#------------------------------------------------------------------------------
#$Date: 2016-03-24 03:24:26 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179629 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/93/4509336.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4509336
loop_
_publ_author_name
'Santillan, Guillermo A.'
'Carrano, Carl J.'
_publ_section_title
;
 Self-Assembly of Silver(I) Coordination Polymers Formed through Hydrogen
 Bonding with Ditopic Heteroscorpionate Ligands
;
_journal_issue                   3
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1590
_journal_paper_doi               10.1021/cg801256h
_journal_volume                  9
_journal_year                    2009
_chemical_formula_sum            'C48 H62 Ag F6 N8 O7 Sb'
_chemical_formula_weight         1206.68
_chemical_name_systematic
;

 ?

;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 120.300(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   41.151(2)
_cell_length_b                   11.2074(6)
_cell_length_c                   26.9455(16)
_cell_measurement_reflns_used    9967
_cell_measurement_temperature    240(2)
_cell_measurement_theta_max      22.30
_cell_measurement_theta_min      2.35
_cell_volume                     10729.5(11)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      240(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0490
_diffrn_reflns_av_sigmaI/netI    0.0754
_diffrn_reflns_limit_h_max       39
_diffrn_reflns_limit_h_min       -54
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       36
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            50674
_diffrn_reflns_theta_full        28.37
_diffrn_reflns_theta_max         28.37
_diffrn_reflns_theta_min         2.07
_exptl_absorpt_coefficient_mu    0.944
_exptl_absorpt_correction_T_max  0.7648
_exptl_absorpt_correction_T_min  0.7039
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.494
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4912
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.30
_refine_diff_density_max         1.460
_refine_diff_density_min         -1.686
_refine_diff_density_rms         0.094
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.023
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     642
_refine_ls_number_reflns         13299
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.023
_refine_ls_R_factor_all          0.1439
_refine_ls_R_factor_gt           0.0631
_refine_ls_shift/su_max          0.063
_refine_ls_shift/su_mean         0.003
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0951P)²+14.1109P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1600
_refine_ls_wR_factor_ref         0.1984
_reflns_number_gt                6694
_reflns_number_total             13299
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg801256hsup1.cif
_cod_data_source_block           gs037a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_cell_volume        10729.5(10)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               4509336
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ag1 Ag 0.887868(12) 0.73753(3) 0.374550(17) 0.05212(16) Uani 1 1 d .
N1 N 0.91797(11) 0.5664(4) 0.36338(17) 0.0467(10) Uani 1 1 d .
N2 N 0.89955(11) 0.4775(3) 0.32515(16) 0.0399(9) Uani 1 1 d .
N3 N 0.84059(11) 0.6778(3) 0.28588(17) 0.0459(10) Uani 1 1 d .
N4 N 0.83995(11) 0.5705(3) 0.26129(16) 0.0438(10) Uani 1 1 d .
N5 N 0.91444(12) 0.9250(4) 0.36958(17) 0.0480(10) Uani 1 1 d .
N6 N 0.92712(11) 1.0055(3) 0.41403(17) 0.0433(10) Uani 1 1 d .
N7 N 0.90904(12) 0.8025(3) 0.46567(17) 0.0450(10) Uani 1 1 d .
N8 N 0.91634(11) 0.9172(3) 0.48544(16) 0.0447(10) Uani 1 1 d .
O1 O 0.91609(13) 0.2964(4) 0.50372(17) 0.0653(11) Uani 1 1 d .
O2 O 0.86974(14) 0.3144(5) 0.5228(2) 0.0889(14) Uani 1 1 d .
O3 O 0.76124(11) 1.1762(4) 0.23453(19) 0.0798(13) Uani 1 1 d .
O4 O 0.81817(12) 1.2077(4) 0.24686(18) 0.0649(11) Uani 1 1 d .
C1 C 0.98349(16) 0.6262(6) 0.4268(3) 0.0770(19) Uani 1 1 d .
H1A H 0.9712 0.6910 0.4349 0.115 Uiso 1 1 calc R
H1B H 0.9986 0.6585 0.4117 0.115 Uiso 1 1 calc R
H1C H 0.9995 0.5824 0.4619 0.115 Uiso 1 1 calc R
C2 C 0.95450(14) 0.5446(5) 0.3836(2) 0.0536(14) Uani 1 1 d .
C3 C 0.95898(15) 0.4418(5) 0.3593(3) 0.0610(15) Uani 1 1 d .
H3A H 0.9819 0.4073 0.3671 0.073 Uiso 1 1 calc R
C4 C 0.92336(15) 0.3997(5) 0.3215(2) 0.0505(13) Uani 1 1 d .
C5 C 0.91059(18) 0.2925(5) 0.2838(3) 0.0667(17) Uani 1 1 d .
H5A H 0.8833 0.2898 0.2625 0.100 Uiso 1 1 calc R
H5B H 0.9203 0.2212 0.3072 0.100 Uiso 1 1 calc R
H5C H 0.9198 0.2964 0.2571 0.100 Uiso 1 1 calc R
C6 C 0.81446(19) 0.8777(5) 0.2522(3) 0.083(2) Uani 1 1 d .
H6A H 0.8270 0.8925 0.2932 0.124 Uiso 1 1 calc R
H6B H 0.7877 0.8931 0.2352 0.124 Uiso 1 1 calc R
H6C H 0.8248 0.9300 0.2349 0.124 Uiso 1 1 calc R
C7 C 0.82038(15) 0.7501(4) 0.2418(2) 0.0513(14) Uani 1 1 d .
C8 C 0.80732(15) 0.6902(5) 0.1898(2) 0.0562(14) Uani 1 1 d .
H8A H 0.7929 0.7222 0.1526 0.067 Uiso 1 1 calc R
C9 C 0.81971(14) 0.5767(4) 0.2038(2) 0.0450(12) Uani 1 1 d .
C10 C 0.8132(2) 0.4692(6) 0.1656(3) 0.0777(19) Uani 1 1 d .
H10A H 0.8259 0.4004 0.1894 0.116 Uiso 1 1 calc R
H10B H 0.8230 0.4855 0.1403 0.116 Uiso 1 1 calc R
H10C H 0.7864 0.4531 0.1429 0.116 Uiso 1 1 calc R
C11 C 0.85847(13) 0.4671(4) 0.29746(19) 0.0400(11) Uani 1 1 d .
H11A H 0.8512 0.3977 0.2712 0.048 Uiso 1 1 calc R
C12 C 0.84510(13) 0.4401(4) 0.3389(2) 0.0414(11) Uani 1 1 d .
C13 C 0.86921(14) 0.3943(4) 0.3929(2) 0.0413(11) Uani 1 1 d .
H13A H 0.8948 0.3843 0.4049 0.050 Uiso 1 1 calc R
C14 C 0.85629(14) 0.3630(4) 0.4295(2) 0.0443(12) Uani 1 1 d .
C15 C 0.81857(16) 0.3740(5) 0.4117(3) 0.0565(14) Uani 1 1 d .
H15A H 0.8095 0.3514 0.4361 0.068 Uiso 1 1 calc R
C16 C 0.79421(16) 0.4188(5) 0.3573(3) 0.0614(15) Uani 1 1 d .
H16A H 0.7684 0.4257 0.3448 0.074 Uiso 1 1 calc R
C17 C 0.80714(14) 0.4533(5) 0.3214(2) 0.0524(13) Uani 1 1 d .
H17A H 0.7904 0.4857 0.2851 0.063 Uiso 1 1 calc R
C18 C 0.88406(19) 0.3209(5) 0.4886(2) 0.0533(14) Uani 1 1 d .
C19 C 0.9319(2) 0.8659(6) 0.2986(3) 0.0802(19) Uani 1 1 d .
H19A H 0.9112 0.8104 0.2876 0.120 Uiso 1 1 calc R
H19B H 0.9549 0.8219 0.3100 0.120 Uiso 1 1 calc R
H19C H 0.9264 0.9172 0.2663 0.120 Uiso 1 1 calc R
C20 C 0.93658(16) 0.9403(5) 0.3478(2) 0.0550(14) Uani 1 1 d .
C21 C 0.96295(16) 1.0311(5) 0.3777(3) 0.0624(15) Uani 1 1 d .
H21A H 0.9816 1.0592 0.3701 0.075 Uiso 1 1 calc R
C22 C 0.95641(14) 1.0700(5) 0.4190(2) 0.0533(14) Uani 1 1 d .
C23 C 0.97613(17) 1.1635(6) 0.4644(3) 0.0712(18) Uani 1 1 d .
H23A H 0.9645 1.1688 0.4879 0.107 Uiso 1 1 calc R
H23B H 0.9742 1.2400 0.4462 0.107 Uiso 1 1 calc R
H23C H 1.0024 1.1422 0.4883 0.107 Uiso 1 1 calc R
C24 C 0.91733(19) 0.6043(5) 0.5081(3) 0.0758(19) Uani 1 1 d .
H24A H 0.9075 0.5808 0.4684 0.114 Uiso 1 1 calc R
H24B H 0.9006 0.5765 0.5211 0.114 Uiso 1 1 calc R
H24C H 0.9421 0.5693 0.5318 0.114 Uiso 1 1 calc R
C25 C 0.92030(16) 0.7368(4) 0.5127(2) 0.0506(13) Uani 1 1 d .
C26 C 0.93339(16) 0.8081(5) 0.5612(2) 0.0583(14) Uani 1 1 d .
H26A H 0.9421 0.7823 0.5990 0.070 Uiso 1 1 calc R
C27 C 0.93109(15) 0.9220(5) 0.5432(2) 0.0513(13) Uani 1 1 d .
C28 C 0.93944(19) 1.0369(5) 0.5759(3) 0.0735(18) Uani 1 1 d .
H28A H 0.9496 1.0200 0.6164 0.110 Uiso 1 1 calc R
H28B H 0.9165 1.0829 0.5615 0.110 Uiso 1 1 calc R
H28C H 0.9577 1.0822 0.5710 0.110 Uiso 1 1 calc R
C29 C 0.90796(13) 1.0171(4) 0.4468(2) 0.0426(11) Uani 1 1 d .
H29A H 0.9189 1.0882 0.4715 0.051 Uiso 1 1 calc R
C30 C 0.86592(14) 1.0424(4) 0.4092(2) 0.0429(11) Uani 1 1 d .
C31 C 0.85154(14) 1.0957(4) 0.3564(2) 0.0454(12) Uani 1 1 d .
H31A H 0.8676 1.1145 0.3421 0.054 Uiso 1 1 calc R
C32 C 0.81341(14) 1.1223(4) 0.3238(2) 0.0476(13) Uani 1 1 d .
C33 C 0.79043(16) 1.0994(5) 0.3464(3) 0.0599(15) Uani 1 1 d .
H33A H 0.7646 1.1178 0.3249 0.072 Uiso 1 1 calc R
C34 C 0.80521(18) 1.0498(6) 0.4002(3) 0.0750(18) Uani 1 1 d .
H34A H 0.7896 1.0356 0.4157 0.090 Uiso 1 1 calc R
C35 C 0.84283(16) 1.0208(5) 0.4314(3) 0.0595(15) Uani 1 1 d .
H35A H 0.8528 0.9862 0.4680 0.071 Uiso 1 1 calc R
C36 C 0.79858(16) 1.1738(4) 0.2653(3) 0.0564(15) Uani 1 1 d .
O5 O 0.73234(17) 0.2299(5) 0.1270(3) 0.1116(19) Uani 1 1 d .
C37 C 0.6925(2) 0.2187(8) 0.0914(5) 0.115(3) Uani 1 1 d .
H37A H 0.6802 0.2943 0.0905 0.138 Uiso 1 1 calc R
H37B H 0.6830 0.1566 0.1065 0.138 Uiso 1 1 calc R
C38 C 0.6845(3) 0.1871(13) 0.0338(5) 0.164(5) Uani 1 1 d .
H38A H 0.6708 0.1113 0.0218 0.196 Uiso 1 1 calc R
H38B H 0.6690 0.2490 0.0063 0.196 Uiso 1 1 calc R
C39 C 0.7197(4) 0.1769(16) 0.0359(6) 0.198(6) Uani 1 1 d .
H39A H 0.7216 0.2368 0.0110 0.238 Uiso 1 1 calc R
H39B H 0.7222 0.0975 0.0229 0.238 Uiso 1 1 calc R
C40 C 0.7489(3) 0.1960(12) 0.0959(6) 0.155(4) Uani 1 1 d .
H40A H 0.7633 0.1223 0.1119 0.186 Uiso 1 1 calc R
H40B H 0.7663 0.2582 0.0981 0.186 Uiso 1 1 calc R
O6 O 0.8508(5) 0.0998(18) 0.0756(9) 0.350(12) Uani 1 1 d .
C41 C 0.8353(8) 0.000(2) 0.0727(9) 0.316(13) Uani 1 1 d .
H41A H 0.8443 -0.0625 0.0570 0.379 Uiso 1 1 calc R
H41B H 0.8078 0.0050 0.0492 0.379 Uiso 1 1 calc R
C42 C 0.8472(7) -0.0234(16) 0.1321(8) 0.255(10) Uani 1 1 d .
H42A H 0.8258 -0.0526 0.1351 0.306 Uiso 1 1 calc R
H42B H 0.8667 -0.0852 0.1472 0.306 Uiso 1 1 calc R
C43 C 0.8605(5) 0.0743(19) 0.1626(7) 0.229(8) Uani 1 1 d .
H43A H 0.8870 0.0622 0.1915 0.275 Uiso 1 1 calc R
H43B H 0.8467 0.0905 0.1828 0.275 Uiso 1 1 calc R
C44 C 0.8570(7) 0.1843(17) 0.1248(11) 0.38(2) Uani 1 1 d .
H44A H 0.8801 0.2317 0.1403 0.461 Uiso 1 1 calc R
H44B H 0.8353 0.2352 0.1154 0.461 Uiso 1 1 calc R
O7 O 0.9127(2) 0.2849(6) 0.6319(2) 0.114(2) Uani 1 1 d .
C45 C 0.8932(4) 0.3421(16) 0.6574(6) 0.185(6) Uani 1 1 d .
H45A H 0.8684 0.3698 0.6274 0.222 Uiso 1 1 calc R
H45B H 0.8899 0.2864 0.6825 0.222 Uiso 1 1 calc R
C46 C 0.9155(5) 0.4386(16) 0.6890(7) 0.272(12) Uani 1 1 d .
H46A H 0.9041 0.5141 0.6697 0.327 Uiso 1 1 calc R
H46B H 0.9187 0.4399 0.7275 0.327 Uiso 1 1 calc R
C47 C 0.9490(4) 0.4217(19) 0.6919(12) 0.39(2) Uani 1 1 d .
H47A H 0.9552 0.4921 0.6767 0.468 Uiso 1 1 calc R
H47B H 0.9688 0.4117 0.7322 0.468 Uiso 1 1 calc R
C48 C 0.9479(4) 0.3248(16) 0.6617(6) 0.175(5) Uani 1 1 d .
H48A H 0.9643 0.2624 0.6879 0.210 Uiso 1 1 calc R
H48B H 0.9570 0.3452 0.6355 0.210 Uiso 1 1 calc R
Sb2 Sb 0.0000 0.18800(7) 0.2500 0.0724(2) Uani 1 2 d S
F1 F 0.8005(2) 0.7280(10) 0.0439(3) 0.251(5) Uani 1 1 d .
F3 F 0.75199(19) 0.8403(9) 0.0604(3) 0.208(4) Uani 1 1 d .
F2 F 0.7562(2) 0.8846(11) -0.0320(3) 0.261(5) Uani 1 1 d .
Sb1 Sb 0.7500 0.7500 0.0000 0.1725(7) Uani 1 2 d S
F4 F 0.04984(17) 0.1895(11) 0.2946(3) 0.254(5) Uani 1 1 d .
F5 F 0.0035(2) 0.0922(11) 0.2023(3) 0.252(5) Uani 1 1 d .
F6 F -0.0024(2) 0.2894(10) 0.3000(4) 0.254(5) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N7 Ag1 N3 151.83(15) . .
N7 Ag1 N1 117.02(14) . .
N3 Ag1 N1 81.68(14) . .
N7 Ag1 N5 80.95(14) . .
N3 Ag1 N5 111.59(14) . .
N1 Ag1 N5 114.60(15) . .
C2 N1 N2 104.9(4) . .
C2 N1 Ag1 130.1(3) . .
N2 N1 Ag1 124.1(3) . .
C4 N2 N1 112.4(4) . .
C4 N2 C11 127.1(4) . .
N1 N2 C11 120.2(4) . .
C7 N3 N4 104.6(4) . .
C7 N3 Ag1 125.1(3) . .
N4 N3 Ag1 124.1(3) . .
C9 N4 N3 111.3(4) . .
C9 N4 C11 128.6(4) . .
N3 N4 C11 120.0(4) . .
C20 N5 N6 105.0(4) . .
C20 N5 Ag1 125.0(3) . .
N6 N5 Ag1 120.6(3) . .
C22 N6 N5 111.4(4) . .
C22 N6 C29 128.4(4) . .
N5 N6 C29 120.2(4) . .
C25 N7 N8 104.3(4) . .
C25 N7 Ag1 127.7(3) . .
N8 N7 Ag1 127.8(3) . .
C27 N8 N7 111.6(4) . .
C27 N8 C29 127.0(4) . .
N7 N8 C29 121.4(4) . .
N1 C2 C3 110.5(5) . .
N1 C2 C1 119.9(5) . .
C3 C2 C1 129.6(5) . .
C2 C3 C4 106.8(5) . .
N2 C4 C3 105.3(4) . .
N2 C4 C5 123.5(5) . .
C3 C4 C5 131.2(5) . .
N3 C7 C8 110.8(5) . .
N3 C7 C6 120.0(5) . .
C8 C7 C6 129.1(5) . .
C9 C8 C7 105.8(5) . .
N4 C9 C8 107.4(4) . .
N4 C9 C10 122.5(5) . .
C8 C9 C10 130.2(5) . .
N4 C11 N2 110.9(4) . .
N4 C11 C12 113.2(4) . .
N2 C11 C12 113.4(4) . .
C13 C12 C17 118.8(5) . .
C13 C12 C11 121.3(4) . .
C17 C12 C11 119.7(4) . .
C14 C13 C12 121.1(5) . .
C15 C14 C13 120.0(5) . .
C15 C14 C18 121.4(5) . .
C13 C14 C18 118.6(5) . .
C14 C15 C16 119.1(5) . .
C17 C16 C15 121.1(5) . .
C16 C17 C12 119.9(5) . .
O1 C18 O2 123.4(6) . .
O1 C18 C14 123.7(5) . .
O2 C18 C14 112.9(6) . .
N5 C20 C21 110.2(5) . .
N5 C20 C19 120.8(5) . .
C21 C20 C19 129.0(6) . .
C22 C21 C20 106.8(5) . .
C21 C22 N6 106.6(5) . .
C21 C22 C23 130.5(5) . .
N6 C22 C23 122.9(5) . .
N7 C25 C26 111.2(5) . .
N7 C25 C24 119.9(5) . .
C26 C25 C24 129.0(5) . .
C27 C26 C25 106.5(5) . .
C26 C27 N8 106.5(4) . .
C26 C27 C28 130.4(5) . .
N8 C27 C28 123.0(5) . .
N8 C29 N6 111.3(4) . .
N8 C29 C30 113.5(4) . .
N6 C29 C30 113.2(4) . .
C31 C30 C35 119.8(5) . .
C31 C30 C29 121.3(5) . .
C35 C30 C29 118.6(5) . .
C30 C31 C32 120.4(5) . .
C33 C32 C31 119.2(5) . .
C33 C32 C36 122.1(5) . .
C31 C32 C36 118.7(5) . .
C34 C33 C32 120.1(5) . .
C33 C34 C35 120.2(6) . .
C34 C35 C30 120.2(6) . .
O4 C36 O3 122.7(6) . .
O4 C36 C32 123.9(5) . .
O3 C36 C32 113.3(6) . .
C40 O5 C37 108.9(8) . .
O5 C37 C38 107.5(9) . .
C39 C38 C37 107.4(10) . .
C38 C39 C40 106.5(12) . .
O5 C40 C39 109.2(11) . .
C41 O6 C44 117(2) . .
O6 C41 C42 102.2(19) . .
C43 C42 C41 110.3(18) . .
C42 C43 C44 112.3(17) . .
C43 C44 O6 89.8(13) . .
C48 O7 C45 105.1(9) . .
C46 C45 O7 106.4(11) . .
C47 C46 C45 105.4(12) . .
C48 C47 C46 110.8(14) . .
C47 C48 O7 109.4(13) . .
F5 Sb2 F5 103.6(8) . 2
F5 Sb2 F4 90.5(4) . .
F5 Sb2 F4 90.2(4) 2 .
F5 Sb2 F4 90.2(4) . 2
F5 Sb2 F4 90.5(4) 2 2
F4 Sb2 F4 178.9(8) . 2
F5 Sb2 F6 77.3(5) . 2
F5 Sb2 F6 178.4(5) 2 2
F4 Sb2 F6 91.1(4) . 2
F4 Sb2 F6 88.2(4) 2 2
F5 Sb2 F6 178.4(5) . .
F5 Sb2 F6 77.3(5) 2 .
F4 Sb2 F6 88.2(4) . .
F4 Sb2 F6 91.1(4) 2 .
F6 Sb2 F6 101.8(9) 2 .
F1 Sb1 F1 180.0(6) 7_665 .
F1 Sb1 F2 88.0(4) 7_665 .
F1 Sb1 F2 92.0(4) . .
F1 Sb1 F2 92.0(4) 7_665 7_665
F1 Sb1 F2 88.0(4) . 7_665
F2 Sb1 F2 180.0(5) . 7_665
F1 Sb1 F3 88.5(3) 7_665 7_665
F1 Sb1 F3 91.5(3) . 7_665
F2 Sb1 F3 89.5(4) . 7_665
F2 Sb1 F3 90.5(4) 7_665 7_665
F1 Sb1 F3 91.5(3) 7_665 .
F1 Sb1 F3 88.5(3) . .
F2 Sb1 F3 90.5(4) . .
F2 Sb1 F3 89.5(4) 7_665 .
F3 Sb1 F3 180.0(4) 7_665 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N7 2.272(4) .
Ag1 N3 2.291(4) .
Ag1 N1 2.383(4) .
Ag1 N5 2.403(4) .
N1 C2 1.338(6) .
N1 N2 1.357(5) .
N2 C4 1.352(6) .
N2 C11 1.468(6) .
N3 C7 1.328(6) .
N3 N4 1.367(5) .
N4 C9 1.340(6) .
N4 C11 1.457(6) .
N5 C20 1.320(7) .
N5 N6 1.375(5) .
N6 C22 1.353(6) .
N6 C29 1.455(6) .
N7 C25 1.330(6) .
N7 N8 1.365(5) .
N8 C27 1.358(6) .
N8 C29 1.448(6) .
O1 C18 1.198(7) .
O2 C18 1.323(7) .
O3 C36 1.328(7) .
O4 C36 1.202(7) .
C1 C2 1.488(7) .
C2 C3 1.382(7) .
C3 C4 1.380(7) .
C4 C5 1.488(7) .
C6 C7 1.501(7) .
C7 C8 1.393(7) .
C8 C9 1.352(7) .
C9 C10 1.517(7) .
C11 C12 1.503(7) .
C12 C13 1.382(7) .
C12 C17 1.394(7) .
C13 C14 1.382(7) .
C14 C15 1.380(7) .
C14 C18 1.492(8) .
C15 C16 1.387(8) .
C16 C17 1.374(8) .
C19 C20 1.493(8) .
C20 C21 1.407(8) .
C21 C22 1.344(8) .
C22 C23 1.500(8) .
C24 C25 1.491(8) .
C25 C26 1.387(7) .
C26 C27 1.351(8) .
C27 C28 1.499(7) .
C29 C30 1.527(7) .
C30 C31 1.372(7) .
C30 C35 1.376(7) .
C31 C32 1.390(7) .
C32 C33 1.383(8) .
C32 C36 1.490(8) .
C33 C34 1.375(9) .
C34 C35 1.377(8) .
O5 C40 1.374(13) .
O5 C37 1.428(10) .
C37 C38 1.458(15) .
C38 C39 1.426(16) .
C39 C40 1.465(15) .
O6 C41 1.28(2) .
O6 C44 1.54(3) .
C41 C42 1.44(2) .
C42 C43 1.311(17) .
C43 C44 1.56(3) .
O7 C48 1.331(13) .
O7 C45 1.442(13) .
C45 C46 1.396(18) .
C46 C47 1.35(2) .
C47 C48 1.344(19) .
Sb2 F5 1.737(7) .
Sb2 F5 1.737(7) 2
Sb2 F4 1.779(6) .
Sb2 F4 1.779(6) 2
Sb2 F6 1.803(7) 2
Sb2 F6 1.803(7) .
F1 Sb1 1.817(7) .
F3 Sb1 1.883(7) .
F2 Sb1 1.817(10) .
Sb1 F1 1.817(7) 7_665
Sb1 F2 1.817(10) 7_665
Sb1 F3 1.883(7) 7_665
