#------------------------------------------------------------------------------
#$Date: 2016-03-24 02:53:39 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179602 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/66/4506682.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4506682
loop_
_publ_author_name
'Cai, Song-Liang'
'Zheng, Sheng-Run'
'Wen, Zhen-Zhen'
'Fan, Jun'
'Wang, Ning'
'Zhang, Wei-Guang'
_publ_section_title
;
 Two Types of New Three-Dimensional d--f Heterometallic Coordination
 Polymers Based on 2-(Pyridin-3-yl)-1H-Imidazole-4,5-Dicarboxylate and
 Oxalate Ligands: Syntheses, Structures, Luminescence, and Magnetic
 Properties
;
_journal_issue                   9
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              4441
_journal_paper_doi               10.1021/cg300613t
_journal_volume                  12
_journal_year                    2012
_chemical_formula_moiety         'C22 H13 Ag3 Dy2 N6 O15'
_chemical_formula_sum            'C22 H13 Ag3 Dy2 N6 O15'
_chemical_formula_weight         1249.99
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 117.257(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   8.4705(10)
_cell_length_b                   23.577(3)
_cell_length_c                   15.4220(14)
_cell_measurement_reflns_used    7436
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      27.87
_cell_measurement_theta_min      2.57
_cell_volume                     2737.9(6)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.962
_diffrn_measured_fraction_theta_max 0.962
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0420
_diffrn_reflns_av_sigmaI/netI    0.0481
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            19038
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.72
_exptl_absorpt_coefficient_mu    7.589
_exptl_absorpt_correction_T_max  0.2742
_exptl_absorpt_correction_T_min  0.1950
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Sheldrick, 1996)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    3.032
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2320
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.26
_exptl_crystal_size_min          0.23
_refine_diff_density_max         4.867
_refine_diff_density_min         -5.445
_refine_diff_density_rms         0.720
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     433
_refine_ls_number_reflns         4642
_refine_ls_number_restraints     144
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.1395
_refine_ls_R_factor_gt           0.1127
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0100P)²+668.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2386
_refine_ls_wR_factor_ref         0.2578
_reflns_number_gt                3618
_reflns_number_total             4642
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg300613t_si_001.cif
_cod_data_source_block           Dy-Ag
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        2737.9(5)
_cod_original_sg_symbol_H-M      P2(1)/c
_cod_database_code               4506682
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Dy1 Dy 0.50042(18) 0.75979(6) 0.34454(10) 0.0277(4) Uani 1 1 d .
Dy2 Dy 0.65927(18) 0.77703(6) 0.64865(10) 0.0265(4) Uani 1 1 d .
Ag1 Ag 0.4883(4) 1.01763(10) 0.72655(17) 0.0384(6) Uani 1 1 d .
Ag2 Ag 0.1802(4) 0.93400(11) 0.27519(17) 0.0443(7) Uani 1 1 d .
Ag3 Ag -0.2633(4) 1.07052(12) 0.17925(18) 0.0494(8) Uani 1 1 d .
O1 O 0.432(3) 0.8635(10) 0.3506(15) 0.040(6) Uani 1 1 d .
O1W O 0.330(3) 0.7801(11) 0.5579(16) 0.046(6) Uani 1 1 d .
H1WB H 0.2228 0.7860 0.5157 0.068 Uiso 1 1 d R
H1WA H 0.3349 0.7836 0.6140 0.068 Uiso 1 1 d R
O2 O 0.582(2) 0.8198(8) 0.4919(14) 0.026(4) Uani 1 1 d U
O2W O 0.816(3) 0.7575(10) 0.4324(15) 0.042(6) Uani 1 1 d .
H2WA H 0.8882 0.7552 0.4085 0.062 Uiso 1 1 d R
H2WB H 0.8761 0.7615 0.4938 0.062 Uiso 1 1 d R
O3 O 0.762(2) 0.8693(8) 0.6749(12) 0.023(4) Uani 1 1 d U
O4 O 0.753(3) 0.9537(9) 0.7377(17) 0.042(6) Uani 1 1 d .
O5 O 0.432(3) 0.6639(9) 0.3873(14) 0.032(5) Uani 1 1 d U
O6 O 0.588(3) 0.7069(9) 0.5246(14) 0.032(5) Uani 1 1 d .
O7 O 0.577(2) 0.8048(8) 0.2174(14) 0.027(4) Uani 1 1 d .
O8 O 0.738(3) 0.8824(11) 0.2796(16) 0.051(6) Uani 1 1 d .
O9 O -0.055(3) 0.7472(11) 0.3041(13) 0.039(6) Uani 1 1 d .
O10 O -0.066(3) 0.7373(10) 0.1275(15) 0.046(6) Uani 1 1 d .
O11 O 0.222(3) 0.7560(10) 0.1923(16) 0.041(6) Uani 1 1 d .
O12 O 0.230(3) 0.7646(10) 0.3731(17) 0.047(6) Uani 1 1 d U
O13 O 0.567(3) 0.6926(9) 0.2627(15) 0.034(5) Uani 1 1 d U
H13 H 0.6530 0.7050 0.2588 0.041 Uiso 1 1 d R
N1 N 0.415(3) 0.9767(10) 0.5870(16) 0.024(5) Uani 1 1 d U
N2 N 0.294(3) 0.9422(9) 0.4326(16) 0.022(5) Uani 1 1 d U
N3 N -0.123(3) 1.0622(11) 0.335(2) 0.038(6) Uani 1 1 d U
N4 N 0.351(4) 0.5737(11) 0.4741(17) 0.034(6) Uani 1 1 d .
N5 N 0.445(3) 0.5556(10) 0.6346(17) 0.031(6) Uani 1 1 d .
N6 N -0.004(4) 0.4353(10) 0.3805(19) 0.038(6) Uani 1 1 d .
C1 C 0.486(4) 0.8603(11) 0.443(2) 0.027(4) Uani 1 1 d U
C2 C 0.435(4) 0.9105(11) 0.489(2) 0.026(4) Uani 1 1 d U
C3 C 0.518(4) 0.9307(11) 0.584(2) 0.026(4) Uani 1 1 d U
C4 C 0.688(4) 0.9168(11) 0.670(2) 0.026(4) Uani 1 1 d U
C5 C 0.282(4) 0.9811(12) 0.493(2) 0.028(4) Uani 1 1 d U
C6 C 0.144(4) 1.0251(12) 0.461(2) 0.029(3) Uani 1 1 d U
C7 C 0.152(4) 1.0688(12) 0.523(2) 0.032(4) Uani 1 1 d U
H7 H 0.2444 1.0718 0.5859 0.038 Uiso 1 1 calc R
C8 C 0.011(4) 1.1087(13) 0.484(2) 0.032(4) Uani 1 1 d U
H8 H 0.0090 1.1382 0.5237 0.039 Uiso 1 1 calc R
C9 C -0.120(4) 1.1050(13) 0.391(2) 0.035(5) Uani 1 1 d U
H9 H -0.2079 1.1326 0.3672 0.042 Uiso 1 1 calc R
C10 C 0.003(4) 1.0223(12) 0.368(2) 0.031(4) Uani 1 1 d U
H10 H -0.0040 0.9919 0.3281 0.038 Uiso 1 1 calc R
C11 C 0.494(4) 0.6671(12) 0.477(2) 0.027(4) Uani 1 1 d U
C12 C 0.450(4) 0.6189(13) 0.527(2) 0.029(4) Uani 1 1 d U
C13 C 0.500(4) 0.6068(13) 0.624(2) 0.031(5) Uani 1 1 d U
C14 C 0.615(3) 0.8568(12) 0.2138(19) 0.023(6) Uani 1 1 d .
C15 C 0.344(4) 0.5389(13) 0.540(2) 0.034(5) Uani 1 1 d U
C16 C 0.234(4) 0.4848(13) 0.509(2) 0.034(4) Uani 1 1 d U
C17 C 0.257(4) 0.4393(13) 0.571(2) 0.036(4) Uani 1 1 d U
H17 H 0.3468 0.4398 0.6353 0.044 Uiso 1 1 calc R
C18 C 0.146(4) 0.3935(14) 0.536(2) 0.037(4) Uani 1 1 d U
H18 H 0.1574 0.3634 0.5772 0.045 Uiso 1 1 calc R
C19 C 0.018(5) 0.3913(14) 0.441(2) 0.040(5) Uani 1 1 d U
H19 H -0.0536 0.3594 0.4185 0.048 Uiso 1 1 calc R
C20 C 0.093(4) 0.4812(14) 0.413(2) 0.036(5) Uani 1 1 d U
H20 H 0.0677 0.5124 0.3721 0.044 Uiso 1 1 calc R
C21 C 0.080(4) 0.7539(12) 0.298(2) 0.033(5) Uani 1 1 d U
C22 C 0.081(4) 0.7496(12) 0.196(2) 0.034(5) Uani 1 1 d U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O13 Dy1 O2W 78.5(7) . .
O13 Dy1 O11 79.3(7) . .
O2W Dy1 O11 151.8(6) . .
O13 Dy1 O2 151.1(7) . .
O2W Dy1 O2 74.0(6) . .
O11 Dy1 O2 129.5(7) . .
O13 Dy1 O5 70.0(7) . .
O2W Dy1 O5 99.5(8) . .
O11 Dy1 O5 89.0(7) . .
O2 Dy1 O5 105.9(6) . .
O13 Dy1 O1 145.4(7) . .
O2W Dy1 O1 102.6(8) . .
O11 Dy1 O1 86.3(8) . .
O2 Dy1 O1 52.3(6) . .
O5 Dy1 O1 141.5(7) . .
O13 Dy1 O12 127.5(8) . .
O2W Dy1 O12 140.7(7) . .
O11 Dy1 O12 67.4(7) . .
O2 Dy1 O12 73.1(7) . .
O5 Dy1 O12 69.9(7) . .
O1 Dy1 O12 73.0(7) . .
O13 Dy1 O7 69.3(7) . .
O2W Dy1 O7 80.4(7) . .
O11 Dy1 O7 75.7(6) . .
O2 Dy1 O7 113.7(6) . .
O5 Dy1 O7 138.4(6) . .
O1 Dy1 O7 76.7(6) . .
O12 Dy1 O7 133.1(7) . .
O13 Dy1 O6 102.7(7) . .
O2W Dy1 O6 73.0(6) . .
O11 Dy1 O6 129.2(6) . .
O2 Dy1 O6 60.9(6) . .
O5 Dy1 O6 47.7(6) . .
O1 Dy1 O6 110.7(6) . .
O12 Dy1 O6 72.5(7) . .
O7 Dy1 O6 153.3(6) . .
O13 Dy1 Dy2 32.0(5) . 4_575
O2W Dy1 Dy2 75.1(5) . 4_575
O11 Dy1 Dy2 76.9(4) . 4_575
O2 Dy1 Dy2 141.2(4) . 4_575
O5 Dy1 Dy2 101.8(4) . 4_575
O1 Dy1 Dy2 114.1(5) . 4_575
O12 Dy1 Dy2 143.3(5) . 4_575
O7 Dy1 Dy2 37.5(4) . 4_575
O6 Dy1 Dy2 129.2(4) . 4_575
O3 Dy2 O13 78.9(6) . 4_576
O3 Dy2 O6 136.9(6) . .
O13 Dy2 O6 139.9(7) 4_576 .
O3 Dy2 O2 72.0(6) . .
O13 Dy2 O2 126.3(7) 4_576 .
O6 Dy2 O2 68.5(7) . .
O3 Dy2 O7 145.5(6) . 4_576
O13 Dy2 O7 70.0(6) 4_576 4_576
O6 Dy2 O7 77.5(7) . 4_576
O2 Dy2 O7 139.5(7) . 4_576
O3 Dy2 O1W 107.8(7) . .
O13 Dy2 O1W 74.8(7) 4_576 .
O6 Dy2 O1W 76.3(7) . .
O2 Dy2 O1W 72.8(7) . .
O7 Dy2 O1W 78.4(7) 4_576 .
O3 Dy2 O10 81.6(7) . 4_676
O13 Dy2 O10 141.8(7) 4_576 4_676
O6 Dy2 O10 73.3(6) . 4_676
O2 Dy2 O10 76.7(7) . 4_676
O7 Dy2 O10 114.4(7) 4_576 4_676
O1W Dy2 O10 142.9(6) . 4_676
O3 Dy2 O9 85.9(7) . 4_676
O13 Dy2 O9 82.1(7) 4_576 4_676
O6 Dy2 O9 112.2(7) . 4_676
O2 Dy2 O9 137.3(6) . 4_676
O7 Dy2 O9 75.7(7) 4_576 4_676
O1W Dy2 O9 149.9(7) . 4_676
O10 Dy2 O9 64.0(7) 4_676 4_676
O3 Dy2 Dy1 107.9(4) . 4_576
O13 Dy2 Dy1 30.6(5) 4_576 4_576
O6 Dy2 Dy1 114.4(5) . 4_576
O2 Dy2 Dy1 146.1(4) . 4_576
O7 Dy2 Dy1 39.5(4) 4_576 4_576
O1W Dy2 Dy1 75.4(5) . 4_576
O10 Dy2 Dy1 137.2(5) 4_676 4_576
O9 Dy2 Dy1 74.9(4) 4_676 4_576
O3 Dy2 H1WA 105.2 . .
O13 Dy2 H1WA 55.9 4_576 .
O6 Dy2 H1WA 91.3 . .
O2 Dy2 H1WA 89.5 . .
O7 Dy2 H1WA 69.3 4_576 .
O1W Dy2 H1WA 19.4 . .
O10 Dy2 H1WA 162.2 4_676 .
O9 Dy2 H1WA 132.1 4_676 .
Dy1 Dy2 H1WA 57.2 4_576 .
N5 Ag1 N1 177.9(10) 2_656 .
N5 Ag1 Ag2 91.7(7) 2_656 3_676
N1 Ag1 Ag2 90.1(6) . 3_676
N6 Ag2 N2 164.6(10) 2 .
N6 Ag2 O1 121.7(8) 2 .
N2 Ag2 O1 72.2(7) . .
N6 Ag2 Ag1 98.8(8) 2 3_676
N2 Ag2 Ag1 92.1(6) . 3_676
O1 Ag2 Ag1 70.3(5) . 3_676
N4 Ag3 N3 168.0(10) 2 .
N4 Ag3 O5 71.3(8) 2 2
N3 Ag3 O5 116.5(8) . 2
C1 O1 Dy1 90.8(16) . .
C1 O1 Ag2 110.2(17) . .
Dy1 O1 Ag2 141.2(11) . .
Dy2 O1W H1WB 164.5 . .
Dy2 O1W H1WA 84.7 . .
H1WB O1W H1WA 107.7 . .
C1 O2 Dy2 136.3(17) . .
C1 O2 Dy1 93.0(16) . .
Dy2 O2 Dy1 120.7(8) . .
Dy1 O2W H2WA 126.9 . .
Dy1 O2W H2WB 125.3 . .
H2WA O2W H2WB 107.7 . .
C4 O3 Dy2 133.4(17) . .
C11 O5 Dy1 102.1(18) . .
C11 O5 Ag3 111.8(18) . 2_545
Dy1 O5 Ag3 145.6(8) . 2_545
C11 O6 Dy2 149.5(19) . .
C11 O6 Dy1 86.7(17) . .
Dy2 O6 Dy1 109.8(8) . .
C14 O7 Dy2 127.8(16) . 4_575
C14 O7 Dy1 126.1(17) . .
Dy2 O7 Dy1 103.1(7) 4_575 .
C21 O9 Dy2 118.5(19) . 4_475
C22 O10 Dy2 123(2) . 4_475
C22 O11 Dy1 119(2) . .
C21 O12 Dy1 115.4(19) . .
Dy1 O13 Dy2 117.4(9) . 4_575
Dy1 O13 H13 104.4 . .
Dy2 O13 H13 38.2 4_575 .
C5 N1 C3 104(2) . .
C5 N1 Ag1 137.3(19) . .
C3 N1 Ag1 118.5(18) . .
C2 N2 C5 105(2) . .
C2 N2 Ag2 119.3(18) . .
C5 N2 Ag2 134.5(19) . .
C9 N3 C10 121(3) . .
C9 N3 Ag3 120(2) . .
C10 N3 Ag3 116(2) . .
C15 N4 C12 105(2) . .
C15 N4 Ag3 136(2) . 2_545
C12 N4 Ag3 119.5(19) . 2_545
C13 N5 C15 102(2) . .
C13 N5 Ag1 124(2) . 2_646
C15 N5 Ag1 134.0(19) . 2_646
C20 N6 C19 120(3) . .
C20 N6 Ag2 115(2) . 2_545
C19 N6 Ag2 124(2) . 2_545
O2 C1 O1 121(2) . .
O2 C1 C2 123(3) . .
O1 C1 C2 116(3) . .
N2 C2 C3 112(2) . .
N2 C2 C1 119(2) . .
C3 C2 C1 129(3) . .
C2 C3 N1 106(3) . .
C2 C3 C4 134(3) . .
N1 C3 C4 120(2) . .
O3 C4 O4 123(3) . .
O3 C4 C3 120(2) . .
O4 C4 C3 117(3) . .
N2 C5 N1 113(3) . .
N2 C5 C6 123(3) . .
N1 C5 C6 124(2) . .
C10 C6 C7 120(3) . .
C10 C6 C5 120(3) . .
C7 C6 C5 120(3) . .
C6 C7 C8 116(3) . .
C6 C7 H7 122.1 . .
C8 C7 H7 122.1 . .
C9 C8 C7 122(3) . .
C9 C8 H8 119.1 . .
C7 C8 H8 119.1 . .
N3 C9 C8 120(3) . .
N3 C9 H9 119.8 . .
C8 C9 H9 119.8 . .
N3 C10 C6 122(3) . .
N3 C10 H10 119.2 . .
C6 C10 H10 119.2 . .
O6 C11 O5 123(3) . .
O6 C11 C12 121(2) . .
O5 C11 C12 116(3) . .
N4 C12 C13 106(3) . .
N4 C12 C11 121(2) . .
C13 C12 C11 133(3) . .
N5 C13 C12 112(3) . .
N5 C13 C14 120(3) . 4_576
C12 C13 C14 128(3) . 4_576
O8 C14 O7 125(3) . .
O8 C14 C13 115(3) . 4_575
O7 C14 C13 121(2) . 4_575
N4 C15 N5 114(3) . .
N4 C15 C16 121(3) . .
N5 C15 C16 125(3) . .
C17 C16 C20 117(3) . .
C17 C16 C15 124(3) . .
C20 C16 C15 119(3) . .
C18 C17 C16 119(3) . .
C18 C17 H17 120.7 . .
C16 C17 H17 120.7 . .
C19 C18 C17 121(3) . .
C19 C18 H18 119.3 . .
C17 C18 H18 119.3 . .
N6 C19 C18 120(3) . .
N6 C19 H19 119.8 . .
C18 C19 H19 119.8 . .
N6 C20 C16 122(3) . .
N6 C20 H20 118.9 . .
C16 C20 H20 118.9 . .
O9 C21 O12 122(3) . .
O9 C21 C22 121(3) . .
O12 C21 C22 117(3) . .
O11 C22 O10 127(3) . .
O11 C22 C21 119(3) . .
O10 C22 C21 114(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Dy1 O13 2.25(2) .
Dy1 O2W 2.38(2) .
Dy1 O11 2.45(2) .
Dy1 O2 2.49(2) .
Dy1 O5 2.49(2) .
Dy1 O1 2.52(2) .
Dy1 O12 2.53(2) .
Dy1 O7 2.563(18) .
Dy1 O6 2.82(2) .
Dy2 O3 2.309(19) .
Dy2 O13 2.34(2) 4_576
Dy2 O6 2.388(19) .
Dy2 O2 2.416(18) .
Dy2 O7 2.451(19) 4_576
Dy2 O1W 2.49(2) .
Dy2 O10 2.52(2) 4_676
Dy2 O9 2.57(2) 4_676
Dy2 H1WA 2.5526 .
Ag1 N5 2.14(2) 2_656
Ag1 N1 2.17(2) .
Ag1 Ag2 3.042(4) 3_676
Ag2 N6 2.17(3) 2
Ag2 N2 2.17(2) .
Ag2 O1 2.53(2) .
Ag2 Ag1 3.043(4) 3_676
Ag3 N4 2.13(2) 2
Ag3 N3 2.14(3) .
Ag3 O5 2.57(2) 2
O1 C1 1.29(3) .
O1W H1WB 0.8499 .
O1W H1WA 0.8499 .
O2 C1 1.25(3) .
O2W H2WA 0.8500 .
O2W H2WB 0.8500 .
O3 C4 1.26(3) .
O4 C4 1.27(3) .
O5 C11 1.24(3) .
O5 Ag3 2.57(2) 2_545
O6 C11 1.23(3) .
O7 C14 1.27(3) .
O7 Dy2 2.451(19) 4_575
O8 C14 1.23(3) .
O9 C21 1.21(4) .
O9 Dy2 2.571(19) 4_475
O10 C22 1.24(4) .
O10 Dy2 2.52(2) 4_475
O11 C22 1.23(4) .
O12 C21 1.29(4) .
O13 Dy2 2.34(2) 4_575
O13 H13 0.8163 .
N1 C5 1.37(4) .
N1 C3 1.41(4) .
N2 C2 1.34(4) .
N2 C5 1.35(3) .
N3 C9 1.33(4) .
N3 C10 1.34(4) .
N4 C15 1.33(4) .
N4 C12 1.37(4) .
N4 Ag3 2.13(2) 2_545
N5 C13 1.33(4) .
N5 C15 1.37(4) .
N5 Ag1 2.14(2) 2_646
N6 C20 1.31(4) .
N6 C19 1.35(4) .
N6 Ag2 2.17(3) 2_545
C1 C2 1.54(4) .
C2 C3 1.38(4) .
C3 C4 1.48(4) .
C5 C6 1.47(4) .
C6 C10 1.38(4) .
C6 C7 1.39(4) .
C7 C8 1.42(4) .
C7 H7 0.9300 .
C8 C9 1.35(4) .
C8 H8 0.9300 .
C9 H9 0.9300 .
C10 H10 0.9300 .
C11 C12 1.51(4) .
C12 C13 1.38(4) .
C13 C14 1.54(4) 4_576
C14 C13 1.54(4) 4_575
C15 C16 1.52(4) .
C16 C17 1.39(4) .
C16 C20 1.42(4) .
C17 C18 1.37(4) .
C17 H17 0.9300 .
C18 C19 1.36(4) .
C18 H18 0.9300 .
C19 H19 0.9300 .
C20 H20 0.9300 .
C21 C22 1.58(4) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O13 Dy1 O1 C1 -155.4(16) . .
O2W Dy1 O1 C1 -67.5(17) . .
O11 Dy1 O1 C1 139.6(17) . .
O2 Dy1 O1 C1 -9.4(15) . .
O5 Dy1 O1 C1 56(2) . .
O12 Dy1 O1 C1 72.0(17) . .
O7 Dy1 O1 C1 -144.3(18) . .
O6 Dy1 O1 C1 8.8(18) . .
Dy2 Dy1 O1 C1 -146.6(15) 4_575 .
O13 Dy1 O1 Ag2 80.0(19) . .
O2W Dy1 O1 Ag2 167.9(13) . .
O11 Dy1 O1 Ag2 14.9(13) . .
O2 Dy1 O1 Ag2 -134.1(17) . .
O5 Dy1 O1 Ag2 -68.7(17) . .
O12 Dy1 O1 Ag2 -52.6(13) . .
O7 Dy1 O1 Ag2 91.1(13) . .
O6 Dy1 O1 Ag2 -115.8(13) . .
Dy2 Dy1 O1 Ag2 88.8(13) 4_575 .
N6 Ag2 O1 C1 -162.8(19) 2 .
N2 Ag2 O1 C1 9.9(19) . .
Ag1 Ag2 O1 C1 109(2) 3_676 .
N6 Ag2 O1 Dy1 -44.0(18) 2 .
N2 Ag2 O1 Dy1 128.7(15) . .
Ag1 Ag2 O1 Dy1 -132.3(14) 3_676 .
O3 Dy2 O2 C1 -63(3) . .
O13 Dy2 O2 C1 -2(3) 4_576 .
O6 Dy2 O2 C1 135(3) . .
O7 Dy2 O2 C1 100(3) 4_576 .
O1W Dy2 O2 C1 53(3) . .
O10 Dy2 O2 C1 -148(3) 4_676 .
O9 Dy2 O2 C1 -125(3) 4_676 .
Dy1 Dy2 O2 C1 33(3) 4_576 .
O3 Dy2 O2 Dy1 162.0(10) . .
O13 Dy2 O2 Dy1 -137.3(8) 4_576 .
O6 Dy2 O2 Dy1 -0.2(7) . .
O7 Dy2 O2 Dy1 -35.4(13) 4_576 .
O1W Dy2 O2 Dy1 -82.0(9) . .
O10 Dy2 O2 Dy1 76.7(9) 4_676 .
O9 Dy2 O2 Dy1 99.7(12) 4_676 .
Dy1 Dy2 O2 Dy1 -102.5(9) 4_576 .
O13 Dy1 O2 C1 148.4(17) . .
O2W Dy1 O2 C1 130.2(16) . .
O11 Dy1 O2 C1 -32.1(18) . .
O5 Dy1 O2 C1 -134.3(15) . .
O1 Dy1 O2 C1 9.7(15) . .
O12 Dy1 O2 C1 -71.7(16) . .
O7 Dy1 O2 C1 58.6(16) . .
O6 Dy1 O2 C1 -150.7(17) . .
Dy2 Dy1 O2 C1 91.7(16) 4_575 .
O13 Dy1 O2 Dy2 -60.6(17) . .
O2W Dy1 O2 Dy2 -78.9(9) . .
O11 Dy1 O2 Dy2 118.8(9) . .
O5 Dy1 O2 Dy2 16.6(10) . .
O1 Dy1 O2 Dy2 160.6(12) . .
O12 Dy1 O2 Dy2 79.3(9) . .
O7 Dy1 O2 Dy2 -150.5(7) . .
O6 Dy1 O2 Dy2 0.2(7) . .
Dy2 Dy1 O2 Dy2 -117.3(7) 4_575 .
O13 Dy2 O3 C4 -54(2) 4_576 .
O6 Dy2 O3 C4 105(2) . .
O2 Dy2 O3 C4 80(2) . .
O7 Dy2 O3 C4 -80(2) 4_576 .
O1W Dy2 O3 C4 16(2) . .
O10 Dy2 O3 C4 159(2) 4_676 .
O9 Dy2 O3 C4 -137(2) 4_676 .
Dy1 Dy2 O3 C4 -64(2) 4_576 .
O13 Dy1 O5 C11 135.5(19) . .
O2W Dy1 O5 C11 61.5(18) . .
O11 Dy1 O5 C11 -145.5(18) . .
O2 Dy1 O5 C11 -14.5(19) . .
O1 Dy1 O5 C11 -63(2) . .
O12 Dy1 O5 C11 -79.2(18) . .
O7 Dy1 O5 C11 147.6(16) . .
O6 Dy1 O5 C11 5.0(16) . .
Dy2 Dy1 O5 C11 138.0(17) 4_575 .
O13 Dy1 O5 Ag3 -54.5(15) . 2_545
O2W Dy1 O5 Ag3 -128.5(15) . 2_545
O11 Dy1 O5 Ag3 24.5(16) . 2_545
O2 Dy1 O5 Ag3 155.5(14) . 2_545
O1 Dy1 O5 Ag3 107.2(16) . 2_545
O12 Dy1 O5 Ag3 90.8(16) . 2_545
O7 Dy1 O5 Ag3 -42(2) . 2_545
O6 Dy1 O5 Ag3 175(2) . 2_545
Dy2 Dy1 O5 Ag3 -51.9(16) 4_575 2_545
O3 Dy2 O6 C11 -144(4) . .
O13 Dy2 O6 C11 2(4) 4_576 .
O2 Dy2 O6 C11 -119(4) . .
O7 Dy2 O6 C11 38(4) 4_576 .
O1W Dy2 O6 C11 -43(4) . .
O10 Dy2 O6 C11 159(4) 4_676 .
O9 Dy2 O6 C11 107(4) 4_676 .
Dy1 Dy2 O6 C11 24(4) 4_576 .
O3 Dy2 O6 Dy1 -24.8(12) . .
O13 Dy2 O6 Dy1 121.6(10) 4_576 .
O2 Dy2 O6 Dy1 0.2(6) . .
O7 Dy2 O6 Dy1 157.7(8) 4_576 .
O1W Dy2 O6 Dy1 76.8(8) . .
O10 Dy2 O6 Dy1 -81.8(8) 4_676 .
O9 Dy2 O6 Dy1 -133.6(7) 4_676 .
Dy1 Dy2 O6 Dy1 143.4(4) 4_576 .
O13 Dy1 O6 C11 -52.0(17) . .
O2W Dy1 O6 C11 -125.6(17) . .
O11 Dy1 O6 C11 34.4(19) . .
O2 Dy1 O6 C11 153.6(18) . .
O5 Dy1 O6 C11 -4.9(16) . .
O1 Dy1 O6 C11 137.1(17) . .
O12 Dy1 O6 C11 73.6(17) . .
O7 Dy1 O6 C11 -121.2(18) . .
Dy2 Dy1 O6 C11 -72.3(17) 4_575 .
O13 Dy1 O6 Dy2 154.2(8) . .
O2W Dy1 O6 Dy2 80.6(8) . .
O11 Dy1 O6 Dy2 -119.3(9) . .
O2 Dy1 O6 Dy2 -0.2(6) . .
O5 Dy1 O6 Dy2 -158.7(12) . .
O1 Dy1 O6 Dy2 -16.7(10) . .
O12 Dy1 O6 Dy2 -80.2(8) . .
O7 Dy1 O6 Dy2 85.1(15) . .
Dy2 Dy1 O6 Dy2 133.9(5) 4_575 .
O13 Dy1 O7 C14 -165(2) . .
O2W Dy1 O7 C14 -83(2) . .
O11 Dy1 O7 C14 112(2) . .
O2 Dy1 O7 C14 -16(2) . .
O5 Dy1 O7 C14 -176.7(19) . .
O1 Dy1 O7 C14 22(2) . .
O12 Dy1 O7 C14 73(2) . .
O6 Dy1 O7 C14 -88(2) . .
Dy2 Dy1 O7 C14 -161(2) 4_575 .
O13 Dy1 O7 Dy2 -3.3(7) . 4_575
O2W Dy1 O7 Dy2 78.0(8) . 4_575
O11 Dy1 O7 Dy2 -87.1(8) . 4_575
O2 Dy1 O7 Dy2 145.7(6) . 4_575
O5 Dy1 O7 Dy2 -15.4(13) . 4_575
O1 Dy1 O7 Dy2 -176.6(9) . 4_575
O12 Dy1 O7 Dy2 -125.8(8) . 4_575
O6 Dy1 O7 Dy2 73.6(15) . 4_575
O13 Dy1 O11 C22 128(2) . .
O2W Dy1 O11 C22 166(2) . .
O2 Dy1 O11 C22 -52(3) . .
O5 Dy1 O11 C22 58(2) . .
O1 Dy1 O11 C22 -84(2) . .
O12 Dy1 O11 C22 -11(2) . .
O7 Dy1 O11 C22 -161(2) . .
O6 Dy1 O11 C22 30(3) . .
Dy2 Dy1 O11 C22 160(2) 4_575 .
O13 Dy1 O12 C21 -45(2) . .
O2W Dy1 O12 C21 -167.3(19) . .
O11 Dy1 O12 C21 10(2) . .
O2 Dy1 O12 C21 158(2) . .
O5 Dy1 O12 C21 -87(2) . .
O1 Dy1 O12 C21 104(2) . .
O7 Dy1 O12 C21 51(2) . .
O6 Dy1 O12 C21 -138(2) . .
Dy2 Dy1 O12 C21 -4(3) 4_575 .
O2W Dy1 O13 Dy2 -80.2(10) . 4_575
O11 Dy1 O13 Dy2 82.4(10) . 4_575
O2 Dy1 O13 Dy2 -98.1(14) . 4_575
O5 Dy1 O13 Dy2 175.2(11) . 4_575
O1 Dy1 O13 Dy2 15.3(19) . 4_575
O12 Dy1 O13 Dy2 132.9(10) . 4_575
O7 Dy1 O13 Dy2 3.8(8) . 4_575
O6 Dy1 O13 Dy2 -149.6(8) . 4_575
Ag2 Ag1 N1 C5 -114(3) 3_676 .
Ag2 Ag1 N1 C3 69.9(18) 3_676 .
N6 Ag2 N2 C2 158(3) 2 .
O1 Ag2 N2 C2 2.2(19) . .
Ag1 Ag2 N2 C2 -66.3(19) 3_676 .
N6 Ag2 N2 C5 -38(5) 2 .
O1 Ag2 N2 C5 166(3) . .
Ag1 Ag2 N2 C5 97(2) 3_676 .
N4 Ag3 N3 C9 126(5) 2 .
O5 Ag3 N3 C9 -3(3) 2 .
N4 Ag3 N3 C10 -33(6) 2 .
O5 Ag3 N3 C10 -161(2) 2 .
Dy2 O2 C1 O1 -160(2) . .
Dy1 O2 C1 O1 -18(3) . .
Dy2 O2 C1 C2 23(4) . .
Dy1 O2 C1 C2 165(2) . .
Dy1 O1 C1 O2 17(3) . .
Ag2 O1 C1 O2 164(2) . .
Dy1 O1 C1 C2 -165(2) . .
Ag2 O1 C1 C2 -19(3) . .
C5 N2 C2 C3 -4(3) . .
Ag2 N2 C2 C3 164.2(17) . .
C5 N2 C2 C1 179(2) . .
Ag2 N2 C2 C1 -13(3) . .
O2 C1 C2 N2 -160(3) . .
O1 C1 C2 N2 23(4) . .
O2 C1 C2 C3 23(4) . .
O1 C1 C2 C3 -154(3) . .
N2 C2 C3 N1 3(3) . .
C1 C2 C3 N1 -180(2) . .
N2 C2 C3 C4 -170(3) . .
C1 C2 C3 C4 7(5) . .
C5 N1 C3 C2 -2(3) . .
Ag1 N1 C3 C2 175.3(16) . .
C5 N1 C3 C4 173(2) . .
Ag1 N1 C3 C4 -10(3) . .
Dy2 O3 C4 O4 131(2) . .
Dy2 O3 C4 C3 -48(3) . .
C2 C3 C4 O3 -21(4) . .
N1 C3 C4 O3 165(2) . .
C2 C3 C4 O4 160(3) . .
N1 C3 C4 O4 -13(4) . .
C2 N2 C5 N1 2(3) . .
Ag2 N2 C5 N1 -162.7(18) . .
C2 N2 C5 C6 -180(2) . .
Ag2 N2 C5 C6 15(4) . .
C3 N1 C5 N2 0(3) . .
Ag1 N1 C5 N2 -176.6(19) . .
C3 N1 C5 C6 -178(2) . .
Ag1 N1 C5 C6 6(4) . .
N2 C5 C6 C10 10(4) . .
N1 C5 C6 C10 -172(3) . .
N2 C5 C6 C7 -171(3) . .
N1 C5 C6 C7 7(4) . .
C10 C6 C7 C8 -1(4) . .
C5 C6 C7 C8 -180(2) . .
C6 C7 C8 C9 -2(4) . .
C10 N3 C9 C8 0(5) . .
Ag3 N3 C9 C8 -158(2) . .
C7 C8 C9 N3 2(5) . .
C9 N3 C10 C6 -2(4) . .
Ag3 N3 C10 C6 156(2) . .
C7 C6 C10 N3 3(4) . .
C5 C6 C10 N3 -178(3) . .
Dy2 O6 C11 O5 134(3) . .
Dy1 O6 C11 O5 9(3) . .
Dy2 O6 C11 C12 -47(5) . .
Dy1 O6 C11 C12 -172(3) . .
Dy1 O5 C11 O6 -10(3) . .
Ag3 O5 C11 O6 176(2) 2_545 .
Dy1 O5 C11 C12 170(2) . .
Ag3 O5 C11 C12 -4(3) 2_545 .
C15 N4 C12 C13 2(3) . .
Ag3 N4 C12 C13 -175(2) 2_545 .
C15 N4 C12 C11 178(3) . .
Ag3 N4 C12 C11 1(4) 2_545 .
O6 C11 C12 N4 -178(3) . .
O5 C11 C12 N4 2(4) . .
O6 C11 C12 C13 -3(5) . .
O5 C11 C12 C13 177(3) . .
C15 N5 C13 C12 -6(3) . .
Ag1 N5 C13 C12 175(2) 2_646 .
C15 N5 C13 C14 178(3) . 4_576
Ag1 N5 C13 C14 -2(4) 2_646 4_576
N4 C12 C13 N5 3(4) . .
C11 C12 C13 N5 -173(3) . .
N4 C12 C13 C14 179(3) . 4_576
C11 C12 C13 C14 4(5) . 4_576
Dy2 O7 C14 O8 -98(3) 4_575 .
Dy1 O7 C14 O8 58(4) . .
Dy2 O7 C14 C13 84(3) 4_575 4_575
Dy1 O7 C14 C13 -120(2) . 4_575
C12 N4 C15 N5 -5(4) . .
Ag3 N4 C15 N5 170(2) 2_545 .
C12 N4 C15 C16 176(3) . .
Ag3 N4 C15 C16 -9(5) 2_545 .
C13 N5 C15 N4 7(4) . .
Ag1 N5 C15 N4 -174(2) 2_646 .
C13 N5 C15 C16 -174(3) . .
Ag1 N5 C15 C16 5(5) 2_646 .
N4 C15 C16 C17 161(3) . .
N5 C15 C16 C17 -17(5) . .
N4 C15 C16 C20 -22(5) . .
N5 C15 C16 C20 159(3) . .
C20 C16 C17 C18 1(5) . .
C15 C16 C17 C18 178(3) . .
C16 C17 C18 C19 2(5) . .
C20 N6 C19 C18 -2(5) . .
Ag2 N6 C19 C18 173(2) 2_545 .
C17 C18 C19 N6 -2(5) . .
C19 N6 C20 C16 6(5) . .
Ag2 N6 C20 C16 -169(2) 2_545 .
C17 C16 C20 N6 -5(5) . .
C15 C16 C20 N6 178(3) . .
Dy2 O9 C21 O12 -178(2) 4_475 .
Dy2 O9 C21 C22 2(4) 4_475 .
Dy1 O12 C21 O9 170(2) . .
Dy1 O12 C21 C22 -10(3) . .
Dy1 O11 C22 O10 -167(2) . .
Dy1 O11 C22 C21 10(4) . .
Dy2 O10 C22 O11 178(2) 4_475 .
Dy2 O10 C22 C21 1(3) 4_475 .
O9 C21 C22 O11 -179(3) . .
O12 C21 C22 O11 1(4) . .
O9 C21 C22 O10 -2(4) . .
O12 C21 C22 O10 178(3) . .
