#------------------------------------------------------------------------------
#$Date: 2016-02-16 22:30:59 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176467 $
#$URL: svn://www.crystallography.net/cod/cif/4/51/03/4510328.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4510328
loop_
_publ_author_name
'Xu, Bing'
'Xie, Juan'
'Hu, Huai-Ming'
'Yang, Xiao-Le'
'Dong, Fa-Xin'
'Yang, Meng-Lin'
'Xue, Gang-Lin'
_publ_section_title
;
 Synthesis, Crystal Structure, and Luminescence of Zn/Cd Coordination
 Polymers with a New Fuctionalized Terpyridyl Carboxylate Ligand
;
_journal_issue                   4
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              1629
_journal_paper_doi               10.1021/cg4016977
_journal_volume                  14
_journal_year                    2014
_chemical_formula_moiety         '2(C30 H19 N3 O7 Zn2), 2(O0.50)'
_chemical_formula_sum            'C30 H19 N3 O7.5 Zn2'
_chemical_formula_weight         672.22
_chemical_name_systematic
;

 ?

;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 112.564(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   23.798(8)
_cell_length_b                   19.705(8)
_cell_length_c                   13.445(5)
_cell_measurement_reflns_used    3613
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      24.64
_cell_measurement_theta_min      2.40
_cell_volume                     5822(4)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 512
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0393
_diffrn_reflns_av_sigmaI/netI    0.0440
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            14522
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         2.41
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.701
_exptl_absorpt_correction_T_max  0.820
_exptl_absorpt_correction_T_min  0.695
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.534
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2720
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.682
_refine_diff_density_min         -0.327
_refine_diff_density_rms         0.071
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     391
_refine_ls_number_reflns         5160
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.051
_refine_ls_R_factor_all          0.0537
_refine_ls_R_factor_gt           0.0402
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0611P)²+1.4691P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1049
_refine_ls_wR_factor_ref         0.1118
_reflns_number_gt                4053
_reflns_number_total             5160
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg4016977_si_005.cif
_cod_data_source_block           1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/usr/data/users/saulius/automatic-downloads/current/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 
;
_cod_original_cell_volume        5822(3)
_cod_original_sg_symbol_H-M      C2/c
_cod_original_formula_sum        'C30 H19 N3 O7.50 Zn2'
_cod_database_code               4510328
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Zn1 Zn 0.348665(16) 0.34316(2) -0.24999(3) 0.03770(14) Uani 1 1 d .
Zn2 Zn 0.407223(17) 0.18925(2) -0.19783(3) 0.04171(15) Uani 1 1 d .
N1 N 0.57763(12) 0.59356(14) 0.1825(2) 0.0408(7) Uani 1 1 d .
N2 N 0.36211(12) 0.52050(13) -0.0009(2) 0.0363(6) Uani 1 1 d .
N3 N 0.16071(12) 0.62376(15) -0.2159(2) 0.0430(7) Uani 1 1 d .
O1 O 0.34152(11) 0.30931(12) -0.11545(19) 0.0468(6) Uani 1 1 d .
O2 O 0.38723(13) 0.20952(14) -0.0711(2) 0.0614(8) Uani 1 1 d .
O3 O 0.47488(10) 0.12818(14) -0.1422(2) 0.0572(7) Uani 1 1 d .
O4 O 0.53674(13) 0.21658(15) -0.0909(3) 0.0731(9) Uani 1 1 d .
O5 O 0.75655(14) 0.1738(2) 0.1393(3) 0.0773(10) Uani 1 1 d .
O6 O 0.78637(14) 0.0720(2) 0.1895(3) 0.0995(13) Uani 1 1 d .
C1 C 0.57785(14) 0.52593(18) 0.1862(3) 0.0380(8) Uani 1 1 d .
H1 H 0.6150 0.5036 0.2176 0.046 Uiso 1 1 calc R
C2 C 0.52553(14) 0.48773(16) 0.1457(3) 0.0354(8) Uani 1 1 d .
H2 H 0.5278 0.4406 0.1499 0.042 Uiso 1 1 calc R
C3 C 0.46958(14) 0.51940(16) 0.0985(3) 0.0348(7) Uani 1 1 d .
C4 C 0.46997(16) 0.58947(17) 0.0924(3) 0.0469(9) Uani 1 1 d .
H4 H 0.4336 0.6129 0.0595 0.056 Uiso 1 1 calc R
C5 C 0.52367(16) 0.62447(19) 0.1347(3) 0.0520(10) Uani 1 1 d .
H5 H 0.5227 0.6716 0.1300 0.062 Uiso 1 1 calc R
C6 C 0.41016(14) 0.48317(16) 0.0591(2) 0.0329(7) Uani 1 1 d .
C7 C 0.40418(14) 0.41682(16) 0.0859(3) 0.0351(8) Uani 1 1 d .
H7 H 0.4385 0.3911 0.1239 0.042 Uiso 1 1 calc R
C8 C 0.34688(14) 0.38868(16) 0.0560(3) 0.0352(7) Uani 1 1 d .
C9 C 0.29753(15) 0.42789(16) -0.0042(3) 0.0384(8) Uani 1 1 d .
H9 H 0.2583 0.4106 -0.0254 0.046 Uiso 1 1 calc R
C10 C 0.30680(14) 0.49299(16) -0.0328(3) 0.0349(7) Uani 1 1 d .
C11 C 0.15216(15) 0.55674(18) -0.2131(3) 0.0447(9) Uani 1 1 d .
H11 H 0.1136 0.5391 -0.2516 0.054 Uiso 1 1 calc R
C12 C 0.19781(16) 0.51343(18) -0.1560(3) 0.0456(9) Uani 1 1 d .
H12 H 0.1899 0.4672 -0.1559 0.055 Uiso 1 1 calc R
C13 C 0.25574(14) 0.53762(16) -0.0984(3) 0.0351(7) Uani 1 1 d .
C14 C 0.26447(15) 0.60682(18) -0.1007(3) 0.0511(10) Uani 1 1 d .
H14 H 0.3027 0.6254 -0.0628 0.061 Uiso 1 1 calc R
C15 C 0.21664(16) 0.64827(19) -0.1588(4) 0.0547(11) Uani 1 1 d .
H15 H 0.2232 0.6948 -0.1587 0.066 Uiso 1 1 calc R
C16 C 0.33859(14) 0.31950(16) 0.0942(3) 0.0364(8) Uani 1 1 d .
C17 C 0.32396(19) 0.3158(2) 0.1845(3) 0.0574(11) Uani 1 1 d .
H17 H 0.3177 0.3556 0.2158 0.069 Uiso 1 1 calc R
C18 C 0.3185(2) 0.2543(2) 0.2286(4) 0.0684(12) Uani 1 1 d .
H18 H 0.3075 0.2525 0.2878 0.082 Uiso 1 1 calc R
C19 C 0.3297(2) 0.1957(2) 0.1839(4) 0.0707(13) Uani 1 1 d .
H19 H 0.3275 0.1540 0.2146 0.085 Uiso 1 1 calc R
C20 C 0.34380(19) 0.19842(19) 0.0947(3) 0.0556(10) Uani 1 1 d .
H20 H 0.3510 0.1583 0.0652 0.067 Uiso 1 1 calc R
C21 C 0.34770(14) 0.25983(16) 0.0472(3) 0.0376(8) Uani 1 1 d .
C22 C 0.35989(14) 0.26017(17) -0.0546(3) 0.0383(8) Uani 1 1 d .
C23 C 0.52691(17) 0.1550(2) -0.0932(3) 0.0499(10) Uani 1 1 d .
C24 C 0.57737(15) 0.10576(19) -0.0358(3) 0.0441(9) Uani 1 1 d .
C25 C 0.56611(16) 0.0367(2) -0.0372(3) 0.0514(10) Uani 1 1 d .
H25 H 0.5271 0.0203 -0.0755 0.062 Uiso 1 1 calc R
C26 C 0.61211(18) -0.0077(2) 0.0177(3) 0.0594(11) Uani 1 1 d .
H26 H 0.6042 -0.0539 0.0172 0.071 Uiso 1 1 calc R
C27 C 0.67016(17) 0.0168(2) 0.0737(3) 0.0587(11) Uani 1 1 d .
H27 H 0.7013 -0.0134 0.1105 0.070 Uiso 1 1 calc R
C28 C 0.68264(16) 0.0852(2) 0.0757(3) 0.0480(9) Uani 1 1 d .
C29 C 0.63629(14) 0.1298(2) 0.0219(3) 0.0463(9) Uani 1 1 d .
H29 H 0.6442 0.1761 0.0239 0.056 Uiso 1 1 calc R
C30 C 0.74580(17) 0.1124(3) 0.1384(3) 0.0642(13) Uani 1 1 d .
O7 O 0.38929(11) 0.26761(13) -0.2874(2) 0.0476(6) Uani 1 1 d D
H7A H 0.4108(15) 0.268(2) -0.318(3) 0.057 Uiso 1 1 d D
O8 O 0.5189(5) 0.2917(6) 0.1482(13) 0.297(10) Uani 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O7 Zn1 O1 101.67(11) . .
O7 Zn1 N1 98.85(11) . 5_665
O1 Zn1 N1 99.06(11) . 5_665
O7 Zn1 O5 100.23(13) . 8_455
O1 Zn1 O5 99.02(11) . 8_455
N1 Zn1 O5 150.38(13) 5_665 8_455
O7 Zn1 O6 145.85(13) . 8_455
O1 Zn1 O6 108.26(12) . 8_455
N1 Zn1 O6 92.43(13) 5_665 8_455
O5 Zn1 O6 59.58(13) 8_455 8_455
O7 Zn1 C30 125.83(15) . 8_455
O1 Zn1 C30 104.95(11) . 8_455
N1 Zn1 C30 121.85(16) 5_665 8_455
O5 Zn1 C30 29.79(14) 8_455 8_455
O6 Zn1 C30 29.81(15) 8_455 8_455
O7 Zn2 O3 135.00(11) . .
O7 Zn2 O2 108.16(11) . .
O3 Zn2 O2 103.53(12) . .
O7 Zn2 N3 102.50(12) . 4_544
O3 Zn2 N3 100.83(12) . 4_544
O2 Zn2 N3 102.53(12) . 4_544
C1 N1 C5 117.5(3) . .
C1 N1 Zn1 126.8(2) . 5_665
C5 N1 Zn1 115.7(2) . 5_665
C10 N2 C6 118.7(3) . .
C11 N3 C15 117.8(3) . .
C11 N3 Zn2 122.8(2) . 4_554
C15 N3 Zn2 119.4(2) . 4_554
C22 O1 Zn1 137.0(2) . .
C22 O2 Zn2 128.7(2) . .
C23 O3 Zn2 116.5(3) . .
C30 O5 Zn1 90.4(3) . 8_556
C30 O6 Zn1 89.3(3) . 8_556
N1 C1 C2 122.8(3) . .
N1 C1 H1 118.6 . .
C2 C1 H1 118.6 . .
C1 C2 C3 120.0(3) . .
C1 C2 H2 120.0 . .
C3 C2 H2 120.0 . .
C4 C3 C2 116.7(3) . .
C4 C3 C6 119.0(3) . .
C2 C3 C6 124.2(3) . .
C5 C4 C3 120.3(3) . .
C5 C4 H4 119.8 . .
C3 C4 H4 119.8 . .
N1 C5 C4 122.6(3) . .
N1 C5 H5 118.7 . .
C4 C5 H5 118.7 . .
N2 C6 C7 121.9(3) . .
N2 C6 C3 115.2(3) . .
C7 C6 C3 122.8(3) . .
C6 C7 C8 119.6(3) . .
C6 C7 H7 120.2 . .
C8 C7 H7 120.2 . .
C9 C8 C7 118.0(3) . .
C9 C8 C16 121.1(3) . .
C7 C8 C16 120.8(3) . .
C8 C9 C10 119.5(3) . .
C8 C9 H9 120.2 . .
C10 C9 H9 120.2 . .
N2 C10 C9 122.1(3) . .
N2 C10 C13 115.6(3) . .
C9 C10 C13 122.3(3) . .
N3 C11 C12 122.4(3) . .
N3 C11 H11 118.8 . .
C12 C11 H11 118.8 . .
C11 C12 C13 120.5(3) . .
C11 C12 H12 119.7 . .
C13 C12 H12 119.7 . .
C14 C13 C12 117.0(3) . .
C14 C13 C10 120.1(3) . .
C12 C13 C10 122.8(3) . .
C15 C14 C13 120.0(3) . .
C15 C14 H14 120.0 . .
C13 C14 H14 120.0 . .
N3 C15 C14 122.2(3) . .
N3 C15 H15 118.9 . .
C14 C15 H15 118.9 . .
C17 C16 C21 119.2(3) . .
C17 C16 C8 117.3(3) . .
C21 C16 C8 123.4(3) . .
C18 C17 C16 121.3(4) . .
C18 C17 H17 119.3 . .
C16 C17 H17 119.3 . .
C19 C18 C17 119.1(4) . .
C19 C18 H18 120.5 . .
C17 C18 H18 120.5 . .
C20 C19 C18 120.4(4) . .
C20 C19 H19 119.8 . .
C18 C19 H19 119.8 . .
C19 C20 C21 121.4(4) . .
C19 C20 H20 119.3 . .
C21 C20 H20 119.3 . .
C20 C21 C16 118.5(3) . .
C20 C21 C22 119.6(3) . .
C16 C21 C22 121.9(3) . .
O1 C22 O2 125.5(3) . .
O1 C22 C21 117.6(3) . .
O2 C22 C21 116.8(3) . .
O4 C23 O3 123.9(4) . .
O4 C23 C24 120.9(3) . .
O3 C23 C24 115.1(3) . .
C25 C24 C29 119.2(3) . .
C25 C24 C23 120.9(3) . .
C29 C24 C23 119.9(3) . .
C26 C25 C24 120.5(4) . .
C26 C25 H25 119.7 . .
C24 C25 H25 119.7 . .
C25 C26 C27 119.6(4) . .
C25 C26 H26 120.2 . .
C27 C26 H26 120.2 . .
C28 C27 C26 121.0(4) . .
C28 C27 H27 119.5 . .
C26 C27 H27 119.5 . .
C29 C28 C27 119.3(3) . .
C29 C28 C30 119.4(4) . .
C27 C28 C30 121.2(4) . .
C28 C29 C24 120.4(4) . .
C28 C29 H29 119.8 . .
C24 C29 H29 119.8 . .
O5 C30 O6 120.7(4) . .
O5 C30 C28 120.7(4) . .
O6 C30 C28 118.6(5) . .
O5 C30 Zn1 59.8(2) . 8_556
O6 C30 Zn1 60.9(2) . 8_556
C28 C30 Zn1 177.1(3) . 8_556
Zn2 O7 Zn1 118.10(13) . .
Zn2 O7 H7A 108(3) . .
Zn1 O7 H7A 129(3) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O7 1.943(3) .
Zn1 O1 1.995(2) .
Zn1 N1 2.058(3) 5_665
Zn1 O5 2.152(3) 8_455
Zn1 O6 2.175(4) 8_455
Zn1 C30 2.488(4) 8_455
Zn2 O7 1.903(3) .
Zn2 O3 1.917(3) .
Zn2 O2 1.977(3) .
Zn2 N3 2.046(3) 4_544
N1 C1 1.334(4) .
N1 C5 1.341(4) .
N1 Zn1 2.058(3) 5_665
N2 C10 1.333(4) .
N2 C6 1.339(4) .
N3 C11 1.339(4) .
N3 C15 1.345(4) .
N3 Zn2 2.046(3) 4_554
O1 C22 1.235(4) .
O2 C22 1.257(4) .
O3 C23 1.273(4) .
O4 C23 1.235(5) .
O5 C30 1.236(6) .
O5 Zn1 2.152(3) 8_556
O6 C30 1.237(6) .
O6 Zn1 2.175(4) 8_556
C1 C2 1.376(4) .
C1 H1 0.9300 .
C2 C3 1.384(4) .
C2 H2 0.9300 .
C3 C4 1.383(4) .
C3 C6 1.488(4) .
C4 C5 1.369(5) .
C4 H4 0.9300 .
C5 H5 0.9300 .
C6 C7 1.378(4) .
C7 C8 1.381(4) .
C7 H7 0.9300 .
C8 C9 1.379(4) .
C8 C16 1.496(4) .
C9 C10 1.381(5) .
C9 H9 0.9300 .
C10 C13 1.485(4) .
C11 C12 1.363(5) .
C11 H11 0.9300 .
C12 C13 1.382(5) .
C12 H12 0.9300 .
C13 C14 1.381(5) .
C14 C15 1.375(5) .
C14 H14 0.9300 .
C15 H15 0.9300 .
C16 C17 1.387(5) .
C16 C21 1.391(5) .
C17 C18 1.377(5) .
C17 H17 0.9300 .
C18 C19 1.373(6) .
C18 H18 0.9300 .
C19 C20 1.365(5) .
C19 H19 0.9300 .
C20 C21 1.389(5) .
C20 H20 0.9300 .
C21 C22 1.503(5) .
C23 C24 1.505(5) .
C24 C25 1.385(5) .
C24 C29 1.399(4) .
C25 C26 1.374(5) .
C25 H25 0.9300 .
C26 C27 1.382(5) .
C26 H26 0.9300 .
C27 C28 1.380(6) .
C27 H27 0.9300 .
C28 C29 1.378(5) .
C28 C30 1.511(5) .
C29 H29 0.9300 .
C30 Zn1 2.488(4) 8_556
O7 H7A 0.772(18) .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O7 Zn1 O1 C22 7.4(4) . .
N1 Zn1 O1 C22 -93.6(3) 5_665 .
O5 Zn1 O1 C22 109.9(3) 8_455 .
O6 Zn1 O1 C22 170.8(3) 8_455 .
C30 Zn1 O1 C22 139.8(3) 8_455 .
O7 Zn2 O2 C22 9.1(3) . .
O3 Zn2 O2 C22 156.7(3) . .
N3 Zn2 O2 C22 -98.7(3) 4_544 .
O7 Zn2 O3 C23 52.3(3) . .
O2 Zn2 O3 C23 -81.7(3) . .
N3 Zn2 O3 C23 172.5(3) 4_544 .
C5 N1 C1 C2 -1.5(5) . .
Zn1 N1 C1 C2 175.0(2) 5_665 .
N1 C1 C2 C3 0.0(5) . .
C1 C2 C3 C4 1.7(5) . .
C1 C2 C3 C6 -175.6(3) . .
C2 C3 C4 C5 -1.9(5) . .
C6 C3 C4 C5 175.6(3) . .
C1 N1 C5 C4 1.3(5) . .
Zn1 N1 C5 C4 -175.6(3) 5_665 .
C3 C4 C5 N1 0.4(6) . .
C10 N2 C6 C7 2.0(5) . .
C10 N2 C6 C3 -175.3(3) . .
C4 C3 C6 N2 14.2(4) . .
C2 C3 C6 N2 -168.6(3) . .
C4 C3 C6 C7 -163.1(3) . .
C2 C3 C6 C7 14.2(5) . .
N2 C6 C7 C8 -4.0(5) . .
C3 C6 C7 C8 173.1(3) . .
C6 C7 C8 C9 2.7(5) . .
C6 C7 C8 C16 -173.2(3) . .
C7 C8 C9 C10 0.4(5) . .
C16 C8 C9 C10 176.3(3) . .
C6 N2 C10 C9 1.2(5) . .
C6 N2 C10 C13 179.6(3) . .
C8 C9 C10 N2 -2.4(5) . .
C8 C9 C10 C13 179.4(3) . .
C15 N3 C11 C12 -0.6(5) . .
Zn2 N3 C11 C12 179.5(3) 4_554 .
N3 C11 C12 C13 -0.4(6) . .
C11 C12 C13 C14 0.8(5) . .
C11 C12 C13 C10 178.5(3) . .
N2 C10 C13 C14 -16.1(5) . .
C9 C10 C13 C14 162.3(3) . .
N2 C10 C13 C12 166.2(3) . .
C9 C10 C13 C12 -15.5(5) . .
C12 C13 C14 C15 -0.2(5) . .
C10 C13 C14 C15 -178.0(3) . .
C11 N3 C15 C14 1.2(6) . .
Zn2 N3 C15 C14 -178.9(3) 4_554 .
C13 C14 C15 N3 -0.9(6) . .
C9 C8 C16 C17 -79.6(4) . .
C7 C8 C16 C17 96.2(4) . .
C9 C8 C16 C21 103.7(4) . .
C7 C8 C16 C21 -80.5(4) . .
C21 C16 C17 C18 0.3(6) . .
C8 C16 C17 C18 -176.6(4) . .
C16 C17 C18 C19 1.9(7) . .
C17 C18 C19 C20 -2.3(8) . .
C18 C19 C20 C21 0.4(7) . .
C19 C20 C21 C16 1.9(6) . .
C19 C20 C21 C22 -176.5(4) . .
C17 C16 C21 C20 -2.1(5) . .
C8 C16 C21 C20 174.6(3) . .
C17 C16 C21 C22 176.2(3) . .
C8 C16 C21 C22 -7.1(5) . .
Zn1 O1 C22 O2 -7.6(6) . .
Zn1 O1 C22 C21 173.6(2) . .
Zn2 O2 C22 O1 -2.5(5) . .
Zn2 O2 C22 C21 176.3(2) . .
C20 C21 C22 O1 153.7(3) . .
C16 C21 C22 O1 -24.6(5) . .
C20 C21 C22 O2 -25.2(5) . .
C16 C21 C22 O2 156.5(3) . .
Zn2 O3 C23 O4 -8.7(5) . .
Zn2 O3 C23 C24 170.9(2) . .
O4 C23 C24 C25 179.1(4) . .
O3 C23 C24 C25 -0.5(5) . .
O4 C23 C24 C29 0.5(6) . .
O3 C23 C24 C29 -179.1(3) . .
C29 C24 C25 C26 0.3(6) . .
C23 C24 C25 C26 -178.3(3) . .
C24 C25 C26 C27 -0.7(6) . .
C25 C26 C27 C28 0.3(6) . .
C26 C27 C28 C29 0.6(6) . .
C26 C27 C28 C30 178.9(3) . .
C27 C28 C29 C24 -1.0(5) . .
C30 C28 C29 C24 -179.4(3) . .
C25 C24 C29 C28 0.6(5) . .
C23 C24 C29 C28 179.3(3) . .
Zn1 O5 C30 O6 -2.7(4) 8_556 .
Zn1 O5 C30 C28 176.7(3) 8_556 .
Zn1 O6 C30 O5 2.7(4) 8_556 .
Zn1 O6 C30 C28 -176.7(3) 8_556 .
C29 C28 C30 O5 -2.0(6) . .
C27 C28 C30 O5 179.6(4) . .
C29 C28 C30 O6 177.4(4) . .
C27 C28 C30 O6 -0.9(6) . .
C29 C28 C30 Zn1 98(8) . 8_556
C27 C28 C30 Zn1 -81(8) . 8_556
O3 Zn2 O7 Zn1 -139.38(14) . .
O2 Zn2 O7 Zn1 -6.83(18) . .
N3 Zn2 O7 Zn1 101.03(15) 4_544 .
O1 Zn1 O7 Zn2 1.61(16) . .
N1 Zn1 O7 Zn2 102.86(15) 5_665 .
O5 Zn1 O7 Zn2 -99.91(16) 8_455 .
O6 Zn1 O7 Zn2 -149.34(18) 8_455 .
C30 Zn1 O7 Zn2 -116.68(17) 8_455 .
