#------------------------------------------------------------------------------
#$Date: 2016-03-24 03:01:27 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179609 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/73/4507343.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4507343
loop_
_publ_author_name
'Xu, Hai-Bing'
'Deng, Jian-Guo'
'Zhang, Li-Yi'
'Chen, Zhong-Ning'
_publ_section_title
;
 Structural and Photophysical Studies on Geometric (Er2Yb2/Yb2Er2) and
 Configurational (EuTb3/Eu3Tb) Isomers of Heterotetranuclear
 Lanthanide(III) Complexes
;
_journal_issue                   2
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              849
_journal_paper_doi               10.1021/cg3015546
_journal_volume                  13
_journal_year                    2013
_chemical_formula_sum            'C123 H135 Cl0 Eu F36 N9 O33 Tb3'
_chemical_formula_weight         3580.12
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           148
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  '-R 3'
_symmetry_space_group_name_H-M   'R -3 :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            6
_cell_length_a                   24.8037(6)
_cell_length_b                   24.8037(6)
_cell_length_c                   42.7922(19)
_cell_measurement_temperature    293(2)
_cell_volume                     22799.7(13)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.960
_diffrn_measured_fraction_theta_max 0.960
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0464
_diffrn_reflns_av_sigmaI/netI    0.0628
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -26
_diffrn_reflns_limit_k_max       29
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       47
_diffrn_reflns_limit_l_min       -50
_diffrn_reflns_number            46988
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.84
_exptl_absorpt_coefficient_mu    1.900
_exptl_absorpt_correction_T_max  0.425
_exptl_absorpt_correction_T_min  0.166
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.564
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             10692
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.50
_exptl_crystal_size_min          0.45
_platon_squeeze_details
;
 The unit cell contains 36 hexane and 18 hydrate molecules which have been 
 treated as a diffuse contribution to the overall scattering without specific 
 atom positions by SQUEEZE/PLATON.
;
_refine_diff_density_max         2.707
_refine_diff_density_min         -1.181
_refine_diff_density_rms         0.119
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.089
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     526
_refine_ls_number_reflns         8549
_refine_ls_number_restraints     112
_refine_ls_restrained_S_all      1.092
_refine_ls_R_factor_all          0.0660
_refine_ls_R_factor_gt           0.0598
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1217P)²+68.8551P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1717
_refine_ls_wR_factor_ref         0.1815
_reflns_number_gt                7426
_reflns_number_total             8549
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg3015546_si_004.cif
_cod_data_source_block           zp
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        22799.6(13)
_cod_original_sg_symbol_H-M      R-3
_cod_database_code               4507343
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Tb1 Tb 0.171205(11) 0.118163(11) 0.811346(6) 0.04671(16) Uani 1 1 d . . .
Eu1 Eu 0.0000 0.0000 0.844227(9) 0.04421(17) Uani 1 3 d S . .
F1 F 0.2281(14) 0.1761(11) 0.6988(4) 0.198(8) Uani 0.50 1 d PDU A 1
F2 F 0.2962(8) 0.1486(13) 0.6939(5) 0.240(9) Uani 0.50 1 d PDU A 1
F3 F 0.1998(11) 0.0811(9) 0.6931(5) 0.232(10) Uani 0.50 1 d PDU A 1
F1' F 0.2666(13) 0.1078(12) 0.6885(5) 0.241(9) Uani 0.50 1 d PDU A 2
F2' F 0.1881(9) 0.1200(14) 0.6942(5) 0.228(10) Uani 0.50 1 d PDU A 2
F3' F 0.2792(13) 0.1937(7) 0.7048(6) 0.233(10) Uani 0.50 1 d PDU A 2
F4 F 0.2996(5) 0.0151(5) 0.8116(4) 0.275(9) Uani 1 1 d DU A .
F5 F 0.3590(7) 0.0630(9) 0.7736(3) 0.354(11) Uani 1 1 d DU A .
F6 F 0.3677(4) 0.1097(5) 0.8166(4) 0.280(8) Uani 1 1 d DU A .
F7 F 0.1109(5) 0.2600(4) 0.8577(2) 0.168(3) Uani 1 1 d . . .
F8 F 0.1396(4) 0.2627(3) 0.90332(16) 0.137(2) Uani 1 1 d . . .
F9 F 0.2048(5) 0.3268(3) 0.8717(2) 0.164(3) Uani 1 1 d . . .
F10 F 0.3233(4) 0.2358(4) 0.9207(2) 0.172(4) Uani 1 1 d . . .
F11 F 0.3020(4) 0.1465(3) 0.9080(2) 0.190(4) Uani 1 1 d . . .
F12 F 0.3628(4) 0.2250(6) 0.8816(2) 0.198(5) Uani 1 1 d . . .
O1 O 0.05905(16) 0.08505(16) 0.80668(8) 0.0480(8) Uani 1 1 d . . .
O2 O -0.01533(18) 0.1021(2) 0.78794(10) 0.0623(10) Uani 1 1 d . . .
O3 O 0.1971(2) 0.1203(2) 0.75598(11) 0.0742(12) Uani 1 1 d . . .
O4 O 0.2470(2) 0.0874(3) 0.80604(14) 0.0845(15) Uani 1 1 d . . .
O5 O 0.1541(2) 0.18806(19) 0.84367(10) 0.0627(10) Uani 1 1 d . . .
O6 O 0.2415(2) 0.1528(2) 0.85498(11) 0.0721(12) Uani 1 1 d . . .
O7 O 0.11260(18) 0.04606(18) 0.85074(9) 0.0556(9) Uani 1 1 d . . .
O8 O -0.0819(2) -0.0534(2) 0.88277(10) 0.0705(12) Uani 1 1 d . . .
O9 O 0.0174(7) 0.3916(6) 0.6478(3) 0.191(5) Uani 1 1 d . . .
O10 O 0.0948(5) 0.4100(6) 0.6229(3) 0.181(5) Uani 1 1 d . . .
N1 N 0.2656(2) 0.2245(2) 0.79503(12) 0.0575(11) Uani 1 1 d . . .
N2 N 0.14735(19) 0.1891(2) 0.77909(10) 0.0465(9) Uani 1 1 d . . .
N3 N 0.0595(6) 0.3861(5) 0.6446(2) 0.125(3) Uani 1 1 d . . .
C1 C 0.3236(3) 0.2427(3) 0.80466(19) 0.0751(18) Uani 1 1 d . . .
H1A H 0.3300 0.2169 0.8180 0.090 Uiso 1 1 calc R . .
C2 C 0.3738(3) 0.2984(4) 0.7956(2) 0.096(3) Uani 1 1 d . . .
H2A H 0.4137 0.3085 0.8020 0.115 Uiso 1 1 calc R . .
C3 C 0.3657(4) 0.3383(5) 0.7774(3) 0.121(4) Uani 1 1 d . . .
H3A H 0.3993 0.3766 0.7718 0.146 Uiso 1 1 calc R . .
C4 C 0.3061(3) 0.3209(4) 0.7675(2) 0.088(2) Uani 1 1 d . . .
H4A H 0.2991 0.3476 0.7551 0.106 Uiso 1 1 calc R . .
C5 C 0.2568(3) 0.2631(3) 0.77607(15) 0.0590(14) Uani 1 1 d . . .
C6 C 0.1920(3) 0.2412(3) 0.76555(13) 0.0513(12) Uani 1 1 d . . .
C7 C 0.1787(3) 0.2727(3) 0.74304(14) 0.0542(12) Uani 1 1 d . . .
H7A H 0.2108 0.3075 0.7333 0.065 Uiso 1 1 calc R . .
C8 C 0.1170(3) 0.2525(3) 0.73493(13) 0.0536(12) Uani 1 1 d . . .
C9 C 0.1015(3) 0.2863(3) 0.71120(15) 0.0624(15) Uani 1 1 d . . .
C10 C 0.1412(4) 0.3133(5) 0.6862(2) 0.096(3) Uani 1 1 d . . .
H10A H 0.1764 0.3095 0.6839 0.115 Uiso 1 1 calc R . .
C11 C 0.1268(4) 0.3471(5) 0.6640(2) 0.109(3) Uani 1 1 d . . .
H11A H 0.1530 0.3663 0.6470 0.130 Uiso 1 1 calc R . .
C12 C 0.0747(5) 0.3510(4) 0.6678(2) 0.094(3) Uani 1 1 d . . .
C13 C 0.0361(5) 0.3253(5) 0.6926(2) 0.100(3) Uani 1 1 d . . .
H13A H 0.0012 0.3297 0.6950 0.120 Uiso 1 1 calc R . .
C14 C 0.0498(4) 0.2925(4) 0.7143(2) 0.087(2) Uani 1 1 d . . .
H14A H 0.0234 0.2744 0.7313 0.104 Uiso 1 1 calc R . .
C15 C 0.0706(3) 0.2004(3) 0.75076(14) 0.0558(13) Uani 1 1 d . . .
H15A H 0.0288 0.1866 0.7470 0.067 Uiso 1 1 calc R . .
C16 C 0.0876(2) 0.1700(2) 0.77194(12) 0.0466(11) Uani 1 1 d . . .
C17 C 0.0397(2) 0.1152(2) 0.79034(12) 0.0455(11) Uani 1 1 d . . .
C18 C -0.0959(3) -0.1070(3) 0.87437(15) 0.0629(15) Uani 1 1 d . . .
C19 C -0.1455(6) -0.1647(5) 0.8895(3) 0.127(4) Uani 1 1 d . . .
H19A H -0.1856 -0.1710 0.8836 0.191 Uiso 1 1 calc R . .
H19B H -0.1410 -0.1605 0.9118 0.191 Uiso 1 1 calc R . .
H19C H -0.1418 -0.1997 0.8828 0.191 Uiso 1 1 calc R . .
C101 C 0.2422(7) 0.1333(6) 0.7060(3) 0.163(5) Uani 1 1 d DU . .
C102 C 0.2390(5) 0.1187(4) 0.7414(2) 0.096(2) Uani 1 1 d U A .
C103 C 0.2831(5) 0.1034(5) 0.7534(3) 0.123(3) Uani 1 1 d U . .
H10B H 0.3136 0.1043 0.7405 0.148 Uiso 1 1 calc R A .
C104 C 0.2803(4) 0.0869(4) 0.7853(3) 0.102(3) Uani 1 1 d U A .
C105 C 0.3286(5) 0.0684(6) 0.7972(3) 0.181(6) Uani 1 1 d DU . .
C106 C 0.1583(6) 0.2691(5) 0.8753(3) 0.113(3) Uani 1 1 d . . .
C107 C 0.1816(4) 0.2228(3) 0.86561(16) 0.0715(17) Uani 1 1 d . . .
C108 C 0.2302(5) 0.2262(4) 0.8835(2) 0.094(3) Uani 1 1 d . . .
H10C H 0.2455 0.2537 0.9002 0.112 Uiso 1 1 calc R . .
C109 C 0.2556(4) 0.1907(3) 0.87699(19) 0.079(2) Uani 1 1 d . . .
C110 C 0.3097(5) 0.1989(4) 0.8971(3) 0.109(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Tb1 O4 96.43(18) . .
O7 Tb1 O6 77.12(16) . .
O4 Tb1 O6 68.79(19) . .
O7 Tb1 O5 82.65(14) . .
O4 Tb1 O5 137.68(17) . .
O6 Tb1 O5 69.82(16) . .
O7 Tb1 O2 72.01(14) . 3
O4 Tb1 O2 74.30(17) . 3
O6 Tb1 O2 128.03(16) . 3
O5 Tb1 O2 142.12(14) . 3
O7 Tb1 O3 139.85(15) . .
O4 Tb1 O3 70.9(2) . .
O6 Tb1 O3 127.53(18) . .
O5 Tb1 O3 132.58(16) . .
O2 Tb1 O3 67.90(15) 3 .
O7 Tb1 O1 69.06(12) . .
O4 Tb1 O1 145.55(15) . .
O6 Tb1 O1 132.34(16) . .
O5 Tb1 O1 73.35(14) . .
O2 Tb1 O1 71.52(13) 3 .
O3 Tb1 O1 99.65(15) . .
O7 Tb1 N2 130.43(13) . .
O4 Tb1 N2 132.21(19) . .
O6 Tb1 N2 123.81(15) . .
O5 Tb1 N2 68.08(14) . .
O2 Tb1 N2 108.02(15) 3 .
O3 Tb1 N2 66.83(15) . .
O1 Tb1 N2 64.73(12) . .
O7 Tb1 N1 149.72(15) . .
O4 Tb1 N1 81.01(18) . .
O6 Tb1 N1 73.84(16) . .
O5 Tb1 N1 79.50(16) . .
O2 Tb1 N1 134.35(15) 3 .
O3 Tb1 N1 67.93(16) . .
O1 Tb1 N1 127.28(13) . .
N2 Tb1 N1 63.40(14) . .
O7 Tb1 Eu1 33.94(9) . .
O4 Tb1 Eu1 121.23(15) . .
O6 Tb1 Eu1 107.57(13) . .
O5 Tb1 Eu1 79.75(11) . .
O2 Tb1 Eu1 63.44(9) 3 .
O3 Tb1 Eu1 121.65(12) . .
O1 Tb1 Eu1 35.58(8) . .
N2 Tb1 Eu1 99.73(10) . .
N1 Tb1 Eu1 157.14(11) . .
O8 Eu1 O8 79.05(18) 3 .
O8 Eu1 O8 79.05(18) 3 2
O8 Eu1 O8 79.05(18) . 2
O8 Eu1 O7 53.00(15) 3 2
O8 Eu1 O7 75.25(15) . 2
O8 Eu1 O7 128.67(15) 2 2
O8 Eu1 O7 75.25(15) 3 .
O8 Eu1 O7 128.67(15) . .
O8 Eu1 O7 53.00(15) 2 .
O7 Eu1 O7 118.72(4) 2 .
O8 Eu1 O7 128.67(15) 3 3
O8 Eu1 O7 53.00(15) . 3
O8 Eu1 O7 75.25(15) 2 3
O7 Eu1 O7 118.72(4) 2 3
O7 Eu1 O7 118.72(3) . 3
O8 Eu1 O1 120.91(14) 3 2
O8 Eu1 O1 85.80(15) . 2
O8 Eu1 O1 152.20(15) 2 2
O7 Eu1 O1 67.92(12) 2 2
O7 Eu1 O1 145.38(12) . 2
O7 Eu1 O1 77.01(13) 3 2
O8 Eu1 O1 85.80(15) 3 .
O8 Eu1 O1 152.20(15) . .
O8 Eu1 O1 120.91(14) 2 .
O7 Eu1 O1 77.01(13) 2 .
O7 Eu1 O1 67.92(12) . .
O7 Eu1 O1 145.38(12) 3 .
O1 Eu1 O1 82.18(13) 2 .
O8 Eu1 O1 152.20(15) 3 3
O8 Eu1 O1 120.91(14) . 3
O8 Eu1 O1 85.80(15) 2 3
O7 Eu1 O1 145.38(12) 2 3
O7 Eu1 O1 77.01(13) . 3
O7 Eu1 O1 67.92(12) 3 3
O1 Eu1 O1 82.18(13) 2 3
O1 Eu1 O1 82.18(13) . 3
O8 Eu1 C18 25.95(17) 3 3
O8 Eu1 C18 75.13(17) . 3
O8 Eu1 C18 103.36(19) 2 3
O7 Eu1 C18 27.06(16) 2 3
O7 Eu1 C18 97.09(16) . 3
O7 Eu1 C18 127.73(16) 3 3
O1 Eu1 C18 94.96(15) 2 3
O1 Eu1 C18 81.04(16) . 3
O1 Eu1 C18 163.20(16) 3 3
O8 Eu1 C18 103.36(19) 3 .
O8 Eu1 C18 25.95(17) . .
O8 Eu1 C18 75.13(18) 2 .
O7 Eu1 C18 97.09(16) 2 .
O7 Eu1 C18 127.73(16) . .
O7 Eu1 C18 27.06(16) 3 .
O1 Eu1 C18 81.04(16) 2 .
O1 Eu1 C18 163.20(16) . .
O1 Eu1 C18 94.96(16) 3 .
C18 Eu1 C18 100.96(18) 3 .
O8 Eu1 C18 75.13(17) 3 2
O8 Eu1 C18 103.36(19) . 2
O8 Eu1 C18 25.95(17) 2 2
O7 Eu1 C18 127.73(16) 2 2
O7 Eu1 C18 27.06(16) . 2
O7 Eu1 C18 97.09(16) 3 2
O1 Eu1 C18 163.20(16) 2 2
O1 Eu1 C18 94.96(16) . 2
O1 Eu1 C18 81.04(16) 3 2
C18 Eu1 C18 100.96(18) 3 2
C18 Eu1 C18 100.96(18) . 2
C17 O1 Eu1 128.3(3) . .
C17 O1 Tb1 122.4(3) . .
Eu1 O1 Tb1 108.56(13) . .
C17 O2 Tb1 147.2(4) . 2
C102 O3 Tb1 134.9(7) . .
C104 O4 Tb1 136.6(7) . .
C107 O5 Tb1 135.0(5) . .
C109 O6 Tb1 137.3(5) . .
C18 O7 Tb1 152.4(4) 2 .
C18 O7 Eu1 93.5(4) 2 .
Tb1 O7 Eu1 113.56(15) . .
C18 O8 Eu1 95.5(3) . .
C1 N1 C5 118.1(5) . .
C1 N1 Tb1 122.0(4) . .
C5 N1 Tb1 119.9(4) . .
C6 N2 C16 118.4(4) . .
C6 N2 Tb1 122.5(3) . .
C16 N2 Tb1 118.5(3) . .
O9 N3 O10 121.4(10) . .
O9 N3 C12 120.7(12) . .
O10 N3 C12 117.8(11) . .
N1 C1 C2 122.3(7) . .
C3 C2 C1 120.3(7) . .
C2 C3 C4 118.4(7) . .
C3 C4 C5 119.5(8) . .
N1 C5 C4 121.3(6) . .
N1 C5 C6 116.7(5) . .
C4 C5 C6 122.0(6) . .
N2 C6 C7 122.0(5) . .
N2 C6 C5 116.3(5) . .
C7 C6 C5 121.7(5) . .
C6 C7 C8 119.9(5) . .
C7 C8 C15 117.3(5) . .
C7 C8 C9 120.9(5) . .
C15 C8 C9 121.7(5) . .
C14 C9 C10 120.0(6) . .
C14 C9 C8 121.2(6) . .
C10 C9 C8 118.7(6) . .
C9 C10 C11 118.4(8) . .
C12 C11 C10 119.3(8) . .
C11 C12 C13 122.4(7) . .
C11 C12 N3 119.4(9) . .
C13 C12 N3 118.2(10) . .
C12 C13 C14 118.6(8) . .
C9 C14 C13 121.3(8) . .
C16 C15 C8 119.3(5) . .
N2 C16 C15 122.8(5) . .
N2 C16 C17 115.6(4) . .
C15 C16 C17 121.4(5) . .
O2 C17 O1 125.3(5) . .
O2 C17 C16 117.5(4) . .
O1 C17 C16 117.2(4) . .
O8 C18 O7 117.9(5) . 3
O8 C18 C19 123.7(6) . .
O7 C18 C19 118.4(7) 3 .
O8 C18 Eu1 58.5(3) . .
O7 C18 Eu1 59.4(3) 3 .
C19 C18 Eu1 177.8(6) . .
F2 C101 F1' 42.0(11) . .
F2 C101 F3' 67.7(12) . .
F1' C101 F3' 107.6(12) . .
F2 C101 F1 108.8(12) . .
F1' C101 F1 129(2) . .
F3' C101 F1 51.9(13) . .
F2 C101 F2' 133.8(19) . .
F1' C101 F2' 108.7(13) . .
F3' C101 F2' 108.4(13) . .
F1 C101 F2' 57.2(12) . .
F2 C101 F3 108.7(11) . .
F1' C101 F3 67.6(12) . .
F3' C101 F3 150.2(19) . .
F1 C101 F3 106.9(13) . .
F2' C101 F3 51.3(12) . .
F2 C101 C102 112.5(15) . .
F1' C101 C102 115.5(16) . .
F3' C101 C102 103.3(14) . .
F1 C101 C102 114.6(11) . .
F2' C101 C102 113.0(12) . .
F3 C101 C102 105.1(13) . .
O3 C102 C103 127.0(9) . .
O3 C102 C101 115.7(10) . .
C103 C102 C101 117.3(9) . .
C104 C103 C102 119.5(7) . .
O4 C104 C103 129.4(9) . .
O4 C104 C105 112.9(10) . .
C103 C104 C105 117.6(9) . .
F6 C105 F4 108.2(11) . .
F6 C105 F5 109.4(10) . .
F4 C105 F5 108.5(11) . .
F6 C105 C104 110.8(9) . .
F4 C105 C104 109.6(9) . .
F5 C105 C104 110.2(11) . .
F8 C106 F7 106.4(11) . .
F8 C106 F9 108.2(8) . .
F7 C106 F9 109.7(11) . .
F8 C106 C107 113.7(9) . .
F7 C106 C107 110.2(7) . .
F9 C106 C107 108.5(10) . .
O5 C107 C108 128.5(7) . .
O5 C107 C106 115.8(7) . .
C108 C107 C106 115.7(7) . .
C109 C108 C107 121.5(7) . .
O6 C109 C108 127.0(7) . .
O6 C109 C110 115.0(8) . .
C108 C109 C110 117.9(8) . .
F10 C110 F11 106.3(10) . .
F10 C110 F12 101.7(9) . .
F11 C110 F12 106.4(12) . .
F10 C110 C109 116.1(10) . .
F11 C110 C109 113.0(7) . .
F12 C110 C109 112.4(9) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Tb1 O7 2.357(4) .
Tb1 O4 2.366(5) .
Tb1 O6 2.401(4) .
Tb1 O5 2.416(4) .
Tb1 O2 2.426(4) 3
Tb1 O3 2.448(5) .
Tb1 O1 2.484(4) .
Tb1 N2 2.529(4) .
Tb1 N1 2.598(5) .
Tb1 Eu1 4.0196(3) .
Eu1 O8 2.432(4) 3
Eu1 O8 2.432(4) .
Eu1 O8 2.432(4) 2
Eu1 O7 2.448(4) 2
Eu1 O7 2.448(4) .
Eu1 O7 2.448(4) 3
Eu1 O1 2.467(3) 2
Eu1 O1 2.467(3) .
Eu1 O1 2.467(3) 3
Eu1 C18 2.838(6) 3
Eu1 C18 2.838(6) .
Eu1 C18 2.838(6) 2
F1 C101 1.310(9) .
F2 C101 1.302(9) .
F3 C101 1.314(9) .
F1' C101 1.307(9) .
F2' C101 1.313(10) .
F3' C101 1.308(9) .
F4 C105 1.301(9) .
F5 C105 1.305(9) .
F6 C105 1.299(9) .
F7 C106 1.319(13) .
F8 C106 1.266(13) .
F9 C106 1.325(14) .
F10 C110 1.293(12) .
F11 C110 1.303(11) .
F12 C110 1.319(15) .
O1 C17 1.278(6) .
O2 C17 1.240(6) .
O2 Tb1 2.426(4) 2
O3 C102 1.229(10) .
O4 C104 1.217(11) .
O5 C107 1.226(8) .
O6 C109 1.251(9) .
O7 C18 1.293(7) 2
O8 C18 1.248(8) .
O9 N3 1.127(15) .
O10 N3 1.209(14) .
N1 C1 1.339(8) .
N1 C5 1.353(8) .
N2 C6 1.342(7) .
N2 C16 1.346(7) .
N3 C12 1.489(10) .
C1 C2 1.374(11) .
C2 C3 1.352(14) .
C3 C4 1.383(12) .
C4 C5 1.390(9) .
C5 C6 1.486(8) .
C6 C7 1.381(8) .
C7 C8 1.394(8) .
C8 C15 1.402(8) .
C8 C9 1.486(8) .
C9 C14 1.373(10) .
C9 C10 1.379(10) .
C10 C11 1.426(11) .
C11 C12 1.354(14) .
C12 C13 1.355(13) .
C13 C14 1.383(11) .
C15 C16 1.373(7) .
C16 C17 1.505(7) .
C18 O7 1.293(7) 3
C18 C19 1.489(11) .
C101 C102 1.550(17) .
C102 C103 1.421(17) .
C103 C104 1.415(17) .
C104 C105 1.567(15) .
C106 C107 1.577(12) .
C107 C108 1.394(11) .
C108 C109 1.343(12) .
C109 C110 1.518(11) .
