#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/4/51/05/4510591.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_4510591
loop_
_publ_author_name
'Li, Meng-Ting'
'Sha, Jing-Quan'
'Zong, Xi-Ming'
'Sun, Jing-Wen'
'Yan, Peng-Fei'
'Li, Liang'
'Yang, Xiao-Ning'
_publ_section_title
;
 Assembly of Polyoxometalate-Based Hybrids with Different Helical Channels
 upon Subtle Ligand Variation
;
_journal_issue                   6
_journal_name_full               'Crystal Growth & Design'
_journal_page_first              2794
_journal_paper_doi               10.1021/cg500045q
_journal_volume                  14
_journal_year                    2014
_chemical_formula_moiety         'C36 H20 Ag7 Ge N28 O40 W12, 8(O0.50)'
_chemical_formula_sum            'C36 H20 Ag7 Ge N28 O47 W12'
_chemical_formula_weight         4630.58
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_Int_Tables_number      2
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                104.870(5)
_cell_angle_beta                 99.856(5)
_cell_angle_gamma                116.097(5)
_cell_formula_units_Z            1
_cell_length_a                   12.387(5)
_cell_length_b                   13.140(5)
_cell_length_c                   14.969(5)
_cell_measurement_temperature    293(2)
_cell_volume                     1998.3(13)
_computing_cell_refinement       'Bruker FRAMBO'
_computing_data_collection       'Bruker FRAMBO'
_computing_data_reduction        'Bruker SHELXTL'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'multiwire proportional'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0323
_diffrn_reflns_av_sigmaI/netI    0.0483
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            14687
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.98
_exptl_absorpt_coefficient_mu    19.337
_exptl_absorpt_correction_T_max  0.008
_exptl_absorpt_correction_T_min  0.001
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs(Sheldrick,1996)
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    3.848
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2057.0
_exptl_crystal_size_max          0.41
_exptl_crystal_size_mid          0.35
_exptl_crystal_size_min          0.25
_refine_diff_density_max         4.147
_refine_diff_density_min         -2.228
_refine_diff_density_rms         0.344
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.203
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     616
_refine_ls_number_reflns         7036
_refine_ls_number_restraints     108
_refine_ls_restrained_S_all      1.204
_refine_ls_R_factor_all          0.0801
_refine_ls_R_factor_gt           0.0713
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0102P)²+153.1011P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1410
_refine_ls_wR_factor_ref         0.1451
_reflns_number_gt                6216
_reflns_number_total             7036
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            cg500045q_si_002.cif
_cod_data_source_block           3
_cod_depositor_comments
'Adding full bibliography for 4510589--4510591.cif.'
_cod_original_sg_symbol_Hall     -P_1
_cod_database_code               4510591
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C 0.2252(18) 0.3235(19) 0.8947(14) 0.023(4) Uani 1 1 d .
H1 H 0.2483 0.3582 0.8492 0.028 Uiso 1 1 calc R
C2 C 0.1069(18) 0.2236(19) 0.8658(14) 0.022(4) Uani 1 1 d .
C3 C 0.070(2) 0.169(2) 0.9314(16) 0.029(5) Uani 1 1 d .
H3 H -0.0103 0.0999 0.9129 0.035 Uiso 1 1 calc R
C4 C 0.154(2) 0.218(2) 1.0245(17) 0.036(6) Uani 1 1 d .
H4 H 0.1325 0.1854 1.0713 0.043 Uiso 1 1 calc R
C5 C 0.2707(19) 0.3161(19) 1.0450(16) 0.033(5) Uani 1 1 d .
H5 H 0.3287 0.3454 1.1067 0.040 Uiso 1 1 calc R
C6 C 0.0312(19) 0.1717(19) 0.7574(15) 0.025(5) Uani 1 1 d .
C7 C -0.016(2) 0.129(2) 0.6085(17) 0.033(5) Uani 1 1 d .
C9 C 0.0034(17) 0.1308(17) 0.5151(13) 0.018(4) Uani 1 1 d .
C10 C 0.426(2) 0.866(2) 0.3726(18) 0.037(6) Uani 1 1 d .
H10 H 0.4295 0.9113 0.3338 0.045 Uiso 1 1 calc R
C11 C 0.309(2) 0.785(2) 0.3772(17) 0.036(5) Uani 1 1 d .
H11 H 0.2351 0.7793 0.3426 0.043 Uiso 1 1 calc R
C12 C 0.301(2) 0.716(2) 0.4304(18) 0.039(6) Uani 1 1 d .
H12 H 0.2221 0.6629 0.4334 0.046 Uiso 1 1 calc R
C13 C 0.411(2) 0.7238(19) 0.4811(14) 0.024(4) Uani 1 1 d .
C14 C 0.523(2) 0.8076(19) 0.4759(13) 0.029(5) Uani 1 1 d .
H14 H 0.5979 0.8163 0.5114 0.035 Uiso 1 1 calc R
C15 C 0.410(2) 0.6397(18) 0.5340(15) 0.026(5) Uani 1 1 d U
C16 C 0.456(2) 0.5494(18) 0.6126(14) 0.025(5) Uani 1 1 d .
C17 C 0.5334(19) 0.5153(17) 0.6671(14) 0.022(4) Uani 1 1 d U
C18 C -0.023(2) 0.108(2) 0.3676(17) 0.037(6) Uani 1 1 d .
H18 H -0.0603 0.0855 0.3010 0.044 Uiso 1 1 calc R
C8 C 0.591(2) 0.422(2) 0.7444(15) 0.031(5) Uani 1 1 d .
H8 H 0.5912 0.3687 0.7746 0.037 Uiso 1 1 calc R
N1 N 0.2990(19) 0.5517(17) 0.5337(15) 0.036(5) Uani 1 1 d .
N2 N 0.6964(17) 0.5150(15) 0.7393(13) 0.032(4) Uani 1 1 d .
N3 N 0.5075(16) 0.6404(16) 0.5779(12) 0.028(4) Uani 1 1 d .
N4 N 0.0988(19) 0.1726(16) 0.4123(14) 0.034(5) Uani 1 1 d .
N5 N 0.3314(19) 0.4923(17) 0.5862(13) 0.034(5) Uani 1 1 d .
N6 N 0.6596(17) 0.5735(16) 0.6904(13) 0.028(4) Uani 1 1 d .
N7 N 0.5318(18) 0.8770(17) 0.4239(13) 0.036(5) Uani 1 1 d .
N8 N 0.4896(19) 0.4218(16) 0.6991(14) 0.034(4) Uani 1 1 d .
N9 N 0.0829(16) 0.1952(15) 0.6919(12) 0.026(4) Uani 1 1 d .
N10 N -0.1253(17) 0.0696(18) 0.6206(12) 0.034(5) Uani 1 1 d .
N11 N -0.0927(17) 0.0966(18) 0.7190(13) 0.035(5) Uani 1 1 d U
N12 N 0.3114(19) 0.3756(18) 0.9856(15) 0.041(5) Uani 1 1 d .
N13 N -0.0893(17) 0.0769(19) 0.4287(12) 0.032(4) Uani 1 1 d .
N14 N 0.1166(17) 0.1906(18) 0.5100(13) 0.033(4) Uani 1 1 d .
O1 O 0.316(2) 0.717(2) 0.7856(18) 0.075(6) Uani 1 1 d U
O2 O 0.5563(19) 0.774(2) 0.8513(18) 0.070(6) Uani 1 1 d U
O1W O 0.047(2) 0.440(2) 0.423(2) 0.108(11) Uani 1 1 d .
O3 O 0.643(2) 1.044(2) 0.9794(18) 0.018(5) Uani 0.50 1 d PU
O4 O 0.475(2) 0.895(2) 0.8926(17) 0.013(5) Uani 0.50 1 d PU
O5 O 0.395(2) 0.986(2) 0.9091(18) 0.016(5) Uani 0.50 1 d PU
O6 O 0.843(2) 1.2052(19) 1.0447(15) 0.072(6) Uani 1 1 d U
O7 O 0.5935(19) 1.206(2) 0.8665(15) 0.072(6) Uani 1 1 d U
O8 O 0.2486(17) 0.7701(16) 0.6255(12) 0.050(5) Uani 1 1 d .
O9 O 0.3688(17) 0.5457(13) 0.8281(11) 0.039(4) Uani 1 1 d .
O10 O 0.1979(19) 0.8362(14) 0.7971(14) 0.055(6) Uani 1 1 d .
O11 O 0.7335(18) 0.9337(15) 1.1162(14) 0.061(6) Uani 1 1 d .
O12 O 0.8540(15) 1.3362(16) 0.9264(13) 0.049(5) Uani 1 1 d .
O13 O 0.7223(15) 0.8862(15) 0.7594(11) 0.036(4) Uani 1 1 d .
O14 O 0.386(2) 1.2263(18) 0.7975(14) 0.057(6) Uani 1 1 d .
O15 O 0.6985(18) 1.0905(17) 0.8575(14) 0.053(4) Uani 1 1 d U
O16 O 0.9690(16) 1.1119(17) 1.1335(16) 0.056(5) Uani 1 1 d .
O17 O 0.3780(16) 1.0062(14) 0.7606(13) 0.043(4) Uani 1 1 d .
O18 O 0.5162(19) 0.731(2) 1.0080(16) 0.074(6) Uani 1 1 d U
O19 O 0.2803(16) 0.676(2) 0.9420(13) 0.084(9) Uani 1 1 d .
O20 O 0.458(2) 0.868(2) 1.0214(19) 0.021(5) Uani 0.50 1 d PU
O21 O 0.499(2) 0.888(2) 0.7492(18) 0.075(6) Uani 1 1 d U
O22 O 0.765(2) 0.969(2) 0.9594(17) 0.080(7) Uani 1 1 d U
Ge1 Ge 0.5000 1.0000 1.0000 0.0228(6) Uani 1 2 d SU
Ag1 Ag 0.71570(16) 0.97940(19) 0.41239(14) 0.0427(5) Uani 1 1 d .
Ag2 Ag 0.28059(17) 0.29492(19) 0.66062(15) 0.0464(5) Uani 1 1 d .
Ag3 Ag 0.5000 0.5000 1.0000 0.0416(6) Uani 1 2 d S
Ag4 Ag 0.7411(2) 0.73190(19) 0.63091(19) 0.0683(8) Uani 1 1 d .
W1 W 0.64741(10) 0.91903(9) 0.83572(8) 0.0367(3) Uani 1 1 d .
W2 W 0.42211(9) 1.15369(9) 0.86281(6) 0.0294(2) Uani 1 1 d .
W3 W 0.32894(9) 0.84327(9) 0.74557(7) 0.0312(2) Uani 1 1 d .
W4 W 0.81798(9) 1.07528(9) 1.08908(7) 0.0331(2) Uani 1 1 d .
W5 W 0.74129(9) 1.23001(9) 0.94987(7) 0.0372(3) Uani 1 1 d U
W6 W 0.40624(10) 0.69049(9) 0.88342(9) 0.0441(3) Uani 1 1 d .
O2W O 1.026(3) 1.441(3) 0.830(2) 0.113(10) Uani 1 1 d .
O3W O 0.935(2) 0.583(3) 0.798(3) 0.155(16) Uani 1 1 d .
O4W O 1.058(4) 1.430(4) 0.649(4) 0.086(16) Uani 0.50 1 d P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N12 C1 C2 124.2(19) . .
C1 C2 C3 119.5(19) . .
C1 C2 C6 115.4(17) . .
C3 C2 C6 124.7(19) . .
C4 C3 C2 118(2) . .
C5 C4 C3 117(2) . .
N12 C5 C4 127(2) . .
N9 C6 N11 111.9(18) . .
N9 C6 C2 123.2(18) . .
N11 C6 C2 124.8(18) . .
N10 C7 N9 114(2) . .
N10 C7 C9 125.8(19) . .
N9 C7 C9 120.3(18) . .
N14 C9 N13 113.4(17) . .
N14 C9 C7 121.3(18) . .
N13 C9 C7 125.3(17) . .
N7 C10 C11 120(2) . .
C12 C11 C10 121(2) . .
C11 C12 C13 119(2) . .
C14 C13 C12 117(2) . .
C14 C13 C15 120.4(19) . .
C12 C13 C15 122.8(19) . .
N7 C14 C13 125(2) . .
N3 C15 N1 114(2) . .
N3 C15 C13 125.1(19) . .
N1 C15 C13 120.6(19) . .
N5 C16 N3 114(2) . .
N5 C16 C17 124.1(19) . .
N3 C16 C17 121.8(19) . .
N6 C17 N8 111.9(19) . .
N6 C17 C16 122.4(18) . .
N8 C17 C16 125.7(19) . .
N4 C18 N13 112(2) . .
N8 C8 N2 109(2) . .
C15 N1 N5 105.7(19) . .
N6 N2 C8 109.0(18) . .
C15 N3 C16 102.0(18) . .
C15 N3 Ag4 148.9(15) . .
C16 N3 Ag4 109.0(14) . .
C18 N4 N14 106.6(17) . .
C18 N4 Ag4 133.6(16) . 2_666
N14 N4 Ag4 119.2(14) . 2_666
C16 N5 N1 104.0(18) . .
C17 N6 N2 104.8(17) . .
C17 N6 Ag4 113.5(14) . .
N2 N6 Ag4 141.6(13) . .
C14 N7 C10 119(2) . .
C14 N7 Ag1 116.1(16) . .
C10 N7 Ag1 124.6(16) . .
C8 N8 C17 105.8(18) . .
C8 N8 Ag2 133.0(15) . .
C17 N8 Ag2 120.9(15) . .
C6 N9 C7 103.2(17) . .
C6 N9 Ag2 145.3(14) . .
C7 N9 Ag2 111.3(13) . .
C7 N10 N11 103.1(17) . .
C6 N11 N10 107.8(16) . .
C5 N12 C1 113.4(18) . .
C5 N12 Ag3 128.2(16) . .
C1 N12 Ag3 115.7(15) . .
C9 N13 C18 102.2(18) . .
C9 N13 Ag1 123.1(13) . 1_445
C18 N13 Ag1 134.7(15) . 1_445
C9 N14 N4 105.4(17) . .
C9 N14 Ag2 114.5(13) . .
N4 N14 Ag2 140.0(14) . .
W3 O1 W6 139.5(13) . .
W1 O2 W6 139.1(13) . .
Ge1 O3 W4 122.4(12) . .
Ge1 O3 W1 118.0(12) . .
W4 O3 W1 98.7(10) . .
Ge1 O3 W5 118.5(13) . .
W4 O3 W5 98.4(9) . .
W1 O3 W5 95.7(8) . .
Ge1 O4 W3 123.4(12) . .
Ge1 O4 W1 119.8(11) . .
W3 O4 W1 97.9(9) . .
Ge1 O4 W6 117.9(11) . .
W3 O4 W6 96.4(8) . .
W1 O4 W6 95.7(8) . .
Ge1 O5 W2 122.3(13) . .
Ge1 O5 W3 122.6(13) . .
W2 O5 W3 95.6(8) . .
Ge1 O5 W4 120.3(12) . 2_677
W2 O5 W4 94.7(9) . 2_677
W3 O5 W4 94.4(9) . 2_677
W4 O6 W5 135.5(13) . .
W5 O7 W2 137.3(13) . .
W3 O10 W4 137.9(11) . 2_677
W4 O11 W2 137.7(12) . 2_677
W1 O13 Ag4 150.5(9) . .
W5 O15 W1 141.8(11) . .
W3 O17 W2 137.5(9) . .
W2 O18 W6 138.6(13) 2_677 .
W6 O19 W5 139.0(12) . 2_677
Ge1 O20 W2 125.1(13) . 2_677
Ge1 O20 W5 118.2(13) . 2_677
W2 O20 W5 98.5(10) 2_677 2_677
Ge1 O20 W6 116.0(12) . .
W2 O20 W6 98.7(10) 2_677 .
W5 O20 W6 94.5(9) 2_677 .
W1 O21 W3 138.0(13) . .
W4 O22 W1 139.6(14) . .
O5 Ge1 O5 180.000(13) . 2_677
O5 Ge1 O4 67.8(12) . .
O5 Ge1 O4 112.2(12) 2_677 .
O5 Ge1 O4 112.2(12) . 2_677
O5 Ge1 O4 67.8(12) 2_677 2_677
O4 Ge1 O4 180.000(12) . 2_677
O5 Ge1 O20 66.2(12) . 2_677
O5 Ge1 O20 113.8(12) 2_677 2_677
O4 Ge1 O20 105.0(12) . 2_677
O4 Ge1 O20 75.0(12) 2_677 2_677
O5 Ge1 O20 113.8(12) . .
O5 Ge1 O20 66.2(12) 2_677 .
O4 Ge1 O20 75.0(12) . .
O4 Ge1 O20 105.0(12) 2_677 .
O20 Ge1 O20 180.000(8) 2_677 .
O5 Ge1 O3 110.5(12) . .
O5 Ge1 O3 69.5(12) 2_677 .
O4 Ge1 O3 72.0(12) . .
O4 Ge1 O3 108.0(12) 2_677 .
O20 Ge1 O3 73.0(12) 2_677 .
O20 Ge1 O3 107.0(12) . .
O5 Ge1 O3 69.5(12) . 2_677
O5 Ge1 O3 110.5(12) 2_677 2_677
O4 Ge1 O3 108.0(12) . 2_677
O4 Ge1 O3 72.0(12) 2_677 2_677
O20 Ge1 O3 107.0(12) 2_677 2_677
O20 Ge1 O3 73.0(12) . 2_677
O3 Ge1 O3 180.000(6) . 2_677
N13 Ag1 N7 168.0(7) 1_665 .
N8 Ag2 N14 130.8(6) . .
N8 Ag2 N9 156.1(6) . .
N14 Ag2 N9 72.6(6) . .
N12 Ag3 N12 180.000(3) 2_667 .
N4 Ag4 N6 139.9(7) 2_666 .
N4 Ag4 N3 140.4(7) 2_666 .
N6 Ag4 N3 73.2(6) . .
N4 Ag4 O13 108.9(6) 2_666 .
N6 Ag4 O13 96.3(5) . .
N3 Ag4 O13 80.0(5) . .
O13 W1 O2 103.5(9) . .
O13 W1 O21 102.1(10) . .
O2 W1 O21 89.7(9) . .
O13 W1 O22 101.9(10) . .
O2 W1 O22 85.9(10) . .
O21 W1 O22 156.0(11) . .
O13 W1 O15 103.8(8) . .
O2 W1 O15 152.7(9) . .
O21 W1 O15 82.8(9) . .
O22 W1 O15 90.4(9) . .
O13 W1 O4 157.3(8) . .
O2 W1 O4 63.4(9) . .
O21 W1 O4 61.5(9) . .
O22 W1 O4 95.7(10) . .
O15 W1 O4 90.2(8) . .
O13 W1 O3 152.4(8) . .
O2 W1 O3 95.7(10) . .
O21 W1 O3 97.6(10) . .
O22 W1 O3 59.5(10) . .
O15 W1 O3 59.7(8) . .
O4 W1 O3 50.2(8) . .
O14 W2 O11 101.2(10) . 2_677
O14 W2 O18 101.6(11) . 2_677
O11 W2 O18 88.2(8) 2_677 2_677
O14 W2 O7 100.8(10) . .
O11 W2 O7 158.0(11) 2_677 .
O18 W2 O7 89.1(8) 2_677 .
O14 W2 O17 100.6(9) . .
O11 W2 O17 88.3(7) 2_677 .
O18 W2 O17 157.8(10) 2_677 .
O7 W2 O17 86.0(8) . .
O14 W2 O20 156.5(11) . 2_677
O11 W2 O20 96.2(10) 2_677 2_677
O18 W2 O20 63.1(10) 2_677 2_677
O7 W2 O20 63.3(10) . 2_677
O17 W2 O20 95.5(9) . 2_677
O14 W2 O5 157.1(10) . .
O11 W2 O5 64.0(9) 2_677 .
O18 W2 O5 95.5(10) 2_677 .
O7 W2 O5 94.6(10) . .
O17 W2 O5 63.4(8) . .
O20 W2 O5 46.4(9) 2_677 .
O8 W3 O1 102.6(10) . .
O8 W3 O17 101.1(8) . .
O1 W3 O17 156.3(10) . .
O8 W3 O10 101.5(9) . .
O1 W3 O10 86.3(9) . .
O17 W3 O10 88.3(7) . .
O8 W3 O21 102.1(10) . .
O1 W3 O21 90.0(9) . .
O17 W3 O21 85.8(8) . .
O10 W3 O21 156.4(10) . .
O8 W3 O4 156.5(9) . .
O1 W3 O4 62.8(9) . .
O17 W3 O4 95.0(8) . .
O10 W3 O4 96.0(9) . .
O21 W3 O4 61.9(9) . .
O8 W3 O5 157.2(9) . .
O1 W3 O5 94.0(10) . .
O17 W3 O5 63.1(8) . .
O10 W3 O5 63.8(8) . .
O21 W3 O5 93.3(10) . .
O4 W3 O5 46.2(8) . .
O16 W4 O22 103.5(11) . .
O16 W4 O11 100.5(10) . .
O22 W4 O11 86.2(9) . .
O16 W4 O10 99.5(10) . 2_677
O22 W4 O10 156.9(11) . 2_677
O11 W4 O10 88.1(7) . 2_677
O16 W4 O6 99.7(10) . .
O22 W4 O6 89.5(9) . .
O11 W4 O6 159.8(10) . .
O10 W4 O6 88.2(9) 2_677 .
O16 W4 O3 156.6(10) . .
O22 W4 O3 61.6(10) . .
O11 W4 O3 96.5(9) . .
O10 W4 O3 96.9(10) 2_677 .
O6 W4 O3 64.3(9) . .
O16 W4 O5 155.6(9) . 2_677
O22 W4 O5 93.9(10) . 2_677
O11 W4 O5 63.4(9) . 2_677
O10 W4 O5 63.6(8) 2_677 2_677
O6 W4 O5 97.3(10) . 2_677
O3 W4 O5 47.8(8) . 2_677
O12 W5 O15 104.5(9) . .
O12 W5 O7 101.8(9) . .
O15 W5 O7 81.8(9) . .
O12 W5 O19 102.6(11) . 2_677
O15 W5 O19 152.8(10) . 2_677
O7 W5 O19 89.8(8) . 2_677
O12 W5 O6 100.3(9) . .
O15 W5 O6 91.9(9) . .
O7 W5 O6 158.0(10) . .
O19 W5 O6 86.3(10) 2_677 .
O12 W5 O3 154.4(9) . .
O15 W5 O3 61.2(9) . .
O7 W5 O3 97.1(10) . .
O19 W5 O3 94.5(11) 2_677 .
O6 W5 O3 61.7(9) . .
O12 W5 O20 155.3(9) . 2_677
O15 W5 O20 90.3(9) . 2_677
O7 W5 O20 60.3(9) . 2_677
O19 W5 O20 63.3(9) 2_677 2_677
O6 W5 O20 98.9(10) . 2_677
O3 W5 O20 50.3(9) . 2_677
O9 W6 O19 103.8(10) . .
O9 W6 O1 103.0(10) . .
O19 W6 O1 87.1(10) . .
O9 W6 O18 100.6(9) . .
O19 W6 O18 87.5(8) . .
O1 W6 O18 156.4(11) . .
O9 W6 O2 99.8(9) . .
O19 W6 O2 156.4(11) . .
O1 W6 O2 88.7(9) . .
O18 W6 O2 87.0(9) . .
O9 W6 O4 153.7(8) . .
O19 W6 O4 96.3(10) . .
O1 W6 O4 60.7(9) . .
O18 W6 O4 97.0(9) . .
O2 W6 O4 61.6(9) . .
O9 W6 O20 154.8(8) . .
O19 W6 O20 63.2(9) . .
O1 W6 O20 97.9(10) . .
O18 W6 O20 59.3(9) . .
O2 W6 O20 94.4(10) . .
O4 W6 O20 51.1(8) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N12 1.36(3) .
C1 C2 1.36(3) .
C2 C3 1.39(3) .
C2 C6 1.52(3) .
C3 C4 1.38(3) .
C4 C5 1.36(3) .
C5 N12 1.35(3) .
C6 N9 1.29(3) .
C6 N11 1.32(3) .
C7 N10 1.30(3) .
C7 N9 1.34(3) .
C7 C9 1.46(3) .
C9 N14 1.30(2) .
C9 N13 1.34(2) .
C10 N7 1.33(3) .
C10 C11 1.40(3) .
C11 C12 1.34(3) .
C12 C13 1.39(3) .
C13 C14 1.37(3) .
C13 C15 1.51(3) .
C14 N7 1.32(3) .
C15 N3 1.27(3) .
C15 N1 1.35(3) .
C16 N5 1.31(3) .
C16 N3 1.37(3) .
C16 C17 1.44(3) .
C17 N6 1.33(3) .
C17 N8 1.36(3) .
C18 N4 1.30(3) .
C18 N13 1.36(3) .
C8 N8 1.32(3) .
C8 N2 1.37(3) .
N1 N5 1.37(3) .
N2 N6 1.35(3) .
N3 Ag4 2.472(18) .
N4 N14 1.38(2) .
N4 Ag4 2.143(17) 2_666
N6 Ag4 2.357(18) .
N7 Ag1 2.142(19) .
N8 Ag2 2.239(19) .
N9 Ag2 2.412(16) .
N10 N11 1.36(2) .
N12 Ag3 2.11(2) .
N13 Ag1 2.109(18) 1_445
N14 Ag2 2.342(19) .
O1 W3 1.86(2) .
O1 W6 1.89(2) .
O2 W1 1.84(2) .
O2 W6 1.92(2) .
O3 Ge1 1.71(2) .
O3 W4 2.29(2) .
O3 W1 2.38(3) .
O3 W5 2.40(2) .
O4 Ge1 1.70(2) .
O4 W3 2.32(2) .
O4 W1 2.35(2) .
O4 W6 2.39(2) .
O5 Ge1 1.62(2) .
O5 W2 2.38(2) .
O5 W3 2.41(2) .
O5 W4 2.41(2) 2_677
O6 W4 1.907(19) .
O6 W5 1.93(2) .
O7 W5 1.88(2) .
O7 W2 1.91(2) .
O8 W3 1.674(16) .
O9 W6 1.674(15) .
O10 W3 1.890(17) .
O10 W4 1.895(16) 2_677
O11 W4 1.882(17) .
O11 W2 1.891(16) 2_677
O12 W5 1.651(15) .
O13 W1 1.678(14) .
O13 Ag4 2.536(16) .
O14 W2 1.667(16) .
O15 W5 1.774(19) .
O15 W1 1.970(19) .
O16 W4 1.670(17) .
O17 W3 1.888(15) .
O17 W2 1.912(16) .
O18 W2 1.89(2) 2_677
O18 W6 1.90(2) .
O19 W6 1.879(17) .
O19 W5 1.905(17) 2_677
O20 Ge1 1.71(3) .
O20 W2 2.24(3) 2_677
O20 W5 2.41(2) 2_677
O20 W6 2.42(3) .
O21 W1 1.87(2) .
O21 W3 1.90(2) .
O22 W4 1.87(2) .
O22 W1 1.89(2) .
Ge1 O5 1.62(2) 2_677
Ge1 O4 1.70(2) 2_677
Ge1 O20 1.71(3) 2_677
Ge1 O3 1.71(2) 2_677
Ag1 N13 2.109(19) 1_665
Ag3 N12 2.11(2) 2_667
Ag4 N4 2.143(17) 2_666
W2 O11 1.891(16) 2_677
W2 O18 1.89(2) 2_677
W2 O20 2.24(3) 2_677
W4 O10 1.895(16) 2_677
W4 O5 2.41(2) 2_677
W5 O19 1.905(17) 2_677
W5 O20 2.41(3) 2_677
