#------------------------------------------------------------------------------
#$Date: 2016-03-25 23:59:21 +0200 (Fri, 25 Mar 2016) $
#$Revision: 180054 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/00/7050059.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7050059
loop_
_publ_author_name
'Zheng, Xiang-Jun'
'Jin, Lin-Pei'
'Gao, Song'
'Lu, Shao-Zhe'
_publ_section_title
;
 Second ligand-directed self-assembly of lanthanide(iii) coordination
 polymers with 1,4-naphthalenedicarboxylate
;
_journal_issue                   6
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              798
_journal_paper_doi               10.1039/b415337e
_journal_volume                  29
_journal_year                    2005
_chemical_formula_sum            'C51 H36 Eu2 N3 O15'
_chemical_formula_weight         1234.75
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.980(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.240(5)
_cell_length_b                   22.191(7)
_cell_length_c                   15.185(5)
_cell_measurement_reflns_used    1006
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      24.31
_cell_measurement_theta_min      2.55
_cell_volume                     4676(3)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0689
_diffrn_reflns_av_sigmaI/netI    0.0991
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       26
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -9
_diffrn_reflns_number            19567
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.35
_exptl_absorpt_coefficient_mu    2.734
_exptl_absorpt_correction_T_max  1.000000
_exptl_absorpt_correction_T_min  0.722898
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   SADABS
_exptl_crystal_density_diffrn    1.754
_exptl_crystal_density_meas      0
_exptl_crystal_density_method    'not measured'
_exptl_crystal_F_000             2436
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.036
_refine_diff_density_min         -0.704
_refine_diff_density_rms         0.140
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.962
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     640
_refine_ls_number_reflns         8160
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.962
_refine_ls_R_factor_all          0.0845
_refine_ls_R_factor_gt           0.0423
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0557
_refine_ls_wR_factor_ref         0.0645
_reflns_number_gt                5526
_reflns_number_total             8160
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b415337e.txt
_cod_data_source_block           complex3
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed
to 'multi-scan' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 
;
_cod_original_cell_volume        4676(2)
_cod_original_sg_symbol_H-M      P2(1)/n
_cod_database_code               7050059
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.49844(2) 0.724319(13) 0.564060(19) 0.01769(9) Uani 1 1 d . . .
Eu2 Eu 0.79775(2) 0.754122(13) 0.665435(19) 0.01656(8) Uani 1 1 d . . .
O1 O 0.5964(3) 0.64222(18) 0.6125(3) 0.0365(12) Uani 1 1 d . . .
O2 O 0.7537(3) 0.65238(19) 0.6581(3) 0.0369(12) Uani 1 1 d . . .
O3 O 0.6302(3) 0.33425(18) 0.7167(3) 0.0321(12) Uani 1 1 d . . .
O4 O 0.7536(3) 0.35770(18) 0.8260(3) 0.0334(12) Uani 1 1 d . . .
O5 O 0.6702(3) 0.76308(17) 0.5308(2) 0.0249(10) Uani 1 1 d . . .
O6 O 0.5464(3) 0.74689(19) 0.4186(2) 0.0294(10) Uani 1 1 d . . .
O7 O 0.8855(3) 0.73272(19) 0.1507(2) 0.0309(11) Uani 1 1 d . . .
O8 O 0.9108(3) 0.8295(2) 0.1609(3) 0.0402(13) Uani 1 1 d . . .
O9 O 0.6108(3) 0.75552(18) 0.6996(3) 0.0286(11) Uani 1 1 d . . .
O10 O 0.7409(3) 0.7366(2) 0.8038(2) 0.0349(13) Uani 1 1 d . . .
O11 O 0.4183(3) 0.6959(2) 1.1039(3) 0.0415(13) Uani 1 1 d . . .
O12 O 0.3775(3) 0.78664(19) 1.0539(3) 0.0318(11) Uani 1 1 d . . .
O13 O 0.4565(3) 0.64100(17) 0.4611(3) 0.0336(12) Uani 1 1 d . . .
H13A H 0.4975 0.6144 0.4574 0.040 Uiso 1 1 d R . .
H13B H 0.3923 0.6262 0.4449 0.040 Uiso 1 1 d R . .
O14 O 0.3370(3) 0.74116(19) 0.4721(2) 0.0403(13) Uani 1 1 d . . .
H14A H 0.3235 0.7723 0.4996 0.048 Uiso 1 1 d R . .
H14B H 0.3157 0.7429 0.4152 0.048 Uiso 1 1 d R . .
O15 O 0.9369(3) 0.70941(18) 0.7592(2) 0.0317(12) Uani 1 1 d . . .
H15A H 0.9700 0.7231 0.8087 0.038 Uiso 1 1 d R . .
H15B H 0.9622 0.6729 0.7410 0.038 Uiso 1 1 d R . .
N1 N 0.6004(5) 0.5574(3) 0.4380(4) 0.056(2) Uani 1 1 d . . .
N2 N 0.9443(5) 0.3803(3) 0.2823(5) 0.0543(19) Uani 1 1 d . . .
N3 N 0.4898(4) 0.8415(2) 0.5363(4) 0.0288(14) Uani 1 1 d . . .
C1 C 0.6787(5) 0.6220(3) 0.6455(4) 0.0254(16) Uani 1 1 d . . .
C2 C 0.6857(4) 0.5562(2) 0.6708(4) 0.0194(15) Uani 1 1 d . . .
C3 C 0.6133(5) 0.5332(3) 0.7061(4) 0.0356(18) Uani 1 1 d . . .
H3 H 0.5619 0.5576 0.7118 0.043 Uiso 1 1 calc R . .
C4 C 0.6160(5) 0.4725(3) 0.7341(4) 0.0348(18) Uani 1 1 d . . .
H4 H 0.5675 0.4578 0.7602 0.042 Uiso 1 1 calc R . .
C5 C 0.6881(5) 0.4353(3) 0.7235(4) 0.0223(15) Uani 1 1 d . . .
C6 C 0.7629(4) 0.4572(3) 0.6836(4) 0.0197(15) Uani 1 1 d . . .
C7 C 0.7630(4) 0.5188(3) 0.6590(4) 0.0219(15) Uani 1 1 d . . .
C8 C 0.8386(5) 0.5388(3) 0.6181(4) 0.0309(17) Uani 1 1 d . . .
H8 H 0.8400 0.5789 0.6008 0.037 Uiso 1 1 calc R . .
C9 C 0.9077(5) 0.5012(3) 0.6041(4) 0.0380(18) Uani 1 1 d . . .
H9 H 0.9566 0.5155 0.5781 0.046 Uiso 1 1 calc R . .
C10 C 0.9063(5) 0.4399(3) 0.6286(4) 0.0412(19) Uani 1 1 d . . .
H10 H 0.9536 0.4138 0.6178 0.049 Uiso 1 1 calc R . .
C11 C 0.8368(5) 0.4192(3) 0.6675(4) 0.0339(18) Uani 1 1 d . . .
H11 H 0.8373 0.3789 0.6842 0.041 Uiso 1 1 calc R . .
C12 C 0.6904(5) 0.3716(3) 0.7569(4) 0.0282(17) Uani 1 1 d . . .
C13 C 0.6327(5) 0.7624(3) 0.4463(4) 0.0218(15) Uani 1 1 d . . .
C14 C 0.6915(4) 0.7757(3) 0.3785(4) 0.0195(14) Uani 1 1 d . . .
C15 C 0.6821(5) 0.7366(3) 0.3069(4) 0.0305(17) Uani 1 1 d . . .
H15 H 0.6353 0.7066 0.2991 0.037 Uiso 1 1 calc R . .
C16 C 0.7417(5) 0.7412(3) 0.2457(4) 0.0309(17) Uani 1 1 d . . .
H16 H 0.7359 0.7128 0.1997 0.037 Uiso 1 1 calc R . .
C17 C 0.8081(5) 0.7861(3) 0.2513(4) 0.0246(16) Uani 1 1 d . . .
C18 C 0.8141(5) 0.8316(3) 0.3184(4) 0.0254(16) Uani 1 1 d . . .
C19 C 0.7554(5) 0.8250(3) 0.3841(4) 0.0250(16) Uani 1 1 d . . .
C20 C 0.7610(5) 0.8711(3) 0.4505(4) 0.0311(17) Uani 1 1 d . . .
H20 H 0.7211 0.8688 0.4912 0.037 Uiso 1 1 calc R . .
C21 C 0.8224(6) 0.9178(3) 0.4559(4) 0.042(2) Uani 1 1 d . . .
H21 H 0.8263 0.9464 0.5013 0.051 Uiso 1 1 calc R . .
C22 C 0.8805(5) 0.9232(3) 0.3931(5) 0.043(2) Uani 1 1 d . . .
H22 H 0.9218 0.9561 0.3965 0.052 Uiso 1 1 calc R . .
C23 C 0.8776(5) 0.8814(3) 0.3275(4) 0.0358(18) Uani 1 1 d . . .
H23 H 0.9181 0.8855 0.2876 0.043 Uiso 1 1 calc R . .
C24 C 0.8724(5) 0.7835(3) 0.1838(4) 0.0286(16) Uani 1 1 d . . .
C25 C 0.6515(5) 0.7416(3) 0.7801(4) 0.0236(15) Uani 1 1 d . . .
C26 C 0.5928(4) 0.7351(3) 0.8504(4) 0.0204(15) Uani 1 1 d . . .
C27 C 0.5248(4) 0.7766(3) 0.8509(4) 0.0257(15) Uani 1 1 d . . .
H27 H 0.5115 0.8052 0.8050 0.031 Uiso 1 1 calc R . .
C28 C 0.4726(4) 0.7778(3) 0.9201(4) 0.0279(16) Uani 1 1 d . . .
H28 H 0.4265 0.8075 0.9201 0.034 Uiso 1 1 calc R . .
C29 C 0.4901(4) 0.7351(3) 0.9868(4) 0.0226(16) Uani 1 1 d . . .
C30 C 0.5591(5) 0.6896(3) 0.9873(4) 0.0250(16) Uani 1 1 d . . .
C31 C 0.6116(5) 0.6887(3) 0.9178(4) 0.0252(16) Uani 1 1 d . . .
C32 C 0.6771(5) 0.6419(3) 0.9148(4) 0.0389(19) Uani 1 1 d . . .
H32 H 0.7080 0.6402 0.8670 0.047 Uiso 1 1 calc R . .
C33 C 0.6966(6) 0.5984(3) 0.9810(5) 0.057(2) Uani 1 1 d . . .
H33 H 0.7416 0.5683 0.9794 0.068 Uiso 1 1 calc R . .
C34 C 0.6468(6) 0.6007(3) 1.0510(5) 0.055(2) Uani 1 1 d . . .
H34 H 0.6596 0.5716 1.0963 0.066 Uiso 1 1 calc R . .
C35 C 0.5811(5) 0.6438(3) 1.0544(4) 0.0353(18) Uani 1 1 d . . .
H35 H 0.5493 0.6436 1.1016 0.042 Uiso 1 1 calc R . .
C36 C 0.4251(4) 0.7391(3) 1.0528(4) 0.0241(16) Uani 1 1 d . . .
C37 C 0.6714(8) 0.5824(4) 0.4067(6) 0.080(3) Uani 1 1 d . . .
H37 H 0.6753 0.6242 0.4075 0.096 Uiso 1 1 calc R . .
C38 C 0.7399(7) 0.5511(4) 0.3730(5) 0.072(3) Uani 1 1 d . . .
H38 H 0.7860 0.5713 0.3494 0.087 Uiso 1 1 calc R . .
C39 C 0.7371(6) 0.4891(3) 0.3759(4) 0.0372(19) Uani 1 1 d . . .
C40 C 0.6694(6) 0.4630(3) 0.4143(5) 0.048(2) Uani 1 1 d . . .
H40 H 0.6689 0.4214 0.4219 0.058 Uiso 1 1 calc R . .
C41 C 0.6019(6) 0.4982(4) 0.4419(5) 0.051(2) Uani 1 1 d . . .
H41 H 0.5544 0.4789 0.4647 0.062 Uiso 1 1 calc R . .
C42 C 0.9072(6) 0.4301(4) 0.2396(6) 0.059(2) Uani 1 1 d . . .
H42 H 0.9264 0.4409 0.1872 0.070 Uiso 1 1 calc R . .
C43 C 0.8427(6) 0.4662(3) 0.2683(5) 0.049(2) Uani 1 1 d . . .
H43 H 0.8210 0.5010 0.2361 0.059 Uiso 1 1 calc R . .
C44 C 0.8097(5) 0.4521(3) 0.3430(5) 0.0402(19) Uani 1 1 d . . .
C45 C 0.8466(6) 0.4003(4) 0.3883(5) 0.051(2) Uani 1 1 d . . .
H45 H 0.8270 0.3879 0.4398 0.061 Uiso 1 1 calc R . .
C46 C 0.9132(6) 0.3674(4) 0.3552(6) 0.055(2) Uani 1 1 d . . .
H46 H 0.9384 0.3332 0.3873 0.066 Uiso 1 1 calc R . .
C47 C 0.5313(6) 0.8786(3) 0.6001(5) 0.047(2) Uani 1 1 d . . .
H47 H 0.5578 0.8624 0.6567 0.056 Uiso 1 1 calc R . .
C48 C 0.5387(6) 0.9410(3) 0.5895(5) 0.056(3) Uani 1 1 d . . .
H48 H 0.5714 0.9646 0.6373 0.067 Uiso 1 1 calc R . .
C49 C 0.4968(5) 0.9676(3) 0.5071(4) 0.0302(18) Uani 1 1 d . . .
C50 C 0.4480(5) 0.9284(3) 0.4409(4) 0.040(2) Uani 1 1 d . . .
H50 H 0.4161 0.9435 0.3851 0.048 Uiso 1 1 calc R . .
C51 C 0.4467(5) 0.8679(3) 0.4575(5) 0.0381(19) Uani 1 1 d . . .
H51 H 0.4139 0.8433 0.4112 0.046 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1 Eu1 O9 73.55(14) . . ?
O1 Eu1 O13 69.25(14) . . ?
O9 Eu1 O13 142.76(14) . . ?
O1 Eu1 O14 136.70(15) . . ?
O9 Eu1 O14 143.74(14) . . ?
O13 Eu1 O14 71.41(14) . . ?
O1 Eu1 O8 77.09(16) . 4_576 ?
O9 Eu1 O8 87.55(14) . 4_576 ?
O13 Eu1 O8 85.97(14) . 4_576 ?
O14 Eu1 O8 82.88(15) . 4_576 ?
O1 Eu1 O7 123.37(15) . 4_576 ?
O9 Eu1 O7 79.75(14) . 4_576 ?
O13 Eu1 O7 122.87(15) . 4_576 ?
O14 Eu1 O7 66.71(13) . 4_576 ?
O8 Eu1 O7 52.45(14) 4_576 4_576 ?
O1 Eu1 O6 99.98(15) . . ?
O9 Eu1 O6 115.83(14) . . ?
O13 Eu1 O6 69.99(14) . . ?
O14 Eu1 O6 82.73(14) . . ?
O8 Eu1 O6 154.92(14) 4_576 . ?
O7 Eu1 O6 136.65(13) 4_576 . ?
O1 Eu1 N3 146.33(17) . . ?
O9 Eu1 N3 81.43(15) . . ?
O13 Eu1 N3 131.17(15) . . ?
O14 Eu1 N3 75.68(16) . . ?
O8 Eu1 N3 124.58(15) 4_576 . ?
O7 Eu1 N3 72.14(14) 4_576 . ?
O6 Eu1 N3 70.94(15) . . ?
O1 Eu1 O5 78.83(14) . . ?
O9 Eu1 O5 67.57(12) . . ?
O13 Eu1 O5 102.86(13) . . ?
O14 Eu1 O5 127.74(13) . . ?
O8 Eu1 O5 149.38(14) 4_576 . ?
O7 Eu1 O5 133.35(13) 4_576 . ?
O6 Eu1 O5 49.03(12) . . ?
N3 Eu1 O5 70.88(14) . . ?
O1 Eu1 C24 99.90(18) . 4_576 ?
O9 Eu1 C24 82.18(16) . 4_576 ?
O13 Eu1 C24 105.65(17) . 4_576 ?
O14 Eu1 C24 74.02(16) . 4_576 ?
O8 Eu1 C24 25.99(15) 4_576 4_576 ?
O7 Eu1 C24 26.49(15) 4_576 4_576 ?
O6 Eu1 C24 156.34(16) . 4_576 ?
N3 Eu1 C24 98.60(18) . 4_576 ?
O5 Eu1 C24 148.92(15) . 4_576 ?
O1 Eu1 C13 89.52(16) . . ?
O9 Eu1 C13 92.18(15) . . ?
O13 Eu1 C13 85.86(15) . . ?
O14 Eu1 C13 105.06(15) . . ?
O8 Eu1 C13 166.12(15) 4_576 . ?
O7 Eu1 C13 141.06(14) 4_576 . ?
O6 Eu1 C13 24.04(13) . . ?
N3 Eu1 C13 68.99(15) . . ?
O5 Eu1 C13 24.99(12) . . ?
C24 Eu1 C13 167.10(18) 4_576 . ?
O1 Eu1 Eu2 61.47(11) . . ?
O9 Eu1 Eu2 39.19(10) . . ?
O13 Eu1 Eu2 115.93(11) . . ?
O14 Eu1 Eu2 157.73(10) . . ?
O8 Eu1 Eu2 117.69(11) 4_576 . ?
O7 Eu1 Eu2 117.68(10) 4_576 . ?
O6 Eu1 Eu2 80.68(10) . . ?
N3 Eu1 Eu2 84.90(12) . . ?
O5 Eu1 Eu2 32.25(8) . . ?
C24 Eu1 Eu2 120.39(12) 4_576 . ?
C13 Eu1 Eu2 56.84(12) . . ?
O1 Eu1 H14A 150.8 . . ?
O9 Eu1 H14A 125.6 . . ?
O13 Eu1 H14A 89.6 . . ?
O14 Eu1 H14A 18.3 . . ?
O8 Eu1 H14A 81.7 4_576 . ?
O7 Eu1 H14A 51.9 4_576 . ?
O6 Eu1 H14A 90.8 . . ?
N3 Eu1 H14A 62.9 . . ?
O5 Eu1 H14A 127.0 . . ?
C24 Eu1 H14A 65.7 4_576 . ?
C13 Eu1 H14A 109.4 . . ?
Eu2 Eu1 H14A 147.6 . . ?
O2 Eu2 O15 78.72(15) . . ?
O2 Eu2 O11 129.37(16) . 4_675 ?
O15 Eu2 O11 81.57(15) . 4_675 ?
O2 Eu2 O12 76.62(15) . 4_675 ?
O15 Eu2 O12 78.68(14) . 4_675 ?
O11 Eu2 O12 53.89(14) 4_675 4_675 ?
O2 Eu2 O5 84.07(14) . . ?
O15 Eu2 O5 154.92(13) . . ?
O11 Eu2 O5 95.75(14) 4_675 . ?
O12 Eu2 O5 79.68(14) 4_675 . ?
O2 Eu2 O4 146.80(15) . 2_656 ?
O15 Eu2 O4 125.69(14) . 2_656 ?
O11 Eu2 O4 80.45(15) 4_675 2_656 ?
O12 Eu2 O4 125.99(14) 4_675 2_656 ?
O5 Eu2 O4 77.83(13) . 2_656 ?
O2 Eu2 O10 75.54(15) . . ?
O15 Eu2 O10 79.14(14) . . ?
O11 Eu2 O10 144.17(14) 4_675 . ?
O12 Eu2 O10 147.18(15) 4_675 . ?
O5 Eu2 O10 114.09(13) . . ?
O4 Eu2 O10 86.71(15) 2_656 . ?
O2 Eu2 O3 139.67(14) . 2_656 ?
O15 Eu2 O3 73.94(13) . 2_656 ?
O11 Eu2 O3 75.11(14) 4_675 2_656 ?
O12 Eu2 O3 124.78(15) 4_675 2_656 ?
O5 Eu2 O3 129.70(13) . 2_656 ?
O4 Eu2 O3 51.98(13) 2_656 2_656 ?
O10 Eu2 O3 70.67(14) . 2_656 ?
O2 Eu2 C36 103.28(18) . 4_675 ?
O15 Eu2 C36 79.57(16) . 4_675 ?
O11 Eu2 C36 26.86(15) 4_675 4_675 ?
O12 Eu2 C36 27.04(15) 4_675 4_675 ?
O5 Eu2 C36 86.87(15) . 4_675 ?
O4 Eu2 C36 103.27(17) 2_656 4_675 ?
O10 Eu2 C36 158.47(16) . 4_675 ?
O3 Eu2 C36 100.29(17) 2_656 4_675 ?
O2 Eu2 O9 76.45(14) . . ?
O15 Eu2 O9 125.94(13) . . ?
O11 Eu2 O9 148.41(14) 4_675 . ?
O12 Eu2 O9 138.04(13) 4_675 . ?
O5 Eu2 O9 66.05(12) . . ?
O4 Eu2 O9 70.82(13) 2_656 . ?
O10 Eu2 O9 48.46(12) . . ?
O3 Eu2 O9 96.31(13) 2_656 . ?
C36 Eu2 O9 152.89(15) 4_675 . ?
O2 Eu2 C12 153.21(17) . 2_656 ?
O15 Eu2 C12 99.79(18) . 2_656 ?
O11 Eu2 C12 75.99(16) 4_675 2_656 ?
O12 Eu2 C12 129.70(16) 4_675 2_656 ?
O5 Eu2 C12 103.75(18) . 2_656 ?
O4 Eu2 C12 25.99(16) 2_656 2_656 ?
O10 Eu2 C12 77.91(16) . 2_656 ?
O3 Eu2 C12 25.99(15) 2_656 2_656 ?
C36 Eu2 C12 102.71(19) 4_675 2_656 ?
O9 Eu2 C12 83.37(16) . 2_656 ?
O2 Eu2 C25 74.06(16) . . ?
O15 Eu2 C25 101.92(16) . . ?
O11 Eu2 C25 156.18(15) 4_675 . ?
O12 Eu2 C25 149.90(15) 4_675 . ?
O5 Eu2 C25 90.59(15) . . ?
O4 Eu2 C25 78.49(16) 2_656 . ?
O10 Eu2 C25 23.65(14) . . ?
O3 Eu2 C25 83.17(15) 2_656 . ?
C36 Eu2 C25 176.52(18) 4_675 . ?
O9 Eu2 C25 24.82(13) . . ?
C12 Eu2 C25 80.20(17) 2_656 . ?
C1 O1 Eu1 148.8(4) . . ?
C1 O2 Eu2 138.1(4) . . ?
C12 O3 Eu2 89.8(4) . 2_646 ?
C12 O4 Eu2 96.3(4) . 2_646 ?
C13 O5 Eu2 156.2(4) . . ?
C13 O5 Eu1 89.6(3) . . ?
Eu2 O5 Eu1 110.51(13) . . ?
C13 O6 Eu1 101.5(4) . . ?
C24 O7 Eu1 92.3(4) . 4_675 ?
C24 O8 Eu1 94.8(4) . 4_675 ?
C25 O9 Eu1 145.7(4) . . ?
C25 O9 Eu2 85.9(3) . . ?
Eu1 O9 Eu2 108.22(14) . . ?
C25 O10 Eu2 104.5(4) . . ?
C36 O11 Eu2 92.8(4) . 4_576 ?
C36 O12 Eu2 92.0(4) . 4_576 ?
Eu1 O13 H13A 120.5 . . ?
Eu1 O13 H13B 121.1 . . ?
H13A O13 H13B 112.4 . . ?
Eu1 O14 H14A 97.5 . . ?
Eu1 O14 H14B 131.7 . . ?
H14A O14 H14B 113.2 . . ?
Eu2 O15 H15A 127.1 . . ?
Eu2 O15 H15B 119.9 . . ?
H15A O15 H15B 113.0 . . ?
C41 N1 C37 115.1(7) . . ?
C46 N2 C42 114.9(7) . . ?
C47 N3 C51 114.9(6) . . ?
C47 N3 Eu1 120.5(5) . . ?
C51 N3 Eu1 124.6(4) . . ?
O2 C1 O1 124.3(6) . . ?
O2 C1 C2 118.8(6) . . ?
O1 C1 C2 116.9(6) . . ?
C3 C2 C7 120.5(6) . . ?
C3 C2 C1 116.7(6) . . ?
C7 C2 C1 122.7(6) . . ?
C2 C3 C4 120.2(6) . . ?
C2 C3 H3 119.9 . . ?
C4 C3 H3 119.9 . . ?
C5 C4 C3 121.2(6) . . ?
C5 C4 H4 119.4 . . ?
C3 C4 H4 119.4 . . ?
C4 C5 C6 120.1(6) . . ?
C4 C5 C12 119.6(6) . . ?
C6 C5 C12 120.3(6) . . ?
C11 C6 C7 119.0(6) . . ?
C11 C6 C5 121.9(6) . . ?
C7 C6 C5 119.1(6) . . ?
C6 C7 C2 118.8(6) . . ?
C6 C7 C8 117.4(6) . . ?
C2 C7 C8 123.7(6) . . ?
C9 C8 C7 121.8(6) . . ?
C9 C8 H8 119.1 . . ?
C7 C8 H8 119.1 . . ?
C8 C9 C10 120.2(6) . . ?
C8 C9 H9 119.9 . . ?
C10 C9 H9 119.9 . . ?
C11 C10 C9 120.0(7) . . ?
C11 C10 H10 120.0 . . ?
C9 C10 H10 120.0 . . ?
C10 C11 C6 121.7(6) . . ?
C10 C11 H11 119.2 . . ?
C6 C11 H11 119.2 . . ?
O3 C12 O4 121.9(6) . . ?
O3 C12 C5 120.0(6) . . ?
O4 C12 C5 118.1(6) . . ?
O3 C12 Eu2 64.2(3) . 2_646 ?
O4 C12 Eu2 57.7(3) . 2_646 ?
C5 C12 Eu2 175.3(5) . 2_646 ?
O6 C13 O5 119.9(5) . . ?
O6 C13 C14 118.7(5) . . ?
O5 C13 C14 121.3(6) . . ?
O6 C13 Eu1 54.5(3) . . ?
O5 C13 Eu1 65.4(3) . . ?
C14 C13 Eu1 172.2(4) . . ?
C15 C14 C19 119.0(6) . . ?
C15 C14 C13 116.8(6) . . ?
C19 C14 C13 124.3(5) . . ?
C14 C15 C16 121.0(6) . . ?
C14 C15 H15 119.5 . . ?
C16 C15 H15 119.5 . . ?
C17 C16 C15 121.9(6) . . ?
C17 C16 H16 119.1 . . ?
C15 C16 H16 119.1 . . ?
C16 C17 C18 119.5(6) . . ?
C16 C17 C24 116.3(6) . . ?
C18 C17 C24 124.2(6) . . ?
C23 C18 C17 123.9(6) . . ?
C23 C18 C19 117.9(6) . . ?
C17 C18 C19 118.2(6) . . ?
C14 C19 C20 122.1(6) . . ?
C14 C19 C18 120.0(5) . . ?
C20 C19 C18 117.9(6) . . ?
C21 C20 C19 121.8(7) . . ?
C21 C20 H20 119.1 . . ?
C19 C20 H20 119.1 . . ?
C20 C21 C22 120.0(7) . . ?
C20 C21 H21 120.0 . . ?
C22 C21 H21 120.0 . . ?
C23 C22 C21 121.0(7) . . ?
C23 C22 H22 119.5 . . ?
C21 C22 H22 119.5 . . ?
C22 C23 C18 121.4(7) . . ?
C22 C23 H23 119.3 . . ?
C18 C23 H23 119.3 . . ?
O8 C24 O7 120.4(6) . . ?
O8 C24 C17 121.7(6) . . ?
O7 C24 C17 117.9(6) . . ?
O8 C24 Eu1 59.3(3) . 4_675 ?
O7 C24 Eu1 61.2(3) . 4_675 ?
C17 C24 Eu1 177.4(4) . 4_675 ?
O10 C25 O9 121.1(5) . . ?
O10 C25 C26 118.7(5) . . ?
O9 C25 C26 120.1(6) . . ?
O10 C25 Eu2 51.8(3) . . ?
O9 C25 Eu2 69.3(3) . . ?
C26 C25 Eu2 170.4(4) . . ?
C27 C26 C31 120.6(6) . . ?
C27 C26 C25 117.2(6) . . ?
C31 C26 C25 122.1(6) . . ?
C26 C27 C28 121.2(6) . . ?
C26 C27 H27 119.4 . . ?
C28 C27 H27 119.4 . . ?
C29 C28 C27 119.9(6) . . ?
C29 C28 H28 120.1 . . ?
C27 C28 H28 120.1 . . ?
C28 C29 C30 120.7(6) . . ?
C28 C29 C36 114.5(6) . . ?
C30 C29 C36 124.7(5) . . ?
C29 C30 C31 119.3(6) . . ?
C29 C30 C35 123.8(6) . . ?
C31 C30 C35 116.9(6) . . ?
C32 C31 C30 119.9(6) . . ?
C32 C31 C26 121.8(6) . . ?
C30 C31 C26 118.3(6) . . ?
C33 C32 C31 121.4(7) . . ?
C33 C32 H32 119.3 . . ?
C31 C32 H32 119.3 . . ?
C32 C33 C34 118.4(7) . . ?
C32 C33 H33 120.8 . . ?
C34 C33 H33 120.8 . . ?
C35 C34 C33 121.8(7) . . ?
C35 C34 H34 119.1 . . ?
C33 C34 H34 119.1 . . ?
C34 C35 C30 121.5(6) . . ?
C34 C35 H35 119.2 . . ?
C30 C35 H35 119.2 . . ?
O11 C36 O12 121.2(6) . . ?
O11 C36 C29 120.8(6) . . ?
O12 C36 C29 118.0(5) . . ?
O11 C36 Eu2 60.3(3) . 4_576 ?
O12 C36 Eu2 61.0(3) . 4_576 ?
C29 C36 Eu2 176.8(4) . 4_576 ?
N1 C37 C38 125.4(9) . . ?
N1 C37 H37 117.3 . . ?
C38 C37 H37 117.3 . . ?
C39 C38 C37 117.4(9) . . ?
C39 C38 H38 121.3 . . ?
C37 C38 H38 121.3 . . ?
C40 C39 C38 117.8(7) . . ?
C40 C39 C44 121.3(7) . . ?
C38 C39 C44 120.8(7) . . ?
C39 C40 C41 120.0(8) . . ?
C39 C40 H40 120.0 . . ?
C41 C40 H40 120.0 . . ?
N1 C41 C40 124.0(8) . . ?
N1 C41 H41 118.0 . . ?
C40 C41 H41 118.0 . . ?
N2 C42 C43 123.8(8) . . ?
N2 C42 H42 118.1 . . ?
C43 C42 H42 118.1 . . ?
C44 C43 C42 121.1(8) . . ?
C44 C43 H43 119.4 . . ?
C42 C43 H43 119.4 . . ?
C43 C44 C45 116.2(7) . . ?
C43 C44 C39 123.3(7) . . ?
C45 C44 C39 120.4(7) . . ?
C46 C45 C44 118.4(8) . . ?
C46 C45 H45 120.8 . . ?
C44 C45 H45 120.8 . . ?
N2 C46 C45 125.6(8) . . ?
N2 C46 H46 117.2 . . ?
C45 C46 H46 117.2 . . ?
N3 C47 C48 124.9(7) . . ?
N3 C47 H47 117.5 . . ?
C48 C47 H47 117.5 . . ?
C49 C48 C47 119.6(6) . . ?
C49 C48 H48 120.2 . . ?
C47 C48 H48 120.2 . . ?
C48 C49 C50 115.4(6) . . ?
C48 C49 C49 121.5(8) . 3_676 ?
C50 C49 C49 123.1(8) . 3_676 ?
C51 C50 C49 120.4(6) . . ?
C51 C50 H50 119.8 . . ?
C49 C50 H50 119.8 . . ?
N3 C51 C50 124.7(6) . . ?
N3 C51 H51 117.7 . . ?
C50 C51 H51 117.7 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O1 2.312(4) . ?
Eu1 O9 2.408(4) . ?
Eu1 O13 2.409(4) . ?
Eu1 O14 2.436(4) . ?
Eu1 O8 2.443(4) 4_576 ?
Eu1 O7 2.484(4) 4_576 ?
Eu1 O6 2.505(4) . ?
Eu1 N3 2.632(5) . ?
Eu1 O5 2.744(4) . ?
Eu1 C24 2.832(7) 4_576 ?
Eu1 C13 3.017(6) . ?
Eu1 Eu2 4.2458(13) . ?
Eu1 H14A 2.6829 . ?
Eu2 O2 2.339(4) . ?
Eu2 O15 2.381(4) . ?
Eu2 O11 2.402(4) 4_675 ?
Eu2 O12 2.417(4) 4_675 ?
Eu2 O5 2.419(4) . ?
Eu2 O4 2.424(4) 2_656 ?
Eu2 O10 2.446(4) . ?
Eu2 O3 2.567(4) 2_656 ?
Eu2 C36 2.762(6) 4_675 ?
Eu2 O9 2.825(4) . ?
Eu2 C12 2.851(6) 2_656 ?
Eu2 C25 3.012(6) . ?
O1 C1 1.250(7) . ?
O2 C1 1.241(7) . ?
O3 C12 1.249(7) . ?
O3 Eu2 2.567(4) 2_646 ?
O4 C12 1.257(7) . ?
O4 Eu2 2.424(4) 2_646 ?
O5 C13 1.275(6) . ?
O6 C13 1.254(7) . ?
O7 C24 1.264(7) . ?
O7 Eu1 2.484(4) 4_675 ?
O8 C24 1.245(7) . ?
O8 Eu1 2.443(4) 4_675 ?
O9 C25 1.268(6) . ?
O10 C25 1.248(7) . ?
O11 C36 1.250(7) . ?
O11 Eu2 2.402(4) 4_576 ?
O12 C36 1.257(7) . ?
O12 Eu2 2.417(4) 4_576 ?
O13 H13A 0.8410 . ?
O13 H13B 0.9510 . ?
O14 H14A 0.8502 . ?
O14 H14B 0.8508 . ?
O15 H15A 0.8495 . ?
O15 H15B 0.9524 . ?
N1 C41 1.317(9) . ?
N1 C37 1.331(11) . ?
N2 C46 1.313(9) . ?
N2 C42 1.328(9) . ?
N3 C47 1.307(8) . ?
N3 C51 1.351(7) . ?
C1 C2 1.508(8) . ?
C2 C3 1.363(8) . ?
C2 C7 1.421(8) . ?
C3 C4 1.410(8) . ?
C3 H3 0.9300 . ?
C4 C5 1.355(8) . ?
C4 H4 0.9300 . ?
C5 C6 1.423(8) . ?
C5 C12 1.500(8) . ?
C6 C11 1.412(8) . ?
C6 C7 1.418(8) . ?
C7 C8 1.428(8) . ?
C8 C9 1.344(8) . ?
C8 H8 0.9300 . ?
C9 C10 1.412(8) . ?
C9 H9 0.9300 . ?
C10 C11 1.343(9) . ?
C10 H10 0.9300 . ?
C11 H11 0.9300 . ?
C12 Eu2 2.851(6) 2_646 ?
C13 C14 1.496(8) . ?
C14 C15 1.373(7) . ?
C14 C19 1.414(8) . ?
C15 C16 1.396(8) . ?
C15 H15 0.9300 . ?
C16 C17 1.364(8) . ?
C16 H16 0.9300 . ?
C17 C18 1.423(8) . ?
C17 C24 1.521(8) . ?
C18 C23 1.415(8) . ?
C18 C19 1.445(8) . ?
C19 C20 1.425(8) . ?
C20 C21 1.347(9) . ?
C20 H20 0.9300 . ?
C21 C22 1.401(9) . ?
C21 H21 0.9300 . ?
C22 C23 1.356(8) . ?
C22 H22 0.9300 . ?
C23 H23 0.9300 . ?
C24 Eu1 2.832(7) 4_675 ?
C25 C26 1.504(8) . ?
C26 C27 1.338(8) . ?
C26 C31 1.435(8) . ?
C27 C28 1.418(7) . ?
C27 H27 0.9300 . ?
C28 C29 1.368(8) . ?
C28 H28 0.9300 . ?
C29 C30 1.409(8) . ?
C29 C36 1.511(8) . ?
C30 C31 1.422(8) . ?
C30 C35 1.424(8) . ?
C31 C32 1.404(8) . ?
C32 C33 1.376(9) . ?
C32 H32 0.9300 . ?
C33 C34 1.405(9) . ?
C33 H33 0.9300 . ?
C34 C35 1.348(9) . ?
C34 H34 0.9300 . ?
C35 H35 0.9300 . ?
C36 Eu2 2.762(6) 4_576 ?
C37 C38 1.385(11) . ?
C37 H37 0.9300 . ?
C38 C39 1.379(9) . ?
C38 H38 0.9300 . ?
C39 C40 1.363(10) . ?
C39 C44 1.491(9) . ?
C40 C41 1.374(9) . ?
C40 H40 0.9300 . ?
C41 H41 0.9300 . ?
C42 C43 1.361(9) . ?
C42 H42 0.9300 . ?
C43 C44 1.359(9) . ?
C43 H43 0.9300 . ?
C44 C45 1.382(9) . ?
C45 C46 1.377(10) . ?
C45 H45 0.9300 . ?
C46 H46 0.9300 . ?
C47 C48 1.401(8) . ?
C47 H47 0.9300 . ?
C48 C49 1.390(8) . ?
C48 H48 0.9300 . ?
C49 C50 1.391(8) . ?
C49 C49 1.461(11) 3_676 ?
C50 C51 1.366(8) . ?
C50 H50 0.9300 . ?
C51 H51 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O9 Eu1 O1 C1 -40.1(8) . . . . ?
O13 Eu1 O1 C1 138.1(9) . . . . ?
O14 Eu1 O1 C1 164.1(8) . . . . ?
O8 Eu1 O1 C1 -131.3(8) 4_576 . . . ?
O7 Eu1 O1 C1 -105.4(8) 4_576 . . . ?
O6 Eu1 O1 C1 74.1(8) . . . . ?
N3 Eu1 O1 C1 3.6(10) . . . . ?
O5 Eu1 O1 C1 29.6(8) . . . . ?
C24 Eu1 O1 C1 -118.8(8) 4_576 . . . ?
C13 Eu1 O1 C1 52.4(8) . . . . ?
Eu2 Eu1 O1 C1 0.5(8) . . . . ?
O15 Eu2 O2 C1 152.9(6) . . . . ?
O11 Eu2 O2 C1 -138.1(6) 4_675 . . . ?
O12 Eu2 O2 C1 -126.2(6) 4_675 . . . ?
O5 Eu2 O2 C1 -45.5(6) . . . . ?
O4 Eu2 O2 C1 11.5(7) 2_656 . . . ?
O10 Eu2 O2 C1 71.3(6) . . . . ?
O3 Eu2 O2 C1 105.0(6) 2_656 . . . ?
C36 Eu2 O2 C1 -130.8(6) 4_675 . . . ?
O9 Eu2 O2 C1 21.3(6) . . . . ?
C12 Eu2 O2 C1 63.5(8) 2_656 . . . ?
C25 Eu2 O2 C1 46.8(6) . . . . ?
O2 Eu2 O5 C13 -88.3(9) . . . . ?
O15 Eu2 O5 C13 -41.6(10) . . . . ?
O11 Eu2 O5 C13 40.8(9) 4_675 . . . ?
O12 Eu2 O5 C13 -10.9(9) 4_675 . . . ?
O4 Eu2 O5 C13 119.7(9) 2_656 . . . ?
O10 Eu2 O5 C13 -159.6(9) . . . . ?
O3 Eu2 O5 C13 116.2(9) 2_656 . . . ?
C36 Eu2 O5 C13 15.4(9) 4_675 . . . ?
O9 Eu2 O5 C13 -166.1(9) . . . . ?
C12 Eu2 O5 C13 117.7(9) 2_656 . . . ?
C25 Eu2 O5 C13 -162.2(9) . . . . ?
O2 Eu2 O5 Eu1 57.68(16) . . . . ?
O15 Eu2 O5 Eu1 104.4(3) . . . . ?
O11 Eu2 O5 Eu1 -173.23(15) 4_675 . . . ?
O12 Eu2 O5 Eu1 135.12(17) 4_675 . . . ?
O4 Eu2 O5 Eu1 -94.32(16) 2_656 . . . ?
O10 Eu2 O5 Eu1 -13.6(2) . . . . ?
O3 Eu2 O5 Eu1 -97.83(19) 2_656 . . . ?
C36 Eu2 O5 Eu1 161.38(19) 4_675 . . . ?
O9 Eu2 O5 Eu1 -20.10(12) . . . . ?
C12 Eu2 O5 Eu1 -96.29(18) 2_656 . . . ?
C25 Eu2 O5 Eu1 -16.23(16) . . . . ?
O1 Eu1 O5 C13 113.8(3) . . . . ?
O9 Eu1 O5 C13 -169.6(3) . . . . ?
O13 Eu1 O5 C13 48.3(3) . . . . ?
O14 Eu1 O5 C13 -28.0(4) . . . . ?
O8 Eu1 O5 C13 152.5(3) 4_576 . . . ?
O7 Eu1 O5 C13 -120.4(3) 4_576 . . . ?
O6 Eu1 O5 C13 -0.1(3) . . . . ?
N3 Eu1 O5 C13 -81.1(3) . . . . ?
C24 Eu1 O5 C13 -155.5(4) 4_576 . . . ?
Eu2 Eu1 O5 C13 166.9(4) . . . . ?
O1 Eu1 O5 Eu2 -53.16(16) . . . . ?
O9 Eu1 O5 Eu2 23.50(14) . . . . ?
O13 Eu1 O5 Eu2 -118.61(15) . . . . ?
O14 Eu1 O5 Eu2 165.09(14) . . . . ?
O8 Eu1 O5 Eu2 -14.5(3) 4_576 . . . ?
O7 Eu1 O5 Eu2 72.6(2) 4_576 . . . ?
O6 Eu1 O5 Eu2 -167.1(2) . . . . ?
N3 Eu1 O5 Eu2 111.92(18) . . . . ?
C24 Eu1 O5 Eu2 37.5(4) 4_576 . . . ?
C13 Eu1 O5 Eu2 -166.9(4) . . . . ?
O1 Eu1 O6 C13 -65.4(4) . . . . ?
O9 Eu1 O6 C13 11.0(4) . . . . ?
O13 Eu1 O6 C13 -128.9(4) . . . . ?
O14 Eu1 O6 C13 158.3(4) . . . . ?
O8 Eu1 O6 C13 -146.3(4) 4_576 . . . ?
O7 Eu1 O6 C13 114.0(4) 4_576 . . . ?
N3 Eu1 O6 C13 81.0(4) . . . . ?
O5 Eu1 O6 C13 0.1(3) . . . . ?
C24 Eu1 O6 C13 147.8(5) 4_576 . . . ?
Eu2 Eu1 O6 C13 -6.8(3) . . . . ?
O1 Eu1 O9 C25 -45.6(7) . . . . ?
O13 Eu1 O9 C25 -48.4(8) . . . . ?
O14 Eu1 O9 C25 106.1(7) . . . . ?
O8 Eu1 O9 C25 31.7(7) 4_576 . . . ?
O7 Eu1 O9 C25 83.9(7) 4_576 . . . ?
O6 Eu1 O9 C25 -138.9(7) . . . . ?
N3 Eu1 O9 C25 157.2(7) . . . . ?
O5 Eu1 O9 C25 -130.1(7) . . . . ?
C24 Eu1 O9 C25 57.2(7) 4_576 . . . ?
C13 Eu1 O9 C25 -134.5(7) . . . . ?
Eu2 Eu1 O9 C25 -110.4(7) . . . . ?
O1 Eu1 O9 Eu2 64.78(16) . . . . ?
O13 Eu1 O9 Eu2 62.0(3) . . . . ?
O14 Eu1 O9 Eu2 -143.51(19) . . . . ?
O8 Eu1 O9 Eu2 142.04(16) 4_576 . . . ?
O7 Eu1 O9 Eu2 -165.71(16) 4_576 . . . ?
O6 Eu1 O9 Eu2 -28.53(19) . . . . ?
N3 Eu1 O9 Eu2 -92.44(16) . . . . ?
O5 Eu1 O9 Eu2 -19.67(12) . . . . ?
C24 Eu1 O9 Eu2 167.6(2) 4_576 . . . ?
C13 Eu1 O9 Eu2 -24.07(16) . . . . ?
O2 Eu2 O9 C25 81.3(3) . . . . ?
O15 Eu2 O9 C25 16.3(4) . . . . ?
O11 Eu2 O9 C25 -130.1(3) 4_675 . . . ?
O12 Eu2 O9 C25 132.7(3) 4_675 . . . ?
O5 Eu2 O9 C25 170.7(3) . . . . ?
O4 Eu2 O9 C25 -104.4(3) 2_656 . . . ?
O10 Eu2 O9 C25 -1.3(3) . . . . ?
O3 Eu2 O9 C25 -58.4(3) 2_656 . . . ?
C36 Eu2 O9 C25 174.0(4) 4_675 . . . ?
C12 Eu2 O9 C25 -81.0(3) 2_656 . . . ?
O2 Eu2 O9 Eu1 -66.75(16) . . . . ?
O15 Eu2 O9 Eu1 -131.71(15) . . . . ?
O11 Eu2 O9 Eu1 81.9(3) 4_675 . . . ?
O12 Eu2 O9 Eu1 -15.4(3) 4_675 . . . ?
O5 Eu2 O9 Eu1 22.72(14) . . . . ?
O4 Eu2 O9 Eu1 107.57(17) 2_656 . . . ?
O10 Eu2 O9 Eu1 -149.3(2) . . . . ?
O3 Eu2 O9 Eu1 153.58(15) 2_656 . . . ?
C36 Eu2 O9 Eu1 26.0(4) 4_675 . . . ?
C12 Eu2 O9 Eu1 130.99(19) 2_656 . . . ?
C25 Eu2 O9 Eu1 -148.0(4) . . . . ?
O2 Eu2 O10 C25 -83.2(4) . . . . ?
O15 Eu2 O10 C25 -164.2(4) . . . . ?
O11 Eu2 O10 C25 137.1(4) 4_675 . . . ?
O12 Eu2 O10 C25 -116.0(4) 4_675 . . . ?
O5 Eu2 O10 C25 -6.6(4) . . . . ?
O4 Eu2 O10 C25 68.5(4) 2_656 . . . ?
O3 Eu2 O10 C25 119.1(4) 2_656 . . . ?
C36 Eu2 O10 C25 -172.8(5) 4_675 . . . ?
O9 Eu2 O10 C25 1.3(3) . . . . ?
C12 Eu2 O10 C25 93.2(4) 2_656 . . . ?
O1 Eu1 N3 C47 -51.0(6) . . . . ?
O9 Eu1 N3 C47 -8.9(5) . . . . ?
O13 Eu1 N3 C47 -168.6(5) . . . . ?
O14 Eu1 N3 C47 142.7(6) . . . . ?
O8 Eu1 N3 C47 72.1(6) 4_576 . . . ?
O7 Eu1 N3 C47 73.0(5) 4_576 . . . ?
O6 Eu1 N3 C47 -130.2(6) . . . . ?
O5 Eu1 N3 C47 -78.1(5) . . . . ?
C24 Eu1 N3 C47 71.7(6) 4_576 . . . ?
C13 Eu1 N3 C47 -104.6(6) . . . . ?
Eu2 Eu1 N3 C47 -48.3(5) . . . . ?
O1 Eu1 N3 C51 126.9(5) . . . . ?
O9 Eu1 N3 C51 168.9(5) . . . . ?
O13 Eu1 N3 C51 9.3(6) . . . . ?
O14 Eu1 N3 C51 -39.4(5) . . . . ?
O8 Eu1 N3 C51 -110.0(5) 4_576 . . . ?
O7 Eu1 N3 C51 -109.1(5) 4_576 . . . ?
O6 Eu1 N3 C51 47.7(5) . . . . ?
O5 Eu1 N3 C51 99.8(5) . . . . ?
C24 Eu1 N3 C51 -110.4(5) 4_576 . . . ?
C13 Eu1 N3 C51 73.3(5) . . . . ?
Eu2 Eu1 N3 C51 129.6(5) . . . . ?
Eu2 O2 C1 O1 16.3(10) . . . . ?
Eu2 O2 C1 C2 -164.0(4) . . . . ?
Eu1 O1 C1 O2 -8.2(13) . . . . ?
Eu1 O1 C1 C2 172.1(5) . . . . ?
O2 C1 C2 C3 143.1(6) . . . . ?
O1 C1 C2 C3 -37.1(8) . . . . ?
O2 C1 C2 C7 -36.9(8) . . . . ?
O1 C1 C2 C7 142.8(6) . . . . ?
C7 C2 C3 C4 2.0(9) . . . . ?
C1 C2 C3 C4 -178.0(5) . . . . ?
C2 C3 C4 C5 -2.5(10) . . . . ?
C3 C4 C5 C6 0.0(9) . . . . ?
C3 C4 C5 C12 178.0(6) . . . . ?
C4 C5 C6 C11 -176.9(6) . . . . ?
C12 C5 C6 C11 5.1(9) . . . . ?
C4 C5 C6 C7 2.8(8) . . . . ?
C12 C5 C6 C7 -175.1(5) . . . . ?
C11 C6 C7 C2 176.6(5) . . . . ?
C5 C6 C7 C2 -3.2(8) . . . . ?
C11 C6 C7 C8 0.5(8) . . . . ?
C5 C6 C7 C8 -179.2(5) . . . . ?
C3 C2 C7 C6 0.8(8) . . . . ?
C1 C2 C7 C6 -179.2(5) . . . . ?
C3 C2 C7 C8 176.6(6) . . . . ?
C1 C2 C7 C8 -3.3(9) . . . . ?
C6 C7 C8 C9 -0.6(9) . . . . ?
C2 C7 C8 C9 -176.5(6) . . . . ?
C7 C8 C9 C10 0.9(10) . . . . ?
C8 C9 C10 C11 -1.1(10) . . . . ?
C9 C10 C11 C6 1.0(10) . . . . ?
C7 C6 C11 C10 -0.8(9) . . . . ?
C5 C6 C11 C10 179.0(6) . . . . ?
Eu2 O3 C12 O4 1.7(6) 2_646 . . . ?
Eu2 O3 C12 C5 -177.8(5) 2_646 . . . ?
Eu2 O4 C12 O3 -1.8(7) 2_646 . . . ?
Eu2 O4 C12 C5 177.7(5) 2_646 . . . ?
C4 C5 C12 O3 71.4(8) . . . . ?
C6 C5 C12 O3 -110.6(7) . . . . ?
C4 C5 C12 O4 -108.1(7) . . . . ?
C6 C5 C12 O4 69.9(8) . . . . ?
C4 C5 C12 Eu2 -83(6) . . . 2_646 ?
C6 C5 C12 Eu2 95(6) . . . 2_646 ?
Eu1 O6 C13 O5 -0.3(6) . . . . ?
Eu1 O6 C13 C14 175.6(4) . . . . ?
Eu2 O5 C13 O6 148.7(7) . . . . ?
Eu1 O5 C13 O6 0.2(5) . . . . ?
Eu2 O5 C13 C14 -27.1(12) . . . . ?
Eu1 O5 C13 C14 -175.5(5) . . . . ?
Eu2 O5 C13 Eu1 148.4(9) . . . . ?
O1 Eu1 C13 O6 116.4(4) . . . . ?
O9 Eu1 C13 O6 -170.1(4) . . . . ?
O13 Eu1 C13 O6 47.2(4) . . . . ?
O14 Eu1 C13 O6 -22.3(4) . . . . ?
O8 Eu1 C13 O6 101.3(7) 4_576 . . . ?
O7 Eu1 C13 O6 -93.8(4) 4_576 . . . ?
N3 Eu1 C13 O6 -90.1(4) . . . . ?
O5 Eu1 C13 O6 -179.7(6) . . . . ?
C24 Eu1 C13 O6 -106.4(8) 4_576 . . . ?
Eu2 Eu1 C13 O6 172.0(4) . . . . ?
O1 Eu1 C13 O5 -63.9(3) . . . . ?
O9 Eu1 C13 O5 9.7(3) . . . . ?
O13 Eu1 C13 O5 -133.1(3) . . . . ?
O14 Eu1 C13 O5 157.4(3) . . . . ?
O8 Eu1 C13 O5 -79.0(7) 4_576 . . . ?
O7 Eu1 C13 O5 86.0(4) 4_576 . . . ?
O6 Eu1 C13 O5 179.7(6) . . . . ?
N3 Eu1 C13 O5 89.6(3) . . . . ?
C24 Eu1 C13 O5 73.3(8) 4_576 . . . ?
Eu2 Eu1 C13 O5 -8.3(2) . . . . ?
O1 Eu1 C13 C14 86(3) . . . . ?
O9 Eu1 C13 C14 160(3) . . . . ?
O13 Eu1 C13 C14 17(3) . . . . ?
O14 Eu1 C13 C14 -52(3) . . . . ?
O8 Eu1 C13 C14 71(3) 4_576 . . . ?
O7 Eu1 C13 C14 -124(3) 4_576 . . . ?
O6 Eu1 C13 C14 -30(3) . . . . ?
N3 Eu1 C13 C14 -120(3) . . . . ?
O5 Eu1 C13 C14 150(3) . . . . ?
C24 Eu1 C13 C14 -137(3) 4_576 . . . ?
Eu2 Eu1 C13 C14 142(3) . . . . ?
O6 C13 C14 C15 -43.3(8) . . . . ?
O5 C13 C14 C15 132.5(6) . . . . ?
Eu1 C13 C14 C15 -16(3) . . . . ?
O6 C13 C14 C19 137.0(6) . . . . ?
O5 C13 C14 C19 -47.2(8) . . . . ?
Eu1 C13 C14 C19 165(3) . . . . ?
C19 C14 C15 C16 6.9(9) . . . . ?
C13 C14 C15 C16 -172.8(6) . . . . ?
C14 C15 C16 C17 -3.4(10) . . . . ?
C15 C16 C17 C18 -3.2(10) . . . . ?
C15 C16 C17 C24 176.3(6) . . . . ?
C16 C17 C18 C23 -177.3(6) . . . . ?
C24 C17 C18 C23 3.2(10) . . . . ?
C16 C17 C18 C19 5.9(9) . . . . ?
C24 C17 C18 C19 -173.6(6) . . . . ?
C15 C14 C19 C20 172.8(6) . . . . ?
C13 C14 C19 C20 -7.5(10) . . . . ?
C15 C14 C19 C18 -4.0(9) . . . . ?
C13 C14 C19 C18 175.7(5) . . . . ?
C23 C18 C19 C14 -179.3(6) . . . . ?
C17 C18 C19 C14 -2.3(9) . . . . ?
C23 C18 C19 C20 3.7(9) . . . . ?
C17 C18 C19 C20 -179.3(6) . . . . ?
C14 C19 C20 C21 179.5(6) . . . . ?
C18 C19 C20 C21 -3.6(10) . . . . ?
C19 C20 C21 C22 2.4(11) . . . . ?
C20 C21 C22 C23 -1.4(12) . . . . ?
C21 C22 C23 C18 1.7(12) . . . . ?
C17 C18 C23 C22 -179.7(7) . . . . ?
C19 C18 C23 C22 -2.9(10) . . . . ?
Eu1 O8 C24 O7 -3.3(6) 4_675 . . . ?
Eu1 O8 C24 C17 177.2(5) 4_675 . . . ?
Eu1 O7 C24 O8 3.3(6) 4_675 . . . ?
Eu1 O7 C24 C17 -177.2(5) 4_675 . . . ?
C16 C17 C24 O8 155.1(6) . . . . ?
C18 C17 C24 O8 -25.4(10) . . . . ?
C16 C17 C24 O7 -24.4(9) . . . . ?
C18 C17 C24 O7 155.1(6) . . . . ?
C16 C17 C24 Eu1 -94(11) . . . 4_675 ?
C18 C17 C24 Eu1 85(11) . . . 4_675 ?
Eu2 O10 C25 O9 -2.6(7) . . . . ?
Eu2 O10 C25 C26 -178.2(4) . . . . ?
Eu1 O9 C25 O10 119.0(6) . . . . ?
Eu2 O9 C25 O10 2.2(5) . . . . ?
Eu1 O9 C25 C26 -65.5(9) . . . . ?
Eu2 O9 C25 C26 177.7(5) . . . . ?
Eu1 O9 C25 Eu2 116.8(6) . . . . ?
O2 Eu2 C25 O10 90.3(4) . . . . ?
O15 Eu2 C25 O10 15.8(4) . . . . ?
O11 Eu2 C25 O10 -80.3(6) 4_675 . . . ?
O12 Eu2 C25 O10 103.8(4) 4_675 . . . ?
O5 Eu2 C25 O10 173.9(4) . . . . ?
O4 Eu2 C25 O10 -108.6(4) 2_656 . . . ?
O3 Eu2 C25 O10 -56.1(4) 2_656 . . . ?
C36 Eu2 C25 O10 131(3) 4_675 . . . ?
O9 Eu2 C25 O10 -177.6(6) . . . . ?
C12 Eu2 C25 O10 -82.2(4) 2_656 . . . ?
O2 Eu2 C25 O9 -92.1(3) . . . . ?
O15 Eu2 C25 O9 -166.6(3) . . . . ?
O11 Eu2 C25 O9 97.3(5) 4_675 . . . ?
O12 Eu2 C25 O9 -78.6(4) 4_675 . . . ?
O5 Eu2 C25 O9 -8.5(3) . . . . ?
O4 Eu2 C25 O9 69.0(3) 2_656 . . . ?
O10 Eu2 C25 O9 177.6(6) . . . . ?
O3 Eu2 C25 O9 121.5(3) 2_656 . . . ?
C36 Eu2 C25 O9 -52(3) 4_675 . . . ?
C12 Eu2 C25 O9 95.4(3) 2_656 . . . ?
O2 Eu2 C25 C26 100(2) . . . . ?
O15 Eu2 C25 C26 25(2) . . . . ?
O11 Eu2 C25 C26 -71(3) 4_675 . . . ?
O12 Eu2 C25 C26 113(2) 4_675 . . . ?
O5 Eu2 C25 C26 -177(2) . . . . ?
O4 Eu2 C25 C26 -99(2) 2_656 . . . ?
O10 Eu2 C25 C26 9(2) . . . . ?
O3 Eu2 C25 C26 -47(2) 2_656 . . . ?
C36 Eu2 C25 C26 140(3) 4_675 . . . ?
O9 Eu2 C25 C26 -168(3) . . . . ?
C12 Eu2 C25 C26 -73(2) 2_656 . . . ?
O10 C25 C26 C27 133.1(6) . . . . ?
O9 C25 C26 C27 -42.5(8) . . . . ?
Eu2 C25 C26 C27 125(2) . . . . ?
O10 C25 C26 C31 -43.5(8) . . . . ?
O9 C25 C26 C31 140.8(6) . . . . ?
Eu2 C25 C26 C31 -52(3) . . . . ?
C31 C26 C27 C28 3.1(9) . . . . ?
C25 C26 C27 C28 -173.6(5) . . . . ?
C26 C27 C28 C29 -1.4(9) . . . . ?
C27 C28 C29 C30 -0.5(9) . . . . ?
C27 C28 C29 C36 -176.2(5) . . . . ?
C28 C29 C30 C31 0.6(9) . . . . ?
C36 C29 C30 C31 175.9(5) . . . . ?
C28 C29 C30 C35 -179.9(6) . . . . ?
C36 C29 C30 C35 -4.7(10) . . . . ?
C29 C30 C31 C32 -176.8(6) . . . . ?
C35 C30 C31 C32 3.7(9) . . . . ?
C29 C30 C31 C26 1.0(9) . . . . ?
C35 C30 C31 C26 -178.5(6) . . . . ?
C27 C26 C31 C32 174.9(6) . . . . ?
C25 C26 C31 C32 -8.6(9) . . . . ?
C27 C26 C31 C30 -2.9(9) . . . . ?
C25 C26 C31 C30 173.6(5) . . . . ?
C30 C31 C32 C33 -4.0(11) . . . . ?
C26 C31 C32 C33 178.2(7) . . . . ?
C31 C32 C33 C34 2.0(12) . . . . ?
C32 C33 C34 C35 0.2(13) . . . . ?
C33 C34 C35 C30 -0.4(13) . . . . ?
C29 C30 C35 C34 179.0(7) . . . . ?
C31 C30 C35 C34 -1.5(10) . . . . ?
Eu2 O11 C36 O12 2.6(6) 4_576 . . . ?
Eu2 O11 C36 C29 -176.6(5) 4_576 . . . ?
Eu2 O12 C36 O11 -2.6(6) 4_576 . . . ?
Eu2 O12 C36 C29 176.6(5) 4_576 . . . ?
C28 C29 C36 O11 163.9(6) . . . . ?
C30 C29 C36 O11 -11.6(10) . . . . ?
C28 C29 C36 O12 -15.3(8) . . . . ?
C30 C29 C36 O12 169.2(6) . . . . ?
C28 C29 C36 Eu2 55(8) . . . 4_576 ?
C30 C29 C36 Eu2 -121(8) . . . 4_576 ?
C41 N1 C37 C38 4.9(14) . . . . ?
N1 C37 C38 C39 -3.1(14) . . . . ?
C37 C38 C39 C40 -2.1(11) . . . . ?
C37 C38 C39 C44 -178.5(8) . . . . ?
C38 C39 C40 C41 5.3(11) . . . . ?
C44 C39 C40 C41 -178.4(6) . . . . ?
C37 N1 C41 C40 -1.4(11) . . . . ?
C39 C40 C41 N1 -3.6(12) . . . . ?
C46 N2 C42 C43 0.7(12) . . . . ?
N2 C42 C43 C44 -1.8(13) . . . . ?
C42 C43 C44 C45 1.2(12) . . . . ?
C42 C43 C44 C39 -178.3(7) . . . . ?
C40 C39 C44 C43 144.4(8) . . . . ?
C38 C39 C44 C43 -39.3(11) . . . . ?
C40 C39 C44 C45 -35.1(11) . . . . ?
C38 C39 C44 C45 141.2(8) . . . . ?
C43 C44 C45 C46 0.2(12) . . . . ?
C39 C44 C45 C46 179.8(7) . . . . ?
C42 N2 C46 C45 0.9(13) . . . . ?
C44 C45 C46 N2 -1.4(13) . . . . ?
C51 N3 C47 C48 -4.4(11) . . . . ?
Eu1 N3 C47 C48 173.7(6) . . . . ?
N3 C47 C48 C49 2.5(12) . . . . ?
C47 C48 C49 C50 1.3(11) . . . . ?
C47 C48 C49 C49 -179.7(8) . . . 3_676 ?
C48 C49 C50 C51 -2.7(11) . . . . ?
C49 C49 C50 C51 178.3(8) 3_676 . . . ?
C47 N3 C51 C50 2.9(10) . . . . ?
Eu1 N3 C51 C50 -175.2(5) . . . . ?
C49 C50 C51 N3 0.7(11) . . . . ?
