#------------------------------------------------------------------------------
#$Date: 2016-03-25 11:23:56 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179788 $
#$URL: svn://www.crystallography.net/cod/cif/7/00/84/7008491.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7008491
loop_
_publ_author_name
'Jones, Peter G.'
'Wölper, Christoph'
_publ_section_title
;
 New stoichiometries from an old system: amine complexes of silver
 chloride.
;
_journal_issue                   10
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1762
_journal_page_last               1763
_journal_paper_doi               10.1039/b503634h
_journal_year                    2005
_chemical_formula_sum            'C24 H52 Ag5 Cl5 N4'
_chemical_formula_weight         1113.30
_chemical_name_systematic
;
?
;
_space_group_IT_number           85
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  '-P 4a'
_symmetry_space_group_name_H-M   'P 4/n :2'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   17.2444(8)
_cell_length_b                   17.2444(8)
_cell_length_c                   6.0965(4)
_cell_measurement_reflns_used    8792
_cell_measurement_temperature    133(2)
_cell_measurement_theta_max      60.4
_cell_measurement_theta_min      2.4
_cell_volume                     1812.91(17)
_computing_cell_refinement       'BRUKER SAINT'
_computing_data_collection       'BRUKER SMART'
_computing_data_reduction        'BRUKER SAINT'
_computing_molecular_graphics    'SIEMENS XP'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      133(2)
_diffrn_detector_area_resol_mean 8.192
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART 1000 CCD'
_diffrn_measurement_method       'ω & φ scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0248
_diffrn_reflns_av_sigmaI/netI    0.0103
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       8
_diffrn_reflns_limit_l_min       -8
_diffrn_reflns_number            33360
_diffrn_reflns_theta_full        30.00
_diffrn_reflns_theta_max         30.54
_diffrn_reflns_theta_min         2.36
_exptl_absorpt_coefficient_mu    3.042
_exptl_absorpt_correction_T_max  0.7116
_exptl_absorpt_correction_T_min  0.3990
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.039
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1088
_exptl_crystal_size_max          0.37
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.738
_refine_diff_density_min         -0.520
_refine_diff_density_rms         0.065
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    'NH free, rigid methyl, others riding'
_refine_ls_matrix_type           full
_refine_ls_number_parameters     93
_refine_ls_number_reflns         2765
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.047
_refine_ls_R_factor_all          0.0215
_refine_ls_R_factor_gt           0.0180
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0195P)²+1.3749P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0427
_refine_ls_wR_factor_ref         0.0443
_reflns_number_gt                2503
_reflns_number_total             2765
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b503634h.txt
_cod_data_source_block           flea
_cod_original_sg_symbol_H-M      'P 4/n'
_cod_database_code               7008491
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y+1/2, z'
'-y+1/2, x, z'
'y, -x+1/2, z'
'-x, -y, -z'
'x-1/2, y-1/2, -z'
'y-1/2, -x, -z'
'-y, x-1/2, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.2500 0.2500 0.27994(4) 0.02807(6) Uani 1 4 d S . .
Ag2 Ag 0.237204(8) 0.395826(8) 0.63176(2) 0.03151(5) Uani 1 1 d . . .
Cl1 Cl 0.2500 0.2500 -0.14901(12) 0.02174(13) Uani 1 4 d S . .
Cl2 Cl 0.33685(2) 0.38371(2) 0.35277(6) 0.02792(8) Uani 1 1 d . . .
N11 N 0.17441(9) 0.44210(8) 0.9201(2) 0.0272(3) Uani 1 1 d . . .
H11 H 0.1761(13) 0.4086(13) 1.006(4) 0.036(6) Uiso 1 1 d . . .
C12 C 0.20926(11) 0.51126(10) 1.0223(3) 0.0311(3) Uani 1 1 d . . .
H12A H 0.2640 0.5006 1.0604 0.037 Uiso 1 1 calc R . .
H12B H 0.1811 0.5243 1.1589 0.037 Uiso 1 1 calc R . .
C13 C 0.20495(11) 0.57896(10) 0.8634(3) 0.0337(4) Uani 1 1 d . . .
H13A H 0.2367 0.5671 0.7323 0.040 Uiso 1 1 calc R . .
H13B H 0.2269 0.6257 0.9341 0.040 Uiso 1 1 calc R . .
C14 C 0.12182(11) 0.59574(10) 0.7922(3) 0.0328(4) Uani 1 1 d . . .
H14 H 0.0924 0.6140 0.9238 0.039 Uiso 1 1 calc R . .
C15 C 0.08361(10) 0.52184(11) 0.7097(3) 0.0335(4) Uani 1 1 d . . .
H15A H 0.0279 0.5319 0.6826 0.040 Uiso 1 1 calc R . .
H15B H 0.1076 0.5066 0.5687 0.040 Uiso 1 1 calc R . .
C16 C 0.09162(10) 0.45567(11) 0.8724(3) 0.0340(4) Uani 1 1 d . . .
H16A H 0.0638 0.4687 1.0096 0.041 Uiso 1 1 calc R . .
H16B H 0.0682 0.4080 0.8105 0.041 Uiso 1 1 calc R . .
C17 C 0.11817(15) 0.65940(13) 0.6188(4) 0.0504(6) Uani 1 1 d . . .
H17A H 0.1436 0.7062 0.6748 0.061 Uiso 1 1 calc R . .
H17B H 0.0639 0.6710 0.5846 0.061 Uiso 1 1 calc R . .
H17C H 0.1448 0.6419 0.4857 0.061 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
Cl1 Ag1 Cl2 99.174(10) . 4 ?
Cl1 Ag1 Cl2 99.173(10) . 2 ?
Cl2 Ag1 Cl2 88.544(3) 4 2 ?
Cl1 Ag1 Cl2 99.173(10) . 3 ?
Cl2 Ag1 Cl2 161.653(19) 4 3 ?
Cl2 Ag1 Cl2 88.543(3) 2 3 ?
Cl1 Ag1 Cl2 99.174(10) . . ?
Cl2 Ag1 Cl2 88.545(3) 4 . ?
Cl2 Ag1 Cl2 161.65(2) 2 . ?
Cl2 Ag1 Cl2 88.543(3) 3 . ?
Cl1 Ag1 Ag2 130.353(5) . . ?
Cl2 Ag1 Ag2 111.111(10) 4 . ?
Cl2 Ag1 Ag2 119.303(11) 2 . ?
Cl2 Ag1 Ag2 55.485(9) 3 . ?
Cl2 Ag1 Ag2 45.901(9) . . ?
Cl1 Ag1 Ag2 130.353(5) . 4 ?
Cl2 Ag1 Ag2 45.902(8) 4 4 ?
Cl2 Ag1 Ag2 111.111(10) 2 4 ?
Cl2 Ag1 Ag2 119.304(11) 3 4 ?
Cl2 Ag1 Ag2 55.486(9) . 4 ?
Ag2 Ag1 Ag2 65.213(5) . 4 ?
Cl1 Ag1 Ag2 130.353(5) . 2 ?
Cl2 Ag1 Ag2 55.485(9) 4 2 ?
Cl2 Ag1 Ag2 45.901(8) 2 2 ?
Cl2 Ag1 Ag2 111.111(10) 3 2 ?
Cl2 Ag1 Ag2 119.305(11) . 2 ?
Ag2 Ag1 Ag2 99.294(10) . 2 ?
Ag2 Ag1 Ag2 65.213(5) 4 2 ?
Cl1 Ag1 Ag2 130.353(5) . 3 ?
Cl2 Ag1 Ag2 119.304(11) 4 3 ?
Cl2 Ag1 Ag2 55.485(9) 2 3 ?
Cl2 Ag1 Ag2 45.901(8) 3 3 ?
Cl2 Ag1 Ag2 111.110(10) . 3 ?
Ag2 Ag1 Ag2 65.212(5) . 3 ?
Ag2 Ag1 Ag2 99.294(9) 4 3 ?
Ag2 Ag1 Ag2 65.213(5) 2 3 ?
N11 Ag2 Cl2 159.07(4) . . ?
N11 Ag2 Cl1 89.06(4) . 1_556 ?
Cl2 Ag2 Cl1 101.388(14) . 1_556 ?
N11 Ag2 Cl2 104.03(4) . 3 ?
Cl2 Ag2 Cl2 93.922(18) . 3 ?
Cl1 Ag2 Cl2 91.228(13) 1_556 3 ?
N11 Ag2 Ag1 145.14(4) . . ?
Cl2 Ag2 Ag1 55.504(11) . . ?
Cl1 Ag2 Ag1 68.253(14) 1_556 . ?
Cl2 Ag2 Ag1 52.918(9) 3 . ?
Ag1 Cl1 Ag2 117.900(14) . 4_554 ?
Ag1 Cl1 Ag2 117.900(14) . 2_554 ?
Ag2 Cl1 Ag2 77.352(11) 4_554 2_554 ?
Ag1 Cl1 Ag2 117.900(14) . 1_554 ?
Ag2 Cl1 Ag2 77.352(11) 4_554 1_554 ?
Ag2 Cl1 Ag2 124.20(3) 2_554 1_554 ?
Ag1 Cl1 Ag2 117.900(14) . 3_554 ?
Ag2 Cl1 Ag2 124.20(3) 4_554 3_554 ?
Ag2 Cl1 Ag2 77.352(12) 2_554 3_554 ?
Ag2 Cl1 Ag2 77.352(12) 1_554 3_554 ?
Ag2 Cl2 Ag1 78.594(13) . . ?
Ag2 Cl2 Ag2 84.167(14) . 4 ?
Ag1 Cl2 Ag2 71.597(11) . 4 ?
C12 N11 C16 110.46(14) . . ?
C12 N11 Ag2 115.34(11) . . ?
C16 N11 Ag2 111.97(11) . . ?
N11 C12 C13 109.41(15) . . ?
C12 C13 C14 111.91(15) . . ?
C15 C14 C17 110.86(18) . . ?
C15 C14 C13 110.02(14) . . ?
C17 C14 C13 111.86(17) . . ?
C16 C15 C14 111.99(16) . . ?
N11 C16 C15 109.62(14) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 Cl1 2.6151(8) . ?
Ag1 Cl2 2.7850(4) 4 ?
Ag1 Cl2 2.7850(4) 2 ?
Ag1 Cl2 2.7850(4) 3 ?
Ag1 Cl2 2.7851(4) . ?
Ag1 Ag2 3.3125(3) . ?
Ag1 Ag2 3.3125(3) 4 ?
Ag1 Ag2 3.3125(3) 2 ?
Ag1 Ag2 3.3125(3) 3 ?
Ag2 N11 2.2132(14) . ?
Ag2 Cl2 2.4268(4) . ?
Ag2 Cl1 2.8564(4) 1_556 ?
Ag2 Cl2 2.8765(5) 3 ?
Cl1 Ag2 2.8564(4) 4_554 ?
Cl1 Ag2 2.8564(4) 2_554 ?
Cl1 Ag2 2.8564(4) 1_554 ?
Cl1 Ag2 2.8564(4) 3_554 ?
Cl2 Ag2 2.8766(4) 4 ?
N11 C12 1.474(2) . ?
N11 C16 1.476(2) . ?
C12 C13 1.519(2) . ?
C13 C14 1.525(3) . ?
C14 C15 1.520(3) . ?
C14 C17 1.525(3) . ?
C15 C16 1.518(3) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
N11 H11 Cl2 0.78(2) 2.66(2) 3.3553(15) 150(2) 3_556
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Cl1 Ag1 Ag2 N11 127.11(7) . . . . ?
Cl2 Ag1 Ag2 N11 -109.36(7) 4 . . . ?
Cl2 Ag1 Ag2 N11 -8.68(7) 2 . . . ?
Cl2 Ag1 Ag2 N11 56.40(7) 3 . . . ?
Cl2 Ag1 Ag2 N11 -175.03(7) . . . . ?
Ag2 Ag1 Ag2 N11 -109.97(7) 4 . . . ?
Ag2 Ag1 Ag2 N11 -52.89(7) 2 . . . ?
Ag2 Ag1 Ag2 N11 4.19(7) 3 . . . ?
Cl1 Ag1 Ag2 Cl2 -57.857(13) . . . . ?
Cl2 Ag1 Ag2 Cl2 65.667(6) 4 . . . ?
Cl2 Ag1 Ag2 Cl2 166.355(14) 2 . . . ?
Cl2 Ag1 Ag2 Cl2 -128.564(16) 3 . . . ?
Ag2 Ag1 Ag2 Cl2 65.066(13) 4 . . . ?
Ag2 Ag1 Ag2 Cl2 122.143(13) 2 . . . ?
Ag2 Ag1 Ag2 Cl2 179.221(13) 3 . . . ?
Cl1 Ag1 Ag2 Cl1 180.0 . . . 1_556 ?
Cl2 Ag1 Ag2 Cl1 -56.476(11) 4 . . 1_556 ?
Cl2 Ag1 Ag2 Cl1 44.212(11) 2 . . 1_556 ?
Cl2 Ag1 Ag2 Cl1 109.293(10) 3 . . 1_556 ?
Cl2 Ag1 Ag2 Cl1 -122.143(13) . . . 1_556 ?
Ag2 Ag1 Ag2 Cl1 -57.077(3) 4 . . 1_556 ?
Ag2 Ag1 Ag2 Cl1 0.0 2 . . 1_556 ?
Ag2 Ag1 Ag2 Cl1 57.078(3) 3 . . 1_556 ?
Cl1 Ag1 Ag2 Cl2 70.707(10) . . . 3 ?
Cl2 Ag1 Ag2 Cl2 -165.768(15) 4 . . 3 ?
Cl2 Ag1 Ag2 Cl2 -65.081(5) 2 . . 3 ?
Cl2 Ag1 Ag2 Cl2 128.564(16) . . . 3 ?
Ag2 Ag1 Ag2 Cl2 -166.370(11) 4 . . 3 ?
Ag2 Ag1 Ag2 Cl2 -109.292(10) 2 . . 3 ?
Ag2 Ag1 Ag2 Cl2 -52.215(10) 3 . . 3 ?
Cl2 Ag1 Cl1 Ag2 -38.021(9) 4 . . 4_554 ?
Cl2 Ag1 Cl1 Ag2 -128.021(9) 2 . . 4_554 ?
Cl2 Ag1 Cl1 Ag2 141.979(9) 3 . . 4_554 ?
Cl2 Ag1 Cl1 Ag2 51.980(9) . . . 4_554 ?
Ag2 Ag1 Cl1 Ag2 90.0 . . . 4_554 ?
Ag2 Ag1 Cl1 Ag2 0.0 4 . . 4_554 ?
Ag2 Ag1 Cl1 Ag2 -90.0 2 . . 4_554 ?
Ag2 Ag1 Cl1 Ag2 180.0 3 . . 4_554 ?
Cl2 Ag1 Cl1 Ag2 51.979(9) 4 . . 2_554 ?
Cl2 Ag1 Cl1 Ag2 -38.021(9) 2 . . 2_554 ?
Cl2 Ag1 Cl1 Ag2 -128.021(9) 3 . . 2_554 ?
Cl2 Ag1 Cl1 Ag2 141.980(9) . . . 2_554 ?
Ag2 Ag1 Cl1 Ag2 180.0 . . . 2_554 ?
Ag2 Ag1 Cl1 Ag2 90.0 4 . . 2_554 ?
Ag2 Ag1 Cl1 Ag2 0.0 2 . . 2_554 ?
Ag2 Ag1 Cl1 Ag2 -90.0 3 . . 2_554 ?
Cl2 Ag1 Cl1 Ag2 -128.022(9) 4 . . 1_554 ?
Cl2 Ag1 Cl1 Ag2 141.978(9) 2 . . 1_554 ?
Cl2 Ag1 Cl1 Ag2 51.979(9) 3 . . 1_554 ?
Cl2 Ag1 Cl1 Ag2 -38.020(9) . . . 1_554 ?
Ag2 Ag1 Cl1 Ag2 0.0 . . . 1_554 ?
Ag2 Ag1 Cl1 Ag2 -90.0 4 . . 1_554 ?
Ag2 Ag1 Cl1 Ag2 180.0 2 . . 1_554 ?
Ag2 Ag1 Cl1 Ag2 90.0 3 . . 1_554 ?
Cl2 Ag1 Cl1 Ag2 141.979(9) 4 . . 3_554 ?
Cl2 Ag1 Cl1 Ag2 51.979(9) 2 . . 3_554 ?
Cl2 Ag1 Cl1 Ag2 -38.021(9) 3 . . 3_554 ?
Cl2 Ag1 Cl1 Ag2 -128.020(9) . . . 3_554 ?
Ag2 Ag1 Cl1 Ag2 -90.0 . . . 3_554 ?
Ag2 Ag1 Cl1 Ag2 180.0 4 . . 3_554 ?
Ag2 Ag1 Cl1 Ag2 90.0 2 . . 3_554 ?
Ag2 Ag1 Cl1 Ag2 0.0 3 . . 3_554 ?
N11 Ag2 Cl2 Ag1 172.03(11) . . . . ?
Cl1 Ag2 Cl2 Ag1 53.346(14) 1_556 . . . ?
Cl2 Ag2 Cl2 Ag1 -38.701(11) 3 . . . ?
N11 Ag2 Cl2 Ag2 99.68(11) . . . 4 ?
Cl1 Ag2 Cl2 Ag2 -19.008(14) 1_556 . . 4 ?
Cl2 Ag2 Cl2 Ag2 -111.055(8) 3 . . 4 ?
Ag1 Ag2 Cl2 Ag2 -72.354(10) . . . 4 ?
Cl1 Ag1 Cl2 Ag2 139.185(8) . . . . ?
Cl2 Ag1 Cl2 Ag2 -121.757(9) 4 . . . ?
Cl2 Ag1 Cl2 Ag2 -40.811(8) 2 . . . ?
Cl2 Ag1 Cl2 Ag2 40.127(15) 3 . . . ?
Ag2 Ag1 Cl2 Ag2 -87.584(12) 4 . . . ?
Ag2 Ag1 Cl2 Ag2 -73.381(14) 2 . . . ?
Ag2 Ag1 Cl2 Ag2 -0.759(12) 3 . . . ?
Cl1 Ag1 Cl2 Ag2 -133.231(6) . . . 4 ?
Cl2 Ag1 Cl2 Ag2 -34.172(13) 4 . . 4 ?
Cl2 Ag1 Cl2 Ag2 46.773(6) 2 . . 4 ?
Cl2 Ag1 Cl2 Ag2 127.711(9) 3 . . 4 ?
Ag2 Ag1 Cl2 Ag2 87.584(12) . . . 4 ?
Ag2 Ag1 Cl2 Ag2 14.203(11) 2 . . 4 ?
Ag2 Ag1 Cl2 Ag2 86.826(11) 3 . . 4 ?
Cl2 Ag2 N11 C12 2.2(2) . . . . ?
Cl1 Ag2 N11 C12 122.85(11) 1_556 . . . ?
Cl2 Ag2 N11 C12 -146.12(11) 3 . . . ?
Ag1 Ag2 N11 C12 170.65(8) . . . . ?
Cl2 Ag2 N11 C16 129.63(12) . . . . ?
Cl1 Ag2 N11 C16 -109.70(11) 1_556 . . . ?
Cl2 Ag2 N11 C16 -18.67(12) 3 . . . ?
Ag1 Ag2 N11 C16 -61.90(14) . . . . ?
C16 N11 C12 C13 -62.28(18) . . . . ?
Ag2 N11 C12 C13 65.93(16) . . . . ?
N11 C12 C13 C14 57.20(19) . . . . ?
C12 C13 C14 C15 -51.7(2) . . . . ?
C12 C13 C14 C17 -175.41(17) . . . . ?
C17 C14 C15 C16 175.78(15) . . . . ?
C13 C14 C15 C16 51.52(19) . . . . ?
C12 N11 C16 C15 62.15(19) . . . . ?
Ag2 N11 C16 C15 -67.88(16) . . . . ?
C14 C15 C16 N11 -56.87(19) . . . . ?
