#------------------------------------------------------------------------------
#$Date: 2016-03-24 03:25:37 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179630 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/94/4509460.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4509460
loop_
_publ_author_name
'Zhao, Xiao-Qing'
'Zuo, Ya'
'Gao, Dong-Liang'
'Zhao, Bin'
'Shi, Wei'
'Cheng, Peng'
_publ_section_title
;
 Syntheses, Structures, and Luminescence Properties of a Series of
 LnIII−BaIIHeterometal-Organic Frameworks
;
_journal_issue                   9
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              3948
_journal_paper_doi               10.1021/cg9000818
_journal_volume                  9
_journal_year                    2009
_chemical_formula_sum            'C70 H108 Ba4 Eu4 N10 O79'
_chemical_formula_weight         3510.91
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                94.763(3)
_cell_angle_beta                 102.297(4)
_cell_angle_gamma                90.479(4)
_cell_formula_units_Z            2
_cell_length_a                   13.426(3)
_cell_length_b                   18.161(4)
_cell_length_c                   24.972(5)
_cell_measurement_reflns_used    5525
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      25.66
_cell_measurement_theta_min      2.25
_cell_volume                     5927(2)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0537
_diffrn_reflns_av_sigmaI/netI    0.1358
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            29462
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         0.84
_exptl_absorpt_coefficient_mu    3.504
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.66843
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_density_diffrn    1.971
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             3412
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_refine_diff_density_max         2.196
_refine_diff_density_min         -1.418
_refine_diff_density_rms         0.224
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.009
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1531
_refine_ls_number_reflns         20711
_refine_ls_number_restraints     72
_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.1376
_refine_ls_R_factor_gt           0.0582
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0589P)²+29.2309P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1257
_refine_ls_wR_factor_ref         0.1632
_reflns_number_gt                11204
_reflns_number_total             20711
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg9000818sup4.cif
_cod_data_source_block           060821b
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from
2011-04-26.

'_exptl_absorpt_correction_type' value 'Multi-Scan'
changed to 'multi-scan' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'NONE' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4509460
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
O36 O 0.7970(7) 0.9515(5) 0.6748(4) 0.031(2) Uani 1 1 d .
O14 O 0.6940(8) 0.3290(5) 0.9548(4) 0.040(3) Uani 1 1 d .
Eu1 Eu 0.55748(5) 0.31828(4) 0.87558(3) 0.02309(18) Uani 1 1 d .
Eu2 Eu 1.10529(5) 0.61488(4) 0.87403(3) 0.02301(18) Uani 1 1 d .
Eu3 Eu 0.40474(5) 0.85339(4) 0.62569(3) 0.02146(17) Uani 1 1 d .
Eu4 Eu 0.08097(5) 0.83897(4) 0.38225(3) 0.02180(18) Uani 1 1 d .
Ba1 Ba 0.62556(7) 0.60913(5) 0.90328(3) 0.0287(2) Uani 1 1 d .
Ba2 Ba 0.71307(6) 0.60499(4) 0.74097(3) 0.0249(2) Uani 1 1 d .
Ba3 Ba 0.79337(7) 0.86357(4) 0.76074(3) 0.0256(2) Uani 1 1 d .
Ba4 Ba 0.88796(7) 0.85926(5) 0.60054(3) 0.0271(2) Uani 1 1 d .
O1 O 0.5079(7) 0.3132(5) 0.7737(4) 0.035(2) Uani 1 1 d .
O2 O 0.4089(9) 0.2686(6) 0.6934(4) 0.057(3) Uani 1 1 d .
O3 O 0.3939(13) 0.1460(8) 0.9515(5) 0.109(6) Uani 1 1 d .
O4 O 0.4875(8) 0.2416(5) 0.9358(4) 0.041(3) Uani 1 1 d .
O5 O 0.6409(8) 0.2020(5) 0.8620(4) 0.039(3) Uani 1 1 d .
O6 O 0.7823(9) 0.1376(6) 0.8559(5) 0.058(3) Uani 1 1 d .
O7 O 0.7190(7) 0.5173(5) 0.8276(4) 0.032(2) Uani 1 1 d .
O8 O 0.6176(6) 0.4435(5) 0.8623(3) 0.025(2) Uani 1 1 d .
O9 O 0.8246(7) 0.5808(5) 0.9472(4) 0.037(3) Uani 1 1 d .
O10 O 0.9560(7) 0.6288(5) 0.9168(3) 0.027(2) Uani 1 1 d .
O11 O 1.2046(7) 0.5029(5) 0.8657(4) 0.033(2) Uani 1 1 d .
O12 O 1.2413(8) 0.3846(5) 0.8834(4) 0.046(3) Uani 1 1 d .
O13 O 1.2173(7) 0.6125(5) 0.9664(4) 0.032(2) Uani 1 1 d .
O15 O 0.9771(8) 0.8421(6) 0.8376(4) 0.049(3) Uani 1 1 d .
O16 O 1.0206(7) 0.7224(5) 0.8329(4) 0.034(2) Uani 1 1 d .
O17 O 1.2727(7) 0.6635(5) 0.8617(4) 0.031(2) Uani 1 1 d .
O18 O 1.3811(7) 0.6878(5) 0.8073(4) 0.040(3) Uani 1 1 d .
O19 O 0.9630(7) 0.5637(5) 0.8018(4) 0.036(3) Uani 1 1 d .
O20 O 0.8861(7) 0.5324(5) 0.7144(4) 0.034(2) Uani 1 1 d .
O21 O 0.5490(7) 0.9038(5) 0.6990(3) 0.028(2) Uani 1 1 d .
O22 O 0.6225(7) 0.9358(5) 0.7871(4) 0.033(2) Uani 1 1 d .
O23 O 0.1307(7) 0.7767(6) 0.6920(4) 0.042(3) Uani 1 1 d .
O24 O 0.2415(7) 0.7985(5) 0.6386(4) 0.030(2) Uani 1 1 d .
O25 O 0.4864(7) 0.7458(5) 0.6666(3) 0.029(2) Uani 1 1 d .
O26 O 0.5359(8) 0.6288(5) 0.6612(4) 0.044(3) Uani 1 1 d .
O27 O 0.2331(7) 0.8063(5) 0.4474(4) 0.037(3) Uani 1 1 d .
O28 O 0.2942(7) 0.8574(5) 0.5331(4) 0.032(2) Uani 1 1 d .
O29 O 0.5569(7) 0.8434(5) 0.5826(4) 0.028(2) Uani 1 1 d .
O30 O 0.6883(7) 0.8957(5) 0.5548(4) 0.031(2) Uani 1 1 d .
O31 O 0.2589(8) 1.0793(5) 0.6088(5) 0.049(3) Uani 1 1 d .
O32 O 0.2992(7) 0.9638(5) 0.6315(4) 0.034(2) Uani 1 1 d .
O33 O 0.1505(7) 0.7237(5) 0.3466(4) 0.029(2) Uani 1 1 d .
O34 O 0.2937(8) 0.6690(5) 0.3365(4) 0.042(3) Uani 1 1 d .
O35 O 0.1283(7) 0.9695(4) 0.3698(4) 0.027(2) Uani 1 1 d .
O37 O 0.0101(8) 0.8548(5) 0.2848(4) 0.039(3) Uani 1 1 d .
O38 O -0.0842(8) 0.8142(6) 0.2021(4) 0.045(3) Uani 1 1 d .
O39 O -0.0844(9) 0.6603(6) 0.4516(4) 0.053(3) Uani 1 1 d .
O40 O 0.0120(7) 0.7567(5) 0.4394(4) 0.037(3) Uani 1 1 d .
O41 O 0.5065(8) 0.3966(5) 0.9560(4) 0.041(3) Uani 1 1 d .
O42 O 0.4027(7) 0.3914(5) 0.8450(4) 0.040(3) Uani 1 1 d .
O43 O 0.6471(8) 0.5187(6) 0.9951(4) 0.049(3) Uani 1 1 d .
O44 O 0.4350(8) 0.5391(5) 0.8940(5) 0.052(3) Uani 1 1 d .
O45 O 0.4620(8) 0.6880(6) 0.9499(4) 0.046(3) Uani 1 1 d .
O46 O 0.7104(10) 0.7192(8) 0.9868(6) 0.106(6) Uani 1 1 d .
O47 O 0.5607(7) 0.7484(5) 0.8561(4) 0.039(3) Uani 1 1 d .
O48 O 0.7736(7) 0.6795(5) 0.8502(4) 0.031(2) Uani 1 1 d .
O49 O 0.5324(7) 0.5918(5) 0.7862(4) 0.037(3) Uani 1 1 d .
O50 O 0.6389(10) 0.4753(6) 0.6814(6) 0.083(5) Uani 1 1 d .
O51 O 0.7487(9) 0.6289(5) 0.6341(4) 0.052(3) Uani 1 1 d .
O52 O 0.8693(7) 0.7147(5) 0.7419(4) 0.030(2) Uani 1 1 d .
O53 O 0.7744(9) 0.8371(6) 0.8712(4) 0.051(3) Uani 1 1 d .
O54 O 0.6360(7) 0.7534(4) 0.7591(3) 0.027(2) Uani 1 1 d .
O55 O 0.7345(7) 0.7879(5) 0.6498(4) 0.030(2) Uani 1 1 d .
O56 O 0.9727(7) 0.8660(5) 0.7158(4) 0.035(2) Uani 1 1 d .
O57 O 0.9490(7) 0.7160(5) 0.6433(4) 0.039(3) Uani 1 1 d .
O58 O 0.8024(9) 0.7529(7) 0.5181(5) 0.078(4) Uani 1 1 d .
O59 O 0.8913(9) 0.9278(5) 0.5039(4) 0.052(3) Uani 1 1 d .
O60 O 0.1010(9) 0.9162(5) 0.4770(4) 0.045(3) Uani 1 1 d .
O61 O -0.0667(8) 0.9140(5) 0.3835(5) 0.051(3) Uani 1 1 d .
N1 N 0.4231(9) 0.2189(6) 0.8284(5) 0.032(3) Uani 1 1 d .
N2 N 0.7208(8) 0.3244(5) 0.8395(4) 0.023(3) Uani 1 1 d .
N3 N 1.0413(8) 0.4989(6) 0.9088(4) 0.026(3) Uani 1 1 d .
N4 N 1.1462(9) 0.7394(6) 0.9300(4) 0.027(3) Uani 1 1 d .
N5 N 1.1354(8) 0.6026(5) 0.7763(4) 0.024(3) Uani 1 1 d .
N6 N 0.3744(8) 0.8652(6) 0.7241(4) 0.024(3) Uani 1 1 d .
N7 N 0.3808(8) 0.7331(5) 0.5647(4) 0.023(3) Uani 1 1 d U
N8 N 0.4663(8) 0.9718(6) 0.5916(4) 0.023(3) Uani 1 1 d .
N9 N 0.2256(8) 0.8553(5) 0.3354(4) 0.020(3) Uani 1 1 d .
N10 N -0.0629(8) 0.7498(6) 0.3332(5) 0.028(3) Uani 1 1 d .
C1 C 0.4394(11) 0.2670(9) 0.7438(6) 0.039(4) Uani 1 1 d .
C2 C 0.3949(11) 0.2095(8) 0.7739(6) 0.034(4) Uani 1 1 d .
C3 C 0.3344(12) 0.1515(9) 0.7457(6) 0.046(4) Uani 1 1 d .
H3A H 0.3157 0.1474 0.7075 0.055 Uiso 1 1 calc R
C4 C 0.3028(13) 0.1002(10) 0.7758(8) 0.063(6) Uani 1 1 d .
H4A H 0.2609 0.0603 0.7585 0.075 Uiso 1 1 calc R
C5 C 0.3341(14) 0.1084(10) 0.8333(8) 0.059(5) Uani 1 1 d .
H5A H 0.3154 0.0728 0.8542 0.071 Uiso 1 1 calc R
C6 C 0.3928(12) 0.1693(8) 0.8586(6) 0.034(4) Uani 1 1 d .
C7 C 0.4254(13) 0.1862(9) 0.9201(7) 0.049(5) Uani 1 1 d .
C8 C 0.7281(11) 0.1931(7) 0.8515(6) 0.031(4) Uani 1 1 d .
C9 C 0.7728(11) 0.2630(7) 0.8336(6) 0.028(3) Uani 1 1 d .
C10 C 0.8592(12) 0.2628(8) 0.8110(6) 0.040(4) Uani 1 1 d .
H10A H 0.8952 0.2197 0.8077 0.048 Uiso 1 1 calc R
C11 C 0.8912(11) 0.3293(8) 0.7930(6) 0.037(4) Uani 1 1 d .
H11A H 0.9467 0.3302 0.7763 0.045 Uiso 1 1 calc R
C12 C 0.8377(11) 0.3931(8) 0.8009(5) 0.033(4) Uani 1 1 d .
H12A H 0.8578 0.4382 0.7910 0.039 Uiso 1 1 calc R
C13 C 0.7517(11) 0.3869(7) 0.8246(5) 0.027(3) Uani 1 1 d .
C14 C 0.6903(11) 0.4553(8) 0.8384(5) 0.030(4) Uani 1 1 d .
C15 C 0.9055(11) 0.5767(8) 0.9313(5) 0.029(3) Uani 1 1 d .
C16 C 0.9536(10) 0.5011(7) 0.9284(5) 0.026(3) Uani 1 1 d .
C17 C 0.9122(10) 0.4375(8) 0.9436(6) 0.032(4) Uani 1 1 d .
H17A H 0.8510 0.4388 0.9554 0.038 Uiso 1 1 calc R
C18 C 0.9645(12) 0.3713(8) 0.9405(6) 0.040(4) Uani 1 1 d .
H18A H 0.9406 0.3284 0.9519 0.048 Uiso 1 1 calc R
C19 C 1.0520(12) 0.3713(9) 0.9202(6) 0.042(4) Uani 1 1 d .
H19A H 1.0864 0.3275 0.9167 0.051 Uiso 1 1 calc R
C20 C 1.0892(10) 0.4354(7) 0.9051(5) 0.025(3) Uani 1 1 d .
C21 C 1.1863(11) 0.4407(8) 0.8834(6) 0.034(4) Uani 1 1 d .
C22 C 1.2508(10) 0.6700(7) 0.9984(5) 0.022(3) Uani 1 1 d .
C23 C 1.2177(11) 0.7454(7) 0.9773(5) 0.026(3) Uani 1 1 d .
C24 C 1.2594(13) 0.8133(8) 1.0028(6) 0.043(4) Uani 1 1 d .
H24A H 1.3096 0.8160 1.0350 0.052 Uiso 1 1 calc R
C25 C 1.2241(14) 0.8755(9) 0.9790(7) 0.058(5) Uani 1 1 d .
H25A H 1.2519 0.9213 0.9947 0.069 Uiso 1 1 calc R
C26 C 1.1465(13) 0.8718(8) 0.9310(7) 0.055(5) Uani 1 1 d .
H26A H 1.1211 0.9145 0.9156 0.066 Uiso 1 1 calc R
C27 C 1.1091(10) 0.8028(8) 0.9076(6) 0.029(3) Uani 1 1 d .
C28 C 1.0273(11) 0.7911(9) 0.8550(5) 0.033(4) Uani 1 1 d .
C29 C 1.2996(12) 0.6625(8) 0.8146(6) 0.034(4) Uani 1 1 d .
C30 C 1.2247(10) 0.6229(7) 0.7665(5) 0.022(3) Uani 1 1 d .
C31 C 1.2471(11) 0.6128(8) 0.7149(6) 0.034(4) Uani 1 1 d .
H31A H 1.3103 0.6277 0.7094 0.041 Uiso 1 1 calc R
C32 C 1.1731(13) 0.5796(9) 0.6709(7) 0.051(5) Uani 1 1 d .
H32A H 1.1856 0.5721 0.6357 0.061 Uiso 1 1 calc R
C33 C 1.0798(12) 0.5580(8) 0.6821(6) 0.041(4) Uani 1 1 d .
H33A H 1.0295 0.5347 0.6543 0.049 Uiso 1 1 calc R
C34 C 1.0629(10) 0.5718(7) 0.7350(5) 0.024(3) Uani 1 1 d .
C35 C 0.9643(11) 0.5543(8) 0.7518(6) 0.029(3) Uani 1 1 d .
C36 C 0.5465(11) 0.9148(7) 0.7498(6) 0.027(3) Uani 1 1 d .
C37 C 0.4462(10) 0.8980(7) 0.7659(5) 0.025(3) Uani 1 1 d .
C38 C 0.4276(12) 0.9094(9) 0.8180(6) 0.041(4) Uani 1 1 d .
H38A H 0.4777 0.9314 0.8466 0.050 Uiso 1 1 calc R
C39 C 0.3345(14) 0.8882(9) 0.8276(7) 0.055(5) Uani 1 1 d .
H39A H 0.3204 0.8975 0.8624 0.066 Uiso 1 1 calc R
C40 C 0.2622(12) 0.8530(9) 0.7848(6) 0.043(4) Uani 1 1 d .
H40A H 0.1996 0.8375 0.7908 0.052 Uiso 1 1 calc R
C41 C 0.2846(10) 0.8412(7) 0.7331(5) 0.023(3) Uani 1 1 d .
C42 C 0.2139(11) 0.8039(7) 0.6844(6) 0.029(3) Uani 1 1 d .
C43 C 0.4878(11) 0.6816(7) 0.6418(6) 0.029(3) Uani 1 1 d .
C44 C 0.4233(10) 0.6710(7) 0.5820(5) 0.025(3) Uani 1 1 d .
C45 C 0.4148(13) 0.6058(8) 0.5496(6) 0.047(5) Uani 1 1 d .
H45A H 0.4454 0.5635 0.5634 0.056 Uiso 1 1 calc R
C46 C 0.3603(15) 0.6040(9) 0.4968(6) 0.059(5) Uani 1 1 d .
H46A H 0.3541 0.5606 0.4737 0.071 Uiso 1 1 calc R
C47 C 0.3147(12) 0.6669(8) 0.4780(6) 0.042(4) Uani 1 1 d .
H47A H 0.2769 0.6666 0.4421 0.051 Uiso 1 1 calc R
C48 C 0.3259(10) 0.7305(8) 0.5132(5) 0.029(3) Uani 1 1 d .
C49 C 0.2797(10) 0.8042(8) 0.4960(6) 0.026(3) Uani 1 1 d .
C50 C 0.6058(11) 0.8973(8) 0.5700(5) 0.024(3) Uani 1 1 d .
C51 C 0.5543(10) 0.9726(7) 0.5734(5) 0.020(3) Uani 1 1 d U
C52 C 0.5947(10) 1.0381(8) 0.5598(5) 0.029(3) Uani 1 1 d .
H52A H 0.6561 1.0385 0.5483 0.035 Uiso 1 1 calc R
C53 C 0.5397(11) 1.1039(8) 0.5640(6) 0.035(4) Uani 1 1 d .
H53A H 0.5645 1.1483 0.5552 0.042 Uiso 1 1 calc R
C54 C 0.4507(11) 1.1012(7) 0.5810(6) 0.029(3) Uani 1 1 d .
H54A H 0.4141 1.1440 0.5840 0.035 Uiso 1 1 calc R
C55 C 0.4133(11) 1.0345(8) 0.5942(5) 0.032(4) Uani 1 1 d .
C56 C 0.3153(11) 1.0258(8) 0.6134(6) 0.033(4) Uani 1 1 d .
C57 C 0.2391(11) 0.7237(7) 0.3361(5) 0.029(3) Uani 1 1 d .
C58 C 0.2778(10) 0.7960(7) 0.3200(6) 0.029(3) Uani 1 1 d .
C59 C 0.3557(10) 0.8020(8) 0.2929(5) 0.030(3) Uani 1 1 d U
H59A H 0.3919 0.7607 0.2846 0.036 Uiso 1 1 calc R
C60 C 0.3796(11) 0.8708(8) 0.2781(6) 0.035(4) Uani 1 1 d .
H60A H 0.4306 0.8760 0.2586 0.042 Uiso 1 1 calc R
C61 C 0.3274(10) 0.9310(8) 0.2926(6) 0.031(4) Uani 1 1 d .
H61A H 0.3429 0.9775 0.2830 0.038 Uiso 1 1 calc R
C62 C 0.2504(10) 0.9225(7) 0.3219(5) 0.023(3) Uani 1 1 d .
C63 C 0.1898(10) 0.9861(7) 0.3398(5) 0.025(3) Uani 1 1 d .
C64 C -0.0532(12) 0.8098(8) 0.2526(6) 0.035(4) Uani 1 1 d .
C65 C -0.0947(10) 0.7476(7) 0.2787(5) 0.028(3) Uani 1 1 d .
C66 C -0.1575(11) 0.6886(9) 0.2495(6) 0.039(4) Uani 1 1 d .
H66A H -0.1787 0.6865 0.2114 0.047 Uiso 1 1 calc R
C67 C -0.1865(14) 0.6349(10) 0.2780(7) 0.056(5) Uani 1 1 d .
H67A H -0.2272 0.5953 0.2592 0.067 Uiso 1 1 calc R
C68 C -0.1571(13) 0.6378(9) 0.3339(7) 0.053(5) Uani 1 1 d .
H68A H -0.1787 0.6014 0.3533 0.063 Uiso 1 1 calc R
C69 C -0.0948(11) 0.6958(8) 0.3609(6) 0.033(4) Uani 1 1 d .
C70 C -0.0546(12) 0.7046(8) 0.4234(6) 0.036(4) Uani 1 1 d .
O64 O 0.4046(15) 0.1364(9) 0.0623(7) 0.135(6) Uani 1 1 d U
O65 O 0.0931(10) 0.2296(7) 0.0323(6) 0.087(4) Uani 1 1 d .
O66 O 0.5592(9) 0.5453(6) 0.2567(4) 0.054(3) Uani 1 1 d .
O67 O 0.5919(12) 0.5502(8) 0.3717(6) 0.100(5) Uani 1 1 d U
O69 O 0.7808(11) 0.5394(7) 0.4488(5) 0.081(4) Uani 1 1 d .
O70 O 0.6487(12) 0.5848(8) 0.5271(6) 0.100(5) Uani 1 1 d .
O71 O 0.0964(13) 0.5405(9) 0.4722(7) 0.113(6) Uani 1 1 d U
O72 O 0.1129(10) 0.5789(6) 0.3738(5) 0.065(4) Uani 1 1 d .
O73 O 0.5028(10) 0.6957(7) 0.3893(5) 0.069(4) Uani 1 1 d .
O74 O 0.5938(9) 0.7262(6) 0.5003(5) 0.057(3) Uani 1 1 d .
O75 O 0.9392(9) 0.9956(6) 0.2569(5) 0.057(3) Uani 1 1 d .
O76 O 0.9299(11) 0.9378(8) 0.1491(6) 0.097(5) Uani 1 1 d .
O77 O 0.3474(19) 0.9713(12) 0.1136(8) 0.060(6) Uani 0.50 1 d PU
O78 O 0.0312(18) 0.3904(11) 0.4421(8) 0.053(6) Uani 0.50 1 d PU
O79 O 0.486(2) 0.9982(12) 0.0553(9) 0.063(7) Uani 0.50 1 d PU
O80 O 0.7884(16) 0.9386(11) 0.0529(8) 0.046(6) Uani 0.50 1 d PU
O81 O 0.9651(18) 0.1533(13) 0.9394(9) 0.065(7) Uani 0.50 1 d PU
O82 O 0.878(3) 0.9635(17) 0.9573(13) 0.110(11) Uani 0.50 1 d PU
O68 O 0.8636(9) 1.0018(6) 0.8170(5) 0.070(4) Uani 1 1 d .
O62 O 1.0885(8) 0.9407(6) 0.6363(5) 0.064(4) Uani 1 1 d .
O63 O 1.0513(8) 0.7955(6) 0.5550(4) 0.054(3) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ba Ba -0.3244 2.2819 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C63 O36 Ba3 147.9(8) 2_676 .
C63 O36 Ba4 101.8(8) 2_676 .
Ba3 O36 Ba4 103.6(3) . .
C22 O14 Eu1 166.5(9) 2_767 .
O14 Eu1 O5 79.9(3) . .
O14 Eu1 O4 80.0(3) . .
O5 Eu1 O4 78.7(3) . .
O14 Eu1 O8 83.7(3) . .
O5 Eu1 O8 127.3(3) . .
O4 Eu1 O8 146.1(3) . .
O14 Eu1 O1 146.5(3) . .
O5 Eu1 O1 86.1(3) . .
O4 Eu1 O1 127.0(3) . .
O8 Eu1 O1 80.9(3) . .
O14 Eu1 O42 133.8(3) . .
O5 Eu1 O42 145.4(3) . .
O4 Eu1 O42 97.5(3) . .
O8 Eu1 O42 73.1(3) . .
O1 Eu1 O42 68.7(3) . .
O14 Eu1 N2 74.0(3) . .
O5 Eu1 N2 63.3(3) . .
O4 Eu1 N2 136.7(3) . .
O8 Eu1 N2 64.1(3) . .
O1 Eu1 N2 72.5(3) . .
O42 Eu1 N2 125.5(3) . .
O14 Eu1 N1 136.2(4) . .
O5 Eu1 N1 70.7(3) . .
O4 Eu1 N1 63.3(4) . .
O8 Eu1 N1 140.1(3) . .
O1 Eu1 N1 63.7(3) . .
O42 Eu1 N1 76.9(3) . .
N2 Eu1 N1 117.2(3) . .
O14 Eu1 O41 68.9(3) . .
O5 Eu1 O41 137.4(3) . .
O4 Eu1 O41 68.1(3) . .
O8 Eu1 O41 78.4(3) . .
O1 Eu1 O41 135.3(3) . .
O42 Eu1 O41 67.5(3) . .
N2 Eu1 O41 129.3(3) . .
N1 Eu1 O41 113.6(3) . .
O19 Eu2 O16 74.7(3) . .
O19 Eu2 O11 91.9(3) . .
O16 Eu2 O11 149.7(3) . .
O19 Eu2 O10 76.2(3) . .
O16 Eu2 O10 76.8(3) . .
O11 Eu2 O10 127.0(3) . .
O19 Eu2 O13 151.0(3) . .
O16 Eu2 O13 127.2(3) . .
O11 Eu2 O13 76.3(3) . .
O10 Eu2 O13 89.7(3) . .
O19 Eu2 O17 127.0(3) . .
O16 Eu2 O17 90.0(3) . .
O11 Eu2 O17 76.4(3) . .
O10 Eu2 O17 149.6(3) . .
O13 Eu2 O17 76.4(3) . .
O19 Eu2 N4 134.9(3) . .
O16 Eu2 N4 63.5(3) . .
O11 Eu2 N4 132.9(3) . .
O10 Eu2 N4 78.6(3) . .
O13 Eu2 N4 63.9(3) . .
O17 Eu2 N4 71.0(3) . .
O19 Eu2 N5 63.6(3) . .
O16 Eu2 N5 76.4(3) . .
O11 Eu2 N5 73.3(3) . .
O10 Eu2 N5 136.1(3) . .
O13 Eu2 N5 134.1(3) . .
O17 Eu2 N5 63.6(3) . .
N4 Eu2 N5 118.0(3) . .
O19 Eu2 N3 73.6(3) . .
O16 Eu2 N3 133.7(3) . .
O11 Eu2 N3 63.6(3) . .
O10 Eu2 N3 63.4(3) . .
O13 Eu2 N3 77.4(3) . .
O17 Eu2 N3 136.2(3) . .
N4 Eu2 N3 125.2(3) . .
N5 Eu2 N3 116.7(3) . .
O25 Eu3 O21 74.7(3) . .
O25 Eu3 O28 127.5(3) . .
O21 Eu3 O28 150.6(3) . .
O25 Eu3 O32 150.1(3) . .
O21 Eu3 O32 94.6(3) . .
O28 Eu3 O32 74.2(3) . .
O25 Eu3 O24 86.4(3) . .
O21 Eu3 O24 126.7(3) . .
O28 Eu3 O24 78.3(3) . .
O32 Eu3 O24 77.8(3) . .
O25 Eu3 O29 78.9(3) . .
O21 Eu3 O29 75.3(3) . .
O28 Eu3 O29 89.3(3) . .
O32 Eu3 O29 126.1(3) . .
O24 Eu3 O29 149.1(3) . .
O25 Eu3 N7 63.7(3) . .
O21 Eu3 N7 131.7(3) . .
O28 Eu3 N7 63.9(3) . .
O32 Eu3 N7 133.7(3) . .
O24 Eu3 N7 75.4(3) . .
O29 Eu3 N7 73.7(3) . .
O25 Eu3 N6 75.9(3) . .
O21 Eu3 N6 63.5(3) . .
O28 Eu3 N6 134.5(3) . .
O32 Eu3 N6 74.4(3) . .
O24 Eu3 N6 63.6(3) . .
O29 Eu3 N6 136.0(3) . .
N7 Eu3 N6 123.4(3) . .
O25 Eu3 N8 135.5(3) . .
O21 Eu3 N8 74.2(3) . .
O28 Eu3 N8 76.5(3) . .
O32 Eu3 N8 63.3(3) . .
O24 Eu3 N8 138.0(3) . .
O29 Eu3 N8 63.0(3) . .
N7 Eu3 N8 120.6(3) . .
N6 Eu3 N8 116.0(3) . .
O61 Eu4 O27 137.6(4) . .
O61 Eu4 O40 87.3(3) . .
O27 Eu4 O40 77.4(3) . .
O61 Eu4 O37 75.7(4) . .
O27 Eu4 O37 144.1(3) . .
O40 Eu4 O37 126.1(3) . .
O61 Eu4 O33 147.5(3) . .
O27 Eu4 O33 70.2(3) . .
O40 Eu4 O33 83.7(3) . .
O37 Eu4 O33 84.7(3) . .
O61 Eu4 N9 129.9(3) . .
O27 Eu4 N9 74.4(3) . .
O40 Eu4 N9 142.8(3) . .
O37 Eu4 N9 71.6(3) . .
O33 Eu4 N9 64.3(3) . .
O61 Eu4 O35 71.9(3) . .
O27 Eu4 O35 100.1(3) . .
O40 Eu4 O35 146.3(3) . .
O37 Eu4 O35 75.0(3) . .
O33 Eu4 O35 127.7(3) . .
N9 Eu4 O35 63.7(3) . .
O61 Eu4 N10 78.6(3) . .
O27 Eu4 N10 125.5(3) . .
O40 Eu4 N10 63.2(3) . .
O37 Eu4 N10 63.4(3) . .
O33 Eu4 N10 69.5(3) . .
N9 Eu4 N10 116.8(3) . .
O35 Eu4 N10 133.6(3) . .
O61 Eu4 O60 69.6(4) . .
O27 Eu4 O60 68.4(3) . .
O40 Eu4 O60 76.0(3) . .
O37 Eu4 O60 137.8(3) . .
O33 Eu4 O60 136.8(3) . .
N9 Eu4 O60 114.3(3) . .
O35 Eu4 O60 72.1(3) . .
N10 Eu4 O60 128.8(4) . .
O9 Ba1 O44 136.7(3) . .
O9 Ba1 O46 69.3(3) . .
O44 Ba1 O46 124.2(4) . .
O9 Ba1 O43 67.4(3) . .
O44 Ba1 O43 73.8(3) . .
O46 Ba1 O43 82.5(4) . .
O9 Ba1 O7 67.6(3) . .
O44 Ba1 O7 103.3(3) . .
O46 Ba1 O7 130.9(3) . .
O43 Ba1 O7 101.3(3) . .
O9 Ba1 O49 124.6(3) . .
O44 Ba1 O49 73.7(3) . .
O46 Ba1 O49 140.5(4) . .
O43 Ba1 O49 136.4(3) . .
O7 Ba1 O49 59.6(3) . .
O9 Ba1 O47 123.1(3) . .
O44 Ba1 O47 100.0(3) . .
O46 Ba1 O47 75.8(4) . .
O43 Ba1 O47 148.7(3) . .
O7 Ba1 O47 110.0(3) . .
O49 Ba1 O47 66.0(3) . .
O9 Ba1 O48 65.9(3) . .
O44 Ba1 O48 149.1(3) . .
O46 Ba1 O48 80.0(4) . .
O43 Ba1 O48 133.3(3) . .
O7 Ba1 O48 61.8(3) . .
O49 Ba1 O48 75.4(3) . .
O47 Ba1 O48 64.8(3) . .
O9 Ba1 O45 132.8(3) . .
O44 Ba1 O45 60.1(3) . .
O46 Ba1 O45 68.8(3) . .
O43 Ba1 O45 86.5(3) . .
O7 Ba1 O45 159.3(3) . .
O49 Ba1 O45 101.7(3) . .
O47 Ba1 O45 64.8(3) . .
O48 Ba1 O45 125.4(3) . .
O9 Ba1 O8 82.9(3) . .
O44 Ba1 O8 65.9(3) . .
O46 Ba1 O8 146.6(4) . .
O43 Ba1 O8 69.6(3) . .
O7 Ba1 O8 44.0(2) . .
O49 Ba1 O8 70.9(2) . .
O47 Ba1 O8 136.9(2) . .
O48 Ba1 O8 105.7(2) . .
O45 Ba1 O8 125.1(3) . .
O50 Ba2 O7 81.3(4) . .
O50 Ba2 O26 69.1(3) . .
O7 Ba2 O26 124.4(3) . .
O50 Ba2 O20 74.3(3) . .
O7 Ba2 O20 90.2(3) . .
O26 Ba2 O20 122.8(3) . .
O50 Ba2 O51 78.3(4) . .
O7 Ba2 O51 151.6(3) . .
O26 Ba2 O51 65.3(3) . .
O20 Ba2 O51 65.3(3) . .
O50 Ba2 O52 137.8(4) . .
O7 Ba2 O52 122.1(3) . .
O26 Ba2 O52 111.0(3) . .
O20 Ba2 O52 71.4(3) . .
O51 Ba2 O52 65.6(3) . .
O50 Ba2 O48 145.1(4) . .
O7 Ba2 O48 64.0(3) . .
O26 Ba2 O48 127.0(3) . .
O20 Ba2 O48 108.3(3) . .
O51 Ba2 O48 135.5(3) . .
O52 Ba2 O48 70.7(3) . .
O50 Ba2 O49 83.4(4) . .
O7 Ba2 O49 61.2(3) . .
O26 Ba2 O49 69.4(3) . .
O20 Ba2 O49 146.2(3) . .
O51 Ba2 O49 134.6(3) . .
O52 Ba2 O49 137.7(3) . .
O48 Ba2 O49 76.5(3) . .
O50 Ba2 O54 136.3(3) . .
O7 Ba2 O54 114.4(3) . .
O26 Ba2 O54 68.7(3) . .
O20 Ba2 O54 141.0(3) . .
O51 Ba2 O54 94.0(3) . .
O52 Ba2 O54 69.8(2) . .
O48 Ba2 O54 62.6(2) . .
O49 Ba2 O54 71.7(3) . .
O36 Ba3 O22 92.2(3) . .
O36 Ba3 O68 77.5(3) . .
O22 Ba3 O68 72.8(3) . .
O36 Ba3 O15 119.3(3) . .
O22 Ba3 O15 124.5(3) . .
O68 Ba3 O15 71.7(3) . .
O36 Ba3 O56 61.3(3) . .
O22 Ba3 O56 149.8(3) . .
O68 Ba3 O56 86.5(3) . .
O15 Ba3 O56 65.8(3) . .
O36 Ba3 O54 123.9(3) . .
O22 Ba3 O54 71.6(3) . .
O68 Ba3 O54 138.7(3) . .
O15 Ba3 O54 113.5(3) . .
O56 Ba3 O54 134.1(3) . .
O36 Ba3 O53 154.4(3) . .
O22 Ba3 O53 69.5(3) . .
O68 Ba3 O53 79.9(4) . .
O15 Ba3 O53 63.4(3) . .
O56 Ba3 O53 129.1(3) . .
O54 Ba3 O53 68.5(3) . .
O36 Ba3 O55 64.6(3) . .
O22 Ba3 O55 109.0(3) . .
O68 Ba3 O55 142.0(3) . .
O15 Ba3 O55 125.2(3) . .
O56 Ba3 O55 74.2(2) . .
O54 Ba3 O55 70.8(2) . .
O53 Ba3 O55 137.4(3) . .
O36 Ba3 O52 113.2(3) . .
O22 Ba3 O52 140.9(3) . .
O68 Ba3 O52 139.3(3) . .
O15 Ba3 O52 69.1(3) . .
O56 Ba3 O52 68.0(3) . .
O54 Ba3 O52 69.6(2) . .
O53 Ba3 O52 91.9(3) . .
O55 Ba3 O52 61.9(2) . .
O58 Ba4 O30 70.3(3) . .
O58 Ba4 O59 76.7(4) . .
O30 Ba4 O59 72.4(3) . .
O58 Ba4 O56 137.2(4) . .
O30 Ba4 O56 124.3(3) . .
O59 Ba4 O56 143.7(3) . .
O58 Ba4 O36 130.7(3) . .
O30 Ba4 O36 67.0(3) . .
O59 Ba4 O36 111.3(3) . .
O56 Ba4 O36 60.6(3) . .
O58 Ba4 O63 72.5(3) . .
O30 Ba4 O63 133.6(3) . .
O59 Ba4 O63 72.8(3) . .
O56 Ba4 O63 101.8(3) . .
O36 Ba4 O63 156.6(3) . .
O58 Ba4 O57 74.1(3) . .
O30 Ba4 O57 124.8(3) . .
O59 Ba4 O57 136.3(3) . .
O56 Ba4 O57 65.0(3) . .
O36 Ba4 O57 112.3(3) . .
O63 Ba4 O57 67.9(3) . .
O58 Ba4 O55 78.2(3) . .
O30 Ba4 O55 66.8(3) . .
O59 Ba4 O55 137.3(3) . .
O56 Ba4 O55 74.1(3) . .
O36 Ba4 O55 63.3(3) . .
O63 Ba4 O55 130.1(3) . .
O57 Ba4 O55 65.6(3) . .
O58 Ba4 O62 136.2(4) . .
O30 Ba4 O62 135.9(3) . .
O59 Ba4 O62 80.7(3) . .
O56 Ba4 O62 65.2(3) . .
O36 Ba4 O62 92.4(3) . .
O63 Ba4 O62 65.1(3) . .
O57 Ba4 O62 98.8(3) . .
O55 Ba4 O62 139.1(3) . .
O58 Ba4 O35 138.6(3) . 2_676
O30 Ba4 O35 73.6(3) . 2_676
O59 Ba4 O35 73.6(3) . 2_676
O56 Ba4 O35 80.8(2) . 2_676
O36 Ba4 O35 43.4(2) . 2_676
O63 Ba4 O35 123.4(3) . 2_676
O57 Ba4 O35 145.8(2) . 2_676
O55 Ba4 O35 105.4(2) . 2_676
O62 Ba4 O35 65.6(3) . 2_676
O58 Ba4 C63 136.2(4) . 2_676
O30 Ba4 C63 66.0(3) . 2_676
O59 Ba4 C63 91.7(3) . 2_676
O56 Ba4 C63 71.6(3) . 2_676
O36 Ba4 C63 21.3(3) . 2_676
O63 Ba4 C63 144.2(3) . 2_676
O57 Ba4 C63 131.6(3) . 2_676
O55 Ba4 C63 83.1(3) . 2_676
O62 Ba4 C63 80.9(3) . 2_676
O35 Ba4 C63 22.4(3) 2_676 2_676
C1 O1 Eu1 123.7(9) . .
C7 O4 Eu1 125.9(10) . .
C8 O5 Eu1 127.3(9) . .
C14 O7 Ba2 142.0(8) . .
C14 O7 Ba1 98.3(8) . .
Ba2 O7 Ba1 103.0(3) . .
C14 O8 Eu1 123.5(9) . .
C14 O8 Ba1 89.4(8) . .
Eu1 O8 Ba1 145.2(3) . .
C15 O9 Ba1 137.1(9) . .
C15 O10 Eu2 126.4(9) . .
C21 O11 Eu2 124.8(9) . .
C22 O13 Eu2 124.4(8) . .
C28 O15 Ba3 137.9(10) . .
C28 O16 Eu2 127.0(8) . .
C29 O17 Eu2 124.2(9) . .
C35 O19 Eu2 125.0(9) . .
C35 O20 Ba2 107.6(8) . .
C36 O21 Eu3 124.8(9) . .
C36 O22 Ba3 107.1(8) . .
C42 O24 Eu3 123.1(8) . .
C43 O25 Eu3 125.7(8) . .
C43 O26 Ba2 138.2(9) . .
C49 O27 Eu4 148.9(9) . .
C49 O28 Eu3 124.6(8) . .
C50 O29 Eu3 125.7(8) . .
C50 O30 Ba4 135.9(8) . .
C56 O32 Eu3 124.9(9) . .
C57 O33 Eu4 120.4(8) . .
C63 O35 Eu4 123.4(8) . .
C63 O35 Ba4 87.3(7) . 2_676
Eu4 O35 Ba4 149.3(4) . 2_676
C64 O37 Eu4 124.6(9) . .
C70 O40 Eu4 127.7(9) . .
Ba2 O48 Ba1 99.2(3) . .
Ba2 O49 Ba1 99.8(3) . .
Ba2 O52 Ba3 110.4(3) . .
Ba3 O54 Ba2 110.2(3) . .
Ba3 O55 Ba4 97.9(3) . .
Ba4 O56 Ba3 101.9(3) . .
C2 N1 C6 119.4(13) . .
C2 N1 Eu1 120.8(10) . .
C6 N1 Eu1 119.0(9) . .
C13 N2 C9 119.9(13) . .
C13 N2 Eu1 120.3(9) . .
C9 N2 Eu1 119.7(9) . .
C20 N3 C16 119.8(12) . .
C20 N3 Eu2 120.5(9) . .
C16 N3 Eu2 119.6(8) . .
C23 N4 C27 118.7(11) . .
C23 N4 Eu2 120.6(8) . .
C27 N4 Eu2 119.7(8) . .
C30 N5 C34 119.6(11) . .
C30 N5 Eu2 120.4(8) . .
C34 N5 Eu2 119.9(9) . .
C41 N6 C37 120.6(11) . .
C41 N6 Eu3 119.1(8) . .
C37 N6 Eu3 120.2(8) . .
C44 N7 C48 117.6(11) . .
C44 N7 Eu3 121.8(8) . .
C48 N7 Eu3 120.5(8) . .
C55 N8 C51 119.7(12) . .
C55 N8 Eu3 120.0(9) . .
C51 N8 Eu3 120.2(8) . .
C62 N9 C58 118.2(11) . .
C62 N9 Eu4 120.8(8) . .
C58 N9 Eu4 120.9(9) . .
C65 N10 C69 119.5(12) . .
C65 N10 Eu4 119.9(9) . .
C69 N10 Eu4 119.6(9) . .
O2 C1 O1 123.4(16) . .
O2 C1 C2 119.9(14) . .
O1 C1 C2 116.7(13) . .
N1 C2 C3 124.0(15) . .
N1 C2 C1 114.6(13) . .
C3 C2 C1 121.3(14) . .
C4 C3 C2 117.4(15) . .
C4 C3 H3A 121.3 . .
C2 C3 H3A 121.3 . .
C3 C4 C5 119.1(15) . .
C3 C4 H4A 120.4 . .
C5 C4 H4A 120.4 . .
C6 C5 C4 119.9(16) . .
C6 C5 H5A 120.1 . .
C4 C5 H5A 120.1 . .
N1 C6 C5 120.1(14) . .
N1 C6 C7 115.5(13) . .
C5 C6 C7 124.4(15) . .
O3 C7 O4 124.9(16) . .
O3 C7 C6 119.9(15) . .
O4 C7 C6 115.2(15) . .
O6 C8 O5 128.9(14) . .
O6 C8 C9 117.6(14) . .
O5 C8 C9 113.4(12) . .
N2 C9 C10 121.7(13) . .
N2 C9 C8 115.1(12) . .
C10 C9 C8 123.2(12) . .
C9 C10 C11 118.9(14) . .
C9 C10 H10A 120.5 . .
C11 C10 H10A 120.5 . .
C12 C11 C10 118.5(14) . .
C12 C11 H11A 120.7 . .
C10 C11 H11A 120.7 . .
C11 C12 C13 117.6(14) . .
C11 C12 H12A 121.2 . .
C13 C12 H12A 121.2 . .
N2 C13 C12 123.2(13) . .
N2 C13 C14 114.8(13) . .
C12 C13 C14 121.9(13) . .
O7 C14 O8 125.7(13) . .
O7 C14 C13 118.0(13) . .
O8 C14 C13 116.2(13) . .
O9 C15 O10 127.9(14) . .
O9 C15 C16 117.6(13) . .
O10 C15 C16 114.5(13) . .
N3 C16 C17 121.0(13) . .
N3 C16 C15 115.3(12) . .
C17 C16 C15 123.6(13) . .
C16 C17 C18 118.6(14) . .
C16 C17 H17A 120.7 . .
C18 C17 H17A 120.7 . .
C19 C18 C17 118.5(15) . .
C19 C18 H18A 120.7 . .
C17 C18 H18A 120.7 . .
C18 C19 C20 120.7(15) . .
C18 C19 H19A 119.7 . .
C20 C19 H19A 119.7 . .
N3 C20 C19 121.3(13) . .
N3 C20 C21 114.5(12) . .
C19 C20 C21 124.1(13) . .
O12 C21 O11 125.5(14) . .
O12 C21 C20 118.4(13) . .
O11 C21 C20 116.1(13) . .
O14 C22 O13 126.3(12) 2_767 .
O14 C22 C23 116.9(12) 2_767 .
O13 C22 C23 116.8(11) . .
N4 C23 C24 122.6(12) . .
N4 C23 C22 113.2(11) . .
C24 C23 C22 124.1(13) . .
C25 C24 C23 117.8(14) . .
C25 C24 H24A 121.1 . .
C23 C24 H24A 121.1 . .
C24 C25 C26 121.3(15) . .
C24 C25 H25A 119.3 . .
C26 C25 H25A 119.3 . .
C27 C26 C25 118.0(14) . .
C27 C26 H26A 121.0 . .
C25 C26 H26A 121.0 . .
N4 C27 C26 121.5(13) . .
N4 C27 C28 115.3(12) . .
C26 C27 C28 123.2(13) . .
O15 C28 O16 126.8(13) . .
O15 C28 C27 120.3(14) . .
O16 C28 C27 112.9(12) . .
O18 C29 O17 125.4(14) . .
O18 C29 C30 119.5(14) . .
O17 C29 C30 115.0(13) . .
N5 C30 C31 122.6(13) . .
N5 C30 C29 116.2(12) . .
C31 C30 C29 121.1(12) . .
C30 C31 C32 119.1(14) . .
C30 C31 H31A 120.4 . .
C32 C31 H31A 120.4 . .
C33 C32 C31 117.5(14) . .
C33 C32 H32A 121.3 . .
C31 C32 H32A 121.3 . .
C34 C33 C32 119.6(14) . .
C34 C33 H33A 120.2 . .
C32 C33 H33A 120.2 . .
N5 C34 C33 121.5(13) . .
N5 C34 C35 113.7(12) . .
C33 C34 C35 124.8(13) . .
O19 C35 O20 123.5(13) . .
O19 C35 C34 117.6(12) . .
O20 C35 C34 118.8(12) . .
O22 C36 O21 123.9(13) . .
O22 C36 C37 118.7(12) . .
O21 C36 C37 117.3(12) . .
N6 C37 C38 120.6(13) . .
N6 C37 C36 113.7(11) . .
C38 C37 C36 125.6(13) . .
C37 C38 C39 119.8(15) . .
C37 C38 H38A 120.1 . .
C39 C38 H38A 120.1 . .
C38 C39 C40 119.3(15) . .
C38 C39 H39A 120.3 . .
C40 C39 H39A 120.3 . .
C39 C40 C41 119.2(15) . .
C39 C40 H40A 120.4 . .
C41 C40 H40A 120.4 . .
N6 C41 C40 120.4(13) . .
N6 C41 C42 115.5(11) . .
C40 C41 C42 124.1(13) . .
O24 C42 O23 124.3(13) . .
O24 C42 C41 118.4(13) . .
O23 C42 C41 117.2(13) . .
O26 C43 O25 125.5(13) . .
O26 C43 C44 118.7(13) . .
O25 C43 C44 115.8(11) . .
N7 C44 C45 123.4(12) . .
N7 C44 C43 112.8(11) . .
C45 C44 C43 123.7(12) . .
C46 C45 C44 118.5(14) . .
C46 C45 H45A 120.8 . .
C44 C45 H45A 120.8 . .
C45 C46 C47 119.4(15) . .
C45 C46 H46A 120.3 . .
C47 C46 H46A 120.3 . .
C46 C47 C48 118.8(13) . .
C46 C47 H47A 120.6 . .
C48 C47 H47A 120.6 . .
N7 C48 C47 122.2(13) . .
N7 C48 C49 114.7(11) . .
C47 C48 C49 123.1(12) . .
O27 C49 O28 126.4(13) . .
O27 C49 C48 117.6(12) . .
O28 C49 C48 116.0(11) . .
O30 C50 O29 127.7(12) . .
O30 C50 C51 117.4(13) . .
O29 C50 C51 114.9(12) . .
N8 C51 C52 121.3(12) . .
N8 C51 C50 115.1(11) . .
C52 C51 C50 123.6(12) . .
C51 C52 C53 118.5(13) . .
C51 C52 H52A 120.8 . .
C53 C52 H52A 120.8 . .
C54 C53 C52 119.0(13) . .
C54 C53 H53A 120.5 . .
C52 C53 H53A 120.5 . .
C53 C54 C55 120.5(13) . .
C53 C54 H54A 119.8 . .
C55 C54 H54A 119.8 . .
N8 C55 C54 121.0(14) . .
N8 C55 C56 114.6(13) . .
C54 C55 C56 124.4(13) . .
O31 C56 O32 127.7(15) . .
O31 C56 C55 115.6(14) . .
O32 C56 C55 116.7(12) . .
O34 C57 O33 124.6(13) . .
O34 C57 C58 118.6(14) . .
O33 C57 C58 116.7(12) . .
N9 C58 C59 122.9(13) . .
N9 C58 C57 112.3(12) . .
C59 C58 C57 124.7(13) . .
C58 C59 C60 118.7(13) . .
C58 C59 H59A 120.6 . .
C60 C59 H59A 120.6 . .
C61 C60 C59 119.3(13) . .
C61 C60 H60A 120.4 . .
C59 C60 H60A 120.4 . .
C60 C61 C62 119.9(13) . .
C60 C61 H61A 120.1 . .
C62 C61 H61A 120.1 . .
N9 C62 C61 120.9(12) . .
N9 C62 C63 116.0(12) . .
C61 C62 C63 123.2(12) . .
O36 C63 O35 125.7(13) 2_676 .
O36 C63 C62 119.5(13) 2_676 .
O35 C63 C62 114.9(11) . .
O36 C63 Ba4 56.9(7) 2_676 2_676
O35 C63 Ba4 70.3(7) . 2_676
C62 C63 Ba4 165.6(9) . 2_676
O38 C64 O37 125.3(14) . .
O38 C64 C65 118.4(14) . .
O37 C64 C65 116.2(12) . .
N10 C65 C66 120.6(13) . .
N10 C65 C64 114.6(12) . .
C66 C65 C64 124.7(13) . .
C67 C66 C65 118.6(14) . .
C67 C66 H66A 120.7 . .
C65 C66 H66A 120.7 . .
C66 C67 C68 121.3(16) . .
C66 C67 H67A 119.3 . .
C68 C67 H67A 119.3 . .
C67 C68 C69 118.3(16) . .
C67 C68 H68A 120.8 . .
C69 C68 H68A 120.8 . .
N10 C69 C68 121.7(14) . .
N10 C69 C70 114.9(12) . .
C68 C69 C70 123.4(14) . .
O39 C70 O40 127.7(14) . .
O39 C70 C69 118.7(13) . .
O40 C70 C69 113.5(13) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
O36 C63 1.241(14) 2_676
O36 Ba3 2.787(9) .
O36 Ba4 2.867(9) .
O14 C22 1.241(14) 2_767
O14 Eu1 2.387(9) .
Eu1 O5 2.431(9) .
Eu1 O4 2.452(9) .
Eu1 O8 2.479(9) .
Eu1 O1 2.483(9) .
Eu1 O42 2.491(9) .
Eu1 N2 2.547(11) .
Eu1 N1 2.566(12) .
Eu1 O41 2.578(9) .
Eu2 O19 2.448(9) .
Eu2 O16 2.457(9) .
Eu2 O11 2.459(9) .
Eu2 O10 2.469(9) .
Eu2 O13 2.474(9) .
Eu2 O17 2.496(9) .
Eu2 N4 2.549(10) .
Eu2 N5 2.550(10) .
Eu2 N3 2.553(11) .
Eu3 O25 2.441(8) .
Eu3 O21 2.474(8) .
Eu3 O28 2.474(8) .
Eu3 O32 2.476(9) .
Eu3 O24 2.494(9) .
Eu3 O29 2.505(9) .
Eu3 N7 2.535(10) .
Eu3 N6 2.568(10) .
Eu3 N8 2.570(11) .
Eu4 O61 2.419(10) .
Eu4 O27 2.436(9) .
Eu4 O40 2.453(9) .
Eu4 O37 2.459(9) .
Eu4 O33 2.475(9) .
Eu4 N9 2.499(11) .
Eu4 O35 2.510(8) .
Eu4 N10 2.543(11) .
Eu4 O60 2.610(9) .
Ba1 O9 2.734(9) .
Ba1 O44 2.804(11) .
Ba1 O46 2.810(12) .
Ba1 O43 2.898(10) .
Ba1 O7 2.906(9) .
Ba1 O49 2.915(9) .
Ba1 O47 2.939(9) .
Ba1 O48 2.950(9) .
Ba1 O45 3.016(10) .
Ba1 O8 3.089(9) .
Ba2 O50 2.739(11) .
Ba2 O7 2.779(9) .
Ba2 O26 2.819(10) .
Ba2 O20 2.852(9) .
Ba2 O51 2.875(11) .
Ba2 O52 2.876(9) .
Ba2 O48 2.891(9) .
Ba2 O49 2.901(10) .
Ba2 O54 2.930(8) .
Ba3 O22 2.822(9) .
Ba3 O68 2.824(11) .
Ba3 O15 2.837(10) .
Ba3 O56 2.867(10) .
Ba3 O54 2.889(8) .
Ba3 O53 2.903(10) .
Ba3 O55 2.933(9) .
Ba3 O52 2.934(9) .
Ba4 O58 2.754(11) .
Ba4 O30 2.788(9) .
Ba4 O59 2.815(10) .
Ba4 O56 2.853(9) .
Ba4 O63 2.886(11) .
Ba4 O57 2.951(9) .
Ba4 O55 2.957(9) .
Ba4 O62 2.988(11) .
Ba4 O35 3.157(8) 2_676
Ba4 C63 3.349(14) 2_676
O1 C1 1.303(16) .
O2 C1 1.241(16) .
O3 C7 1.249(19) .
O4 C7 1.282(18) .
O5 C8 1.263(17) .
O6 C8 1.248(16) .
O7 C14 1.256(16) .
O8 C14 1.274(16) .
O9 C15 1.236(16) .
O10 C15 1.280(16) .
O11 C21 1.287(16) .
O12 C21 1.264(17) .
O13 C22 1.279(15) .
O15 C28 1.205(16) .
O16 C28 1.316(17) .
O17 C29 1.301(16) .
O18 C29 1.238(17) .
O19 C35 1.248(15) .
O20 C35 1.283(15) .
O21 C36 1.276(15) .
O22 C36 1.258(15) .
O23 C42 1.275(16) .
O24 C42 1.272(16) .
O25 C43 1.275(15) .
O26 C43 1.236(15) .
O27 C49 1.247(15) .
O28 C49 1.265(15) .
O29 C50 1.270(16) .
O30 C50 1.245(16) .
O31 C56 1.236(16) .
O32 C56 1.282(16) .
O33 C57 1.272(16) .
O34 C57 1.240(16) .
O35 C63 1.279(15) .
O35 Ba4 3.157(8) 2_676
O37 C64 1.274(17) .
O38 C64 1.251(15) .
O39 C70 1.229(16) .
O40 C70 1.275(16) .
N1 C2 1.329(17) .
N1 C6 1.335(17) .
N2 C13 1.314(16) .
N2 C9 1.335(15) .
N3 C20 1.332(16) .
N3 C16 1.367(17) .
N4 C23 1.349(16) .
N4 C27 1.374(16) .
N5 C30 1.328(16) .
N5 C34 1.339(15) .
N6 C41 1.347(16) .
N6 C37 1.354(16) .
N7 C44 1.331(15) .
N7 C48 1.336(15) .
N8 C55 1.351(17) .
N8 C51 1.353(16) .
N9 C62 1.351(15) .
N9 C58 1.363(16) .
N10 C65 1.333(16) .
N10 C69 1.362(16) .
C1 C2 1.52(2) .
C2 C3 1.37(2) .
C3 C4 1.36(2) .
C3 H3A 0.9300 .
C4 C5 1.40(2) .
C4 H4A 0.9300 .
C5 C6 1.38(2) .
C5 H5A 0.9300 .
C6 C7 1.51(2) .
C8 C9 1.538(19) .
C9 C10 1.39(2) .
C10 C11 1.42(2) .
C10 H10A 0.9300 .
C11 C12 1.390(19) .
C11 H11A 0.9300 .
C12 C13 1.412(19) .
C12 H12A 0.9300 .
C13 C14 1.552(19) .
C15 C16 1.524(19) .
C16 C17 1.393(18) .
C17 C18 1.40(2) .
C17 H17A 0.9300 .
C18 C19 1.37(2) .
C18 H18A 0.9300 .
C19 C20 1.376(19) .
C19 H19A 0.9300 .
C20 C21 1.519(19) .
C22 O14 1.241(14) 2_767
C22 C23 1.543(17) .
C23 C24 1.395(18) .
C24 C25 1.36(2) .
C24 H24A 0.9300 .
C25 C26 1.41(2) .
C25 H25A 0.9300 .
C26 C27 1.380(19) .
C26 H26A 0.9300 .
C27 C28 1.520(18) .
C29 C30 1.517(19) .
C30 C31 1.382(18) .
C31 C32 1.40(2) .
C31 H31A 0.9300 .
C32 C33 1.40(2) .
C32 H32A 0.9300 .
C33 C34 1.390(18) .
C33 H33A 0.9300 .
C34 C35 1.511(19) .
C36 C37 1.520(19) .
C37 C38 1.375(18) .
C38 C39 1.38(2) .
C38 H38A 0.9300 .
C39 C40 1.39(2) .
C39 H39A 0.9300 .
C40 C41 1.389(18) .
C40 H40A 0.9300 .
C41 C42 1.482(18) .
C43 C44 1.555(18) .
C44 C45 1.367(18) .
C45 C46 1.364(19) .
C45 H45A 0.9300 .
C46 C47 1.37(2) .
C46 H46A 0.9300 .
C47 C48 1.379(19) .
C47 H47A 0.9300 .
C48 C49 1.535(19) .
C50 C51 1.542(17) .
C51 C52 1.400(18) .
C52 C53 1.418(19) .
C52 H52A 0.9300 .
C53 C54 1.353(19) .
C53 H53A 0.9300 .
C54 C55 1.398(18) .
C54 H54A 0.9300 .
C55 C56 1.50(2) .
C57 C58 1.523(19) .
C58 C59 1.368(18) .
C59 C60 1.387(18) .
C59 H59A 0.9300 .
C60 C61 1.369(18) .
C60 H60A 0.9300 .
C61 C62 1.402(18) .
C61 H61A 0.9300 .
C62 C63 1.509(18) .
C63 O36 1.241(14) 2_676
C63 Ba4 3.349(14) 2_676
C64 C65 1.509(19) .
C65 C66 1.410(19) .
C66 C67 1.36(2) .
C66 H66A 0.9300 .
C67 C68 1.36(2) .
C67 H67A 0.9300 .
C68 C69 1.37(2) .
C68 H68A 0.9300 .
C69 C70 1.534(19) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C22 O14 Eu1 O5 -100(4) 2_767 .
C22 O14 Eu1 O4 -20(4) 2_767 .
C22 O14 Eu1 O8 130(4) 2_767 .
C22 O14 Eu1 O1 -167(4) 2_767 .
C22 O14 Eu1 O42 71(4) 2_767 .
C22 O14 Eu1 N2 -165(4) 2_767 .
C22 O14 Eu1 N1 -53(4) 2_767 .
C22 O14 Eu1 O41 50(4) 2_767 .
C63 O36 Ba3 O22 66.2(17) 2_676 .
Ba4 O36 Ba3 O22 -152.5(3) . .
C63 O36 Ba3 O68 -5.7(16) 2_676 .
Ba4 O36 Ba3 O68 135.6(4) . .
C63 O36 Ba3 O15 -66.1(17) 2_676 .
Ba4 O36 Ba3 O15 75.2(4) . .
C63 O36 Ba3 O56 -98.6(17) 2_676 .
Ba4 O36 Ba3 O56 42.7(3) . .
C63 O36 Ba3 O54 135.4(16) 2_676 .
Ba4 O36 Ba3 O54 -83.2(4) . .
C63 O36 Ba3 O53 23(2) 2_676 .
Ba4 O36 Ba3 O53 164.3(6) . .
C63 O36 Ba3 O55 176.2(17) 2_676 .
Ba4 O36 Ba3 O55 -42.5(3) . .
C63 O36 Ba3 O52 -144.3(16) 2_676 .
Ba4 O36 Ba3 O52 -3.0(4) . .
C63 O36 Ba4 O58 -114.5(9) 2_676 .
Ba3 O36 Ba4 O58 85.3(5) . .
C63 O36 Ba4 O30 -82.6(8) 2_676 .
Ba3 O36 Ba4 O30 117.2(4) . .
C63 O36 Ba4 O59 -23.8(9) 2_676 .
Ba3 O36 Ba4 O59 176.0(3) . .
C63 O36 Ba4 O56 116.8(8) 2_676 .
Ba3 O36 Ba4 O56 -43.4(3) . .
C63 O36 Ba4 O63 72.2(11) 2_676 .
Ba3 O36 Ba4 O63 -88.0(7) . .
C63 O36 Ba4 O57 157.7(8) 2_676 .
Ba3 O36 Ba4 O57 -2.5(4) . .
C63 O36 Ba4 O55 -157.2(8) 2_676 .
Ba3 O36 Ba4 O55 42.7(3) . .
C63 O36 Ba4 O62 57.2(8) 2_676 .
Ba3 O36 Ba4 O62 -103.0(3) . .
C63 O36 Ba4 O35 7.5(7) 2_676 2_676
Ba3 O36 Ba4 O35 -152.7(5) . 2_676
Ba3 O36 Ba4 C63 -160.2(9) . 2_676
O14 Eu1 O1 C1 136.8(10) . .
O5 Eu1 O1 C1 71.7(10) . .
O4 Eu1 O1 C1 -0.9(12) . .
O8 Eu1 O1 C1 -159.5(10) . .
O42 Eu1 O1 C1 -84.2(10) . .
N2 Eu1 O1 C1 134.9(11) . .
N1 Eu1 O1 C1 1.4(10) . .
O41 Eu1 O1 C1 -96.4(11) . .
O14 Eu1 O4 C7 -150.3(13) . .
O5 Eu1 O4 C7 -68.7(13) . .
O8 Eu1 O4 C7 147.3(11) . .
O1 Eu1 O4 C7 7.5(14) . .
O42 Eu1 O4 C7 76.4(13) . .
N2 Eu1 O4 C7 -97.0(13) . .
N1 Eu1 O4 C7 5.2(12) . .
O41 Eu1 O4 C7 138.5(13) . .
O14 Eu1 O5 C8 -67.1(12) . .
O4 Eu1 O5 C8 -148.8(12) . .
O8 Eu1 O5 C8 6.8(13) . .
O1 Eu1 O5 C8 82.3(12) . .
O42 Eu1 O5 C8 124.4(11) . .
N2 Eu1 O5 C8 9.9(11) . .
N1 Eu1 O5 C8 145.8(12) . .
O41 Eu1 O5 C8 -110.1(12) . .
O50 Ba2 O7 C14 -10.3(14) . .
O26 Ba2 O7 C14 46.9(15) . .
O20 Ba2 O7 C14 -84.3(15) . .
O51 Ba2 O7 C14 -54.7(17) . .
O52 Ba2 O7 C14 -152.4(14) . .
O48 Ba2 O7 C14 165.4(15) . .
O49 Ba2 O7 C14 77.0(14) . .
O54 Ba2 O7 C14 126.9(14) . .
O50 Ba2 O7 Ba1 -132.6(4) . .
O26 Ba2 O7 Ba1 -75.5(4) . .
O20 Ba2 O7 Ba1 153.3(3) . .
O51 Ba2 O7 Ba1 -177.1(5) . .
O52 Ba2 O7 Ba1 85.3(3) . .
O48 Ba2 O7 Ba1 43.0(3) . .
O49 Ba2 O7 Ba1 -45.4(3) . .
O54 Ba2 O7 Ba1 4.6(4) . .
O9 Ba1 O7 C14 94.9(8) . .
O44 Ba1 O7 C14 -40.5(8) . .
O46 Ba1 O7 C14 125.2(9) . .
O43 Ba1 O7 C14 35.4(8) . .
O49 Ba1 O7 C14 -102.3(8) . .
O47 Ba1 O7 C14 -146.5(7) . .
O48 Ba1 O7 C14 168.7(8) . .
O45 Ba1 O7 C14 -75.2(11) . .
O8 Ba1 O7 C14 -8.7(7) . .
O9 Ba1 O7 Ba2 -116.8(4) . .
O44 Ba1 O7 Ba2 107.8(3) . .
O46 Ba1 O7 Ba2 -86.5(6) . .
O43 Ba1 O7 Ba2 -176.3(3) . .
O49 Ba1 O7 Ba2 46.0(3) . .
O47 Ba1 O7 Ba2 1.8(4) . .
O48 Ba1 O7 Ba2 -43.0(3) . .
O45 Ba1 O7 Ba2 73.1(8) . .
O8 Ba1 O7 Ba2 139.6(5) . .
O14 Eu1 O8 C14 84.3(10) . .
O5 Eu1 O8 C14 12.1(11) . .
O4 Eu1 O8 C14 145.6(9) . .
O1 Eu1 O8 C14 -65.9(9) . .
O42 Eu1 O8 C14 -136.2(10) . .
N2 Eu1 O8 C14 9.0(9) . .
N1 Eu1 O8 C14 -93.1(10) . .
O41 Eu1 O8 C14 154.0(10) . .
O14 Eu1 O8 Ba1 -74.3(6) . .
O5 Eu1 O8 Ba1 -146.5(5) . .
O4 Eu1 O8 Ba1 -12.9(10) . .
O1 Eu1 O8 Ba1 135.6(6) . .
O42 Eu1 O8 Ba1 65.2(6) . .
N2 Eu1 O8 Ba1 -149.5(7) . .
N1 Eu1 O8 Ba1 108.4(7) . .
O41 Eu1 O8 Ba1 -4.5(6) . .
O9 Ba1 O8 C14 -56.4(7) . .
O44 Ba1 O8 C14 154.2(8) . .
O46 Ba1 O8 C14 -89.6(9) . .
O43 Ba1 O8 C14 -124.9(8) . .
O7 Ba1 O8 C14 8.4(7) . .
O49 Ba1 O8 C14 74.0(7) . .
O47 Ba1 O8 C14 75.8(8) . .
O48 Ba1 O8 C14 6.0(7) . .
O45 Ba1 O8 C14 165.1(7) . .
O9 Ba1 O8 Eu1 105.8(6) . .
O44 Ba1 O8 Eu1 -43.5(6) . .
O46 Ba1 O8 Eu1 72.6(9) . .
O43 Ba1 O8 Eu1 37.4(6) . .
O7 Ba1 O8 Eu1 170.7(8) . .
O49 Ba1 O8 Eu1 -123.7(6) . .
O47 Ba1 O8 Eu1 -122.0(6) . .
O48 Ba1 O8 Eu1 168.2(6) . .
O45 Ba1 O8 Eu1 -32.7(7) . .
O44 Ba1 O9 C15 125.6(13) . .
O46 Ba1 O9 C15 -115.9(15) . .
O43 Ba1 O9 C15 153.7(15) . .
O7 Ba1 O9 C15 40.0(14) . .
O49 Ba1 O9 C15 22.0(15) . .
O47 Ba1 O9 C15 -59.9(15) . .
O48 Ba1 O9 C15 -28.0(13) . .
O45 Ba1 O9 C15 -144.8(13) . .
O8 Ba1 O9 C15 82.8(14) . .
O19 Eu2 O10 C15 70.2(10) . .
O16 Eu2 O10 C15 147.3(10) . .
O11 Eu2 O10 C15 -11.6(11) . .
O13 Eu2 O10 C15 -84.2(10) . .
O17 Eu2 O10 C15 -146.1(9) . .
N4 Eu2 O10 C15 -147.5(10) . .
N5 Eu2 O10 C15 93.7(10) . .
N3 Eu2 O10 C15 -8.1(9) . .
O19 Eu2 O11 C21 -74.0(10) . .
O16 Eu2 O11 C21 -136.1(10) . .
O10 Eu2 O11 C21 0.1(12) . .
O13 Eu2 O11 C21 79.2(10) . .
O17 Eu2 O11 C21 158.3(11) . .
N4 Eu2 O11 C21 111.4(10) . .
N5 Eu2 O11 C21 -135.6(11) . .
N3 Eu2 O11 C21 -3.4(10) . .
O19 Eu2 O13 C22 -142.1(10) . .
O16 Eu2 O13 C22 -9.0(12) . .
O11 Eu2 O13 C22 149.6(11) . .
O10 Eu2 O13 C22 -82.1(10) . .
O17 Eu2 O13 C22 70.5(10) . .
N4 Eu2 O13 C22 -4.7(10) . .
N5 Eu2 O13 C22 99.9(11) . .
N3 Eu2 O13 C22 -144.9(11) . .
O36 Ba3 O15 C28 -123.5(15) . .
O22 Ba3 O15 C28 120.4(15) . .
O68 Ba3 O15 C28 173.1(16) . .
O56 Ba3 O15 C28 -92.4(15) . .
O54 Ba3 O15 C28 37.1(16) . .
O53 Ba3 O15 C28 85.5(15) . .
O55 Ba3 O15 C28 -45.4(16) . .
O52 Ba3 O15 C28 -17.9(14) . .
O19 Eu2 O16 C28 160.1(12) . .
O11 Eu2 O16 C28 -133.5(11) . .
O10 Eu2 O16 C28 81.1(11) . .
O13 Eu2 O16 C28 1.7(13) . .
O17 Eu2 O16 C28 -71.2(11) . .
N4 Eu2 O16 C28 -2.6(11) . .
N5 Eu2 O16 C28 -134.0(12) . .
N3 Eu2 O16 C28 111.9(11) . .
O19 Eu2 O17 C29 -3.1(11) . .
O16 Eu2 O17 C29 -73.7(10) . .
O11 Eu2 O17 C29 78.9(10) . .
O10 Eu2 O17 C29 -137.0(9) . .
O13 Eu2 O17 C29 157.8(10) . .
N4 Eu2 O17 C29 -135.5(10) . .
N5 Eu2 O17 C29 1.0(10) . .
N3 Eu2 O17 C29 103.0(10) . .
O16 Eu2 O19 C35 81.7(11) . .
O11 Eu2 O19 C35 -70.7(11) . .
O10 Eu2 O19 C35 161.6(11) . .
O13 Eu2 O19 C35 -135.3(10) . .
O17 Eu2 O19 C35 3.6(12) . .
N4 Eu2 O19 C35 103.7(11) . .
N5 Eu2 O19 C35 -0.4(10) . .
N3 Eu2 O19 C35 -132.5(11) . .
O50 Ba2 O20 C35 -153.1(9) . .
O7 Ba2 O20 C35 -72.1(8) . .
O26 Ba2 O20 C35 155.4(8) . .
O51 Ba2 O20 C35 122.9(9) . .
O52 Ba2 O20 C35 51.9(8) . .
O48 Ba2 O20 C35 -9.5(9) . .
O49 Ba2 O20 C35 -102.5(9) . .
O54 Ba2 O20 C35 59.2(10) . .
O25 Eu3 O21 C36 -83.1(10) . .
O28 Eu3 O21 C36 134.0(9) . .
O32 Eu3 O21 C36 68.5(10) . .
O24 Eu3 O21 C36 -9.7(11) . .
O29 Eu3 O21 C36 -165.3(10) . .
N7 Eu3 O21 C36 -113.8(10) . .
N6 Eu3 O21 C36 -1.5(9) . .
N8 Eu3 O21 C36 129.1(10) . .
O36 Ba3 O22 C36 72.8(8) . .
O68 Ba3 O22 C36 149.0(9) . .
O15 Ba3 O22 C36 -158.7(8) . .
O56 Ba3 O22 C36 100.2(9) . .
O54 Ba3 O22 C36 -52.3(8) . .
O53 Ba3 O22 C36 -125.6(9) . .
O55 Ba3 O22 C36 9.0(9) . .
O52 Ba3 O22 C36 -59.5(9) . .
O25 Eu3 O24 C42 80.1(10) . .
O21 Eu3 O24 C42 12.3(11) . .
O28 Eu3 O24 C42 -150.4(10) . .
O32 Eu3 O24 C42 -74.3(10) . .
O29 Eu3 O24 C42 141.3(9) . .
N7 Eu3 O24 C42 143.9(10) . .
N6 Eu3 O24 C42 4.1(9) . .
N8 Eu3 O24 C42 -96.3(10) . .
O21 Eu3 O25 C43 -150.9(11) . .
O28 Eu3 O25 C43 7.2(12) . .
O32 Eu3 O25 C43 137.2(10) . .
O24 Eu3 O25 C43 79.4(11) . .
O29 Eu3 O25 C43 -73.2(11) . .
N7 Eu3 O25 C43 3.9(10) . .
N6 Eu3 O25 C43 143.1(11) . .
N8 Eu3 O25 C43 -104.0(11) . .
O50 Ba2 O26 C43 -170.8(15) . .
O7 Ba2 O26 C43 126.4(14) . .
O20 Ba2 O26 C43 -117.0(14) . .
O51 Ba2 O26 C43 -84.5(15) . .
O52 Ba2 O26 C43 -36.1(15) . .
O48 Ba2 O26 C43 45.0(16) . .
O49 Ba2 O26 C43 98.5(15) . .
O54 Ba2 O26 C43 20.7(14) . .
O61 Eu4 O27 C49 15(2) . .
O40 Eu4 O27 C49 -56.4(17) . .
O37 Eu4 O27 C49 167.5(16) . .
O33 Eu4 O27 C49 -144.2(18) . .
N9 Eu4 O27 C49 148.1(18) . .
O35 Eu4 O27 C49 89.2(18) . .
N10 Eu4 O27 C49 -99.8(18) . .
O60 Eu4 O27 C49 23.3(17) . .
O25 Eu3 O28 C49 -8.5(12) . .
O21 Eu3 O28 C49 124.4(10) . .
O32 Eu3 O28 C49 -165.1(11) . .
O24 Eu3 O28 C49 -84.6(10) . .
O29 Eu3 O28 C49 66.9(11) . .
N7 Eu3 O28 C49 -5.3(10) . .
N6 Eu3 O28 C49 -117.4(10) . .
N8 Eu3 O28 C49 129.2(11) . .
O25 Eu3 O29 C50 -146.6(10) . .
O21 Eu3 O29 C50 -69.8(9) . .
O28 Eu3 O29 C50 84.9(10) . .
O32 Eu3 O29 C50 15.1(11) . .
O24 Eu3 O29 C50 150.3(9) . .
N7 Eu3 O29 C50 147.8(10) . .
N6 Eu3 O29 C50 -90.8(10) . .
N8 Eu3 O29 C50 9.7(9) . .
O58 Ba4 O30 C50 109.2(13) . .
O59 Ba4 O30 C50 -169.0(13) . .
O56 Ba4 O30 C50 -25.2(14) . .
O36 Ba4 O30 C50 -45.7(12) . .
O63 Ba4 O30 C50 147.8(12) . .
O57 Ba4 O30 C50 56.2(13) . .
O55 Ba4 O30 C50 23.9(12) . .
O62 Ba4 O30 C50 -113.8(13) . .
O35 Ba4 O30 C50 -91.4(13) 2_676 .
C63 Ba4 O30 C50 -68.9(13) 2_676 .
O25 Eu3 O32 C56 140.9(10) . .
O21 Eu3 O32 C56 74.1(11) . .
O28 Eu3 O32 C56 -78.2(11) . .
O24 Eu3 O32 C56 -159.3(11) . .
O29 Eu3 O32 C56 -1.1(12) . .
N7 Eu3 O32 C56 -103.6(11) . .
N6 Eu3 O32 C56 135.0(11) . .
N8 Eu3 O32 C56 4.4(10) . .
O61 Eu4 O33 C57 144.1(10) . .
O27 Eu4 O33 C57 -62.3(10) . .
O40 Eu4 O33 C57 -141.1(10) . .
O37 Eu4 O33 C57 91.6(10) . .
N9 Eu4 O33 C57 19.5(9) . .
O35 Eu4 O33 C57 25.2(11) . .
N10 Eu4 O33 C57 155.1(11) . .
O60 Eu4 O33 C57 -79.4(11) . .
O61 Eu4 O35 C63 -145.5(10) . .
O27 Eu4 O35 C63 77.6(10) . .
O40 Eu4 O35 C63 159.9(9) . .
O37 Eu4 O35 C63 -66.0(9) . .
O33 Eu4 O35 C63 4.9(11) . .
N9 Eu4 O35 C63 10.6(9) . .
N10 Eu4 O35 C63 -92.3(10) . .
O60 Eu4 O35 C63 140.7(10) . .
O61 Eu4 O35 Ba4 37.8(7) . 2_676
O27 Eu4 O35 Ba4 -99.1(7) . 2_676
O40 Eu4 O35 Ba4 -16.8(10) . 2_676
O37 Eu4 O35 Ba4 117.4(7) . 2_676
O33 Eu4 O35 Ba4 -171.8(6) . 2_676
N9 Eu4 O35 Ba4 -166.0(8) . 2_676
N10 Eu4 O35 Ba4 91.1(8) . 2_676
O60 Eu4 O35 Ba4 -35.9(7) . 2_676
O61 Eu4 O37 C64 -93.0(12) . .
O27 Eu4 O37 C64 105.8(12) . .
O40 Eu4 O37 C64 -17.3(13) . .
O33 Eu4 O37 C64 60.9(11) . .
N9 Eu4 O37 C64 125.5(12) . .
O35 Eu4 O37 C64 -167.7(12) . .
N10 Eu4 O37 C64 -8.8(11) . .
O60 Eu4 O37 C64 -128.2(11) . .
O61 Eu4 O40 C70 83.8(12) . .
O27 Eu4 O40 C70 -136.0(12) . .
O37 Eu4 O40 C70 13.8(13) . .
O33 Eu4 O40 C70 -64.9(12) . .
N9 Eu4 O40 C70 -94.6(13) . .
O35 Eu4 O40 C70 134.7(11) . .
N10 Eu4 O40 C70 5.2(11) . .
O60 Eu4 O40 C70 153.5(12) . .
O50 Ba2 O48 Ba1 -34.0(7) . .
O7 Ba2 O48 Ba1 -41.6(3) . .
O26 Ba2 O48 Ba1 73.3(4) . .
O20 Ba2 O48 Ba1 -122.6(3) . .
O51 Ba2 O48 Ba1 164.3(3) . .
O52 Ba2 O48 Ba1 175.5(3) . .
O49 Ba2 O48 Ba1 22.6(3) . .
O54 Ba2 O48 Ba1 98.8(3) . .
O9 Ba1 O48 Ba2 116.8(3) . .
O44 Ba1 O48 Ba2 -26.9(6) . .
O46 Ba1 O48 Ba2 -171.5(4) . .
O43 Ba1 O48 Ba2 118.8(3) . .
O7 Ba1 O48 Ba2 40.3(3) . .
O49 Ba1 O48 Ba2 -22.6(3) . .
O47 Ba1 O48 Ba2 -92.6(3) . .
O45 Ba1 O48 Ba2 -116.8(3) . .
O8 Ba1 O48 Ba2 42.3(3) . .
O50 Ba2 O49 Ba1 128.3(4) . .
O7 Ba2 O49 Ba1 44.6(3) . .
O26 Ba2 O49 Ba1 -161.6(4) . .
O20 Ba2 O49 Ba1 79.9(5) . .
O51 Ba2 O49 Ba1 -165.4(3) . .
O52 Ba2 O49 Ba1 -62.6(4) . .
O48 Ba2 O49 Ba1 -23.0(3) . .
O54 Ba2 O49 Ba1 -88.2(3) . .
O9 Ba1 O49 Ba2 -23.6(4) . .
O44 Ba1 O49 Ba2 -159.7(3) . .
O46 Ba1 O49 Ba2 75.7(6) . .
O43 Ba1 O49 Ba2 -116.3(4) . .
O7 Ba1 O49 Ba2 -43.0(3) . .
O47 Ba1 O49 Ba2 91.1(3) . .
O48 Ba1 O49 Ba2 22.6(3) . .
O45 Ba1 O49 Ba2 146.5(3) . .
O8 Ba1 O49 Ba2 -90.2(3) . .
O50 Ba2 O52 Ba3 138.2(4) . .
O7 Ba2 O52 Ba3 -106.5(3) . .
O26 Ba2 O52 Ba3 56.6(4) . .
O20 Ba2 O52 Ba3 175.4(4) . .
O51 Ba2 O52 Ba3 104.8(4) . .
O48 Ba2 O52 Ba3 -66.6(3) . .
O49 Ba2 O52 Ba3 -25.5(5) . .
O54 Ba2 O52 Ba3 0.4(3) . .
O36 Ba3 O52 Ba2 -119.6(3) . .
O22 Ba3 O52 Ba2 6.9(5) . .
O68 Ba3 O52 Ba2 142.5(5) . .
O15 Ba3 O52 Ba2 126.4(4) . .
O56 Ba3 O52 Ba2 -162.2(4) . .
O54 Ba3 O52 Ba2 -0.4(3) . .
O53 Ba3 O52 Ba2 65.9(3) . .
O55 Ba3 O52 Ba2 -78.9(3) . .
O36 Ba3 O54 Ba2 105.2(3) . .
O22 Ba3 O54 Ba2 -174.8(3) . .
O68 Ba3 O54 Ba2 -143.0(4) . .
O15 Ba3 O54 Ba2 -54.4(4) . .
O56 Ba3 O54 Ba2 24.0(5) . .
O53 Ba3 O54 Ba2 -100.2(3) . .
O55 Ba3 O54 Ba2 66.6(3) . .
O52 Ba3 O54 Ba2 0.4(3) . .
O50 Ba2 O54 Ba3 -139.7(5) . .
O7 Ba2 O54 Ba3 116.7(3) . .
O26 Ba2 O54 Ba3 -124.0(4) . .
O20 Ba2 O54 Ba3 -7.8(5) . .
O51 Ba2 O54 Ba3 -62.5(3) . .
O52 Ba2 O54 Ba3 -0.4(3) . .
O48 Ba2 O54 Ba3 77.7(3) . .
O49 Ba2 O54 Ba3 161.6(3) . .
O36 Ba3 O55 Ba4 40.0(3) . .
O22 Ba3 O55 Ba4 123.3(3) . .
O68 Ba3 O55 Ba4 37.1(6) . .
O15 Ba3 O55 Ba4 -69.1(4) . .
O56 Ba3 O55 Ba4 -25.3(2) . .
O54 Ba3 O55 Ba4 -174.9(3) . .
O53 Ba3 O55 Ba4 -156.7(3) . .
O52 Ba3 O55 Ba4 -98.4(3) . .
O58 Ba4 O55 Ba3 172.5(4) . .
O30 Ba4 O55 Ba3 -114.1(3) . .
O59 Ba4 O55 Ba3 -132.4(3) . .
O56 Ba4 O55 Ba3 25.4(3) . .
O36 Ba4 O55 Ba3 -39.2(2) . .
O63 Ba4 O55 Ba3 117.6(3) . .
O57 Ba4 O55 Ba3 94.7(3) . .
O62 Ba4 O55 Ba3 20.2(5) . .
O35 Ba4 O55 Ba3 -50.0(3) 2_676 .
C63 Ba4 O55 Ba3 -47.4(3) 2_676 .
O58 Ba4 O56 Ba3 -78.0(5) . .
O30 Ba4 O56 Ba3 19.8(4) . .
O59 Ba4 O56 Ba3 128.0(4) . .
O36 Ba4 O56 Ba3 41.6(3) . .
O63 Ba4 O56 Ba3 -155.0(3) . .
O57 Ba4 O56 Ba3 -96.5(3) . .
O55 Ba4 O56 Ba3 -26.4(3) . .
O62 Ba4 O56 Ba3 149.9(4) . .
O35 Ba4 O56 Ba3 82.6(3) 2_676 .
C63 Ba4 O56 Ba3 61.5(3) 2_676 .
O36 Ba3 O56 Ba4 -42.6(3) . .
O22 Ba3 O56 Ba4 -74.2(6) . .
O68 Ba3 O56 Ba4 -120.3(4) . .
O15 Ba3 O56 Ba4 168.2(4) . .
O54 Ba3 O56 Ba4 68.2(4) . .
O53 Ba3 O56 Ba4 165.7(3) . .
O55 Ba3 O56 Ba4 26.6(3) . .
O52 Ba3 O56 Ba4 92.2(3) . .
O14 Eu1 N1 C2 -142.9(10) . .
O5 Eu1 N1 C2 -92.2(11) . .
O4 Eu1 N1 C2 -179.0(12) . .
O8 Eu1 N1 C2 33.3(13) . .
O1 Eu1 N1 C2 3.1(10) . .
O42 Eu1 N1 C2 75.5(11) . .
N2 Eu1 N1 C2 -47.9(11) . .
O41 Eu1 N1 C2 133.6(10) . .
O14 Eu1 N1 C6 27.1(12) . .
O5 Eu1 N1 C6 77.7(10) . .
O4 Eu1 N1 C6 -9.1(10) . .
O8 Eu1 N1 C6 -156.8(9) . .
O1 Eu1 N1 C6 173.0(11) . .
O42 Eu1 N1 C6 -114.6(11) . .
N2 Eu1 N1 C6 122.0(10) . .
O41 Eu1 N1 C6 -56.5(11) . .
O14 Eu1 N2 C13 -99.3(9) . .
O5 Eu1 N2 C13 174.1(10) . .
O4 Eu1 N2 C13 -154.6(8) . .
O8 Eu1 N2 C13 -8.6(9) . .
O1 Eu1 N2 C13 79.6(9) . .
O42 Eu1 N2 C13 33.5(10) . .
N1 Eu1 N2 C13 126.5(9) . .
O41 Eu1 N2 C13 -55.2(10) . .
O14 Eu1 N2 C9 83.6(10) . .
O5 Eu1 N2 C9 -3.0(9) . .
O4 Eu1 N2 C9 28.3(12) . .
O8 Eu1 N2 C9 174.3(10) . .
O1 Eu1 N2 C9 -97.5(10) . .
O42 Eu1 N2 C9 -143.7(9) . .
N1 Eu1 N2 C9 -50.6(10) . .
O41 Eu1 N2 C9 127.7(9) . .
O19 Eu2 N3 C20 99.4(10) . .
O16 Eu2 N3 C20 147.9(9) . .
O11 Eu2 N3 C20 -1.2(9) . .
O10 Eu2 N3 C20 -178.1(10) . .
O13 Eu2 N3 C20 -82.0(9) . .
O17 Eu2 N3 C20 -27.5(11) . .
N4 Eu2 N3 C20 -126.7(9) . .
N5 Eu2 N3 C20 51.3(10) . .
O19 Eu2 N3 C16 -76.7(9) . .
O16 Eu2 N3 C16 -28.1(11) . .
O11 Eu2 N3 C16 -177.3(10) . .
O10 Eu2 N3 C16 5.8(8) . .
O13 Eu2 N3 C16 101.9(9) . .
O17 Eu2 N3 C16 156.4(8) . .
N4 Eu2 N3 C16 57.2(10) . .
N5 Eu2 N3 C16 -124.8(9) . .
O19 Eu2 N4 C23 161.8(9) . .
O16 Eu2 N4 C23 -174.3(11) . .
O11 Eu2 N4 C23 -25.8(12) . .
O10 Eu2 N4 C23 104.8(10) . .
O13 Eu2 N4 C23 9.4(9) . .
O17 Eu2 N4 C23 -74.4(10) . .
N5 Eu2 N4 C23 -118.7(10) . .
N3 Eu2 N4 C23 59.3(11) . .
O19 Eu2 N4 C27 -29.8(12) . .
O16 Eu2 N4 C27 -6.0(9) . .
O11 Eu2 N4 C27 142.6(9) . .
O10 Eu2 N4 C27 -86.8(10) . .
O13 Eu2 N4 C27 177.8(11) . .
O17 Eu2 N4 C27 94.0(10) . .
N5 Eu2 N4 C27 49.7(11) . .
N3 Eu2 N4 C27 -132.3(9) . .
O19 Eu2 N5 C30 -179.5(10) . .
O16 Eu2 N5 C30 101.1(10) . .
O11 Eu2 N5 C30 -78.7(9) . .
O10 Eu2 N5 C30 154.9(8) . .
O13 Eu2 N5 C30 -28.1(11) . .
O17 Eu2 N5 C30 4.1(9) . .
N4 Eu2 N5 C30 51.5(10) . .
N3 Eu2 N5 C30 -126.6(9) . .
O19 Eu2 N5 C34 -3.2(9) . .
O16 Eu2 N5 C34 -82.7(9) . .
O11 Eu2 N5 C34 97.6(9) . .
O10 Eu2 N5 C34 -28.9(11) . .
O13 Eu2 N5 C34 148.1(8) . .
O17 Eu2 N5 C34 -179.6(10) . .
N4 Eu2 N5 C34 -132.2(9) . .
N3 Eu2 N5 C34 49.6(10) . .
O25 Eu3 N6 C41 -97.6(9) . .
O21 Eu3 N6 C41 -177.3(10) . .
O28 Eu3 N6 C41 31.6(11) . .
O32 Eu3 N6 C41 79.3(9) . .
O24 Eu3 N6 C41 -4.6(9) . .
O29 Eu3 N6 C41 -154.4(9) . .
N7 Eu3 N6 C41 -53.1(10) . .
N8 Eu3 N6 C41 128.3(9) . .
O25 Eu3 N6 C37 85.3(9) . .
O21 Eu3 N6 C37 5.6(9) . .
O28 Eu3 N6 C37 -145.5(8) . .
O32 Eu3 N6 C37 -97.8(9) . .
O24 Eu3 N6 C37 178.3(10) . .
O29 Eu3 N6 C37 28.5(11) . .
N7 Eu3 N6 C37 129.8(9) . .
N8 Eu3 N6 C37 -48.8(10) . .
O25 Eu3 N7 C44 -1.3(9) . .
O21 Eu3 N7 C44 32.0(12) . .
O28 Eu3 N7 C44 -178.5(11) . .
O32 Eu3 N7 C44 -151.2(9) . .
O24 Eu3 N7 C44 -94.5(10) . .
O29 Eu3 N7 C44 84.1(10) . .
N6 Eu3 N7 C44 -50.7(11) . .
N8 Eu3 N7 C44 127.9(10) . .
O25 Eu3 N7 C48 179.9(11) . .
O21 Eu3 N7 C48 -146.7(9) . .
O28 Eu3 N7 C48 2.8(10) . .
O32 Eu3 N7 C48 30.1(12) . .
O24 Eu3 N7 C48 86.7(10) . .
O29 Eu3 N7 C48 -94.6(10) . .
N6 Eu3 N7 C48 130.6(10) . .
N8 Eu3 N7 C48 -50.9(11) . .
O25 Eu3 N8 C55 -149.8(8) . .
O21 Eu3 N8 C55 -102.7(9) . .
O28 Eu3 N8 C55 79.8(9) . .
O32 Eu3 N8 C55 0.9(9) . .
O24 Eu3 N8 C55 25.1(11) . .
O29 Eu3 N8 C55 176.0(10) . .
N7 Eu3 N8 C55 127.8(9) . .
N6 Eu3 N8 C55 -53.5(10) . .
O25 Eu3 N8 C51 27.0(11) . .
O21 Eu3 N8 C51 74.1(9) . .
O28 Eu3 N8 C51 -103.4(9) . .
O32 Eu3 N8 C51 177.7(10) . .
O24 Eu3 N8 C51 -158.1(8) . .
O29 Eu3 N8 C51 -7.2(8) . .
N7 Eu3 N8 C51 -55.4(9) . .
N6 Eu3 N8 C51 123.3(9) . .
O61 Eu4 N9 C62 23.5(11) . .
O27 Eu4 N9 C62 -116.5(9) . .
O40 Eu4 N9 C62 -158.5(8) . .
O37 Eu4 N9 C62 75.4(9) . .
O33 Eu4 N9 C62 168.4(10) . .
O35 Eu4 N9 C62 -6.5(8) . .
N10 Eu4 N9 C62 121.2(9) . .
O60 Eu4 N9 C62 -59.6(9) . .
O61 Eu4 N9 C58 -152.7(9) . .
O27 Eu4 N9 C58 67.3(9) . .
O40 Eu4 N9 C58 25.2(12) . .
O37 Eu4 N9 C58 -100.9(10) . .
O33 Eu4 N9 C58 -7.9(9) . .
O35 Eu4 N9 C58 177.2(10) . .
N10 Eu4 N9 C58 -55.1(10) . .
O60 Eu4 N9 C58 124.2(9) . .
O61 Eu4 N10 C65 89.6(10) . .
O27 Eu4 N10 C65 -129.0(10) . .
O40 Eu4 N10 C65 -177.7(11) . .
O37 Eu4 N10 C65 10.0(9) . .
O33 Eu4 N10 C65 -84.4(10) . .
N9 Eu4 N10 C65 -39.5(11) . .
O35 Eu4 N10 C65 38.6(12) . .
O60 Eu4 N10 C65 141.4(9) . .
O61 Eu4 N10 C69 -101.9(10) . .
O27 Eu4 N10 C69 39.5(11) . .
O40 Eu4 N10 C69 -9.1(9) . .
O37 Eu4 N10 C69 178.6(11) . .
O33 Eu4 N10 C69 84.1(10) . .
N9 Eu4 N10 C69 129.0(10) . .
O35 Eu4 N10 C69 -152.8(9) . .
O60 Eu4 N10 C69 -50.1(11) . .
Eu1 O1 C1 O2 173.9(11) . .
Eu1 O1 C1 C2 -5.0(17) . .
C6 N1 C2 C3 1(2) . .
Eu1 N1 C2 C3 170.7(12) . .
C6 N1 C2 C1 -176.3(12) . .
Eu1 N1 C2 C1 -6.4(16) . .
O2 C1 C2 N1 -171.5(14) . .
O1 C1 C2 N1 7.4(19) . .
O2 C1 C2 C3 11(2) . .
O1 C1 C2 C3 -169.9(14) . .
N1 C2 C3 C4 -1(2) . .
C1 C2 C3 C4 176.1(15) . .
C2 C3 C4 C5 -1(3) . .
C3 C4 C5 C6 3(3) . .
C2 N1 C6 C5 1(2) . .
Eu1 N1 C6 C5 -169.1(12) . .
C2 N1 C6 C7 -177.9(13) . .
Eu1 N1 C6 C7 12.1(17) . .
C4 C5 C6 N1 -3(3) . .
C4 C5 C6 C7 176.1(17) . .
Eu1 O4 C7 O3 176.8(15) . .
Eu1 O4 C7 C6 -1(2) . .
N1 C6 C7 O3 174.4(17) . .
C5 C6 C7 O3 -4(3) . .
N1 C6 C7 O4 -7(2) . .
C5 C6 C7 O4 173.8(16) . .
Eu1 O5 C8 O6 162.8(12) . .
Eu1 O5 C8 C9 -14.0(17) . .
C13 N2 C9 C10 -1(2) . .
Eu1 N2 C9 C10 176.2(10) . .
C13 N2 C9 C8 -179.0(11) . .
Eu1 N2 C9 C8 -1.8(15) . .
O6 C8 C9 N2 -167.8(13) . .
O5 C8 C9 N2 9.4(18) . .
O6 C8 C9 C10 14(2) . .
O5 C8 C9 C10 -168.5(13) . .
N2 C9 C10 C11 -1(2) . .
C8 C9 C10 C11 176.6(13) . .
C9 C10 C11 C12 3(2) . .
C10 C11 C12 C13 -2(2) . .
C9 N2 C13 C12 1.5(19) . .
Eu1 N2 C13 C12 -175.7(9) . .
C9 N2 C13 C14 -174.9(11) . .
Eu1 N2 C13 C14 7.9(14) . .
C11 C12 C13 N2 0(2) . .
C11 C12 C13 C14 176.5(12) . .
Ba2 O7 C14 O8 -105.5(16) . .
Ba1 O7 C14 O8 18.2(14) . .
Ba2 O7 C14 C13 78.3(17) . .
Ba1 O7 C14 C13 -158.0(9) . .
Eu1 O8 C14 O7 175.1(9) . .
Ba1 O8 C14 O7 -16.9(13) . .
Eu1 O8 C14 C13 -8.6(15) . .
Ba1 O8 C14 C13 159.3(10) . .
N2 C13 C14 O7 176.7(11) . .
C12 C13 C14 O7 0.2(19) . .
N2 C13 C14 O8 0.1(17) . .
C12 C13 C14 O8 -176.3(12) . .
Ba1 O9 C15 O10 67(2) . .
Ba1 O9 C15 C16 -113.1(13) . .
Eu2 O10 C15 O9 -171.6(10) . .
Eu2 O10 C15 C16 8.9(15) . .
C20 N3 C16 C17 -1.3(19) . .
Eu2 N3 C16 C17 174.8(9) . .
C20 N3 C16 C15 179.7(11) . .
Eu2 N3 C16 C15 -4.2(14) . .
O9 C15 C16 N3 178.0(11) . .
O10 C15 C16 N3 -2.5(16) . .
O9 C15 C16 C17 -1.0(19) . .
O10 C15 C16 C17 178.6(12) . .
N3 C16 C17 C18 3(2) . .
C15 C16 C17 C18 -178.5(12) . .
C16 C17 C18 C19 -3(2) . .
C17 C18 C19 C20 2(2) . .
C16 N3 C20 C19 0.4(19) . .
Eu2 N3 C20 C19 -175.7(10) . .
C16 N3 C20 C21 -179.2(11) . .
Eu2 N3 C20 C21 4.7(15) . .
C18 C19 C20 N3 -1(2) . .
C18 C19 C20 C21 178.7(13) . .
Eu2 O11 C21 O12 -174.0(10) . .
Eu2 O11 C21 C20 6.9(16) . .
N3 C20 C21 O12 173.5(12) . .
C19 C20 C21 O12 -6(2) . .
N3 C20 C21 O11 -7.3(17) . .
C19 C20 C21 O11 173.0(13) . .
Eu2 O13 C22 O14 179.1(10) . 2_767
Eu2 O13 C22 C23 0.3(16) . .
C27 N4 C23 C24 -3(2) . .
Eu2 N4 C23 C24 165.0(11) . .
C27 N4 C23 C22 178.9(11) . .
Eu2 N4 C23 C22 -12.6(15) . .
O14 C22 C23 N4 -170.8(12) 2_767 .
O13 C22 C23 N4 8.2(17) . .
O14 C22 C23 C24 12(2) 2_767 .
O13 C22 C23 C24 -169.4(14) . .
N4 C23 C24 C25 1(2) . .
C22 C23 C24 C25 178.7(15) . .
C23 C24 C25 C26 2(3) . .
C24 C25 C26 C27 -2(3) . .
C23 N4 C27 C26 3(2) . .
Eu2 N4 C27 C26 -165.8(12) . .
C23 N4 C27 C28 -178.7(12) . .
Eu2 N4 C27 C28 12.6(15) . .
C25 C26 C27 N4 0(2) . .
C25 C26 C27 C28 -178.4(15) . .
Ba3 O15 C28 O16 16(3) . .
Ba3 O15 C28 C27 -164.3(9) . .
Eu2 O16 C28 O15 -170.9(12) . .
Eu2 O16 C28 C27 9.5(17) . .
N4 C27 C28 O15 166.5(14) . .
C26 C27 C28 O15 -15(2) . .
N4 C27 C28 O16 -13.9(17) . .
C26 C27 C28 O16 164.5(15) . .
Eu2 O17 C29 O18 178.3(10) . .
Eu2 O17 C29 C30 -5.2(16) . .
C34 N5 C30 C31 -1(2) . .
Eu2 N5 C30 C31 175.5(10) . .
C34 N5 C30 C29 175.6(11) . .
Eu2 N5 C30 C29 -8.1(15) . .
O18 C29 C30 N5 -174.6(12) . .
O17 C29 C30 N5 8.6(18) . .
O18 C29 C30 C31 2(2) . .
O17 C29 C30 C31 -175.0(12) . .
N5 C30 C31 C32 0(2) . .
C29 C30 C31 C32 -176.4(13) . .
C30 C31 C32 C33 0(2) . .
C31 C32 C33 C34 2(2) . .
C30 N5 C34 C33 2.2(19) . .
Eu2 N5 C34 C33 -174.1(10) . .
C30 N5 C34 C35 -177.8(11) . .
Eu2 N5 C34 C35 5.9(14) . .
C32 C33 C34 N5 -3(2) . .
C32 C33 C34 C35 177.3(14) . .
Eu2 O19 C35 O20 -174.7(9) . .
Eu2 O19 C35 C34 3.6(17) . .
Ba2 O20 C35 O19 40.1(16) . .
Ba2 O20 C35 C34 -138.2(10) . .
N5 C34 C35 O19 -6.1(18) . .
C33 C34 C35 O19 173.8(13) . .
N5 C34 C35 O20 172.2(11) . .
C33 C34 C35 O20 -8(2) . .
Ba3 O22 C36 O21 -38.3(14) . .
Ba3 O22 C36 C37 139.0(9) . .
Eu3 O21 C36 O22 175.1(9) . .
Eu3 O21 C36 C37 -2.2(15) . .
C41 N6 C37 C38 -2(2) . .
Eu3 N6 C37 C38 175.2(10) . .
C41 N6 C37 C36 174.4(11) . .
Eu3 N6 C37 C36 -8.6(14) . .
O22 C36 C37 N6 -170.4(11) . .
O21 C36 C37 N6 7.1(17) . .
O22 C36 C37 C38 6(2) . .
O21 C36 C37 C38 -176.9(13) . .
N6 C37 C38 C39 -1(2) . .
C36 C37 C38 C39 -176.7(14) . .
C37 C38 C39 C40 2(3) . .
C38 C39 C40 C41 -1(2) . .
C37 N6 C41 C40 3(2) . .
Eu3 N6 C41 C40 -174.0(10) . .
C37 N6 C41 C42 -177.9(11) . .
Eu3 N6 C41 C42 4.9(15) . .
C39 C40 C41 N6 -1(2) . .
C39 C40 C41 C42 179.6(14) . .
Eu3 O24 C42 O23 179.7(10) . .
Eu3 O24 C42 C41 -3.3(16) . .
N6 C41 C42 O24 -1.3(18) . .
C40 C41 C42 O24 177.7(13) . .
N6 C41 C42 O23 175.9(12) . .
C40 C41 C42 O23 -5(2) . .
Ba2 O26 C43 O25 -27(2) . .
Ba2 O26 C43 C44 152.7(10) . .
Eu3 O25 C43 O26 173.9(11) . .
Eu3 O25 C43 C44 -5.6(17) . .
C48 N7 C44 C45 1(2) . .
Eu3 N7 C44 C45 -177.8(12) . .
C48 N7 C44 C43 178.2(12) . .
Eu3 N7 C44 C43 -0.6(15) . .
O26 C43 C44 N7 -175.8(13) . .
O25 C43 C44 N7 3.8(17) . .
O26 C43 C44 C45 1(2) . .
O25 C43 C44 C45 -179.0(14) . .
N7 C44 C45 C46 0(3) . .
C43 C44 C45 C46 -176.6(15) . .
C44 C45 C46 C47 -1(3) . .
C45 C46 C47 C48 0(3) . .
C44 N7 C48 C47 -2(2) . .
Eu3 N7 C48 C47 177.2(11) . .
C44 N7 C48 C49 -179.7(12) . .
Eu3 N7 C48 C49 -1.0(16) . .
C46 C47 C48 N7 1(2) . .
C46 C47 C48 C49 178.9(15) . .
Eu4 O27 C49 O28 -51(3) . .
Eu4 O27 C49 C48 130.0(15) . .
Eu3 O28 C49 O27 -172.3(10) . .
Eu3 O28 C49 C48 6.7(16) . .
N7 C48 C49 O27 175.6(12) . .
C47 C48 C49 O27 -3(2) . .
N7 C48 C49 O28 -3.5(18) . .
C47 C48 C49 O28 178.3(14) . .
Ba4 O30 C50 O29 -62.2(19) . .
Ba4 O30 C50 C51 118.8(11) . .
Eu3 O29 C50 O30 170.6(10) . .
Eu3 O29 C50 C51 -10.4(14) . .
C55 N8 C51 C52 3.3(18) . .
Eu3 N8 C51 C52 -173.5(9) . .
C55 N8 C51 C50 -177.7(11) . .
Eu3 N8 C51 C50 5.5(13) . .
O30 C50 C51 N8 -178.3(11) . .
O29 C50 C51 N8 2.7(16) . .
O30 C50 C51 C52 0.7(18) . .
O29 C50 C51 C52 -178.3(11) . .
N8 C51 C52 C53 -1.7(18) . .
C50 C51 C52 C53 179.3(11) . .
C51 C52 C53 C54 0(2) . .
C52 C53 C54 C55 0(2) . .
C51 N8 C55 C54 -3.3(18) . .
Eu3 N8 C55 C54 173.5(9) . .
C51 N8 C55 C56 178.2(11) . .
Eu3 N8 C55 C56 -4.9(15) . .
C53 C54 C55 N8 2(2) . .
C53 C54 C55 C56 -179.9(13) . .
Eu3 O32 C56 O31 170.1(12) . .
Eu3 O32 C56 C55 -8.5(17) . .
N8 C55 C56 O31 -170.3(12) . .
C54 C55 C56 O31 11(2) . .
N8 C55 C56 O32 8.5(18) . .
C54 C55 C56 O32 -169.9(13) . .
Eu4 O33 C57 O34 154.1(11) . .
Eu4 O33 C57 C58 -28.2(15) . .
C62 N9 C58 C59 1.8(19) . .
Eu4 N9 C58 C59 178.2(10) . .
C62 N9 C58 C57 -177.9(11) . .
Eu4 N9 C58 C57 -1.6(14) . .
O34 C57 C58 N9 -163.1(12) . .
O33 C57 C58 N9 19.0(17) . .
O34 C57 C58 C59 17(2) . .
O33 C57 C58 C59 -160.8(13) . .
N9 C58 C59 C60 -3(2) . .
C57 C58 C59 C60 176.5(13) . .
C58 C59 C60 C61 2(2) . .
C59 C60 C61 C62 0(2) . .
C58 N9 C62 C61 0.4(18) . .
Eu4 N9 C62 C61 -176.0(9) . .
C58 N9 C62 C63 179.7(11) . .
Eu4 N9 C62 C63 3.3(14) . .
C60 C61 C62 N9 -1(2) . .
C60 C61 C62 C63 179.6(13) . .
Eu4 O35 C63 O36 167.6(10) . 2_676
Ba4 O35 C63 O36 -14.1(13) 2_676 2_676
Eu4 O35 C63 C62 -12.8(15) . .
Ba4 O35 C63 C62 165.5(10) 2_676 .
Eu4 O35 C63 Ba4 -178.3(7) . 2_676
N9 C62 C63 O36 -174.5(11) . 2_676
C61 C62 C63 O36 5(2) . 2_676
N9 C62 C63 O35 5.9(17) . .
C61 C62 C63 O35 -174.8(12) . .
N9 C62 C63 Ba4 114(3) . 2_676
C61 C62 C63 Ba4 -67(4) . 2_676
Eu4 O37 C64 O38 -174.5(11) . .
Eu4 O37 C64 C65 6.8(18) . .
C69 N10 C65 C66 -3(2) . .
Eu4 N10 C65 C66 166.0(10) . .
C69 N10 C65 C64 -179.3(12) . .
Eu4 N10 C65 C64 -10.8(16) . .
O38 C64 C65 N10 -175.8(13) . .
O37 C64 C65 N10 3.0(19) . .
O38 C64 C65 C66 8(2) . .
O37 C64 C65 C66 -173.6(13) . .
N10 C65 C66 C67 1(2) . .
C64 C65 C66 C67 177.7(15) . .
C65 C66 C67 C68 1(3) . .
C66 C67 C68 C69 -2(3) . .
C65 N10 C69 C68 2(2) . .
Eu4 N10 C69 C68 -166.8(12) . .
C65 N10 C69 C70 -179.2(12) . .
Eu4 N10 C69 C70 12.3(16) . .
C67 C68 C69 N10 0(3) . .
C67 C68 C69 C70 -178.6(16) . .
Eu4 O40 C70 O39 174.9(12) . .
Eu4 O40 C70 C69 -1.1(18) . .
N10 C69 C70 O39 176.1(14) . .
C68 C69 C70 O39 -5(2) . .
N10 C69 C70 O40 -7.5(19) . .
C68 C69 C70 O40 171.5(15) . .
