#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/81/4508182.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4508182
loop_
_publ_author_name
'Zhang, Zhe'
'Ma, Jian-Fang'
'Liu, Ying-Ying'
'Kan, Wei-Qiu'
'Yang, Jin'
_publ_section_title
;
 A Series of Coordination Polymers Constructed from a Multidentate N-Donor
 Ligand and Varied Carboxylate Anions: Syntheses, Structures, and
 Luminescent Properties
;
_journal_issue                   10
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              4338
_journal_paper_doi               10.1021/cg400680r
_journal_volume                  13
_journal_year                    2013
_chemical_formula_moiety         'C42 H39 Ag5 N18 O16'
_chemical_formula_sum            'C42 H39 Ag5 N18 O16'
_chemical_formula_weight         1591.26
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.015(5)
_cell_angle_beta                 107.880(5)
_cell_angle_gamma                111.846(5)
_cell_formula_units_Z            1
_cell_length_a                   9.3480(5)
_cell_length_b                   12.3510(7)
_cell_length_c                   12.4570(6)
_cell_measurement_reflns_used    4059
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.0652
_cell_measurement_theta_min      3.2533
_cell_volume                     1200.99(14)
_computing_cell_refinement       CrysAlis
_computing_data_collection       'CrysAlis (Oxford Diffraction, 2006)'
_computing_data_reduction        CrysAlis
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.0
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Oxford Diffraction Gemini R Ultra'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0177
_diffrn_reflns_av_sigmaI/netI    0.0290
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            7275
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.35
_diffrn_reflns_theta_min         3.26
_exptl_absorpt_coefficient_mu    2.097
_exptl_absorpt_correction_T_max  0.7722
_exptl_absorpt_correction_T_min  0.5535
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis (Oxford Diffraction, 2006)
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.200
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             780
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.13
_refine_diff_density_max         1.351
_refine_diff_density_min         -0.838
_refine_diff_density_rms         0.096
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.051
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     367
_refine_ls_number_reflns         4375
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.051
_refine_ls_R_factor_all          0.0341
_refine_ls_R_factor_gt           0.0310
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0396P)²+1.5184P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0787
_refine_ls_wR_factor_ref         0.0813
_reflns_number_gt                4017
_reflns_number_total             4375
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            cg400680r_si_002.cif
_cod_data_source_block           Compound-6
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        1200.99(11)
_cod_original_sg_symbol_Hall     '-P 1 '
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4508182
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag -0.12661(3) -0.52562(3) 0.54699(3) 0.03520(10) Uani 1 1 d .
Ag2 Ag -1.33233(4) -0.95865(3) -0.04953(3) 0.04043(11) Uani 1 1 d .
Ag3 Ag 0.0000 0.0000 0.0000 0.04493(14) Uani 1 2 d S
C1 C -0.8818(4) -0.9464(3) 0.4531(3) 0.0177(6) Uani 1 1 d .
C2 C -0.9876(4) -0.8947(3) 0.4695(3) 0.0166(6) Uani 1 1 d .
C3 C -1.1071(4) -0.9485(3) 0.5152(3) 0.0166(6) Uani 1 1 d .
C4 C -0.7612(4) -0.8872(3) 0.3987(3) 0.0235(7) Uani 1 1 d .
H4A H -0.7355 -0.9485 0.3603 0.028 Uiso 1 1 calc R
H4B H -0.8156 -0.8589 0.3379 0.028 Uiso 1 1 calc R
C5 C -0.5265(4) -0.6665(4) 0.4889(4) 0.0323(8) Uani 1 1 d .
H5 H -0.5693 -0.6351 0.4311 0.039 Uiso 1 1 calc R
C6 C -0.3762(5) -0.6883(4) 0.6382(3) 0.0364(9) Uani 1 1 d .
H6 H -0.2865 -0.6704 0.7087 0.044 Uiso 1 1 calc R
C7 C -0.9607(4) -0.7732(3) 0.4476(3) 0.0205(7) Uani 1 1 d .
H7A H -1.0048 -0.7328 0.4933 0.025 Uiso 1 1 calc R
H7B H -0.8404 -0.7205 0.4773 0.025 Uiso 1 1 calc R
C8 C -1.1337(4) -0.8799(3) 0.2238(3) 0.0269(8) Uani 1 1 d .
H8 H -1.1622 -0.9616 0.2198 0.032 Uiso 1 1 calc R
C9 C -1.1096(5) -0.7186(4) 0.1807(4) 0.0341(9) Uani 1 1 d .
H9 H -1.1215 -0.6668 0.1364 0.041 Uiso 1 1 calc R
C10 C -1.2227(4) -0.8915(3) 0.5288(3) 0.0212(7) Uani 1 1 d .
H10A H -1.2962 -0.9387 0.5619 0.025 Uiso 1 1 calc R
H10B H -1.1548 -0.8080 0.5843 0.025 Uiso 1 1 calc R
C11 C -1.4378(4) -0.9807(4) 0.3151(3) 0.0304(8) Uani 1 1 d .
H11 H -1.4691 -1.0639 0.3048 0.036 Uiso 1 1 calc R
C12 C -1.4175(4) -0.8130(3) 0.2874(3) 0.0283(8) Uani 1 1 d .
H12 H -1.4346 -0.7573 0.2500 0.034 Uiso 1 1 calc R
C13 C -0.3010(4) -0.4115(3) 0.2257(3) 0.0223(7) Uani 1 1 d .
C14 C -0.4750(4) -0.4683(3) 0.1885(3) 0.0232(7) Uani 1 1 d .
H14 H -0.5251 -0.5317 0.2158 0.028 Uiso 1 1 calc R
C15 C -0.5755(4) -0.4312(3) 0.1107(3) 0.0245(7) Uani 1 1 d .
C16 C -0.5000(4) -0.3366(3) 0.0704(3) 0.0260(7) Uani 1 1 d .
H16 H -0.5664 -0.3110 0.0192 0.031 Uiso 1 1 calc R
C17 C -0.3260(4) -0.2796(3) 0.1059(3) 0.0246(7) Uani 1 1 d .
C18 C -0.2275(4) -0.3173(3) 0.1843(3) 0.0235(7) Uani 1 1 d .
H18 H -0.1110 -0.2787 0.2092 0.028 Uiso 1 1 calc R
C19 C -0.1935(4) -0.4505(3) 0.3129(3) 0.0220(7) Uani 1 1 d .
C20 C -0.2473(5) -0.1819(3) 0.0561(3) 0.0308(8) Uani 1 1 d .
C21 C -0.7647(4) -0.4970(4) 0.0709(3) 0.0289(8) Uani 1 1 d .
N1 N -0.3814(4) -0.6027(3) 0.5834(3) 0.0375(8) Uani 1 1 d .
N2 N -0.6034(3) -0.7825(3) 0.4877(3) 0.0263(6) Uani 1 1 d .
N3 N -0.5066(4) -0.7979(3) 0.5845(3) 0.0346(7) Uani 1 1 d .
N4 N -1.1814(4) -0.8425(3) 0.1316(3) 0.0334(7) Uani 1 1 d .
N5 N -1.0400(3) -0.7840(3) 0.3220(2) 0.0219(6) Uani 1 1 d .
N6 N -1.0217(4) -0.6780(3) 0.2964(3) 0.0314(7) Uani 1 1 d .
N7 N -1.4988(4) -0.9367(3) 0.2323(3) 0.0331(7) Uani 1 1 d .
N8 N -1.3258(3) -0.8890(3) 0.4147(2) 0.0217(6) Uani 1 1 d .
N9 N -1.3114(4) -0.7791(3) 0.3996(3) 0.0277(7) Uani 1 1 d .
O1 O -0.2641(3) -0.5197(2) 0.3627(2) 0.0341(6) Uani 1 1 d .
O2 O -0.0394(3) -0.4065(2) 0.3325(2) 0.0274(5) Uani 1 1 d .
O3 O -0.0876(3) -0.1190(3) 0.1026(2) 0.0374(6) Uani 1 1 d .
O4 O -0.3422(4) -0.1671(3) -0.0296(3) 0.0481(8) Uani 1 1 d .
O5 O -0.8462(3) -0.4409(3) 0.0243(3) 0.0462(8) Uani 1 1 d .
O6 O -0.8333(3) -0.5963(3) 0.0831(3) 0.0442(7) Uani 1 1 d .
O1W O -1.1727(4) -0.7996(3) -0.1514(3) 0.0648(10) Uani 1 1 d .
H2B H -1.0877 -0.8135 -0.1364 0.097 Uiso 1 1 d R
H2A H -1.1390 -0.7313 -0.0989 0.097 Uiso 1 1 d R
02W O -0.7700(4) -0.7542(3) 0.2049(3) 0.0538(8) Uani 1 1 d .
H1A H -0.7948 -0.7071 0.1692 0.081 Uiso 1 1 d R
H1B H -0.7232 -0.7824 0.1667 0.081 Uiso 1 1 d R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Ag1 O2 150.66(9) . 2_546
O1 Ag1 N1 93.35(11) . .
O2 Ag1 N1 102.48(11) 2_546 .
O1 Ag1 N6 112.75(10) . 2_446
O2 Ag1 N6 89.89(9) 2_546 2_446
N1 Ag1 N6 97.01(11) . 2_446
O1 Ag1 Ag1 77.65(7) . 2_546
O2 Ag1 Ag1 82.29(6) 2_546 2_546
N1 Ag1 Ag1 167.37(8) . 2_546
N6 Ag1 Ag1 94.67(7) 2_446 2_546
N4 Ag2 N7 173.18(12) . 2_235
N4 Ag2 O4 99.93(11) . 1_445
N7 Ag2 O4 85.44(11) 2_235 1_445
N4 Ag2 Ag3 79.27(8) . 1_445
N7 Ag2 Ag3 107.20(8) 2_235 1_445
O4 Ag2 Ag3 59.80(7) 1_445 1_445
O3 Ag3 O3 180.00(13) 2 .
O3 Ag3 Ag2 92.03(7) 2 1_665
O3 Ag3 Ag2 87.97(7) . 1_665
O3 Ag3 Ag2 87.97(7) 2 2_445
O3 Ag3 Ag2 92.03(7) . 2_445
Ag2 Ag3 Ag2 180.000(11) 1_665 2_445
C3 C1 C2 119.6(3) 2_336 .
C3 C1 C4 122.1(3) 2_336 .
C2 C1 C4 118.4(3) . .
C1 C2 C3 121.0(3) . .
C1 C2 C7 118.8(3) . .
C3 C2 C7 120.0(3) . .
C1 C3 C2 119.4(3) 2_336 .
C1 C3 C10 121.1(3) 2_336 .
C2 C3 C10 119.5(3) . .
N2 C4 C1 112.4(3) . .
N2 C4 H4A 109.1 . .
C1 C4 H4A 109.1 . .
N2 C4 H4B 109.1 . .
C1 C4 H4B 109.1 . .
H4A C4 H4B 107.9 . .
N1 C5 N2 110.7(4) . .
N1 C5 H5 124.6 . .
N2 C5 H5 124.6 . .
N3 C6 N1 115.3(3) . .
N3 C6 H6 122.4 . .
N1 C6 H6 122.4 . .
N5 C7 C2 114.6(3) . .
N5 C7 H7A 108.6 . .
C2 C7 H7A 108.6 . .
N5 C7 H7B 108.6 . .
C2 C7 H7B 108.6 . .
H7A C7 H7B 107.6 . .
N5 C8 N4 109.7(3) . .
N5 C8 H8 125.1 . .
N4 C8 H8 125.1 . .
N6 C9 N4 114.0(3) . .
N6 C9 H9 123.0 . .
N4 C9 H9 123.0 . .
N8 C10 C3 112.0(3) . .
N8 C10 H10A 109.2 . .
C3 C10 H10A 109.2 . .
N8 C10 H10B 109.2 . .
C3 C10 H10B 109.2 . .
H10A C10 H10B 107.9 . .
N7 C11 N8 110.0(3) . .
N7 C11 H11 125.0 . .
N8 C11 H11 125.0 . .
N9 C12 N7 113.5(3) . .
N9 C12 H12 123.2 . .
N7 C12 H12 123.2 . .
C18 C13 C14 119.3(3) . .
C18 C13 C19 120.8(3) . .
C14 C13 C19 119.9(3) . .
C13 C14 C15 120.6(3) . .
C13 C14 H14 119.7 . .
C15 C14 H14 119.7 . .
C16 C15 C14 119.4(3) . .
C16 C15 C21 121.7(3) . .
C14 C15 C21 118.9(3) . .
C15 C16 C17 120.7(3) . .
C15 C16 H16 119.7 . .
C17 C16 H16 119.7 . .
C16 C17 C18 119.1(3) . .
C16 C17 C20 119.9(3) . .
C18 C17 C20 120.9(3) . .
C13 C18 C17 120.9(3) . .
C13 C18 H18 119.6 . .
C17 C18 H18 119.6 . .
O1 C19 O2 125.7(3) . .
O1 C19 C13 117.2(3) . .
O2 C19 C13 117.0(3) . .
O4 C20 O3 123.2(4) . .
O4 C20 C17 118.4(3) . .
O3 C20 C17 118.4(3) . .
O6 C21 O5 123.0(3) . .
O6 C21 C15 121.3(3) . .
O5 C21 C15 115.7(3) . .
C5 N1 C6 102.1(3) . .
C5 N1 Ag1 117.1(3) . .
C6 N1 Ag1 107.0(2) . .
C5 N2 N3 109.5(3) . .
C5 N2 C4 130.1(3) . .
N3 N2 C4 120.3(3) . .
C6 N3 N2 102.5(3) . .
C8 N4 C9 103.6(3) . .
C8 N4 Ag2 125.8(3) . .
C9 N4 Ag2 130.7(3) . .
C8 N5 N6 110.1(3) . .
C8 N5 C7 132.4(3) . .
N6 N5 C7 117.5(3) . .
C9 N6 N5 102.6(3) . .
C9 N6 Ag1 134.8(3) . 2_446
N5 N6 Ag1 122.4(2) . 2_446
C11 N7 C12 103.9(3) . .
C11 N7 Ag2 126.2(3) . 2_235
C12 N7 Ag2 129.6(3) . 2_235
C11 N8 N9 109.8(3) . .
C11 N8 C10 130.1(3) . .
N9 N8 C10 120.2(3) . .
C12 N9 N8 102.8(3) . .
C19 O1 Ag1 123.9(2) . .
C19 O2 Ag1 118.6(2) . 2_546
C20 O3 Ag3 111.7(2) . .
C20 O4 Ag2 126.7(3) . 1_665
H2B O1W H2A 105.1 . .
H1A 02W H1B 103.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 O1 2.290(2) .
Ag1 O2 2.311(2) 2_546
Ag1 N1 2.431(3) .
Ag1 N6 2.468(3) 2_446
Ag1 Ag1 2.8668(6) 2_546
Ag2 N4 2.133(3) .
Ag2 N7 2.145(3) 2_235
Ag2 O4 2.600(3) 1_445
Ag2 Ag3 3.2258(4) 1_445
Ag3 O3 2.206(3) 2
Ag3 O3 2.206(3) .
Ag3 Ag2 3.2258(4) 1_665
Ag3 Ag2 3.2258(4) 2_445
C1 C3 1.399(4) 2_336
C1 C2 1.406(4) .
C1 C4 1.514(4) .
C2 C3 1.408(4) .
C2 C7 1.514(4) .
C3 C1 1.399(4) 2_336
C3 C10 1.526(4) .
C4 N2 1.468(4) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 N1 1.322(5) .
C5 N2 1.338(5) .
C5 H5 0.9300 .
C6 N3 1.312(5) .
C6 N1 1.362(5) .
C6 H6 0.9300 .
C7 N5 1.468(4) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 N5 1.316(4) .
C8 N4 1.325(5) .
C8 H8 0.9300 .
C9 N6 1.311(5) .
C9 N4 1.351(5) .
C9 H9 0.9300 .
C10 N8 1.465(4) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 N7 1.322(5) .
C11 N8 1.323(5) .
C11 H11 0.9300 .
C12 N9 1.322(5) .
C12 N7 1.354(5) .
C12 H12 0.9300 .
C13 C18 1.386(5) .
C13 C14 1.388(5) .
C13 C19 1.515(4) .
C14 C15 1.396(5) .
C14 H14 0.9300 .
C15 C16 1.386(5) .
C15 C21 1.513(5) .
C16 C17 1.392(5) .
C16 H16 0.9300 .
C17 C18 1.394(5) .
C17 C20 1.503(5) .
C18 H18 0.9300 .
C19 O1 1.252(4) .
C19 O2 1.259(4) .
C20 O4 1.252(5) .
C20 O3 1.272(4) .
C21 O6 1.216(5) .
C21 O5 1.287(4) .
N2 N3 1.358(4) .
N5 N6 1.363(4) .
N6 Ag1 2.468(3) 2_446
N7 Ag2 2.145(3) 2_235
N8 N9 1.367(4) .
O2 Ag1 2.311(2) 2_546
O4 Ag2 2.600(3) 1_665
O1W H2B 0.8469 .
O1W H2A 0.8499 .
02W H1A 0.8471 .
02W H1B 0.8500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C3 C1 C2 C3 -1.3(5) 2_336 .
C4 C1 C2 C3 177.5(3) . .
C3 C1 C2 C7 173.3(3) 2_336 .
C4 C1 C2 C7 -8.0(4) . .
C1 C2 C3 C1 1.3(5) . 2_336
C7 C2 C3 C1 -173.2(3) . 2_336
C1 C2 C3 C10 -178.5(3) . .
C7 C2 C3 C10 7.0(4) . .
C3 C1 C4 N2 -97.1(4) 2_336 .
C2 C1 C4 N2 84.2(3) . .
C1 C2 C7 N5 82.7(3) . .
C3 C2 C7 N5 -102.7(3) . .
C1 C3 C10 N8 -120.3(3) 2_336 .
C2 C3 C10 N8 59.4(4) . .
C18 C13 C14 C15 -0.2(5) . .
C19 C13 C14 C15 178.3(3) . .
C13 C14 C15 C16 0.0(5) . .
C13 C14 C15 C21 179.0(3) . .
C14 C15 C16 C17 0.7(5) . .
C21 C15 C16 C17 -178.3(3) . .
C15 C16 C17 C18 -1.1(5) . .
C15 C16 C17 C20 176.7(3) . .
C14 C13 C18 C17 -0.2(5) . .
C19 C13 C18 C17 -178.7(3) . .
C16 C17 C18 C13 0.9(5) . .
C20 C17 C18 C13 -176.9(3) . .
C18 C13 C19 O1 167.5(3) . .
C14 C13 C19 O1 -11.0(5) . .
C18 C13 C19 O2 -9.7(5) . .
C14 C13 C19 O2 171.8(3) . .
C16 C17 C20 O4 -10.6(5) . .
C18 C17 C20 O4 167.2(4) . .
C16 C17 C20 O3 169.9(3) . .
C18 C17 C20 O3 -12.3(5) . .
C16 C15 C21 O6 162.8(4) . .
C14 C15 C21 O6 -16.2(5) . .
C16 C15 C21 O5 -17.4(5) . .
C14 C15 C21 O5 163.6(3) . .
N2 C5 N1 C6 0.3(4) . .
N2 C5 N1 Ag1 116.8(3) . .
N3 C6 N1 C5 -0.3(4) . .
N3 C6 N1 Ag1 -123.8(3) . .
O1 Ag1 N1 C5 26.5(3) . .
O2 Ag1 N1 C5 -128.7(3) 2_546 .
N6 Ag1 N1 C5 139.9(3) 2_446 .
Ag1 Ag1 N1 C5 -17.6(6) 2_546 .
O1 Ag1 N1 C6 140.2(3) . .
O2 Ag1 N1 C6 -14.9(3) 2_546 .
N6 Ag1 N1 C6 -106.4(3) 2_446 .
Ag1 Ag1 N1 C6 96.1(4) 2_546 .
N1 C5 N2 N3 -0.3(4) . .
N1 C5 N2 C4 -176.7(3) . .
C1 C4 N2 C5 -127.2(4) . .
C1 C4 N2 N3 56.7(4) . .
N1 C6 N3 N2 0.1(4) . .
C5 N2 N3 C6 0.1(4) . .
C4 N2 N3 C6 177.0(3) . .
N5 C8 N4 C9 0.3(4) . .
N5 C8 N4 Ag2 179.2(2) . .
N6 C9 N4 C8 0.0(4) . .
N6 C9 N4 Ag2 -178.8(2) . .
Ag3 Ag2 N4 C8 -64.7(3) 1_445 .
O4 Ag2 N4 C9 170.2(3) 1_445 .
Ag3 Ag2 N4 C9 113.8(3) 1_445 .
N4 C8 N5 N6 -0.5(4) . .
N4 C8 N5 C7 177.5(3) . .
C2 C7 N5 C8 1.5(5) . .
C2 C7 N5 N6 179.4(3) . .
N4 C9 N6 N5 -0.3(4) . .
N4 C9 N6 Ag1 -174.4(2) . 2_446
C8 N5 N6 C9 0.5(4) . .
C7 N5 N6 C9 -177.9(3) . .
C8 N5 N6 Ag1 175.5(2) . 2_446
C7 N5 N6 Ag1 -2.8(4) . 2_446
N8 C11 N7 C12 0.0(4) . .
N8 C11 N7 Ag2 174.2(2) . 2_235
N9 C12 N7 C11 -0.6(4) . .
N9 C12 N7 Ag2 -174.6(2) . 2_235
N7 C11 N8 N9 0.6(4) . .
N7 C11 N8 C10 -178.5(3) . .
C3 C10 N8 C11 60.1(4) . .
C3 C10 N8 N9 -119.0(3) . .
N7 C12 N9 N8 1.0(4) . .
C11 N8 N9 C12 -1.0(4) . .
C10 N8 N9 C12 178.3(3) . .
O2 C19 O1 Ag1 24.9(5) . .
C13 C19 O1 Ag1 -152.1(2) . .
O2 Ag1 O1 C19 -81.6(3) 2_546 .
N1 Ag1 O1 C19 155.3(3) . .
N6 Ag1 O1 C19 56.3(3) 2_446 .
Ag1 Ag1 O1 C19 -33.6(3) 2_546 .
O1 C19 O2 Ag1 7.8(5) . 2_546
C13 C19 O2 Ag1 -175.2(2) . 2_546
O4 C20 O3 Ag3 -7.2(5) . .
C17 C20 O3 Ag3 172.3(2) . .
Ag2 Ag3 O3 C20 36.5(2) 1_665 .
Ag2 Ag3 O3 C20 -143.5(2) 2_445 .
O3 C20 O4 Ag2 -47.7(5) . 1_665
C17 C20 O4 Ag2 132.9(3) . 1_665
