#------------------------------------------------------------------------------
#$Date: 2016-03-25 12:48:47 +0200 (Fri, 25 Mar 2016) $
#$Revision: 179816 $
#$URL: svn://www.crystallography.net/cod/cif/7/01/12/7011242.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7011242
loop_
_publ_author_name
'Elena V. Grachova'
'Peter Jutzi'
'Beate Neumann'
'Lars O. Schebaum'
'Hans-Georg Stammler'
'Sergey P. Tunik'
_publ_section_title
;
 Unusual selective substitution of triply bridging carbonyl ligands for
 GaCp* in Rh6(CO)16. Synthesis and structural characterization of the
 Rh6(μ3-CO)4 −x(μ3-GaCp*)x(CO)12 clusters, x = 1--4
;
_journal_issue                   3
_journal_name_full               'J. Chem. Soc., Dalton Trans.'
_journal_page_first              302
_journal_page_last               304
_journal_paper_doi               10.1039/b109327d
_journal_year                    2002
_chemical_formula_moiety         'C25 H15 Ga O15 Rh6'
_chemical_formula_sum            'C25 H15 Ga O15 Rh6'
_chemical_formula_weight         1242.55
_chemical_name_systematic        ?
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.2290(11)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.5540(3)
_cell_length_b                   15.5970(4)
_cell_length_c                   17.1100(5)
_cell_measurement_reflns_used    9576
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      30.034
_cell_measurement_theta_min      2.037
_cell_volume                     3315.72(15)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       KappaCCD
_computing_data_reduction
'Denzo and Scalepak (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'SHELXTL-PLUS (1990)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  KappaCCD
_diffrn_measurement_method       'CCD; rotation images; thick slices'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.090
_diffrn_reflns_av_sigmaI/netI    0.0651
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            68198
_diffrn_reflns_theta_full        29.99
_diffrn_reflns_theta_max         29.99
_diffrn_reflns_theta_min         2.10
_exptl_absorpt_coefficient_mu    3.779
_exptl_absorpt_correction_T_max  0.9283
_exptl_absorpt_correction_T_min  0.4641
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    2.489
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             2344
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.02
_refine_diff_density_max         1.548
_refine_diff_density_min         -1.472
_refine_diff_density_rms         0.219
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.038
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     429
_refine_ls_number_reflns         9563
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.038
_refine_ls_R_factor_all          0.0891
_refine_ls_R_factor_gt           0.0435
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0398P)²+9.0941P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0827
_refine_ls_wR_factor_ref         0.0986
_reflns_number_gt                6281
_reflns_number_total             9563
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b109327d.txt
_cod_data_source_block           compound1
_cod_depositor_comments
;
The following automatic conversions were performed:
'_atom_site_symetry_multiplicity' tag replaced with
'_atom_site_symmetry_multiplicity'.

Automatic conversion script
Id: cif_correct_tags 1440 2010-10-19 06:21:57Z saulius 

The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               7011242
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.79318(3) 0.17132(2) 0.18707(2) 0.01731(10) Uani 1 1 d . . .
Rh2 Rh 0.77636(3) 0.34976(2) 0.14949(2) 0.01664(10) Uani 1 1 d . . .
Rh3 Rh 0.74073(3) 0.22588(2) 0.02859(2) 0.01685(10) Uani 1 1 d . . .
Rh4 Rh 0.58881(3) 0.14882(3) 0.10896(2) 0.01838(10) Uani 1 1 d . . .
Rh5 Rh 0.62680(3) 0.27072(3) 0.22652(2) 0.01781(10) Uani 1 1 d . . .
Rh6 Rh 0.57213(3) 0.32051(3) 0.07065(2) 0.01785(10) Uani 1 1 d . . .
Ga1 Ga 0.92844(5) 0.25247(4) 0.11521(3) 0.02020(13) Uani 1 1 d . . .
O1 O 0.8764(3) 0.0025(2) 0.1328(2) 0.0310(10) Uani 1 1 d . . .
O2 O 0.9227(4) 0.1612(3) 0.3511(2) 0.0357(10) Uani 1 1 d . . .
O3 O 0.9163(3) 0.4155(2) 0.2965(2) 0.0294(9) Uani 1 1 d . . .
O4 O 0.8242(4) 0.4976(3) 0.0450(2) 0.0389(11) Uani 1 1 d . . .
O5 O 0.7864(3) 0.3498(3) -0.0989(2) 0.0324(10) Uani 1 1 d . . .
O6 O 0.8022(4) 0.0705(3) -0.0629(2) 0.0373(11) Uani 1 1 d . . .
O7 O 0.6340(3) 0.0819(2) 0.2824(2) 0.0252(9) Uani 1 1 d . . .
O8 O 0.5965(3) 0.4666(2) 0.1939(2) 0.0249(9) Uani 1 1 d . . .
O9 O 0.5156(3) 0.1901(2) -0.0667(2) 0.0240(8) Uani 1 1 d . . .
O10 O 0.6265(3) -0.0265(2) 0.0408(2) 0.0311(10) Uani 1 1 d . . .
O11 O 0.3530(4) 0.1173(3) 0.1230(3) 0.0501(13) Uani 1 1 d . . .
O12 O 0.7429(3) 0.3108(3) 0.3915(2) 0.0321(10) Uani 1 1 d . . .
O13 O 0.4033(4) 0.2780(4) 0.2743(3) 0.0605(15) Uani 1 1 d . . .
O14 O 0.5840(3) 0.4597(2) -0.0525(2) 0.0302(9) Uani 1 1 d . . .
O15 O 0.3297(4) 0.3370(3) 0.0665(3) 0.0472(12) Uani 1 1 d . . .
C1 C 0.8470(5) 0.0654(3) 0.1551(3) 0.0231(12) Uani 1 1 d . . .
C2 C 0.8777(5) 0.1685(3) 0.2889(3) 0.0246(12) Uani 1 1 d . . .
C3 C 0.8639(4) 0.3908(3) 0.2412(3) 0.0196(11) Uani 1 1 d . . .
C4 C 0.8096(4) 0.4417(4) 0.0856(3) 0.0233(12) Uani 1 1 d . . .
C5 C 0.7707(5) 0.3024(3) -0.0509(3) 0.0238(12) Uani 1 1 d . . .
C6 C 0.7812(5) 0.1277(4) -0.0269(3) 0.0231(12) Uani 1 1 d . . .
C7 C 0.6494(5) 0.1324(3) 0.2343(3) 0.0247(12) Uani 1 1 d . . .
C8 C 0.6241(5) 0.3997(4) 0.1732(3) 0.0237(12) Uani 1 1 d . . .
C9 C 0.5666(4) 0.2087(3) -0.0069(3) 0.0201(11) Uani 1 1 d . . .
C10 C 0.6110(5) 0.0374(3) 0.0686(3) 0.0227(12) Uani 1 1 d . . .
C11 C 0.4410(5) 0.1292(4) 0.1176(3) 0.0301(14) Uani 1 1 d . . .
C12 C 0.6992(4) 0.2969(3) 0.3296(3) 0.0219(11) Uani 1 1 d . . .
C13 C 0.4857(5) 0.2754(4) 0.2554(4) 0.0326(14) Uani 1 1 d . . .
C14 C 0.5780(4) 0.4073(3) -0.0074(3) 0.0232(12) Uani 1 1 d . . .
C15 C 0.4201(5) 0.3307(4) 0.0678(3) 0.0264(13) Uani 1 1 d . . .
C16 C 1.0661(4) 0.2844(3) 0.0501(3) 0.0216(11) Uani 1 1 d . . .
C17 C 1.0761(4) 0.1953(4) 0.0720(3) 0.0252(12) Uani 1 1 d . . .
C18 C 1.0994(5) 0.1920(4) 0.1556(3) 0.0261(12) Uani 1 1 d . . .
C19 C 1.1044(4) 0.2770(4) 0.1854(3) 0.0256(12) Uani 1 1 d . . .
C20 C 1.0843(4) 0.3345(4) 0.1201(3) 0.0258(13) Uani 1 1 d . . .
C21 C 1.0516(5) 0.3188(4) -0.0330(3) 0.0291(13) Uani 1 1 d . . .
H21A H 1.0105 0.3724 -0.0353 0.044 Uiso 1 1 calc R . .
H21B H 1.0127 0.2767 -0.0688 0.044 Uiso 1 1 calc R . .
H21C H 1.1223 0.3298 -0.0489 0.044 Uiso 1 1 calc R . .
C22 C 1.0713(5) 0.1213(4) 0.0157(3) 0.0260(12) Uani 1 1 d . . .
H22A H 1.1444 0.1053 0.0078 0.039 Uiso 1 1 calc R . .
H22B H 1.0299 0.1379 -0.0350 0.039 Uiso 1 1 calc R . .
H22C H 1.0363 0.0724 0.0375 0.039 Uiso 1 1 calc R . .
C23 C 1.1217(5) 0.1124(4) 0.2049(4) 0.0344(15) Uani 1 1 d . . .
H23A H 1.1950 0.1149 0.2336 0.052 Uiso 1 1 calc R . .
H23B H 1.1145 0.0619 0.1704 0.052 Uiso 1 1 calc R . .
H23C H 1.0702 0.1084 0.2426 0.052 Uiso 1 1 calc R . .
C24 C 1.1320(5) 0.3022(4) 0.2708(3) 0.0351(15) Uani 1 1 d . . .
H24A H 1.0909 0.2667 0.3031 0.053 Uiso 1 1 calc R . .
H24B H 1.1138 0.3627 0.2771 0.053 Uiso 1 1 calc R . .
H24C H 1.2091 0.2937 0.2878 0.053 Uiso 1 1 calc R . .
C25 C 1.0892(5) 0.4310(4) 0.1251(4) 0.0327(14) Uani 1 1 d . . .
H25A H 1.1645 0.4494 0.1359 0.049 Uiso 1 1 calc R . .
H25B H 1.0507 0.4505 0.1677 0.049 Uiso 1 1 calc R . .
H25C H 1.0556 0.4556 0.0749 0.049 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ga Ga 0.2307 1.6083 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Rh1 C2 93.9(2) . . ?
C1 Rh1 C7 102.3(2) . . ?
C2 Rh1 C7 92.1(2) . . ?
C1 Rh1 Ga1 90.25(17) . . ?
C2 Rh1 Ga1 97.43(17) . . ?
C7 Rh1 Ga1 163.67(15) . . ?
C1 Rh1 Rh4 95.46(17) . . ?
C2 Rh1 Rh4 143.37(17) . . ?
C7 Rh1 Rh4 51.27(14) . . ?
Ga1 Rh1 Rh4 117.82(2) . . ?
C1 Rh1 Rh5 150.85(18) . . ?
C2 Rh1 Rh5 97.53(17) . . ?
C7 Rh1 Rh5 50.70(14) . . ?
Ga1 Rh1 Rh5 114.55(2) . . ?
Rh4 Rh1 Rh5 60.200(15) . . ?
C1 Rh1 Rh3 91.70(16) . . ?
C2 Rh1 Rh3 154.95(17) . . ?
C7 Rh1 Rh3 110.47(14) . . ?
Ga1 Rh1 Rh3 58.119(17) . . ?
Rh4 Rh1 Rh3 59.851(14) . . ?
Rh5 Rh1 Rh3 89.140(16) . . ?
C1 Rh1 Rh2 143.36(16) . . ?
C2 Rh1 Rh2 103.99(16) . . ?
C7 Rh1 Rh2 108.55(14) . . ?
Ga1 Rh1 Rh2 56.278(17) . . ?
Rh4 Rh1 Rh2 88.921(16) . . ?
Rh5 Rh1 Rh2 58.272(14) . . ?
Rh3 Rh1 Rh2 59.444(13) . . ?
C4 Rh2 C3 94.2(2) . . ?
C4 Rh2 C8 96.3(2) . . ?
C3 Rh2 C8 98.4(2) . . ?
C4 Rh2 Ga1 94.77(18) . . ?
C3 Rh2 Ga1 91.54(16) . . ?
C8 Rh2 Ga1 164.46(15) . . ?
C4 Rh2 Rh5 147.76(18) . . ?
C3 Rh2 Rh5 96.32(16) . . ?
C8 Rh2 Rh5 52.00(15) . . ?
Ga1 Rh2 Rh5 115.27(2) . . ?
C4 Rh2 Rh6 96.30(16) . . ?
C3 Rh2 Rh6 148.15(16) . . ?
C8 Rh2 Rh6 50.56(14) . . ?
Ga1 Rh2 Rh6 117.34(2) . . ?
Rh5 Rh2 Rh6 60.485(15) . . ?
C4 Rh2 Rh3 96.94(16) . . ?
C3 Rh2 Rh3 148.44(15) . . ?
C8 Rh2 Rh3 109.50(14) . . ?
Ga1 Rh2 Rh3 58.210(17) . . ?
Rh5 Rh2 Rh3 89.820(16) . . ?
Rh6 Rh2 Rh3 59.279(14) . . ?
C4 Rh2 Rh1 148.83(17) . . ?
C3 Rh2 Rh1 97.33(15) . . ?
C8 Rh2 Rh1 110.40(15) . . ?
Ga1 Rh2 Rh1 56.164(18) . . ?
Rh5 Rh2 Rh1 59.108(14) . . ?
Rh6 Rh2 Rh1 88.997(16) . . ?
Rh3 Rh2 Rh1 59.762(14) . . ?
C5 Rh3 C6 93.1(2) . . ?
C5 Rh3 C9 99.8(2) . . ?
C6 Rh3 C9 95.2(2) . . ?
C5 Rh3 Ga1 92.97(17) . . ?
C6 Rh3 Ga1 97.22(17) . . ?
C9 Rh3 Ga1 161.67(14) . . ?
C5 Rh3 Rh6 95.12(17) . . ?
C6 Rh3 Rh6 145.88(17) . . ?
C9 Rh3 Rh6 50.81(13) . . ?
Ga1 Rh3 Rh6 115.31(2) . . ?
C5 Rh3 Rh4 148.39(18) . . ?
C6 Rh3 Rh4 98.61(17) . . ?
C9 Rh3 Rh4 50.10(13) . . ?
Ga1 Rh3 Rh4 114.35(2) . . ?
Rh6 Rh3 Rh4 59.729(15) . . ?
C5 Rh3 Rh2 93.94(16) . . ?
C6 Rh3 Rh2 152.78(16) . . ?
C9 Rh3 Rh2 109.46(14) . . ?
Ga1 Rh3 Rh2 56.178(17) . . ?
Rh6 Rh3 Rh2 59.274(14) . . ?
Rh4 Rh3 Rh2 88.939(16) . . ?
C5 Rh3 Rh1 146.96(16) . . ?
C6 Rh3 Rh1 101.15(16) . . ?
C9 Rh3 Rh1 108.28(14) . . ?
Ga1 Rh3 Rh1 55.981(17) . . ?
Rh6 Rh3 Rh1 89.594(16) . . ?
Rh4 Rh3 Rh1 58.507(14) . . ?
Rh2 Rh3 Rh1 60.794(14) . . ?
C10 Rh4 C11 94.4(2) . . ?
C10 Rh4 C9 93.8(2) . . ?
C11 Rh4 C9 98.1(2) . . ?
C10 Rh4 C7 101.6(2) . . ?
C11 Rh4 C7 96.3(2) . . ?
C9 Rh4 C7 158.0(2) . . ?
C10 Rh4 Rh1 96.79(16) . . ?
C11 Rh4 Rh1 146.71(18) . . ?
C9 Rh4 Rh1 112.27(15) . . ?
C7 Rh4 Rh1 50.70(16) . . ?
C10 Rh4 Rh6 144.04(15) . . ?
C11 Rh4 Rh6 97.61(18) . . ?
C9 Rh4 Rh6 50.98(14) . . ?
C7 Rh4 Rh6 110.55(14) . . ?
Rh1 Rh4 Rh6 91.459(17) . . ?
C10 Rh4 Rh5 150.92(15) . . ?
C11 Rh4 Rh5 97.02(17) . . ?
C9 Rh4 Rh5 110.81(14) . . ?
C7 Rh4 Rh5 50.65(14) . . ?
Rh1 Rh4 Rh5 60.276(15) . . ?
Rh6 Rh4 Rh5 60.230(14) . . ?
C10 Rh4 Rh3 93.92(17) . . ?
C11 Rh4 Rh3 148.43(19) . . ?
C9 Rh4 Rh3 50.98(15) . . ?
C7 Rh4 Rh3 111.67(16) . . ?
Rh1 Rh4 Rh3 61.642(15) . . ?
Rh6 Rh4 Rh3 59.773(14) . . ?
Rh5 Rh4 Rh3 90.196(17) . . ?
C13 Rh5 C12 95.1(2) . . ?
C13 Rh5 C7 98.0(2) . . ?
C12 Rh5 C7 96.6(2) . . ?
C13 Rh5 C8 96.5(2) . . ?
C12 Rh5 C8 99.4(2) . . ?
C7 Rh5 C8 157.3(2) . . ?
C13 Rh5 Rh2 146.54(19) . . ?
C12 Rh5 Rh2 94.59(16) . . ?
C7 Rh5 Rh2 112.55(16) . . ?
C8 Rh5 Rh2 50.30(15) . . ?
C13 Rh5 Rh4 98.35(19) . . ?
C12 Rh5 Rh4 146.19(16) . . ?
C7 Rh5 Rh4 50.90(14) . . ?
C8 Rh5 Rh4 109.62(13) . . ?
Rh2 Rh5 Rh4 91.044(17) . . ?
C13 Rh5 Rh1 148.0(2) . . ?
C12 Rh5 Rh1 93.99(16) . . ?
C7 Rh5 Rh1 50.39(16) . . ?
C8 Rh5 Rh1 112.20(15) . . ?
Rh2 Rh5 Rh1 62.621(15) . . ?
Rh4 Rh5 Rh1 59.524(15) . . ?
C13 Rh5 Rh6 97.34(18) . . ?
C12 Rh5 Rh6 148.16(16) . . ?
C7 Rh5 Rh6 110.43(14) . . ?
C8 Rh5 Rh6 50.13(13) . . ?
Rh2 Rh5 Rh6 60.148(15) . . ?
Rh4 Rh5 Rh6 59.857(14) . . ?
Rh1 Rh5 Rh6 90.796(17) . . ?
C15 Rh6 C14 93.5(2) . . ?
C15 Rh6 C8 99.1(2) . . ?
C14 Rh6 C8 97.2(2) . . ?
C15 Rh6 C9 96.1(2) . . ?
C14 Rh6 C9 98.2(2) . . ?
C8 Rh6 C9 157.7(2) . . ?
C15 Rh6 Rh4 97.40(17) . . ?
C14 Rh6 Rh4 147.67(16) . . ?
C8 Rh6 Rh4 110.92(14) . . ?
C9 Rh6 Rh4 50.53(13) . . ?
C15 Rh6 Rh2 148.73(17) . . ?
C14 Rh6 Rh2 95.64(16) . . ?
C8 Rh6 Rh2 50.14(16) . . ?
C9 Rh6 Rh2 112.04(14) . . ?
Rh4 Rh6 Rh2 90.617(17) . . ?
C15 Rh6 Rh3 147.08(17) . . ?
C14 Rh6 Rh3 95.09(17) . . ?
C8 Rh6 Rh3 111.25(16) . . ?
C9 Rh6 Rh3 51.25(14) . . ?
Rh4 Rh6 Rh3 60.499(15) . . ?
Rh2 Rh6 Rh3 61.447(15) . . ?
C15 Rh6 Rh5 99.06(17) . . ?
C14 Rh6 Rh5 147.48(16) . . ?
C8 Rh6 Rh5 51.39(14) . . ?
C9 Rh6 Rh5 110.04(13) . . ?
Rh4 Rh6 Rh5 59.913(14) . . ?
Rh2 Rh6 Rh5 59.368(14) . . ?
Rh3 Rh6 Rh5 90.433(17) . . ?
C16 Ga1 C17 37.19(19) . . ?
C16 Ga1 C20 36.11(18) . . ?
C17 Ga1 C20 60.5(2) . . ?
C16 Ga1 C18 60.02(19) . . ?
C17 Ga1 C18 35.69(19) . . ?
C20 Ga1 C18 58.9(2) . . ?
C16 Ga1 C19 59.40(19) . . ?
C17 Ga1 C19 59.2(2) . . ?
C20 Ga1 C19 35.16(19) . . ?
C18 Ga1 C19 34.8(2) . . ?
C16 Ga1 Rh1 163.14(14) . . ?
C17 Ga1 Rh1 126.03(14) . . ?
C20 Ga1 Rh1 149.68(14) . . ?
C18 Ga1 Rh1 107.41(14) . . ?
C19 Ga1 Rh1 117.74(14) . . ?
C16 Ga1 Rh2 129.22(14) . . ?
C17 Ga1 Rh2 166.41(14) . . ?
C20 Ga1 Rh2 108.38(14) . . ?
C18 Ga1 Rh2 147.58(14) . . ?
C19 Ga1 Rh2 116.99(14) . . ?
Rh1 Ga1 Rh2 67.557(19) . . ?
C16 Ga1 Rh3 116.57(14) . . ?
C17 Ga1 Rh3 117.46(14) . . ?
C20 Ga1 Rh3 141.89(15) . . ?
C18 Ga1 Rh3 143.84(15) . . ?
C19 Ga1 Rh3 175.94(14) . . ?
Rh1 Ga1 Rh3 65.900(19) . . ?
Rh2 Ga1 Rh3 65.612(19) . . ?
O1 C1 Rh1 176.9(5) . . ?
O2 C2 Rh1 174.1(5) . . ?
O3 C3 Rh2 179.8(6) . . ?
O4 C4 Rh2 176.3(5) . . ?
O5 C5 Rh3 178.2(5) . . ?
O6 C6 Rh3 176.8(5) . . ?
O7 C7 Rh1 132.7(5) . . ?
O7 C7 Rh5 132.4(4) . . ?
Rh1 C7 Rh5 78.91(19) . . ?
O7 C7 Rh4 134.2(4) . . ?
Rh1 C7 Rh4 78.03(19) . . ?
Rh5 C7 Rh4 78.46(18) . . ?
O8 C8 Rh2 133.5(4) . . ?
O8 C8 Rh6 133.2(4) . . ?
Rh2 C8 Rh6 79.30(19) . . ?
O8 C8 Rh5 132.5(4) . . ?
Rh2 C8 Rh5 77.70(19) . . ?
Rh6 C8 Rh5 78.48(18) . . ?
O9 C9 Rh4 132.7(4) . . ?
O9 C9 Rh6 134.3(4) . . ?
Rh4 C9 Rh6 78.49(17) . . ?
O9 C9 Rh3 132.3(4) . . ?
Rh4 C9 Rh3 78.92(17) . . ?
Rh6 C9 Rh3 77.94(18) . . ?
O10 C10 Rh4 175.9(5) . . ?
O11 C11 Rh4 179.7(7) . . ?
O12 C12 Rh5 178.5(5) . . ?
O13 C13 Rh5 178.4(6) . . ?
O14 C14 Rh6 178.1(5) . . ?
O15 C15 Rh6 179.6(6) . . ?
C20 C16 C17 108.3(5) . . ?
C20 C16 C21 125.7(5) . . ?
C17 C16 C21 125.7(5) . . ?
C20 C16 Ga1 75.3(3) . . ?
C17 C16 Ga1 72.6(3) . . ?
C21 C16 Ga1 123.4(4) . . ?
C18 C17 C16 107.1(5) . . ?
C18 C17 C22 127.1(5) . . ?
C16 C17 C22 125.6(5) . . ?
C18 C17 Ga1 75.3(3) . . ?
C16 C17 Ga1 70.2(3) . . ?
C22 C17 Ga1 123.5(4) . . ?
C19 C18 C17 108.7(5) . . ?
C19 C18 C23 125.2(5) . . ?
C17 C18 C23 126.1(5) . . ?
C19 C18 Ga1 73.9(3) . . ?
C17 C18 Ga1 69.0(3) . . ?
C23 C18 Ga1 125.7(4) . . ?
C18 C19 C20 108.2(5) . . ?
C18 C19 C24 125.8(5) . . ?
C20 C19 C24 126.0(5) . . ?
C18 C19 Ga1 71.3(3) . . ?
C20 C19 Ga1 70.1(3) . . ?
C24 C19 Ga1 126.7(4) . . ?
C16 C20 C19 107.7(5) . . ?
C16 C20 C25 126.7(5) . . ?
C19 C20 C25 125.5(5) . . ?
C16 C20 Ga1 68.6(3) . . ?
C19 C20 Ga1 74.7(3) . . ?
C25 C20 Ga1 125.2(4) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Rh1 C1 1.895(5) . ?
Rh1 C2 1.906(6) . ?
Rh1 C7 2.168(6) . ?
Rh1 Ga1 2.5680(7) . ?
Rh1 Rh4 2.7404(6) . ?
Rh1 Rh5 2.7614(6) . ?
Rh1 Rh3 2.8282(5) . ?
Rh1 Rh2 2.8574(5) . ?
Rh2 C4 1.886(6) . ?
Rh2 C3 1.894(5) . ?
Rh2 C8 2.155(6) . ?
Rh2 Ga1 2.5714(7) . ?
Rh2 Rh5 2.7370(6) . ?
Rh2 Rh6 2.7588(6) . ?
Rh2 Rh3 2.8190(5) . ?
Rh3 C5 1.887(6) . ?
Rh3 C6 1.909(6) . ?
Rh3 C9 2.200(5) . ?
Rh3 Ga1 2.6309(7) . ?
Rh3 Rh6 2.7589(6) . ?
Rh3 Rh4 2.7791(6) . ?
Rh4 C10 1.905(6) . ?
Rh4 C11 1.907(7) . ?
Rh4 C9 2.172(5) . ?
Rh4 C7 2.185(5) . ?
Rh4 Rh6 2.7577(6) . ?
Rh4 Rh5 2.7593(6) . ?
Rh5 C13 1.908(6) . ?
Rh5 C12 1.909(5) . ?
Rh5 C7 2.178(5) . ?
Rh5 C8 2.207(5) . ?
Rh5 Rh6 2.7681(6) . ?
Rh6 C15 1.909(6) . ?
Rh6 C14 1.909(6) . ?
Rh6 C8 2.168(5) . ?
Rh6 C9 2.187(5) . ?
Ga1 C16 2.242(5) . ?
Ga1 C17 2.273(6) . ?
Ga1 C20 2.329(6) . ?
Ga1 C18 2.355(6) . ?
Ga1 C19 2.390(5) . ?
O1 C1 1.134(6) . ?
O2 C2 1.137(7) . ?
O3 C3 1.139(6) . ?
O4 C4 1.146(6) . ?
O5 C5 1.143(6) . ?
O6 C6 1.136(6) . ?
O7 C7 1.174(6) . ?
O8 C8 1.170(6) . ?
O9 C9 1.163(6) . ?
O10 C10 1.134(6) . ?
O11 C11 1.137(7) . ?
O12 C12 1.142(6) . ?
O13 C13 1.127(7) . ?
O14 C14 1.135(6) . ?
O15 C15 1.135(7) . ?
C16 C20 1.419(7) . ?
C16 C17 1.440(8) . ?
C16 C21 1.507(7) . ?
C17 C18 1.420(8) . ?
C17 C22 1.499(8) . ?
C18 C19 1.419(8) . ?
C18 C23 1.504(8) . ?
C19 C20 1.426(8) . ?
C19 C24 1.504(8) . ?
C20 C25 1.508(8) . ?
