#------------------------------------------------------------------------------
#$Date: 2016-02-16 03:10:39 +0200 (Tue, 16 Feb 2016) $
#$Revision: 176453 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/64/7006479.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7006479
loop_
_publ_author_name
'Mochida, Tomoyuki'
'Okazawa, Kazuya'
'Horikoshi, Ryo'
_publ_section_title
;
 Metal complexes from 1,1'-di(pyrazinyl)ferrocene: coordination
 polymers and bridged diferrocenes.
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              693
_journal_page_last               704
_journal_paper_doi               10.1039/b511286a
_journal_year                    2006
_chemical_formula_sum            'C42 H33 Ag2 Cl Fe N10 O6'
_chemical_formula_weight         1136.67
_chemical_name_systematic
;
?
;
_space_group_IT_number           9
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  'C -2yc'
_symmetry_space_group_name_H-M   'C 1 c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.0440(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   20.7418(10)
_cell_length_b                   13.2726(7)
_cell_length_c                   14.9841(7)
_cell_measurement_temperature    296(2)
_cell_volume                     4084.5(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 8.366
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0172
_diffrn_reflns_av_sigmaI/netI    0.0294
_diffrn_reflns_limit_h_max       26
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            15015
_diffrn_reflns_theta_full        28.34
_diffrn_reflns_theta_max         28.34
_diffrn_reflns_theta_min         1.83
_exptl_absorpt_coefficient_mu    1.770
_exptl_absorpt_correction_T_max  0.7185
_exptl_absorpt_correction_T_min  0.5379
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'SADABS;Sheldrick 1996'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.848
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             2264
_exptl_crystal_size_max          0.40
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.05
_refine_diff_density_max         1.444
_refine_diff_density_min         -0.677
_refine_diff_density_rms         0.098
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.50(2)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     527
_refine_ls_number_reflns         7337
_refine_ls_number_restraints     2
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0436
_refine_ls_R_factor_gt           0.0406
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0842P)²+0.6300P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1119
_refine_ls_wR_factor_ref         0.1152
_reflns_number_gt                6807
_reflns_number_total             7337
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b511286a.txt
_cod_data_source_block           6b
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      Cc
_cod_original_formula_sum        'C42 H33 Ag2 Cl Fe1 N10 O6'
_cod_database_code               7006479
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.95001(2) 0.28800(4) 0.55678(3) 0.06637(15) Uani 1 1 d . . .
Ag2 Ag 0.86409(2) 0.30291(3) 0.72290(3) 0.05713(12) Uani 1 1 d . . .
C1 C 0.8416(2) 0.6589(3) 0.4436(3) 0.0388(9) Uani 1 1 d . . .
C2 C 0.8856(2) 0.7174(4) 0.5044(4) 0.0487(11) Uani 1 1 d . . .
H2 H 0.9184 0.6923 0.5471 0.058 Uiso 1 1 calc R . .
C3 C 0.8704(3) 0.8213(5) 0.4883(5) 0.0610(15) Uani 1 1 d . . .
H3 H 0.8921 0.8757 0.5180 0.073 Uiso 1 1 calc R . .
C4 C 0.8163(3) 0.8270(4) 0.4189(5) 0.0593(15) Uani 1 1 d . . .
H4 H 0.7965 0.8861 0.3956 0.071 Uiso 1 1 calc R . .
C5 C 0.7973(3) 0.7270(4) 0.3904(4) 0.0479(11) Uani 1 1 d . . .
H5 H 0.7630 0.7093 0.3463 0.057 Uiso 1 1 calc R . .
C6 C 0.7415(3) 0.6577(4) 0.6046(4) 0.0457(11) Uani 1 1 d . . .
C7 C 0.7878(3) 0.7185(4) 0.6580(4) 0.0539(13) Uani 1 1 d . . .
H7 H 0.8227 0.6965 0.6992 0.065 Uiso 1 1 calc R . .
C8 C 0.7704(4) 0.8198(5) 0.6361(5) 0.0663(19) Uani 1 1 d . . .
H8 H 0.7917 0.8763 0.6626 0.080 Uiso 1 1 calc R . .
C9 C 0.7184(4) 0.8217(5) 0.5711(6) 0.070(2) Uani 1 1 d . . .
H9 H 0.6987 0.8797 0.5451 0.084 Uiso 1 1 calc R . .
C10 C 0.6981(3) 0.7208(4) 0.5482(5) 0.0592(15) Uani 1 1 d . . .
H10 H 0.6637 0.7007 0.5054 0.071 Uiso 1 1 calc R . .
C11 C 0.8377(2) 0.5501(4) 0.4359(3) 0.0384(9) Uani 1 1 d . . .
C12 C 0.7861(3) 0.4103(4) 0.3713(4) 0.0514(11) Uani 1 1 d . . .
H12 H 0.7521 0.3812 0.3329 0.062 Uiso 1 1 calc R . .
C13 C 0.8335(3) 0.3484(4) 0.4191(4) 0.0553(12) Uani 1 1 d . . .
H13 H 0.8309 0.2790 0.4105 0.066 Uiso 1 1 calc R . .
C14 C 0.8842(2) 0.4863(4) 0.4844(3) 0.0422(9) Uani 1 1 d . . .
H14 H 0.9179 0.5149 0.5237 0.051 Uiso 1 1 calc R . .
C15 C 0.7389(2) 0.5456(3) 0.6011(3) 0.0393(9) Uani 1 1 d . . .
C16 C 0.6887(3) 0.4035(5) 0.5473(4) 0.0565(12) Uani 1 1 d . . .
H16 H 0.6545 0.3711 0.5120 0.068 Uiso 1 1 calc R . .
C17 C 0.7370(3) 0.3452(4) 0.5953(4) 0.0531(12) Uani 1 1 d . . .
H17 H 0.7352 0.2754 0.5899 0.064 Uiso 1 1 calc R . .
C18 C 0.7860(2) 0.4886(4) 0.6521(3) 0.0436(10) Uani 1 1 d . . .
H18 H 0.8191 0.5207 0.6899 0.052 Uiso 1 1 calc R . .
C19 C 0.9921(2) -0.0407(4) 0.8691(3) 0.0402(9) Uani 1 1 d . . .
C20 C 0.9492(3) -0.1103(4) 0.8168(4) 0.0506(11) Uani 1 1 d . . .
H20 H 0.9135 -0.0933 0.7749 0.061 Uiso 1 1 calc R . .
C21 C 0.9706(3) -0.2087(4) 0.8400(5) 0.0535(13) Uani 1 1 d . . .
H21 H 0.9513 -0.2679 0.8162 0.064 Uiso 1 1 calc R . .
C22 C 1.0271(3) -0.2022(4) 0.9063(4) 0.0518(12) Uani 1 1 d . . .
H22 H 1.0511 -0.2563 0.9326 0.062 Uiso 1 1 calc R . .
C23 C 1.0403(3) -0.0987(4) 0.9253(3) 0.0443(10) Uani 1 1 d . . .
H23 H 1.0740 -0.0732 0.9666 0.053 Uiso 1 1 calc R . .
C24 C 1.0889(2) -0.0427(3) 0.7075(3) 0.0395(9) Uani 1 1 d . . .
C25 C 1.0470(3) -0.1115(4) 0.6582(3) 0.0473(10) Uani 1 1 d . . .
H25 H 1.0120 -0.0951 0.6148 0.057 Uiso 1 1 calc R . .
C26 C 1.0672(4) -0.2116(4) 0.6859(5) 0.0555(13) Uani 1 1 d . . .
H26 H 1.0476 -0.2714 0.6641 0.067 Uiso 1 1 calc R . .
C27 C 1.1216(3) -0.2023(4) 0.7517(5) 0.0549(14) Uani 1 1 d . . .
H27 H 1.1448 -0.2553 0.7814 0.066 Uiso 1 1 calc R . .
C28 C 1.1357(2) -0.0977(4) 0.7656(4) 0.0454(10) Uani 1 1 d . . .
H28 H 1.1696 -0.0707 0.8056 0.054 Uiso 1 1 calc R . .
C29 C 0.9891(2) 0.0685(4) 0.8668(3) 0.0379(8) Uani 1 1 d . . .
C30 C 1.0318(3) 0.2202(4) 0.9165(4) 0.0513(11) Uani 1 1 d . . .
H30 H 1.0620 0.2579 0.9543 0.062 Uiso 1 1 calc R . .
C31 C 0.9870(3) 0.2699(4) 0.8583(4) 0.0493(11) Uani 1 1 d . . .
H31 H 0.9883 0.3399 0.8557 0.059 Uiso 1 1 calc R . .
C32 C 0.9420(2) 0.1195(4) 0.8096(3) 0.0417(9) Uani 1 1 d . . .
H32 H 0.9101 0.0826 0.7738 0.050 Uiso 1 1 calc R . .
C33 C 1.0866(2) 0.0679(3) 0.7011(3) 0.0368(8) Uani 1 1 d . . .
C34 C 1.1290(3) 0.2219(4) 0.7399(4) 0.0528(12) Uani 1 1 d . . .
H34 H 1.1618 0.2610 0.7713 0.063 Uiso 1 1 calc R . .
C35 C 1.0795(3) 0.2691(4) 0.6874(4) 0.0489(11) Uani 1 1 d . . .
H35 H 1.0782 0.3391 0.6850 0.059 Uiso 1 1 calc R . .
C36 C 1.0367(2) 0.1163(4) 0.6447(3) 0.0439(10) Uani 1 1 d . . .
H36 H 1.0052 0.0776 0.6100 0.053 Uiso 1 1 calc R . .
C37 C 0.6554(3) 0.0251(5) 0.3823(4) 0.1104(14) Uani 1 1 d G . .
C38 C 0.5938(4) -0.0182(5) 0.3751(4) 0.1104(14) Uani 1 1 d G . .
H38 H 0.5762 -0.0498 0.3218 0.132 Uiso 1 1 calc R . .
C39 C 0.5586(3) -0.0141(5) 0.4474(5) 0.1104(14) Uani 1 1 d G . .
H39 H 0.5175 -0.0431 0.4426 0.132 Uiso 1 1 calc R . .
C40 C 0.5850(3) 0.0332(5) 0.5270(4) 0.1104(14) Uani 1 1 d G . .
H40 H 0.5615 0.0359 0.5754 0.132 Uiso 1 1 calc R . .
C41 C 0.6465(4) 0.0764(4) 0.5342(4) 0.1104(14) Uani 1 1 d G . .
H41 H 0.6642 0.1081 0.5874 0.132 Uiso 1 1 calc R . .
C42 C 0.6817(3) 0.0724(5) 0.4619(5) 0.1104(14) Uani 1 1 d G . .
H42 H 0.7229 0.1014 0.4667 0.132 Uiso 1 1 calc R . .
Cl1 Cl 0.6974(3) 0.0190(4) 0.2941(4) 0.194(2) Uani 1 1 d . . .
Fe2 Fe 1.04364(3) -0.12939(4) 0.79198(4) 0.03605(13) Uani 1 1 d . . .
Fe1 Fe 0.79202(3) 0.74523(5) 0.52590(5) 0.04296(16) Uani 1 1 d . . .
N1 N 0.7887(2) 0.5101(4) 0.3799(3) 0.0485(9) Uani 1 1 d . . .
N2 N 0.8818(2) 0.3861(3) 0.4761(3) 0.0473(9) Uani 1 1 d . . .
N3 N 0.6890(2) 0.5032(4) 0.5492(3) 0.0504(10) Uani 1 1 d . . .
N4 N 0.7850(2) 0.3873(3) 0.6483(3) 0.0436(8) Uani 1 1 d . . .
N5 N 1.0350(2) 0.1195(3) 0.9226(3) 0.0472(9) Uani 1 1 d . . .
N6 N 0.9407(2) 0.2199(3) 0.8041(3) 0.0428(8) Uani 1 1 d . . .
N7 N 1.1326(2) 0.1219(3) 0.7487(3) 0.0466(9) Uani 1 1 d . . .
N8 N 1.0331(2) 0.2158(3) 0.6394(3) 0.0495(10) Uani 1 1 d . . .
N9 N 0.8527(3) 0.0949(5) 0.5952(5) 0.0785(17) Uani 1 1 d . . .
N10 N 0.9542(2) 0.5150(3) 0.7185(3) 0.0486(9) Uani 1 1 d . . .
O1 O 0.8833(4) 0.0213(6) 0.6145(6) 0.117(2) Uani 1 1 d . . .
O2 O 0.8525(6) 0.1641(9) 0.5554(9) 0.196(6) Uani 1 1 d . . .
O3 O 0.8086(5) 0.1019(10) 0.6479(8) 0.161(4) Uani 1 1 d . . .
O4 O 0.9281(3) 0.5049(6) 0.7843(4) 0.097(2) Uani 1 1 d . . .
O5 O 0.9704(4) 0.4344(5) 0.6851(5) 0.112(2) Uani 1 1 d . . .
O6 O 0.9593(5) 0.5959(5) 0.6859(5) 0.132(3) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N2 Ag1 N8 167.94(18) . . ?
N2 Ag1 Ag2 90.33(11) . . ?
N8 Ag1 Ag2 93.76(11) . . ?
N6 Ag2 N4 176.83(15) . . ?
N6 Ag2 Ag1 87.81(10) . . ?
N4 Ag2 Ag1 95.32(11) . . ?
C2 C1 C5 108.2(5) . . ?
C2 C1 C11 128.1(5) . . ?
C5 C1 C11 123.7(5) . . ?
C2 C1 Fe1 69.1(3) . . ?
C5 C1 Fe1 69.5(3) . . ?
C11 C1 Fe1 125.0(3) . . ?
C1 C2 C3 108.2(5) . . ?
C1 C2 Fe1 70.3(3) . . ?
C3 C2 Fe1 70.2(3) . . ?
C4 C3 C2 107.9(6) . . ?
C4 C3 Fe1 69.7(3) . . ?
C2 C3 Fe1 69.1(3) . . ?
C3 C4 C5 109.0(5) . . ?
C3 C4 Fe1 69.8(3) . . ?
C5 C4 Fe1 69.8(3) . . ?
C4 C5 C1 106.7(5) . . ?
C4 C5 Fe1 69.5(3) . . ?
C1 C5 Fe1 69.4(3) . . ?
C7 C6 C10 109.0(5) . . ?
C7 C6 C15 127.5(5) . . ?
C10 C6 C15 123.5(6) . . ?
C7 C6 Fe1 68.9(3) . . ?
C10 C6 Fe1 69.8(3) . . ?
C15 C6 Fe1 124.5(3) . . ?
C6 C7 C8 106.2(6) . . ?
C6 C7 Fe1 70.5(3) . . ?
C8 C7 Fe1 69.7(4) . . ?
C9 C8 C7 109.7(6) . . ?
C9 C8 Fe1 70.5(4) . . ?
C7 C8 Fe1 69.4(3) . . ?
C8 C9 C10 109.5(6) . . ?
C8 C9 Fe1 70.6(4) . . ?
C10 C9 Fe1 70.2(3) . . ?
C6 C10 C9 105.6(7) . . ?
C6 C10 Fe1 69.6(3) . . ?
C9 C10 Fe1 68.7(3) . . ?
N1 C11 C14 119.4(5) . . ?
N1 C11 C1 118.4(4) . . ?
C14 C11 C1 122.1(4) . . ?
N1 C12 C13 121.3(5) . . ?
N2 C13 C12 121.5(5) . . ?
N2 C14 C11 122.5(5) . . ?
N3 C15 C18 121.6(4) . . ?
N3 C15 C6 117.7(5) . . ?
C18 C15 C6 120.6(5) . . ?
N3 C16 C17 123.2(6) . . ?
N4 C17 C16 120.6(5) . . ?
N4 C18 C15 121.3(4) . . ?
C23 C19 C20 107.5(5) . . ?
C23 C19 C29 125.0(4) . . ?
C20 C19 C29 127.4(5) . . ?
C23 C19 Fe2 69.4(3) . . ?
C20 C19 Fe2 69.8(3) . . ?
C29 C19 Fe2 125.7(3) . . ?
C21 C20 C19 108.2(5) . . ?
C21 C20 Fe2 69.9(3) . . ?
C19 C20 Fe2 69.2(3) . . ?
C20 C21 C22 108.4(5) . . ?
C20 C21 Fe2 70.2(3) . . ?
C22 C21 Fe2 68.9(3) . . ?
C23 C22 C21 108.3(5) . . ?
C23 C22 Fe2 70.1(3) . . ?
C21 C22 Fe2 70.3(3) . . ?
C22 C23 C19 107.6(5) . . ?
C22 C23 Fe2 69.2(3) . . ?
C19 C23 Fe2 69.6(2) . . ?
C25 C24 C28 108.1(4) . . ?
C25 C24 C33 127.2(4) . . ?
C28 C24 C33 124.7(4) . . ?
C25 C24 Fe2 69.7(3) . . ?
C28 C24 Fe2 70.2(3) . . ?
C33 C24 Fe2 126.2(3) . . ?
C24 C25 C26 108.5(5) . . ?
C24 C25 Fe2 70.1(3) . . ?
C26 C25 Fe2 69.8(3) . . ?
C27 C26 C25 107.2(5) . . ?
C27 C26 Fe2 70.2(3) . . ?
C25 C26 Fe2 68.8(3) . . ?
C26 C27 C28 108.5(5) . . ?
C26 C27 Fe2 69.8(3) . . ?
C28 C27 Fe2 69.6(3) . . ?
C24 C28 C27 107.7(5) . . ?
C24 C28 Fe2 69.3(2) . . ?
C27 C28 Fe2 69.6(3) . . ?
N5 C29 C32 120.8(4) . . ?
N5 C29 C19 117.4(4) . . ?
C32 C29 C19 121.8(4) . . ?
N5 C30 C31 123.6(5) . . ?
N6 C31 C30 121.1(5) . . ?
N6 C32 C29 122.1(5) . . ?
N7 C33 C36 119.7(4) . . ?
N7 C33 C24 119.4(4) . . ?
C36 C33 C24 120.8(4) . . ?
N7 C34 C35 123.0(5) . . ?
N8 C35 C34 120.2(5) . . ?
N8 C36 C33 121.7(5) . . ?
C38 C37 C42 120.0 . . ?
C38 C37 Cl1 119.3(5) . . ?
C42 C37 Cl1 120.7(5) . . ?
C39 C38 C37 120.0 . . ?
C38 C39 C40 120.0 . . ?
C41 C40 C39 120.0 . . ?
C40 C41 C42 120.0 . . ?
C41 C42 C37 120.0 . . ?
C25 Fe2 C24 40.2(2) . . ?
C25 Fe2 C22 156.8(2) . . ?
C24 Fe2 C22 159.7(2) . . ?
C25 Fe2 C26 41.3(2) . . ?
C24 Fe2 C26 68.7(2) . . ?
C22 Fe2 C26 119.2(2) . . ?
C25 Fe2 C28 67.8(2) . . ?
C24 Fe2 C28 40.49(19) . . ?
C22 Fe2 C28 122.1(2) . . ?
C26 Fe2 C28 68.2(2) . . ?
C25 Fe2 C27 68.0(3) . . ?
C24 Fe2 C27 68.35(19) . . ?
C22 Fe2 C27 104.9(2) . . ?
C26 Fe2 C27 40.0(3) . . ?
C28 Fe2 C27 40.8(2) . . ?
C25 Fe2 C23 161.79(19) . . ?
C24 Fe2 C23 125.1(2) . . ?
C22 Fe2 C23 40.7(2) . . ?
C26 Fe2 C23 155.4(2) . . ?
C28 Fe2 C23 107.9(2) . . ?
C27 Fe2 C23 121.2(3) . . ?
C25 Fe2 C19 125.6(2) . . ?
C24 Fe2 C19 110.36(18) . . ?
C22 Fe2 C19 68.6(2) . . ?
C26 Fe2 C19 160.9(3) . . ?
C28 Fe2 C19 124.4(2) . . ?
C27 Fe2 C19 158.8(2) . . ?
C23 Fe2 C19 40.99(19) . . ?
C25 Fe2 C21 122.3(3) . . ?
C24 Fe2 C21 159.1(3) . . ?
C22 Fe2 C21 40.8(3) . . ?
C26 Fe2 C21 105.5(2) . . ?
C28 Fe2 C21 157.8(2) . . ?
C27 Fe2 C21 120.9(2) . . ?
C23 Fe2 C21 68.5(2) . . ?
C19 Fe2 C21 68.2(2) . . ?
C25 Fe2 C20 109.2(2) . . ?
C24 Fe2 C20 125.2(2) . . ?
C22 Fe2 C20 68.3(3) . . ?
C26 Fe2 C20 122.9(3) . . ?
C28 Fe2 C20 161.1(2) . . ?
C27 Fe2 C20 157.2(2) . . ?
C23 Fe2 C20 68.7(2) . . ?
C19 Fe2 C20 40.9(2) . . ?
C21 Fe2 C20 40.0(2) . . ?
C7 Fe1 C9 67.9(3) . . ?
C7 Fe1 C8 41.0(3) . . ?
C9 Fe1 C8 38.9(3) . . ?
C7 Fe1 C2 107.1(3) . . ?
C9 Fe1 C2 156.8(3) . . ?
C8 Fe1 C2 122.6(3) . . ?
C7 Fe1 C6 40.7(2) . . ?
C9 Fe1 C6 67.8(2) . . ?
C8 Fe1 C6 67.6(2) . . ?
C2 Fe1 C6 124.2(2) . . ?
C7 Fe1 C10 68.9(3) . . ?
C9 Fe1 C10 41.1(3) . . ?
C8 Fe1 C10 67.7(3) . . ?
C2 Fe1 C10 160.5(2) . . ?
C6 Fe1 C10 40.5(2) . . ?
C7 Fe1 C4 154.6(3) . . ?
C9 Fe1 C4 105.9(3) . . ?
C8 Fe1 C4 118.9(2) . . ?
C2 Fe1 C4 68.3(2) . . ?
C6 Fe1 C4 161.9(3) . . ?
C10 Fe1 C4 123.6(3) . . ?
C7 Fe1 C3 119.8(3) . . ?
C9 Fe1 C3 120.4(2) . . ?
C8 Fe1 C3 104.8(3) . . ?
C2 Fe1 C3 40.7(2) . . ?
C6 Fe1 C3 157.6(3) . . ?
C10 Fe1 C3 158.2(3) . . ?
C4 Fe1 C3 40.4(3) . . ?
C7 Fe1 C1 125.5(2) . . ?
C9 Fe1 C1 160.1(3) . . ?
C8 Fe1 C1 160.8(3) . . ?
C2 Fe1 C1 40.6(2) . . ?
C6 Fe1 C1 111.61(18) . . ?
C10 Fe1 C1 125.1(2) . . ?
C4 Fe1 C1 68.2(2) . . ?
C3 Fe1 C1 68.3(2) . . ?
C7 Fe1 C5 163.2(2) . . ?
C9 Fe1 C5 122.2(3) . . ?
C8 Fe1 C5 155.0(3) . . ?
C2 Fe1 C5 69.0(2) . . ?
C6 Fe1 C5 127.1(2) . . ?
C10 Fe1 C5 108.9(3) . . ?
C4 Fe1 C5 40.7(2) . . ?
C3 Fe1 C5 68.6(3) . . ?
C1 Fe1 C5 41.07(19) . . ?
C12 N1 C11 118.3(5) . . ?
C13 N2 C14 116.9(5) . . ?
C13 N2 Ag1 120.7(4) . . ?
C14 N2 Ag1 122.3(4) . . ?
C16 N3 C15 115.9(5) . . ?
C17 N4 C18 117.3(4) . . ?
C17 N4 Ag2 123.3(4) . . ?
C18 N4 Ag2 119.3(3) . . ?
C30 N5 C29 115.6(4) . . ?
C32 N6 C31 116.8(5) . . ?
C32 N6 Ag2 123.3(4) . . ?
C31 N6 Ag2 119.7(3) . . ?
C33 N7 C34 117.4(5) . . ?
C35 N8 C36 118.0(5) . . ?
C35 N8 Ag1 121.8(3) . . ?
C36 N8 Ag1 120.2(4) . . ?
O2 N9 O1 142.0(13) . . ?
O2 N9 O3 108.9(12) . . ?
O1 N9 O3 108.3(9) . . ?
O6 N10 O4 121.1(7) . . ?
O6 N10 O5 124.3(7) . . ?
O4 N10 O5 114.4(7) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N2 2.164(4) . ?
Ag1 N8 2.196(5) . ?
Ag1 Ag2 3.2639(6) . ?
Ag2 N6 2.163(4) . ?
Ag2 N4 2.164(4) . ?
C1 C2 1.425(8) . ?
C1 C5 1.446(7) . ?
C1 C11 1.450(7) . ?
C1 Fe1 2.061(4) . ?
C2 C3 1.427(8) . ?
C2 Fe1 2.044(5) . ?
C3 C4 1.421(11) . ?
C3 Fe1 2.058(5) . ?
C4 C5 1.433(9) . ?
C4 Fe1 2.057(5) . ?
C5 Fe1 2.062(5) . ?
C6 C7 1.414(9) . ?
C6 C10 1.418(9) . ?
C6 C15 1.489(7) . ?
C6 Fe1 2.045(5) . ?
C7 C8 1.419(9) . ?
C7 Fe1 2.024(6) . ?
C8 C9 1.350(12) . ?
C8 Fe1 2.029(6) . ?
C9 C10 1.432(10) . ?
C9 Fe1 2.028(5) . ?
C10 Fe1 2.048(5) . ?
C11 N1 1.334(7) . ?
C11 C14 1.407(7) . ?
C12 N1 1.331(7) . ?
C12 C13 1.399(9) . ?
C13 N2 1.321(8) . ?
C14 N2 1.336(7) . ?
C15 N3 1.330(7) . ?
C15 C18 1.380(7) . ?
C16 N3 1.323(8) . ?
C16 C17 1.384(9) . ?
C17 N4 1.309(7) . ?
C18 N4 1.345(7) . ?
C19 C23 1.436(7) . ?
C19 C20 1.438(7) . ?
C19 C29 1.451(7) . ?
C19 Fe2 2.052(4) . ?
C20 C21 1.407(9) . ?
C20 Fe2 2.060(5) . ?
C21 C22 1.429(10) . ?
C21 Fe2 2.056(5) . ?
C22 C23 1.422(7) . ?
C22 Fe2 2.038(5) . ?
C23 Fe2 2.049(5) . ?
C24 C25 1.398(7) . ?
C24 C28 1.412(7) . ?
C24 C33 1.472(6) . ?
C24 Fe2 2.035(4) . ?
C25 C26 1.436(8) . ?
C25 Fe2 2.029(5) . ?
C26 C27 1.398(10) . ?
C26 Fe2 2.042(5) . ?
C27 C28 1.427(7) . ?
C27 Fe2 2.047(5) . ?
C28 Fe2 2.047(5) . ?
C29 N5 1.357(6) . ?
C29 C32 1.383(7) . ?
C30 N5 1.340(7) . ?
C30 C31 1.355(8) . ?
C31 N6 1.343(8) . ?
C32 N6 1.335(6) . ?
C33 N7 1.320(6) . ?
C33 C36 1.398(7) . ?
C34 N7 1.335(7) . ?
C34 C35 1.356(9) . ?
C35 N8 1.323(8) . ?
C36 N8 1.324(7) . ?
C37 C38 1.3900 . ?
C37 C42 1.3900 . ?
C37 Cl1 1.684(7) . ?
C38 C39 1.3900 . ?
C39 C40 1.3900 . ?
C40 C41 1.3900 . ?
C41 C42 1.3900 . ?
N9 O2 1.095(11) . ?
N9 O1 1.180(9) . ?
N9 O3 1.291(13) . ?
N10 O6 1.190(7) . ?
N10 O4 1.196(7) . ?
N10 O5 1.248(7) . ?
