#------------------------------------------------------------------------------
#$Date: 2016-03-24 14:07:12 +0200 (Thu, 24 Mar 2016) $
#$Revision: 179652 $
#$URL: svn://www.crystallography.net/cod/cif/4/51/05/4510590.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4510590
loop_
_publ_author_name
'Li, Meng-Ting'
'Sha, Jing-Quan'
'Zong, Xi-Ming'
'Sun, Jing-Wen'
'Yan, Peng-Fei'
'Li, Liang'
'Yang, Xiao-Ning'
_publ_section_title
;
 Assembly of Polyoxometalate-Based Hybrids with Different Helical Channels
 upon Subtle Ligand Variation
;
_journal_issue                   6
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              2794
_journal_paper_doi               10.1021/cg500045q
_journal_volume                  14
_journal_year                    2014
_chemical_formula_moiety         'C36 H26 Ag6 Co N28 O40 W12, 2(O)'
_chemical_formula_sum            'C36 H26 Ag6 Co N28 O42 W12'
_chemical_formula_weight         4435.08
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                105.033(5)
_cell_angle_beta                 99.809(5)
_cell_angle_gamma                115.518(5)
_cell_formula_units_Z            1
_cell_length_a                   11.830(5)
_cell_length_b                   12.709(5)
_cell_length_c                   14.789(5)
_cell_measurement_temperature    293(2)
_cell_volume                     1833.6(12)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.979
_diffrn_measured_fraction_theta_max 0.979
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0812
_diffrn_reflns_av_sigmaI/netI    0.1552
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            9953
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.91
_exptl_absorpt_coefficient_mu    20.621
_exptl_absorpt_correction_T_max  0.004
_exptl_absorpt_correction_T_min  0.000
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    4.017
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             1971
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.34
_exptl_crystal_size_min          0.27
_refine_diff_density_max         4.173
_refine_diff_density_min         -3.028
_refine_diff_density_rms         0.491
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     583
_refine_ls_number_reflns         6324
_refine_ls_number_restraints     197
_refine_ls_restrained_S_all      1.026
_refine_ls_R_factor_all          0.1811
_refine_ls_R_factor_gt           0.1022
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1075P)²+195.3812P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2434
_refine_ls_wR_factor_ref         0.2915
_reflns_number_gt                3284
_reflns_number_total             6462
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg500045q_si_002.cif
_cod_data_source_block           2_audit_creation_method_SHELXL-97
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_absorpt_correction_type' value 'Multi-scan' changed to
'multi-scan' according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/ACS/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 4510589--4510591.cif.
;
_cod_database_code               4510590
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.477(4) 0.694(3) 0.521(3) 0.050(11) Uani 1 1 d DU
H1 H 0.3977 0.6843 0.4868 0.060 Uiso 1 1 calc R
C2 C 0.591(3) 0.779(3) 0.512(3) 0.046(10) Uani 1 1 d DU
C3 C 0.704(4) 0.787(3) 0.566(2) 0.056(14) Uani 1 1 d D
H3 H 0.7848 0.8452 0.5638 0.067 Uiso 1 1 calc R
C4 C 0.709(4) 0.718(4) 0.621(3) 0.054(13) Uani 1 1 d DU
H4 H 0.7874 0.7233 0.6528 0.065 Uiso 1 1 calc R
C5 C 0.590(3) 0.639(4) 0.628(3) 0.046(11) Uani 1 1 d DU
H5 H 0.5894 0.5952 0.6699 0.055 Uiso 1 1 calc R
C6 C 0.596(4) 0.865(4) 0.464(3) 0.033(9) Uani 1 1 d U
C7 C 0.539(6) 0.949(5) 0.384(4) 0.061(15) Uani 1 1 d .
C8 C 0.462(4) 0.985(3) 0.331(3) 0.032(9) Uani 1 1 d U
C9 C 0.403(7) 1.083(5) 0.259(4) 0.071(18) Uani 1 1 d .
H9 H 0.4044 1.1450 0.2356 0.086 Uiso 1 1 calc R
C10 C -0.022(5) 0.617(4) 0.372(4) 0.054(12) Uani 1 1 d U
H10 H -0.0581 0.6022 0.3061 0.065 Uiso 1 1 calc R
C11 C 0.003(4) 0.633(4) 0.513(3) 0.035(9) Uani 1 1 d U
C12 C -0.017(5) 0.625(5) 0.608(4) 0.054(12) Uani 1 1 d U
C13 C 0.030(4) 0.671(4) 0.753(3) 0.035(10) Uani 1 1 d .
C14 C 0.103(4) 0.727(4) 0.863(4) 0.044(11) Uani 1 1 d .
C15 C 0.222(5) 0.830(4) 0.905(4) 0.071(17) Uani 1 1 d .
H15 H 0.2564 0.8706 0.8639 0.086 Uiso 1 1 calc R
C16 C 0.242(5) 0.806(4) 1.054(4) 0.052(11) Uani 1 1 d U
H16 H 0.2833 0.8314 1.1212 0.062 Uiso 1 1 calc R
C17 C 0.062(5) 0.659(5) 0.916(4) 0.070(17) Uani 1 1 d .
H17 H -0.0159 0.5817 0.8892 0.083 Uiso 1 1 calc R
C18 C 0.136(4) 0.705(4) 1.011(3) 0.033(9) Uani 1 1 d U
H18 H 0.1060 0.6565 1.0485 0.040 Uiso 1 1 calc R
N1 N -0.091(4) 0.584(4) 0.430(3) 0.055(9) Uani 1 1 d U
N2 N 0.082(3) 0.699(3) 0.695(2) 0.033(8) Uani 1 1 d .
N3 N 0.100(5) 0.672(3) 0.418(4) 0.063(13) Uani 1 1 d .
N4 N 0.513(4) 1.076(3) 0.303(3) 0.043(9) Uani 1 1 d U
N5 N -0.098(4) 0.597(4) 0.720(3) 0.056(11) Uani 1 1 d .
N6 N -0.128(4) 0.564(4) 0.620(3) 0.064(12) Uani 1 1 d .
H6 H -0.2044 0.5133 0.5753 0.077 Uiso 1 1 calc R
N7 N 0.120(3) 0.694(3) 0.517(2) 0.031(7) Uani 1 1 d U
N8 N 0.471(3) 0.622(3) 0.576(2) 0.053(11) Uani 1 1 d D
N9 N 0.297(5) 0.988(4) 0.258(3) 0.052(11) Uani 1 1 d .
H9A H 0.2168 0.9648 0.2266 0.063 Uiso 1 1 calc R
N10 N 0.333(4) 0.931(3) 0.313(3) 0.041(9) Uani 1 1 d U
N11 N 0.494(4) 0.861(4) 0.422(3) 0.052(10) Uani 1 1 d U
N12 N 0.703(4) 0.955(3) 0.469(3) 0.040(8) Uani 1 1 d U
N13 N 0.664(5) 1.006(4) 0.412(3) 0.058(12) Uani 1 1 d .
H13 H 0.7146 1.0670 0.3963 0.069 Uiso 1 1 calc R
N14 N 0.302(5) 0.882(5) 1.005(3) 0.083(15) Uani 1 1 d U
O1 O 0.812(4) 0.671(3) 0.195(3) 0.065(10) Uani 1 1 d U
O2 O 0.978(3) 0.618(3) 0.130(2) 0.060(10) Uani 1 1 d .
O1W O 0.952(5) 1.062(5) 0.580(5) 0.13(2) Uani 1 1 d .
O3 O 0.850(4) 0.713(4) 0.039(3) 0.091(13) Uani 1 1 d U
O4 O 0.765(3) 0.742(3) 0.370(2) 0.053(8) Uani 1 1 d .
O5 O 0.269(4) 0.613(3) 0.234(2) 0.060(9) Uani 1 1 d .
O6 O 0.434(5) 0.734(4) 0.147(4) 0.101(14) Uani 1 1 d U
O7 O 0.304(4) 0.418(3) 0.148(3) 0.078(11) Uani 1 1 d U
O8 O 0.751(4) 0.437(3) 0.115(3) 0.075(11) Uani 1 1 d U
O10 O 0.414(3) 0.295(5) 0.142(3) 0.110(19) Uani 1 1 d .
O11 O 0.637(4) 0.505(3) 0.246(3) 0.086(13) Uani 1 1 d .
O12 O 0.496(4) 0.608(4) 0.248(3) 0.088(12) Uani 1 1 d U
O13 O 0.625(3) 0.956(2) 0.1642(19) 0.033(6) Uani 1 1 d U
O14 O 0.684(4) 0.797(4) 0.207(5) 0.13(2) Uani 1 1 d .
O15 O 0.468(4) 0.760(4) -0.009(3) 0.100(14) Uani 1 1 d U
O16 O 0.715(4) 0.818(4) 0.051(3) 0.095(13) Uani 1 1 d U
O17 O 0.636(4) 0.285(4) 0.207(3) 0.075(11) Uani 1 1 d .
O18 O 0.222(5) 0.535(4) 0.042(4) 0.108(15) Uani 1 1 d U
O19 O 0.839(3) 0.825(4) -0.082(3) 0.073(11) Uani 1 1 d .
O20 O 0.533(5) 0.623(5) 0.127(4) 0.031(12) Uani 0.50 1 d PU
O21 O 0.630(5) 0.527(5) 0.107(4) 0.037(13) Uani 0.50 1 d PU
O22 O 0.332(4) 0.445(4) 0.018(3) 0.019(10) Uani 0.50 1 d PU
O23 O 0.456(4) 0.355(4) 0.023(3) 0.023(11) Uani 0.50 1 d PU
Co1 Co 0.5000 0.5000 0.0000 0.0181(14) Uani 1 2 d S
Ag1 Ag -0.2893(4) 0.4786(4) 0.4124(3) 0.0647(12) Uani 1 1 d .
Ag2 Ag 0.2830(4) 0.8013(4) 0.6685(4) 0.0757(14) Uani 1 1 d .
Ag3 Ag 0.2613(5) 0.7668(4) 0.3724(4) 0.0929(19) Uani 1 1 d .
W1 W 0.67335(19) 0.66030(17) 0.24877(13) 0.0447(5) Uani 1 1 d .
W2 W 0.7341(2) 0.72637(17) -0.05683(15) 0.0551(6) Uani 1 1 d .
W3 W 0.8239(2) 0.58285(18) 0.08584(13) 0.0477(6) Uani 1 1 d .
W4 W 0.5908(2) 0.35209(18) 0.13675(14) 0.0472(6) Uani 1 1 d .
W5 W 0.5881(2) 0.80883(16) 0.10984(18) 0.0609(7) Uani 1 1 d .
W6 W 0.3513(2) 0.58373(19) 0.16172(16) 0.0562(7) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N8 C1 C2 125(4) . .
C1 C2 C3 113(4) . .
C1 C2 C6 124(3) . .
C3 C2 C6 122(4) . .
C4 C3 C2 126(4) . .
C3 C4 C5 116(4) . .
C4 C5 N8 123(4) . .
N11 C6 N12 116(4) . .
N11 C6 C2 121(4) . .
N12 C6 C2 123(4) . .
N11 C6 C7 40(3) . .
N12 C6 C7 76(3) . .
C2 C6 C7 161(4) . .
N13 C7 N11 111(5) . .
N13 C7 C8 123(5) . .
N11 C7 C8 126(5) . .
N13 C7 C6 74(4) . .
N11 C7 C6 37(3) . .
C8 C7 C6 163(5) . .
N4 C8 N10 116(4) . .
N4 C8 C7 122(4) . .
N10 C8 C7 122(4) . .
N9 C9 N4 107(4) . .
N3 C10 N1 111(5) . .
N3 C10 C11 72(3) . .
N1 C10 C11 40(3) . .
N7 C11 N1 119(4) . .
N7 C11 C12 116(4) . .
N1 C11 C12 125(4) . .
N7 C11 C10 79(3) . .
N1 C11 C10 40(2) . .
C12 C11 C10 165(4) . .
N6 C12 N2 113(5) . .
N6 C12 C11 126(5) . .
N2 C12 C11 121(5) . .
N6 C12 C13 77(3) . .
N2 C12 C13 36(2) . .
C11 C12 C13 157(4) . .
N2 C13 N5 118(4) . .
N2 C13 C14 123(4) . .
N5 C13 C14 119(4) . .
N2 C13 C12 42(3) . .
N5 C13 C12 76(3) . .
C14 C13 C12 165(4) . .
C17 C14 C15 117(5) . .
C17 C14 C13 119(4) . .
C15 C14 C13 122(4) . .
C14 C15 N14 126(5) . .
C18 C16 N14 122(5) . .
C14 C17 C18 118(5) . .
C16 C18 C17 126(5) . .
C11 N1 C10 100(4) . .
C11 N1 Ag1 124(3) . .
C10 N1 Ag1 136(3) . .
C13 N2 C12 102(4) . .
C13 N2 Ag2 146(3) . .
C12 N2 Ag2 111(3) . .
C10 N3 N7 109(4) . .
C10 N3 Ag3 129(4) . .
N7 N3 Ag3 119(3) . .
C8 N4 C9 103(4) . .
C8 N4 Ag2 127(3) . 2_676
C9 N4 Ag2 129(4) . 2_676
C13 N5 N6 103(4) . .
C12 N6 N5 104(4) . .
C11 N7 N3 99(3) . .
C11 N7 Ag2 119(3) . .
N3 N7 Ag2 142(3) . .
C1 N8 C5 117(4) . .
C1 N8 Ag1 115(3) . 2_566
C5 N8 Ag1 128(3) . 2_566
C9 N9 N10 110(4) . .
C8 N10 N9 103(4) . .
C8 N10 Ag3 110(3) . .
N9 N10 Ag3 147(3) . .
C6 N11 C7 103(4) . .
C6 N11 Ag3 150(3) . .
C7 N11 Ag3 108(4) . .
C6 N12 N13 104(4) . .
C7 N13 N12 106(4) . .
C16 N14 C15 110(5) . .
W3 O1 W1 136(2) . .
W3 O3 W2 131(2) . .
W6 O5 Ag3 148(2) . .
W6 O6 W5 131(3) . .
W2 O7 W6 140(2) 2_665 .
W4 O8 W3 131(2) . .
W2 O10 W4 131(3) 2_665 .
W1 O11 W4 131(2) . .
W6 O12 W1 134(2) . .
W5 O14 W1 135(3) . .
W5 O15 W4 139(3) . 2_665
W2 O16 W5 140(3) . .
W6 O18 W3 131(3) . 2_665
Co1 O20 W1 120(2) . .
Co1 O20 W6 112(2) . .
W1 O20 W6 109(2) . .
Co1 O20 W5 108(2) . .
W1 O20 W5 106(2) . .
W6 O20 W5 100.1(19) . .
Co1 O21 W1 119(3) . .
Co1 O21 W3 114(3) . .
W1 O21 W3 104(2) . .
Co1 O21 W4 113(3) . .
W1 O21 W4 104(2) . .
W3 O21 W4 100(2) . .
Co1 O22 W3 121(2) . 2_665
Co1 O22 W2 112.4(19) . 2_665
W3 O22 W2 107.5(19) 2_665 2_665
Co1 O22 W6 109(2) . .
W3 O22 W6 105.6(18) 2_665 .
W2 O22 W6 98.9(17) 2_665 .
Co1 O23 W4 120(2) . .
Co1 O23 W2 115(2) . 2_665
W4 O23 W2 103(2) . 2_665
Co1 O23 W5 114(2) . 2_665
W4 O23 W5 102.8(18) . 2_665
W2 O23 W5 99.8(18) 2_665 2_665
O23 Co1 O23 180(3) 2_665 .
O23 Co1 O21 70(2) 2_665 2_665
O23 Co1 O21 110(2) . 2_665
O23 Co1 O21 110(2) 2_665 .
O23 Co1 O21 70(2) . .
O21 Co1 O21 180(4) 2_665 .
O23 Co1 O22 73.1(18) 2_665 2_665
O23 Co1 O22 106.9(18) . 2_665
O21 Co1 O22 113(2) 2_665 2_665
O21 Co1 O22 67(2) . 2_665
O23 Co1 O22 106.9(18) 2_665 .
O23 Co1 O22 73.1(18) . .
O21 Co1 O22 67(2) 2_665 .
O21 Co1 O22 113(2) . .
O22 Co1 O22 180.000(2) 2_665 .
O23 Co1 O20 104(2) 2_665 2_665
O23 Co1 O20 76(2) . 2_665
O21 Co1 O20 63(2) 2_665 2_665
O21 Co1 O20 117(2) . 2_665
O22 Co1 O20 75(2) 2_665 2_665
O22 Co1 O20 105(2) . 2_665
O23 Co1 O20 76(2) 2_665 .
O23 Co1 O20 104(2) . .
O21 Co1 O20 117(2) 2_665 .
O21 Co1 O20 63(2) . .
O22 Co1 O20 105(2) 2_665 .
O22 Co1 O20 75(2) . .
O20 Co1 O20 180(4) 2_665 .
N8 Ag1 N1 168.4(14) 2_566 .
N4 Ag2 N7 126.5(12) 2_676 .
N4 Ag2 N2 160.5(13) 2_676 .
N7 Ag2 N2 72.6(12) . .
N3 Ag3 N10 136.5(15) . .
N3 Ag3 N11 140.8(17) . .
N10 Ag3 N11 74.9(13) . .
N3 Ag3 O5 109.4(13) . .
N10 Ag3 O5 95.9(11) . .
N11 Ag3 O5 83.6(13) . .
O4 W1 O11 97.6(17) . .
O4 W1 O12 104.0(18) . .
O11 W1 O12 85.2(18) . .
O4 W1 O1 99.0(16) . .
O11 W1 O1 89.8(16) . .
O12 W1 O1 156.9(18) . .
O4 W1 O14 101(2) . .
O11 W1 O14 162(2) . .
O12 W1 O14 91.8(17) . .
O1 W1 O14 85.9(18) . .
O4 W1 O20 151.6(18) . .
O11 W1 O20 103(2) . .
O12 W1 O20 59.3(19) . .
O1 W1 O20 100.3(18) . .
O14 W1 O20 61(2) . .
O4 W1 O21 150.7(18) . .
O11 W1 O21 65(2) . .
O12 W1 O21 98(2) . .
O1 W1 O21 59.8(18) . .
O14 W1 O21 98(2) . .
O20 W1 O21 58(2) . .
O19 W2 O7 102.9(19) . 2_665
O19 W2 O16 104(2) . .
O7 W2 O16 153.3(19) 2_665 .
O19 W2 O10 99(2) . 2_665
O7 W2 O10 84.0(17) 2_665 2_665
O16 W2 O10 92.5(18) . 2_665
O19 W2 O3 97.6(18) . .
O7 W2 O3 92.1(17) 2_665 .
O16 W2 O3 84(2) . .
O10 W2 O3 164(2) 2_665 .
O19 W2 O22 148.3(17) . 2_665
O7 W2 O22 61.6(16) 2_665 2_665
O16 W2 O22 94.4(19) . 2_665
O10 W2 O22 106(2) 2_665 2_665
O3 W2 O22 58.4(17) . 2_665
O19 W2 O23 152.4(18) . 2_665
O7 W2 O23 95.0(17) 2_665 2_665
O16 W2 O23 60.4(18) . 2_665
O10 W2 O23 62.3(19) 2_665 2_665
O3 W2 O23 102.6(18) . 2_665
O22 W2 O23 59.2(16) 2_665 2_665
O2 W3 O1 98.2(16) . .
O2 W3 O8 95.2(16) . .
O1 W3 O8 91.1(16) . .
O2 W3 O3 99.7(18) . .
O1 W3 O3 89.2(18) . .
O8 W3 O3 164.9(17) . .
O2 W3 O18 99.3(18) . 2_665
O1 W3 O18 161.8(19) . 2_665
O8 W3 O18 82.7(19) . 2_665
O3 W3 O18 92.4(19) . 2_665
O2 W3 O22 153.7(18) . 2_665
O1 W3 O22 100.9(17) . 2_665
O8 W3 O22 102.4(17) . 2_665
O3 W3 O22 62.8(18) . 2_665
O18 W3 O22 64.1(19) 2_665 2_665
O2 W3 O21 148.0(19) . .
O1 W3 O21 60.1(18) . .
O8 W3 O21 64.6(18) . .
O3 W3 O21 103(2) . .
O18 W3 O21 102(2) 2_665 .
O22 W3 O21 58.3(19) 2_665 .
O17 W4 O15 105(2) . 2_665
O17 W4 O8 98.8(17) . .
O15 W4 O8 86.3(18) 2_665 .
O17 W4 O10 98(2) . .
O15 W4 O10 92.3(17) 2_665 .
O8 W4 O10 163(2) . .
O17 W4 O11 96.1(18) . .
O15 W4 O11 159(2) 2_665 .
O8 W4 O11 90.3(17) . .
O10 W4 O11 85.0(17) . .
O17 W4 O23 153.7(19) . .
O15 W4 O23 60.1(18) 2_665 .
O8 W4 O23 101.5(17) . .
O10 W4 O23 64(2) . .
O11 W4 O23 100.3(17) . .
O17 W4 O21 149(2) . .
O15 W4 O21 100(2) 2_665 .
O8 W4 O21 63.7(18) . .
O10 W4 O21 100(2) . .
O11 W4 O21 60.4(18) . .
O23 W4 O21 57.2(18) . .
O13 W5 O14 99(2) . .
O13 W5 O15 102.1(17) . .
O14 W5 O15 159(2) . .
O13 W5 O16 105.1(17) . .
O14 W5 O16 87(2) . .
O15 W5 O16 90.8(19) . .
O13 W5 O6 96.2(17) . .
O14 W5 O6 91(2) . .
O15 W5 O6 83.4(19) . .
O16 W5 O6 159(2) . .
O13 W5 O23 152.2(15) . 2_665
O14 W5 O23 103(2) . 2_665
O15 W5 O23 57.9(18) . 2_665
O16 W5 O23 60.1(18) . 2_665
O6 W5 O23 100.0(19) . 2_665
O13 W5 O20 145.7(16) . .
O14 W5 O20 57.9(19) . .
O15 W5 O20 102(2) . .
O16 W5 O20 98.7(19) . .
O6 W5 O20 62.8(18) . .
O23 W5 O20 62.1(18) 2_665 .
O5 W6 O12 102.8(18) . .
O5 W6 O6 101(2) . .
O12 W6 O6 95.7(19) . .
O5 W6 O18 96.0(19) . .
O12 W6 O18 161(2) . .
O6 W6 O18 85(2) . .
O5 W6 O7 100.7(18) . .
O12 W6 O7 78.9(17) . .
O6 W6 O7 159(2) . .
O18 W6 O7 93.6(18) . .
O5 W6 O20 152.3(18) . .
O12 W6 O20 57.5(19) . .
O6 W6 O20 66(2) . .
O18 W6 O20 106(2) . .
O7 W6 O20 94.4(18) . .
O5 W6 O22 143.8(16) . .
O12 W6 O22 102.3(18) . .
O6 W6 O22 102.4(19) . .
O18 W6 O22 59.0(19) . .
O7 W6 O22 59.5(16) . .
O20 W6 O22 63.7(17) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N8 1.362(19) .
C1 C2 1.37(2) .
C2 C3 1.38(2) .
C2 C6 1.44(6) .
C3 C4 1.37(2) .
C4 C5 1.37(2) .
C5 N8 1.373(19) .
C6 N11 1.23(5) .
C6 N12 1.26(5) .
C6 C7 2.00(7) .
C7 N13 1.27(6) .
C7 N11 1.33(7) .
C7 C8 1.40(7) .
C8 N4 1.27(5) .
C8 N10 1.33(5) .
C9 N9 1.31(7) .
C9 N4 1.41(6) .
C10 N3 1.26(6) .
C10 N1 1.31(6) .
C10 C11 2.00(7) .
C11 N7 1.24(5) .
C11 N1 1.30(5) .
C11 C12 1.49(6) .
C12 N6 1.27(6) .
C12 N2 1.35(6) .
C12 C13 1.97(7) .
C13 N2 1.17(5) .
C13 N5 1.30(5) .
C13 C14 1.52(6) .
C14 C17 1.31(6) .
C14 C15 1.33(6) .
C15 N14 1.41(6) .
C16 C18 1.24(6) .
C16 N14 1.38(6) .
C17 C18 1.34(6) .
N1 Ag1 2.07(4) .
N2 Ag2 2.33(3) .
N3 N7 1.38(5) .
N3 Ag3 2.10(4) .
N4 Ag2 2.12(4) 2_676
N5 N6 1.36(5) .
N7 Ag2 2.30(3) .
N8 Ag1 2.04(4) 2_566
N9 N10 1.35(5) .
N10 Ag3 2.35(4) .
N11 Ag3 2.36(4) .
N12 N13 1.34(5) .
O1 W3 1.78(3) .
O1 W1 1.91(3) .
O2 W3 1.64(3) .
O3 W3 1.88(4) .
O3 W2 1.89(4) .
O4 W1 1.70(3) .
O5 W6 1.63(3) .
O5 Ag3 2.49(3) .
O6 W6 1.83(4) .
O6 W5 1.91(5) .
O7 W2 1.78(4) 2_665
O7 W6 1.88(4) .
O8 W4 1.87(4) .
O8 W3 1.88(4) .
O10 W2 1.84(4) 2_665
O10 W4 1.91(3) .
O11 W1 1.81(4) .
O11 W4 1.96(4) .
O12 W6 1.80(4) .
O12 W1 1.90(4) .
O13 W5 1.65(2) .
O14 W5 1.76(5) .
O14 W1 1.95(4) .
O15 W5 1.82(5) .
O15 W4 1.84(4) 2_665
O16 W2 1.82(4) .
O16 W5 1.84(4) .
O17 W4 1.67(4) .
O18 W6 1.88(5) .
O18 W3 1.90(5) 2_665
O19 W2 1.51(4) .
O20 Co1 1.96(5) .
O20 W1 2.01(5) .
O20 W6 2.17(5) .
O20 W5 2.27(5) .
O21 Co1 1.85(5) .
O21 W1 2.13(5) .
O21 W3 2.20(5) .
O21 W4 2.25(5) .
O22 Co1 1.89(4) .
O22 W3 2.02(4) 2_665
O22 W2 2.24(4) 2_665
O22 W6 2.29(4) .
O23 Co1 1.82(5) .
O23 W4 2.13(5) .
O23 W2 2.24(5) 2_665
O23 W5 2.25(4) 2_665
Co1 O23 1.82(5) 2_665
Co1 O21 1.85(5) 2_665
Co1 O22 1.89(4) 2_665
Co1 O20 1.96(5) 2_665
Ag1 N8 2.04(4) 2_566
Ag2 N4 2.12(4) 2_676
W2 O7 1.78(4) 2_665
W2 O10 1.84(4) 2_665
W2 O22 2.24(4) 2_665
W2 O23 2.24(5) 2_665
W3 O18 1.90(5) 2_665
W3 O22 2.02(4) 2_665
W4 O15 1.84(4) 2_665
W5 O23 2.25(4) 2_665
