#------------------------------------------------------------------------------
#$Date: 2016-03-26 00:32:38 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180084 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/30/7053059.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7053059
loop_
_publ_author_name
'Sarwar, Masood'
'Madalan, Augustin M.'
'Tiseanu, Carmen'
'Novitchi, Ghenadie'
'Maxim, Catalin'
'Marinescu, Gabriela'
'Luneau, Dominique'
'Andruh, Marius'
_publ_section_title
;
 A new synthetic route towards binuclear 3d--4f complexes, using
 non-compartmental ligands derived from o-vanillin. Syntheses, crystal
 structures, magnetic and luminescent properties
;
_journal_issue                   8
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              2280
_journal_paper_doi               10.1039/c3nj00199g
_journal_volume                  37
_journal_year                    2013
_chemical_formula_sum            'C32 H35 Dy N8 Ni O14'
_chemical_formula_weight         976.89
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.045(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   12.8557(5)
_cell_length_b                   19.4086(7)
_cell_length_c                   15.1631(7)
_cell_measurement_reflns_used    21895
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.36
_cell_measurement_theta_min      2.49
_cell_volume                     3736.3(3)
_computing_cell_refinement       X-Area
_computing_data_collection       X-Area
_computing_data_reduction        X-Area
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'STOE IPDS II'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0392
_diffrn_reflns_av_sigmaI/netI    0.0304
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            39575
_diffrn_reflns_theta_full        28.36
_diffrn_reflns_theta_max         28.36
_diffrn_reflns_theta_min         2.49
_exptl_absorpt_coefficient_mu    2.566
_exptl_absorpt_correction_T_max  0.4942
_exptl_absorpt_correction_T_min  0.3322
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
[c.f. r.h. blessing, acta cryst. (1995), a51, 33-38]
;
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.737
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1956
_exptl_crystal_size_max          0.5
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.311
_refine_diff_density_min         -1.052
_refine_diff_density_rms         0.064
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.002
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     514
_refine_ls_number_reflns         9291
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.002
_refine_ls_R_factor_all          0.0420
_refine_ls_R_factor_gt           0.0272
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0290P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0522
_refine_ls_wR_factor_ref         0.0560
_reflns_number_gt                7507
_reflns_number_total             9291
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3nj00199g.txt
_cod_data_source_block           shelxl3
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 1891 2012-01-12 08:04:46Z andrius 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      P21/n
_cod_database_code               7053059
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
C1 C -0.1377(3) 0.2866(2) 0.6886(5) 0.122(2) Uani 1 1 d .
H1A H -0.1097 0.3312 0.6781 0.182 Uiso 1 1 calc R
H1B H -0.1789 0.2897 0.7360 0.182 Uiso 1 1 calc R
H1C H -0.1813 0.2708 0.6352 0.182 Uiso 1 1 calc R
C2 C -0.0787(2) 0.17356(17) 0.72991(18) 0.0465(7) Uani 1 1 d .
C3 C -0.1730(2) 0.1523(2) 0.7551(2) 0.0614(9) Uani 1 1 d .
H3 H -0.2236 0.1849 0.7632 0.074 Uiso 1 1 calc R
C4 C -0.1927(2) 0.0837(3) 0.7682(2) 0.0711(11) Uani 1 1 d .
H4 H -0.2567 0.0703 0.7842 0.085 Uiso 1 1 calc R
C5 C -0.1184(2) 0.0350(2) 0.7578(2) 0.0595(9) Uani 1 1 d .
H5 H -0.1322 -0.0113 0.7666 0.071 Uiso 1 1 calc R
C6 C -0.0212(2) 0.05461(16) 0.73389(17) 0.0430(6) Uani 1 1 d .
C7 C -0.00120(18) 0.12390(15) 0.71868(16) 0.0373(5) Uani 1 1 d .
C8 C 0.0522(2) 0.00059(15) 0.72033(18) 0.0436(6) Uani 1 1 d .
H8 H 0.0252 -0.0438 0.7116 0.052 Uiso 1 1 calc R
C9 C 0.2095(2) -0.05574(14) 0.70776(19) 0.0448(6) Uani 1 1 d .
H9A H 0.1683 -0.0840 0.6623 0.054 Uiso 1 1 calc R
H9B H 0.2192 -0.0814 0.7633 0.054 Uiso 1 1 calc R
C10 C 0.3161(2) -0.04157(15) 0.68095(19) 0.0461(6) Uani 1 1 d .
H10A H 0.3437 -0.0841 0.6603 0.055 Uiso 1 1 calc R
H10B H 0.3074 -0.0092 0.6316 0.055 Uiso 1 1 calc R
C11 C 0.3943(2) -0.01276(15) 0.75590(19) 0.0440(6) Uani 1 1 d .
C12 C 0.4867(3) -0.0478(2) 0.7871(3) 0.0671(9) Uani 1 1 d .
H12 H 0.5015 -0.0892 0.7609 0.081 Uiso 1 1 calc R
C13 C 0.5563(3) -0.0214(2) 0.8566(3) 0.0837(13) Uani 1 1 d .
H13 H 0.6187 -0.0446 0.8774 0.100 Uiso 1 1 calc R
C14 C 0.5334(3) 0.0392(2) 0.8951(3) 0.0680(9) Uani 1 1 d .
H14 H 0.5792 0.0578 0.9428 0.082 Uiso 1 1 calc R
C15 C 0.4407(2) 0.07198(17) 0.8616(2) 0.0502(7) Uani 1 1 d .
H15 H 0.4250 0.1133 0.8876 0.060 Uiso 1 1 calc R
C16 C 0.3715(3) 0.0455(2) 0.4004(2) 0.0657(9) Uani 1 1 d .
H16A H 0.3239 0.0117 0.3705 0.099 Uiso 1 1 calc R
H16B H 0.4427 0.0302 0.4018 0.099 Uiso 1 1 calc R
H16C H 0.3615 0.0885 0.3690 0.099 Uiso 1 1 calc R
C17 C 0.41143(19) 0.10125(15) 0.54214(18) 0.0399(5) Uani 1 1 d .
C18 C 0.5152(2) 0.11604(16) 0.5339(2) 0.0510(7) Uani 1 1 d .
H18 H 0.5458 0.0947 0.4894 0.061 Uiso 1 1 calc R
C19 C 0.5735(2) 0.16213(19) 0.5910(2) 0.0575(8) Uani 1 1 d .
H19 H 0.6430 0.1715 0.5851 0.069 Uiso 1 1 calc R
C20 C 0.5289(2) 0.19392(17) 0.6564(2) 0.0516(7) Uani 1 1 d .
H20 H 0.5680 0.2256 0.6939 0.062 Uiso 1 1 calc R
C21 C 0.42452(19) 0.17922(14) 0.66730(18) 0.0391(5) Uani 1 1 d .
C22 C 0.36364(17) 0.13270(13) 0.61000(16) 0.0338(5) Uani 1 1 d .
C23 C 0.38292(19) 0.21559(14) 0.73748(18) 0.0406(6) Uani 1 1 d .
H23 H 0.4153 0.2569 0.7569 0.049 Uiso 1 1 calc R
C24 C 0.2790(3) 0.24239(17) 0.8450(2) 0.0579(8) Uani 1 1 d .
H24A H 0.2787 0.2895 0.8235 0.070 Uiso 1 1 calc R
H24B H 0.3332 0.2388 0.8971 0.070 Uiso 1 1 calc R
C25 C 0.1731(2) 0.22661(16) 0.8721(2) 0.0493(7) Uani 1 1 d .
H25A H 0.1543 0.2636 0.9097 0.059 Uiso 1 1 calc R
H25B H 0.1200 0.2249 0.8190 0.059 Uiso 1 1 calc R
C26 C 0.1727(2) 0.15955(17) 0.92142(17) 0.0452(6) Uani 1 1 d .
C27 C 0.1524(3) 0.1572(2) 1.0092(2) 0.0664(9) Uani 1 1 d .
H27 H 0.1391 0.1978 1.0380 0.080 Uiso 1 1 calc R
C28 C 0.1517(3) 0.0960(3) 1.0531(2) 0.0777(12) Uani 1 1 d .
H28 H 0.1380 0.0945 1.1115 0.093 Uiso 1 1 calc R
C29 C 0.1717(3) 0.0365(2) 1.0094(2) 0.0658(9) Uani 1 1 d .
H29 H 0.1708 -0.0062 1.0373 0.079 Uiso 1 1 calc R
C30 C 0.1930(2) 0.04153(17) 0.92377(19) 0.0498(7) Uani 1 1 d .
H30 H 0.2080 0.0014 0.8947 0.060 Uiso 1 1 calc R
C31 C 0.4017(3) 0.3495(2) 0.5627(3) 0.0756(10) Uani 1 1 d .
C32 C 0.3804(4) 0.3079(3) 0.4826(3) 0.0942(14) Uani 1 1 d .
H32A H 0.4038 0.2615 0.4960 0.141 Uiso 1 1 calc R
H32B H 0.4171 0.3267 0.4377 0.141 Uiso 1 1 calc R
H32C H 0.3060 0.3078 0.4610 0.141 Uiso 1 1 calc R
Dy1 Dy 0.103829(8) 0.159295(6) 0.543264(7) 0.03330(4) Uani 1 1 d .
N1 N 0.15111(16) 0.00832(11) 0.71924(14) 0.0370(4) Uani 1 1 d .
N2 N 0.37165(16) 0.04714(12) 0.79272(14) 0.0397(5) Uani 1 1 d .
N3 N 0.30541(16) 0.19594(11) 0.77528(14) 0.0383(5) Uani 1 1 d .
N4 N 0.19320(17) 0.10157(13) 0.87980(14) 0.0411(5) Uani 1 1 d .
N5 N -0.12171(17) 0.12425(15) 0.52028(15) 0.0463(6) Uani 1 1 d .
N6 N 0.1326(2) 0.17337(15) 0.36031(16) 0.0535(6) Uani 1 1 d .
N7 N 0.1329(2) 0.30673(14) 0.5641(2) 0.0576(6) Uani 1 1 d .
N8 N 0.4205(4) 0.3811(3) 0.6254(3) 0.1128(15) Uani 1 1 d .
Ni1 Ni 0.23065(2) 0.101704(16) 0.74846(2) 0.03128(7) Uani 1 1 d .
O1 O -0.05382(15) 0.23976(13) 0.71287(17) 0.0621(6) Uani 1 1 d .
O2 O 0.08713(12) 0.14407(9) 0.68906(11) 0.0344(4) Uani 1 1 d .
O3 O 0.35133(15) 0.05442(11) 0.48924(13) 0.0483(5) Uani 1 1 d .
O4 O 0.26428(11) 0.11786(9) 0.61819(11) 0.0318(3) Uani 1 1 d .
O5 O -0.04875(14) 0.07947(11) 0.52302(14) 0.0488(5) Uani 1 1 d .
O6 O -0.09057(16) 0.18535(13) 0.52858(15) 0.0546(5) Uani 1 1 d .
O7 O -0.21352(15) 0.10788(16) 0.50980(17) 0.0734(8) Uani 1 1 d .
O8 O 0.04200(15) 0.16627(13) 0.38037(14) 0.0550(5) Uani 1 1 d .
O9 O 0.20719(16) 0.18307(12) 0.42536(14) 0.0536(5) Uani 1 1 d .
O10 O 0.1486(2) 0.17004(18) 0.28367(16) 0.0895(10) Uani 1 1 d .
O11 O 0.19320(19) 0.26316(12) 0.60618(17) 0.0645(6) Uani 1 1 d .
O12 O 0.0599(2) 0.28188(13) 0.5082(2) 0.0731(7) Uani 1 1 d .
O13 O 0.1458(3) 0.36803(15) 0.5752(3) 0.1028(11) Uani 1 1 d .
O14 O 0.13802(17) 0.05094(12) 0.48048(16) 0.0514(5) Uani 1 1 d .
H1W H 0.198(3) 0.044(2) 0.491(3) 0.071(12) Uiso 1 1 d .
H2W H 0.102(3) 0.010(2) 0.482(3) 0.094(15) Uiso 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
O1 C1 H1A 109.5
O1 C1 H1B 109.5
H1A C1 H1B 109.5
O1 C1 H1C 109.5
H1A C1 H1C 109.5
H1B C1 H1C 109.5
O1 C2 C3 125.1(3)
O1 C2 C7 115.4(2)
C3 C2 C7 119.4(3)
C4 C3 C2 121.1(3)
C4 C3 H3 119.5
C2 C3 H3 119.5
C5 C4 C3 120.2(3)
C5 C4 H4 119.9
C3 C4 H4 119.9
C4 C5 C6 120.5(3)
C4 C5 H5 119.8
C6 C5 H5 119.8
C7 C6 C5 119.9(3)
C7 C6 C8 122.2(2)
C5 C6 C8 117.8(3)
O2 C7 C6 121.6(2)
O2 C7 C2 119.3(3)
C6 C7 C2 119.0(2)
N1 C8 C6 125.9(3)
N1 C8 H8 117.0
C6 C8 H8 117.0
N1 C9 C10 112.1(2)
N1 C9 H9A 109.2
C10 C9 H9A 109.2
N1 C9 H9B 109.2
C10 C9 H9B 109.2
H9A C9 H9B 107.9
C11 C10 C9 113.0(2)
C11 C10 H10A 109.0
C9 C10 H10A 109.0
C11 C10 H10B 109.0
C9 C10 H10B 109.0
H10A C10 H10B 107.8
N2 C11 C12 120.9(3)
N2 C11 C10 118.3(2)
C12 C11 C10 120.8(3)
C13 C12 C11 120.1(3)
C13 C12 H12 120.0
C11 C12 H12 120.0
C14 C13 C12 119.4(3)
C14 C13 H13 120.3
C12 C13 H13 120.3
C13 C14 C15 118.2(3)
C13 C14 H14 120.9
C15 C14 H14 120.9
N2 C15 C14 123.2(3)
N2 C15 H15 118.4
C14 C15 H15 118.4
O3 C16 H16A 109.5
O3 C16 H16B 109.5
H16A C16 H16B 109.5
O3 C16 H16C 109.5
H16A C16 H16C 109.5
H16B C16 H16C 109.5
O3 C17 C18 123.1(2)
O3 C17 C22 116.3(2)
C18 C17 C22 120.6(3)
C19 C18 C17 120.7(3)
C19 C18 H18 119.6
C17 C18 H18 119.6
C20 C19 C18 120.0(2)
C20 C19 H19 120.0
C18 C19 H19 120.0
C19 C20 C21 120.7(3)
C19 C20 H20 119.7
C21 C20 H20 119.7
C22 C21 C20 120.5(3)
C22 C21 C23 122.3(2)
C20 C21 C23 117.2(2)
O4 C22 C21 122.0(2)
O4 C22 C17 120.4(2)
C21 C22 C17 117.6(2)
N3 C23 C21 125.9(2)
N3 C23 H23 117.1
C21 C23 H23 117.1
N3 C24 C25 113.0(2)
N3 C24 H24A 109.0
C25 C24 H24A 109.0
N3 C24 H24B 109.0
C25 C24 H24B 109.0
H24A C24 H24B 107.8
C26 C25 C24 112.5(3)
C26 C25 H25A 109.1
C24 C25 H25A 109.1
C26 C25 H25B 109.1
C24 C25 H25B 109.1
H25A C25 H25B 107.8
N4 C26 C27 120.2(3)
N4 C26 C25 118.6(2)
C27 C26 C25 121.3(3)
C28 C27 C26 120.7(4)
C28 C27 H27 119.6
C26 C27 H27 119.6
C27 C28 C29 118.7(3)
C27 C28 H28 120.6
C29 C28 H28 120.6
C30 C29 C28 118.4(4)
C30 C29 H29 120.8
C28 C29 H29 120.8
N4 C30 C29 123.3(3)
N4 C30 H30 118.4
C29 C30 H30 118.4
N8 C31 C32 178.4(6)
C31 C32 H32A 109.5
C31 C32 H32B 109.5
H32A C32 H32B 109.5
C31 C32 H32C 109.5
H32A C32 H32C 109.5
H32B C32 H32C 109.5
O2 Dy1 O4 72.15(5)
O2 Dy1 O14 109.02(8)
O4 Dy1 O14 71.67(7)
O2 Dy1 O9 152.24(6)
O4 Dy1 O9 83.12(6)
O14 Dy1 O9 73.55(8)
O2 Dy1 O11 80.66(8)
O4 Dy1 O11 76.62(7)
O14 Dy1 O11 141.46(8)
O9 Dy1 O11 81.52(8)
O2 Dy1 O8 155.82(6)
O4 Dy1 O8 128.64(6)
O14 Dy1 O8 72.52(8)
O9 Dy1 O8 51.95(7)
O11 Dy1 O8 113.73(8)
O2 Dy1 O5 81.11(6)
O4 Dy1 O5 117.77(6)
O14 Dy1 O5 65.82(7)
O9 Dy1 O5 122.68(7)
O11 Dy1 O5 151.56(8)
O8 Dy1 O5 77.71(7)
O2 Dy1 O12 106.23(8)
O4 Dy1 O12 126.00(7)
O14 Dy1 O12 144.27(9)
O9 Dy1 O12 78.08(9)
O11 Dy1 O12 50.90(8)
O8 Dy1 O12 73.00(9)
O5 Dy1 O12 115.02(8)
O2 Dy1 O6 82.43(6)
O4 Dy1 O6 153.89(6)
O14 Dy1 O6 112.61(8)
O9 Dy1 O6 122.99(7)
O11 Dy1 O6 105.53(8)
O8 Dy1 O6 75.11(7)
O5 Dy1 O6 50.34(7)
O12 Dy1 O6 66.45(8)
O2 Dy1 N6 177.20(7)
O4 Dy1 N6 105.35(6)
O14 Dy1 N6 68.71(8)
O9 Dy1 N6 26.25(7)
O11 Dy1 N6 100.08(8)
O8 Dy1 N6 25.89(7)
O5 Dy1 N6 99.18(7)
O12 Dy1 N6 76.21(9)
O6 Dy1 N6 99.91(7)
O2 Dy1 N7 93.03(7)
O4 Dy1 N7 101.42(7)
O14 Dy1 N7 152.68(8)
O9 Dy1 N7 79.43(8)
O11 Dy1 N7 25.32(8)
O8 Dy1 N7 94.04(8)
O5 Dy1 N7 135.78(7)
O12 Dy1 N7 25.59(8)
O6 Dy1 N7 85.47(8)
N6 Dy1 N7 88.70(8)
O2 Dy1 N5 80.99(6)
O4 Dy1 N5 139.10(7)
O14 Dy1 N5 89.36(7)
O9 Dy1 N5 126.73(7)
O11 Dy1 N5 129.17(8)
O8 Dy1 N5 74.87(6)
O5 Dy1 N5 25.37(7)
O12 Dy1 N5 90.53(8)
O6 Dy1 N5 24.97(7)
N6 Dy1 N5 100.48(7)
N7 Dy1 N5 110.43(8)
C8 N1 C9 115.2(2)
C8 N1 Ni1 123.40(19)
C9 N1 Ni1 120.88(16)
C11 N2 C15 118.2(2)
C11 N2 Ni1 122.23(18)
C15 N2 Ni1 119.6(2)
C23 N3 C24 115.0(2)
C23 N3 Ni1 122.84(18)
C24 N3 Ni1 121.97(17)
C26 N4 C30 118.7(2)
C26 N4 Ni1 122.21(19)
C30 N4 Ni1 119.06(19)
O7 N5 O6 123.5(3)
O7 N5 O5 121.6(3)
O6 N5 O5 114.9(2)
O7 N5 Dy1 177.9(2)
O6 N5 Dy1 58.40(12)
O5 N5 Dy1 56.49(13)
O10 N6 O8 121.9(3)
O10 N6 O9 121.9(3)
O8 N6 O9 116.2(2)
O10 N6 Dy1 171.2(3)
O8 N6 Dy1 59.35(13)
O9 N6 Dy1 57.47(12)
O13 N7 O11 122.2(3)
O13 N7 O12 122.8(3)
O11 N7 O12 114.9(3)
O13 N7 Dy1 178.2(3)
O11 N7 Dy1 56.45(15)
O12 N7 Dy1 58.53(15)
N3 Ni1 O2 95.04(8)
N3 Ni1 N1 178.18(9)
O2 Ni1 N1 83.15(8)
N3 Ni1 O4 84.02(7)
O2 Ni1 O4 80.51(6)
N1 Ni1 O4 95.49(7)
N3 Ni1 N2 91.82(9)
O2 Ni1 N2 171.09(8)
N1 Ni1 N2 89.97(9)
O4 Ni1 N2 94.59(7)
N3 Ni1 N4 89.06(9)
O2 Ni1 N4 95.15(8)
N1 Ni1 N4 91.27(9)
O4 Ni1 N4 171.45(8)
N2 Ni1 N4 90.64(8)
N3 Ni1 Dy1 91.70(6)
O2 Ni1 Dy1 39.37(4)
N1 Ni1 Dy1 86.79(6)
O4 Ni1 Dy1 41.24(4)
N2 Ni1 Dy1 134.87(6)
N4 Ni1 Dy1 134.39(6)
C2 O1 C1 117.7(3)
C7 O2 Ni1 118.46(15)
C7 O2 Dy1 125.23(15)
Ni1 O2 Dy1 104.96(6)
C17 O3 C16 117.8(2)
C22 O4 Ni1 117.33(14)
C22 O4 Dy1 131.74(14)
Ni1 O4 Dy1 102.19(6)
N5 O5 Dy1 98.14(17)
N5 O6 Dy1 96.64(15)
N6 O8 Dy1 94.76(16)
N6 O9 Dy1 96.28(15)
N7 O11 Dy1 98.23(19)
N7 O12 Dy1 95.88(18)
Dy1 O14 H1W 109(3)
Dy1 O14 H2W 129(3)
H1W O14 H2W 109(4)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
C1 O1 1.414(4)
C1 H1A 0.9600
C1 H1B 0.9600
C1 H1C 0.9600
C2 O1 1.359(4)
C2 C3 1.390(4)
C2 C7 1.416(4)
C3 C4 1.376(6)
C3 H3 0.9300
C4 C5 1.370(5)
C4 H4 0.9300
C5 C6 1.406(4)
C5 H5 0.9300
C6 C7 1.395(4)
C6 C8 1.447(4)
C7 O2 1.343(3)
C8 N1 1.283(3)
C8 H8 0.9300
C9 N1 1.477(3)
C9 C10 1.514(4)
C9 H9A 0.9700
C9 H9B 0.9700
C10 C11 1.502(4)
C10 H10A 0.9700
C10 H10B 0.9700
C11 N2 1.341(4)
C11 C12 1.386(4)
C12 C13 1.369(5)
C12 H12 0.9300
C13 C14 1.367(6)
C13 H13 0.9300
C14 C15 1.375(4)
C14 H14 0.9300
C15 N2 1.349(4)
C15 H15 0.9300
C16 O3 1.421(3)
C16 H16A 0.9600
C16 H16B 0.9600
C16 H16C 0.9600
C17 O3 1.368(3)
C17 C18 1.390(3)
C17 C22 1.417(3)
C18 C19 1.382(5)
C18 H18 0.9300
C19 C20 1.367(4)
C19 H19 0.9300
C20 C21 1.408(3)
C20 H20 0.9300
C21 C22 1.403(4)
C21 C23 1.448(4)
C22 O4 1.334(3)
C23 N3 1.283(3)
C23 H23 0.9300
C24 N3 1.469(3)
C24 C25 1.515(4)
C24 H24A 0.9700
C24 H24B 0.9700
C25 C26 1.502(4)
C25 H25A 0.9700
C25 H25B 0.9700
C26 N4 1.336(4)
C26 C27 1.397(4)
C27 C28 1.362(6)
C27 H27 0.9300
C28 C29 1.376(6)
C28 H28 0.9300
C29 C30 1.372(4)
C29 H29 0.9300
C30 N4 1.343(4)
C30 H30 0.9300
C31 N8 1.125(6)
C31 C32 1.449(6)
C32 H32A 0.9600
C32 H32B 0.9600
C32 H32C 0.9600
Dy1 O2 2.2738(16)
Dy1 O4 2.3356(16)
Dy1 O14 2.378(2)
Dy1 O9 2.4334(19)
Dy1 O11 2.439(2)
Dy1 O8 2.477(2)
Dy1 O5 2.4805(19)
Dy1 O12 2.484(2)
Dy1 O6 2.525(2)
Dy1 N6 2.869(2)
Dy1 N7 2.897(3)
Dy1 N5 2.945(2)
N1 Ni1 2.094(2)
N2 Ni1 2.115(2)
N3 Ni1 2.076(2)
N4 Ni1 2.121(2)
N5 O7 1.208(3)
N5 O6 1.251(3)
N5 O5 1.275(3)
N6 O10 1.213(3)
N6 O8 1.257(3)
N6 O9 1.277(3)
N7 O13 1.209(4)
N7 O11 1.252(3)
N7 O12 1.258(4)
Ni1 O2 2.0902(16)
Ni1 O4 2.1108(16)
O14 H1W 0.77(4)
O14 H2W 0.92(5)
