#------------------------------------------------------------------------------
#$Date: 2016-03-24 03:01:27 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179609 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/73/4507344.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4507344
loop_
_publ_author_name
'Xu, Hai-Bing'
'Deng, Jian-Guo'
'Zhang, Li-Yi'
'Chen, Zhong-Ning'
_publ_section_title
;
 Structural and Photophysical Studies on Geometric (Er2Yb2/Yb2Er2) and
 Configurational (EuTb3/Eu3Tb) Isomers of Heterotetranuclear
 Lanthanide(III) Complexes
;
_journal_issue                   2
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              849
_journal_paper_doi               10.1021/cg3015546
_journal_volume                  13
_journal_year                    2013
_chemical_formula_sum            'C105 H87 Cl0 Eu3 F36 N9 O30 Tb'
_chemical_formula_weight         3253.64
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           148
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  '-R 3'
_symmetry_space_group_name_H-M   'R -3 :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            6
_cell_length_a                   24.8541(7)
_cell_length_b                   24.8541(7)
_cell_length_c                   42.446(4)
_cell_measurement_temperature    293(2)
_cell_volume                     22707(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.971
_diffrn_measured_fraction_theta_max 0.971
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0552
_diffrn_reflns_av_sigmaI/netI    0.0386
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -29
_diffrn_reflns_limit_l_max       50
_diffrn_reflns_limit_l_min       -37
_diffrn_reflns_number            46720
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.68
_exptl_absorpt_coefficient_mu    1.793
_exptl_absorpt_correction_T_max  0.7156
_exptl_absorpt_correction_T_min  0.2556
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.428
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             9588
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.20
_platon_squeeze_details
;
The unit cell contains 18 hexane molecules which have been treated as a 
diffuse contribution to the overall scattering without specific atom 
positions by SQUEEZE/PLATON.
;
_refine_diff_density_max         2.711
_refine_diff_density_min         -1.072
_refine_diff_density_rms         0.096
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     564
_refine_ls_number_reflns         8627
_refine_ls_number_restraints     211
_refine_ls_restrained_S_all      1.085
_refine_ls_R_factor_all          0.0607
_refine_ls_R_factor_gt           0.0515
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0854P)²+48.1012P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1382
_refine_ls_wR_factor_ref         0.1485
_reflns_number_gt                7027
_reflns_number_total             8627
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg3015546_si_005.cif
_cod_data_source_block           z
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_H-M      R-3
_cod_database_code               4507344
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Tb1 Tb 0.6667 0.3333 -0.012136(10) 0.05522(15) Uani 1 3 d S . .
Eu1 Eu 0.720787(11) 0.215761(11) 0.021374(6) 0.05196(13) Uani 1 1 d . . .
F1 F 0.5189(2) 0.0736(4) -0.0251(2) 0.195(4) Uani 1 1 d . . .
F2 F 0.5440(3) 0.0714(3) -0.07157(17) 0.161(3) Uani 1 1 d . . .
F3 F 0.5451(3) 0.0075(3) -0.0391(2) 0.177(3) Uani 1 1 d . . .
F4 F 0.8032(5) 0.1073(5) -0.0504(2) 0.222(5) Uani 1 1 d . . .
F5 F 0.8239(3) 0.1861(3) -0.0748(2) 0.186(4) Uani 1 1 d . . .
F6 F 0.7550(4) 0.0979(4) -0.08874(19) 0.183(3) Uani 1 1 d . . .
F7 F 0.7211(9) 0.1990(12) 0.1386(5) 0.217(8) Uani 0.50 1 d PDU A 1
F8 F 0.8197(9) 0.2363(10) 0.1457(5) 0.221(9) Uani 0.50 1 d PDU A 1
F9 F 0.7621(11) 0.1413(8) 0.1299(5) 0.206(7) Uani 0.50 1 d PDU A 1
F7' F 0.8222(7) 0.1968(10) 0.1403(4) 0.192(7) Uani 0.50 1 d PDU A 2
F8' F 0.7222(7) 0.1513(8) 0.1336(4) 0.172(6) Uani 0.50 1 d PDU A 2
F9' F 0.7766(9) 0.2512(7) 0.1411(4) 0.172(5) Uani 0.50 1 d PDU A 2
F10 F 0.9263(7) 0.2311(7) 0.0113(4) 0.157(6) Uani 0.50 1 d PDU A 1
F11 F 0.9535(10) 0.2451(10) 0.0610(4) 0.201(7) Uani 0.50 1 d PDU A 1
F12 F 0.9578(10) 0.3212(7) 0.0329(5) 0.190(7) Uani 0.50 1 d PDU A 1
F10' F 0.9682(6) 0.2874(8) 0.0609(3) 0.156(5) Uani 0.50 1 d PDU A 2
F11' F 0.9472(7) 0.3074(8) 0.0144(4) 0.164(6) Uani 0.50 1 d PDU A 2
F12' F 0.9235(10) 0.2118(7) 0.0277(5) 0.180(7) Uani 0.50 1 d PDU A 2
O1 O 0.63411(18) 0.14504(18) -0.01117(10) 0.0699(10) Uani 1 1 d . . .
O2 O 0.7568(2) 0.1811(2) -0.02286(11) 0.0769(11) Uani 1 1 d . . .
O3 O 0.7444(2) 0.21381(19) 0.07789(11) 0.0826(12) Uani 1 1 d . . .
O4 O 0.8275(2) 0.2461(2) 0.02722(14) 0.0926(15) Uani 1 1 d . . .
O5 O 0.76969(18) 0.31908(17) 0.04467(10) 0.0689(10) Uani 1 1 d . . .
O6 O 0.64108(15) 0.24835(15) 0.02614(9) 0.0533(8) Uani 1 1 d . . .
O7 O 0.73343(17) 0.28726(18) -0.01886(9) 0.0627(9) Uani 1 1 d . . .
O8 O 0.7492(2) 0.3620(2) -0.05070(10) 0.0810(12) Uani 1 1 d . . .
O22 O 0.3511(4) -0.0766(4) 0.2112(2) 0.169(4) Uani 1 1 d . . .
O23 O 0.2910(4) -0.0580(4) 0.1851(2) 0.170(4) Uani 1 1 d . . .
N1 N 0.7080(2) 0.1087(2) 0.03795(12) 0.0646(11) Uani 1 1 d . . .
N2 N 0.62498(19) 0.14448(19) 0.05390(11) 0.0554(10) Uani 1 1 d . . .
N3 N 0.3401(4) -0.0533(4) 0.1890(2) 0.125(3) Uani 1 1 d . . .
C1 C 0.7489(3) 0.0917(3) 0.02862(18) 0.0802(18) Uani 1 1 d . . .
H1A H 0.7816 0.1182 0.0155 0.066(17) Uiso 1 1 calc R . .
C2 C 0.7443(4) 0.0363(4) 0.0378(3) 0.114(3) Uani 1 1 d . . .
H2A H 0.7738 0.0259 0.0314 0.137 Uiso 1 1 calc R . .
C3 C 0.6948(5) -0.0035(4) 0.0567(3) 0.133(4) Uani 1 1 d . . .
H3A H 0.6900 -0.0416 0.0627 0.15(4) Uiso 1 1 calc R . .
C4 C 0.6539(4) 0.0134(3) 0.0661(2) 0.096(2) Uani 1 1 d . . .
H4A H 0.6203 -0.0132 0.0786 0.11(3) Uiso 1 1 calc R . .
C5 C 0.6619(3) 0.0712(3) 0.05709(15) 0.0666(14) Uani 1 1 d . . .
C6 C 0.6183(2) 0.0929(2) 0.06822(14) 0.0574(12) Uani 1 1 d . . .
C7 C 0.5728(2) 0.0606(3) 0.09063(13) 0.0607(13) Uani 1 1 d . . .
H7A H 0.5696 0.0256 0.1003 0.10(2) Uiso 1 1 calc R . .
C8 C 0.5322(2) 0.0813(2) 0.09837(13) 0.0590(12) Uani 1 1 d . . .
C9 C 0.4822(3) 0.0471(3) 0.12230(14) 0.0677(14) Uani 1 1 d . . .
C10 C 0.4920(4) 0.0194(4) 0.14806(18) 0.097(2) Uani 1 1 d . . .
H10A H 0.5307 0.0229 0.1508 0.10(2) Uiso 1 1 calc R . .
C11 C 0.4468(4) -0.0130(4) 0.1696(2) 0.108(3) Uani 1 1 d . . .
H11A H 0.4544 -0.0313 0.1868 0.060(15) Uiso 1 1 calc R . .
C12 C 0.3903(4) -0.0180(4) 0.16549(19) 0.095(2) Uani 1 1 d . . .
C13 C 0.3778(4) 0.0077(4) 0.1403(2) 0.100(2) Uani 1 1 d . . .
H13A H 0.3387 0.0035 0.1379 0.13(3) Uiso 1 1 calc R . .
C14 C 0.4242(3) 0.0405(4) 0.11811(19) 0.091(2) Uani 1 1 d . . .
H14A H 0.4161 0.0577 0.1006 0.16(4) Uiso 1 1 calc R . .
C15 C 0.5377(2) 0.1335(3) 0.08237(13) 0.0584(12) Uani 1 1 d . . .
H15A H 0.5101 0.1476 0.0863 0.053(14) Uiso 1 1 calc R . .
C16 C 0.5852(2) 0.1630(2) 0.06082(12) 0.0507(11) Uani 1 1 d . . .
C17 C 0.5923(2) 0.2188(2) 0.04228(12) 0.0525(11) Uani 1 1 d . . .
C18 C 0.7618(3) 0.3224(3) -0.04257(15) 0.0710(16) Uani 1 1 d . . .
C19 C 0.8115(5) 0.3139(4) -0.0586(3) 0.132(4) Uani 1 1 d . . .
H19A H 0.8518 0.3466 -0.0523 0.198 Uiso 1 1 calc R . .
H19B H 0.8074 0.3152 -0.0810 0.198 Uiso 1 1 calc R . .
H19C H 0.8069 0.2745 -0.0527 0.198 Uiso 1 1 calc R . .
C101 C 0.5566(5) 0.0651(5) -0.0425(3) 0.120(3) Uani 1 1 d . . .
C102 C 0.6260(3) 0.1099(3) -0.03351(18) 0.0840(19) Uani 1 1 d . . .
C103 C 0.6706(4) 0.1064(4) -0.0513(2) 0.105(3) Uani 1 1 d . . .
H10C H 0.6582 0.0787 -0.0682 0.09(2) Uiso 1 1 calc R . .
C104 C 0.7327(3) 0.1428(3) -0.04481(18) 0.084(2) Uani 1 1 d . . .
C105 C 0.7799(5) 0.1363(5) -0.0656(3) 0.129(4) Uani 1 1 d . . .
C106 C 0.7741(6) 0.2006(6) 0.1286(3) 0.166(5) Uani 1 1 d DU . .
C107 C 0.7879(5) 0.2152(4) 0.0920(2) 0.109(2) Uani 1 1 d U A .
C108 C 0.8463(5) 0.2297(5) 0.0801(3) 0.127(3) Uani 1 1 d U . .
H10B H 0.8754 0.2287 0.0935 0.16(4) Uiso 1 1 calc R A .
C109 C 0.8615(4) 0.2455(4) 0.0489(3) 0.118(3) Uani 1 1 d U A .
C110 C 0.9281(6) 0.2631(6) 0.0375(3) 0.165(4) Uani 1 1 d DU . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Tb Tb -0.1723 4.1537 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O8 Tb1 O8 79.79(18) . 3_665
O8 Tb1 O8 79.79(18) . 2_655
O8 Tb1 O8 79.79(18) 3_665 2_655
O8 Tb1 O7 52.58(14) . .
O8 Tb1 O7 75.20(15) 3_665 .
O8 Tb1 O7 128.97(15) 2_655 .
O8 Tb1 O7 128.97(15) . 3_665
O8 Tb1 O7 52.58(14) 3_665 3_665
O8 Tb1 O7 75.20(15) 2_655 3_665
O7 Tb1 O7 118.67(4) . 3_665
O8 Tb1 O7 75.20(14) . 2_655
O8 Tb1 O7 128.97(15) 3_665 2_655
O8 Tb1 O7 52.58(14) 2_655 2_655
O7 Tb1 O7 118.67(4) . 2_655
O7 Tb1 O7 118.67(4) 3_665 2_655
O8 Tb1 O6 85.65(15) . 2_655
O8 Tb1 O6 152.45(14) 3_665 2_655
O8 Tb1 O6 120.57(13) 2_655 2_655
O7 Tb1 O6 77.37(12) . 2_655
O7 Tb1 O6 145.24(12) 3_665 2_655
O7 Tb1 O6 67.98(12) 2_655 2_655
O8 Tb1 O6 120.57(13) . .
O8 Tb1 O6 85.65(15) 3_665 .
O8 Tb1 O6 152.45(14) 2_655 .
O7 Tb1 O6 67.98(12) . .
O7 Tb1 O6 77.37(12) 3_665 .
O7 Tb1 O6 145.24(12) 2_655 .
O6 Tb1 O6 81.81(12) 2_655 .
O8 Tb1 O6 152.45(14) . 3_665
O8 Tb1 O6 120.57(13) 3_665 3_665
O8 Tb1 O6 85.65(15) 2_655 3_665
O7 Tb1 O6 145.24(12) . 3_665
O7 Tb1 O6 67.98(12) 3_665 3_665
O7 Tb1 O6 77.37(12) 2_655 3_665
O6 Tb1 O6 81.81(12) 2_655 3_665
O6 Tb1 O6 81.81(12) . 3_665
O8 Tb1 C18 25.52(16) . .
O8 Tb1 C18 75.27(17) 3_665 .
O8 Tb1 C18 103.56(19) 2_655 .
O7 Tb1 C18 27.09(16) . .
O7 Tb1 C18 127.53(15) 3_665 .
O7 Tb1 C18 96.99(15) 2_655 .
O6 Tb1 C18 81.51(16) 2_655 .
O6 Tb1 C18 95.06(16) . .
O6 Tb1 C18 163.30(16) 3_665 .
O8 Tb1 C18 103.56(19) . 3_665
O8 Tb1 C18 25.52(16) 3_665 3_665
O8 Tb1 C18 75.27(17) 2_655 3_665
O7 Tb1 C18 96.99(15) . 3_665
O7 Tb1 C18 27.09(16) 3_665 3_665
O7 Tb1 C18 127.53(15) 2_655 3_665
O6 Tb1 C18 163.30(16) 2_655 3_665
O6 Tb1 C18 81.51(16) . 3_665
O6 Tb1 C18 95.06(16) 3_665 3_665
C18 Tb1 C18 100.72(18) . 3_665
O8 Tb1 C18 75.27(17) . 2_655
O8 Tb1 C18 103.56(19) 3_665 2_655
O8 Tb1 C18 25.52(16) 2_655 2_655
O7 Tb1 C18 127.53(15) . 2_655
O7 Tb1 C18 96.99(15) 3_665 2_655
O7 Tb1 C18 27.09(16) 2_655 2_655
O6 Tb1 C18 95.06(16) 2_655 2_655
O6 Tb1 C18 163.30(16) . 2_655
O6 Tb1 C18 81.51(16) 3_665 2_655
C18 Tb1 C18 100.72(18) . 2_655
C18 Tb1 C18 100.72(18) 3_665 2_655
O7 Eu1 O4 97.39(17) . .
O7 Eu1 O2 76.91(15) . .
O4 Eu1 O2 68.98(17) . .
O7 Eu1 O1 82.49(14) . .
O4 Eu1 O1 137.41(16) . .
O2 Eu1 O1 69.59(15) . .
O7 Eu1 O5 72.10(14) . .
O4 Eu1 O5 74.56(15) . .
O2 Eu1 O5 127.81(15) . .
O1 Eu1 O5 142.36(13) . .
O7 Eu1 O3 140.28(13) . .
O4 Eu1 O3 70.59(19) . .
O2 Eu1 O3 127.75(16) . .
O1 Eu1 O3 132.28(14) . .
O5 Eu1 O3 68.22(14) . .
O7 Eu1 O6 69.15(12) . .
O4 Eu1 O6 145.94(14) . .
O2 Eu1 O6 132.41(14) . .
O1 Eu1 O6 73.68(13) . .
O5 Eu1 O6 71.55(12) . .
O3 Eu1 O6 99.34(15) . .
O7 Eu1 N2 129.73(13) . .
O4 Eu1 N2 132.03(18) . .
O2 Eu1 N2 123.84(14) . .
O1 Eu1 N2 67.74(14) . .
O5 Eu1 N2 108.26(15) . .
O3 Eu1 N2 67.03(15) . .
O6 Eu1 N2 64.17(12) . .
O7 Eu1 N1 149.38(15) . .
O4 Eu1 N1 81.00(16) . .
O2 Eu1 N1 74.00(16) . .
O1 Eu1 N1 78.65(14) . .
O5 Eu1 N1 134.98(15) . .
O3 Eu1 N1 68.20(15) . .
O6 Eu1 N1 126.62(13) . .
N2 Eu1 N1 63.30(14) . .
O7 Eu1 Tb1 33.96(9) . .
O4 Eu1 Tb1 121.95(13) . .
O2 Eu1 Tb1 107.53(11) . .
O1 Eu1 Tb1 80.03(10) . .
O5 Eu1 Tb1 63.32(9) . .
O3 Eu1 Tb1 121.57(11) . .
O6 Eu1 Tb1 35.68(8) . .
N2 Eu1 Tb1 99.23(9) . .
N1 Eu1 Tb1 156.45(10) . .
C102 O1 Eu1 136.3(4) . .
C104 O2 Eu1 136.8(4) . .
C107 O3 Eu1 133.6(6) . .
C109 O4 Eu1 136.4(6) . .
C17 O5 Eu1 147.1(4) 2_655 .
C17 O6 Tb1 128.0(3) . .
C17 O6 Eu1 122.8(3) . .
Tb1 O6 Eu1 108.42(12) . .
C18 O7 Eu1 153.5(4) . .
C18 O7 Tb1 92.4(4) . .
Eu1 O7 Tb1 113.46(14) . .
C18 O8 Tb1 95.2(4) . .
C5 N1 C1 118.7(5) . .
C5 N1 Eu1 120.1(3) . .
C1 N1 Eu1 121.1(4) . .
C16 N2 C6 118.2(4) . .
C16 N2 Eu1 118.8(3) . .
C6 N2 Eu1 122.2(3) . .
O23 N3 O22 122.4(8) . .
O23 N3 C12 118.9(10) . .
O22 N3 C12 118.8(10) . .
N1 C1 C2 122.3(7) . .
C1 C2 C3 118.4(7) . .
C4 C3 C2 119.5(7) . .
C3 C4 C5 119.9(8) . .
N1 C5 C4 121.1(6) . .
N1 C5 C6 117.4(5) . .
C4 C5 C6 121.5(6) . .
N2 C6 C7 122.4(5) . .
N2 C6 C5 115.4(5) . .
C7 C6 C5 122.2(5) . .
C8 C7 C6 119.0(5) . .
C7 C8 C15 118.4(5) . .
C7 C8 C9 120.3(5) . .
C15 C8 C9 121.3(5) . .
C10 C9 C14 118.6(6) . .
C10 C9 C8 121.2(6) . .
C14 C9 C8 120.2(6) . .
C11 C10 C9 122.0(7) . .
C10 C11 C12 118.7(7) . .
C11 C12 C13 121.8(6) . .
C11 C12 N3 119.3(8) . .
C13 C12 N3 118.8(8) . .
C12 C13 C14 119.3(7) . .
C9 C14 C13 119.6(7) . .
C16 C15 C8 118.2(5) . .
N2 C16 C15 123.7(5) . .
N2 C16 C17 115.9(4) . .
C15 C16 C17 120.4(4) . .
O5 C17 O6 126.7(5) 3_665 .
O5 C17 C16 116.5(4) 3_665 .
O6 C17 C16 116.9(4) . .
O8 C18 O7 119.7(5) . .
O8 C18 C19 122.7(6) . .
O7 C18 C19 117.6(6) . .
O8 C18 Tb1 59.3(3) . .
O7 C18 Tb1 60.5(3) . .
C19 C18 Tb1 177.8(5) . .
F1 C101 F2 106.5(11) . .
F1 C101 F3 109.4(10) . .
F2 C101 F3 107.6(9) . .
F1 C101 C102 112.0(8) . .
F2 C101 C102 113.1(9) . .
F3 C101 C102 108.1(9) . .
O1 C102 C103 127.9(7) . .
O1 C102 C101 115.1(7) . .
C103 C102 C101 117.0(7) . .
C104 C103 C102 121.4(7) . .
O2 C104 C103 127.2(6) . .
O2 C104 C105 114.1(7) . .
C103 C104 C105 118.7(7) . .
F5 C105 F6 111.1(10) . .
F5 C105 F4 107.1(12) . .
F6 C105 F4 98.6(9) . .
F5 C105 C104 114.5(7) . .
F6 C105 C104 114.0(10) . .
F4 C105 C104 110.2(9) . .
F8 C106 F8' 134.6(17) . .
F8 C106 F9' 60.5(11) . .
F8' C106 F9' 112.7(13) . .
F8 C106 F7' 47.0(10) . .
F8' C106 F7' 112.4(11) . .
F9' C106 F7' 107.1(11) . .
F8 C106 F9 112.0(13) . .
F8' C106 F9 51.7(10) . .
F9' C106 F9 153.0(16) . .
F7' C106 F9 68.1(10) . .
F8 C106 F7 110.9(14) . .
F8' C106 F7 54.8(10) . .
F9' C106 F7 59.7(11) . .
F7' C106 F7 139.9(16) . .
F9 C106 F7 105.8(13) . .
F8 C106 C107 112.7(15) . .
F8' C106 C107 112.2(11) . .
F9' C106 C107 105.6(10) . .
F7' C106 C107 106.3(12) . .
F9 C106 C107 101.2(13) . .
F7 C106 C107 113.7(12) . .
O3 C107 C108 128.1(10) . .
O3 C107 C106 112.7(10) . .
C108 C107 C106 119.1(9) . .
C109 C108 C107 121.3(8) . .
O4 C109 C108 128.1(9) . .
O4 C109 C110 113.4(11) . .
C108 C109 C110 118.5(9) . .
F12 C110 F12' 142.1(17) . .
F12 C110 F10' 73.7(11) . .
F12' C110 F10' 111.6(12) . .
F12 C110 F10 111.7(13) . .
F12' C110 F10 36.4(10) . .
F10' C110 F10 133.0(13) . .
F12 C110 F11 112.6(12) . .
F12' C110 F11 74.9(11) . .
F10' C110 F11 40.2(9) . .
F10 C110 F11 107.0(11) . .
F12 C110 F11' 37.2(10) . .
F12' C110 F11' 112.5(13) . .
F10' C110 F11' 107.1(12) . .
F10 C110 F11' 77.1(12) . .
F11 C110 F11' 138.8(16) . .
F12 C110 C109 107.5(13) . .
F12' C110 C109 105.3(13) . .
F10' C110 C109 110.5(12) . .
F10 C110 C109 111.6(10) . .
F11 C110 C109 106.4(14) . .
F11' C110 C109 109.9(11) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Tb1 O8 2.436(4) .
Tb1 O8 2.436(4) 3_665
Tb1 O8 2.436(4) 2_655
Tb1 O7 2.459(4) .
Tb1 O7 2.459(4) 3_665
Tb1 O7 2.459(4) 2_655
Tb1 O6 2.482(3) 2_655
Tb1 O6 2.482(3) .
Tb1 O6 2.482(3) 3_665
Tb1 C18 2.823(6) .
Tb1 C18 2.823(6) 3_665
Tb1 C18 2.823(6) 2_655
Eu1 O7 2.370(4) .
Eu1 O4 2.379(4) .
Eu1 O2 2.417(4) .
Eu1 O1 2.419(4) .
Eu1 O5 2.435(4) .
Eu1 O3 2.476(5) .
Eu1 O6 2.495(3) .
Eu1 N2 2.549(4) .
Eu1 N1 2.613(4) .
F1 C101 1.295(11) .
F2 C101 1.301(12) .
F3 C101 1.318(13) .
F4 C105 1.303(15) .
F5 C105 1.234(11) .
F6 C105 1.290(12) .
F7 C106 1.365(15) .
F8 C106 1.262(15) .
F9 C106 1.350(14) .
F7' C106 1.340(13) .
F8' C106 1.276(13) .
F9' C106 1.339(14) .
F10 C110 1.358(14) .
F11 C110 1.368(14) .
F12 C110 1.265(14) .
F10' C110 1.318(13) .
F11' C110 1.372(14) .
F12' C110 1.291(14) .
O1 C102 1.235(7) .
O2 C104 1.250(8) .
O3 C107 1.221(9) .
O4 C109 1.254(11) .
O5 C17 1.241(6) 2_655
O6 C17 1.260(6) .
O7 C18 1.287(7) .
O8 C18 1.221(8) .
O22 N3 1.204(12) .
O23 N3 1.179(12) .
N1 C5 1.332(8) .
N1 C1 1.343(7) .
N2 C16 1.315(6) .
N2 C6 1.352(7) .
N3 C12 1.493(9) .
C1 C2 1.378(10) .
C2 C3 1.385(12) .
C3 C4 1.339(11) .
C4 C5 1.400(8) .
C5 C6 1.509(8) .
C6 C7 1.385(8) .
C7 C8 1.380(8) .
C8 C15 1.409(8) .
C8 C9 1.498(8) .
C9 C10 1.377(9) .
C9 C14 1.377(9) .
C10 C11 1.356(10) .
C11 C12 1.357(12) .
C12 C13 1.358(12) .
C13 C14 1.393(10) .
C15 C16 1.379(7) .
C16 C17 1.525(7) .
C17 O5 1.241(6) 3_665
C18 C19 1.517(9) .
C101 C102 1.563(12) .
C102 C103 1.380(10) .
C103 C104 1.372(11) .
C104 C105 1.539(10) .
C106 C107 1.595(16) .
C107 C108 1.404(16) .
C108 C109 1.379(16) .
C109 C110 1.562(16) .
