#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:05:32 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180025 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/19/7031957.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7031957
loop_
_publ_author_name
'Wang, Yue'
'Qi, Yan'
'Blatov, Vladislav A.'
'Zheng, Jimin'
'Li, Qun'
'Zhang, Chao'
_publ_section_title
;
 Two new zinc(ii) coordination complexes with helix characteristics
 showing both interpenetration and self-catenation features: a platform
 for the synthesis of chiral and catenated structures assembled by
 length-modulated dicarboxylates.
;
_journal_issue                   40
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              15151
_journal_page_last               15158
_journal_paper_doi               10.1039/c4dt01431f
_journal_volume                  43
_journal_year                    2014
_chemical_formula_sum            'C56 H48 N8 O15 Zn2'
_chemical_formula_weight         1203.80
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           167
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  '-R 3 2"c'
_symmetry_space_group_name_H-M   'R -3 c :H'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            18
_cell_length_a                   18.772(3)
_cell_length_b                   18.772(3)
_cell_length_c                   84.147(17)
_cell_measurement_temperature    293(2)
_cell_volume                     25680(8)
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1836
_diffrn_reflns_av_sigmaI/netI    0.1041
_diffrn_reflns_limit_h_max       23
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       108
_diffrn_reflns_limit_l_min       -109
_diffrn_reflns_number            66249
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.08
_exptl_absorpt_coefficient_mu    0.910
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.401
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             10150
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.622
_refine_diff_density_min         -0.575
_refine_diff_density_rms         0.077
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     370
_refine_ls_number_reflns         6545
_refine_ls_number_restraints     27
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.1924
_refine_ls_R_factor_gt           0.0902
_refine_ls_shift/su_max          0.005
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1051P)²+68.6298P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1992
_refine_ls_wR_factor_ref         0.2445
_reflns_number_gt                3070
_reflns_number_total             6545
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4dt01431f2.cif
_cod_data_source_block           shelxl
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Trigonal' changed to 'trigonal'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 2281 2013-09-26 08:29:07Z andrius 

 Adding full bibliography for 7031956--7031957.cif.
;
_cod_original_sg_symbol_H-M      R-3c
_cod_database_code               7031957
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z+1/2'
'-x, -x+y, -z+1/2'
'x-y, -y, -z+1/2'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+5/6'
'-x+2/3, -x+y+1/3, -z+5/6'
'x-y+2/3, -y+1/3, -z+5/6'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+7/6'
'-x+1/3, -x+y+2/3, -z+7/6'
'x-y+1/3, -y+2/3, -z+7/6'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-y, -x, z-1/2'
'x, x-y, z-1/2'
'-x+y, y, z-1/2'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-y+2/3, -x+1/3, z-1/6'
'x+2/3, x-y+1/3, z-1/6'
'-x+y+2/3, y+1/3, z-1/6'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
'-y+1/3, -x+2/3, z+1/6'
'x+1/3, x-y+2/3, z+1/6'
'-x+y+1/3, y+2/3, z+1/6'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
O9 O 0.102(3) 0.468(3) 0.9051(3) 0.44(3) Uani 0.50 1 d P
Zn1 Zn 0.66312(4) 0.03141(4) 1.008906(8) 0.0509(3) Uani 1 1 d .
O1 O 0.7011(3) 0.1166(2) 0.99274(5) 0.0638(11) Uani 1 1 d .
O2 O 0.7886(3) 0.0768(3) 0.98400(6) 0.0823(14) Uani 1 1 d .
O3 O 0.8482(7) 0.3634(6) 0.93554(11) 0.224(4) Uani 1 1 d U
O5 O 1.2407(3) 0.8802(3) 0.85447(6) 0.0866(15) Uani 1 1 d .
O6 O 1.3240(3) 0.8648(3) 0.87043(7) 0.1027(18) Uani 1 1 d .
O7 O 0.9848(4) 0.6057(5) 0.90059(9) 0.154(3) Uani 1 1 d .
O8 O 0.8431(8) 0.4516(6) 0.90760(11) 0.204(4) Uani 1 1 d U
N1 N 0.5970(3) -0.0769(3) 0.99800(6) 0.0512(12) Uani 1 1 d .
N2 N 0.4910(3) -0.1954(3) 0.99128(6) 0.0545(13) Uani 1 1 d .
N3 N 0.7579(3) 0.0385(3) 1.02127(6) 0.0592(13) Uani 1 1 d .
N4 N 0.8706(3) 0.0331(3) 1.02616(6) 0.0593(13) Uani 1 1 d .
C1 C 0.4107(3) -0.2656(3) 0.99127(7) 0.0535(16) Uani 1 1 d .
C2 C 0.4019(3) -0.3432(3) 0.99141(7) 0.0554(16) Uani 1 1 d .
H2 H 0.4478 -0.3498 0.9916 0.066 Uiso 1 1 calc R
C3 C 0.5186(4) -0.1282(4) 1.00027(8) 0.0571(16) Uani 1 1 d .
H3 H 0.4859 -0.1190 1.0073 0.068 Uiso 1 1 calc R
C4 C 0.8091(4) 0.0142(4) 1.01581(8) 0.0626(17) Uani 1 1 d .
H4 H 0.8031 -0.0122 1.0061 0.075 Uiso 1 1 calc R
C5 C 0.5567(4) -0.1866(4) 0.98239(8) 0.0627(17) Uani 1 1 d .
H5 H 0.5566 -0.2237 0.9751 0.075 Uiso 1 1 calc R
C6 C 0.9364(4) 0.0165(4) 1.02467(7) 0.0592(16) Uani 1 1 d .
C7 C 0.7881(4) 0.0731(4) 1.03582(9) 0.074(2) Uani 1 1 d .
H7 H 0.7647 0.0954 1.0425 0.089 Uiso 1 1 calc R
C8 C 1.1822(4) 0.7833(4) 0.87494(8) 0.074(2) Uani 1 1 d .
C9 C 0.6211(4) -0.1127(4) 0.98651(8) 0.0601(17) Uani 1 1 d .
H9 H 0.6737 -0.0895 0.9822 0.072 Uiso 1 1 calc R
C10 C 0.7578(4) 0.1215(4) 0.98358(8) 0.0614(17) Uani 1 1 d .
C11 C 0.8567(5) 0.0701(5) 1.03904(9) 0.087(2) Uani 1 1 d .
H11 H 0.8886 0.0892 1.0482 0.104 Uiso 1 1 calc R
C12 C 0.9190(4) -0.0648(4) 1.02471(7) 0.0625(17) Uani 1 1 d .
H12 H 0.8648 -0.1080 1.0248 0.075 Uiso 1 1 calc R
C13 C 0.8489(5) 0.2011(5) 0.96069(9) 0.087(2) Uani 1 1 d .
H13 H 0.8768 0.1722 0.9619 0.105 Uiso 1 1 calc R
C14 C 1.0367(5) 0.7128(5) 0.88093(9) 0.082(2) Uani 1 1 d .
H14 H 0.9849 0.7064 0.8792 0.099 Uiso 1 1 calc R
C15 C 0.7847(4) 0.1861(4) 0.97085(8) 0.0683(18) Uani 1 1 d .
C16 C 1.1054(5) 0.7720(4) 0.87271(9) 0.077(2) Uani 1 1 d .
H16 H 1.0985 0.8052 0.8654 0.092 Uiso 1 1 calc R
C17 C 1.1902(6) 0.7343(7) 0.88553(14) 0.150(5) Uani 1 1 d .
H17 H 1.2424 0.7420 0.8875 0.180 Uiso 1 1 calc R
C18 C 1.2541(5) 0.8475(4) 0.86625(10) 0.074(2) Uani 1 1 d .
C19 C 0.9043(6) 0.5891(5) 0.89815(11) 0.106(3) Uani 1 1 d .
H19A H 0.8864 0.5680 0.8875 0.127 Uiso 1 1 calc R
H19B H 0.9016 0.6391 0.8994 0.127 Uiso 1 1 calc R
C20 C 1.0476(5) 0.6649(6) 0.89155(11) 0.112(3) Uani 1 1 d .
C21 C 0.7707(7) 0.2894(6) 0.95728(12) 0.135(4) Uani 1 1 d .
H21 H 0.7440 0.3195 0.9560 0.162 Uiso 1 1 calc R
C22 C 0.8506(6) 0.5270(6) 0.91007(12) 0.124(4) Uani 1 1 d .
H22A H 0.8731 0.5463 0.9206 0.149 Uiso 1 1 calc R
H22B H 0.7965 0.5216 0.9097 0.149 Uiso 1 1 calc R
C23 C 0.7468(5) 0.2311(5) 0.96915(9) 0.089(2) Uani 1 1 d .
H23 H 0.7044 0.2225 0.9760 0.107 Uiso 1 1 calc R
C24 C 0.8338(8) 0.3022(7) 0.94749(13) 0.132(4) Uani 1 1 d .
C25 C 0.8713(7) 0.2581(7) 0.94888(12) 0.119(3) Uani 1 1 d .
H25 H 0.9127 0.2663 0.9418 0.142 Uiso 1 1 calc R
C26 C 1.1233(6) 0.6720(8) 0.89376(14) 0.160(5) Uani 1 1 d .
H26 H 1.1299 0.6366 0.9005 0.192 Uiso 1 1 calc R
C27 C 0.9110(11) 0.3828(9) 0.92609(19) 0.238(5) Uani 1 1 d U
H27A H 0.9012 0.3354 0.9198 0.286 Uiso 1 1 calc R
H27B H 0.9606 0.4003 0.9323 0.286 Uiso 1 1 calc R
C28 C 0.9215(13) 0.4533(11) 0.9151(2) 0.240(6) Uani 1 1 d U
H28A H 0.9568 0.4565 0.9064 0.288 Uiso 1 1 calc R
H28B H 0.9513 0.5042 0.9210 0.288 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O5 Zn1 O1 111.2(2) 35_445 .
O5 Zn1 N1 96.8(2) 35_445 .
O1 Zn1 N1 107.54(19) . .
O5 Zn1 N3 116.6(2) 35_445 .
O1 Zn1 N3 111.1(2) . .
N1 Zn1 N3 112.7(2) . .
C10 O1 Zn1 115.5(4) . .
C27 O3 C24 115.2(13) . .
C18 O5 Zn1 121.5(5) . 29
C20 O7 C19 119.5(7) . .
C22 O8 C28 107.7(13) . .
C3 N1 C9 105.4(5) . .
C3 N1 Zn1 125.5(4) . .
C9 N1 Zn1 129.1(4) . .
C3 N2 C5 107.0(5) . .
C3 N2 C1 127.4(5) . .
C5 N2 C1 125.5(5) . .
C4 N3 C7 105.8(5) . .
C4 N3 Zn1 124.4(5) . .
C7 N3 Zn1 129.7(4) . .
C4 N4 C11 106.7(5) . .
C4 N4 C6 127.6(6) . .
C11 N4 C6 125.6(6) . .
C2 C1 C2 121.3(6) 2_545 .
C2 C1 N2 119.4(5) 2_545 .
C2 C1 N2 119.3(5) . .
C1 C2 C1 118.7(6) 3_655 .
C1 C2 H2 120.7 3_655 .
C1 C2 H2 120.7 . .
N1 C3 N2 112.1(5) . .
N1 C3 H3 124.0 . .
N2 C3 H3 124.0 . .
N3 C4 N4 110.9(6) . .
N3 C4 H4 124.5 . .
N4 C4 H4 124.5 . .
C9 C5 N2 105.8(6) . .
C9 C5 H5 127.1 . .
N2 C5 H5 127.1 . .
C12 C6 C12 121.4(7) 3_765 .
C12 C6 N4 119.2(6) 3_765 .
C12 C6 N4 119.1(6) . .
C11 C7 N3 109.8(6) . .
C11 C7 H7 125.1 . .
N3 C7 H7 125.1 . .
C17 C8 C16 117.3(7) . .
C17 C8 C18 121.2(8) . .
C16 C8 C18 121.6(7) . .
C5 C9 N1 109.7(6) . .
C5 C9 H9 125.2 . .
N1 C9 H9 125.2 . .
O2 C10 O1 126.0(6) . .
O2 C10 C15 119.1(7) . .
O1 C10 C15 114.8(6) . .
C7 C11 N4 106.8(6) . .
C7 C11 H11 126.6 . .
N4 C11 H11 126.6 . .
C6 C12 C6 118.6(7) 2_645 .
C6 C12 H12 120.7 2_645 .
C6 C12 H12 120.7 . .
C25 C13 C15 120.2(9) . .
C25 C13 H13 119.9 . .
C15 C13 H13 119.9 . .
C20 C14 C16 118.0(8) . .
C20 C14 H14 121.0 . .
C16 C14 H14 121.0 . .
C23 C15 C13 118.8(7) . .
C23 C15 C10 120.5(7) . .
C13 C15 C10 120.7(7) . .
C8 C16 C14 122.8(7) . .
C8 C16 H16 118.6 . .
C14 C16 H16 118.6 . .
C8 C17 C26 122.6(9) . .
C8 C17 H17 118.7 . .
C26 C17 H17 118.7 . .
O6 C18 O5 122.8(7) . .
O6 C18 C8 119.4(8) . .
O5 C18 C8 117.7(7) . .
O7 C19 C22 108.1(8) . .
O7 C19 H19A 110.1 . .
C22 C19 H19A 110.1 . .
O7 C19 H19B 110.1 . .
C22 C19 H19B 110.1 . .
H19A C19 H19B 108.4 . .
C14 C20 C26 121.2(8) . .
C14 C20 O7 123.3(8) . .
C26 C20 O7 115.5(9) . .
C24 C21 C23 119.1(10) . .
C24 C21 H21 120.4 . .
C23 C21 H21 120.4 . .
O8 C22 C19 112.8(9) . .
O8 C22 H22A 109.0 . .
C19 C22 H22A 109.0 . .
O8 C22 H22B 109.0 . .
C19 C22 H22B 109.0 . .
H22A C22 H22B 107.8 . .
C15 C23 C21 120.4(8) . .
C15 C23 H23 119.8 . .
C21 C23 H23 119.8 . .
C25 C24 C21 121.3(9) . .
C25 C24 O3 127.4(11) . .
C21 C24 O3 111.2(11) . .
C24 C25 C13 120.1(10) . .
C24 C25 H25 120.0 . .
C13 C25 H25 120.0 . .
C20 C26 C17 117.9(9) . .
C20 C26 H26 121.0 . .
C17 C26 H26 121.0 . .
O3 C27 C28 108.2(15) . .
O3 C27 H27A 110.1 . .
C28 C27 H27A 110.1 . .
O3 C27 H27B 110.1 . .
C28 C27 H27B 110.1 . .
H27A C27 H27B 108.4 . .
C27 C28 O8 120.1(15) . .
C27 C28 H28A 107.3 . .
O8 C28 H28A 107.3 . .
C27 C28 H28B 107.3 . .
O8 C28 H28B 107.3 . .
H28A C28 H28B 106.9 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Zn1 O5 1.931(5) 35_445
Zn1 O1 1.943(4) .
Zn1 N1 1.998(5) .
Zn1 N3 2.007(5) .
O1 C10 1.280(7) .
O2 C10 1.234(8) .
O3 C27 1.314(16) .
O3 C24 1.447(12) .
O5 C18 1.255(9) .
O5 Zn1 1.931(5) 29
O6 C18 1.235(9) .
O7 C20 1.376(9) .
O7 C19 1.396(11) .
O8 C22 1.366(12) .
O8 C28 1.59(2) .
N1 C3 1.309(7) .
N1 C9 1.377(8) .
N2 C3 1.333(7) .
N2 C5 1.379(7) .
N2 C1 1.422(7) .
N3 C4 1.335(8) .
N3 C7 1.368(8) .
N4 C4 1.343(7) .
N4 C11 1.381(8) .
N4 C6 1.423(7) .
C1 C2 1.379(7) 2_545
C1 C2 1.381(7) .
C2 C1 1.379(7) 3_655
C2 H2 0.9300 .
C3 H3 0.9300 .
C4 H4 0.9300 .
C5 C9 1.353(8) .
C5 H5 0.9300 .
C6 C12 1.377(8) 3_765
C6 C12 1.392(8) .
C7 C11 1.344(9) .
C7 H7 0.9300 .
C8 C17 1.343(11) .
C8 C16 1.360(10) .
C8 C18 1.477(10) .
C9 H9 0.9300 .
C10 C15 1.503(9) .
C11 H11 0.9300 .
C12 C6 1.377(8) 2_645
C12 H12 0.9300 .
C13 C25 1.363(12) .
C13 C15 1.387(10) .
C13 H13 0.9300 .
C14 C20 1.353(11) .
C14 C16 1.396(10) .
C14 H14 0.9300 .
C15 C23 1.357(10) .
C16 H16 0.9300 .
C17 C26 1.398(13) .
C17 H17 0.9300 .
C19 C22 1.485(11) .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 C26 1.372(12) .
C21 C24 1.362(14) .
C21 C23 1.381(10) .
C21 H21 0.9300 .
C22 H22A 0.9700 .
C22 H22B 0.9700 .
C23 H23 0.9300 .
C24 C25 1.333(13) .
C25 H25 0.9300 .
C26 H26 0.9300 .
C27 C28 1.55(2) .
C27 H27A 0.9700 .
C27 H27B 0.9700 .
C28 H28A 0.9700 .
C28 H28B 0.9700 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O5 Zn1 O1 C10 -177.1(4) 35_445 .
N1 Zn1 O1 C10 -72.3(4) . .
N3 Zn1 O1 C10 51.4(5) . .
O5 Zn1 N1 C3 -1.9(5) 35_445 .
O1 Zn1 N1 C3 -116.6(5) . .
N3 Zn1 N1 C3 120.6(5) . .
O5 Zn1 N1 C9 176.1(5) 35_445 .
O1 Zn1 N1 C9 61.3(5) . .
N3 Zn1 N1 C9 -61.4(5) . .
O5 Zn1 N3 C4 155.9(5) 35_445 .
O1 Zn1 N3 C4 -75.5(5) . .
N1 Zn1 N3 C4 45.3(6) . .
O5 Zn1 N3 C7 -29.7(7) 35_445 .
O1 Zn1 N3 C7 99.0(6) . .
N1 Zn1 N3 C7 -140.3(6) . .
C3 N2 C1 C2 44.9(9) . 2_545
C5 N2 C1 C2 -138.7(6) . 2_545
C3 N2 C1 C2 -134.0(7) . .
C5 N2 C1 C2 42.5(9) . .
C2 C1 C2 C1 1.7(13) 2_545 3_655
N2 C1 C2 C1 -179.5(4) . 3_655
C9 N1 C3 N2 1.4(7) . .
Zn1 N1 C3 N2 179.8(4) . .
C5 N2 C3 N1 -0.6(7) . .
C1 N2 C3 N1 176.4(5) . .
C7 N3 C4 N4 -0.9(7) . .
Zn1 N3 C4 N4 174.6(4) . .
C11 N4 C4 N3 1.2(8) . .
C6 N4 C4 N3 179.3(6) . .
C3 N2 C5 C9 -0.5(7) . .
C1 N2 C5 C9 -177.6(6) . .
C4 N4 C6 C12 120.2(7) . 3_765
C11 N4 C6 C12 -62.0(9) . 3_765
C4 N4 C6 C12 -65.8(9) . .
C11 N4 C6 C12 112.0(8) . .
C4 N3 C7 C11 0.3(8) . .
Zn1 N3 C7 C11 -174.9(5) . .
N2 C5 C9 N1 1.4(7) . .
C3 N1 C9 C5 -1.7(7) . .
Zn1 N1 C9 C5 180.0(4) . .
Zn1 O1 C10 O2 1.3(8) . .
Zn1 O1 C10 C15 178.3(4) . .
N3 C7 C11 N4 0.4(9) . .
C4 N4 C11 C7 -0.9(9) . .
C6 N4 C11 C7 -179.1(6) . .
C12 C6 C12 C6 -0.5(14) 3_765 2_645
N4 C6 C12 C6 -174.4(4) . 2_645
C25 C13 C15 C23 -2.2(12) . .
C25 C13 C15 C10 178.1(8) . .
O2 C10 C15 C23 173.9(7) . .
O1 C10 C15 C23 -3.4(9) . .
O2 C10 C15 C13 -6.4(10) . .
O1 C10 C15 C13 176.3(6) . .
C17 C8 C16 C14 0.3(13) . .
C18 C8 C16 C14 -179.0(7) . .
C20 C14 C16 C8 0.0(13) . .
C16 C8 C17 C26 1.8(18) . .
C18 C8 C17 C26 -178.9(11) . .
Zn1 O5 C18 O6 -2.8(11) 29 .
Zn1 O5 C18 C8 179.7(5) 29 .
C17 C8 C18 O6 -11.0(13) . .
C16 C8 C18 O6 168.2(7) . .
C17 C8 C18 O5 166.5(9) . .
C16 C8 C18 O5 -14.2(11) . .
C20 O7 C19 C22 -176.5(9) . .
C16 C14 C20 C26 -2.5(16) . .
C16 C14 C20 O7 178.6(9) . .
C19 O7 C20 C14 4.5(16) . .
C19 O7 C20 C26 -174.5(11) . .
C28 O8 C22 C19 81.8(12) . .
O7 C19 C22 O8 -68.1(13) . .
C13 C15 C23 C21 1.4(13) . .
C10 C15 C23 C21 -178.9(8) . .
C24 C21 C23 C15 -1.2(16) . .
C23 C21 C24 C25 2(2) . .
C23 C21 C24 O3 178.2(10) . .
C27 O3 C24 C25 -7(2) . .
C27 O3 C24 C21 176.5(13) . .
C21 C24 C25 C13 -3(2) . .
O3 C24 C25 C13 -178.4(11) . .
C15 C13 C25 C24 2.9(16) . .
C14 C20 C26 C17 4(2) . .
O7 C20 C26 C17 -176.6(12) . .
C8 C17 C26 C20 -4(2) . .
C24 O3 C27 C28 -175.5(12) . .
O3 C27 C28 O8 -41(2) . .
C22 O8 C28 C27 131.6(13) . .
