#------------------------------------------------------------------------------
#$Date: 2016-03-24 03:06:31 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179613 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/77/4507737.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4507737
loop_
_publ_author_name
'Yang, Jü-Hua'
'Wu, Xin-Yi'
'He, Run-Tian'
'Ren, Zhi-Gang'
'Li, Hong-Xi'
'Wang, Hui-Fang'
'Lang, Jian-Ping'
_publ_section_title
;
 Degradation versus Expansion of the AgX Frameworks: Formation of
 Oligomeric and Polymeric Silver Complexes from Reactions of Bulk AgX
 withN,N-Bis(diphenylphosphanylmethyl)-2-aminopyridine
;
_journal_issue                   5
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              2124
_journal_paper_doi               10.1021/cg4002048
_journal_volume                  13
_journal_year                    2013
_chemical_formula_moiety         'C97 H84 Ag4 N10 P6, C H2 Cl2'
_chemical_formula_sum            'C98 H86 Ag4 Cl2 N10 P6'
_chemical_formula_weight         2091.97
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 123.51(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   20.499(4)
_cell_length_b                   11.142(2)
_cell_length_c                   26.080(10)
_cell_measurement_reflns_used    22873
_cell_measurement_temperature    223(2)
_cell_measurement_theta_max      27.4932
_cell_measurement_theta_min      2.9829
_cell_volume                     4967(3)
_computing_cell_refinement       'CrystalClear, Ver. 1.30 (Rigaku/MSC, 2001)'
_computing_data_collection       'CrystalClear, Ver. 1.30 (Rigaku/MSC, 2001)'
_computing_data_reduction
'CrystalStructure, Ver. 3.60 (Rigaku/MSC,2004)'
_computing_molecular_graphics    'SHELXS-97 (Sheldrick, 1990)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      223(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type  'Rigaku Mercury'
_diffrn_measurement_method       /w
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0644
_diffrn_reflns_av_sigmaI/netI    0.0544
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -31
_diffrn_reflns_number            38005
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         3.00
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.976
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.7619
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'Jacobson, R. (1998) Private communication to Rigaku Company, Tokyo, Japan.'
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.399
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             2112
_exptl_crystal_size_max          0.60
_exptl_crystal_size_mid          0.50
_exptl_crystal_size_min          0.30
_refine_diff_density_max         1.342
_refine_diff_density_min         -0.883
_refine_diff_density_rms         0.107
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.074
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     447
_refine_ls_number_reflns         8615
_refine_ls_number_restraints     5
_refine_ls_restrained_S_all      1.074
_refine_ls_R_factor_all          0.0828
_refine_ls_R_factor_gt           0.0685
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0943P)²+8.3572P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1758
_refine_ls_wR_factor_ref         0.1880
_reflns_number_gt                7112
_reflns_number_total             8615
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg4002048_si_002.cif
_cod_data_source_block           6
_cod_original_cell_volume        4967(2)
_cod_original_sg_symbol_H-M      'P 2/c'
_cod_database_code               4507737
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.16813(2) -0.03749(4) -0.105761(18) 0.04283(17) Uani 1 1 d . . .
Ag2 Ag 0.20987(4) 0.32789(5) -0.21729(3) 0.0720(2) Uani 1 1 d . . .
P1 P 0.26479(9) -0.14292(14) -0.12054(7) 0.0460(4) Uani 1 1 d . . .
P2 P 0.26865(9) 0.01864(14) 0.00339(7) 0.0447(4) Uani 1 1 d . . .
P3 P 0.03323(8) -0.08381(13) -0.13961(6) 0.0396(3) Uani 1 1 d . . .
N1 N 0.4949(4) -0.1783(8) 0.0220(4) 0.1028(13) Uani 1 1 d . . .
N2 N 0.3905(3) -0.0477(5) -0.0087(2) 0.0521(12) Uani 1 1 d . . .
N3 N -0.0481(4) -0.3559(6) -0.2376(3) 0.0695(18) Uani 0.50 1 d P . .
N4 N 0.0000 -0.1726(6) -0.2500 0.0428(15) Uani 1 2 d S . .
N5 N 0.1580(4) 0.1534(5) -0.1497(3) 0.0695(13) Uani 1 1 d . . .
N6 N 0.2681(6) 0.4693(7) -0.2896(4) 0.102(2) Uani 1 1 d . . .
C1 C 0.4577(5) -0.1021(10) 0.0381(5) 0.1028(13) Uani 1 1 d . . .
C2 C 0.4851(5) -0.0780(10) 0.0998(5) 0.1028(13) Uani 1 1 d . . .
H2 H 0.4602 -0.0228 0.1109 0.123 Uiso 1 1 calc R . .
C3 C 0.5522(5) -0.1421(10) 0.1437(5) 0.1028(13) Uani 1 1 d . . .
H3 H 0.5735 -0.1294 0.1857 0.123 Uiso 1 1 calc R . .
C4 C 0.5860(5) -0.2200(10) 0.1272(5) 0.1028(13) Uani 1 1 d . . .
H4 H 0.6297 -0.2639 0.1573 0.123 Uiso 1 1 calc R . .
C5 C 0.5578(5) -0.2361(10) 0.0676(5) 0.1028(13) Uani 1 1 d . . .
H5 H 0.5836 -0.2908 0.0571 0.123 Uiso 1 1 calc R . .
C6 C 0.3628(4) -0.0712(6) -0.0729(3) 0.0511(14) Uani 1 1 d . . .
H6A H 0.4011 -0.1229 -0.0735 0.061 Uiso 1 1 calc R . .
H6B H 0.3614 0.0051 -0.0922 0.061 Uiso 1 1 calc R . .
C7 C 0.3577(4) 0.0557(6) 0.0033(3) 0.0502(14) Uani 1 1 d . . .
H7A H 0.3440 0.1169 -0.0281 0.060 Uiso 1 1 calc R . .
H7B H 0.3976 0.0899 0.0433 0.060 Uiso 1 1 calc R . .
C8 C 0.2556(3) -0.1412(6) -0.1943(3) 0.0482(14) Uani 1 1 d . . .
C9 C 0.2417(4) -0.0309(6) -0.2237(3) 0.0602(17) Uani 1 1 d . . .
H9 H 0.2370 0.0385 -0.2055 0.072 Uiso 1 1 calc R . .
C10 C 0.2345(4) -0.0226(7) -0.2794(3) 0.0673(19) Uani 1 1 d . . .
H10 H 0.2252 0.0521 -0.2990 0.081 Uiso 1 1 calc R . .
C11 C 0.2413(4) -0.1252(7) -0.3060(3) 0.0677(19) Uani 1 1 d . . .
H11 H 0.2373 -0.1200 -0.3437 0.081 Uiso 1 1 calc R . .
C12 C 0.2538(5) -0.2335(7) -0.2780(3) 0.0684(19) Uani 1 1 d . . .
H12 H 0.2572 -0.3029 -0.2969 0.082 Uiso 1 1 calc R . .
C13 C 0.2614(4) -0.2430(6) -0.2225(3) 0.0553(15) Uani 1 1 d . . .
H13 H 0.2705 -0.3184 -0.2035 0.066 Uiso 1 1 calc R . .
C14 C 0.2772(5) -0.3004(7) -0.0984(4) 0.0752(9) Uani 1 1 d . . .
C15 C 0.2121(5) -0.3642(7) -0.1128(4) 0.0752(9) Uani 1 1 d . . .
H15 H 0.1627 -0.3272 -0.1356 0.090 Uiso 1 1 calc R . .
C16 C 0.2177(5) -0.4819(7) -0.0943(4) 0.0752(9) Uani 1 1 d . . .
H16 H 0.1721 -0.5241 -0.1050 0.090 Uiso 1 1 calc R . .
C17 C 0.2889(5) -0.5381(7) -0.0606(4) 0.0752(9) Uani 1 1 d . . .
H17 H 0.2927 -0.6173 -0.0468 0.090 Uiso 1 1 calc R . .
C18 C 0.3547(5) -0.4766(7) -0.0474(4) 0.0752(9) Uani 1 1 d . . .
H18 H 0.4038 -0.5145 -0.0259 0.090 Uiso 1 1 calc R . .
C19 C 0.3480(5) -0.3588(7) -0.0658(4) 0.0752(9) Uani 1 1 d . . .
H19 H 0.3934 -0.3170 -0.0558 0.090 Uiso 1 1 calc R . .
C20 C 0.2527(4) 0.1543(6) 0.0336(3) 0.0484(14) Uani 1 1 d . . .
C21 C 0.3112(4) 0.2247(7) 0.0789(3) 0.0662(19) Uani 1 1 d . . .
H21 H 0.3637 0.2035 0.0958 0.079 Uiso 1 1 calc R . .
C22 C 0.2944(5) 0.3268(7) 0.1003(4) 0.072(2) Uani 1 1 d . . .
H22 H 0.3352 0.3738 0.1315 0.086 Uiso 1 1 calc R . .
C23 C 0.2186(5) 0.3582(6) 0.0759(3) 0.069(2) Uani 1 1 d . . .
H23 H 0.2077 0.4278 0.0902 0.083 Uiso 1 1 calc R . .
C24 C 0.1584(5) 0.2915(8) 0.0315(4) 0.080(2) Uani 1 1 d . . .
H24 H 0.1063 0.3131 0.0158 0.096 Uiso 1 1 calc R . .
C25 C 0.1759(4) 0.1881(7) 0.0091(3) 0.0669(19) Uani 1 1 d . . .
H25 H 0.1349 0.1423 -0.0226 0.080 Uiso 1 1 calc R . .
C26 C 0.2998(6) -0.0956(8) 0.0622(4) 0.0856(11) Uani 1 1 d . . .
C27 C 0.3137(6) -0.0733(8) 0.1193(4) 0.0856(11) Uani 1 1 d . . .
H27 H 0.3113 0.0052 0.1314 0.103 Uiso 1 1 calc R . .
C28 C 0.3319(6) -0.1727(8) 0.1600(4) 0.0856(11) Uani 1 1 d . . .
H28 H 0.3401 -0.1597 0.1988 0.103 Uiso 1 1 calc R . .
C29 C 0.3372(6) -0.2816(8) 0.1436(4) 0.0856(11) Uani 1 1 d . . .
H29 H 0.3507 -0.3445 0.1718 0.103 Uiso 1 1 calc R . .
C30 C 0.3240(6) -0.3080(8) 0.0877(4) 0.0856(11) Uani 1 1 d . . .
H30 H 0.3275 -0.3872 0.0770 0.103 Uiso 1 1 calc R . .
C31 C 0.3051(6) -0.2135(8) 0.0469(4) 0.0856(11) Uani 1 1 d . . .
H31 H 0.2956 -0.2296 0.0080 0.103 Uiso 1 1 calc R . .
C32 C 0.0000 -0.2990(7) -0.2500 0.0406(17) Uani 1 2 d S . .
C33 C -0.0481(4) -0.3559(6) -0.2376(3) 0.0695(18) Uani 0.50 1 d P . .
C34 C -0.0454(7) -0.4796(9) -0.2369(5) 0.108(4) Uani 1 1 d . . .
H34 H -0.0760 -0.5216 -0.2268 0.130 Uiso 1 1 d R . .
C35 C 0.0000 -0.5425(13) -0.2500 0.135(8) Uani 1 2 d S . .
H35 H 0.0000 -0.6268 -0.2500 0.162 Uiso 1 2 calc SR . .
C36 C -0.0358(4) -0.1061(5) -0.2246(2) 0.0465(13) Uani 1 1 d . . .
H36A H -0.0823 -0.1493 -0.2328 0.056 Uiso 1 1 calc R . .
H36B H -0.0528 -0.0277 -0.2449 0.056 Uiso 1 1 calc R . .
C37 C 0.0252(3) -0.2198(5) -0.1048(2) 0.0427(12) Uani 1 1 d . . .
C38 C 0.0926(4) -0.2746(6) -0.0602(3) 0.0615(17) Uani 1 1 d . . .
H38 H 0.1410 -0.2382 -0.0463 0.074 Uiso 1 1 calc R . .
C39 C 0.0907(6) -0.3841(8) -0.0348(4) 0.085(3) Uani 1 1 d . . .
H39 H 0.1376 -0.4206 -0.0040 0.102 Uiso 1 1 calc R . .
C40 C 0.0206(6) -0.4381(7) -0.0547(4) 0.081(2) Uani 1 1 d . . .
H40 H 0.0196 -0.5125 -0.0382 0.097 Uiso 1 1 calc R . .
C41 C -0.0480(5) -0.3841(7) -0.0987(4) 0.076(2) Uani 1 1 d . . .
H41 H -0.0962 -0.4206 -0.1120 0.091 Uiso 1 1 calc R . .
C42 C -0.0459(4) -0.2739(7) -0.1237(3) 0.0611(17) Uani 1 1 d . . .
H42 H -0.0930 -0.2362 -0.1535 0.073 Uiso 1 1 calc R . .
C43 C -0.0156(3) 0.0331(5) -0.1233(2) 0.0445(13) Uani 1 1 d . . .
C44 C -0.0203(4) 0.1486(6) -0.1470(3) 0.0618(17) Uani 1 1 d . . .
H44 H -0.0004 0.1625 -0.1715 0.074 Uiso 1 1 calc R . .
C45 C -0.0540(5) 0.2417(7) -0.1345(3) 0.074(2) Uani 1 1 d . . .
H45 H -0.0576 0.3184 -0.1509 0.089 Uiso 1 1 calc R . .
C46 C -0.0823(5) 0.2229(8) -0.0983(3) 0.078(2) Uani 1 1 d . . .
H46 H -0.1056 0.2866 -0.0903 0.093 Uiso 1 1 calc R . .
C47 C -0.0771(5) 0.1126(8) -0.0736(4) 0.078(2) Uani 1 1 d . . .
H47 H -0.0958 0.1010 -0.0482 0.093 Uiso 1 1 calc R . .
C48 C -0.0439(4) 0.0164(7) -0.0862(3) 0.0613(17) Uani 1 1 d . . .
H48 H -0.0407 -0.0598 -0.0695 0.074 Uiso 1 1 calc R . .
C49 C 0.1746(5) 0.2203(6) -0.1731(4) 0.0695(13) Uani 1 1 d . . .
C50 C 0.2469(7) 0.4215(8) -0.2635(5) 0.102(2) Uani 1 1 d . . .
C51 C 0.447(2) 0.387(3) 0.3140(14) 0.212(17) Uiso 0.50 1 d PD . .
Cl1 Cl 0.495(2) 0.501(3) 0.3102(16) 0.271(13) Uiso 0.25 1 d PD A 1
Cl2 Cl 0.4925(11) 0.3459(17) 0.3882(8) 0.159(6) Uiso 0.25 1 d PD A 1
Cl1A Cl 0.494(2) 0.482(3) 0.3765(16) 0.283(14) Uiso 0.25 1 d PD A 2
Cl2A Cl 0.4695(12) 0.2583(18) 0.3545(9) 0.170(6) Uiso 0.25 1 d PD A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N5 Ag1 P3 103.59(17) . .
N5 Ag1 P2 97.05(17) . .
P3 Ag1 P2 121.30(5) . .
N5 Ag1 P1 102.22(16) . .
P3 Ag1 P1 132.54(5) . .
P2 Ag1 P1 93.87(6) . .
C50 Ag2 C49 175.1(3) . .
C14 P1 C8 105.0(3) . .
C14 P1 C6 107.0(3) . .
C8 P1 C6 98.3(3) . .
C14 P1 Ag1 112.7(3) . .
C8 P1 Ag1 121.7(2) . .
C6 P1 Ag1 110.4(2) . .
C20 P2 C26 106.3(3) . .
C20 P2 C7 103.1(3) . .
C26 P2 C7 105.5(4) . .
C20 P2 Ag1 117.96(19) . .
C26 P2 Ag1 118.0(3) . .
C7 P2 Ag1 104.17(19) . .
C37 P3 C43 105.4(3) . .
C37 P3 C36 105.2(3) . .
C43 P3 C36 102.5(3) . .
C37 P3 Ag1 113.00(19) . .
C43 P3 Ag1 114.8(2) . .
C36 P3 Ag1 114.8(2) . .
C5 N1 C1 117.1(10) . .
C1 N2 C7 120.9(7) . .
C1 N2 C6 120.1(7) . .
C7 N2 C6 117.1(5) . .
C32 N3 C34 116.3(8) . .
C32 N4 C36 121.0(3) . .
C32 N4 C36 121.0(3) . 2_554
C36 N4 C36 118.0(7) . 2_554
C49 N5 Ag1 151.9(6) . .
N1 C1 N2 117.3(10) . .
N1 C1 C2 122.5(9) . .
N2 C1 C2 120.2(10) . .
C3 C2 C1 115.4(11) . .
C3 C2 H2 122.3 . .
C1 C2 H2 122.3 . .
C4 C3 C2 121.4(12) . .
C4 C3 H3 119.3 . .
C2 C3 H3 119.3 . .
C3 C4 C5 119.9(10) . .
C3 C4 H4 120.0 . .
C5 C4 H4 120.0 . .
C4 C5 N1 123.5(11) . .
C4 C5 H5 118.2 . .
N1 C5 H5 118.2 . .
N2 C6 P1 115.8(4) . .
N2 C6 H6A 108.3 . .
P1 C6 H6A 108.3 . .
N2 C6 H6B 108.3 . .
P1 C6 H6B 108.3 . .
H6A C6 H6B 107.4 . .
N2 C7 P2 113.2(4) . .
N2 C7 H7A 108.9 . .
P2 C7 H7A 108.9 . .
N2 C7 H7B 108.9 . .
P2 C7 H7B 108.9 . .
H7A C7 H7B 107.8 . .
C9 C8 C13 118.7(6) . .
C9 C8 P1 117.4(5) . .
C13 C8 P1 123.9(5) . .
C10 C9 C8 120.6(6) . .
C10 C9 H9 119.7 . .
C8 C9 H9 119.7 . .
C9 C10 C11 119.4(7) . .
C9 C10 H10 120.3 . .
C11 C10 H10 120.3 . .
C12 C11 C10 120.2(7) . .
C12 C11 H11 119.9 . .
C10 C11 H11 119.9 . .
C11 C12 C13 121.0(7) . .
C11 C12 H12 119.5 . .
C13 C12 H12 119.5 . .
C12 C13 C8 120.1(7) . .
C12 C13 H13 120.0 . .
C8 C13 H13 120.0 . .
C15 C14 C19 117.4(7) . .
C15 C14 P1 118.0(6) . .
C19 C14 P1 124.6(6) . .
C14 C15 C16 121.1(8) . .
C14 C15 H15 119.4 . .
C16 C15 H15 119.4 . .
C17 C16 C15 120.8(8) . .
C17 C16 H16 119.6 . .
C15 C16 H16 119.6 . .
C16 C17 C18 118.8(7) . .
C16 C17 H17 120.6 . .
C18 C17 H17 120.6 . .
C17 C18 C19 119.5(8) . .
C17 C18 H18 120.3 . .
C19 C18 H18 120.3 . .
C14 C19 C18 122.3(8) . .
C14 C19 H19 118.8 . .
C18 C19 H19 118.8 . .
C21 C20 C25 118.2(6) . .
C21 C20 P2 124.5(5) . .
C25 C20 P2 117.3(5) . .
C20 C21 C22 121.3(7) . .
C20 C21 H21 119.4 . .
C22 C21 H21 119.3 . .
C23 C22 C21 119.6(7) . .
C23 C22 H22 120.2 . .
C21 C22 H22 120.2 . .
C24 C23 C22 121.7(7) . .
C24 C23 H23 119.2 . .
C22 C23 H23 119.2 . .
C23 C24 C25 118.5(7) . .
C23 C24 H24 120.8 . .
C25 C24 H24 120.8 . .
C20 C25 C24 120.7(7) . .
C20 C25 H25 119.6 . .
C24 C25 H25 119.6 . .
C27 C26 C31 118.5(7) . .
C27 C26 P2 123.6(7) . .
C31 C26 P2 117.8(6) . .
C26 C27 C28 118.4(8) . .
C26 C27 H27 120.8 . .
C28 C27 H27 120.8 . .
C29 C28 C27 120.5(8) . .
C29 C28 H28 119.8 . .
C27 C28 H28 119.8 . .
C28 C29 C30 123.2(8) . .
C28 C29 H29 118.4 . .
C30 C29 H29 118.4 . .
C29 C30 C31 117.6(9) . .
C29 C30 H30 121.2 . .
C31 C30 H30 121.2 . .
C30 C31 C26 121.9(8) . .
C30 C31 H31 119.1 . .
C26 C31 H31 119.1 . .
N3 C32 C33 124.1(9) . 2_554
N3 C32 N3 124.1(9) . 2_554
C33 C32 N3 0.0(4) 2_554 2_554
N3 C32 N4 118.0(4) . .
C33 C32 N4 118.0(4) 2_554 .
N3 C32 N4 118.0(4) 2_554 .
C35 C34 N3 122.8(11) . .
C35 C34 H34 118.6 . .
N3 C34 H34 118.6 . .
C34 C35 C34 117.6(14) 2_554 .
C34 C35 H35 121.2 2_554 .
C34 C35 H35 121.2 . .
N4 C36 P3 111.6(3) . .
N4 C36 H36A 109.3 . .
P3 C36 H36A 109.3 . .
N4 C36 H36B 109.3 . .
P3 C36 H36B 109.3 . .
H36A C36 H36B 108.0 . .
C38 C37 C42 118.6(6) . .
C38 C37 P3 118.1(5) . .
C42 C37 P3 123.3(5) . .
C37 C38 C39 121.0(7) . .
C37 C38 H38 119.5 . .
C39 C38 H38 119.5 . .
C40 C39 C38 120.1(8) . .
C40 C39 H39 119.9 . .
C38 C39 H39 119.9 . .
C39 C40 C41 120.2(7) . .
C39 C40 H40 119.9 . .
C41 C40 H40 119.9 . .
C40 C41 C42 119.6(7) . .
C40 C41 H41 120.2 . .
C42 C41 H41 120.2 . .
C37 C42 C41 120.6(7) . .
C37 C42 H42 119.7 . .
C41 C42 H42 119.7 . .
C48 C43 C44 118.3(6) . .
C48 C43 P3 123.9(5) . .
C44 C43 P3 117.6(5) . .
C45 C44 C43 120.3(7) . .
C45 C44 H44 119.8 . .
C43 C44 H44 119.8 . .
C46 C45 C44 120.3(7) . .
C46 C45 H45 119.8 . .
C44 C45 H45 119.8 . .
C47 C46 C45 120.7(7) . .
C47 C46 H46 119.6 . .
C45 C46 H46 119.6 . .
C46 C47 C48 119.9(8) . .
C46 C47 H47 120.0 . .
C48 C47 H47 120.0 . .
C43 C48 C47 120.3(7) . .
C43 C48 H48 119.8 . .
C47 C48 H48 119.8 . .
N5 C49 Ag2 174.3(7) . .
N6 C50 Ag2 177.4(9) . .
Cl1 C51 Cl2 108(2) . .
Cl1 C51 Cl2A 137(3) . .
Cl2 C51 Cl2A 42.5(10) . .
Cl1 C51 Cl1A 62.6(18) . .
Cl2 C51 Cl1A 54.2(15) . .
Cl2A C51 Cl1A 96.6(19) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N5 2.370(6) .
Ag1 P3 2.4488(16) .
Ag1 P2 2.5027(18) .
Ag1 P1 2.5097(16) .
Ag2 C50 2.031(10) .
Ag2 C49 2.051(8) .
P1 C14 1.821(8) .
P1 C8 1.826(6) .
P1 C6 1.862(6) .
P2 C20 1.816(6) .
P2 C26 1.816(8) .
P2 C7 1.873(6) .
P3 C37 1.820(6) .
P3 C43 1.830(6) .
P3 C36 1.875(6) .
N1 C5 1.342(12) .
N1 C1 1.354(14) .
N2 C1 1.378(10) .
N2 C7 1.453(8) .
N2 C6 1.464(8) .
N3 C32 1.353(7) .
N3 C34 1.379(12) .
N4 C32 1.408(10) .
N4 C36 1.436(7) .
N4 C36 1.436(7) 2_554
N5 C49 1.128(9) .
N6 C50 1.125(11) .
C1 C2 1.406(15) .
C2 C3 1.405(13) .
C2 H2 0.9400 .
C3 C4 1.322(15) .
C3 H3 0.9400 .
C4 C5 1.338(15) .
C4 H4 0.9400 .
C5 H5 0.9400 .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C8 C9 1.392(9) .
C8 C13 1.392(9) .
C9 C10 1.380(10) .
C9 H9 0.9400 .
C10 C11 1.384(11) .
C10 H10 0.9400 .
C11 C12 1.361(11) .
C11 H11 0.9400 .
C12 C13 1.371(9) .
C12 H12 0.9400 .
C13 H13 0.9400 .
C14 C15 1.370(11) .
C14 C19 1.375(11) .
C15 C16 1.379(11) .
C15 H15 0.9400 .
C16 C17 1.371(11) .
C16 H16 0.9400 .
C17 C18 1.376(11) .
C17 H17 0.9400 .
C18 C19 1.378(11) .
C18 H18 0.9400 .
C19 H19 0.9400 .
C20 C21 1.373(9) .
C20 C25 1.384(9) .
C21 C22 1.393(10) .
C21 H21 0.9400 .
C22 C23 1.360(12) .
C22 H22 0.9400 .
C23 C24 1.355(12) .
C23 H23 0.9400 .
C24 C25 1.424(10) .
C24 H24 0.9400 .
C25 H25 0.9400 .
C26 C27 1.377(12) .
C26 C31 1.393(13) .
C27 C28 1.434(11) .
C27 H27 0.9400 .
C28 C29 1.311(12) .
C28 H28 0.9400 .
C29 C30 1.360(11) .
C29 H29 0.9400 .
C30 C31 1.391(11) .
C30 H30 0.9400 .
C31 H31 0.9400 .
C32 C33 1.353(7) 2_554
C32 N3 1.353(7) 2_554
C34 C35 1.351(14) .
C34 H34 0.9301 .
C35 C34 1.351(14) 2_554
C35 H35 0.9400 .
C36 H36A 0.9800 .
C36 H36B 0.9800 .
C37 C38 1.364(8) .
C37 C42 1.392(9) .
C38 C39 1.399(10) .
C38 H38 0.9400 .
C39 C40 1.367(13) .
C39 H39 0.9400 .
C40 C41 1.369(12) .
C40 H40 0.9400 .
C41 C42 1.402(11) .
C41 H41 0.9400 .
C42 H42 0.9400 .
C43 C48 1.388(9) .
C43 C44 1.407(9) .
C44 C45 1.382(9) .
C44 H44 0.9400 .
C45 C46 1.370(12) .
C45 H45 0.9400 .
C46 C47 1.363(12) .
C46 H46 0.9400 .
C47 C48 1.404(10) .
C47 H47 0.9400 .
C48 H48 0.9400 .
C51 Cl1 1.65(3) .
C51 Cl2 1.68(3) .
C51 Cl2A 1.69(3) .
C51 Cl1A 1.73(3) .
