#------------------------------------------------------------------------------
#$Date: 2016-03-25 10:35:27 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179755 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/51/7005183.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7005183
loop_
_publ_author_name
'Copsey, May C.'
'Panneerselvam, Arunkumar'
'Afzaal, Mohammad'
'Chivers, Tristram'
'O'Brien, Paul'
_publ_section_title
;
 Syntheses, X-ray structures and AACVD studies of group 11
 ditelluroimidodiphosphinate complexes.
;
_journal_issue                   15
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1528
_journal_page_last               1538
_journal_paper_doi               10.1039/B617429A
_journal_year                    2007
_chemical_formula_moiety         'C96 H80 Ag4 N4 P8 Te8, 2(C4 H8 O)'
_chemical_formula_sum            'C104 H96 Ag4 N4 O2 P8 Te8'
_chemical_formula_weight         3133.89
_chemical_name_systematic
;
?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                98.443(2)
_cell_angle_beta                 100.975(1)
_cell_angle_gamma                103.106(2)
_cell_formula_units_Z            1
_cell_length_a                   10.5800(3)
_cell_length_b                   15.0793(3)
_cell_length_c                   17.7612(5)
_cell_measurement_reflns_used    11730
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.50
_cell_measurement_theta_min      1.00
_cell_volume                     2655.29(12)
_computing_cell_refinement       'Nonius DENZO'
_computing_data_collection       'Nonius COLLECT'
_computing_data_reduction        'Nonius DENZO'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Nonius Kappa CCD'
_diffrn_measurement_method       'phi/omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0257
_diffrn_reflns_av_sigmaI/netI    0.0363
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            18045
_diffrn_reflns_theta_full        25.03
_diffrn_reflns_theta_max         25.03
_diffrn_reflns_theta_min         2.83
_exptl_absorpt_coefficient_mu    3.050
_exptl_absorpt_correction_T_max  0.9415
_exptl_absorpt_correction_T_min  0.8381
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   'SCALEPACK (Otwinowski and Minor, 1997)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.960
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1488
_exptl_crystal_size_max          0.06
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.551
_refine_diff_density_min         -0.834
_refine_diff_density_rms         0.145
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.104
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     613
_refine_ls_number_reflns         9349
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.104
_refine_ls_R_factor_all          0.0479
_refine_ls_R_factor_gt           0.0359
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0458P)²+7.5146P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0901
_refine_ls_wR_factor_ref         0.0971
_reflns_number_gt                7760
_reflns_number_total             9349
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            B617429A.txt
_cod_data_source_block           complex8
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7005183
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.50287(5) 0.09371(3) 0.67148(3) 0.03573(12) Uani 1 1 d . . .
Ag2 Ag 0.60416(5) 0.08920(3) 0.51005(3) 0.03452(12) Uani 1 1 d . . .
Te1 Te 0.24273(3) 0.00235(2) 0.57233(2) 0.02496(10) Uani 1 1 d . . .
Te2 Te 0.61006(3) -0.06170(2) 0.62929(2) 0.02696(10) Uani 1 1 d . . .
Te3 Te 0.55290(5) 0.14856(3) 0.83378(2) 0.04215(12) Uani 1 1 d . A .
Te4 Te 0.57228(3) 0.24573(2) 0.59879(2) 0.02562(10) Uani 1 1 d . A .
P1 P 0.18694(13) -0.13597(9) 0.62702(8) 0.0226(3) Uani 1 1 d . . .
P2 P 0.44573(13) -0.17870(9) 0.66763(8) 0.0230(3) Uani 1 1 d . . .
P3 P 0.61922(14) 0.31023(10) 0.83247(8) 0.0244(3) Uani 1 1 d . . .
P4 P 0.76445(13) 0.31310(9) 0.70827(8) 0.0222(3) Uani 1 1 d . . .
N1 N 0.2897(4) -0.1997(3) 0.6285(3) 0.0243(10) Uani 1 1 d . . .
N2 N 0.7404(4) 0.3443(3) 0.7926(3) 0.0281(10) Uani 1 1 d . A .
C1 C 0.0294(5) -0.2039(4) 0.5640(3) 0.0231(11) Uani 1 1 d . . .
C2 C 0.0200(5) -0.2873(4) 0.5151(3) 0.0266(12) Uani 1 1 d . . .
H2 H 0.0953 -0.3121 0.5169 0.032 Uiso 1 1 calc R . .
C3 C -0.1025(6) -0.3344(4) 0.4632(3) 0.0320(13) Uani 1 1 d . . .
H3 H -0.1097 -0.3906 0.4285 0.038 Uiso 1 1 calc R . .
C4 C -0.2097(5) -0.3003(4) 0.4621(3) 0.0280(12) Uani 1 1 d . . .
H4 H -0.2918 -0.3334 0.4267 0.034 Uiso 1 1 calc R . .
C5 C -0.2036(6) -0.2189(4) 0.5106(4) 0.0374(15) Uani 1 1 d . . .
H5 H -0.2809 -0.1966 0.5096 0.045 Uiso 1 1 calc R . .
C6 C -0.0824(6) -0.1696(4) 0.5613(4) 0.0349(14) Uani 1 1 d . . .
H6 H -0.0761 -0.1122 0.5941 0.042 Uiso 1 1 calc R . .
C7 C 0.1504(6) -0.1105(4) 0.7227(3) 0.0288(13) Uani 1 1 d . . .
C8 C 0.2319(6) -0.0348(4) 0.7779(3) 0.0334(13) Uani 1 1 d . . .
H8 H 0.3021 0.0066 0.7644 0.040 Uiso 1 1 calc R . .
C9 C 0.2118(7) -0.0192(5) 0.8530(4) 0.0451(16) Uani 1 1 d . . .
H9 H 0.2675 0.0331 0.8908 0.054 Uiso 1 1 calc R . .
C10 C 0.1103(8) -0.0800(6) 0.8726(4) 0.057(2) Uani 1 1 d . . .
H10 H 0.0973 -0.0696 0.9243 0.068 Uiso 1 1 calc R . .
C11 C 0.0272(9) -0.1559(6) 0.8182(5) 0.062(2) Uani 1 1 d . . .
H11 H -0.0425 -0.1975 0.8320 0.075 Uiso 1 1 calc R . .
C12 C 0.0480(7) -0.1703(5) 0.7427(4) 0.0475(18) Uani 1 1 d . . .
H12 H -0.0090 -0.2217 0.7045 0.057 Uiso 1 1 calc R . .
C13 C 0.4717(6) -0.1581(4) 0.7735(3) 0.0311(13) Uani 1 1 d . . .
C14 C 0.5730(7) -0.0857(5) 0.8241(4) 0.0404(15) Uani 1 1 d . . .
H14 H 0.6355 -0.0462 0.8035 0.049 Uiso 1 1 calc R . .
C15 C 0.5822(9) -0.0715(5) 0.9038(4) 0.056(2) Uani 1 1 d . . .
H15 H 0.6490 -0.0207 0.9375 0.067 Uiso 1 1 calc R . .
C16 C 0.4950(9) -0.1307(6) 0.9353(4) 0.056(2) Uani 1 1 d . . .
H16 H 0.5032 -0.1215 0.9903 0.068 Uiso 1 1 calc R . .
C17 C 0.3953(8) -0.2035(5) 0.8853(4) 0.0483(18) Uani 1 1 d . . .
H17 H 0.3345 -0.2439 0.9062 0.058 Uiso 1 1 calc R . .
C18 C 0.3844(7) -0.2171(5) 0.8057(4) 0.0401(15) Uani 1 1 d . . .
H18 H 0.3165 -0.2674 0.7722 0.048 Uiso 1 1 calc R . .
C19 C 0.4872(5) -0.2875(4) 0.6427(3) 0.0258(12) Uani 1 1 d . . .
C20 C 0.6166(6) -0.2938(4) 0.6728(4) 0.0392(15) Uani 1 1 d . . .
H20 H 0.6818 -0.2417 0.7059 0.047 Uiso 1 1 calc R . .
C21 C 0.6479(7) -0.3780(5) 0.6532(5) 0.0491(18) Uani 1 1 d . . .
H21 H 0.7358 -0.3828 0.6722 0.059 Uiso 1 1 calc R . .
C22 C 0.5519(8) -0.4550(5) 0.6062(4) 0.0457(17) Uani 1 1 d . . .
H22 H 0.5734 -0.5126 0.5947 0.055 Uiso 1 1 calc R . .
C23 C 0.4281(7) -0.4476(4) 0.5771(4) 0.0389(15) Uani 1 1 d . . .
H23 H 0.3630 -0.4997 0.5441 0.047 Uiso 1 1 calc R . .
C24 C 0.3956(6) -0.3645(4) 0.5951(3) 0.0337(14) Uani 1 1 d . . .
H24 H 0.3080 -0.3604 0.5741 0.040 Uiso 1 1 calc R . .
C25 C 0.6812(4) 0.3702(3) 0.93454(19) 0.0268(12) Uani 0.50 1 d PG A 1
C26 C 0.8054(5) 0.3654(4) 0.9740(3) 0.041(2) Uani 0.50 1 d PG A 1
H26 H 0.8548 0.3307 0.9481 0.049 Uiso 0.50 1 calc PR A 1
C27 C 0.8574(5) 0.4112(5) 1.0514(3) 0.051(3) Uani 0.50 1 d PG A 1
H27 H 0.9423 0.4079 1.0784 0.062 Uiso 0.50 1 calc PR A 1
C28 C 0.7852(5) 0.4619(4) 1.0894(2) 0.046(2) Uani 0.50 1 d PG A 1
H28 H 0.8208 0.4932 1.1423 0.055 Uiso 0.50 1 calc PR A 1
C29 C 0.6610(5) 0.4668(4) 1.0499(3) 0.045(3) Uani 0.50 1 d PG A 1
H29 H 0.6116 0.5014 1.0759 0.054 Uiso 0.50 1 calc PR A 1
C30 C 0.6090(4) 0.4209(4) 0.9725(2) 0.039(3) Uani 0.50 1 d PG A 1
H30 H 0.5241 0.4242 0.9455 0.047 Uiso 0.50 1 calc PR A 1
C25A C 0.6802(4) 0.3759(3) 0.93128(19) 0.0268(12) Uani 0.50 1 d PG A 2
C26A C 0.8135(4) 0.4251(4) 0.9574(3) 0.041(2) Uani 0.50 1 d PG A 2
H26A H 0.8731 0.4224 0.9238 0.049 Uiso 0.50 1 calc PR A 2
C27A C 0.8598(4) 0.4784(4) 1.0328(3) 0.051(3) Uani 0.50 1 d PG A 2
H27A H 0.9509 0.5121 1.0506 0.062 Uiso 0.50 1 calc PR A 2
C28A C 0.7727(5) 0.4825(4) 1.0819(2) 0.046(2) Uani 0.50 1 d PG A 2
H28A H 0.8043 0.5189 1.1334 0.055 Uiso 0.50 1 calc PR A 2
C29A C 0.6393(4) 0.4332(5) 1.0558(2) 0.045(3) Uani 0.50 1 d PG A 2
H29A H 0.5798 0.4360 1.0894 0.054 Uiso 0.50 1 calc PR A 2
C30A C 0.5931(3) 0.3799(4) 0.9805(3) 0.039(3) Uani 0.50 1 d PG A 2
H30A H 0.5019 0.3462 0.9626 0.047 Uiso 0.50 1 calc PR A 2
C31 C 0.4812(6) 0.3558(4) 0.7933(3) 0.0333(14) Uani 1 1 d . A .
C32 C 0.5118(7) 0.4460(5) 0.7802(4) 0.0425(16) Uani 1 1 d . . .
H32 H 0.6025 0.4803 0.7901 0.051 Uiso 1 1 calc R A .
C33 C 0.4119(8) 0.4861(6) 0.7528(4) 0.053(2) Uani 1 1 d . A .
H33 H 0.4337 0.5483 0.7452 0.064 Uiso 1 1 calc R . .
C34 C 0.2808(9) 0.4361(7) 0.7367(4) 0.064(3) Uani 1 1 d . . .
H34 H 0.2120 0.4630 0.7163 0.077 Uiso 1 1 calc R A .
C35 C 0.2495(7) 0.3488(7) 0.7499(5) 0.065(3) Uani 1 1 d . A .
H35 H 0.1584 0.3156 0.7401 0.078 Uiso 1 1 calc R . .
C36 C 0.3488(6) 0.3059(6) 0.7779(4) 0.0494(18) Uani 1 1 d . . .
H36 H 0.3257 0.2440 0.7862 0.059 Uiso 1 1 calc R A .
C37 C 0.8608(5) 0.4193(4) 0.6878(3) 0.0278(12) Uani 1 1 d . A .
C38 C 0.8584(6) 0.4340(4) 0.6127(4) 0.0335(14) Uani 1 1 d . . .
H38 H 0.8027 0.3885 0.5692 0.040 Uiso 1 1 calc R A .
C39 C 0.9372(7) 0.5152(5) 0.6008(4) 0.0422(16) Uani 1 1 d . A .
H39 H 0.9360 0.5247 0.5490 0.051 Uiso 1 1 calc R . .
C40 C 1.0174(6) 0.5823(4) 0.6634(4) 0.0403(16) Uani 1 1 d . . .
H40 H 1.0728 0.6371 0.6547 0.048 Uiso 1 1 calc R A .
C41 C 1.0169(7) 0.5697(5) 0.7375(5) 0.0486(18) Uani 1 1 d . A .
H41 H 1.0697 0.6168 0.7808 0.058 Uiso 1 1 calc R . .
C42 C 0.9394(6) 0.4882(4) 0.7502(4) 0.0372(14) Uani 1 1 d . . .
H42 H 0.9402 0.4797 0.8022 0.045 Uiso 1 1 calc R A .
C43 C 0.8681(5) 0.2327(4) 0.7115(3) 0.0253(12) Uani 1 1 d . A .
C44 C 0.9058(6) 0.1969(4) 0.6452(4) 0.0328(13) Uani 1 1 d . . .
H44 H 0.8784 0.2154 0.5972 0.039 Uiso 1 1 calc R A .
C45 C 0.9820(6) 0.1353(5) 0.6491(4) 0.0412(16) Uani 1 1 d . A .
H45 H 1.0102 0.1135 0.6038 0.049 Uiso 1 1 calc R . .
C46 C 1.0184(8) 0.1045(6) 0.7150(5) 0.063(2) Uani 1 1 d . . .
H46 H 1.0679 0.0592 0.7155 0.076 Uiso 1 1 calc R A .
C47 C 0.9827(9) 0.1396(6) 0.7822(5) 0.068(3) Uani 1 1 d . A .
H47 H 1.0102 0.1198 0.8296 0.081 Uiso 1 1 calc R . .
C48 C 0.9074(7) 0.2032(5) 0.7804(4) 0.0473(18) Uani 1 1 d . . .
H48 H 0.8825 0.2267 0.8264 0.057 Uiso 1 1 calc R A .
O1 O 0.797(3) 0.664(3) 0.873(3) 0.115(7) Uani 0.50 1 d P B 1
C50 C 0.704(2) 0.7097(16) 0.9055(15) 0.080(6) Uani 0.50 1 d P B 1
H50A H 0.6271 0.6636 0.9135 0.096 Uiso 0.50 1 calc PR B 1
H50B H 0.6706 0.7497 0.8712 0.096 Uiso 0.50 1 calc PR B 1
C51 C 0.791(4) 0.766(2) 0.9818(19) 0.107(9) Uani 0.50 1 d P B 1
H51A H 0.7395 0.7708 1.0225 0.129 Uiso 0.50 1 calc PR B 1
H51B H 0.8348 0.8294 0.9761 0.129 Uiso 0.50 1 calc PR B 1
C52 C 0.897(3) 0.709(2) 1.0021(19) 0.105(9) Uani 0.50 1 d P B 1
H52A H 0.9888 0.7503 1.0201 0.126 Uiso 0.50 1 calc PR B 1
H52B H 0.8771 0.6729 1.0425 0.126 Uiso 0.50 1 calc PR B 1
C53 C 0.879(3) 0.649(2) 0.9276(19) 0.095(9) Uani 0.50 1 d P B 1
H53A H 0.9662 0.6575 0.9134 0.114 Uiso 0.50 1 calc PR B 1
H53B H 0.8484 0.5841 0.9330 0.114 Uiso 0.50 1 calc PR B 1
C57 C 0.757(5) 0.671(5) 0.888(5) 0.115(7) Uani 0.50 1 d P C 2
H57A H 0.7307 0.7143 0.8546 0.139 Uiso 0.50 1 calc PR C 2
H57B H 0.7478 0.6107 0.8536 0.139 Uiso 0.50 1 calc PR C 2
C54 C 0.680(2) 0.6601(18) 0.9428(18) 0.097(7) Uani 0.50 1 d P C 2
H54A H 0.6649 0.5960 0.9525 0.117 Uiso 0.50 1 calc PR C 2
H54B H 0.5927 0.6720 0.9237 0.117 Uiso 0.50 1 calc PR C 2
C55 C 0.754(3) 0.727(2) 1.015(2) 0.114(11) Uani 0.50 1 d P C 2
H55A H 0.7662 0.6953 1.0597 0.136 Uiso 0.50 1 calc PR C 2
H55B H 0.7061 0.7747 1.0267 0.136 Uiso 0.50 1 calc PR C 2
C56 C 0.895(3) 0.774(3) 0.9987(18) 0.110(11) Uani 0.50 1 d P C 2
H56A H 0.8970 0.8351 0.9847 0.132 Uiso 0.50 1 calc PR C 2
H56B H 0.9687 0.7812 1.0448 0.132 Uiso 0.50 1 calc PR C 2
O2 O 0.904(2) 0.7123(19) 0.9379(19) 0.132(10) Uani 0.50 1 d P C 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Te Te -0.5308 1.6751 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Te3 Ag1 Te4 111.93(3) . . ?
Te3 Ag1 Te1 124.08(3) . . ?
Te4 Ag1 Te1 99.55(3) . . ?
Te3 Ag1 Te2 111.01(3) . . ?
Te4 Ag1 Te2 116.10(3) . . ?
Te1 Ag1 Te2 93.11(3) . . ?
Te3 Ag1 Ag2 150.35(2) . . ?
Te4 Ag1 Ag2 53.72(3) . . ?
Te1 Ag1 Ag2 85.43(3) . . ?
Te2 Ag1 Ag2 65.49(3) . . ?
Te4 Ag2 Te1 151.02(3) . 2_656 ?
Te4 Ag2 Te2 100.38(4) . 2_656 ?
Te1 Ag2 Te2 93.42(3) 2_656 2_656 ?
Te4 Ag2 Ag2 117.43(3) . 2_656 ?
Te1 Ag2 Ag2 91.29(3) 2_656 2_656 ?
Te2 Ag2 Ag2 68.48(4) 2_656 2_656 ?
Te4 Ag2 Ag1 55.20(2) . . ?
Te1 Ag2 Ag1 139.50(3) 2_656 . ?
Te2 Ag2 Ag1 113.78(3) 2_656 . ?
Ag2 Ag2 Ag1 73.22(4) 2_656 . ?
P1 Te1 Ag2 86.93(4) . 2_656 ?
P1 Te1 Ag1 100.46(5) . . ?
Ag2 Te1 Ag1 81.44(3) 2_656 . ?
P2 Te2 Ag1 96.71(4) . . ?
P2 Te2 Ag2 83.67(5) . 2_656 ?
Ag1 Te2 Ag2 79.59(3) . 2_656 ?
P3 Te3 Ag1 94.18(5) . . ?
P4 Te4 Ag2 110.64(5) . . ?
P4 Te4 Ag1 88.75(5) . . ?
Ag2 Te4 Ag1 71.07(2) . . ?
N1 P1 C1 107.7(2) . . ?
N1 P1 C7 110.8(3) . . ?
C1 P1 C7 104.4(3) . . ?
N1 P1 Te1 116.17(18) . . ?
C1 P1 Te1 104.47(18) . . ?
C7 P1 Te1 112.24(19) . . ?
N1 P2 C19 105.0(2) . . ?
N1 P2 C13 109.6(3) . . ?
C19 P2 C13 104.3(3) . . ?
N1 P2 Te2 120.65(18) . . ?
C19 P2 Te2 105.80(19) . . ?
C13 P2 Te2 110.1(2) . . ?
N2 P3 C25A 102.8(2) . . ?
N2 P3 C31 109.3(3) . . ?
C25A P3 C31 103.4(2) . . ?
N2 P3 C25 104.2(2) . . ?
C25A P3 C25 3.4 . . ?
C31 P3 C25 105.7(2) . . ?
N2 P3 Te3 117.01(18) . . ?
C25A P3 Te3 109.80(18) . . ?
C31 P3 Te3 113.2(2) . . ?
C25 P3 Te3 106.46(18) . . ?
N2 P4 C43 110.3(3) . . ?
N2 P4 C37 104.1(3) . . ?
C43 P4 C37 107.3(3) . . ?
N2 P4 Te4 118.97(18) . . ?
C43 P4 Te4 107.51(18) . . ?
C37 P4 Te4 108.14(19) . . ?
P2 N1 P1 132.4(3) . . ?
P4 N2 P3 132.4(3) . . ?
C6 C1 C2 119.7(5) . . ?
C6 C1 P1 119.2(4) . . ?
C2 C1 P1 121.0(4) . . ?
C1 C2 C3 118.9(5) . . ?
C1 C2 H2 120.5 . . ?
C3 C2 H2 120.5 . . ?
C4 C3 C2 120.4(5) . . ?
C4 C3 H3 119.8 . . ?
C2 C3 H3 119.8 . . ?
C3 C4 C5 121.8(5) . . ?
C3 C4 H4 119.1 . . ?
C5 C4 H4 119.1 . . ?
C4 C5 C6 118.9(5) . . ?
C4 C5 H5 120.5 . . ?
C6 C5 H5 120.5 . . ?
C1 C6 C5 120.2(5) . . ?
C1 C6 H6 119.9 . . ?
C5 C6 H6 119.9 . . ?
C8 C7 C12 119.5(6) . . ?
C8 C7 P1 119.9(4) . . ?
C12 C7 P1 120.4(5) . . ?
C7 C8 C9 120.4(6) . . ?
C7 C8 H8 119.8 . . ?
C9 C8 H8 119.8 . . ?
C10 C9 C8 119.6(7) . . ?
C10 C9 H9 120.2 . . ?
C8 C9 H9 120.2 . . ?
C9 C10 C11 121.1(7) . . ?
C9 C10 H10 119.5 . . ?
C11 C10 H10 119.5 . . ?
C10 C11 C12 118.7(7) . . ?
C10 C11 H11 120.7 . . ?
C12 C11 H11 120.7 . . ?
C7 C12 C11 120.8(7) . . ?
C7 C12 H12 119.6 . . ?
C11 C12 H12 119.6 . . ?
C18 C13 C14 118.6(6) . . ?
C18 C13 P2 117.9(5) . . ?
C14 C13 P2 123.6(5) . . ?
C15 C14 C13 120.2(7) . . ?
C15 C14 H14 119.9 . . ?
C13 C14 H14 119.9 . . ?
C14 C15 C16 120.8(7) . . ?
C14 C15 H15 119.6 . . ?
C16 C15 H15 119.6 . . ?
C15 C16 C17 119.2(6) . . ?
C15 C16 H16 120.4 . . ?
C17 C16 H16 120.4 . . ?
C18 C17 C16 120.3(7) . . ?
C18 C17 H17 119.9 . . ?
C16 C17 H17 119.9 . . ?
C17 C18 C13 121.0(7) . . ?
C17 C18 H18 119.5 . . ?
C13 C18 H18 119.5 . . ?
C24 C19 C20 118.9(5) . . ?
C24 C19 P2 122.0(4) . . ?
C20 C19 P2 119.1(4) . . ?
C21 C20 C19 118.7(6) . . ?
C21 C20 H20 120.6 . . ?
C19 C20 H20 120.6 . . ?
C22 C21 C20 120.8(6) . . ?
C22 C21 H21 119.6 . . ?
C20 C21 H21 119.6 . . ?
C23 C22 C21 119.7(6) . . ?
C23 C22 H22 120.2 . . ?
C21 C22 H22 120.2 . . ?
C22 C23 C24 120.4(6) . . ?
C22 C23 H23 119.8 . . ?
C24 C23 H23 119.8 . . ?
C19 C24 C23 121.5(6) . . ?
C19 C24 H24 119.3 . . ?
C23 C24 H24 119.3 . . ?
C26 C25 C30 120.0 . . ?
C26 C25 P3 118.0(2) . . ?
C30 C25 P3 122.0(2) . . ?
C25 C26 C27 120.0 . . ?
C25 C26 H26 120.0 . . ?
C27 C26 H26 120.0 . . ?
C28 C27 C26 120.0 . . ?
C28 C27 H27 120.0 . . ?
C26 C27 H27 120.0 . . ?
C27 C28 C29 120.0 . . ?
C27 C28 H28 120.0 . . ?
C29 C28 H28 120.0 . . ?
C28 C29 C30 120.0 . . ?
C28 C29 H29 120.0 . . ?
C30 C29 H29 120.0 . . ?
C29 C30 C25 120.0 . . ?
C29 C30 H30 120.0 . . ?
C25 C30 H30 120.0 . . ?
C26A C25A C30A 120.0 . . ?
C26A C25A P3 119.9(3) . . ?
C30A C25A P3 120.1(3) . . ?
C25A C26A C27A 120.0 . . ?
C25A C26A H26A 120.0 . . ?
C27A C26A H26A 120.0 . . ?
C26A C27A C28A 120.0 . . ?
C26A C27A H27A 120.0 . . ?
C28A C27A H27A 120.0 . . ?
C29A C28A C27A 120.0 . . ?
C29A C28A H28A 120.0 . . ?
C27A C28A H28A 120.0 . . ?
C30A C29A C28A 120.0 . . ?
C30A C29A H29A 120.0 . . ?
C28A C29A H29A 120.0 . . ?
C29A C30A C25A 120.0 . . ?
C29A C30A H30A 120.0 . . ?
C25A C30A H30A 120.0 . . ?
C36 C31 C32 119.3(6) . . ?
C36 C31 P3 123.2(6) . . ?
C32 C31 P3 117.5(5) . . ?
C33 C32 C31 120.6(7) . . ?
C33 C32 H32 119.7 . . ?
C31 C32 H32 119.7 . . ?
C34 C33 C32 119.9(8) . . ?
C34 C33 H33 120.0 . . ?
C32 C33 H33 120.0 . . ?
C35 C34 C33 120.1(7) . . ?
C35 C34 H34 120.0 . . ?
C33 C34 H34 120.0 . . ?
C34 C35 C36 121.5(8) . . ?
C34 C35 H35 119.3 . . ?
C36 C35 H35 119.3 . . ?
C31 C36 C35 118.5(8) . . ?
C31 C36 H36 120.7 . . ?
C35 C36 H36 120.7 . . ?
C38 C37 C42 118.8(6) . . ?
C38 C37 P4 122.7(5) . . ?
C42 C37 P4 118.5(5) . . ?
C37 C38 C39 119.9(6) . . ?
C37 C38 H38 120.0 . . ?
C39 C38 H38 120.0 . . ?
C40 C39 C38 120.7(6) . . ?
C40 C39 H39 119.7 . . ?
C38 C39 H39 119.7 . . ?
C41 C40 C39 119.7(6) . . ?
C41 C40 H40 120.2 . . ?
C39 C40 H40 120.2 . . ?
C40 C41 C42 120.2(7) . . ?
C40 C41 H41 119.9 . . ?
C42 C41 H41 119.9 . . ?
C37 C42 C41 120.6(6) . . ?
C37 C42 H42 119.7 . . ?
C41 C42 H42 119.7 . . ?
C48 C43 C44 118.7(5) . . ?
C48 C43 P4 120.0(4) . . ?
C44 C43 P4 121.3(4) . . ?
C45 C44 C43 120.0(6) . . ?
C45 C44 H44 120.0 . . ?
C43 C44 H44 120.0 . . ?
C46 C45 C44 122.0(7) . . ?
C46 C45 H45 119.0 . . ?
C44 C45 H45 119.0 . . ?
C45 C46 C47 119.1(6) . . ?
C45 C46 H46 120.5 . . ?
C47 C46 H46 120.5 . . ?
C48 C47 C46 120.2(7) . . ?
C48 C47 H47 119.9 . . ?
C46 C47 H47 119.9 . . ?
C47 C48 C43 120.0(6) . . ?
C47 C48 H48 120.0 . . ?
C43 C48 H48 120.0 . . ?
C53 O1 C50 110(4) . . ?
O1 C50 C51 102(3) . . ?
O1 C50 H50A 111.4 . . ?
C51 C50 H50A 111.4 . . ?
O1 C50 H50B 111.4 . . ?
C51 C50 H50B 111.4 . . ?
H50A C50 H50B 109.3 . . ?
C50 C51 C52 103(2) . . ?
C50 C51 H51A 111.2 . . ?
C52 C51 H51A 111.2 . . ?
C50 C51 H51B 111.2 . . ?
C52 C51 H51B 111.2 . . ?
H51A C51 H51B 109.1 . . ?
C53 C52 C51 101(2) . . ?
C53 C52 H52A 111.5 . . ?
C51 C52 H52A 111.5 . . ?
C53 C52 H52B 111.5 . . ?
C51 C52 H52B 111.5 . . ?
H52A C52 H52B 109.3 . . ?
O1 C53 C52 114(3) . . ?
O1 C53 H53A 108.7 . . ?
C52 C53 H53A 108.7 . . ?
O1 C53 H53B 108.7 . . ?
C52 C53 H53B 108.7 . . ?
H53A C53 H53B 107.6 . . ?
C54 C57 O2 104(5) . . ?
C54 C57 H57A 110.9 . . ?
O2 C57 H57A 110.9 . . ?
C54 C57 H57B 110.9 . . ?
O2 C57 H57B 110.9 . . ?
H57A C57 H57B 108.9 . . ?
C57 C54 C55 107(4) . . ?
C57 C54 H54A 110.3 . . ?
C55 C54 H54A 110.3 . . ?
C57 C54 H54B 110.3 . . ?
C55 C54 H54B 110.3 . . ?
H54A C54 H54B 108.5 . . ?
C54 C55 C56 106(2) . . ?
C54 C55 H55A 110.6 . . ?
C56 C55 H55A 110.6 . . ?
C54 C55 H55B 110.6 . . ?
C56 C55 H55B 110.6 . . ?
H55A C55 H55B 108.7 . . ?
O2 C56 C55 103(3) . . ?
O2 C56 H56A 111.2 . . ?
C55 C56 H56A 111.2 . . ?
O2 C56 H56B 111.2 . . ?
C55 C56 H56B 111.2 . . ?
H56A C56 H56B 109.1 . . ?
C56 O2 C57 105(3) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Te3 2.7918(10) . ?
Ag1 Te4 2.8156(10) . ?
Ag1 Te1 2.8804(14) . ?
Ag1 Te2 2.8901(9) . ?
Ag1 Ag2 3.2434(10) . ?
Ag2 Te4 2.7642(10) . ?
Ag2 Te1 2.8273(10) 2_656 ?
Ag2 Te2 2.9275(12) 2_656 ?
Ag2 Ag2 2.9919(15) 2_656 ?
Te1 P1 2.4283(16) . ?
Te1 Ag2 2.8273(10) 2_656 ?
Te2 P2 2.4518(17) . ?
Te2 Ag2 2.9275(12) 2_656 ?
Te3 P3 2.3839(16) . ?
Te4 P4 2.4341(18) . ?
P1 N1 1.605(4) . ?
P1 C1 1.805(5) . ?
P1 C7 1.819(6) . ?
P2 N1 1.603(5) . ?
P2 C19 1.807(5) . ?
P2 C13 1.816(6) . ?
P3 N2 1.601(5) . ?
P3 C25A 1.801(3) . ?
P3 C31 1.816(6) . ?
P3 C25 1.825(3) . ?
P4 N2 1.588(5) . ?
P4 C43 1.810(6) . ?
P4 C37 1.819(6) . ?
C1 C6 1.390(8) . ?
C1 C2 1.391(8) . ?
C2 C3 1.403(8) . ?
C2 H2 0.9500 . ?
C3 C4 1.346(8) . ?
C3 H3 0.9500 . ?
C4 C5 1.373(8) . ?
C4 H4 0.9500 . ?
C5 C6 1.393(9) . ?
C5 H5 0.9500 . ?
C6 H6 0.9500 . ?
C7 C8 1.382(8) . ?
C7 C12 1.383(9) . ?
C8 C9 1.384(9) . ?
C8 H8 0.9500 . ?
C9 C10 1.380(11) . ?
C9 H9 0.9500 . ?
C10 C11 1.383(11) . ?
C10 H10 0.9500 . ?
C11 C12 1.393(10) . ?
C11 H11 0.9500 . ?
C12 H12 0.9500 . ?
C13 C18 1.397(9) . ?
C13 C14 1.401(9) . ?
C14 C15 1.383(9) . ?
C14 H14 0.9500 . ?
C15 C16 1.389(12) . ?
C15 H15 0.9500 . ?
C16 C17 1.392(11) . ?
C16 H16 0.9500 . ?
C17 C18 1.378(9) . ?
C17 H17 0.9500 . ?
C18 H18 0.9500 . ?
C19 C24 1.375(8) . ?
C19 C20 1.402(8) . ?
C20 C21 1.396(9) . ?
C20 H20 0.9500 . ?
C21 C22 1.390(11) . ?
C21 H21 0.9500 . ?
C22 C23 1.350(10) . ?
C22 H22 0.9500 . ?
C23 C24 1.382(8) . ?
C23 H23 0.9500 . ?
C24 H24 0.9500 . ?
C25 C26 1.3900 . ?
C25 C30 1.3900 . ?
C26 C27 1.3900 . ?
C26 H26 0.9500 . ?
C27 C28 1.3900 . ?
C27 H27 0.9500 . ?
C28 C29 1.3900 . ?
C28 H28 0.9500 . ?
C29 C30 1.3900 . ?
C29 H29 0.9500 . ?
C30 H30 0.9500 . ?
C25A C26A 1.3900 . ?
C25A C30A 1.3901 . ?
C26A C27A 1.3900 . ?
C26A H26A 0.9500 . ?
C27A C28A 1.3900 . ?
C27A H27A 0.9500 . ?
C28A C29A 1.3900 . ?
C28A H28A 0.9500 . ?
C29A C30A 1.3900 . ?
C29A H29A 0.9500 . ?
C30A H30A 0.9500 . ?
C31 C36 1.385(9) . ?
C31 C32 1.389(9) . ?
C32 C33 1.379(9) . ?
C32 H32 0.9500 . ?
C33 C34 1.373(12) . ?
C33 H33 0.9500 . ?
C34 C35 1.349(13) . ?
C34 H34 0.9500 . ?
C35 C36 1.405(11) . ?
C35 H35 0.9500 . ?
C36 H36 0.9500 . ?
C37 C38 1.380(8) . ?
C37 C42 1.386(8) . ?
C38 C39 1.385(9) . ?
C38 H38 0.9500 . ?
C39 C40 1.378(10) . ?
C39 H39 0.9500 . ?
C40 C41 1.359(10) . ?
C40 H40 0.9500 . ?
C41 C42 1.388(9) . ?
C41 H41 0.9500 . ?
C42 H42 0.9500 . ?
C43 C48 1.385(9) . ?
C43 C44 1.388(8) . ?
C44 C45 1.362(8) . ?
C44 H44 0.9500 . ?
C45 C46 1.344(11) . ?
C45 H45 0.9500 . ?
C46 C47 1.388(11) . ?
C46 H46 0.9500 . ?
C47 C48 1.378(10) . ?
C47 H47 0.9500 . ?
C48 H48 0.9500 . ?
O1 C53 1.25(6) . ?
O1 C50 1.48(3) . ?
C50 C51 1.50(4) . ?
C50 H50A 0.9900 . ?
C50 H50B 0.9900 . ?
C51 C52 1.58(4) . ?
C51 H51A 0.9900 . ?
C51 H51B 0.9900 . ?
C52 C53 1.44(5) . ?
C52 H52A 0.9900 . ?
C52 H52B 0.9900 . ?
C53 H53A 0.9900 . ?
C53 H53B 0.9900 . ?
C57 C54 1.39(6) . ?
C57 O2 1.57(7) . ?
C57 H57A 0.9900 . ?
C57 H57B 0.9900 . ?
C54 C55 1.47(4) . ?
C54 H54A 0.9900 . ?
C54 H54B 0.9900 . ?
C55 C56 1.60(5) . ?
C55 H55A 0.9900 . ?
C55 H55B 0.9900 . ?
C56 O2 1.35(4) . ?
C56 H56A 0.9900 . ?
C56 H56B 0.9900 . ?
