#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/81/4508183.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4508183
loop_
_publ_author_name
'Zhang, Zhe'
'Ma, Jian-Fang'
'Liu, Ying-Ying'
'Kan, Wei-Qiu'
'Yang, Jin'
_publ_section_title
;
 A Series of Coordination Polymers Constructed from a Multidentate N-Donor
 Ligand and Varied Carboxylate Anions: Syntheses, Structures, and
 Luminescent Properties
;
_journal_issue                   10
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              4338
_journal_paper_doi               10.1021/cg400680r
_journal_volume                  13
_journal_year                    2013
_chemical_formula_moiety         'C93 H83 Ag6 N36 O35'
_chemical_formula_sum            'C93 H83 Ag6 N36 O35'
_chemical_formula_weight         2912.17
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                107.339(4)
_cell_angle_beta                 99.509(4)
_cell_angle_gamma                92.536(4)
_cell_formula_units_Z            1
_cell_length_a                   9.7460(5)
_cell_length_b                   15.2850(7)
_cell_length_c                   18.6560(9)
_cell_measurement_reflns_used    3380
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      29.2486
_cell_measurement_theta_min      2.6742
_cell_volume                     2603.5(2)
_computing_cell_refinement       CrysAlis
_computing_data_collection       'CrysAlis (Oxford Diffraction, 2006)'
_computing_data_reduction        CrysAlis
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 10.0
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Oxford Diffraction Gemini R Ultra'
_diffrn_measurement_method       'ω scan'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0392
_diffrn_reflns_av_sigmaI/netI    0.0768
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            16697
_diffrn_reflns_theta_full        25.35
_diffrn_reflns_theta_max         25.35
_diffrn_reflns_theta_min         2.68
_exptl_absorpt_coefficient_mu    1.211
_exptl_absorpt_correction_T_max  0.8683
_exptl_absorpt_correction_T_min  0.8206
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis (Oxford Diffraction, 2006)
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.857
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1455
_exptl_crystal_size_max          0.17
_exptl_crystal_size_mid          0.14
_exptl_crystal_size_min          0.12
_refine_diff_density_max         1.079
_refine_diff_density_min         -0.625
_refine_diff_density_rms         0.106
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     815
_refine_ls_number_reflns         9501
_refine_ls_number_restraints     48
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.1011
_refine_ls_R_factor_gt           0.0590
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0580P)²+4.1001P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1262
_refine_ls_wR_factor_ref         0.1493
_reflns_number_gt                6274
_reflns_number_total             9501
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            cg400680r_si_002.cif
_cod_data_source_block           Compound-7
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_sg_symbol_Hall     '-P 1 '
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4508183
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.9157(4) 0.3531(3) 0.7793(3) 0.0319(10) Uani 0.50 1 d P
Ag1A Ag 0.9197(6) 0.3504(4) 0.7758(3) 0.0644(18) Uani 0.50 1 d P
Ag2 Ag 1.21777(6) 0.25773(4) 0.74888(3) 0.0479(2) Uani 1 1 d .
Ag3 Ag 0.5163(8) 0.1719(4) 0.7512(4) 0.0525(11) Uani 0.50 1 d P
Ag3A Ag 0.5343(7) 0.1483(4) 0.7369(4) 0.0605(13) Uani 0.50 1 d P
C1 C 0.6388(6) 0.4796(4) 0.5084(3) 0.0286(14) Uani 1 1 d .
C2 C 0.5330(6) 0.4138(4) 0.5060(3) 0.0316(14) Uani 1 1 d .
C3 C 0.3930(6) 0.4336(4) 0.4964(3) 0.0296(14) Uani 1 1 d .
C4 C 0.7910(6) 0.4575(5) 0.5177(4) 0.0364(16) Uani 1 1 d .
H4A H 0.7967 0.3957 0.4850 0.044 Uiso 1 1 calc R
H4B H 0.8467 0.5001 0.5020 0.044 Uiso 1 1 calc R
C5 C 0.8808(6) 0.3989(5) 0.6280(4) 0.0388(16) Uani 1 1 d .
H5 H 0.8824 0.3374 0.6005 0.047 Uiso 1 1 calc R
C6 C 0.8955(8) 0.5241(5) 0.7162(4) 0.055(2) Uani 1 1 d .
H6 H 0.9120 0.5668 0.7649 0.066 Uiso 1 1 calc R
C7 C 0.5666(7) 0.3204(4) 0.5129(4) 0.0388(16) Uani 1 1 d .
H7A H 0.5007 0.2731 0.4749 0.047 Uiso 1 1 calc R
H7B H 0.6595 0.3095 0.5021 0.047 Uiso 1 1 calc R
C8 C 0.5492(8) 0.2357(6) 0.6086(5) 0.064(2) Uani 1 1 d .
H8 H 0.5395 0.1760 0.5751 0.077 Uiso 1 1 calc R
C9 C 0.5696(7) 0.3515(6) 0.7069(5) 0.056(2) Uani 1 1 d .
H9 H 0.5769 0.3868 0.7577 0.067 Uiso 1 1 calc R
C10 C 0.2777(6) 0.3617(4) 0.4926(4) 0.0353(15) Uani 1 1 d .
H10A H 0.1927 0.3707 0.4614 0.042 Uiso 1 1 calc R
H10B H 0.3038 0.3010 0.4683 0.042 Uiso 1 1 calc R
C11 C 0.2369(7) 0.2987(5) 0.5979(4) 0.0399(16) Uani 1 1 d .
H11 H 0.2391 0.2367 0.5721 0.048 Uiso 1 1 calc R
C12 C 0.2249(7) 0.4240(5) 0.6809(4) 0.0423(17) Uani 1 1 d .
H12 H 0.2174 0.4664 0.7273 0.051 Uiso 1 1 calc R
C13 C 1.1062(6) 0.0660(4) 1.0031(3) 0.0232(13) Uani 1 1 d .
C14 C 0.9691(6) 0.0893(4) 1.0030(3) 0.0223(12) Uani 1 1 d .
C15 C 0.8615(6) 0.0236(4) 1.0004(3) 0.0224(13) Uani 1 1 d .
C16 C 1.2210(6) 0.1370(4) 1.0041(3) 0.0285(14) Uani 1 1 d .
H16A H 1.2024 0.1977 1.0336 0.034 Uiso 1 1 calc R
H16B H 1.3100 0.1236 1.0283 0.034 Uiso 1 1 calc R
C17 C 1.2250(6) 0.2061(4) 0.8970(4) 0.0324(15) Uani 1 1 d .
H17 H 1.2232 0.2675 0.9248 0.039 Uiso 1 1 calc R
C18 C 1.2285(7) 0.0831(4) 0.8093(4) 0.0364(16) Uani 1 1 d .
H18 H 1.2297 0.0427 0.7611 0.044 Uiso 1 1 calc R
C19 C 0.9367(6) 0.1865(4) 1.0062(3) 0.0270(13) Uani 1 1 d .
H19A H 0.8534 0.2002 1.0280 0.032 Uiso 1 1 calc R
H19B H 1.0137 0.2302 1.0389 0.032 Uiso 1 1 calc R
C20 C 0.9031(6) 0.2731(4) 0.9101(4) 0.0327(15) Uani 1 1 d .
H20 H 0.9093 0.3320 0.9446 0.039 Uiso 1 1 calc R
C21 C 0.8801(6) 0.1621(4) 0.8108(4) 0.0342(15) Uani 1 1 d .
H21 H 0.8662 0.1288 0.7591 0.041 Uiso 1 1 calc R
C22 C 0.7131(6) 0.0511(4) 1.0032(3) 0.0284(14) Uani 1 1 d .
H22A H 0.6621 0.0091 1.0218 0.034 Uiso 1 1 calc R
H22B H 0.7175 0.1126 1.0389 0.034 Uiso 1 1 calc R
C23 C 0.6064(6) 0.1181(5) 0.9000(4) 0.0369(16) Uani 1 1 d .
H23 H 0.6223 0.1803 0.9282 0.044 Uiso 1 1 calc R
C24 C 0.5472(7) -0.0062(5) 0.8122(4) 0.0471(18) Uani 1 1 d .
H24 H 0.5100 -0.0478 0.7644 0.057 Uiso 1 1 calc R
C25 C 1.0524(7) -0.1551(5) 0.7254(4) 0.0401(16) Uani 1 1 d .
C26 C 1.0335(7) -0.1728(4) 0.6458(4) 0.0411(17) Uani 1 1 d .
C27 C 0.9174(7) -0.1438(5) 0.6082(4) 0.0438(17) Uani 1 1 d .
H27 H 0.9051 -0.1563 0.5555 0.053 Uiso 1 1 calc R
C28 C 0.8207(7) -0.0975(5) 0.6463(4) 0.0416(17) Uani 1 1 d .
C29 C 0.8429(7) -0.0763(5) 0.7257(4) 0.0435(17) Uani 1 1 d .
H29 H 0.7803 -0.0425 0.7526 0.052 Uiso 1 1 calc R
C30 C 0.9555(7) -0.1042(5) 0.7648(4) 0.0477(18) Uani 1 1 d .
H30 H 0.9680 -0.0895 0.8177 0.057 Uiso 1 1 calc R
C31 C 1.1635(8) -0.1889(5) 0.7734(5) 0.052(2) Uani 1 1 d .
C32 C 1.1217(9) -0.2249(6) 0.5921(5) 0.065(2) Uani 1 1 d .
C33 C 0.6892(8) -0.0804(5) 0.6001(5) 0.0493(19) Uani 1 1 d .
C34 C 1.3744(6) 0.4914(4) 0.8994(3) 0.0264(13) Uani 1 1 d .
C35 C 1.4315(6) 0.5775(4) 0.9034(3) 0.0263(13) Uani 1 1 d .
C36 C 1.5758(6) 0.5962(4) 0.9117(3) 0.0290(14) Uani 1 1 d .
H36 H 1.6127 0.6544 0.9143 0.035 Uiso 1 1 calc R
C37 C 1.6650(5) 0.5284(4) 0.9164(3) 0.0252(13) Uani 1 1 d .
C38 C 1.6075(6) 0.4413(4) 0.9102(4) 0.0296(14) Uani 1 1 d .
H38 H 1.6654 0.3948 0.9113 0.036 Uiso 1 1 calc R
C39 C 1.4649(6) 0.4230(4) 0.9024(3) 0.0274(14) Uani 1 1 d .
H39 H 1.4281 0.3644 0.8990 0.033 Uiso 1 1 calc R
C40 C 1.2189(6) 0.4695(4) 0.8957(4) 0.0286(14) Uani 1 1 d .
C41 C 1.3454(6) 0.6562(5) 0.9003(4) 0.0372(16) Uani 1 1 d .
C42 C 1.8182(6) 0.5554(4) 0.9286(4) 0.0298(14) Uani 1 1 d .
C43 C 0.0401(9) 0.0650(5) 0.5702(5) 0.059(2) Uani 1 1 d .
H43 H 0.0689 0.1093 0.6177 0.070 Uiso 1 1 calc R
C44 C 0.1378(8) 0.0051(5) 0.5399(5) 0.056(2) Uani 1 1 d .
C45 C 0.0962(8) -0.0608(5) 0.4675(5) 0.056(2) Uani 1 1 d .
C46 C 0.2831(9) 0.0208(8) 0.5881(6) 0.070(3) Uani 1 1 d .
C47 C 0.1586(14) -0.1311(10) 0.4253(9) 0.048(4) Uani 0.50 1 d PU
N1 N 0.9118(6) 0.4328(4) 0.7030(3) 0.0398(13) Uani 1 1 d .
N2 N 0.8471(5) 0.4645(4) 0.5972(3) 0.0365(13) Uani 1 1 d .
N3 N 0.8544(7) 0.5460(4) 0.6537(4) 0.0554(17) Uani 1 1 d .
N4 N 0.5539(7) 0.2582(5) 0.6836(4) 0.067(2) Uani 1 1 d .
N5 N 0.5607(5) 0.3130(4) 0.5891(3) 0.0399(14) Uani 1 1 d .
N6 N 0.5734(6) 0.3877(4) 0.6519(3) 0.0453(15) Uani 1 1 d .
N7 N 0.2197(6) 0.3320(4) 0.6693(3) 0.0411(14) Uani 1 1 d .
N8 N 0.2507(5) 0.3666(4) 0.5683(3) 0.0334(13) Uani 1 1 d .
N9 N 0.2416(6) 0.4477(4) 0.6207(3) 0.0422(14) Uani 1 1 d .
N10 N 1.2247(5) 0.1749(3) 0.8227(3) 0.0347(13) Uani 1 1 d .
N11 N 1.2284(5) 0.1362(3) 0.9259(3) 0.0245(11) Uani 1 1 d .
N12 N 1.2301(5) 0.0557(3) 0.8695(3) 0.0337(13) Uani 1 1 d .
N13 N 0.8819(5) 0.2537(3) 0.8354(3) 0.0365(13) Uani 1 1 d .
N14 N 0.9145(5) 0.1964(3) 0.9291(3) 0.0255(11) Uani 1 1 d .
N15 N 0.8991(5) 0.1226(3) 0.8642(3) 0.0317(12) Uani 1 1 d .
N16 N 0.5498(5) 0.0859(4) 0.8268(3) 0.0406(14) Uani 1 1 d .
N17 N 0.6376(5) 0.0496(3) 0.9278(3) 0.0293(12) Uani 1 1 d .
N18 N 0.6012(6) -0.0319(4) 0.8708(3) 0.0476(15) Uani 1 1 d .
O1 O 1.1294(6) -0.2152(4) 0.8257(3) 0.0681(17) Uani 1 1 d .
O2 O 1.2835(6) -0.1909(5) 0.7571(4) 0.085(2) Uani 1 1 d .
H2 H 1.3354 -0.2104 0.7869 0.128 Uiso 1 1 calc R
O3 O 1.2509(6) -0.2340(5) 0.6190(4) 0.095(2) Uani 1 1 d .
H3 H 1.2686 -0.2079 0.6653 0.143 Uiso 1 1 calc R
O4 O 1.0753(7) -0.2592(5) 0.5254(4) 0.095(2) Uani 1 1 d .
O5 O 0.6537(6) -0.1224(4) 0.5337(3) 0.0684(16) Uani 1 1 d .
O6 O 0.6154(5) -0.0201(4) 0.6403(3) 0.0735(18) Uani 1 1 d .
H6A H 0.5453 -0.0137 0.6121 0.110 Uiso 1 1 calc R
O7 O 1.1669(5) 0.3893(3) 0.8645(3) 0.0465(12) Uiso 1 1 d .
O8 O 1.1537(4) 0.5352(3) 0.9264(3) 0.0431(12) Uani 1 1 d .
O9 O 1.2601(5) 0.6412(3) 0.8356(3) 0.0516(13) Uani 1 1 d .
H9A H 1.2161 0.6860 0.8371 0.077 Uiso 1 1 calc R
O10 O 1.3616(6) 0.7268(4) 0.9522(3) 0.0667(17) Uani 1 1 d .
O11 O 1.8651(5) 0.6335(3) 0.9580(4) 0.0622(16) Uani 1 1 d .
O12 O 1.8960(4) 0.4883(3) 0.9084(3) 0.0390(11) Uani 1 1 d .
O13 O 0.3023(16) 0.1070(9) 0.6446(8) 0.057(4) Uani 0.50 1 d PU
O13A O 0.3231(17) 0.0636(12) 0.6462(11) 0.069(4) Uani 0.50 1 d PU
O14 O 0.3680(8) -0.0348(5) 0.5660(6) 0.138(4) Uani 1 1 d .
O15 O 0.2724(15) -0.1474(10) 0.4653(9) 0.023(3) Uani 0.25 1 d PU
O15A O 0.1084(13) -0.1762(9) 0.3619(8) 0.013(3) Uani 0.25 1 d PU
O1W O 0.8335(12) 0.7298(7) 0.8269(6) 0.164(4) Uani 1 1 d .
O2W O 0.5512(14) 0.7576(9) 0.8193(9) 0.221(6) Uani 1 1 d U
O3W O 0.5050(18) 0.6021(11) 0.6987(10) 0.124(5) Uani 0.50 1 d PU
O4W O 0.628(2) 0.7370(13) 0.6676(10) 0.138(6) Uani 0.50 1 d PU
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N1 Ag1 N13 166.6(3) . .
N1 Ag1A N13 167.1(4) . .
N1 Ag1A Ag2 100.1(2) . .
N13 Ag1A Ag2 87.5(2) . .
N7 Ag2 N10 175.2(2) 1_655 .
N7 Ag2 Ag3 102.81(19) 1_655 1_655
N10 Ag2 Ag3 73.35(17) . 1_655
N7 Ag2 Ag1A 84.34(17) 1_655 .
N10 Ag2 Ag1A 99.76(16) . .
Ag3 Ag2 Ag1A 171.03(15) 1_655 .
N4 Ag3 N16 161.9(4) . .
N4 Ag3 O13 83.0(5) . .
N16 Ag3 O13 111.5(5) . .
N4 Ag3 O13A 94.1(5) . .
N16 Ag3 O13A 98.3(5) . .
O13 Ag3 O13A 15.8(4) . .
N4 Ag3 Ag2 83.6(3) . 1_455
N16 Ag3 Ag2 113.3(3) . 1_455
O13 Ag3 Ag2 56.0(3) . 1_455
O13A Ag3 Ag2 68.5(4) . 1_455
N16 Ag3A N4 157.6(4) . .
N16 Ag3A O13A 103.2(5) . .
N4 Ag3A O13A 95.7(5) . .
N16 Ag3A O13 114.1(5) . .
N4 Ag3A O13 82.3(4) . .
O13A Ag3A O13 16.2(4) . .
C2 C1 C3 120.5(5) . 2_666
C2 C1 C4 119.8(5) . .
C3 C1 C4 119.7(5) 2_666 .
C1 C2 C3 119.9(5) . .
C1 C2 C7 120.9(5) . .
C3 C2 C7 119.2(5) . .
C1 C3 C2 119.6(5) 2_666 .
C1 C3 C10 120.4(5) 2_666 .
C2 C3 C10 120.0(5) . .
N2 C4 C1 110.9(5) . .
N2 C4 H4A 109.5 . .
C1 C4 H4A 109.5 . .
N2 C4 H4B 109.5 . .
C1 C4 H4B 109.5 . .
H4A C4 H4B 108.0 . .
N1 C5 N2 110.7(6) . .
N1 C5 H5 124.7 . .
N2 C5 H5 124.7 . .
N3 C6 N1 113.6(7) . .
N3 C6 H6 123.2 . .
N1 C6 H6 123.2 . .
N5 C7 C2 112.6(5) . .
N5 C7 H7A 109.1 . .
C2 C7 H7A 109.1 . .
N5 C7 H7B 109.1 . .
C2 C7 H7B 109.1 . .
H7A C7 H7B 107.8 . .
N4 C8 N5 109.0(8) . .
N4 C8 H8 125.5 . .
N5 C8 H8 125.5 . .
N6 C9 N4 114.4(7) . .
N6 C9 H9 122.8 . .
N4 C9 H9 122.8 . .
N8 C10 C3 112.0(5) . .
N8 C10 H10A 109.2 . .
C3 C10 H10A 109.2 . .
N8 C10 H10B 109.2 . .
C3 C10 H10B 109.2 . .
H10A C10 H10B 107.9 . .
N7 C11 N8 110.0(6) . .
N7 C11 H11 125.0 . .
N8 C11 H11 125.0 . .
N9 C12 N7 113.7(6) . .
N9 C12 H12 123.1 . .
N7 C12 H12 123.1 . .
C14 C13 C15 120.7(5) . 2_757
C14 C13 C16 119.9(5) . .
C15 C13 C16 119.3(5) 2_757 .
C13 C14 C15 120.4(5) . .
C13 C14 C19 119.7(5) . .
C15 C14 C19 119.9(5) . .
C13 C15 C14 118.9(5) 2_757 .
C13 C15 C22 121.3(5) 2_757 .
C14 C15 C22 119.8(5) . .
N11 C16 C13 110.4(5) . .
N11 C16 H16A 109.6 . .
C13 C16 H16A 109.6 . .
N11 C16 H16B 109.6 . .
C13 C16 H16B 109.6 . .
H16A C16 H16B 108.1 . .
N10 C17 N11 109.7(5) . .
N10 C17 H17 125.1 . .
N11 C17 H17 125.1 . .
N12 C18 N10 114.8(6) . .
N12 C18 H18 122.6 . .
N10 C18 H18 122.6 . .
N14 C19 C14 110.5(4) . .
N14 C19 H19A 109.6 . .
C14 C19 H19A 109.6 . .
N14 C19 H19B 109.6 . .
C14 C19 H19B 109.6 . .
H19A C19 H19B 108.1 . .
N13 C20 N14 110.0(6) . .
N13 C20 H20 125.0 . .
N14 C20 H20 125.0 . .
N15 C21 N13 115.4(6) . .
N15 C21 H21 122.3 . .
N13 C21 H21 122.3 . .
N17 C22 C15 111.9(4) . .
N17 C22 H22A 109.2 . .
C15 C22 H22A 109.2 . .
N17 C22 H22B 109.2 . .
C15 C22 H22B 109.2 . .
H22A C22 H22B 107.9 . .
N16 C23 N17 110.5(6) . .
N16 C23 H23 124.7 . .
N17 C23 H23 124.7 . .
N18 C24 N16 114.4(7) . .
N18 C24 H24 122.8 . .
N16 C24 H24 122.8 . .
C26 C25 C30 118.2(6) . .
C26 C25 C31 126.2(6) . .
C30 C25 C31 115.5(6) . .
C27 C26 C25 119.4(6) . .
C27 C26 C32 112.7(6) . .
C25 C26 C32 127.9(6) . .
C28 C27 C26 122.2(7) . .
C28 C27 H27 118.9 . .
C26 C27 H27 118.9 . .
C27 C28 C29 118.4(6) . .
C27 C28 C33 118.3(7) . .
C29 C28 C33 123.0(6) . .
C30 C29 C28 121.2(6) . .
C30 C29 H29 119.4 . .
C28 C29 H29 119.4 . .
C29 C30 C25 120.5(7) . .
C29 C30 H30 119.8 . .
C25 C30 H30 119.8 . .
O1 C31 O2 124.5(7) . .
O1 C31 C25 117.6(6) . .
O2 C31 C25 117.9(7) . .
O4 C32 O3 119.6(7) . .
O4 C32 C26 121.2(8) . .
O3 C32 C26 119.2(8) . .
O5 C33 O6 124.6(7) . .
O5 C33 C28 121.2(6) . .
O6 C33 C28 114.1(7) . .
C35 C34 C39 118.3(5) . .
C35 C34 C40 122.5(5) . .
C39 C34 C40 119.1(5) . .
C34 C35 C36 120.6(5) . .
C34 C35 C41 123.2(5) . .
C36 C35 C41 116.2(5) . .
C37 C36 C35 120.7(5) . .
C37 C36 H36 119.7 . .
C35 C36 H36 119.7 . .
C38 C37 C36 118.8(5) . .
C38 C37 C42 124.1(5) . .
C36 C37 C42 117.2(5) . .
C39 C38 C37 120.5(5) . .
C39 C38 H38 119.7 . .
C37 C38 H38 119.7 . .
C38 C39 C34 121.1(5) . .
C38 C39 H39 119.5 . .
C34 C39 H39 119.5 . .
O7 C40 O8 124.8(5) . .
O7 C40 C34 118.4(5) . .
O8 C40 C34 116.7(5) . .
O10 C41 O9 124.7(6) . .
O10 C41 C35 121.6(6) . .
O9 C41 C35 113.5(6) . .
O11 C42 O12 122.9(5) . .
O11 C42 C37 120.9(5) . .
O12 C42 C37 116.2(5) . .
C45 C43 C44 123.2(8) 2_556 .
C45 C43 H43 118.4 2_556 .
C44 C43 H43 118.4 . .
C45 C44 C43 118.8(7) . .
C45 C44 C46 125.0(9) . .
C43 C44 C46 116.2(8) . .
C47 C45 C43 108.1(10) . 2_556
C47 C45 C44 133.6(10) . .
C43 C45 C44 118.0(8) 2_556 .
O13A C46 O14 109.9(12) . .
O14 C46 O13 131.0(10) . .
O13A C46 C44 130.9(14) . .
O14 C46 C44 117.7(9) . .
O13 C46 C44 110.4(10) . .
O15A C47 O15 124.7(13) . .
O15A C47 C45 123.2(13) . .
O15 C47 C45 111.8(14) . .
C5 N1 C6 103.2(6) . .
C5 N1 Ag1A 123.2(5) . .
C6 N1 Ag1A 131.1(5) . .
C5 N1 Ag1 124.8(5) . .
C6 N1 Ag1 129.1(5) . .
C5 N2 N3 109.3(6) . .
C5 N2 C4 129.8(6) . .
N3 N2 C4 120.4(5) . .
C6 N3 N2 103.2(6) . .
C8 N4 C9 103.5(6) . .
C8 N4 Ag3 129.2(6) . .
C9 N4 Ag3 126.7(6) . .
C8 N4 Ag3A 119.5(6) . .
C9 N4 Ag3A 137.0(6) . .
C8 N5 N6 110.0(6) . .
C8 N5 C7 127.4(7) . .
N6 N5 C7 122.5(5) . .
C9 N6 N5 103.1(6) . .
C11 N7 C12 103.3(5) . .
C11 N7 Ag2 126.5(5) . 1_455
C12 N7 Ag2 129.6(5) . 1_455
C11 N8 N9 109.7(5) . .
C11 N8 C10 128.6(6) . .
N9 N8 C10 121.6(5) . .
C12 N9 N8 103.2(5) . .
C17 N10 C18 103.2(5) . .
C17 N10 Ag2 125.0(4) . .
C18 N10 Ag2 131.8(4) . .
C17 N11 N12 109.9(5) . .
C17 N11 C16 128.9(5) . .
N12 N11 C16 121.0(4) . .
C18 N12 N11 102.4(5) . .
C20 N13 C21 103.3(5) . .
C20 N13 Ag1 123.3(4) . .
C21 N13 Ag1 130.3(5) . .
C20 N13 Ag1A 124.9(5) . .
C21 N13 Ag1A 128.2(5) . .
C20 N14 N15 109.3(5) . .
C20 N14 C19 127.9(5) . .
N15 N14 C19 122.7(4) . .
C21 N15 N14 102.0(5) . .
C23 N16 C24 103.1(5) . .
C23 N16 Ag3A 131.5(5) . .
C24 N16 Ag3A 121.7(5) . .
C23 N16 Ag3 123.8(5) . .
C24 N16 Ag3 131.9(5) . .
C23 N17 N18 109.1(5) . .
C23 N17 C22 130.5(6) . .
N18 N17 C22 120.1(5) . .
C24 N18 N17 102.9(5) . .
C31 O2 H2 109.5 . .
C32 O3 H3 109.5 . .
C33 O6 H6A 109.5 . .
C41 O9 H9A 109.5 . .
O13A O13 C46 49(2) . .
O13A O13 Ag3A 77(2) . .
C46 O13 Ag3A 117.0(9) . .
O13A O13 Ag3 84(2) . .
C46 O13 Ag3 126.7(9) . .
O13 O13A C46 101(3) . .
O13 O13A Ag3A 87(2) . .
C46 O13A Ag3A 144.6(14) . .
O13 O13A Ag3 80(2) . .
C46 O13A Ag3 152.2(14) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N1 2.128(7) .
Ag1 N13 2.129(6) .
Ag1A N1 2.105(7) .
Ag1A N13 2.150(7) .
Ag1A Ag2 3.335(5) .
Ag2 N7 2.124(5) 1_655
Ag2 N10 2.126(5) .
Ag2 Ag3 3.243(6) 1_655
Ag3 N4 2.136(9) .
Ag3 N16 2.195(8) .
Ag3 O13 2.560(16) .
Ag3 O13A 2.59(2) .
Ag3 Ag2 3.243(6) 1_455
Ag3A N16 2.152(8) .
Ag3A N4 2.208(9) .
Ag3A O13A 2.466(19) .
Ag3A O13 2.532(16) .
C1 C2 1.393(8) .
C1 C3 1.402(8) 2_666
C1 C4 1.529(8) .
C2 C3 1.404(8) .
C2 C7 1.516(8) .
C3 C1 1.402(8) 2_666
C3 C10 1.514(8) .
C4 N2 1.464(8) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 N1 1.315(8) .
C5 N2 1.324(7) .
C5 H5 0.9300 .
C6 N3 1.311(9) .
C6 N1 1.365(9) .
C6 H6 0.9300 .
C7 N5 1.470(8) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C8 N4 1.331(10) .
C8 N5 1.341(8) .
C8 H8 0.9300 .
C9 N6 1.309(9) .
C9 N4 1.354(10) .
C9 H9 0.9300 .
C10 N8 1.459(7) .
C10 H10A 0.9700 .
C10 H10B 0.9700 .
C11 N7 1.318(8) .
C11 N8 1.324(7) .
C11 H11 0.9300 .
C12 N9 1.309(8) .
C12 N7 1.355(8) .
C12 H12 0.9300 .
C13 C14 1.398(7) .
C13 C15 1.403(7) 2_757
C13 C16 1.518(8) .
C14 C15 1.404(7) .
C14 C19 1.519(7) .
C15 C13 1.403(7) 2_757
C15 C22 1.529(7) .
C16 N11 1.469(7) .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 N10 1.324(8) .
C17 N11 1.332(7) .
C17 H17 0.9300 .
C18 N12 1.309(8) .
C18 N10 1.353(8) .
C18 H18 0.9300 .
C19 N14 1.473(7) .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 N13 1.314(8) .
C20 N14 1.327(7) .
C20 H20 0.9300 .
C21 N15 1.303(7) .
C21 N13 1.336(8) .
C21 H21 0.9300 .
C22 N17 1.468(7) .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 N16 1.318(8) .
C23 N17 1.327(7) .
C23 H23 0.9300 .
C24 N18 1.309(9) .
C24 N16 1.349(9) .
C24 H24 0.9300 .
C25 C26 1.407(9) .
C25 C30 1.412(9) .
C25 C31 1.499(9) .
C26 C27 1.391(9) .
C26 C32 1.498(10) .
C27 C28 1.369(9) .
C27 H27 0.9300 .
C28 C29 1.395(9) .
C28 C33 1.501(10) .
C29 C30 1.372(9) .
C29 H29 0.9300 .
C30 H30 0.9300 .
C31 O1 1.246(9) .
C31 O2 1.256(8) .
C32 O4 1.197(10) .
C32 O3 1.306(10) .
C33 O5 1.197(9) .
C33 O6 1.324(8) .
C34 C35 1.383(8) .
C34 C39 1.405(7) .
C34 C40 1.523(8) .
C35 C36 1.395(8) .
C35 C41 1.506(8) .
C36 C37 1.395(7) .
C36 H36 0.9300 .
C37 C38 1.387(8) .
C37 C42 1.493(8) .
C38 C39 1.380(8) .
C38 H38 0.9300 .
C39 H39 0.9300 .
C40 O7 1.233(7) .
C40 O8 1.254(7) .
C41 O10 1.200(8) .
C41 O9 1.298(8) .
C42 O11 1.190(7) .
C42 O12 1.305(7) .
C43 C45 1.386(11) 2_556
C43 C44 1.418(11) .
C43 H43 0.9300 .
C44 C45 1.406(11) .
C44 C46 1.513(11) .
C45 C47 1.363(15) .
C45 C43 1.386(11) 2_556
C46 O13A 1.082(17) .
C46 O14 1.242(12) .
C46 O13 1.403(17) .
C47 O15A 1.185(19) .
C47 O15 1.31(2) .
N2 N3 1.361(8) .
N5 N6 1.354(8) .
N7 Ag2 2.124(5) 1_455
N8 N9 1.349(7) .
N11 N12 1.362(7) .
N14 N15 1.368(7) .
N17 N18 1.363(7) .
O2 H2 0.8200 .
O3 H3 0.8200 .
O6 H6A 0.8200 .
O9 H9A 0.8200 .
O13 O13A 0.709(16) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 Ag1A Ag2 N7 -2.6(3) . 1_655
N13 Ag1A Ag2 N7 167.0(3) . 1_655
N1 Ag1A Ag2 N10 179.9(3) . .
N13 Ag1A Ag2 N10 -10.5(3) . .
C3 C1 C2 C3 1.9(10) 2_666 .
C4 C1 C2 C3 -179.2(6) . .
C3 C1 C2 C7 -178.7(5) 2_666 .
C4 C1 C2 C7 0.3(9) . .
C1 C2 C3 C1 -1.8(10) . 2_666
C7 C2 C3 C1 178.7(5) . 2_666
C1 C2 C3 C10 179.1(5) . .
C7 C2 C3 C10 -0.4(9) . .
C2 C1 C4 N2 -77.6(7) . .
C3 C1 C4 N2 101.4(6) 2_666 .
C1 C2 C7 N5 102.9(7) . .
C3 C2 C7 N5 -77.6(8) . .
C1 C3 C10 N8 -91.1(7) 2_666 .
C2 C3 C10 N8 88.0(7) . .
C15 C13 C14 C15 0.7(9) 2_757 .
C16 C13 C14 C15 178.6(5) . .
C15 C13 C14 C19 -179.6(5) 2_757 .
C16 C13 C14 C19 -1.7(8) . .
C13 C14 C15 C13 -0.7(9) . 2_757
C19 C14 C15 C13 179.6(5) . 2_757
C13 C14 C15 C22 177.8(5) . .
C19 C14 C15 C22 -1.9(8) . .
C14 C13 C16 N11 -86.9(6) . .
C15 C13 C16 N11 90.9(6) 2_757 .
C13 C14 C19 N14 84.3(7) . .
C15 C14 C19 N14 -96.0(6) . .
C13 C15 C22 N17 -99.2(6) 2_757 .
C14 C15 C22 N17 82.3(7) . .
C30 C25 C26 C27 -3.1(10) . .
C31 C25 C26 C27 174.0(7) . .
C30 C25 C26 C32 -179.9(7) . .
C31 C25 C26 C32 -2.8(13) . .
C25 C26 C27 C28 0.7(11) . .
C32 C26 C27 C28 177.9(7) . .
C26 C27 C28 C29 2.2(11) . .
C26 C27 C28 C33 -171.8(7) . .
C27 C28 C29 C30 -2.7(11) . .
C33 C28 C29 C30 171.0(7) . .
C28 C29 C30 C25 0.3(11) . .
C26 C25 C30 C29 2.6(11) . .
C31 C25 C30 C29 -174.7(7) . .
C26 C25 C31 O1 -139.8(8) . .
C30 C25 C31 O1 37.3(10) . .
C26 C25 C31 O2 38.5(12) . .
C30 C25 C31 O2 -144.4(8) . .
C27 C26 C32 O4 -19.9(12) . .
C25 C26 C32 O4 157.1(9) . .
C27 C26 C32 O3 161.0(8) . .
C25 C26 C32 O3 -22.0(13) . .
C27 C28 C33 O5 16.6(11) . .
C29 C28 C33 O5 -157.1(8) . .
C27 C28 C33 O6 -167.2(6) . .
C29 C28 C33 O6 19.1(10) . .
C39 C34 C35 C36 -1.4(9) . .
C40 C34 C35 C36 175.8(6) . .
C39 C34 C35 C41 179.6(6) . .
C40 C34 C35 C41 -3.2(10) . .
C34 C35 C36 C37 -0.1(9) . .
C41 C35 C36 C37 179.0(6) . .
C35 C36 C37 C38 1.9(9) . .
C35 C36 C37 C42 -177.5(5) . .
C36 C37 C38 C39 -2.3(9) . .
C42 C37 C38 C39 177.1(6) . .
C37 C38 C39 C34 0.9(9) . .
C35 C34 C39 C38 1.0(9) . .
C40 C34 C39 C38 -176.3(6) . .
C35 C34 C40 O7 153.1(6) . .
C39 C34 C40 O7 -29.7(9) . .
C35 C34 C40 O8 -28.3(9) . .
C39 C34 C40 O8 148.9(6) . .
C34 C35 C41 O10 119.0(8) . .
C36 C35 C41 O10 -60.0(9) . .
C34 C35 C41 O9 -64.5(8) . .
C36 C35 C41 O9 116.5(6) . .
C38 C37 C42 O11 -154.9(7) . .
C36 C37 C42 O11 24.5(9) . .
C38 C37 C42 O12 22.2(9) . .
C36 C37 C42 O12 -158.4(6) . .
C45 C43 C44 C45 1.2(13) 2_556 .
C45 C43 C44 C46 178.7(7) 2_556 .
C43 C44 C45 C47 -174.6(11) . .
C46 C44 C45 C47 8.1(15) . .
C43 C44 C45 C43 -1.2(12) . 2_556
C46 C44 C45 C43 -178.4(7) . 2_556
C45 C44 C46 O13A -172.4(16) . .
C43 C44 C46 O13A 10.3(19) . .
C45 C44 C46 O14 -8.0(13) . .
C43 C44 C46 O14 174.7(9) . .
C45 C44 C46 O13 162.2(10) . .
C43 C44 C46 O13 -15.1(12) . .
C43 C45 C47 O15A 11.3(18) 2_556 .
C44 C45 C47 O15A -174.8(12) . .
C43 C45 C47 O15 -162.9(11) 2_556 .
C44 C45 C47 O15 11.0(19) . .
N2 C5 N1 C6 -0.3(7) . .
N2 C5 N1 Ag1A 163.5(4) . .
N2 C5 N1 Ag1 161.7(4) . .
N3 C6 N1 C5 1.2(8) . .
N3 C6 N1 Ag1A -160.8(5) . .
N3 C6 N1 Ag1 -159.8(5) . .
N13 Ag1A N1 C5 -51.6(17) . .
Ag2 Ag1A N1 C5 73.8(5) . .
N13 Ag1A N1 C6 107.3(16) . .
Ag2 Ag1A N1 C6 -127.3(6) . .
N13 Ag1A N1 Ag1 85(7) . .
Ag2 Ag1A N1 Ag1 -149(8) . .
N13 Ag1 N1 C5 -32.0(14) . .
N13 Ag1 N1 C6 125.3(12) . .
N13 Ag1 N1 Ag1A -76(7) . .
N1 C5 N2 N3 -0.5(7) . .
N1 C5 N2 C4 -172.4(5) . .
C1 C4 N2 C5 109.8(7) . .
C1 C4 N2 N3 -61.3(8) . .
N1 C6 N3 N2 -1.5(9) . .
C5 N2 N3 C6 1.2(8) . .
C4 N2 N3 C6 174.0(6) . .
N5 C8 N4 C9 -0.4(9) . .
N5 C8 N4 Ag3 171.4(5) . .
N5 C8 N4 Ag3A 178.9(5) . .
N6 C9 N4 C8 0.6(9) . .
N6 C9 N4 Ag3 -171.5(5) . .
N6 C9 N4 Ag3A -178.5(6) . .
N16 Ag3 N4 C8 98.0(15) . .
O13 Ag3 N4 C8 -46.3(8) . .
O13A Ag3 N4 C8 -35.0(8) . .
Ag2 Ag3 N4 C8 -102.8(7) 1_455 .
N16 Ag3 N4 C9 -91.9(15) . .
O13 Ag3 N4 C9 123.8(7) . .
O13A Ag3 N4 C9 135.1(7) . .
Ag2 Ag3 N4 C9 67.3(7) 1_455 .
N16 Ag3 N4 Ag3A 63.5(17) . .
O13 Ag3 N4 Ag3A -81(2) . .
O13A Ag3 N4 Ag3A -70(2) . .
Ag2 Ag3 N4 Ag3A -137(2) 1_455 .
N16 Ag3A N4 C8 162.1(9) . .
O13A Ag3A N4 C8 -49.8(7) . .
O13 Ag3A N4 C8 -59.0(7) . .
N16 Ag3A N4 C9 -18.8(15) . .
O13A Ag3A N4 C9 129.2(9) . .
O13 Ag3A N4 C9 120.1(9) . .
N16 Ag3A N4 Ag3 -48.2(16) . .
O13A Ag3A N4 Ag3 100(2) . .
O13 Ag3A N4 Ag3 91(2) . .
N4 C8 N5 N6 0.1(9) . .
N4 C8 N5 C7 177.1(6) . .
C2 C7 N5 C8 161.5(7) . .
C2 C7 N5 N6 -21.8(8) . .
N4 C9 N6 N5 -0.5(8) . .
C8 N5 N6 C9 0.3(7) . .
C7 N5 N6 C9 -176.9(6) . .
N8 C11 N7 C12 -0.4(7) . .
N8 C11 N7 Ag2 -171.8(4) . 1_455
N9 C12 N7 C11 1.2(8) . .
N9 C12 N7 Ag2 172.2(4) . 1_455
N7 C11 N8 N9 -0.4(8) . .
N7 C11 N8 C10 177.1(6) . .
C3 C10 N8 C11 -132.6(6) . .
C3 C10 N8 N9 44.6(8) . .
N7 C12 N9 N8 -1.4(7) . .
C11 N8 N9 C12 1.1(7) . .
C10 N8 N9 C12 -176.6(5) . .
N11 C17 N10 C18 -0.1(7) . .
N11 C17 N10 Ag2 179.3(4) . .
N12 C18 N10 C17 0.4(7) . .
N12 C18 N10 Ag2 -179.0(4) . .
Ag3 Ag2 N10 C17 115.6(5) 1_655 .
Ag1A Ag2 N10 C17 -58.5(5) . .
Ag3 Ag2 N10 C18 -65.1(6) 1_655 .
Ag1A Ag2 N10 C18 120.8(6) . .
N10 C17 N11 N12 -0.2(7) . .
N10 C17 N11 C16 -175.7(5) . .
C13 C16 N11 C17 127.0(6) . .
C13 C16 N11 N12 -48.1(7) . .
N10 C18 N12 N11 -0.5(7) . .
C17 N11 N12 C18 0.4(6) . .
C16 N11 N12 C18 176.3(5) . .
N14 C20 N13 C21 0.4(7) . .
N14 C20 N13 Ag1 -161.5(4) . .
N14 C20 N13 Ag1A -159.7(4) . .
N15 C21 N13 C20 -0.3(7) . .
N15 C21 N13 Ag1 159.9(4) . .
N15 C21 N13 Ag1A 159.0(5) . .
N1 Ag1 N13 C20 -150.3(11) . .
N1 Ag1 N13 C21 53.0(14) . .
N1 Ag1 N13 Ag1A 72(7) . .
N1 Ag1A N13 C20 -132.6(15) . .
Ag2 Ag1A N13 C20 100.8(5) . .
N1 Ag1A N13 C21 72.2(16) . .
Ag2 Ag1A N13 C21 -54.4(6) . .
N1 Ag1A N13 Ag1 -89(7) . .
Ag2 Ag1A N13 Ag1 144(8) . .
N13 C20 N14 N15 -0.4(7) . .
N13 C20 N14 C19 -179.1(5) . .
C14 C19 N14 C20 -169.9(5) . .
C14 C19 N14 N15 11.6(7) . .
N13 C21 N15 N14 0.0(7) . .
C20 N14 N15 C21 0.2(6) . .
C19 N14 N15 C21 179.0(5) . .
N17 C23 N16 C24 0.6(7) . .
N17 C23 N16 Ag3A -157.3(5) . .
N17 C23 N16 Ag3 -168.3(4) . .
N18 C24 N16 C23 -1.6(8) . .
N18 C24 N16 Ag3A 159.1(5) . .
N18 C24 N16 Ag3 166.0(5) . .
N4 Ag3A N16 C23 -6.2(13) . .
O13A Ag3A N16 C23 -153.4(6) . .
O13 Ag3A N16 C23 -140.6(6) . .
N4 Ag3A N16 C24 -160.6(9) . .
O13A Ag3A N16 C24 52.1(7) . .
O13 Ag3A N16 C24 64.9(7) . .
N4 Ag3A N16 Ag3 46.0(15) . .
O13A Ag3A N16 Ag3 -101(2) . .
O13 Ag3A N16 Ag3 -88(2) . .
N4 Ag3 N16 C23 68.9(15) . .
O13 Ag3 N16 C23 -149.5(6) . .
O13A Ag3 N16 C23 -158.5(6) . .
Ag2 Ag3 N16 C23 -88.5(5) 1_455 .
N4 Ag3 N16 C24 -96.5(15) . .
O13 Ag3 N16 C24 45.0(8) . .
O13A Ag3 N16 C24 36.0(8) . .
Ag2 Ag3 N16 C24 106.0(6) 1_455 .
N4 Ag3 N16 Ag3A -65.7(18) . .
O13 Ag3 N16 Ag3A 76(2) . .
O13A Ag3 N16 Ag3A 67(2) . .
Ag2 Ag3 N16 Ag3A 137(2) 1_455 .
N16 C23 N17 N18 0.4(7) . .
N16 C23 N17 C22 173.5(5) . .
C15 C22 N17 C23 -104.6(7) . .
C15 C22 N17 N18 67.8(7) . .
N16 C24 N18 N17 1.8(8) . .
C23 N17 N18 C24 -1.3(7) . .
C22 N17 N18 C24 -175.3(5) . .
O14 C46 O13 O13A -52(3) . .
C44 C46 O13 O13A 139(3) . .
O13A C46 O13 Ag3A 38(2) . .
O14 C46 O13 Ag3A -13.8(18) . .
C44 C46 O13 Ag3A 177.7(7) . .
O13A C46 O13 Ag3 36(2) . .
O14 C46 O13 Ag3 -16(2) . .
C44 C46 O13 Ag3 175.2(8) . .
N16 Ag3A O13 O13A -50(3) . .
N4 Ag3A O13 O13A 146(3) . .
N16 Ag3A O13 C46 -79.3(11) . .
N4 Ag3A O13 C46 116.6(11) . .
O13A Ag3A O13 C46 -28.9(19) . .
N16 Ag3A O13 Ag3 89.2(18) . .
N4 Ag3A O13 Ag3 -74.9(17) . .
O13A Ag3A O13 Ag3 140(3) . .
N4 Ag3 O13 O13A 134(3) . .
N16 Ag3 O13 O13A -35(3) . .
Ag2 Ag3 O13 O13A -139(3) 1_455 .
N4 Ag3 O13 C46 107.5(13) . .
N16 Ag3 O13 C46 -61.2(13) . .
O13A Ag3 O13 C46 -26.5(18) . .
Ag2 Ag3 O13 C46 -165.5(14) 1_455 .
N4 Ag3 O13 Ag3A 94.7(18) . .
N16 Ag3 O13 Ag3A -74.1(17) . .
O13A Ag3 O13 Ag3A -39(3) . .
Ag2 Ag3 O13 Ag3A -178.3(18) 1_455 .
Ag3A O13 O13A C46 -145.3(18) . .
Ag3 O13 O13A C46 -151.8(15) . .
C46 O13 O13A Ag3A 145.3(18) . .
Ag3 O13 O13A Ag3A -6.5(4) . .
C46 O13 O13A Ag3 151.8(15) . .
Ag3A O13 O13A Ag3 6.5(4) . .
O14 C46 O13A O13 141(3) . .
C44 C46 O13A O13 -54(4) . .
O14 C46 O13A Ag3A 40(3) . .
O13 C46 O13A Ag3A -101(4) . .
C44 C46 O13A Ag3A -154.9(13) . .
O14 C46 O13A Ag3 51(3) . .
O13 C46 O13A Ag3 -89(4) . .
C44 C46 O13A Ag3 -143(2) . .
N16 Ag3A O13A O13 134(3) . .
N4 Ag3A O13A O13 -34(3) . .
N16 Ag3A O13A C46 -121(2) . .
N4 Ag3A O13A C46 71(2) . .
O13 Ag3A O13A C46 105(4) . .
N16 Ag3A O13A Ag3 92.4(18) . .
N4 Ag3A O13A Ag3 -75.7(17) . .
O13 Ag3A O13A Ag3 -41(3) . .
N4 Ag3 O13A O13 -46(3) . .
N16 Ag3 O13A O13 148(3) . .
Ag2 Ag3 O13A O13 36(2) 1_455 .
N4 Ag3 O13A C46 49(3) . .
N16 Ag3 O13A C46 -118(3) . .
O13 Ag3 O13A C46 95(4) . .
Ag2 Ag3 O13A C46 131(3) 1_455 .
N4 Ag3 O13A Ag3A 92.3(18) . .
N16 Ag3 O13A Ag3A -74.4(18) . .
O13 Ag3 O13A Ag3A 138(3) . .
Ag2 Ag3 O13A Ag3A 173.7(19) 1_455 .
