#------------------------------------------------------------------------------
#$Date: 2018-01-28 01:56:17 +0200 (Sun, 28 Jan 2018) $
#$Revision: 205782 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/01/21/7012190.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7012190
loop_
_publ_author_name
'Guzei, Ilia A.'
'Li, Kelin'
'Bikzhanova, Galina A.'
'Darkwa, James'
'Mapolie, Selwyn F.'
_publ_section_title
;
 Benzenedicarbonyl and benzenetricarbonyl linker pyrazolyl complexes of
 palladium(II): synthesis, X-ray structures and evaluation as ethylene
 polymerisation catalysts
;
_journal_coden_ASTM              DTARAF
_journal_issue                   4
_journal_name_full               'Dalton Transactions'
_journal_page_first              715
_journal_page_last               722
_journal_paper_doi               10.1039/b208376k
_journal_year                    2003
_chemical_formula_sum            'C19 H20 Cl6 N4 O2 Pd2'
_chemical_formula_weight         761.89
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.520(2)
_cell_angle_beta                 118.329(2)
_cell_angle_gamma                98.458(2)
_cell_formula_units_Z            2
_cell_length_a                   11.4285(11)
_cell_length_b                   11.5080(11)
_cell_length_c                   11.9381(12)
_cell_measurement_temperature    296(2)
_cell_volume                     1308.3(2)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.931
_diffrn_measured_fraction_theta_max 0.931
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0369
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            4790
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.87
_exptl_absorpt_coefficient_mu    2.012
_exptl_absorpt_correction_T_max  0.8888
_exptl_absorpt_correction_T_min  0.6332
_exptl_absorpt_correction_type   'Empirical with SADABS'
_exptl_crystal_density_diffrn    1.934
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             744
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.007
_refine_diff_density_min         -1.020
_refine_diff_density_rms         0.123
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.962
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     297
_refine_ls_number_reflns         4790
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      0.968
_refine_ls_R_factor_all          0.0525
_refine_ls_R_factor_gt           0.0407
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0781P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1065
_refine_ls_wR_factor_ref         0.1100
_reflns_number_gt                3727
_reflns_number_total             4790
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b208376k.txt
_cod_data_source_block           darp
_cod_depositor_comments
;
 Correcting the space group by changing it from 'C 1 2/c 1' to 'P -1'
 after consulting the original publication.

 Antanas Vaitkus,
 2018-01-28

The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7012190
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,-y,-z
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 0.91585(4) 0.54605(3) 0.64287(4) 0.03764(13) Uani 1 1 d . . .
Pd2 Pd 0.76653(4) 0.65501(3) 0.39837(4) 0.03587(13) Uani 1 1 d . . .
Cl1 Cl 0.82737(16) 0.38197(13) 0.68472(16) 0.0624(4) Uani 1 1 d . . .
Cl2 Cl 0.54772(14) 0.59083(12) 0.22018(14) 0.0546(4) Uani 1 1 d . . .
Cl3 Cl 0.99451(12) 0.70777(11) 0.57932(13) 0.0436(3) Uani 1 1 d . . .
Cl4 Cl 0.76399(13) 0.45952(11) 0.41753(13) 0.0461(3) Uani 1 1 d . . .
Cl5 Cl 0.6716(5) 0.8427(6) 0.9761(5) 0.1024(10) Uiso 0.601(7) 1 d PD A -1
Cl6 Cl 0.3848(5) 0.8087(6) 0.9137(7) 0.1290(14) Uiso 0.601(7) 1 d PD A -1
Cl5A Cl 0.6349(8) 0.7889(8) 0.9687(7) 0.1024(10) Uiso 0.399(7) 1 d PD A -2
Cl6A Cl 0.4038(8) 0.8603(10) 0.9629(10) 0.1290(14) Uiso 0.399(7) 1 d PD A -2
O1 O 0.4745(4) 0.8626(4) 0.3888(4) 0.0591(10) Uani 1 1 d . . .
O2 O 1.0391(4) 0.9296(3) 0.8854(4) 0.0633(11) Uani 1 1 d . . .
N3 N 0.7727(4) 0.8298(4) 0.3891(4) 0.0410(10) Uani 1 1 d . . .
N4 N 0.6791(4) 0.8896(4) 0.3947(4) 0.0415(10) Uani 1 1 d . . .
N2 N 1.0520(4) 0.7397(4) 0.9110(4) 0.0444(10) Uani 1 1 d . . .
N1 N 1.0463(4) 0.6273(4) 0.8408(4) 0.0413(10) Uani 1 1 d . . .
C1 C 1.1771(7) 0.4720(6) 0.8926(7) 0.0699(19) Uani 1 1 d . . .
H1A H 1.1143 0.4041 0.8891 0.105 Uiso 1 1 calc R . .
H1B H 1.2700 0.4758 0.9572 0.105 Uiso 1 1 calc R . .
H1C H 1.1679 0.4612 0.8068 0.105 Uiso 1 1 calc R . .
C2 C 1.1446(6) 0.5882(5) 0.9307(6) 0.0496(13) Uani 1 1 d . . .
C3 C 1.2092(6) 0.6734(5) 1.0548(5) 0.0524(14) Uani 1 1 d . . .
H3 H 1.2797 0.6664 1.1333 0.063 Uiso 1 1 calc R . .
C4 C 1.1526(6) 0.7679(5) 1.0420(5) 0.0490(13) Uani 1 1 d . . .
C5 C 1.1793(7) 0.8814(6) 1.1427(6) 0.075(2) Uani 1 1 d . . .
H5A H 1.2337 0.8734 1.2302 0.113 Uiso 1 1 calc R . .
H5B H 1.0931 0.8938 1.1300 0.113 Uiso 1 1 calc R . .
H5C H 1.2283 0.9504 1.1330 0.113 Uiso 1 1 calc R . .
C6 C 0.9774(6) 0.8217(5) 0.8478(5) 0.0440(12) Uani 1 1 d . . .
C7 C 0.8302(5) 0.7709(4) 0.7446(5) 0.0385(11) Uani 1 1 d . . .
C8 C 0.7793(5) 0.8282(4) 0.6446(5) 0.0367(11) Uani 1 1 d . . .
H8 H 0.8380 0.8941 0.6454 0.044 Uiso 1 1 calc R . .
C9 C 0.6439(5) 0.7883(5) 0.5454(5) 0.0382(11) Uani 1 1 d . . .
C10 C 0.5534(5) 0.6934(5) 0.5488(5) 0.0442(12) Uani 1 1 d . . .
H10 H 0.4599 0.6689 0.4844 0.053 Uiso 1 1 calc R . .
C11 C 0.6047(5) 0.6373(5) 0.6483(5) 0.0461(13) Uani 1 1 d . . .
H11 H 0.5458 0.5737 0.6502 0.055 Uiso 1 1 calc R . .
C12 C 0.7436(6) 0.6754(5) 0.7454(5) 0.0451(12) Uani 1 1 d . . .
H12 H 0.7782 0.6362 0.8112 0.054 Uiso 1 1 calc R . .
C13 C 0.5862(6) 0.8460(4) 0.4360(5) 0.0442(12) Uani 1 1 d . . .
C14 C 0.6076(8) 1.0830(6) 0.3551(7) 0.0725(19) Uani 1 1 d . . .
H14A H 0.6507 1.1591 0.3512 0.109 Uiso 1 1 calc R . .
H14B H 0.6056 1.0965 0.4359 0.109 Uiso 1 1 calc R . .
H14C H 0.5150 1.0517 0.2802 0.109 Uiso 1 1 calc R . .
C15 C 0.6872(6) 0.9929(5) 0.3521(5) 0.0501(14) Uani 1 1 d . . .
C16 C 0.7852(6) 0.9945(5) 0.3191(6) 0.0554(15) Uani 1 1 d . . .
H2 H 0.8141 1.0537 0.2873 0.066 Uiso 1 1 calc R . .
C17 C 0.8356(6) 0.8930(5) 0.3406(5) 0.0468(13) Uani 1 1 d . . .
C18 C 0.9444(6) 0.8548(6) 0.3191(6) 0.0581(15) Uani 1 1 d . . .
H18A H 0.9733 0.7935 0.3630 0.087 Uiso 0.50 1 calc PR . .
H18B H 1.0220 0.9247 0.3549 0.087 Uiso 0.50 1 calc PR . .
H18C H 0.9078 0.8216 0.2256 0.087 Uiso 0.50 1 calc PR . .
H18D H 0.9621 0.8997 0.2660 0.087 Uiso 0.50 1 calc PR . .
H18E H 0.9134 0.7685 0.2741 0.087 Uiso 0.50 1 calc PR . .
H18F H 1.0276 0.8716 0.4034 0.087 Uiso 0.50 1 calc PR . .
C19 C 0.5226(9) 0.7490(8) 0.947(2) 0.110(4) Uiso 0.601(7) 1 d PD A -1
H19A H 0.4930 0.6782 0.8718 0.132 Uiso 0.601(7) 1 calc PR A -1
H19B H 0.5449 0.7194 1.0234 0.132 Uiso 0.601(7) 1 calc PR A -1
C19A C 0.4840(17) 0.7454(11) 0.967(3) 0.110(4) Uiso 0.399(7) 1 d PD A -2
H19C H 0.4219 0.6755 0.8897 0.132 Uiso 0.399(7) 1 calc PR A -2
H19D H 0.5034 0.7196 1.0455 0.132 Uiso 0.399(7) 1 calc PR A -2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Pd1 Cl1 90.37(12) . . ?
N1 Pd1 Cl4 177.94(12) . . ?
Cl1 Pd1 Cl4 90.60(5) . . ?
N1 Pd1 Cl3 94.68(12) . . ?
Cl1 Pd1 Cl3 174.95(5) . . ?
Cl4 Pd1 Cl3 84.35(5) . . ?
N1 Pd1 Pd2 132.32(11) . . ?
Cl1 Pd1 Pd2 128.55(4) . . ?
Cl4 Pd1 Pd2 45.90(3) . . ?
Cl3 Pd1 Pd2 47.16(3) . . ?
N3 Pd2 Cl2 89.66(12) . . ?
N3 Pd2 Cl4 177.82(12) . . ?
Cl2 Pd2 Cl4 92.01(5) . . ?
N3 Pd2 Cl3 93.95(12) . . ?
Cl2 Pd2 Cl3 176.08(5) . . ?
Cl4 Pd2 Cl3 84.42(4) . . ?
N3 Pd2 Pd1 131.76(12) . . ?
Cl2 Pd2 Pd1 130.63(4) . . ?
Cl4 Pd2 Pd1 46.09(3) . . ?
Cl3 Pd2 Pd1 47.05(3) . . ?
Pd1 Cl3 Pd2 85.78(4) . . ?
Pd2 Cl4 Pd1 88.00(4) . . ?
C17 N3 N4 106.4(4) . . ?
C17 N3 Pd2 127.4(4) . . ?
N4 N3 Pd2 123.6(3) . . ?
N3 N4 C15 110.1(4) . . ?
N3 N4 C13 123.3(4) . . ?
C15 N4 C13 126.7(5) . . ?
C4 N2 N1 110.4(4) . . ?
C4 N2 C6 125.9(5) . . ?
N1 N2 C6 123.0(4) . . ?
C2 N1 N2 105.1(4) . . ?
C2 N1 Pd1 129.4(4) . . ?
N2 N1 Pd1 125.5(3) . . ?
N1 C2 C3 109.8(5) . . ?
N1 C2 C1 121.9(5) . . ?
C3 C2 C1 128.3(5) . . ?
C4 C3 C2 108.2(5) . . ?
C3 C4 N2 106.5(5) . . ?
C3 C4 C5 130.9(5) . . ?
N2 C4 C5 122.5(5) . . ?
O2 C6 N2 117.8(5) . . ?
O2 C6 C7 123.9(5) . . ?
N2 C6 C7 118.3(4) . . ?
C12 C7 C8 120.1(5) . . ?
C12 C7 C6 123.7(5) . . ?
C8 C7 C6 116.1(4) . . ?
C9 C8 C7 120.3(4) . . ?
C8 C9 C10 119.7(4) . . ?
C8 C9 C13 121.9(5) . . ?
C10 C9 C13 118.3(5) . . ?
C11 C10 C9 119.4(5) . . ?
C10 C11 C12 120.2(5) . . ?
C7 C12 C11 120.1(5) . . ?
O1 C13 N4 120.5(5) . . ?
O1 C13 C9 124.2(5) . . ?
N4 C13 C9 115.2(5) . . ?
C16 C15 N4 105.6(5) . . ?
C16 C15 C14 130.3(5) . . ?
N4 C15 C14 123.9(6) . . ?
C15 C16 C17 108.6(5) . . ?
N3 C17 C16 109.2(5) . . ?
N3 C17 C18 122.0(5) . . ?
C16 C17 C18 128.8(5) . . ?
Cl6 C19 Cl5 118.2(4) . . ?
Cl6A C19A Cl5A 112.9(5) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pd1 N1 2.029(4) . ?
Pd1 Cl1 2.2583(14) . ?
Pd1 Cl4 2.3072(13) . ?
Pd1 Cl3 2.3490(13) . ?
Pd1 Pd2 3.2004(6) . ?
Pd2 N3 2.027(4) . ?
Pd2 Cl2 2.2712(14) . ?
Pd2 Cl4 2.2998(13) . ?
Pd2 Cl3 2.3532(13) . ?
Cl5 C19 1.714(2) . ?
Cl6 C19 1.713(2) . ?
Cl5A C19A 1.713(2) . ?
Cl6A C19A 1.711(2) . ?
O1 C13 1.189(6) . ?
O2 C6 1.216(6) . ?
N3 C17 1.333(7) . ?
N3 N4 1.374(6) . ?
N4 C15 1.383(6) . ?
N4 C13 1.432(7) . ?
N2 C4 1.368(7) . ?
N2 N1 1.381(6) . ?
N2 C6 1.439(6) . ?
N1 C2 1.340(7) . ?
C1 C2 1.489(8) . ?
C2 C3 1.386(8) . ?
C3 C4 1.341(8) . ?
C4 C5 1.486(8) . ?
C6 C7 1.473(7) . ?
C7 C12 1.370(7) . ?
C7 C8 1.393(7) . ?
C8 C9 1.364(7) . ?
C9 C10 1.410(7) . ?
C9 C13 1.487(7) . ?
C10 C11 1.379(7) . ?
C11 C12 1.386(7) . ?
C14 C15 1.483(9) . ?
C15 C16 1.351(8) . ?
C16 C17 1.388(8) . ?
C17 C18 1.493(8) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Pd1 Pd2 N3 0.9(2) . . . . ?
Cl1 Pd1 Pd2 N3 138.37(18) . . . . ?
Cl4 Pd1 Pd2 N3 179.47(17) . . . . ?
Cl3 Pd1 Pd2 N3 -45.16(17) . . . . ?
N1 Pd1 Pd2 Cl2 -138.17(17) . . . . ?
Cl1 Pd1 Pd2 Cl2 -0.71(9) . . . . ?
Cl4 Pd1 Pd2 Cl2 40.39(8) . . . . ?
Cl3 Pd1 Pd2 Cl2 175.76(7) . . . . ?
N1 Pd1 Pd2 Cl4 -178.57(17) . . . . ?
Cl1 Pd1 Pd2 Cl4 -41.11(8) . . . . ?
Cl3 Pd1 Pd2 Cl4 135.36(7) . . . . ?
N1 Pd1 Pd2 Cl3 46.07(17) . . . . ?
Cl1 Pd1 Pd2 Cl3 -176.47(8) . . . . ?
Cl4 Pd1 Pd2 Cl3 -135.36(7) . . . . ?
N1 Pd1 Cl3 Pd2 -147.71(12) . . . . ?
Cl1 Pd1 Cl3 Pd2 33.2(6) . . . . ?
Cl4 Pd1 Cl3 Pd2 30.47(5) . . . . ?
N3 Pd2 Cl3 Pd1 147.98(13) . . . . ?
Cl2 Pd2 Cl3 Pd1 -55.2(8) . . . . ?
Cl4 Pd2 Cl3 Pd1 -30.57(5) . . . . ?
N3 Pd2 Cl4 Pd1 -10(3) . . . . ?
Cl2 Pd2 Cl4 Pd1 -150.52(6) . . . . ?
Cl3 Pd2 Cl4 Pd1 31.11(5) . . . . ?
N1 Pd1 Cl4 Pd2 31(3) . . . . ?
Cl1 Pd1 Cl4 Pd2 149.06(6) . . . . ?
Cl3 Pd1 Cl4 Pd2 -31.18(5) . . . . ?
Cl2 Pd2 N3 C17 -102.6(4) . . . . ?
Cl4 Pd2 N3 C17 117(3) . . . . ?
Cl3 Pd2 N3 C17 75.8(4) . . . . ?
Pd1 Pd2 N3 C17 107.2(4) . . . . ?
Cl2 Pd2 N3 N4 56.7(4) . . . . ?
Cl4 Pd2 N3 N4 -83(3) . . . . ?
Cl3 Pd2 N3 N4 -124.8(4) . . . . ?
Pd1 Pd2 N3 N4 -93.5(4) . . . . ?
C17 N3 N4 C15 -1.5(5) . . . . ?
Pd2 N3 N4 C15 -164.5(3) . . . . ?
C17 N3 N4 C13 176.9(5) . . . . ?
Pd2 N3 N4 C13 13.9(6) . . . . ?
C4 N2 N1 C2 -0.2(6) . . . . ?
C6 N2 N1 C2 170.3(5) . . . . ?
C4 N2 N1 Pd1 -179.2(4) . . . . ?
C6 N2 N1 Pd1 -8.7(7) . . . . ?
Cl1 Pd1 N1 C2 60.1(5) . . . . ?
Cl4 Pd1 N1 C2 178(57) . . . . ?
Cl3 Pd1 N1 C2 -119.8(5) . . . . ?
Pd2 Pd1 N1 C2 -151.8(4) . . . . ?
Cl1 Pd1 N1 N2 -121.1(4) . . . . ?
Cl4 Pd1 N1 N2 -3(4) . . . . ?
Cl3 Pd1 N1 N2 59.0(4) . . . . ?
Pd2 Pd1 N1 N2 27.0(5) . . . . ?
N2 N1 C2 C3 0.8(6) . . . . ?
Pd1 N1 C2 C3 179.8(4) . . . . ?
N2 N1 C2 C1 -176.5(5) . . . . ?
Pd1 N1 C2 C1 2.5(8) . . . . ?
N1 C2 C3 C4 -1.2(7) . . . . ?
C1 C2 C3 C4 175.9(6) . . . . ?
C2 C3 C4 N2 1.0(7) . . . . ?
C2 C3 C4 C5 177.9(6) . . . . ?
N1 N2 C4 C3 -0.5(6) . . . . ?
C6 N2 C4 C3 -170.7(5) . . . . ?
N1 N2 C4 C5 -177.7(5) . . . . ?
C6 N2 C4 C5 12.1(9) . . . . ?
C4 N2 C6 O2 34.9(8) . . . . ?
N1 N2 C6 O2 -134.1(5) . . . . ?
C4 N2 C6 C7 -143.1(5) . . . . ?
N1 N2 C6 C7 47.9(7) . . . . ?
O2 C6 C7 C12 -145.7(6) . . . . ?
N2 C6 C7 C12 32.2(7) . . . . ?
O2 C6 C7 C8 32.4(8) . . . . ?
N2 C6 C7 C8 -149.7(5) . . . . ?
C12 C7 C8 C9 -1.3(7) . . . . ?
C6 C7 C8 C9 -179.4(5) . . . . ?
C7 C8 C9 C10 3.8(7) . . . . ?
C7 C8 C9 C13 -179.2(5) . . . . ?
C8 C9 C10 C11 -3.7(8) . . . . ?
C13 C9 C10 C11 179.1(5) . . . . ?
C9 C10 C11 C12 1.1(8) . . . . ?
C8 C7 C12 C11 -1.4(8) . . . . ?
C6 C7 C12 C11 176.6(5) . . . . ?
C10 C11 C12 C7 1.4(8) . . . . ?
N3 N4 C13 O1 -147.0(5) . . . . ?
C15 N4 C13 O1 31.2(8) . . . . ?
N3 N4 C13 C9 37.0(6) . . . . ?
C15 N4 C13 C9 -144.8(5) . . . . ?
C8 C9 C13 O1 -141.7(6) . . . . ?
C10 C9 C13 O1 35.3(8) . . . . ?
C8 C9 C13 N4 34.2(7) . . . . ?
C10 C9 C13 N4 -148.8(5) . . . . ?
N3 N4 C15 C16 0.7(6) . . . . ?
C13 N4 C15 C16 -177.7(5) . . . . ?
N3 N4 C15 C14 -175.3(5) . . . . ?
C13 N4 C15 C14 6.3(9) . . . . ?
N4 C15 C16 C17 0.4(6) . . . . ?
C14 C15 C16 C17 176.0(6) . . . . ?
N4 N3 C17 C16 1.7(6) . . . . ?
Pd2 N3 C17 C16 163.9(4) . . . . ?
N4 N3 C17 C18 -179.5(5) . . . . ?
Pd2 N3 C17 C18 -17.3(7) . . . . ?
C15 C16 C17 N3 -1.3(7) . . . . ?
C15 C16 C17 C18 -180.0(6) . . . . ?
