#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/7/03/57/7035774.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7035774
loop_
_publ_author_name
'Burrows, Andrew D.'
'Jurcic, Monika'
'Mahon, Mary F.'
'Pierrat, Sandrine'
'Roffe, Gavin W.'
'Windle, Henry J.'
'Spencer, John'
_publ_section_title
;
 Bismuth coordination networks containing deferiprone: synthesis,
 characterisation, stability and antibacterial activity.
;
_journal_issue                   31
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              13814
_journal_page_last               13817
_journal_paper_doi               10.1039/c5dt02458g
_journal_volume                  44
_journal_year                    2015
_chemical_formula_sum            'C21 H27 Bi N3 O9'
_chemical_formula_weight         674.44
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-03-02 deposited with the CCDC.
2015-06-02 downloaded from the CCDC.
;
_cell_angle_alpha                108.125(1)
_cell_angle_beta                 93.568(1)
_cell_angle_gamma                118.699(1)
_cell_formula_units_Z            2
_cell_length_a                   10.3170(1)
_cell_length_b                   10.6650(1)
_cell_length_c                   12.7980(2)
_cell_measurement_reflns_used    18122
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.485
_cell_measurement_theta_min      2.910
_cell_volume                     1135.44(3)
_computing_cell_refinement       'HKL Scalepack (Otwinowski & Minor 1997)'
_computing_data_collection       'Collect (Bruker AXS BV, 1997-2004)'
_computing_data_reduction
'Denzo & Scalepack (Otwinowski & Minor, 1997)'
_computing_molecular_graphics    'ORTEX (P.McArdle, 1995)'
_computing_publication_material  'SHELXL-97/2 (Sheldrick,1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  '95mm CCD camera on κ-goniostat'
_diffrn_measurement_method       CCD
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0471
_diffrn_reflns_av_sigmaI/netI    0.0342
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            22651
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         3.65
_exptl_absorpt_coefficient_mu    7.822
_exptl_absorpt_correction_T_max  0.235
_exptl_absorpt_correction_T_min  0.179
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
multi-scan from symmetry-related measurements 
 Sortav (Blessing 1995)
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.973
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             658
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.25
_refine_diff_density_max         1.758
_refine_diff_density_min         -2.366
_refine_diff_density_rms         0.133
_refine_ls_extinction_coef       0.0029(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.094
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     335
_refine_ls_number_reflns         5180
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.094
_refine_ls_R_factor_all          0.0258
_refine_ls_R_factor_gt           0.0247
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0309P)²+1.0596P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0598
_refine_ls_wR_factor_ref         0.0605
_reflns_number_gt                5000
_reflns_number_total             5180
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5dt02458g2.cif
_cod_data_source_block           k13mfm5
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 3271 2015-04-21 07:52:19Z andrius 

 Adding full bibliography for 7035772--7035775.cif.
;
_cod_original_cell_volume        1135.44(2)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7035774
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Bi1 Bi 0.567342(11) 0.682363(12) 0.654581(8) 0.01784(6) Uani 1 1 d .
O1 O 0.5218(3) 0.7261(3) 0.49333(19) 0.0214(5) Uani 1 1 d .
O2 O 0.4288(3) 0.7938(3) 0.68387(19) 0.0214(5) Uani 1 1 d .
O3 O 0.6280(3) 0.7794(3) 0.8511(2) 0.0223(5) Uani 1 1 d .
O4 O 0.7721(3) 0.9141(3) 0.71188(19) 0.0222(5) Uani 1 1 d .
O5 O 0.7977(3) 0.6292(3) 0.6910(2) 0.0273(5) Uani 1 1 d .
O6 O 0.7223(3) 0.6229(3) 0.5223(2) 0.0260(5) Uani 1 1 d .
O7A O 0.8723(4) 0.5921(4) 0.3658(3) 0.0228(7) Uani 0.70 1 d PD
O7B O 0.9701(8) 0.5174(9) 0.7144(7) 0.0215(15) Uani 0.30 1 d P
O9 O 0.5433(3) 0.6891(3) 0.1134(3) 0.0365(6) Uani 1 1 d .
O10 O 0.6026(3) 0.6073(3) 0.2952(2) 0.0342(6) Uani 1 1 d D
N1 N 0.3794(3) 0.7122(3) 0.0048(3) 0.0249(6) Uani 1 1 d .
N2 N 1.0225(3) 1.2023(3) 0.9880(2) 0.0217(6) Uani 1 1 d .
N3 N 0.2489(3) 0.9057(3) 0.5103(2) 0.0206(5) Uani 1 1 d .
C1 C 0.8023(4) 0.6045(4) 0.5887(3) 0.0208(6) Uani 1 1 d .
C2 C 0.9055(3) 0.5516(4) 0.5423(3) 0.0191(6) Uani 1 1 d .
C3 C 0.9283(4) 0.5435(4) 0.4338(3) 0.0204(6) Uani 1 1 d .
C4 C 0.9773(4) 0.5080(4) 0.6071(3) 0.0192(6) Uani 1 1 d .
C5 C 0.8323(4) 0.9874(4) 0.8249(3) 0.0191(6) Uani 1 1 d .
C6 C 0.9675(4) 1.1290(4) 0.8717(3) 0.0214(6) Uani 1 1 d .
C7 C 0.9467(4) 1.1359(4) 1.0576(3) 0.0235(7) Uani 1 1 d .
H7 H 0.9870 1.1892 1.1376 0.028 Uiso 1 1 calc R
C8 C 0.8141(4) 0.9946(4) 1.0148(3) 0.0225(6) Uani 1 1 d .
H8 H 0.7633 0.9505 1.0650 0.027 Uiso 1 1 calc R
C9 C 0.7519(3) 0.9133(4) 0.8964(3) 0.0186(6) Uani 1 1 d .
C10 C 1.0584(4) 1.2054(4) 0.7996(3) 0.0316(8) Uani 1 1 d .
H10C H 1.0543 1.2978 0.8077 0.047 Uiso 1 1 calc R
H10D H 1.0156 1.1327 0.7198 0.047 Uiso 1 1 calc R
H10E H 1.1648 1.2357 0.8239 0.047 Uiso 1 1 calc R
C11 C 1.1669(4) 1.3533(4) 1.0403(3) 0.0295(8) Uani 1 1 d .
H11A H 1.1891 1.3870 1.1231 0.044 Uiso 1 1 calc R
H11B H 1.1582 1.4301 1.0189 0.044 Uiso 1 1 calc R
H11C H 1.2499 1.3434 1.0135 0.044 Uiso 1 1 calc R
C12 C 0.3828(3) 0.8180(4) 0.5965(3) 0.0191(6) Uani 1 1 d .
C13 C 0.2902(3) 0.8791(4) 0.6022(3) 0.0201(6) Uani 1 1 d .
C14 C 0.2925(4) 0.8696(4) 0.4145(3) 0.0225(7) Uani 1 1 d .
H14 H 0.2615 0.8889 0.3527 0.027 Uiso 1 1 calc R
C15 C 0.3815(4) 0.8050(4) 0.4040(3) 0.0215(6) Uani 1 1 d .
H15 H 0.4088 0.7774 0.3346 0.026 Uiso 1 1 calc R
C16 C 0.4315(3) 0.7801(4) 0.4946(3) 0.0190(6) Uani 1 1 d .
C17 C 0.2339(4) 0.9174(4) 0.7055(3) 0.0244(7) Uani 1 1 d .
H17A H 0.2523 0.8710 0.7555 0.037 Uiso 1 1 calc R
H17B H 0.1242 0.8758 0.6826 0.037 Uiso 1 1 calc R
H17C H 0.2885 1.0303 0.7461 0.037 Uiso 1 1 calc R
C18 C 0.1561(4) 0.9775(4) 0.5175(3) 0.0260(7) Uani 1 1 d .
H18A H 0.1550 1.0085 0.4531 0.039 Uiso 1 1 calc R
H18B H 0.2004 1.0691 0.5887 0.039 Uiso 1 1 calc R
H18C H 0.0514 0.9025 0.5154 0.039 Uiso 1 1 calc R
C19 C 0.4642(4) 0.6546(4) 0.0214(3) 0.0250(7) Uani 1 1 d .
H19 H 0.4637 0.5803 -0.0434 0.030 Uiso 1 1 calc R
C20 C 0.3774(6) 0.8301(6) 0.0984(4) 0.0450(11) Uani 1 1 d .
H20A H 0.4342 0.8451 0.1700 0.067 Uiso 1 1 calc R
H20B H 0.2715 0.7969 0.1012 0.067 Uiso 1 1 calc R
H20C H 0.4252 0.9280 0.0873 0.067 Uiso 1 1 calc R
C21 C 0.2953(5) 0.6678(5) -0.1086(3) 0.0379(9) Uani 1 1 d .
H21A H 0.3410 0.7566 -0.1311 0.057 Uiso 1 1 calc R
H21B H 0.1886 0.6347 -0.1091 0.057 Uiso 1 1 calc R
H21C H 0.2994 0.5820 -0.1623 0.057 Uiso 1 1 calc R
H10A H 0.582(6) 0.638(6) 0.234(3) 0.050(14) Uiso 1 1 d D
H10B H 0.583(9) 0.664(8) 0.363(4) 0.13(3) Uiso 1 1 d D
H7A H 0.798(6) 0.610(7) 0.401(5) 0.039(17) Uiso 0.70 1 d PD
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O4 Bi1 O2 88.37(9) . .
O4 Bi1 O3 73.90(8) . .
O2 Bi1 O3 81.22(8) . .
O4 Bi1 O1 84.29(8) . .
O2 Bi1 O1 72.35(8) . .
O3 Bi1 O1 146.08(8) . .
O4 Bi1 O6 80.55(9) . .
O2 Bi1 O6 142.33(8) . .
O3 Bi1 O6 128.50(8) . .
O1 Bi1 O6 70.79(8) . .
O4 Bi1 O5 77.28(8) . .
O2 Bi1 O5 159.86(8) . .
O3 Bi1 O5 81.26(8) . .
O1 Bi1 O5 119.33(7) . .
O6 Bi1 O5 49.49(7) . .
C16 O1 Bi1 114.51(19) . .
C12 O2 Bi1 116.05(19) . .
C9 O3 Bi1 112.66(19) . .
C5 O4 Bi1 115.50(19) . .
C1 O5 Bi1 89.46(19) . .
C1 O6 Bi1 98.4(2) . .
C3 O7A H7A 105(4) . .
H10A O10 H10B 107(6) . .
C19 N1 C21 120.9(3) . .
C19 N1 C20 120.9(3) . .
C21 N1 C20 118.0(3) . .
C7 N2 C6 121.1(3) . .
C7 N2 C11 118.3(3) . .
C6 N2 C11 120.6(3) . .
C14 N3 C13 121.6(3) . .
C14 N3 C18 118.7(3) . .
C13 N3 C18 119.6(3) . .
O5 C1 O6 122.4(3) . .
O5 C1 C2 119.7(3) . .
O6 C1 C2 118.0(3) . .
C4 C2 C3 120.0(3) . .
C4 C2 C1 119.4(3) . .
C3 C2 C1 120.6(3) . .
O7A C3 C4 115.5(3) . 2_766
O7A C3 C2 125.3(3) . .
C4 C3 C2 119.1(3) 2_766 .
O7B C4 C3 113.5(4) . 2_766
O7B C4 C2 125.5(4) . .
C3 C4 C2 120.9(3) 2_766 .
O4 C5 C6 121.4(3) . .
O4 C5 C9 118.1(3) . .
C6 C5 C9 120.5(3) . .
N2 C6 C5 119.5(3) . .
N2 C6 C10 118.6(3) . .
C5 C6 C10 121.9(3) . .
N2 C7 C8 121.3(3) . .
N2 C7 H7 119.3 . .
C8 C7 H7 119.3 . .
C7 C8 C9 120.4(3) . .
C7 C8 H8 119.8 . .
C9 C8 H8 119.8 . .
O3 C9 C8 123.2(3) . .
O3 C9 C5 119.6(3) . .
C8 C9 C5 117.2(3) . .
C6 C10 H10C 109.5 . .
C6 C10 H10D 109.5 . .
H10C C10 H10D 109.5 . .
C6 C10 H10E 109.5 . .
H10C C10 H10E 109.5 . .
H10D C10 H10E 109.5 . .
N2 C11 H11A 109.5 . .
N2 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
N2 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
O2 C12 C13 121.5(3) . .
O2 C12 C16 118.8(3) . .
C13 C12 C16 119.7(3) . .
N3 C13 C12 119.2(3) . .
N3 C13 C17 119.1(3) . .
C12 C13 C17 121.7(3) . .
N3 C14 C15 121.2(3) . .
N3 C14 H14 119.4 . .
C15 C14 H14 119.4 . .
C14 C15 C16 120.2(3) . .
C14 C15 H15 119.9 . .
C16 C15 H15 119.9 . .
O1 C16 C15 124.0(3) . .
O1 C16 C12 118.0(3) . .
C15 C16 C12 118.1(3) . .
C13 C17 H17A 109.5 . .
C13 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C13 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
N3 C18 H18A 109.5 . .
N3 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
N3 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
O9 C19 N1 125.6(3) . .
O9 C19 H19 117.2 . .
N1 C19 H19 117.2 . .
N1 C20 H20A 109.5 . .
N1 C20 H20B 109.5 . .
H20A C20 H20B 109.5 . .
N1 C20 H20C 109.5 . .
H20A C20 H20C 109.5 . .
H20B C20 H20C 109.5 . .
N1 C21 H21A 109.5 . .
N1 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
N1 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Bi1 O4 2.185(2) .
Bi1 O2 2.239(2) .
Bi1 O3 2.313(2) .
Bi1 O1 2.321(2) .
Bi1 O6 2.543(2) .
Bi1 O5 2.739(2) .
O1 C16 1.308(4) .
O2 C12 1.331(4) .
O3 C9 1.284(4) .
O4 C5 1.345(4) .
O5 C1 1.260(4) .
O6 C1 1.271(4) .
O7A C3 1.366(4) .
O7A H7A 0.979(5) .
O7B C4 1.355(8) .
O9 C19 1.228(5) .
O10 H10A 0.978(5) .
O10 H10B 0.978(5) .
N1 C19 1.328(4) .
N1 C21 1.451(5) .
N1 C20 1.452(5) .
N2 C7 1.361(4) .
N2 C6 1.376(4) .
N2 C11 1.471(4) .
N3 C14 1.339(4) .
N3 C13 1.381(4) .
N3 C18 1.478(4) .
C1 C2 1.501(4) .
C2 C4 1.396(5) .
C2 C3 1.405(5) .
C3 C4 1.387(4) 2_766
C4 C3 1.387(4) 2_766
C5 C6 1.376(5) .
C5 C9 1.437(4) .
C6 C10 1.496(5) .
C7 C8 1.362(5) .
C7 H7 0.9500 .
C8 C9 1.409(5) .
C8 H8 0.9500 .
C10 H10C 0.9800 .
C10 H10D 0.9800 .
C10 H10E 0.9800 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 C13 1.386(4) .
C12 C16 1.437(4) .
C13 C17 1.496(5) .
C14 C15 1.380(5) .
C14 H14 0.9500 .
C15 C16 1.389(5) .
C15 H15 0.9500 .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 H19 0.9500 .
C20 H20A 0.9800 .
C20 H20B 0.9800 .
C20 H20C 0.9800 .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_4
O4 Bi1 O1 C16 -95.2(2) .
O2 Bi1 O1 C16 -5.1(2) .
O3 Bi1 O1 C16 -45.6(3) .
O6 Bi1 O1 C16 -177.1(2) .
O5 Bi1 O1 C16 -167.1(2) .
O4 Bi1 O2 C12 88.9(2) .
O3 Bi1 O2 C12 162.9(2) .
O1 Bi1 O2 C12 4.4(2) .
O6 Bi1 O2 C12 16.7(3) .
O5 Bi1 O2 C12 133.1(3) .
O4 Bi1 O3 C9 -3.32(19) .
O2 Bi1 O3 C9 -94.2(2) .
O1 Bi1 O3 C9 -55.4(3) .
O6 Bi1 O3 C9 60.1(2) .
O5 Bi1 O3 C9 75.9(2) .
O2 Bi1 O4 C5 85.4(2) .
O3 Bi1 O4 C5 4.1(2) .
O1 Bi1 O4 C5 157.8(2) .
O6 Bi1 O4 C5 -130.7(2) .
O5 Bi1 O4 C5 -80.3(2) .
O4 Bi1 O5 C1 -91.3(2) .
O2 Bi1 O5 C1 -136.8(2) .
O3 Bi1 O5 C1 -166.6(2) .
O1 Bi1 O5 C1 -15.4(2) .
O6 Bi1 O5 C1 -2.88(18) .
O4 Bi1 O6 C1 84.2(2) .
O2 Bi1 O6 C1 158.95(19) .
O3 Bi1 O6 C1 23.6(2) .
O1 Bi1 O6 C1 171.4(2) .
O5 Bi1 O6 C1 2.89(18) .
Bi1 O5 C1 O6 5.2(3) .
Bi1 O5 C1 C2 -175.0(3) .
Bi1 O6 C1 O5 -5.7(4) .
Bi1 O6 C1 C2 174.5(2) .
O5 C1 C2 C4 9.7(5) .
O6 C1 C2 C4 -170.5(3) .
O5 C1 C2 C3 -171.3(3) .
O6 C1 C2 C3 8.5(5) .
C4 C2 C3 O7A -175.6(3) .
C1 C2 C3 O7A 5.5(5) .
C4 C2 C3 C4 -0.1(5) 2_766
C1 C2 C3 C4 -179.1(3) 2_766
C3 C2 C4 O7B 176.8(5) .
C1 C2 C4 O7B -4.2(6) .
C3 C2 C4 C3 0.1(5) 2_766
C1 C2 C4 C3 179.1(3) 2_766
Bi1 O4 C5 C6 175.1(2) .
Bi1 O4 C5 C9 -4.6(3) .
C7 N2 C6 C5 1.1(5) .
C11 N2 C6 C5 179.7(3) .
C7 N2 C6 C10 -178.1(3) .
C11 N2 C6 C10 0.5(5) .
O4 C5 C6 N2 177.9(3) .
C9 C5 C6 N2 -2.4(5) .
O4 C5 C6 C10 -3.0(5) .
C9 C5 C6 C10 176.7(3) .
C6 N2 C7 C8 0.2(5) .
C11 N2 C7 C8 -178.4(3) .
N2 C7 C8 C9 -0.1(5) .
Bi1 O3 C9 C8 -178.6(2) .
Bi1 O3 C9 C5 2.2(3) .
C7 C8 C9 O3 179.5(3) .
C7 C8 C9 C5 -1.2(5) .
O4 C5 C9 O3 1.5(4) .
C6 C5 C9 O3 -178.2(3) .
O4 C5 C9 C8 -177.8(3) .
C6 C5 C9 C8 2.5(4) .
Bi1 O2 C12 C13 176.8(2) .
Bi1 O2 C12 C16 -3.5(4) .
C14 N3 C13 C12 2.0(5) .
C18 N3 C13 C12 -177.2(3) .
C14 N3 C13 C17 -178.1(3) .
C18 N3 C13 C17 2.7(4) .
O2 C12 C13 N3 178.3(3) .
C16 C12 C13 N3 -1.4(5) .
O2 C12 C13 C17 -1.5(5) .
C16 C12 C13 C17 178.7(3) .
C13 N3 C14 C15 -0.4(5) .
C18 N3 C14 C15 178.8(3) .
N3 C14 C15 C16 -1.8(5) .
Bi1 O1 C16 C15 -175.7(2) .
Bi1 O1 C16 C12 5.2(4) .
C14 C15 C16 O1 -176.7(3) .
C14 C15 C16 C12 2.3(5) .
O2 C12 C16 O1 -1.3(4) .
C13 C12 C16 O1 178.4(3) .
O2 C12 C16 C15 179.5(3) .
C13 C12 C16 C15 -0.7(5) .
C21 N1 C19 O9 177.3(4) .
C20 N1 C19 O9 2.1(6) .
