#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/50/95/4509542.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided the Crystal Eye server at
# http://wwmm.ch.cam.ac.uk/crystaleye/, created by Nick Day at the
# Peter Murray-Rust laboratory.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_4509542
loop_
_publ_author_name
'Biju, S.'
'Reddy, M. L. P.'
'Cowley, Alan H.'
'Vasudevan, Kalyan V.'
_publ_section_title
;
 Molecular Ladders of Lanthanide-3-phenyl-4-benzoyl-5-isoxazolonate and
 Bis(2-(diphenylphosphino)phenyl) Ether Oxide Complexes: The Role of the
 Ancillary Ligand in the Sensitization of Eu3+and Tb3+Luminescence
;
_journal_issue                   8
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              3562
_journal_paper_doi               10.1021/cg900304g
_journal_volume                  9
_journal_year                    2009
_chemical_formula_moiety         'C84 H58 Eu N3 O12 P2'
_chemical_formula_sum            'C84 H58 Eu N3 O12 P2'
_chemical_formula_weight         1515.23
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method
;
manual editing of the .cif file 
created by SHELXTL Ver. 6.10 
;
_cell_angle_alpha                100.6170(3)
_cell_angle_beta                 95.7297(3)
_cell_angle_gamma                107.3852(3)
_cell_formula_units_Z            2
_cell_length_a                   12.38290(3)
_cell_length_b                   12.83870(3)
_cell_length_c                   23.5343(4)
_cell_measurement_reflns_used    15511
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      1.00
_cell_volume                     3461.27(6)
_computing_cell_refinement       'Collect software, Nonius B.V. 1998'
_computing_data_collection       'Collect software, Nonius B.V. 1998'
_computing_data_reduction
;
DENZO and Scalepack (Otwinoski and Minor, 1997)
;
_computing_molecular_graphics    'XP SHELXTL/PC, Siemens Analytical'
_computing_structure_refinement  'XL SHELXTL/PC, Siemens Analytical'
_computing_structure_solution
;
SIR97 - Altomare A., Burla M.C., Camalli M., Cascarano G.L., Giacovazzo C., 
Guagliardi A., Moliterni A.G.G., Polidori G.,Spagna R.
;
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 0.988
_diffrn_measured_fraction_theta_max 0.988
_diffrn_measurement_device_type  'Nonius Kappa CCD'
_diffrn_measurement_method       ω-scan
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0448
_diffrn_reflns_av_sigmaI/netI    0.1118
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            23730
_diffrn_reflns_theta_full        27.37
_diffrn_reflns_theta_max         27.37
_diffrn_reflns_theta_min         1.75
_exptl_absorpt_coefficient_mu    1.021
_exptl_absorpt_correction_T_max  0.904
_exptl_absorpt_correction_T_min  0.855
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
'DENZO and Scalepack (Otwinoski and Minor, 1997'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.454
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             1544
_exptl_crystal_size_max          0.14
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.09
_refine_diff_density_max         1.127
_refine_diff_density_min         -0.574
_refine_diff_density_rms         0.117
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     919
_refine_ls_number_reflns         15502
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.1000
_refine_ls_R_factor_gt           0.0524
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0287P)²+2.4398P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0861
_refine_ls_wR_factor_ref         0.0993
_reflns_number_gt                10772
_reflns_number_total             15502
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg900304gsup1.cif
_cod_data_source_block           sbkv123e
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 
;
_cod_original_cell_volume        3461.3(12)
_cod_original_sg_symbol_Hall     -P1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               4509542
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.3692(3) -0.1362(3) 0.66760(17) 0.0262(9) Uani 1 1 d .
C2 C 0.2485(3) -0.1646(3) 0.65486(16) 0.0244(9) Uani 1 1 d .
C3 C 0.2110(3) -0.2803(3) 0.62382(16) 0.0261(9) Uani 1 1 d .
C4 C 0.0946(3) -0.3551(3) 0.59508(17) 0.0268(9) Uani 1 1 d .
C5 C 0.0438(4) -0.4551(3) 0.61120(18) 0.0327(10) Uani 1 1 d .
H5 H 0.0833 -0.4763 0.6403 0.039 Uiso 1 1 calc R
C6 C -0.0653(4) -0.5230(4) 0.5841(2) 0.0396(11) Uani 1 1 d .
H6 H -0.0994 -0.5891 0.5956 0.048 Uiso 1 1 calc R
C7 C -0.1241(4) -0.4930(4) 0.5400(2) 0.0434(12) Uani 1 1 d .
H7 H -0.1970 -0.5393 0.5214 0.052 Uiso 1 1 calc R
C8 C -0.0735(4) -0.3944(4) 0.52390(19) 0.0424(12) Uani 1 1 d .
H8 H -0.1130 -0.3738 0.4945 0.051 Uiso 1 1 calc R
C9 C 0.0350(4) -0.3255(4) 0.55080(17) 0.0342(11) Uani 1 1 d .
H9 H 0.0683 -0.2592 0.5393 0.041 Uiso 1 1 calc R
C10 C 0.1905(3) -0.0858(3) 0.67043(16) 0.0228(9) Uani 1 1 d .
C11 C 0.0629(3) -0.1170(3) 0.66084(16) 0.0222(9) Uani 1 1 d .
C12 C -0.0077(4) -0.2132(3) 0.67416(17) 0.0304(10) Uani 1 1 d .
H12 H 0.0247 -0.2615 0.6889 0.037 Uiso 1 1 calc R
C13 C -0.1240(4) -0.2372(3) 0.6657(2) 0.0397(11) Uani 1 1 d .
H13 H -0.1702 -0.3021 0.6744 0.048 Uiso 1 1 calc R
C14 C -0.1737(4) -0.1661(4) 0.64438(19) 0.0382(11) Uani 1 1 d .
H14 H -0.2530 -0.1831 0.6386 0.046 Uiso 1 1 calc R
C15 C -0.1050(3) -0.0697(4) 0.63165(19) 0.0366(11) Uani 1 1 d .
H15 H -0.1380 -0.0217 0.6170 0.044 Uiso 1 1 calc R
C16 C 0.0124(3) -0.0445(3) 0.64055(17) 0.0275(10) Uani 1 1 d .
H16 H 0.0584 0.0217 0.6329 0.033 Uiso 1 1 calc R
C17 C 0.4229(3) -0.0278(3) 0.83958(17) 0.0241(9) Uani 1 1 d .
C18 C 0.5334(3) 0.0262(3) 0.87313(16) 0.0214(9) Uani 1 1 d .
C19 C 0.5455(3) -0.0464(3) 0.91088(16) 0.0223(9) Uani 1 1 d .
C20 C 0.6470(3) -0.0427(3) 0.95160(17) 0.0264(9) Uani 1 1 d .
C21 C 0.6368(4) -0.0649(3) 1.00627(17) 0.0324(10) Uani 1 1 d .
H21 H 0.5652 -0.0808 1.0181 0.039 Uiso 1 1 calc R
C22 C 0.7301(4) -0.0641(4) 1.0440(2) 0.0424(12) Uani 1 1 d .
H22 H 0.7217 -0.0775 1.0811 0.051 Uiso 1 1 calc R
C23 C 0.8336(4) -0.0439(5) 1.0265(2) 0.0659(17) Uani 1 1 d .
H23 H 0.8965 -0.0445 1.0514 0.079 Uiso 1 1 calc R
C24 C 0.8462(4) -0.0225(6) 0.9723(3) 0.085(2) Uani 1 1 d .
H24 H 0.9176 -0.0097 0.9605 0.102 Uiso 1 1 calc R
C25 C 0.7533(4) -0.0197(5) 0.9345(2) 0.0583(15) Uani 1 1 d .
H25 H 0.7630 -0.0025 0.8982 0.070 Uiso 1 1 calc R
C26 C 0.5998(3) 0.1342(3) 0.86804(16) 0.0244(9) Uani 1 1 d .
C27 C 0.6952(3) 0.2124(3) 0.91488(17) 0.0281(10) Uani 1 1 d .
C28 C 0.6927(4) 0.2158(4) 0.97414(18) 0.0392(12) Uani 1 1 d .
H28 H 0.6312 0.1671 0.9857 0.047 Uiso 1 1 calc R
C29 C 0.7810(5) 0.2911(4) 1.0156(2) 0.0605(16) Uani 1 1 d .
H29 H 0.7787 0.2949 1.0553 0.073 Uiso 1 1 calc R
C30 C 0.8735(5) 0.3616(5) 0.9977(3) 0.081(2) Uani 1 1 d .
H30 H 0.9350 0.4103 1.0255 0.097 Uiso 1 1 calc R
C31 C 0.8755(5) 0.3604(5) 0.9391(3) 0.0718(19) Uani 1 1 d .
H31 H 0.9374 0.4088 0.9277 0.086 Uiso 1 1 calc R
C32 C 0.7858(4) 0.2875(4) 0.8979(2) 0.0468(13) Uani 1 1 d .
H32 H 0.7856 0.2883 0.8585 0.056 Uiso 1 1 calc R
C33 C 0.7033(3) 0.2689(4) 0.72151(16) 0.0257(9) Uani 1 1 d .
C34 C 0.7139(3) 0.3762(3) 0.75323(16) 0.0222(9) Uani 1 1 d .
C35 C 0.8340(3) 0.4386(3) 0.76006(18) 0.0280(10) Uani 1 1 d .
C36 C 0.9027(3) 0.5508(3) 0.79561(18) 0.0313(10) Uani 1 1 d .
C37 C 0.8769(4) 0.5931(4) 0.84950(19) 0.0435(12) Uani 1 1 d .
H37 H 0.8134 0.5513 0.8630 0.052 Uiso 1 1 calc R
C38 C 0.9445(5) 0.6964(4) 0.8831(2) 0.0544(14) Uani 1 1 d .
H38 H 0.9258 0.7243 0.9188 0.065 Uiso 1 1 calc R
C39 C 1.0392(5) 0.7579(4) 0.8642(3) 0.0570(16) Uani 1 1 d .
H39 H 1.0852 0.8271 0.8872 0.068 Uiso 1 1 calc R
C40 C 1.0660(4) 0.7175(4) 0.8114(3) 0.0492(14) Uani 1 1 d .
H40 H 1.1297 0.7598 0.7984 0.059 Uiso 1 1 calc R
C41 C 0.9991(3) 0.6143(4) 0.7772(2) 0.0396(12) Uani 1 1 d .
H41 H 1.0187 0.5872 0.7417 0.048 Uiso 1 1 calc R
C42 C 0.6148(3) 0.4047(3) 0.76610(15) 0.0218(9) Uani 1 1 d .
C43 C 0.6174(3) 0.5236(3) 0.78182(16) 0.0219(9) Uani 1 1 d .
C44 C 0.6723(4) 0.6012(4) 0.75161(19) 0.0373(11) Uani 1 1 d .
H44 H 0.7137 0.5812 0.7230 0.045 Uiso 1 1 calc R
C45 C 0.6658(4) 0.7085(4) 0.7640(2) 0.0447(12) Uani 1 1 d .
H45 H 0.7011 0.7597 0.7428 0.054 Uiso 1 1 calc R
C46 C 0.6080(4) 0.7402(3) 0.8071(2) 0.0400(11) Uani 1 1 d .
H46 H 0.6051 0.8129 0.8156 0.048 Uiso 1 1 calc R
C47 C 0.5537(4) 0.6634(3) 0.83801(19) 0.0352(11) Uani 1 1 d .
H47 H 0.5159 0.6849 0.8680 0.042 Uiso 1 1 calc R
C48 C 0.5558(3) 0.5545(3) 0.82412(17) 0.0265(9) Uani 1 1 d .
H48 H 0.5157 0.5018 0.8433 0.032 Uiso 1 1 calc R
C49 C 0.2770(5) 0.3057(4) 0.8957(2) 0.0474(13) Uani 1 1 d .
C50 C 0.3893(6) 0.3243(4) 0.9215(2) 0.0706(19) Uani 1 1 d .
H50 H 0.4437 0.3139 0.8985 0.085 Uiso 1 1 calc R
C51 C 0.4198(9) 0.3597(5) 0.9838(3) 0.107(3) Uani 1 1 d .
H51 H 0.4935 0.3711 1.0027 0.128 Uiso 1 1 calc R
C52 C 0.3349(11) 0.3762(6) 1.0149(3) 0.125(4) Uani 1 1 d .
H52 H 0.3540 0.4006 1.0555 0.149 Uiso 1 1 calc R
C53 C 0.2251(10) 0.3591(6) 0.9898(3) 0.118(3) Uani 1 1 d .
H53 H 0.1712 0.3715 1.0126 0.142 Uiso 1 1 calc R
C54 C 0.1961(6) 0.3229(4) 0.9299(2) 0.0735(19) Uani 1 1 d .
H54 H 0.1213 0.3097 0.9121 0.088 Uiso 1 1 calc R
C55 C 0.0984(4) 0.1673(3) 0.80201(17) 0.0305(10) Uani 1 1 d .
C56 C 0.0841(4) 0.0570(4) 0.80472(17) 0.0342(11) Uani 1 1 d .
H56 H 0.1478 0.0336 0.8105 0.041 Uiso 1 1 calc R
C57 C -0.0249(4) -0.0179(4) 0.79888(19) 0.0407(12) Uani 1 1 d .
H57 H -0.0344 -0.0914 0.8014 0.049 Uiso 1 1 calc R
C58 C -0.1196(4) 0.0155(4) 0.7893(2) 0.0474(13) Uani 1 1 d .
H58 H -0.1927 -0.0352 0.7860 0.057 Uiso 1 1 calc R
C59 C -0.1067(4) 0.1241(4) 0.7844(2) 0.0546(14) Uani 1 1 d .
H59 H -0.1709 0.1457 0.7765 0.066 Uiso 1 1 calc R
C60 C 0.0026(4) 0.2009(4) 0.7914(2) 0.0432(12) Uani 1 1 d .
H60 H 0.0118 0.2744 0.7889 0.052 Uiso 1 1 calc R
C61 C 0.2510(3) 0.3880(3) 0.79196(16) 0.0235(9) Uani 1 1 d .
C62 C 0.2557(3) 0.4868(3) 0.83047(18) 0.0312(10) Uani 1 1 d .
H62 H 0.2501 0.4863 0.8695 0.037 Uiso 1 1 calc R
C63 C 0.2683(4) 0.5848(3) 0.81193(19) 0.0351(11) Uani 1 1 d .
H63 H 0.2692 0.6491 0.8380 0.042 Uiso 1 1 calc R
C64 C 0.2797(3) 0.5873(3) 0.75422(18) 0.0325(10) Uani 1 1 d .
H64 H 0.2907 0.6539 0.7418 0.039 Uiso 1 1 calc R
C65 C 0.2749(3) 0.4912(3) 0.71511(18) 0.0291(10) Uani 1 1 d .
H65 H 0.2821 0.4929 0.6763 0.035 Uiso 1 1 calc R
C66 C 0.2595(3) 0.3928(3) 0.73349(16) 0.0225(9) Uani 1 1 d .
C67 C 0.1768(3) 0.2541(3) 0.64485(16) 0.0197(9) Uani 1 1 d .
C68 C 0.0657(3) 0.2579(3) 0.64576(18) 0.0262(9) Uani 1 1 d .
H68 H 0.0468 0.2953 0.6791 0.031 Uiso 1 1 calc R
C69 C -0.0158(3) 0.2047(3) 0.59596(19) 0.0278(10) Uani 1 1 d .
H69 H -0.0906 0.2056 0.5961 0.033 Uiso 1 1 calc R
C70 C 0.0118(3) 0.1504(3) 0.54620(18) 0.0265(10) Uani 1 1 d .
H70 H -0.0444 0.1144 0.5133 0.032 Uiso 1 1 calc R
C71 C 0.1225(3) 0.1495(3) 0.54510(16) 0.0214(9) Uani 1 1 d .
H71 H 0.1412 0.1144 0.5111 0.026 Uiso 1 1 calc R
C72 C 0.2074(3) 0.2014(3) 0.59514(16) 0.0182(8) Uani 1 1 d .
C73 C 0.4389(3) 0.3399(3) 0.59186(16) 0.0220(9) Uani 1 1 d .
C74 C 0.3931(4) 0.4190(3) 0.57546(17) 0.0307(10) Uani 1 1 d .
H74 H 0.3140 0.4016 0.5663 0.037 Uiso 1 1 calc R
C75 C 0.4645(4) 0.5228(4) 0.57277(19) 0.0390(11) Uani 1 1 d .
H75 H 0.4336 0.5755 0.5622 0.047 Uiso 1 1 calc R
C76 C 0.5819(4) 0.5482(4) 0.5858(2) 0.0459(13) Uani 1 1 d .
H76 H 0.6301 0.6178 0.5834 0.055 Uiso 1 1 calc R
C77 C 0.6277(4) 0.4711(4) 0.60237(19) 0.0434(12) Uani 1 1 d .
H77 H 0.7069 0.4893 0.6116 0.052 Uiso 1 1 calc R
C78 C 0.5575(3) 0.3668(4) 0.60554(17) 0.0329(10) Uani 1 1 d .
H78 H 0.5891 0.3150 0.6167 0.039 Uiso 1 1 calc R
C79 C 0.6454(3) -0.1073(3) 0.47168(16) 0.0238(9) Uani 1 1 d .
C80 C 0.6116(3) -0.1440(4) 0.52109(18) 0.0344(11) Uani 1 1 d .
H80 H 0.5926 -0.2196 0.5215 0.041 Uiso 1 1 calc R
C81 C 0.6065(4) -0.0670(5) 0.56985(19) 0.0466(13) Uani 1 1 d .
H81 H 0.5845 -0.0910 0.6032 0.056 Uiso 1 1 calc R
C82 C 0.6341(4) 0.0453(5) 0.5689(2) 0.0521(15) Uani 1 1 d .
H82 H 0.6303 0.0966 0.6016 0.063 Uiso 1 1 calc R
C83 C 0.6670(4) 0.0815(4) 0.5197(2) 0.0457(13) Uani 1 1 d .
H83 H 0.6859 0.1570 0.5193 0.055 Uiso 1 1 calc R
C84 C 0.6721(3) 0.0058(4) 0.47131(19) 0.0345(11) Uani 1 1 d .
H84 H 0.6935 0.0304 0.4381 0.041 Uiso 1 1 calc R
N1 N 0.2953(3) -0.3206(3) 0.61907(15) 0.0327(9) Uani 1 1 d .
N2 N 0.4535(3) -0.1341(3) 0.90389(14) 0.0277(8) Uani 1 1 d .
N3 N 0.8914(3) 0.3791(3) 0.73274(17) 0.0395(9) Uani 1 1 d .
O1 O 0.4488(2) -0.0477(2) 0.69099(12) 0.0316(7) Uani 1 1 d .
O2 O 0.2457(2) 0.0155(2) 0.69314(11) 0.0289(7) Uani 1 1 d .
O3 O 0.3979(2) -0.2298(2) 0.64750(12) 0.0335(7) Uani 1 1 d .
O4 O 0.3662(2) -0.0047(2) 0.80005(11) 0.0282(7) Uani 1 1 d .
O5 O 0.5782(2) 0.1704(2) 0.82313(11) 0.0307(7) Uani 1 1 d .
O6 O 0.3725(2) -0.1218(2) 0.85925(11) 0.0286(7) Uani 1 1 d .
O7 O 0.6218(2) 0.1785(2) 0.70539(11) 0.0277(6) Uani 1 1 d .
O8 O 0.5199(2) 0.3307(2) 0.76254(11) 0.0244(6) Uani 1 1 d .
O9 O 0.8074(2) 0.2708(2) 0.70550(13) 0.0384(7) Uani 1 1 d .
O10 O 0.2602(2) 0.2974(2) 0.69441(11) 0.0254(6) Uani 1 1 d .
O11 O 0.4008(2) 0.1656(2) 0.64634(11) 0.0272(6) Uani 1 1 d .
O12 O 0.3255(2) 0.2054(2) 0.79497(12) 0.0295(7) Uani 1 1 d .
P1 P 0.24355(10) 0.26180(9) 0.81734(4) 0.0271(3) Uani 1 1 d .
P2 P 0.35330(8) 0.20137(8) 0.59506(4) 0.0204(2) Uani 1 1 d .
Eu1 Eu 0.436976(17) 0.129197(16) 0.738431(9) 0.02072(7) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 C1 O3 117.8(3) . .
O1 C1 C2 133.9(4) . .
O3 C1 C2 108.2(3) . .
C1 C2 C10 122.5(4) . .
C1 C2 C3 103.8(3) . .
C10 C2 C3 133.7(4) . .
N1 C3 C2 112.8(3) . .
N1 C3 C4 117.3(3) . .
C2 C3 C4 129.8(4) . .
C5 C4 C9 119.1(4) . .
C5 C4 C3 121.3(3) . .
C9 C4 C3 119.7(3) . .
C6 C5 C4 120.2(4) . .
C6 C5 H5 119.9 . .
C4 C5 H5 119.9 . .
C5 C6 C7 120.3(4) . .
C5 C6 H6 119.8 . .
C7 C6 H6 119.8 . .
C8 C7 C6 119.4(4) . .
C8 C7 H7 120.3 . .
C6 C7 H7 120.3 . .
C7 C8 C9 120.9(4) . .
C7 C8 H8 119.6 . .
C9 C8 H8 119.6 . .
C8 C9 C4 120.1(4) . .
C8 C9 H9 120.0 . .
C4 C9 H9 120.0 . .
O2 C10 C2 120.9(3) . .
O2 C10 C11 116.4(3) . .
C2 C10 C11 122.8(3) . .
C12 C11 C16 118.5(4) . .
C12 C11 C10 122.6(3) . .
C16 C11 C10 118.8(3) . .
C13 C12 C11 120.5(4) . .
C13 C12 H12 119.7 . .
C11 C12 H12 119.7 . .
C12 C13 C14 120.7(4) . .
C12 C13 H13 119.7 . .
C14 C13 H13 119.7 . .
C15 C14 C13 119.6(4) . .
C15 C14 H14 120.2 . .
C13 C14 H14 120.2 . .
C16 C15 C14 120.1(4) . .
C16 C15 H15 120.0 . .
C14 C15 H15 120.0 . .
C15 C16 C11 120.7(4) . .
C15 C16 H16 119.7 . .
C11 C16 H16 119.7 . .
O4 C17 O6 118.3(3) . .
O4 C17 C18 133.5(3) . .
O6 C17 C18 108.1(3) . .
C17 C18 C26 120.6(3) . .
C17 C18 C19 104.3(3) . .
C26 C18 C19 134.8(3) . .
N2 C19 C18 112.8(3) . .
N2 C19 C20 116.7(3) . .
C18 C19 C20 130.3(4) . .
C21 C20 C25 118.7(4) . .
C21 C20 C19 121.1(4) . .
C25 C20 C19 120.2(4) . .
C20 C21 C22 121.6(4) . .
C20 C21 H21 119.2 . .
C22 C21 H21 119.2 . .
C23 C22 C21 119.4(4) . .
C23 C22 H22 120.3 . .
C21 C22 H22 120.3 . .
C22 C23 C24 120.3(4) . .
C22 C23 H23 119.9 . .
C24 C23 H23 119.9 . .
C23 C24 C25 120.9(5) . .
C23 C24 H24 119.6 . .
C25 C24 H24 119.6 . .
C20 C25 C24 119.1(5) . .
C20 C25 H25 120.5 . .
C24 C25 H25 120.5 . .
O5 C26 C18 120.5(3) . .
O5 C26 C27 116.4(3) . .
C18 C26 C27 123.1(3) . .
C32 C27 C28 119.7(4) . .
C32 C27 C26 118.0(4) . .
C28 C27 C26 122.2(4) . .
C29 C28 C27 120.1(4) . .
C29 C28 H28 120.0 . .
C27 C28 H28 120.0 . .
C28 C29 C30 119.4(5) . .
C28 C29 H29 120.3 . .
C30 C29 H29 120.3 . .
C31 C30 C29 120.9(5) . .
C31 C30 H30 119.6 . .
C29 C30 H30 119.6 . .
C32 C31 C30 119.7(5) . .
C32 C31 H31 120.2 . .
C30 C31 H31 120.2 . .
C31 C32 C27 120.2(5) . .
C31 C32 H32 119.9 . .
C27 C32 H32 119.9 . .
O7 C33 O9 117.7(4) . .
O7 C33 C34 133.9(4) . .
O9 C33 C34 108.4(3) . .
C33 C34 C42 120.7(3) . .
C33 C34 C35 104.7(3) . .
C42 C34 C35 134.2(4) . .
N3 C35 C34 112.1(4) . .
N3 C35 C36 116.3(4) . .
C34 C35 C36 131.4(4) . .
C41 C36 C37 118.3(4) . .
C41 C36 C35 120.3(4) . .
C37 C36 C35 121.3(4) . .
C38 C37 C36 120.6(5) . .
C38 C37 H37 119.7 . .
C36 C37 H37 119.7 . .
C39 C38 C37 120.3(5) . .
C39 C38 H38 119.9 . .
C37 C38 H38 119.9 . .
C40 C39 C38 119.9(5) . .
C40 C39 H39 120.1 . .
C38 C39 H39 120.1 . .
C39 C40 C41 120.5(5) . .
C39 C40 H40 119.7 . .
C41 C40 H40 119.7 . .
C40 C41 C36 120.5(5) . .
C40 C41 H41 119.8 . .
C36 C41 H41 119.8 . .
O8 C42 C34 121.4(3) . .
O8 C42 C43 116.7(3) . .
C34 C42 C43 121.9(3) . .
C48 C43 C44 119.3(4) . .
C48 C43 C42 119.3(3) . .
C44 C43 C42 121.2(4) . .
C45 C44 C43 120.0(4) . .
C45 C44 H44 120.0 . .
C43 C44 H44 120.0 . .
C46 C45 C44 120.7(4) . .
C46 C45 H45 119.6 . .
C44 C45 H45 119.6 . .
C45 C46 C47 119.7(4) . .
C45 C46 H46 120.2 . .
C47 C46 H46 120.2 . .
C48 C47 C46 119.8(4) . .
C48 C47 H47 120.1 . .
C46 C47 H47 120.1 . .
C43 C48 C47 120.4(4) . .
C43 C48 H48 119.8 . .
C47 C48 H48 119.8 . .
C54 C49 C50 120.5(5) . .
C54 C49 P1 122.2(4) . .
C50 C49 P1 117.3(4) . .
C49 C50 C51 119.1(7) . .
C49 C50 H50 120.4 . .
C51 C50 H50 120.4 . .
C52 C51 C50 117.1(8) . .
C52 C51 H51 121.5 . .
C50 C51 H51 121.5 . .
C53 C52 C51 124.0(8) . .
C53 C52 H52 118.0 . .
C51 C52 H52 118.0 . .
C52 C53 C54 118.4(8) . .
C52 C53 H53 120.8 . .
C54 C53 H53 120.8 . .
C53 C54 C49 120.9(7) . .
C53 C54 H54 119.6 . .
C49 C54 H54 119.6 . .
C56 C55 C60 119.8(4) . .
C56 C55 P1 116.5(3) . .
C60 C55 P1 123.6(3) . .
C57 C56 C55 119.8(4) . .
C57 C56 H56 120.1 . .
C55 C56 H56 120.1 . .
C58 C57 C56 120.5(4) . .
C58 C57 H57 119.8 . .
C56 C57 H57 119.8 . .
C57 C58 C59 120.3(4) . .
C57 C58 H58 119.8 . .
C59 C58 H58 119.8 . .
C58 C59 C60 119.8(4) . .
C58 C59 H59 120.1 . .
C60 C59 H59 120.1 . .
C59 C60 C55 119.7(4) . .
C59 C60 H60 120.1 . .
C55 C60 H60 120.1 . .
C62 C61 C66 117.1(3) . .
C62 C61 P1 121.5(3) . .
C66 C61 P1 121.2(3) . .
C63 C62 C61 121.6(4) . .
C63 C62 H62 119.2 . .
C61 C62 H62 119.2 . .
C62 C63 C64 119.7(4) . .
C62 C63 H63 120.2 . .
C64 C63 H63 120.2 . .
C65 C64 C63 120.1(4) . .
C65 C64 H64 119.9 . .
C63 C64 H64 119.9 . .
C66 C65 C64 120.0(4) . .
C66 C65 H65 120.0 . .
C64 C65 H65 120.0 . .
C65 C66 O10 119.6(3) . .
C65 C66 C61 121.4(4) . .
O10 C66 C61 118.8(3) . .
O10 C67 C72 116.7(3) . .
O10 C67 C68 121.6(4) . .
C72 C67 C68 121.6(3) . .
C69 C68 C67 118.5(4) . .
C69 C68 H68 120.8 . .
C67 C68 H68 120.8 . .
C70 C69 C68 121.2(4) . .
C70 C69 H69 119.4 . .
C68 C69 H69 119.4 . .
C69 C70 C71 120.0(4) . .
C69 C70 H70 120.0 . .
C71 C70 H70 120.0 . .
C70 C71 C72 120.4(4) . .
C70 C71 H71 119.8 . .
C72 C71 H71 119.8 . .
C67 C72 C71 118.3(3) . .
C67 C72 P2 120.3(3) . .
C71 C72 P2 121.4(3) . .
C78 C73 C74 119.3(4) . .
C78 C73 P2 116.9(3) . .
C74 C73 P2 123.7(3) . .
C75 C74 C73 120.4(4) . .
C75 C74 H74 119.8 . .
C73 C74 H74 119.8 . .
C74 C75 C76 119.8(4) . .
C74 C75 H75 120.1 . .
C76 C75 H75 120.1 . .
C77 C76 C75 120.2(4) . .
C77 C76 H76 119.9 . .
C75 C76 H76 119.9 . .
C76 C77 C78 120.7(4) . .
C76 C77 H77 119.6 . .
C78 C77 H77 119.6 . .
C77 C78 C73 119.5(4) . .
C77 C78 H78 120.2 . .
C73 C78 H78 120.2 . .
C80 C79 C84 119.6(4) . .
C80 C79 P2 122.8(3) . 2_656
C84 C79 P2 117.4(3) . 2_656
C79 C80 C81 119.5(4) . .
C79 C80 H80 120.2 . .
C81 C80 H80 120.2 . .
C82 C81 C80 120.1(4) . .
C82 C81 H81 119.9 . .
C80 C81 H81 119.9 . .
C83 C82 C81 120.2(5) . .
C83 C82 H82 119.9 . .
C81 C82 H82 119.9 . .
C84 C83 C82 120.0(5) . .
C84 C83 H83 120.0 . .
C82 C83 H83 120.0 . .
C83 C84 C79 120.5(4) . .
C83 C84 H84 119.8 . .
C79 C84 H84 119.8 . .
C3 N1 O3 105.9(3) . .
C19 N2 O6 105.4(3) . .
C35 N3 O9 105.7(3) . .
C1 O1 Eu1 128.7(2) . .
C10 O2 Eu1 138.9(2) . .
C1 O3 N1 109.2(3) . .
C17 O4 Eu1 127.9(2) . .
C26 O5 Eu1 141.5(2) . .
C17 O6 N2 109.2(3) . .
C33 O7 Eu1 128.0(2) . .
C42 O8 Eu1 139.4(2) . .
C33 O9 N3 108.8(3) . .
C67 O10 C66 118.4(3) . .
P2 O11 Eu1 163.74(17) . .
P1 O12 Eu1 165.39(16) . .
O12 P1 C49 109.7(2) . .
O12 P1 C55 111.82(18) . .
C49 P1 C55 105.2(2) . .
O12 P1 C61 113.85(17) . .
C49 P1 C61 105.1(2) . .
C55 P1 C61 110.55(18) . .
O11 P2 C73 111.29(16) . .
O11 P2 C79 109.30(16) . 2_656
C73 P2 C79 107.52(18) . 2_656
O11 P2 C72 113.81(16) . .
C73 P2 C72 107.35(17) . .
C79 P2 C72 107.30(17) 2_656 .
O12 Eu1 O11 105.62(9) . .
O12 Eu1 O5 89.85(10) . .
O11 Eu1 O5 144.63(9) . .
O12 Eu1 O1 141.22(10) . .
O11 Eu1 O1 88.56(9) . .
O5 Eu1 O1 99.07(9) . .
O12 Eu1 O2 77.14(10) . .
O11 Eu1 O2 71.46(9) . .
O5 Eu1 O2 143.83(9) . .
O1 Eu1 O2 73.55(9) . .
O12 Eu1 O8 70.70(9) . .
O11 Eu1 O8 80.22(9) . .
O5 Eu1 O8 75.17(9) . .
O1 Eu1 O8 148.06(9) . .
O2 Eu1 O8 128.93(9) . .
O12 Eu1 O7 141.75(9) . .
O11 Eu1 O7 74.62(9) . .
O5 Eu1 O7 73.77(9) . .
O1 Eu1 O7 76.47(10) . .
O2 Eu1 O7 134.68(9) . .
O8 Eu1 O7 71.74(9) . .
O12 Eu1 O4 74.95(9) . .
O11 Eu1 O4 143.11(9) . .
O5 Eu1 O4 71.18(9) . .
O1 Eu1 O4 72.55(9) . .
O2 Eu1 O4 72.87(9) . .
O8 Eu1 O4 131.26(9) . .
O7 Eu1 O4 127.97(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 O1 1.248(4) .
C1 O3 1.369(5) .
C1 C2 1.415(5) .
C2 C10 1.423(5) .
C2 C3 1.441(5) .
C3 N1 1.301(5) .
C3 C4 1.482(5) .
C4 C5 1.391(5) .
C4 C9 1.391(5) .
C5 C6 1.382(6) .
C5 H5 0.9300 .
C6 C7 1.386(6) .
C6 H6 0.9300 .
C7 C8 1.375(6) .
C7 H7 0.9300 .
C8 C9 1.379(6) .
C8 H8 0.9300 .
C9 H9 0.9300 .
C10 O2 1.258(4) .
C10 C11 1.491(5) .
C11 C12 1.393(5) .
C11 C16 1.393(5) .
C12 C13 1.365(6) .
C12 H12 0.9300 .
C13 C14 1.381(6) .
C13 H13 0.9300 .
C14 C15 1.380(6) .
C14 H14 0.9300 .
C15 C16 1.376(5) .
C15 H15 0.9300 .
C16 H16 0.9300 .
C17 O4 1.242(4) .
C17 O6 1.369(4) .
C17 C18 1.412(5) .
C18 C26 1.419(5) .
C18 C19 1.429(5) .
C19 N2 1.312(5) .
C19 C20 1.486(5) .
C20 C21 1.378(5) .
C20 C25 1.378(6) .
C21 C22 1.382(5) .
C21 H21 0.9300 .
C22 C23 1.352(7) .
C22 H22 0.9300 .
C23 C24 1.367(7) .
C23 H23 0.9300 .
C24 C25 1.397(6) .
C24 H24 0.9300 .
C25 H25 0.9300 .
C26 O5 1.266(4) .
C26 C27 1.498(5) .
C27 C32 1.390(6) .
C27 C28 1.391(6) .
C28 C29 1.375(6) .
C28 H28 0.9300 .
C29 C30 1.388(8) .
C29 H29 0.9300 .
C30 C31 1.377(8) .
C30 H30 0.9300 .
C31 C32 1.371(6) .
C31 H31 0.9300 .
C32 H32 0.9300 .
C33 O7 1.253(5) .
C33 O9 1.373(5) .
C33 C34 1.402(5) .
C34 C42 1.426(5) .
C34 C35 1.439(5) .
C35 N3 1.318(5) .
C35 C36 1.476(6) .
C36 C41 1.389(6) .
C36 C37 1.392(6) .
C37 C38 1.380(6) .
C37 H37 0.9300 .
C38 C39 1.370(7) .
C38 H38 0.9300 .
C39 C40 1.369(7) .
C39 H39 0.9300 .
C40 C41 1.380(6) .
C40 H40 0.9300 .
C41 H41 0.9300 .
C42 O8 1.255(4) .
C42 C43 1.492(5) .
C43 C48 1.384(5) .
C43 C44 1.384(5) .
C44 C45 1.382(6) .
C44 H44 0.9300 .
C45 C46 1.370(6) .
C45 H45 0.9300 .
C46 C47 1.385(6) .
C46 H46 0.9300 .
C47 C48 1.384(5) .
C47 H47 0.9300 .
C48 H48 0.9300 .
C49 C54 1.390(8) .
C49 C50 1.392(7) .
C49 P1 1.792(5) .
C50 C51 1.430(9) .
C50 H50 0.9300 .
C51 C52 1.384(12) .
C51 H51 0.9300 .
C52 C53 1.364(12) .
C52 H52 0.9300 .
C53 C54 1.374(8) .
C53 H53 0.9300 .
C54 H54 0.9300 .
C55 C56 1.389(5) .
C55 C60 1.394(6) .
C55 P1 1.799(4) .
C56 C57 1.380(6) .
C56 H56 0.9300 .
C57 C58 1.376(6) .
C57 H57 0.9300 .
C58 C59 1.383(6) .
C58 H58 0.9300 .
C59 C60 1.389(6) .
C59 H59 0.9300 .
C60 H60 0.9300 .
C61 C62 1.399(5) .
C61 C66 1.402(5) .
C61 P1 1.808(4) .
C62 C63 1.377(5) .
C62 H62 0.9300 .
C63 C64 1.385(6) .
C63 H63 0.9300 .
C64 C65 1.378(6) .
C64 H64 0.9300 .
C65 C66 1.376(5) .
C65 H65 0.9300 .
C66 O10 1.392(4) .
C67 O10 1.383(4) .
C67 C72 1.386(5) .
C67 C68 1.393(5) .
C68 C69 1.384(5) .
C68 H68 0.9300 .
C69 C70 1.377(6) .
C69 H69 0.9300 .
C70 C71 1.377(5) .
C70 H70 0.9300 .
C71 C72 1.408(5) .
C71 H71 0.9300 .
C72 P2 1.807(4) .
C73 C78 1.394(5) .
C73 C74 1.395(5) .
C73 P2 1.797(4) .
C74 C75 1.378(6) .
C74 H74 0.9300 .
C75 C76 1.380(6) .
C75 H75 0.9300 .
C76 C77 1.374(6) .
C76 H76 0.9300 .
C77 C78 1.382(6) .
C77 H77 0.9300 .
C78 H78 0.9300 .
C79 C80 1.389(5) .
C79 C84 1.391(5) .
C79 P2 1.801(4) 2_656
C80 C81 1.390(6) .
C80 H80 0.9300 .
C81 C82 1.384(7) .
C81 H81 0.9300 .
C82 C83 1.379(7) .
C82 H82 0.9300 .
C83 C84 1.375(6) .
C83 H83 0.9300 .
C84 H84 0.9300 .
N1 O3 1.441(4) .
N2 O6 1.442(4) .
N3 O9 1.449(4) .
O1 Eu1 2.392(3) .
O2 Eu1 2.394(3) .
O4 Eu1 2.469(3) .
O5 Eu1 2.382(2) .
O7 Eu1 2.432(3) .
O8 Eu1 2.414(3) .
O11 P2 1.496(2) .
O11 Eu1 2.328(2) .
O12 P1 1.495(3) .
O12 Eu1 2.309(3) .
P2 C79 1.801(4) 2_656
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O1 C1 C2 C10 -2.0(7) . .
O3 C1 C2 C10 179.6(3) . .
O1 C1 C2 C3 176.1(4) . .
O3 C1 C2 C3 -2.3(4) . .
C1 C2 C3 N1 1.7(4) . .
C10 C2 C3 N1 179.5(4) . .
C1 C2 C3 C4 -175.0(4) . .
C10 C2 C3 C4 2.9(7) . .
N1 C3 C4 C5 61.2(5) . .
C2 C3 C4 C5 -122.2(5) . .
N1 C3 C4 C9 -118.3(4) . .
C2 C3 C4 C9 58.2(6) . .
C9 C4 C5 C6 -1.0(6) . .
C3 C4 C5 C6 179.4(4) . .
C4 C5 C6 C7 1.2(7) . .
C5 C6 C7 C8 -0.9(7) . .
C6 C7 C8 C9 0.5(7) . .
C7 C8 C9 C4 -0.4(7) . .
C5 C4 C9 C8 0.6(6) . .
C3 C4 C9 C8 -179.8(4) . .
C1 C2 C10 O2 4.6(6) . .
C3 C2 C10 O2 -172.9(4) . .
C1 C2 C10 C11 -175.7(3) . .
C3 C2 C10 C11 6.9(6) . .
O2 C10 C11 C12 -136.1(4) . .
C2 C10 C11 C12 44.2(6) . .
O2 C10 C11 C16 40.6(5) . .
C2 C10 C11 C16 -139.1(4) . .
C16 C11 C12 C13 2.0(6) . .
C10 C11 C12 C13 178.7(4) . .
C11 C12 C13 C14 -0.6(7) . .
C12 C13 C14 C15 -0.2(7) . .
C13 C14 C15 C16 -0.4(7) . .
C14 C15 C16 C11 1.8(7) . .
C12 C11 C16 C15 -2.6(6) . .
C10 C11 C16 C15 -179.4(4) . .
O4 C17 C18 C26 5.8(7) . .
O6 C17 C18 C26 -171.2(3) . .
O4 C17 C18 C19 -179.7(4) . .
O6 C17 C18 C19 3.3(4) . .
C17 C18 C19 N2 -1.7(4) . .
C26 C18 C19 N2 171.6(4) . .
C17 C18 C19 C20 172.2(4) . .
C26 C18 C19 C20 -14.5(7) . .
N2 C19 C20 C21 -47.4(5) . .
C18 C19 C20 C21 138.9(4) . .
N2 C19 C20 C25 130.8(5) . .
C18 C19 C20 C25 -42.9(6) . .
C25 C20 C21 C22 0.3(7) . .
C19 C20 C21 C22 178.5(4) . .
C20 C21 C22 C23 -1.7(7) . .
C21 C22 C23 C24 1.1(9) . .
C22 C23 C24 C25 0.9(10) . .
C21 C20 C25 C24 1.7(8) . .
C19 C20 C25 C24 -176.6(5) . .
C23 C24 C25 C20 -2.3(10) . .
C17 C18 C26 O5 -20.5(6) . .
C19 C18 C26 O5 167.0(4) . .
C17 C18 C26 C27 157.7(4) . .
C19 C18 C26 C27 -14.8(7) . .
O5 C26 C27 C32 -31.3(6) . .
C18 C26 C27 C32 150.4(4) . .
O5 C26 C27 C28 145.3(4) . .
C18 C26 C27 C28 -33.0(6) . .
C32 C27 C28 C29 -1.7(7) . .
C26 C27 C28 C29 -178.3(4) . .
C27 C28 C29 C30 -1.5(8) . .
C28 C29 C30 C31 2.9(9) . .
C29 C30 C31 C32 -1.0(10) . .
C30 C31 C32 C27 -2.3(9) . .
C28 C27 C32 C31 3.6(7) . .
C26 C27 C32 C31 -179.7(5) . .
O7 C33 C34 C42 -10.5(6) . .
O9 C33 C34 C42 168.2(3) . .
O7 C33 C34 C35 175.6(4) . .
O9 C33 C34 C35 -5.7(4) . .
C33 C34 C35 N3 3.3(4) . .
C42 C34 C35 N3 -169.4(4) . .
C33 C34 C35 C36 -170.7(4) . .
C42 C34 C35 C36 16.6(7) . .
N3 C35 C36 C41 35.5(5) . .
C34 C35 C36 C41 -150.7(4) . .
N3 C35 C36 C37 -141.0(4) . .
C34 C35 C36 C37 32.8(6) . .
C41 C36 C37 C38 1.1(6) . .
C35 C36 C37 C38 177.6(4) . .
C36 C37 C38 C39 -1.0(7) . .
C37 C38 C39 C40 0.9(7) . .
C38 C39 C40 C41 -0.9(7) . .
C39 C40 C41 C36 1.0(6) . .
C37 C36 C41 C40 -1.0(6) . .
C35 C36 C41 C40 -177.6(4) . .
C33 C34 C42 O8 17.4(5) . .
C35 C34 C42 O8 -170.8(4) . .
C33 C34 C42 C43 -159.9(3) . .
C35 C34 C42 C43 11.9(6) . .
O8 C42 C43 C48 40.4(5) . .
C34 C42 C43 C48 -142.3(4) . .
O8 C42 C43 C44 -134.3(4) . .
C34 C42 C43 C44 43.0(5) . .
C48 C43 C44 C45 0.2(6) . .
C42 C43 C44 C45 174.9(4) . .
C43 C44 C45 C46 1.8(7) . .
C44 C45 C46 C47 -1.1(7) . .
C45 C46 C47 C48 -1.6(7) . .
C44 C43 C48 C47 -3.0(6) . .
C42 C43 C48 C47 -177.8(3) . .
C46 C47 C48 C43 3.7(6) . .
C54 C49 C50 C51 1.0(7) . .
P1 C49 C50 C51 179.8(4) . .
C49 C50 C51 C52 -1.7(9) . .
C50 C51 C52 C53 1.1(12) . .
C51 C52 C53 C54 0.2(13) . .
C52 C53 C54 C49 -0.9(10) . .
C50 C49 C54 C53 0.3(8) . .
P1 C49 C54 C53 -178.5(5) . .
C60 C55 C56 C57 -2.2(6) . .
P1 C55 C56 C57 174.0(3) . .
C55 C56 C57 C58 1.2(7) . .
C56 C57 C58 C59 1.1(7) . .
C57 C58 C59 C60 -2.3(8) . .
C58 C59 C60 C55 1.3(7) . .
C56 C55 C60 C59 1.0(7) . .
P1 C55 C60 C59 -175.0(4) . .
C66 C61 C62 C63 -0.1(6) . .
P1 C61 C62 C63 176.0(3) . .
C61 C62 C63 C64 -1.7(6) . .
C62 C63 C64 C65 2.0(6) . .
C63 C64 C65 C66 -0.5(6) . .
C64 C65 C66 O10 -177.0(3) . .
C64 C65 C66 C61 -1.4(6) . .
C62 C61 C66 C65 1.7(6) . .
P1 C61 C66 C65 -174.5(3) . .
C62 C61 C66 O10 177.3(3) . .
P1 C61 C66 O10 1.1(5) . .
O10 C67 C68 C69 -174.6(3) . .
C72 C67 C68 C69 1.7(5) . .
C67 C68 C69 C70 -0.9(5) . .
C68 C69 C70 C71 -0.8(5) . .
C69 C70 C71 C72 1.6(5) . .
O10 C67 C72 C71 175.6(3) . .
C68 C67 C72 C71 -0.9(5) . .
O10 C67 C72 P2 -5.1(4) . .
C68 C67 C72 P2 178.4(3) . .
C70 C71 C72 C67 -0.8(5) . .
C70 C71 C72 P2 179.9(3) . .
C78 C73 C74 C75 0.0(6) . .
P2 C73 C74 C75 -178.5(3) . .
C73 C74 C75 C76 0.6(7) . .
C74 C75 C76 C77 -1.1(7) . .
C75 C76 C77 C78 0.8(7) . .
C76 C77 C78 C73 -0.1(7) . .
C74 C73 C78 C77 -0.3(6) . .
P2 C73 C78 C77 178.4(3) . .
C84 C79 C80 C81 -0.9(6) . .
P2 C79 C80 C81 -176.3(3) 2_656 .
C79 C80 C81 C82 0.5(6) . .
C80 C81 C82 C83 -0.2(6) . .
C81 C82 C83 C84 0.3(7) . .
C82 C83 C84 C79 -0.7(6) . .
C80 C79 C84 C83 1.0(6) . .
P2 C79 C84 C83 176.7(3) 2_656 .
C2 C3 N1 O3 -0.4(4) . .
C4 C3 N1 O3 176.7(3) . .
C18 C19 N2 O6 -0.5(4) . .
C20 C19 N2 O6 -175.3(3) . .
C34 C35 N3 O9 0.3(4) . .
C36 C35 N3 O9 175.3(3) . .
O3 C1 O1 Eu1 -174.6(2) . .
C2 C1 O1 Eu1 7.1(6) . .
C2 C10 O2 Eu1 -14.5(6) . .
C11 C10 O2 Eu1 165.8(2) . .
O1 C1 O3 N1 -176.5(3) . .
C2 C1 O3 N1 2.2(4) . .
C3 N1 O3 C1 -1.1(4) . .
O6 C17 O4 Eu1 -165.2(2) . .
C18 C17 O4 Eu1 18.0(6) . .
C18 C26 O5 Eu1 11.4(6) . .
C27 C26 O5 Eu1 -166.9(3) . .
O4 C17 O6 N2 178.8(3) . .
C18 C17 O6 N2 -3.7(4) . .
C19 N2 O6 C17 2.6(4) . .
O9 C33 O7 Eu1 167.7(2) . .
C34 C33 O7 Eu1 -13.7(6) . .
C34 C42 O8 Eu1 0.4(5) . .
C43 C42 O8 Eu1 177.7(2) . .
O7 C33 O9 N3 -175.0(3) . .
C34 C33 O9 N3 6.1(4) . .
C35 N3 O9 C33 -3.9(4) . .
C72 C67 O10 C66 148.5(3) . .
C68 C67 O10 C66 -35.0(5) . .
C65 C66 O10 C67 -62.1(5) . .
C61 C66 O10 C67 122.2(4) . .
Eu1 O12 P1 C49 -159.8(6) . .
Eu1 O12 P1 C55 83.9(7) . .
Eu1 O12 P1 C61 -42.3(7) . .
C54 C49 P1 O12 -156.4(4) . .
C50 C49 P1 O12 24.8(4) . .
C54 C49 P1 C55 -36.0(4) . .
C50 C49 P1 C55 145.2(4) . .
C54 C49 P1 C61 80.8(4) . .
C50 C49 P1 C61 -98.1(4) . .
C56 C55 P1 O12 35.6(4) . .
C60 C55 P1 O12 -148.3(4) . .
C56 C55 P1 C49 -83.4(4) . .
C60 C55 P1 C49 92.7(4) . .
C56 C55 P1 C61 163.6(3) . .
C60 C55 P1 C61 -20.3(4) . .
C62 C61 P1 O12 -133.0(3) . .
C66 C61 P1 O12 43.0(4) . .
C62 C61 P1 C49 -12.9(4) . .
C66 C61 P1 C49 163.1(3) . .
C62 C61 P1 C55 100.2(4) . .
C66 C61 P1 C55 -83.9(4) . .
Eu1 O11 P2 C73 94.9(6) . .
Eu1 O11 P2 C79 -146.5(6) . 2_656
Eu1 O11 P2 C72 -26.5(7) . .
C78 C73 P2 O11 39.7(4) . .
C74 C73 P2 O11 -141.7(3) . .
C78 C73 P2 C79 -79.9(3) . 2_656
C74 C73 P2 C79 98.7(3) . 2_656
C78 C73 P2 C72 164.9(3) . .
C74 C73 P2 C72 -16.5(4) . .
C67 C72 P2 O11 49.9(3) . .
C71 C72 P2 O11 -130.8(3) . .
C67 C72 P2 C73 -73.7(3) . .
C71 C72 P2 C73 105.6(3) . .
C67 C72 P2 C79 171.0(3) . 2_656
C71 C72 P2 C79 -9.7(3) . 2_656
P1 O12 Eu1 O11 2.1(7) . .
P1 O12 Eu1 O5 149.9(7) . .
P1 O12 Eu1 O1 -105.7(7) . .
P1 O12 Eu1 O2 -64.1(7) . .
P1 O12 Eu1 O8 75.6(7) . .
P1 O12 Eu1 O7 86.9(7) . .
P1 O12 Eu1 O4 -139.6(7) . .
P2 O11 Eu1 O12 -5.3(6) . .
P2 O11 Eu1 O5 -118.2(6) . .
P2 O11 Eu1 O1 138.1(6) . .
P2 O11 Eu1 O2 65.0(6) . .
P2 O11 Eu1 O8 -72.0(6) . .
P2 O11 Eu1 O7 -145.6(6) . .
P2 O11 Eu1 O4 80.3(6) . .
C26 O5 Eu1 O12 79.2(4) . .
C26 O5 Eu1 O11 -163.3(4) . .
C26 O5 Eu1 O1 -62.9(4) . .
C26 O5 Eu1 O2 11.6(5) . .
C26 O5 Eu1 O8 149.3(4) . .
C26 O5 Eu1 O7 -135.8(4) . .
C26 O5 Eu1 O4 5.1(4) . .
C1 O1 Eu1 O12 33.6(4) . .
C1 O1 Eu1 O11 -79.9(3) . .
C1 O1 Eu1 O5 134.8(3) . .
C1 O1 Eu1 O2 -8.8(3) . .
C1 O1 Eu1 O8 -148.7(3) . .
C1 O1 Eu1 O7 -154.4(3) . .
C1 O1 Eu1 O4 68.0(3) . .
C10 O2 Eu1 O12 -140.3(4) . .
C10 O2 Eu1 O11 108.2(4) . .
C10 O2 Eu1 O5 -68.7(4) . .
C10 O2 Eu1 O1 14.1(4) . .
C10 O2 Eu1 O8 168.1(3) . .
C10 O2 Eu1 O7 64.6(4) . .
C10 O2 Eu1 O4 -62.3(4) . .
C42 O8 Eu1 O12 158.1(4) . .
C42 O8 Eu1 O11 -91.4(3) . .
C42 O8 Eu1 O5 62.9(3) . .
C42 O8 Eu1 O1 -20.4(4) . .
C42 O8 Eu1 O2 -147.8(3) . .
C42 O8 Eu1 O7 -14.5(3) . .
C42 O8 Eu1 O4 110.4(3) . .
C33 O7 Eu1 O12 7.9(3) . .
C33 O7 Eu1 O11 103.8(3) . .
C33 O7 Eu1 O5 -60.1(3) . .
C33 O7 Eu1 O1 -163.9(3) . .
C33 O7 Eu1 O2 146.4(3) . .
C33 O7 Eu1 O8 19.2(3) . .
C33 O7 Eu1 O4 -109.3(3) . .
C17 O4 Eu1 O12 -113.3(3) . .
C17 O4 Eu1 O11 150.6(3) . .
C17 O4 Eu1 O5 -18.2(3) . .
C17 O4 Eu1 O1 88.1(3) . .
C17 O4 Eu1 O2 165.8(3) . .
C17 O4 Eu1 O8 -67.0(3) . .
C17 O4 Eu1 O7 31.9(3) . .
