#------------------------------------------------------------------------------
#$Date: 2017-08-15 05:45:03 +0300 (Tue, 15 Aug 2017) $
#$Revision: 199756 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/04/39/7043967.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7043967
loop_
_publ_author_name
'Choi, Woongjin'
'Lee, Junsu'
'Lee, Yunho'
'Ahn, Kyunghan'
'You, Tae-Soo'
_publ_section_title
;
 Single and Double-Doping Effects on the Thermoelectric Properties of Two
 Zintl Compounds: Eu11Bi8.07(2)Sn1.93 and Eu10.74(2)K0.26Bi9.14(2)Sn0.86
;
_journal_name_full               'Dalton Trans.'
_journal_paper_doi               10.1039/C7DT02410J
_journal_year                    2017
_chemical_formula_moiety         'Bi8.07 Eu11 Sn1.93'
_chemical_formula_sum            'Bi8.07 Eu11 Sn1.93'
_chemical_formula_weight         3587.10
_chemical_name_systematic        Eu11Bi8.07(2)Sn1.93
_space_group_crystal_system      tetragonal
_space_group_IT_number           139
_space_group_name_Hall           '-I 4 2'
_space_group_name_H-M_alt        'I 4/m m m'
_symmetry_space_group_name_Hall  '-I 4 2'
_symmetry_space_group_name_H-M   'I 4/m m m'
_audit_creation_method           SHELXL-2013
_audit_update_record
;
2017-07-03 deposited with the CCDC.
2017-08-14 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   12.5369(18)
_cell_length_b                   12.5369(18)
_cell_length_c                   18.124(3)
_cell_measurement_reflns_used    878
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.37
_cell_measurement_theta_min      3.21
_cell_volume                     2848.6(7)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXL-2013 (Sheldrick, 2013)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0871
_diffrn_reflns_av_unetI/netI     0.0380
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            9514
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.366
_diffrn_reflns_theta_min         3.215
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    75.076
_exptl_absorpt_correction_T_max  0.7458
_exptl_absorpt_correction_T_min  0.3385
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            silver
_exptl_crystal_density_diffrn    8.364
_exptl_crystal_density_meas      8.364
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             5837
_exptl_crystal_preparation       ', electrical conductivity'
_exptl_crystal_recrystallization_method 'From the Melt'
_exptl_crystal_size_max          0.07
_exptl_crystal_size_mid          0.05
_exptl_crystal_size_min          0.03
_refine_diff_density_max         1.934
_refine_diff_density_min         -2.102
_refine_diff_density_rms         0.424
_refine_ls_extinction_coef       0.000058(4)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.093
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     41
_refine_ls_number_reflns         878
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.093
_refine_ls_R_factor_all          0.0372
_refine_ls_R_factor_gt           0.0274
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+43.6939P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0411
_refine_ls_wR_factor_ref         0.0432
_reflns_Friedel_coverage         0.000
_reflns_number_gt                750
_reflns_number_total             878
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7dt02410j2.cif
_cod_data_source_block           yts57_0m
_cod_original_cell_volume        2848.6(9)
_cod_database_code               7043967
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelxl_version_number           2013-3
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'-y, x, z'
'y, -x, z'
'-x, y, -z'
'x, -y, -z'
'y, x, -z'
'-y, -x, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1/2, -y+1/2, z+1/2'
'-y+1/2, x+1/2, z+1/2'
'y+1/2, -x+1/2, z+1/2'
'-x+1/2, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'y+1/2, x+1/2, -z+1/2'
'-y+1/2, -x+1/2, -z+1/2'
'-x, -y, -z'
'x, y, -z'
'y, -x, -z'
'-y, x, -z'
'x, -y, z'
'-x, y, z'
'-y, -x, z'
'y, x, z'
'-x+1/2, -y+1/2, -z+1/2'
'x+1/2, y+1/2, -z+1/2'
'y+1/2, -x+1/2, -z+1/2'
'-y+1/2, x+1/2, -z+1/2'
'x+1/2, -y+1/2, z+1/2'
'-x+1/2, y+1/2, z+1/2'
'-y+1/2, -x+1/2, z+1/2'
'y+1/2, x+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Eu1 Eu 0.0000 0.25149(6) 0.31101(5) 0.0131(2) Uani 1 2 d S T P
Eu2 Eu 0.0000 0.33341(6) 0.10147(4) 0.01022(19) Uani 1 2 d S T P
Eu3 Eu 0.32598(8) 0.32598(8) 0.0000 0.0245(3) Uani 1 4 d S T P
Eu4 Eu 0.0000 0.0000 0.16552(9) 0.0142(4) Uani 1 8 d S T P
Bi1 Bi 0.20554(3) 0.20554(3) 0.17296(4) 0.01220(16) Uani 1 2 d S T P
Bi2 Bi 0.14843(7) 0.5000 0.0000 0.0100(2) Uani 1 4 d S T P
Bi3 Bi 0.11994(9) 0.11994(9) 0.0000 0.0156(6) Uani 0.035(10) 4 d S T P
Sn1 Sn 0.11994(9) 0.11994(9) 0.0000 0.0156(6) Uani 0.965(10) 4 d S T P
Bi4 Bi 0.0000 0.0000 0.37750(7) 0.0123(3) Uani 1 8 d S T P
Bi5 Bi 0.0000 0.5000 0.2500 0.0077(3) Uani 1 8 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
Bi5 Eu1 Bi4 178.62(4) . .
Bi5 Eu1 Bi1 85.365(18) . 3
Bi4 Eu1 Bi1 95.60(2) . 3
Bi5 Eu1 Bi1 85.364(18) . .
Bi4 Eu1 Bi1 95.60(2) . .
Bi1 Eu1 Bi1 90.21(3) 3 .
Bi5 Eu1 Bi2 89.42(2) . 27_455
Bi4 Eu1 Bi2 89.20(3) . 27_455
Bi1 Eu1 Bi2 134.454(15) 3 27_455
Bi1 Eu1 Bi2 134.454(15) . 27_455
Bi5 Eu1 Bi1 83.701(13) . 25
Bi4 Eu1 Bi1 96.129(14) . 25
Bi1 Eu1 Bi1 140.81(2) 3 25
Bi1 Eu1 Bi1 51.492(19) . 25
Bi2 Eu1 Bi1 82.968(16) 27_455 25
Bi5 Eu1 Bi1 83.701(13) . 27_455
Bi4 Eu1 Bi1 96.129(14) . 27_455
Bi1 Eu1 Bi1 51.491(19) 3 27_455
Bi1 Eu1 Bi1 140.81(2) . 27_455
Bi2 Eu1 Bi1 82.968(15) 27_455 27_455
Bi1 Eu1 Bi1 161.17(3) 25 27_455
Bi5 Eu1 Eu2 55.326(17) . .
Bi4 Eu1 Eu2 126.05(3) . .
Bi1 Eu1 Eu2 51.491(15) 3 .
Bi1 Eu1 Eu2 51.490(15) . .
Bi2 Eu1 Eu2 144.75(3) 27_455 .
Bi1 Eu1 Eu2 92.141(16) 25 .
Bi1 Eu1 Eu2 92.141(16) 27_455 .
Bi5 Eu1 Eu2 53.793(15) . 28
Bi4 Eu1 Eu2 125.14(3) . 28
Bi1 Eu1 Eu2 138.79(2) 3 28
Bi1 Eu1 Eu2 91.478(18) . 28
Bi2 Eu1 Eu2 51.033(17) 27_455 28
Bi1 Eu1 Eu2 49.735(13) 25 28
Bi1 Eu1 Eu2 111.44(2) 27_455 28
Eu2 Eu1 Eu2 100.15(2) . 28
Bi5 Eu1 Eu2 53.793(15) . 27_455
Bi4 Eu1 Eu2 125.14(3) . 27_455
Bi1 Eu1 Eu2 91.478(18) 3 27_455
Bi1 Eu1 Eu2 138.79(2) . 27_455
Bi2 Eu1 Eu2 51.033(17) 27_455 27_455
Bi1 Eu1 Eu2 111.44(2) 25 27_455
Bi1 Eu1 Eu2 49.735(13) 27_455 27_455
Eu2 Eu1 Eu2 100.15(2) . 27_455
Eu2 Eu1 Eu2 61.71(2) 28 27_455
Bi5 Eu1 Eu4 120.55(3) . .
Bi4 Eu1 Eu4 60.83(3) . .
Bi1 Eu1 Eu4 55.753(18) 3 .
Bi1 Eu1 Eu4 55.753(18) . .
Bi2 Eu1 Eu4 150.03(3) 27_455 .
Bi1 Eu1 Eu4 99.222(14) 25 .
Bi1 Eu1 Eu4 99.222(14) 27_455 .
Eu2 Eu1 Eu4 65.23(3) . .
Eu2 Eu1 Eu4 146.796(16) 28 .
Eu2 Eu1 Eu4 146.796(16) 27_455 .
Bi5 Eu1 Eu3 119.57(3) . 25
Bi4 Eu1 Eu3 59.33(3) . 25
Bi1 Eu1 Eu3 153.84(3) 3 25
Bi1 Eu1 Eu3 99.049(18) . 25
Bi2 Eu1 Eu3 46.350(15) 27_455 25
Bi1 Eu1 Eu3 56.93(2) 25 25
Bi1 Eu1 Eu3 119.03(2) 27_455 25
Eu2 Eu1 Eu3 148.493(16) . 25
Eu2 Eu1 Eu3 65.82(2) 28 25
Eu2 Eu1 Eu3 97.26(2) 27_455 25
Eu4 Eu1 Eu3 110.36(3) . 25
Bi1 Eu2 Bi1 102.69(3) . 3
Bi1 Eu2 Bi2 94.860(17) . .
Bi1 Eu2 Bi2 162.34(2) 3 .
Bi1 Eu2 Bi2 162.34(2) . 17_565
Bi1 Eu2 Bi2 94.860(17) 3 17_565
Bi2 Eu2 Bi2 67.54(3) . 17_565
Bi1 Eu2 Bi5 89.29(2) . .
Bi1 Eu2 Bi5 89.29(2) 3 .
Bi2 Eu2 Bi5 92.96(2) . .
Bi2 Eu2 Bi5 92.96(2) 17_565 .
Bi1 Eu2 Sn1 99.59(3) . 3
Bi1 Eu2 Sn1 60.680(18) 3 3
Bi2 Eu2 Sn1 114.70(2) . 3
Bi2 Eu2 Sn1 87.17(3) 17_565 3
Bi5 Eu2 Sn1 149.824(19) . 3
Bi1 Eu2 Bi3 99.59(3) . 3
Bi1 Eu2 Bi3 60.680(18) 3 3
Bi2 Eu2 Bi3 114.70(2) . 3
Bi2 Eu2 Bi3 87.17(3) 17_565 3
Bi5 Eu2 Bi3 149.824(19) . 3
Sn1 Eu2 Bi3 0.000(9) 3 3
Bi1 Eu2 Bi3 60.680(18) . .
Bi1 Eu2 Bi3 99.59(3) 3 .
Bi2 Eu2 Bi3 87.17(3) . .
Bi2 Eu2 Bi3 114.70(2) 17_565 .
Bi5 Eu2 Bi3 149.824(19) . .
Sn1 Eu2 Bi3 49.69(5) 3 .
Bi3 Eu2 Bi3 49.69(5) 3 .
Bi1 Eu2 Eu2 113.119(17) . 18
Bi1 Eu2 Eu2 113.119(17) 3 18
Bi2 Eu2 Eu2 56.676(15) . 18
Bi2 Eu2 Eu2 56.677(15) 17_565 18
Bi5 Eu2 Eu2 142.193(14) . 18
Sn1 Eu2 Eu2 59.075(13) 3 18
Bi3 Eu2 Eu2 59.075(13) 3 18
Bi3 Eu2 Eu2 59.075(13) . 18
Bi1 Eu2 Eu1 59.612(17) . .
Bi1 Eu2 Eu1 59.612(17) 3 .
Bi2 Eu2 Eu1 133.88(2) . .
Bi2 Eu2 Eu1 133.88(2) 17_565 .
Bi5 Eu2 Eu1 52.939(18) . .
Sn1 Eu2 Eu1 107.51(2) 3 .
Bi3 Eu2 Eu1 107.51(2) 3 .
Bi3 Eu2 Eu1 107.51(2) . .
Eu2 Eu2 Eu1 164.868(16) 18 .
Bi1 Eu2 Eu1 59.921(13) . 28
Bi1 Eu2 Eu1 133.92(3) 3 28
Bi2 Eu2 Eu1 57.911(18) . 28
Bi2 Eu2 Eu1 108.62(2) 17_565 28
Bi5 Eu2 Eu1 51.530(14) . 28
Sn1 Eu2 Eu1 154.85(3) 3 28
Bi3 Eu2 Eu1 154.85(3) 3 28
Bi3 Eu2 Eu1 105.20(2) . 28
Eu2 Eu2 Eu1 112.922(16) 18 28
Eu1 Eu2 Eu1 75.990(18) . 28
Bi2 Eu3 Bi2 178.85(6) 3_655 .
Bi2 Eu3 Bi3 89.43(3) 3_655 .
Bi2 Eu3 Bi3 89.43(3) . .
Bi2 Eu3 Bi1 89.677(16) 3_655 .
Bi2 Eu3 Bi1 89.676(16) . .
Bi3 Eu3 Bi1 55.74(2) . .
Bi2 Eu3 Bi1 89.677(16) 3_655 18
Bi2 Eu3 Bi1 89.676(16) . 18
Bi3 Eu3 Bi1 55.74(2) . 18
Bi1 Eu3 Bi1 111.47(4) . 18
Bi2 Eu3 Bi4 90.47(2) 3_655 25
Bi2 Eu3 Bi4 90.47(2) . 25
Bi3 Eu3 Bi4 144.26(2) . 25
Bi1 Eu3 Bi4 88.53(2) . 25
Bi1 Eu3 Bi4 160.00(4) 18 25
Bi2 Eu3 Bi4 90.47(2) 3_655 9_554
Bi2 Eu3 Bi4 90.47(2) . 9_554
Bi3 Eu3 Bi4 144.26(2) . 9_554
Bi1 Eu3 Bi4 160.00(4) . 9_554
Bi1 Eu3 Bi4 88.53(2) 18 9_554
Bi4 Eu3 Bi4 71.47(4) 25 9_554
Bi2 Eu3 Eu1 57.870(12) 3_655 25
Bi2 Eu3 Eu1 122.409(14) . 25
Bi3 Eu3 Eu1 101.83(2) . 25
Bi1 Eu3 Eu1 55.769(13) . 25
Bi1 Eu3 Eu1 142.50(3) 18 25
Bi4 Eu3 Eu1 49.796(18) 25 25
Bi4 Eu3 Eu1 108.22(3) 9_554 25
Bi2 Eu3 Eu1 122.409(14) 3_655 28
Bi2 Eu3 Eu1 57.870(12) . 28
Bi3 Eu3 Eu1 101.83(2) . 28
Bi1 Eu3 Eu1 55.769(13) . 28
Bi1 Eu3 Eu1 142.50(3) 18 28
Bi4 Eu3 Eu1 49.796(18) 25 28
Bi4 Eu3 Eu1 108.22(3) 9_554 28
Eu1 Eu3 Eu1 64.54(2) 25 28
Bi2 Eu3 Eu1 57.870(12) 3_655 10_554
Bi2 Eu3 Eu1 122.409(14) . 10_554
Bi3 Eu3 Eu1 101.83(2) . 10_554
Bi1 Eu3 Eu1 142.50(3) . 10_554
Bi1 Eu3 Eu1 55.769(13) 18 10_554
Bi4 Eu3 Eu1 108.22(3) 25 10_554
Bi4 Eu3 Eu1 49.796(18) 9_554 10_554
Eu1 Eu3 Eu1 110.23(2) 25 10_554
Eu1 Eu3 Eu1 156.34(4) 28 10_554
Bi2 Eu3 Eu1 122.409(14) 3_655 11_554
Bi2 Eu3 Eu1 57.870(12) . 11_554
Bi3 Eu3 Eu1 101.83(2) . 11_554
Bi1 Eu3 Eu1 142.50(3) . 11_554
Bi1 Eu3 Eu1 55.769(13) 18 11_554
Bi4 Eu3 Eu1 108.22(3) 25 11_554
Bi4 Eu3 Eu1 49.796(18) 9_554 11_554
Eu1 Eu3 Eu1 156.34(4) 25 11_554
Eu1 Eu3 Eu1 110.23(2) 28 11_554
Eu1 Eu3 Eu1 64.54(2) 10_554 11_554
Bi1 Eu4 Bi1 89.922(2) 2 4
Bi1 Eu4 Bi1 89.922(2) 2 3
Bi1 Eu4 Bi1 175.76(6) 4 3
Bi1 Eu4 Bi1 175.76(6) 2 .
Bi1 Eu4 Bi1 89.922(2) 4 .
Bi1 Eu4 Bi1 89.922(2) 3 .
Bi1 Eu4 Bi3 127.45(5) 2 .
Bi1 Eu4 Bi3 91.73(2) 4 .
Bi1 Eu4 Bi3 91.73(2) 3 .
Bi1 Eu4 Bi3 56.79(3) . .
Bi1 Eu4 Sn1 56.79(3) 2 17
Bi1 Eu4 Sn1 91.73(2) 4 17
Bi1 Eu4 Sn1 91.73(2) 3 17
Bi1 Eu4 Sn1 127.45(5) . 17
Bi3 Eu4 Sn1 70.66(5) . 17
Bi1 Eu4 Bi3 56.79(3) 2 17
Bi1 Eu4 Bi3 91.73(2) 4 17
Bi1 Eu4 Bi3 91.73(2) 3 17
Bi1 Eu4 Bi3 127.45(5) . 17
Bi3 Eu4 Bi3 70.66(5) . 17
Sn1 Eu4 Bi3 0.00(6) 17 17
Bi1 Eu4 Sn1 91.73(2) 2 19
Bi1 Eu4 Sn1 56.79(3) 4 19
Bi1 Eu4 Sn1 127.45(5) 3 19
Bi1 Eu4 Sn1 91.73(2) . 19
Bi3 Eu4 Sn1 48.28(3) . 19
Sn1 Eu4 Sn1 48.28(3) 17 19
Bi3 Eu4 Sn1 48.28(3) 17 19
Bi1 Eu4 Sn1 91.73(2) 2 3
Bi1 Eu4 Sn1 127.45(5) 4 3
Bi1 Eu4 Sn1 56.79(3) 3 3
Bi1 Eu4 Sn1 91.73(2) . 3
Bi3 Eu4 Sn1 48.28(3) . 3
Sn1 Eu4 Sn1 48.28(3) 17 3
Bi3 Eu4 Sn1 48.28(3) 17 3
Sn1 Eu4 Sn1 70.66(5) 19 3
Bi1 Eu4 Bi3 91.73(2) 2 19
Bi1 Eu4 Bi3 56.79(3) 4 19
Bi1 Eu4 Bi3 127.45(5) 3 19
Bi1 Eu4 Bi3 91.73(2) . 19
Bi3 Eu4 Bi3 48.28(3) . 19
Sn1 Eu4 Bi3 48.28(3) 17 19
Bi3 Eu4 Bi3 48.28(3) 17 19
Sn1 Eu4 Bi3 0.00(6) 19 19
Sn1 Eu4 Bi3 70.66(5) 3 19
Bi1 Eu4 Bi3 91.73(2) 2 3
Bi1 Eu4 Bi3 127.45(5) 4 3
Bi1 Eu4 Bi3 56.79(3) 3 3
Bi1 Eu4 Bi3 91.73(2) . 3
Bi3 Eu4 Bi3 48.28(3) . 3
Sn1 Eu4 Bi3 48.28(3) 17 3
Bi3 Eu4 Bi3 48.28(3) 17 3
Sn1 Eu4 Bi3 70.66(5) 19 3
Sn1 Eu4 Bi3 0.00(6) 3 3
Bi3 Eu4 Bi3 70.66(5) 19 3
Bi1 Bi1 Eu2 116.390(17) 25 .
Bi1 Bi1 Eu2 116.390(17) 25 4
Eu2 Bi1 Eu2 127.20(3) . 4
Bi1 Bi1 Bi3 176.39(4) 25 .
Eu2 Bi1 Bi3 63.621(17) . .
Eu2 Bi1 Bi3 63.621(17) 4 .
Bi1 Bi1 Eu1 65.94(2) 25 .
Eu2 Bi1 Eu1 68.90(2) . .
Eu2 Bi1 Eu1 137.55(2) 4 .
Bi3 Bi1 Eu1 116.72(3) . .
Bi1 Bi1 Eu1 65.93(2) 25 4
Eu2 Bi1 Eu1 137.55(2) . 4
Eu2 Bi1 Eu1 68.90(2) 4 4
Bi3 Bi1 Eu1 116.72(3) . 4
Eu1 Bi1 Eu1 75.60(3) . 4
Bi1 Bi1 Eu4 121.57(4) 25 .
Eu2 Bi1 Eu4 77.113(19) . .
Eu2 Bi1 Eu4 77.114(19) 4 .
Bi3 Bi1 Eu4 62.05(4) . .
Eu1 Bi1 Eu4 68.70(3) . .
Eu1 Bi1 Eu4 68.70(3) 4 .
Bi1 Bi1 Eu1 62.57(2) 25 28
Eu2 Bi1 Eu1 70.344(18) . 28
Eu2 Bi1 Eu1 136.96(2) 4 28
Bi3 Bi1 Eu1 114.72(3) . 28
Eu1 Bi1 Eu1 83.82(2) . 28
Eu1 Bi1 Eu1 128.508(19) 4 28
Eu4 Bi1 Eu1 143.294(13) . 28
Bi1 Bi1 Eu1 62.57(2) 25 25
Eu2 Bi1 Eu1 136.96(2) . 25
Eu2 Bi1 Eu1 70.344(18) 4 25
Bi3 Bi1 Eu1 114.72(3) . 25
Eu1 Bi1 Eu1 128.508(19) . 25
Eu1 Bi1 Eu1 83.82(2) 4 25
Eu4 Bi1 Eu1 143.294(13) . 25
Eu1 Bi1 Eu1 73.14(3) 28 25
Bi1 Bi1 Eu3 116.29(3) 25 .
Eu2 Bi1 Eu3 78.052(19) . .
Eu2 Bi1 Eu3 78.051(19) 4 .
Bi3 Bi1 Eu3 60.10(3) . .
Eu1 Bi1 Eu3 141.946(14) . .
Eu1 Bi1 Eu3 141.946(14) 4 .
Eu4 Bi1 Eu3 122.14(4) . .
Eu1 Bi1 Eu3 67.30(2) 28 .
Eu1 Bi1 Eu3 67.30(2) 25 .
Eu3 Bi2 Eu3 88.85(6) 19_565 .
Eu3 Bi2 Eu2 146.478(16) 19_565 18
Eu3 Bi2 Eu2 87.72(2) . 18
Eu3 Bi2 Eu2 87.72(2) 19_565 2_565
Eu3 Bi2 Eu2 146.478(16) . 2_565
Eu2 Bi2 Eu2 112.46(3) 18 2_565
Eu3 Bi2 Eu2 87.72(2) 19_565 17_565
Eu3 Bi2 Eu2 146.478(15) . 17_565
Eu2 Bi2 Eu2 77.20(3) 18 17_565
Eu2 Bi2 Eu2 66.65(3) 2_565 17_565
Eu3 Bi2 Eu2 146.478(16) 19_565 .
Eu3 Bi2 Eu2 87.72(2) . .
Eu2 Bi2 Eu2 66.65(3) 18 .
Eu2 Bi2 Eu2 77.20(3) 2_565 .
Eu2 Bi2 Eu2 112.46(3) 17_565 .
Eu3 Bi2 Eu1 75.780(16) 19_565 28
Eu3 Bi2 Eu1 75.780(16) . 28
Eu2 Bi2 Eu1 134.995(16) 18 28
Eu2 Bi2 Eu1 71.056(17) 2_565 28
Eu2 Bi2 Eu1 134.995(16) 17_565 28
Eu2 Bi2 Eu1 71.056(16) . 28
Eu3 Bi2 Eu1 75.780(16) 19_565 11_554
Eu3 Bi2 Eu1 75.780(16) . 11_554
Eu2 Bi2 Eu1 71.056(17) 18 11_554
Eu2 Bi2 Eu1 134.995(16) 2_565 11_554
Eu2 Bi2 Eu1 71.056(17) 17_565 11_554
Eu2 Bi2 Eu1 134.995(16) . 11_554
Eu1 Bi2 Eu1 139.76(4) 28 11_554
Sn1 Bi3 Sn1 90.0 19 3
Sn1 Bi3 Bi3 0.0 19 19
Sn1 Bi3 Bi3 90.0 3 19
Sn1 Bi3 Bi3 90.0 19 3
Sn1 Bi3 Bi3 0.00(4) 3 3
Bi3 Bi3 Bi3 90.0 19 3
Sn1 Bi3 Bi1 107.947(17) 19 .
Sn1 Bi3 Bi1 107.947(17) 3 .
Bi3 Bi3 Bi1 107.947(17) 19 .
Bi3 Bi3 Bi1 107.947(17) 3 .
Sn1 Bi3 Bi1 107.946(17) 19 18
Sn1 Bi3 Bi1 107.946(17) 3 18
Bi3 Bi3 Bi1 107.946(17) 19 18
Bi3 Bi3 Bi1 107.946(17) 3 18
Bi1 Bi3 Bi1 128.33(5) . 18
Sn1 Bi3 Eu2 138.41(2) 19 .
Sn1 Bi3 Eu2 65.15(2) 3 .
Bi3 Bi3 Eu2 138.41(2) 19 .
Bi3 Bi3 Eu2 65.15(2) 3 .
Bi1 Bi3 Eu2 55.700(14) . .
Bi1 Bi3 Eu2 111.20(3) 18 .
Sn1 Bi3 Eu2 65.15(2) 19 4
Sn1 Bi3 Eu2 138.41(2) 3 4
Bi3 Bi3 Eu2 65.15(2) 19 4
Bi3 Bi3 Eu2 138.41(2) 3 4
Bi1 Bi3 Eu2 55.700(14) . 4
Bi1 Bi3 Eu2 111.20(3) 18 4
Eu2 Bi3 Eu2 111.37(3) . 4
Sn1 Bi3 Eu2 138.41(2) 19 18
Sn1 Bi3 Eu2 65.15(2) 3 18
Bi3 Bi3 Eu2 138.41(2) 19 18
Bi3 Bi3 Eu2 65.15(2) 3 18
Bi1 Bi3 Eu2 111.20(3) . 18
Bi1 Bi3 Eu2 55.700(14) 18 18
Eu2 Bi3 Eu2 61.85(3) . 18
Eu2 Bi3 Eu2 153.20(5) 4 18
Sn1 Bi3 Eu2 65.15(2) 19 19
Sn1 Bi3 Eu2 138.41(2) 3 19
Bi3 Bi3 Eu2 65.15(2) 19 19
Bi3 Bi3 Eu2 138.41(2) 3 19
Bi1 Bi3 Eu2 111.20(3) . 19
Bi1 Bi3 Eu2 55.700(14) 18 19
Eu2 Bi3 Eu2 153.20(5) . 19
Eu2 Bi3 Eu2 61.85(3) 4 19
Eu2 Bi3 Eu2 111.37(3) 18 19
Sn1 Bi3 Eu3 135.0 19 .
Sn1 Bi3 Eu3 135.0 3 .
Bi3 Bi3 Eu3 135.0 19 .
Bi3 Bi3 Eu3 135.0 3 .
Bi1 Bi3 Eu3 64.17(3) . .
Bi1 Bi3 Eu3 64.17(3) 18 .
Eu2 Bi3 Eu3 76.60(3) . .
Eu2 Bi3 Eu3 76.60(3) 4 .
Eu2 Bi3 Eu3 76.60(3) 18 .
Eu2 Bi3 Eu3 76.60(3) 19 .
Sn1 Bi3 Eu4 65.863(16) 19 .
Sn1 Bi3 Eu4 65.863(16) 3 .
Bi3 Bi3 Eu4 65.863(16) 19 .
Bi3 Bi3 Eu4 65.863(16) 3 .
Bi1 Bi3 Eu4 61.17(2) . .
Bi1 Bi3 Eu4 170.50(5) 18 .
Eu2 Bi3 Eu4 73.425(17) . .
Eu2 Bi3 Eu4 73.426(17) 4 .
Eu2 Bi3 Eu4 123.591(19) 18 .
Eu2 Bi3 Eu4 123.591(19) 19 .
Eu3 Bi3 Eu4 125.33(3) . .
Eu1 Bi4 Eu1 82.676(17) . 3
Eu1 Bi4 Eu1 138.16(5) . 2
Eu1 Bi4 Eu1 82.676(17) 3 2
Eu1 Bi4 Eu1 82.676(17) . 4
Eu1 Bi4 Eu1 138.16(5) 3 4
Eu1 Bi4 Eu1 82.677(17) 2 4
Eu1 Bi4 Eu3 70.877(17) . 25
Eu1 Bi4 Eu3 138.130(15) 3 25
Eu1 Bi4 Eu3 138.130(15) 2 25
Eu1 Bi4 Eu3 70.876(17) 4 25
Eu1 Bi4 Eu3 70.877(17) . 27_455
Eu1 Bi4 Eu3 70.876(17) 3 27_455
Eu1 Bi4 Eu3 138.130(15) 2 27_455
Eu1 Bi4 Eu3 138.130(15) 4 27_455
Eu3 Bi4 Eu3 70.05(2) 25 27_455
Eu1 Bi4 Eu3 138.131(15) . 11_545
Eu1 Bi4 Eu3 138.130(15) 3 11_545
Eu1 Bi4 Eu3 70.876(17) 2 11_545
Eu1 Bi4 Eu3 70.876(17) 4 11_545
Eu3 Bi4 Eu3 70.05(2) 25 11_545
Eu3 Bi4 Eu3 108.53(4) 27_455 11_545
Eu1 Bi4 Eu3 138.131(15) . 9_445
Eu1 Bi4 Eu3 70.876(17) 3 9_445
Eu1 Bi4 Eu3 70.876(17) 2 9_445
Eu1 Bi4 Eu3 138.130(15) 4 9_445
Eu3 Bi4 Eu3 108.53(4) 25 9_445
Eu3 Bi4 Eu3 70.05(2) 27_455 9_445
Eu3 Bi4 Eu3 70.05(2) 11_545 9_445
Eu1 Bi4 Eu4 69.08(3) . .
Eu1 Bi4 Eu4 69.08(3) 3 .
Eu1 Bi4 Eu4 69.08(3) 2 .
Eu1 Bi4 Eu4 69.08(3) 4 .
Eu3 Bi4 Eu4 125.74(2) 25 .
Eu3 Bi4 Eu4 125.74(2) 27_455 .
Eu3 Bi4 Eu4 125.74(2) 11_545 .
Eu3 Bi4 Eu4 125.74(2) 9_445 .
Eu1 Bi5 Eu1 96.424(10) 27_455 2_565
Eu1 Bi5 Eu1 140.92(3) 27_455 28
Eu1 Bi5 Eu1 96.424(10) 2_565 28
Eu1 Bi5 Eu1 96.423(10) 27_455 .
Eu1 Bi5 Eu1 140.92(3) 2_565 .
Eu1 Bi5 Eu1 96.423(9) 28 .
Eu1 Bi5 Eu2 147.35(2) 27_455 28
Eu1 Bi5 Eu2 74.676(12) 2_565 28
Eu1 Bi5 Eu2 71.74(2) 28 28
Eu1 Bi5 Eu2 74.677(12) . 28
Eu1 Bi5 Eu2 71.74(2) 27_455 27_455
Eu1 Bi5 Eu2 74.676(12) 2_565 27_455
Eu1 Bi5 Eu2 147.35(2) 28 27_455
Eu1 Bi5 Eu2 74.677(12) . 27_455
Eu2 Bi5 Eu2 75.61(3) 28 27_455
Eu1 Bi5 Eu2 74.676(12) 27_455 2_565
Eu1 Bi5 Eu2 71.74(2) 2_565 2_565
Eu1 Bi5 Eu2 74.676(12) 28 2_565
Eu1 Bi5 Eu2 147.35(2) . 2_565
Eu2 Bi5 Eu2 128.628(18) 28 2_565
Eu2 Bi5 Eu2 128.628(17) 27_455 2_565
Eu1 Bi5 Eu2 74.676(12) 27_455 .
Eu1 Bi5 Eu2 147.35(2) 2_565 .
Eu1 Bi5 Eu2 74.676(12) 28 .
Eu1 Bi5 Eu2 71.73(2) . .
Eu2 Bi5 Eu2 128.627(17) 28 .
Eu2 Bi5 Eu2 128.627(18) 27_455 .
Eu2 Bi5 Eu2 75.61(3) 2_565 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 Bi5 3.3060(9) .
Eu1 Bi4 3.3753(10) .
Eu1 Bi1 3.6376(9) 3
Eu1 Bi1 3.6376(9) .
Eu1 Bi2 3.6478(10) 27_455
Eu1 Bi1 3.7421(7) 25
Eu1 Bi1 3.7421(7) 27_455
Eu1 Eu2 3.9341(13) .
Eu1 Eu2 4.0724(10) 28
Eu1 Eu2 4.0724(10) 27_455
Eu1 Eu4 4.1102(14) .
Eu1 Eu3 4.1756(9) 25
Eu2 Bi1 3.2998(7) .
Eu2 Bi1 3.2998(7) 3
Eu2 Bi2 3.3477(9) .
Eu2 Bi2 3.3477(9) 17_565
Eu2 Bi5 3.4071(8) .
Eu2 Sn1 3.5785(9) 3
Eu2 Bi3 3.5785(9) 3
Eu2 Bi3 3.5785(9) .
Eu2 Eu2 3.6781(16) 18
Eu2 Eu1 4.0724(10) 28
Eu3 Bi2 3.1168(7) 3_655
Eu3 Bi2 3.1168(7) .
Eu3 Bi3 3.653(2) .
Eu3 Bi1 3.7929(11) .
Eu3 Bi1 3.7929(11) 18
Eu3 Bi4 3.8011(14) 25
Eu3 Bi4 3.8011(14) 9_554
Eu3 Eu1 4.1755(9) 25
Eu3 Eu1 4.1755(9) 28
Eu3 Eu1 4.1755(9) 10_554
Eu3 Eu1 4.1755(9) 11_554
Eu4 Bi1 3.6466(8) 2
Eu4 Bi1 3.6466(8) 4
Eu4 Bi1 3.6466(8) 3
Eu4 Bi1 3.6466(8) .
Eu4 Bi3 3.6771(17) .
Eu4 Sn1 3.6771(17) 17
Eu4 Bi3 3.6771(17) 17
Eu4 Sn1 3.6771(17) 19
Eu4 Sn1 3.6771(17) 3
Eu4 Bi3 3.6771(17) 19
Eu4 Bi3 3.6771(17) 3
Bi1 Bi1 3.2070(13) 25
Bi1 Eu2 3.2998(7) 4
Bi1 Bi3 3.4827(10) .
Bi1 Eu1 3.6376(9) 4
Bi1 Eu1 3.7421(7) 28
Bi1 Eu1 3.7421(7) 25
Bi2 Eu3 3.1168(7) 19_565
Bi2 Eu2 3.3476(9) 18
Bi2 Eu2 3.3476(9) 2_565
Bi2 Eu2 3.3476(9) 17_565
Bi2 Eu1 3.6478(10) 28
Bi2 Eu1 3.6478(10) 11_554
Bi3 Sn1 3.007(2) 19
Bi3 Sn1 3.007(2) 3
Bi3 Bi3 3.007(2) 19
Bi3 Bi3 3.007(2) 3
Bi3 Bi1 3.4828(10) 18
Bi3 Eu2 3.5785(9) 4
Bi3 Eu2 3.5785(9) 18
Bi3 Eu2 3.5785(9) 19
Bi4 Eu1 3.3753(10) 3
Bi4 Eu1 3.3753(10) 2
Bi4 Eu1 3.3753(10) 4
Bi4 Eu3 3.8012(14) 25
Bi4 Eu3 3.8012(14) 27_455
Bi4 Eu3 3.8012(14) 11_545
Bi4 Eu3 3.8012(14) 9_445
Bi5 Eu1 3.3060(9) 27_455
Bi5 Eu1 3.3060(9) 2_565
Bi5 Eu1 3.3060(9) 28
Bi5 Eu2 3.4071(9) 28
Bi5 Eu2 3.4071(9) 27_455
Bi5 Eu2 3.4071(8) 2_565
