#------------------------------------------------------------------------------
#$Date: 2016-10-08 01:16:13 +0300 (Sat, 08 Oct 2016) $
#$Revision: 187113 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/02/7040250.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7040250
loop_
_publ_author_name
'Wächtler, Erik'
'Gericke, Robert'
'Brendler, Erica'
'Gerke, Birgit'
'Langer, Thorsten'
'Pöttgen, Rainer'
'Zhechkov, Lyuben'
'Heine, Thomas'
'Wagler, Jörg'
_publ_section_title
;
 Group 10-group 14 metal complexes [E-TM](IV): the role of the group 14
 site as an L, X and Z-type ligand.
;
_journal_issue                   36
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              14252
_journal_page_last               14264
_journal_paper_doi               10.1039/c6dt01621a
_journal_volume                  45
_journal_year                    2016
_chemical_formula_moiety         '(C40 H32 Cl8 N8 Pd4 S8 Sn4), 2(C4 H8 O)'
_chemical_formula_sum            'C48 H48 Cl8 N8 O2 Pd4 S8 Sn4'
_chemical_formula_weight         2209.38
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           82
_symmetry_cell_setting           tetragonal
_symmetry_space_group_name_Hall  'I -4'
_symmetry_space_group_name_H-M   'I -4'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2016-08-04 deposited with the CCDC.
2016-08-08 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.8143(3)
_cell_length_b                   11.8143(3)
_cell_length_c                   24.1508(8)
_cell_measurement_reflns_used    47050
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      32.15
_cell_measurement_theta_min      2.44
_cell_volume                     3370.91(16)
_computing_cell_refinement       'STOE X-AREA'
_computing_data_collection       'STOE X-AREA'
_computing_data_reduction        'STOE X-RED'
_computing_molecular_graphics    'ORTEP32 (Farugia)'
_computing_publication_material  'Ciftab (Sheldrick)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Stoe IPDS-2T'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0286
_diffrn_reflns_av_sigmaI/netI    0.0113
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       33
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            40152
_diffrn_reflns_theta_full        29.97
_diffrn_reflns_theta_max         29.97
_diffrn_reflns_theta_min         2.44
_exptl_absorpt_coefficient_mu    3.107
_exptl_absorpt_correction_T_max  0.6454
_exptl_absorpt_correction_T_min  0.5034
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details   XShape
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    2.177
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       polyhedron
_exptl_crystal_F_000             2112
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.380
_refine_diff_density_min         -0.485
_refine_diff_density_rms         0.073
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.00(4)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.176
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     206
_refine_ls_number_reflns         4938
_refine_ls_number_restraints     28
_refine_ls_restrained_S_all      1.172
_refine_ls_R_factor_all          0.0196
_refine_ls_R_factor_gt           0.0183
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0094P)²+7.8636P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0394
_refine_ls_wR_factor_ref         0.0400
_reflns_number_gt                4795
_reflns_number_total             4938
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c6dt01621a2.cif
_cod_data_source_block           10
_cod_depositor_comments
'Adding full bibliography for 7040238--7040250.cif.'
_cod_original_cell_volume        3370.9(2)
_cod_original_sg_symbol_Hall     I-4
_cod_original_sg_symbol_H-M      I-4
_cod_database_code               7040250
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'y, -x, -z'
'-y, x, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'-y+1/2, x+1/2, -z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
O1 O 0.4935(12) 0.0444(16) 0.8083(7) 0.097(4) Uani 0.25 1 d PD A -1
C11 C 0.4069(13) 0.004(4) 0.7707(7) 0.097(4) Uani 0.25 1 d PD A -1
H11A H 0.3368 0.0487 0.7747 0.117 Uiso 0.25 1 calc PR A -1
H11B H 0.3891 -0.0768 0.7785 0.117 Uiso 0.25 1 calc PR A -1
C12 C 0.4542(14) 0.016(4) 0.7142(7) 0.097(4) Uani 0.25 1 d PD A -1
H12A H 0.4255 -0.0443 0.6896 0.117 Uiso 0.25 1 calc PR A -1
H12B H 0.4335 0.0905 0.6984 0.117 Uiso 0.25 1 calc PR A -1
C13 C 0.5786(14) 0.007(4) 0.7208(7) 0.097(4) Uani 0.25 1 d PD A -1
H13A H 0.6176 0.0664 0.6992 0.117 Uiso 0.25 1 calc PR A -1
H13B H 0.6056 -0.0681 0.7082 0.117 Uiso 0.25 1 calc PR A -1
C14 C 0.6002(15) 0.022(4) 0.7808(8) 0.097(4) Uani 0.25 1 d PD A -1
H14A H 0.6350 -0.0477 0.7963 0.117 Uiso 0.25 1 calc PR A -1
H14B H 0.6531 0.0855 0.7868 0.117 Uiso 0.25 1 calc PR A -1
O2 O 0.042(2) -0.038(2) 0.5475(9) 0.133(6) Uani 0.25 1 d PD B -2
C15 C 0.1009(19) -0.074(3) 0.4979(10) 0.133(6) Uani 0.25 1 d PD B -2
H15A H 0.1251 -0.1543 0.4999 0.160 Uiso 0.25 1 calc PR B -2
H15B H 0.1667 -0.0254 0.4892 0.160 Uiso 0.25 1 calc PR B -2
C16 C 0.006(2) -0.057(3) 0.4587(11) 0.133(6) Uani 0.25 1 d PD B -2
H16A H -0.0473 -0.1217 0.4602 0.160 Uiso 0.25 1 calc PR B -2
H16B H 0.0345 -0.0494 0.4203 0.160 Uiso 0.25 1 calc PR B -2
C17 C -0.051(3) 0.049(3) 0.4768(12) 0.133(6) Uani 0.25 1 d PD B -2
H17A H -0.1338 0.0392 0.4768 0.160 Uiso 0.25 1 calc PR B -2
H17B H -0.0307 0.1122 0.4519 0.160 Uiso 0.25 1 calc PR B -2
C18 C -0.008(4) 0.070(3) 0.5336(11) 0.133(6) Uani 0.25 1 d PD B -2
H18A H 0.0484 0.1319 0.5341 0.160 Uiso 0.25 1 calc PR B -2
H18B H -0.0711 0.0895 0.5592 0.160 Uiso 0.25 1 calc PR B -2
Pd1 Pd 0.051365(16) 0.126949(17) 0.064937(7) 0.01985(4) Uani 1 1 d . . .
Sn1 Sn 0.229475(15) 0.113519(17) 0.118867(7) 0.02474(4) Uani 1 1 d . . .
Cl1 Cl 0.34603(7) -0.03539(8) 0.15000(3) 0.04135(19) Uani 1 1 d . . .
Cl2 Cl 0.33325(10) 0.27705(10) 0.14568(4) 0.0575(3) Uani 1 1 d . . .
S1 S -0.04529(7) 0.14838(10) 0.14693(3) 0.0446(2) Uani 1 1 d . . .
S2 S 0.14975(5) 0.12876(5) -0.01811(2) 0.01876(11) Uani 1 1 d . . .
N1 N 0.1518(2) 0.1208(3) 0.20418(10) 0.0395(7) Uani 1 1 d . . .
N2 N 0.3471(2) 0.1243(2) 0.04023(10) 0.0270(5) Uani 1 1 d . . .
C1 C 0.0397(3) 0.1379(4) 0.20619(12) 0.0498(10) Uani 1 1 d . . .
C2 C -0.0148(4) 0.1490(7) 0.25800(16) 0.094(2) Uani 1 1 d . . .
H2 H -0.0944 0.1595 0.2599 0.113 Uiso 1 1 calc R . .
C3 C 0.0488(4) 0.1442(7) 0.30575(15) 0.099(3) Uani 1 1 d . . .
H3 H 0.0131 0.1525 0.3408 0.119 Uiso 1 1 calc R . .
C4 C 0.1648(4) 0.1274(6) 0.30287(15) 0.0748(17) Uani 1 1 d . . .
H4 H 0.2093 0.1229 0.3356 0.090 Uiso 1 1 calc R . .
C5 C 0.2140(3) 0.1172(4) 0.25146(13) 0.0514(10) Uani 1 1 d . . .
H5 H 0.2936 0.1074 0.2490 0.062 Uiso 1 1 calc R . .
C6 C 0.2999(2) 0.1319(2) -0.01047(11) 0.0245(5) Uani 1 1 d . . .
C7 C 0.3670(3) 0.1449(3) -0.05803(14) 0.0393(7) Uani 1 1 d . . .
H7 H 0.3327 0.1489 -0.0936 0.047 Uiso 1 1 calc R . .
C8 C 0.4835(3) 0.1519(4) -0.05278(17) 0.0537(11) Uani 1 1 d . . .
H8 H 0.5301 0.1613 -0.0845 0.064 Uiso 1 1 calc R . .
C9 C 0.5311(3) 0.1450(4) -0.00002(18) 0.0513(10) Uani 1 1 d . . .
H9 H 0.6109 0.1496 0.0046 0.062 Uiso 1 1 calc R . .
C10 C 0.4620(3) 0.1313(3) 0.04524(15) 0.0379(7) Uani 1 1 d . . .
H10 H 0.4951 0.1265 0.0810 0.045 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C14 O1 C11 105.4(15) . .
O1 C11 C12 106.1(15) . .
O1 C11 H11A 110.5 . .
C12 C11 H11A 110.5 . .
O1 C11 H11B 110.5 . .
C12 C11 H11B 110.5 . .
H11A C11 H11B 108.7 . .
C13 C12 C11 105.5(6) . .
C13 C12 H12A 110.6 . .
C11 C12 H12A 110.6 . .
C13 C12 H12B 110.6 . .
C11 C12 H12B 110.6 . .
H12A C12 H12B 108.8 . .
C12 C13 C14 105.5(6) . .
C12 C13 H13A 110.6 . .
C14 C13 H13A 110.6 . .
C12 C13 H13B 110.6 . .
C14 C13 H13B 110.6 . .
H13A C13 H13B 108.8 . .
O1 C14 C13 108.6(12) . .
O1 C14 H14A 110.0 . .
C13 C14 H14A 110.0 . .
O1 C14 H14B 110.0 . .
C13 C14 H14B 110.0 . .
H14A C14 H14B 108.3 . .
C15 O2 C18 105.4(15) . .
O2 C15 C16 97.2(15) . .
O2 C15 H15A 112.3 . .
C16 C15 H15A 112.3 . .
O2 C15 H15B 112.3 . .
C16 C15 H15B 112.3 . .
H15A C15 H15B 109.9 . .
C15 C16 C17 105.5(6) . .
C15 C16 H16A 110.6 . .
C17 C16 H16A 110.6 . .
C15 C16 H16B 110.6 . .
C17 C16 H16B 110.6 . .
H16A C16 H16B 108.8 . .
C16 C17 C18 105.5(6) . .
C16 C17 H17A 110.6 . .
C18 C17 H17A 110.6 . .
C16 C17 H17B 110.6 . .
C18 C17 H17B 110.6 . .
H17A C17 H17B 108.8 . .
O2 C18 C17 101.6(13) . .
O2 C18 H18A 111.4 . .
C17 C18 H18A 111.4 . .
O2 C18 H18B 111.4 . .
C17 C18 H18B 111.4 . .
H18A C18 H18B 109.3 . .
S1 Pd1 S2 173.15(4) . .
S1 Pd1 S2 87.34(2) . 4
S2 Pd1 S2 92.034(16) . 4
S1 Pd1 Sn1 88.63(2) . .
S2 Pd1 Sn1 91.692(17) . .
S2 Pd1 Sn1 175.372(17) 4 .
S1 Pd1 Pd1 85.17(3) . 2
S2 Pd1 Pd1 101.341(16) . 2
S2 Pd1 Pd1 76.928(16) 4 2
Sn1 Pd1 Pd1 105.008(9) . 2
N1 Sn1 N2 166.74(9) . .
N1 Sn1 Cl1 88.56(8) . .
N2 Sn1 Cl1 87.31(7) . .
N1 Sn1 Cl2 86.00(9) . .
N2 Sn1 Cl2 82.62(6) . .
Cl1 Sn1 Cl2 102.61(4) . .
N1 Sn1 Pd1 97.57(7) . .
N2 Sn1 Pd1 94.21(6) . .
Cl1 Sn1 Pd1 135.31(3) . .
Cl2 Sn1 Pd1 121.91(3) . .
C1 S1 Pd1 114.26(12) . .
C6 S2 Pd1 114.16(9) . .
C6 S2 Pd1 100.19(10) . 3
Pd1 S2 Pd1 109.86(3) . 3
C1 N1 C5 120.6(3) . .
C1 N1 Sn1 116.15(19) . .
C5 N1 Sn1 123.1(2) . .
C6 N2 C10 119.2(3) . .
C6 N2 Sn1 119.48(18) . .
C10 N2 Sn1 121.2(2) . .
N1 C1 C2 119.7(3) . .
N1 C1 S1 123.2(2) . .
C2 C1 S1 117.1(3) . .
C3 C2 C1 119.3(4) . .
C3 C2 H2 120.4 . .
C1 C2 H2 120.4 . .
C2 C3 C4 120.2(4) . .
C2 C3 H3 119.9 . .
C4 C3 H3 119.9 . .
C5 C4 C3 118.4(4) . .
C5 C4 H4 120.8 . .
C3 C4 H4 120.8 . .
N1 C5 C4 121.8(3) . .
N1 C5 H5 119.1 . .
C4 C5 H5 119.1 . .
N2 C6 C7 121.1(3) . .
N2 C6 S2 120.2(2) . .
C7 C6 S2 118.6(2) . .
C8 C7 C6 119.5(3) . .
C8 C7 H7 120.2 . .
C6 C7 H7 120.2 . .
C7 C8 C9 118.7(3) . .
C7 C8 H8 120.6 . .
C9 C8 H8 120.6 . .
C10 C9 C8 119.6(3) . .
C10 C9 H9 120.2 . .
C8 C9 H9 120.2 . .
N2 C10 C9 121.8(3) . .
N2 C10 H10 119.1 . .
C9 C10 H10 119.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
O1 C14 1.450(15) .
O1 C11 1.450(15) .
C11 C12 1.482(12) .
C11 H11A 0.9900 .
C11 H11B 0.9900 .
C12 C13 1.482(12) .
C12 H12A 0.9900 .
C12 H12B 0.9900 .
C13 C14 1.482(12) .
C13 H13A 0.9900 .
C13 H13B 0.9900 .
C14 H14A 0.9900 .
C14 H14B 0.9900 .
O2 C15 1.451(15) .
O2 C18 1.451(15) .
C15 C16 1.482(12) .
C15 H15A 0.9900 .
C15 H15B 0.9900 .
C16 C17 1.482(12) .
C16 H16A 0.9900 .
C16 H16B 0.9900 .
C17 C18 1.482(12) .
C17 H17A 0.9900 .
C17 H17B 0.9900 .
C18 H18A 0.9900 .
C18 H18B 0.9900 .
Pd1 S1 2.2999(8) .
Pd1 S2 2.3182(6) .
Pd1 S2 2.4250(6) 4
Pd1 Sn1 2.4798(3) .
Pd1 Pd1 3.2359(4) 2
Sn1 N1 2.257(3) .
Sn1 N2 2.356(3) .
Sn1 Cl1 2.3572(8) .
Sn1 Cl2 2.3781(9) .
S1 C1 1.753(3) .
S2 C6 1.784(3) .
S2 Pd1 2.4250(6) 3
N1 C1 1.340(5) .
N1 C5 1.359(4) .
N2 C6 1.348(4) .
N2 C10 1.366(4) .
C1 C2 1.413(5) .
C2 C3 1.378(6) .
C2 H2 0.9500 .
C3 C4 1.386(6) .
C3 H3 0.9500 .
C4 C5 1.376(5) .
C4 H4 0.9500 .
C5 H5 0.9500 .
C6 C7 1.404(4) .
C7 C8 1.385(5) .
C7 H7 0.9500 .
C8 C9 1.396(6) .
C8 H8 0.9500 .
C9 C10 1.374(5) .
C9 H9 0.9500 .
C10 H10 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
C14 O1 C11 C12 -30(4) . .
O1 C11 C12 C13 28(3) . .
C11 C12 C13 C14 -15(2) . .
C11 O1 C14 C13 20(4) . .
C12 C13 C14 O1 -3(3) . .
C18 O2 C15 C16 -50(3) . .
O2 C15 C16 C17 39(2) . .
C15 C16 C17 C18 -16(2) . .
C15 O2 C18 C17 41(3) . .
C16 C17 C18 O2 -15(2) . .
S1 Pd1 Sn1 N1 3.73(10) . .
S2 Pd1 Sn1 N1 176.89(9) . .
Pd1 Pd1 Sn1 N1 -80.90(9) 2 .
S1 Pd1 Sn1 N2 -170.19(7) . .
S2 Pd1 Sn1 N2 2.96(7) . .
Pd1 Pd1 Sn1 N2 105.18(6) 2 .
S1 Pd1 Sn1 Cl1 99.38(4) . .
S2 Pd1 Sn1 Cl1 -87.47(3) . .
Pd1 Pd1 Sn1 Cl1 14.75(3) 2 .
S1 Pd1 Sn1 Cl2 -86.26(4) . .
S2 Pd1 Sn1 Cl2 86.89(4) . .
Pd1 Pd1 Sn1 Cl2 -170.89(3) 2 .
S2 Pd1 S1 C1 178.8(2) 4 .
Sn1 Pd1 S1 C1 -3.5(2) . .
Pd1 Pd1 S1 C1 101.7(2) 2 .
S2 Pd1 S2 C6 172.54(11) 4 .
Sn1 Pd1 S2 C6 -4.71(10) . .
Pd1 Pd1 S2 C6 -110.39(10) 2 .
S2 Pd1 S2 Pd1 -75.863(13) 4 3
Sn1 Pd1 S2 Pd1 106.88(2) . 3
Pd1 Pd1 S2 Pd1 1.21(3) 2 3
N2 Sn1 N1 C1 147.9(4) . .
Cl1 Sn1 N1 C1 -140.2(3) . .
Cl2 Sn1 N1 C1 117.0(3) . .
Pd1 Sn1 N1 C1 -4.6(3) . .
N2 Sn1 N1 C5 -27.0(7) . .
Cl1 Sn1 N1 C5 44.9(4) . .
Cl2 Sn1 N1 C5 -57.9(4) . .
Pd1 Sn1 N1 C5 -179.6(3) . .
N1 Sn1 N2 C6 -154.0(4) . .
Cl1 Sn1 N2 C6 134.0(2) . .
Cl2 Sn1 N2 C6 -122.9(2) . .
Pd1 Sn1 N2 C6 -1.3(2) . .
N1 Sn1 N2 C10 21.2(6) . .
Cl1 Sn1 N2 C10 -50.8(3) . .
Cl2 Sn1 N2 C10 52.3(3) . .
Pd1 Sn1 N2 C10 173.9(3) . .
C5 N1 C1 C2 -1.9(8) . .
Sn1 N1 C1 C2 -177.0(5) . .
C5 N1 C1 S1 177.8(4) . .
Sn1 N1 C1 S1 2.7(6) . .
Pd1 S1 C1 N1 1.0(5) . .
Pd1 S1 C1 C2 -179.2(5) . .
N1 C1 C2 C3 1.4(11) . .
S1 C1 C2 C3 -178.4(6) . .
C1 C2 C3 C4 -0.8(13) . .
C2 C3 C4 C5 0.9(12) . .
C1 N1 C5 C4 2.0(8) . .
Sn1 N1 C5 C4 176.7(5) . .
C3 C4 C5 N1 -1.4(10) . .
C10 N2 C6 C7 1.0(5) . .
Sn1 N2 C6 C7 176.4(2) . .
C10 N2 C6 S2 -177.5(3) . .
Sn1 N2 C6 S2 -2.2(3) . .
Pd1 S2 C6 N2 5.1(3) . .
Pd1 S2 C6 N2 -112.3(2) 3 .
Pd1 S2 C6 C7 -173.5(2) . .
Pd1 S2 C6 C7 69.2(3) 3 .
N2 C6 C7 C8 -1.0(6) . .
S2 C6 C7 C8 177.5(3) . .
C6 C7 C8 C9 0.5(7) . .
C7 C8 C9 C10 0.1(7) . .
C6 N2 C10 C9 -0.5(6) . .
Sn1 N2 C10 C9 -175.7(3) . .
C8 C9 C10 N2 -0.1(7) . .
