#------------------------------------------------------------------------------
#$Date: 2022-11-07 07:35:33 +0200 (Mon, 07 Nov 2022) $
#$Revision: 278997 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/06/19/7061972.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7061972
loop_
_publ_author_name
'Chen, Mingyu'
'Wang, Ming'
'Liu, Cheng'
'Yang, Tao'
'Zhou, Xinhui'
'You, Yujian'
_publ_section_title
;
 A reusable fluorescence Eu-based coordination polymer for the detection
 of Zr4+ ions in aqueous media
;
_journal_issue                   41
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              19991
_journal_page_last               19996
_journal_paper_doi               10.1039/D2NJ03658D
_journal_volume                  46
_journal_year                    2022
_chemical_formula_sum            'C36 H22 Eu N2 O7'
_chemical_formula_weight         746.51
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2021-12-30 deposited with the CCDC.	2022-09-22 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 96.314(4)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   24.198(5)
_cell_length_b                   15.541(3)
_cell_length_c                   15.939(3)
_cell_measurement_reflns_used    2374
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      22.6
_cell_measurement_theta_min      2.1
_cell_volume                     5958(2)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 2008)'
_computing_data_reduction        'SAINT (Bruker, 2008)'
_computing_molecular_graphics    'SHELXTL (Bruker, 2008)'
_computing_publication_material  'SHELXTL (Bruker, 2008)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXTL (Bruker, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker Smart Apex CCD'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0655
_diffrn_reflns_av_unetI/netI     0.0385
_diffrn_reflns_Laue_measured_fraction_full 0.997
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       28
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            21587
_diffrn_reflns_point_group_measured_fraction_full 0.997
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.998
_diffrn_reflns_theta_min         2.571
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    2.161
_exptl_absorpt_process_details   'SADABS; Bruker, 2008'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.665
_exptl_crystal_description       block
_exptl_crystal_F_000             2968
_exptl_crystal_size_max          0.130
_exptl_crystal_size_mid          0.120
_exptl_crystal_size_min          0.100
_refine_diff_density_max         1.096
_refine_diff_density_min         -0.842
_refine_diff_density_rms         0.103
_refine_ls_extinction_coef       0.00063(11)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL-2014/7 (Sheldrick 2014'
_refine_ls_goodness_of_fit_ref   1.022
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     416
_refine_ls_number_reflns         5837
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.022
_refine_ls_R_factor_all          0.0413
_refine_ls_R_factor_gt           0.0307
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1000P)²+0.2089P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1091
_refine_ls_wR_factor_ref         0.1357
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4542
_reflns_number_total             5837
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d2nj03658d2.cif
_cod_data_source_block           1
_cod_depositor_comments          'Adding full bibliography for 7061972.cif.'
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               7061972
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.766
_shelx_estimated_absorpt_t_max   0.813
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.09149(2) 0.25006(2) 0.27189(2) 0.01604(13) Uani 1 1 d . . . . .
C1 C 0.16401(17) 0.4421(3) 0.2691(3) 0.0511(11) Uani 1 1 d . . . . .
H1 H 0.1516 0.4374 0.2120 0.061 Uiso 1 1 calc R U . . .
C2 C 0.1909(2) 0.5176(3) 0.2981(4) 0.0713(14) Uani 1 1 d . . . . .
H2 H 0.1967 0.5613 0.2602 0.086 Uiso 1 1 calc R U . . .
C3 C 0.2084(2) 0.5272(4) 0.3806(4) 0.0769(16) Uani 1 1 d . . . . .
H3 H 0.2254 0.5781 0.4002 0.092 Uiso 1 1 calc R U . . .
C4 C 0.20075(17) 0.4601(3) 0.4368(3) 0.0624(13) Uani 1 1 d . . . . .
C5 C 0.2207(2) 0.4621(5) 0.5250(4) 0.0885(19) Uani 1 1 d . . . . .
H5 H 0.2360 0.5128 0.5483 0.106 Uiso 1 1 calc R U . . .
C6 C 0.2180(2) 0.3930(5) 0.5746(4) 0.095(2) Uani 1 1 d . . . . .
H6 H 0.2319 0.3965 0.6313 0.113 Uiso 1 1 calc R U . . .
C7 C 0.19390(18) 0.3133(4) 0.5418(3) 0.0621(15) Uani 1 1 d . . . . .
C8 C 0.1944(3) 0.2371(5) 0.5891(4) 0.083(3) Uani 1 1 d . . . . .
H8 H 0.2099 0.2366 0.6451 0.100 Uiso 1 1 calc R U . . .
C9 C 0.1719(2) 0.1630(5) 0.5522(3) 0.0748(18) Uani 1 1 d . . . . .
H9 H 0.1718 0.1123 0.5832 0.090 Uiso 1 1 calc R U . . .
C10 C 0.14896(19) 0.1648(4) 0.4667(3) 0.0571(13) Uani 1 1 d . . . . .
H10 H 0.1340 0.1145 0.4419 0.069 Uiso 1 1 calc R U . . .
C11 C 0.17124(16) 0.3092(3) 0.4560(3) 0.0475(11) Uani 1 1 d . . . . .
C12 C 0.17492(15) 0.3830(3) 0.4040(2) 0.0426(10) Uani 1 1 d . . . . .
C13 C 0.33953(15) 0.4023(2) 0.1345(3) 0.0436(9) Uani 1 1 d . . . . .
H13 H 0.3536 0.4357 0.1804 0.052 Uiso 1 1 calc R U . . .
C14 C 0.29594(15) 0.3485(2) 0.1420(2) 0.0381(8) Uani 1 1 d . . . . .
H14 H 0.2812 0.3448 0.1933 0.046 Uiso 1 1 calc R U . . .
C15 C 0.27238(12) 0.2977(2) 0.07215(19) 0.0263(7) Uani 1 1 d . . . . .
C16 C 0.22663(17) 0.24345(18) 0.0773(3) 0.0233(8) Uani 1 1 d . . . . .
C17 C 0.20338(16) 0.2309(3) 0.1612(3) 0.0291(8) Uani 1 1 d . . . . .
C18 C 0.20345(13) 0.1960(2) 0.0068(2) 0.0261(7) Uani 1 1 d . . . . .
C19 C 0.15704(14) 0.1393(2) 0.0102(2) 0.0368(8) Uani 1 1 d . . . . .
H19 H 0.1406 0.1347 0.0601 0.044 Uiso 1 1 calc R U . . .
C20 C 0.13650(15) 0.0921(2) -0.0581(3) 0.0427(9) Uani 1 1 d . . . . .
H20 H 0.1063 0.0558 -0.0543 0.051 Uiso 1 1 calc R U . . .
C21 C 0.00631(15) 0.1298(2) 0.1336(2) 0.0239(7) Uani 1 1 d . . . . .
C22 C 0.05235(16) -0.1342(2) 0.1855(2) 0.0417(9) Uani 1 1 d . . . . .
H22 H 0.0647 -0.1505 0.2405 0.050 Uiso 1 1 calc R U . . .
C23 C 0.04012(14) -0.0504(2) 0.1679(2) 0.0352(8) Uani 1 1 d . . . . .
H23 H 0.0449 -0.0099 0.2111 0.042 Uiso 1 1 calc R U . . .
C24 C 0.02002(12) -0.0232(2) 0.08433(19) 0.0252(7) Uani 1 1 d . . . . .
C25 C 0.00415(13) 0.0620(2) 0.0651(2) 0.0213(7) Uani 1 1 d . . . . .
C26 C -0.01524(12) 0.0870(2) -0.01818(19) 0.0252(7) Uani 1 1 d . . . . .
C27 C -0.02912(15) 0.1744(2) -0.0399(2) 0.0350(8) Uani 1 1 d . . . . .
H27 H -0.0262 0.2163 0.0021 0.042 Uiso 1 1 calc R U . . .
C28 C -0.04641(17) 0.1970(2) -0.1206(2) 0.0432(9) Uani 1 1 d . . . . .
H28 H -0.0545 0.2543 -0.1336 0.052 Uiso 1 1 calc R U . . .
C29 C 0.08254(17) 0.3286(2) -0.0923(2) 0.0441(9) Uani 1 1 d . . . . .
H29 H 0.1025 0.2783 -0.0984 0.053 Uiso 1 1 calc R U . . .
C30 C 0.06170(15) 0.3456(2) -0.0177(2) 0.0353(8) Uani 1 1 d . . . . .
H30 H 0.0679 0.3070 0.0268 0.042 Uiso 1 1 calc R U . . .
C31 C 0.03038(12) 0.4223(2) -0.00758(19) 0.0258(7) Uani 1 1 d . . . . .
C32 C 0.00485(13) 0.4390(2) 0.0663(2) 0.0213(7) Uani 1 1 d . . . . .
C33 C 0.00696(15) 0.3712(2) 0.1347(2) 0.0230(7) Uani 1 1 d . . . . .
C34 C -0.02483(12) 0.5161(2) 0.07519(19) 0.0261(7) Uani 1 1 d . . . . .
C35 C -0.04783(15) 0.5367(2) 0.1518(2) 0.0343(8) Uani 1 1 d . . . . .
H35 H -0.0448 0.4975 0.1962 0.041 Uiso 1 1 calc R U . . .
C36 C -0.07389(16) 0.6128(2) 0.1602(2) 0.0436(9) Uani 1 1 d . . . . .
H36 H -0.0863 0.6268 0.2116 0.052 Uiso 1 1 calc R U . . .
N1 N 0.15540(12) 0.3767(2) 0.3198(2) 0.0370(8) Uani 1 1 d . . . . .
N2 N 0.14814(16) 0.2368(2) 0.4206(3) 0.0373(9) Uani 1 1 d . . . . .
O1 O 0.23146(11) 0.1861(2) 0.21568(17) 0.0541(8) Uani 1 1 d . . . . .
O2 O 0.15717(12) 0.26416(16) 0.1706(2) 0.0325(6) Uani 1 1 d . . . . .
O3 O 0.05230(12) 0.16289(18) 0.15705(16) 0.0382(7) Uani 1 1 d . . . . .
O4 O -0.03856(11) 0.14533(16) 0.16361(16) 0.0351(6) Uani 1 1 d . . . . .
O5 O 0.05168(11) 0.35919(17) 0.18074(16) 0.0353(6) Uani 1 1 d . . . . .
O6 O -0.03748(11) 0.33020(16) 0.14127(16) 0.0356(6) Uani 1 1 d . . . . .
O7 O 0.14617(11) 0.11181(18) 0.27688(18) 0.0456(7) Uani 1 1 d . . . . .
H7A H 0.1775 0.1209 0.2591 0.055 Uiso 1 1 d R U . . .
H7B H 0.1282 0.0743 0.2460 0.055 Uiso 1 1 d R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O6 Eu1 O5 76.57(9) 2 . ?
O6 Eu1 O4 75.40(9) 2 2 ?
O5 Eu1 O4 123.65(9) . 2 ?
O6 Eu1 O3 123.36(9) 2 . ?
O5 Eu1 O3 80.53(10) . . ?
O4 Eu1 O3 75.83(9) 2 . ?
O6 Eu1 O2 142.91(8) 2 . ?
O5 Eu1 O2 77.08(9) . . ?
O4 Eu1 O2 141.59(8) 2 . ?
O3 Eu1 O2 76.83(10) . . ?
O6 Eu1 O7 138.93(9) 2 . ?
O5 Eu1 O7 143.78(9) . . ?
O4 Eu1 O7 73.03(9) 2 . ?
O3 Eu1 O7 72.74(10) . . ?
O2 Eu1 O7 73.41(8) . . ?
O6 Eu1 N1 77.01(9) 2 . ?
O5 Eu1 N1 79.89(10) . . ?
O4 Eu1 N1 137.13(9) 2 . ?
O3 Eu1 N1 146.99(10) . . ?
O2 Eu1 N1 73.04(10) . . ?
O7 Eu1 N1 110.34(10) . . ?
O6 Eu1 N2 77.23(11) 2 . ?
O5 Eu1 N2 138.66(10) . . ?
O4 Eu1 N2 78.89(11) 2 . ?
O3 Eu1 N2 140.81(11) . . ?
O2 Eu1 N2 107.33(12) . . ?
O7 Eu1 N2 71.50(11) . . ?
N1 Eu1 N2 63.37(11) . . ?
O6 Eu1 Eu1 58.75(7) 2 2 ?
O5 Eu1 Eu1 64.46(7) . 2 ?
O4 Eu1 Eu1 59.20(7) 2 2 ?
O3 Eu1 Eu1 64.61(7) . 2 ?
O2 Eu1 Eu1 128.49(8) . 2 ?
O7 Eu1 Eu1 121.33(7) . 2 ?
N1 Eu1 Eu1 127.52(7) . 2 ?
N2 Eu1 Eu1 124.17(9) . 2 ?
N1 C1 C2 122.7(5) . . ?
N1 C1 H1 118.7 . . ?
C2 C1 H1 118.7 . . ?
C3 C2 C1 120.2(5) . . ?
C3 C2 H2 119.9 . . ?
C1 C2 H2 119.9 . . ?
C2 C3 C4 119.5(4) . . ?
C2 C3 H3 120.2 . . ?
C4 C3 H3 120.2 . . ?
C3 C4 C12 118.4(4) . . ?
C3 C4 C5 123.8(5) . . ?
C12 C4 C5 117.7(5) . . ?
C6 C5 C4 121.9(5) . . ?
C6 C5 H5 119.1 . . ?
C4 C5 H5 119.1 . . ?
C5 C6 C7 121.2(5) . . ?
C5 C6 H6 119.4 . . ?
C7 C6 H6 119.4 . . ?
C8 C7 C11 117.4(5) . . ?
C8 C7 C6 123.4(5) . . ?
C11 C7 C6 119.0(6) . . ?
C9 C8 C7 119.8(5) . . ?
C9 C8 H8 120.1 . . ?
C7 C8 H8 120.1 . . ?
C8 C9 C10 119.4(6) . . ?
C8 C9 H9 120.3 . . ?
C10 C9 H9 120.3 . . ?
N2 C10 C9 121.8(6) . . ?
N2 C10 H10 119.1 . . ?
C9 C10 H10 119.1 . . ?
N2 C11 C7 122.5(5) . . ?
N2 C11 C12 118.5(4) . . ?
C7 C11 C12 118.9(5) . . ?
N1 C12 C11 118.3(3) . . ?
N1 C12 C4 120.5(4) . . ?
C11 C12 C4 121.1(4) . . ?
C14 C13 C20 120.6(3) . 7 ?
C14 C13 H13 119.7 . . ?
C20 C13 H13 119.7 7 . ?
C13 C14 C15 121.2(3) . . ?
C13 C14 H14 119.4 . . ?
C15 C14 H14 119.4 . . ?
C16 C15 C14 122.5(3) . . ?
C16 C15 C18 119.3(3) . 7 ?
C14 C15 C18 118.3(3) . 7 ?
C15 C16 C18 121.1(3) . . ?
C15 C16 C17 120.0(3) . . ?
C18 C16 C17 118.8(3) . . ?
O2 C17 O1 124.7(4) . . ?
O2 C17 C16 118.2(4) . . ?
O1 C17 C16 117.2(3) . . ?
C16 C18 C19 122.5(3) . . ?
C16 C18 C15 119.6(3) . 7 ?
C19 C18 C15 117.9(3) . 7 ?
C20 C19 C18 121.3(3) . . ?
C20 C19 H19 119.3 . . ?
C18 C19 H19 119.3 . . ?
C19 C20 C13 120.7(3) . 7 ?
C19 C20 H20 119.7 . . ?
C13 C20 H20 119.7 7 . ?
O3 C21 O4 125.9(3) . . ?
O3 C21 C25 117.6(3) . . ?
O4 C21 C25 116.5(3) . . ?
C23 C22 C28 120.5(3) . 5 ?
C23 C22 H22 119.7 . . ?
C28 C22 H22 119.7 5 . ?
C22 C23 C24 121.2(3) . . ?
C22 C23 H23 119.4 . . ?
C24 C23 H23 119.4 . . ?
C25 C24 C23 122.6(3) . . ?
C25 C24 C26 119.4(3) . 5 ?
C23 C24 C26 118.0(3) . 5 ?
C24 C25 C26 121.3(3) . . ?
C24 C25 C21 120.8(3) . . ?
C26 C25 C21 117.9(3) . . ?
C25 C26 C27 122.2(3) . . ?
C25 C26 C24 119.3(3) . 5 ?
C27 C26 C24 118.5(3) . 5 ?
C28 C27 C26 121.0(3) . . ?
C28 C27 H27 119.5 . . ?
C26 C27 H27 119.5 . . ?
C27 C28 C22 120.7(3) . 5 ?
C27 C28 H28 119.6 . . ?
C22 C28 H28 119.6 5 . ?
C30 C29 C36 120.3(3) . 5_565 ?
C30 C29 H29 119.9 . . ?
C36 C29 H29 119.9 5_565 . ?
C29 C30 C31 120.7(3) . . ?
C29 C30 H30 119.7 . . ?
C31 C30 H30 119.7 . . ?
C32 C31 C30 122.2(3) . . ?
C32 C31 C34 119.3(3) . 5_565 ?
C30 C31 C34 118.5(3) . 5_565 ?
C31 C32 C34 120.9(3) . . ?
C31 C32 C33 119.3(3) . . ?
C34 C32 C33 119.7(3) . . ?
O5 C33 O6 124.4(3) . . ?
O5 C33 C32 119.0(3) . . ?
O6 C33 C32 116.7(3) . . ?
C32 C34 C35 121.6(3) . . ?
C32 C34 C31 119.8(3) . 5_565 ?
C35 C34 C31 118.5(3) . 5_565 ?
C36 C35 C34 120.5(3) . . ?
C36 C35 H35 119.8 . . ?
C34 C35 H35 119.8 . . ?
C35 C36 C29 121.3(3) . 5_565 ?
C35 C36 H36 119.3 . . ?
C29 C36 H36 119.3 5_565 . ?
C1 N1 C12 118.6(3) . . ?
C1 N1 Eu1 122.3(3) . . ?
C12 N1 Eu1 118.4(2) . . ?
C10 N2 C11 119.1(4) . . ?
C10 N2 Eu1 122.6(3) . . ?
C11 N2 Eu1 117.7(3) . . ?
C17 O2 Eu1 135.0(3) . . ?
C21 O3 Eu1 137.0(2) . . ?
C21 O4 Eu1 145.7(2) . 2 ?
C33 O5 Eu1 137.1(2) . . ?
C33 O6 Eu1 147.7(2) . 2 ?
Eu1 O7 H7A 109.4 . . ?
Eu1 O7 H7B 109.4 . . ?
H7A O7 H7B 109.8 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O6 2.361(2) 2 ?
Eu1 O5 2.368(2) . ?
Eu1 O4 2.374(2) 2 ?
Eu1 O3 2.388(3) . ?
Eu1 O2 2.397(3) . ?
Eu1 O7 2.520(3) . ?
Eu1 N1 2.567(3) . ?
Eu1 N2 2.612(4) . ?
Eu1 Eu1 4.4061(9) 2 ?
C1 N1 1.329(5) . ?
C1 C2 1.395(6) . ?
C1 H1 0.9300 . ?
C2 C3 1.346(8) . ?
C2 H2 0.9300 . ?
C3 C4 1.401(8) . ?
C3 H3 0.9300 . ?
C4 C12 1.424(6) . ?
C4 C5 1.435(8) . ?
C5 C6 1.340(8) . ?
C5 H5 0.9300 . ?
C6 C7 1.443(8) . ?
C6 H6 0.9300 . ?
C7 C8 1.402(9) . ?
C7 C11 1.418(6) . ?
C8 C9 1.378(9) . ?
C8 H8 0.9300 . ?
C9 C10 1.413(7) . ?
C9 H9 0.9300 . ?
C10 N2 1.338(6) . ?
C10 H10 0.9300 . ?
C11 N2 1.353(6) . ?
C11 C12 1.423(6) . ?
C12 N1 1.376(5) . ?
C13 C14 1.361(5) . ?
C13 C20 1.408(5) 7 ?
C13 H13 0.9300 . ?
C14 C15 1.431(5) . ?
C14 H14 0.9300 . ?
C15 C16 1.401(5) . ?
C15 C18 1.449(4) 7 ?
C16 C18 1.407(5) . ?
C16 C17 1.520(5) . ?
C17 O2 1.256(5) . ?
C17 O1 1.253(5) . ?
C18 C19 1.433(5) . ?
C18 C15 1.449(4) 7 ?
C19 C20 1.361(5) . ?
C19 H19 0.9300 . ?
C20 C13 1.408(5) 7 ?
C20 H20 0.9300 . ?
C21 O3 1.246(4) . ?
C21 O4 1.258(4) . ?
C21 C25 1.513(5) . ?
C22 C23 1.358(5) . ?
C22 C28 1.417(5) 5 ?
C22 H22 0.9300 . ?
C23 C24 1.431(5) . ?
C23 H23 0.9300 . ?
C24 C25 1.404(5) . ?
C24 C26 1.442(4) 5 ?
C25 C26 1.412(5) . ?
C26 C27 1.433(4) . ?
C26 C24 1.442(4) 5 ?
C27 C28 1.355(5) . ?
C27 H27 0.9300 . ?
C28 C22 1.417(5) 5 ?
C28 H28 0.9300 . ?
C29 C30 1.367(5) . ?
C29 C36 1.411(5) 5_565 ?
C29 H29 0.9300 . ?
C30 C31 1.431(4) . ?
C30 H30 0.9300 . ?
C31 C32 1.413(4) . ?
C31 C34 1.436(4) 5_565 ?
C32 C34 1.412(5) . ?
C32 C33 1.513(5) . ?
C33 O5 1.252(4) . ?
C33 O6 1.264(4) . ?
C34 C35 1.433(4) . ?
C34 C31 1.436(4) 5_565 ?
C35 C36 1.354(5) . ?
C35 H35 0.9300 . ?
C36 C29 1.411(5) 5_565 ?
C36 H36 0.9300 . ?
O4 Eu1 2.374(2) 2 ?
O6 Eu1 2.361(2) 2 ?
O7 H7A 0.8499 . ?
O7 H7B 0.8500 . ?
