(8) 0.8336(7) 0.6647(6) 0.046(3) Uani 1 1 d .
H2 H -0.0850 0.8635 0.6757 0.055 Uiso 1 1 calc R
C2 C 0.1430(9) 0.7540(9) 0.6836(7) 0.039(3) Uani 1 1 d .
C3 C 0.0771(8) 0.7958(8) 0.7372(7) 0.035(3) Uani 1 1 d .
C5 C -0.0139(11) 0.8153(8) 0.5762(7) 0.044(3) Uani 1 1 d .
O2 O 0.3191(7) 0.6871(6) 0.8050(6) 0.055(3) Uani 1 1 d .
C1 C 0.2578(11) 0.6975(8) 0.7149(8) 0.048(3) Uani 1 1 d .
C8 C -0.2165(13) 0.8249(10) 0.2996(9) 0.068(5) Uani 1 1 d .
H8 H -0.2395 0.7894 0.2354 0.082 Uiso 1 1 calc R
N3 N -0.2414(11) 0.9652(9) 0.3991(8) 0.069(4) Uani 1 1 d .
C9 C -0.2634(14) 0.9130(10) 0.3112(9) 0.069(5) Uani 1 1 d .
H9 H -0.3147 0.9384 0.2531 0.083 Uiso 1 1 calc R
C10 C -0.1661(13) 0.9327(10) 0.4803(8) 0.064(4) Uani 1 1 d .
H10 H -0.1489 0.9706 0.5423 0.077 Uiso 1 1 calc R
O13 O 0.0331(8) 0.5857(5) 0.1096(5) 0.046(2) Uani 1 1 d .
O15 O 0.4453(7) 0.9091(5) -0.1099(5) 0.045(2) Uani 1 1 d .
C4 C 0.0817(11) 0.8030(7) 0.8404(7) 0.043(3) Uani 1 1 d .
O9 O -0.1197(6) 0.8611(6) 0.0379(5) 0.046(2) Uani 1 1 d .
O11 O -0.2003(7) 0.6545(6) -0.0201(5) 0.051(2) Uani 1 1 d .
C21 C -0.2426(10) 0.8119(8) 0.0277(8) 0.0429(15) Uani 1 1 d U
C22 C -0.2931(10) 0.6955(9) -0.0133(8) 0.0446(16) Uani 1 1 d U
C24 C 0.5025(9) 0.9995(7) -0.0551(7) 0.036(3) Uani 1 1 d .
O10 O -0.3369(7) 0.8527(6) 0.0356(5) 0.047(2) Uani 1 1 d .
O12 O -0.4228(7) 0.6503(6) -0.0357(6) 0.061(3) Uani 1 1 d .
C23 C 0.0129(11) 0.4986(8) 0.0562(8) 0.046(4) Uani 1 1 d .
O2W O 0.0776(7) 0.5650(6) 0.4419(5) 0.050(2) Uani 1 1 d .
H2WA H 0.1063 0.5088 0.4379 0.075 Uiso 1 1 d R
H2WB H 0.0042 0.5598 0.3899 0.075 Uiso 1 1 d R
O1W O 0.3530(8) 0.8747(7) 0.5727(6) 0.065(3) Uani 1 1 d .
H1WA H 0.4319 0.9052 0.5712 0.097 Uiso 1 1 d R
H1WB H 0.3271 0.9214 0.6023 0.097 Uiso 1 1 d R
O3W O 0.1686(7) 0.9435(6) 0.0605(5) 0.048(2) Uani 1 1 d .
H3WA H 0.2263 0.9650 0.1213 0.072 Uiso 1 1 d R
H3WB H 0.1595 0.9990 0.0306 0.072 Uiso 1 1 d R
O4W O 0.3086(9) 0.5547(7) -0.0426(6) 0.067(3) Uani 1 1 d .
H4WA H 0.2615 0.5127 -0.0153 0.101 Uiso 1 1 d R
H4WB H 0.3139 0.5176 -0.0920 0.101 Uiso 1 1 d R
O5W O 0.6149(10) 0.5263(8) 0.2581(7) 0.085(4) Uani 1 1 d .
H5WA H 0.5311 0.5303 0.2307 0.127 Uiso 1 1 d R
H5WB H 0.6151 0.4743 0.2944 0.127 Uiso 1 1 d R
O6W O 0.8925(10) 0.5614(10) 0.2460(7) 0.097(5) Uani 1 1 d .
H6WA H 0.9375 0.5683 0.2060 0.146 Uiso 1 1 d R
H6WB H 0.8476 0.6095 0.2382 0.146 Uiso 1 1 d R
O7W O 0.8464(10) 0.9736(7) 0.7362(7) 0.086(4) Uani 1 1 d .
H7WA H 0.8720 1.0419 0.7437 0.129 Uiso 1 1 d R
H7WB H 0.8971 0.9514 0.7892 0.129 Uiso 1 1 d R
O8W O 0.5803(12) 0.8855(12) 0.7541(9) 0.132(6) Uani 1 1 d .
H8WA H 0.5220 0.8833 0.7837 0.197 Uiso 1 1 d R
H8WB H 0.5378 0.8514 0.6957 0.197 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O6 Eu1 O11 106.2(3) . .
O6 Eu1 O7 74.5(3) . .
O11 Eu1 O7 142.2(3) . .
O6 Eu1 O13 71.3(2) . .
O11 Eu1 O13 72.3(2) . .
O7 Eu1 O13 72.5(3) . .
O6 Eu1 O14 136.1(3) . 2_565
O11 Eu1 O14 71.2(3) . 2_565
O7 Eu1 O14 82.6(2) . 2_565
O13 Eu1 O14 66.3(2) . 2_565
O6 Eu1 O3W 75.9(2) . .
O11 Eu1 O3W 134.7(3) . .
O7 Eu1 O3W 82.8(2) . .
O13 Eu1 O3W 143.0(2) . .
O14 Eu1 O3W 137.9(3) 2_565 .
O6 Eu1 O9 81.5(2) . .
O11 Eu1 O9 64.2(2) . .
O7 Eu1 O9 148.5(2) . .
O13 Eu1 O9 118.6(3) . .
O14 Eu1 O9 128.8(2) 2_565 .
O3W Eu1 O9 71.7(2) . .
O6 Eu1 O4 148.3(3) . 1_554
O11 Eu1 O4 85.6(2) . 1_554
O7 Eu1 O4 114.0(3) . 1_554
O13 Eu1 O4 140.0(2) . 1_554
O14 Eu1 O4 75.3(3) 2_565 1_554
O3W Eu1 O4 75.2(2) . 1_554
O9 Eu1 O4 77.5(3) . 1_554
O6 Eu1 O3 128.9(2) . 1_554
O11 Eu1 O3 124.7(2) . 1_554
O7 Eu1 O3 63.1(3) . 1_554
O13 Eu1 O3 117.4(3) . 1_554
O14 Eu1 O3 66.3(2) 2_565 1_554
O3W Eu1 O3 71.9(2) . 1_554
O9 Eu1 O3 122.5(3) . 1_554
O4 Eu1 O3 51.0(2) 1_554 1_554
O6 Eu1 C4 146.9(2) . 1_554
O11 Eu1 C4 104.4(3) . 1_554
O7 Eu1 C4 88.7(3) . 1_554
O13 Eu1 C4 130.9(3) . 1_554
O14 Eu1 C4 66.6(3) 2_565 1_554
O3W Eu1 C4 73.9(2) . 1_554
O9 Eu1 C4 101.2(3) . 1_554
O4 Eu1 C4 25.6(3) 1_554 1_554
O3 Eu1 C4 25.6(3) 1_554 1_554
O6 Eu1 C23 91.0(3) . .
O11 Eu1 C23 69.1(3) . .
O7 Eu1 C23 73.1(3) . .
O13 Eu1 C23 20.1(3) . .
O14 Eu1 C23 46.2(3) 2_565 .
O3W Eu1 C23 155.0(2) . .
O9 Eu1 C23 128.0(3) . .
O4 Eu1 C23 120.6(3) 1_554 .
O3 Eu1 C23 102.0(3) 1_554 .
C4 Eu1 C23 111.5(3) 1_554 .
O6 Eu1 C23 118.0(3) . 2_565
O11 Eu1 C23 67.6(3) . 2_565
O7 Eu1 C23 78.7(2) . 2_565
O13 Eu1 C23 47.4(3) . 2_565
O14 Eu1 C23 18.9(3) 2_565 2_565
O3W Eu1 C23 152.3(3) . 2_565
O9 Eu1 C23 131.4(2) . 2_565
O4 Eu1 C23 93.7(3) 1_554 2_565
O3 Eu1 C23 81.3(3) 1_554 2_565
C4 Eu1 C23 85.1(3) 1_554 2_565
C23 Eu1 C23 27.3(4) . 2_565
O2 Eu2 O3 74.3(3) 1_554 1_554
O2 Eu2 O12 79.2(3) 1_554 1_655
O3 Eu2 O12 150.9(2) 1_554 1_655
O2 Eu2 O15 74.3(2) 1_554 .
O3 Eu2 O15 77.0(3) 1_554 .
O12 Eu2 O15 107.4(3) 1_655 .
O2 Eu2 O4W 72.3(3) 1_554 .
O3 Eu2 O4W 90.3(3) 1_554 .
O12 Eu2 O4W 69.9(3) 1_655 .
O15 Eu2 O4W 146.4(2) . .
O2 Eu2 O16 136.0(3) 1_554 2_675
O3 Eu2 O16 78.3(2) 1_554 2_675
O12 Eu2 O16 130.3(2) 1_655 2_675
O15 Eu2 O16 66.4(2) . 2_675
O4W Eu2 O16 141.8(3) . 2_675
O2 Eu2 O8 145.1(3) 1_554 .
O3 Eu2 O8 114.1(3) 1_554 .
O12 Eu2 O8 81.6(3) 1_655 .
O15 Eu2 O8 139.8(2) . .
O4W Eu2 O8 73.8(2) . .
O16 Eu2 O8 77.9(2) 2_675 .
O2 Eu2 O10 113.2(3) 1_554 1_655
O3 Eu2 O10 139.5(2) 1_554 1_655
O12 Eu2 O10 63.4(2) 1_655 1_655
O15 Eu2 O10 68.0(2) . 1_655
O4W Eu2 O10 130.2(3) . 1_655
O16 Eu2 O10 69.5(2) 2_675 1_655
O8 Eu2 O10 83.1(2) . 1_655
O2 Eu2 O7 125.5(2) 1_554 .
O3 Eu2 O7 63.3(3) 1_554 .
O12 Eu2 O7 127.2(3) 1_655 .
O15 Eu2 O7 123.3(3) . .
O4W Eu2 O7 75.1(3) . .
O16 Eu2 O7 67.1(2) 2_675 .
O8 Eu2 O7 50.8(2) . .
O10 Eu2 O7 121.3(2) 1_655 .
O2 Eu2 C14 141.5(3) 1_554 .
O3 Eu2 C14 88.2(3) 1_554 .
O12 Eu2 C14 105.6(3) 1_655 .
O15 Eu2 C14 135.5(3) . .
O4W Eu2 C14 73.8(3) . .
O16 Eu2 C14 69.6(3) 2_675 .
O8 Eu2 C14 25.9(3) . .
O10 Eu2 C14 102.5(2) 1_655 .
O7 Eu2 C14 24.9(3) . .
O2 Eu2 C24 121.6(3) 1_554 2_675
O3 Eu2 C24 81.5(2) 1_554 2_675
O12 Eu2 C24 123.6(2) 1_655 2_675
O15 Eu2 C24 48.5(2) . 2_675
O4W Eu2 C24 160.5(3) . 2_675
O16 Eu2 C24 18.9(3) 2_675 2_675
O8 Eu2 C24 93.3(2) . 2_675
O10 Eu2 C24 60.3(3) 1_655 2_675
O7 Eu2 C24 85.3(2) . 2_675
C14 Eu2 C24 88.2(3) . 2_675
O2 Eu2 C24 94.8(3) 1_554 .
O3 Eu2 C24 81.9(2) 1_554 .
O12 Eu2 C24 112.6(3) 1_655 .
O15 Eu2 C24 20.5(2) . .
O4W Eu2 C24 166.4(2) . .
O16 Eu2 C24 47.3(3) 2_675 .
O8 Eu2 C24 119.5(2) . .
O10 Eu2 C24 58.2(2) 1_655 .
O7 Eu2 C24 110.7(3) . .
C14 Eu2 C24 116.9(3) . .
C24 Eu2 C24 28.7(4) 2_675 .
O1W Fe1 O1 90.0(3) . .
O1W Fe1 O5 90.8(3) . .
O1 Fe1 O5 176.7(3) . .
O1W Fe1 O2W 175.9(3) . .
O1 Fe1 O2W 86.0(3) . .
O5 Fe1 O2W 93.1(3) . .
O1W Fe1 N1 86.0(3) . .
O1 Fe1 N1 75.3(3) . .
O5 Fe1 N1 101.6(3) . .
O2W Fe1 N1 91.9(3) . .
O1W Fe1 N4 88.4(4) . .
O1 Fe1 N4 107.6(3) . .
O5 Fe1 N4 75.6(3) . .
O2W Fe1 N4 93.8(3) . .
N1 Fe1 N4 173.7(3) . .
N5 C13 C12 104.9(8) . .
N5 C13 C14 118.6(10) . .
C12 C13 C14 136.4(9) . .
O7 C14 O8 114.9(10) . .
O7 C14 C13 126.2(11) . .
O8 C14 C13 118.5(8) . .
O7 C14 Eu2 59.5(7) . .
O8 C14 Eu2 55.6(5) . .
C13 C14 Eu2 169.1(6) . .
N4 C12 C13 108.3(9) . .
N4 C12 C11 121.4(11) . .
C13 C12 C11 130.0(9) . .
O5 C11 O6 122.6(10) . .
O5 C11 C12 113.7(9) . .
O6 C11 C12 123.7(11) . .
N5 C15 N4 112.5(9) . .
N5 C15 C16 123.6(10) . .
N4 C15 C16 123.8(10) . .
C20 C16 C17 118.2(9) . .
C20 C16 C15 121.0(11) . .
C17 C16 C15 120.6(10) . .
C15 N4 C12 105.5(10) . .
C15 N4 Fe1 146.7(8) . .
C12 N4 Fe1 106.8(8) . .
C15 N5 C13 108.8(9) . .
C11 O6 Eu1 149.9(7) . .
C14 O8 Eu2 98.5(6) . .
C14 O7 Eu1 147.3(9) . .
C14 O7 Eu2 95.6(8) . .
Eu1 O7 Eu2 117.1(3) . .
C11 O5 Fe1 120.0(7) . .
C1 O1 Fe1 117.9(7) . .
C5 N1 C2 105.2(9) . .
C5 N1 Fe1 142.0(8) . .
C2 N1 Fe1 109.9(7) . .
C4 O3 Eu2 148.8(8) . 1_556
C4 O3 Eu1 94.6(7) . 1_556
Eu2 O3 Eu1 116.5(3) 1_556 1_556
C24 O16 Eu2 118.4(7) . 2_675
C4 O4 Eu1 97.5(5) . 1_556
C23 O14 Eu1 121.5(7) . 2_565
C20 N6 C19 113.9(10) . .
C19 C18 C17 124.6(13) . .
C18 C19 N6 122.7(10) . .
N6 C20 C16 125.7(11) . .
C18 C17 C16 114.5(12) . .
C10 C6 C7 118.9(10) . .
C10 C6 C5 122.5(10) . .
C7 C6 C5 118.4(12) . .
C8 C7 C6 115.3(12) . .
C5 N2 C3 107.8(9) . .
N1 C2 C3 110.9(9) . .
N1 C2 C1 117.4(10) . .
C3 C2 C1 131.6(9) . .
C2 C3 N2 104.3(8) . .
C2 C3 C4 137.5(9) . .
N2 C3 C4 118.1(9) . .
N2 C5 N1 111.6(9) . .
N2 C5 C6 121.7(11) . .
N1 C5 C6 126.6(10) . .
C1 O2 Eu2 152.2(8) . 1_556
O2 C1 O1 124.2(11) . .
O2 C1 C2 121.9(11) . .
O1 C1 C2 114.0(9) . .
C9 C8 C7 119.1(12) . .
C10 N3 C9 118.1(13) . .
N3 C9 C8 124.5(12) . .
N3 C10 C6 123.9(12) . .
C23 O13 Eu1 118.5(7) . .
C24 O15 Eu2 117.2(6) . .
O3 C4 O4 116.2(9) . .
O3 C4 C3 122.1(11) . .
O4 C4 C3 120.8(8) . .
O3 C4 Eu1 59.9(6) . 1_556
O4 C4 Eu1 56.9(5) . 1_556
C3 C4 Eu1 163.3(6) . 1_556
C21 O9 Eu1 117.9(7) . .
C22 O11 Eu1 123.7(6) . .
O10 C21 O9 127.3(10) . .
O10 C21 C22 113.7(8) . .
O9 C21 C22 118.3(11) . .
O10 C21 Eu1 168.6(6) . .
C22 C21 Eu1 77.6(6) . .
O11 C22 O12 128.3(10) . .
O11 C22 C21 114.0(9) . .
O12 C22 C21 117.7(11) . .
O12 C22 Eu1 166.1(8) . .
C21 C22 Eu1 76.1(6) . .
O16 C24 O15 126.7(10) . .
O16 C24 C24 118.4(9) . 2_675
O15 C24 C24 114.7(9) . 2_675
O15 C24 Eu2 162.8(6) . 2_675
C24 C24 Eu2 76.8(6) 2_675 2_675
O16 C24 Eu2 164.3(8) . .
C24 C24 Eu2 74.5(6) 2_675 .
Eu2 C24 Eu2 151.3(4) 2_675 .
C21 O10 Eu2 122.5(6) . 1_455
C22 O12 Eu2 122.5(7) . 1_455
O14 C23 O13 126.3(10) . .
O14 C23 C23 114.9(11) . 2_565
O13 C23 C23 118.5(11) . 2_565
O14 C23 Eu1 167.5(8) . .
C23 C23 Eu1 77.2(8) 2_565 .
O13 C23 Eu1 165.8(8) . 2_565
C23 C23 Eu1 75.5(7) 2_565 2_565
Eu1 C23 Eu1 152.7(4) . 2_565
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O6 2.339(7) .
Eu1 O11 2.414(7) .
Eu1 O7 2.413(9) .
Eu1 O13 2.422(7) .
Eu1 O14 2.424(8) 2_565
Eu1 O3W 2.451(7) .
Eu1 O9 2.462(8) .
Eu1 O4 2.502(7) 1_554
Eu1 O3 2.568(9) 1_554
Eu1 C4 2.961(11) 1_554
Eu1 C23 3.219(10) .
Eu1 C23 3.242(10) 2_565
Eu2 O2 2.313(7) 1_554
Eu2 O3 2.415(9) 1_554
Eu2 O12 2.413(8) 1_655
Eu2 O15 2.432(7) .
Eu2 O4W 2.442(8) .
Eu2 O16 2.453(7) 2_675
Eu2 O8 2.462(7) .
Eu2 O10 2.495(6) 1_655
Eu2 O7 2.555(10) .
Eu2 C14 2.952(12) .
Eu2 C24 3.182(8) 2_675
Eu2 C24 3.214(9) .
Fe1 O1W 2.090(8) .
Fe1 O1 2.105(7) .
Fe1 O5 2.110(7) .
Fe1 O2W 2.163(7) .
Fe1 N1 2.209(11) .
Fe1 N4 2.250(11) .
C13 N5 1.359(12) .
C13 C12 1.401(16) .
C13 C14 1.430(15) .
C14 O7 1.250(12) .
C14 O8 1.306(15) .
C12 N4 1.366(13) .
C12 C11 1.455(15) .
C11 O5 1.257(14) .
C11 O6 1.265(11) .
C15 N5 1.296(15) .
C15 N4 1.324(15) .
C15 C16 1.520(14) .
C16 C20 1.391(16) .
C16 C17 1.404(17) .
O1 C1 1.279(15) .
N1 C5 1.332(16) .
N1 C2 1.360(12) .
O3 C4 1.282(12) .
O3 Eu2 2.415(9) 1_556
O3 Eu1 2.568(9) 1_556
O16 C24 1.171(11) .
O16 Eu2 2.453(7) 2_675
O4 C4 1.290(15) .
O4 Eu1 2.502(7) 1_556
O14 C23 1.231(13) .
O14 Eu1 2.424(8) 2_565
N6 C20 1.342(13) .
N6 C19 1.360(16) .
C18 C19 1.333(19) .
C18 C17 1.363(16) .
C6 C10 1.36(2) .
C6 C7 1.436(17) .
C6 C5 1.514(15) .
C7 C8 1.399(16) .
N2 C5 1.322(14) .
N2 C3 1.396(12) .
C2 C3 1.362(15) .
C2 C1 1.490(16) .
C3 C4 1.449(14) .
O2 C1 1.244(12) .
O2 Eu2 2.313(7) 1_556
C8 C9 1.35(2) .
N3 C10 1.295(15) .
N3 C9 1.315(17) .
O13 C23 1.259(13) .
O15 C24 1.265(10) .
C4 Eu1 2.961(11) 1_556
O9 C21 1.259(12) .
O11 C22 1.238(15) .
C21 O10 1.256(14) .
C21 C22 1.483(14) .
C22 O12 1.275(12) .
C24 C24 1.59(2) 2_675
C24 Eu2 3.182(8) 2_675
O10 Eu2 2.495(6) 1_455
O12 Eu2 2.413(8) 1_455
C23 C23 1.53(2) 2_565
C23 Eu1 3.242(10) 2_565
