#------------------------------------------------------------------------------
#$Date: 2016-03-26 02:21:33 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180134 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/32/7103281.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7103281
loop_
_publ_author_name
'Chomitz, Wayne A'
'Arnold, John'
_publ_section_title
;
 Reactivity of a Co(i) [N(2)P(2)] complex with azides: evidence for a
 transient Co(iii) imido species.
;
_journal_issue                   31
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3648
_journal_page_last               3650
_journal_paper_doi               10.1039/b804754e
_journal_year                    2008
_chemical_formula_moiety         'C22 H51 Co N2 P2 Si'
_chemical_formula_sum            'C22 H51 Co N2 P2 Si'
_chemical_formula_weight         492.61
_chemical_name_systematic
;
?
;
_space_group_IT_number           62
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2n'
_symmetry_space_group_name_H-M   'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.742(4)
_cell_length_b                   17.148(5)
_cell_length_c                   11.265(3)
_cell_measurement_reflns_used    3150
_cell_measurement_temperature    244(2)
_cell_measurement_theta_max      25.3
_cell_measurement_theta_min      3.3
_cell_volume                     2847.6(13)
_computing_cell_refinement       'Bruker SAINT v7.07'
_computing_data_collection       'Bruker SMART v5.054d'
_computing_data_reduction        'Bruker SAINT v7.07'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      244(2)
_diffrn_measured_fraction_theta_full 0.954
_diffrn_measured_fraction_theta_max 0.954
_diffrn_measurement_device_type  'SMART 1000'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0423
_diffrn_reflns_av_sigmaI/netI    0.0420
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            14951
_diffrn_reflns_theta_full        26.53
_diffrn_reflns_theta_max         26.53
_diffrn_reflns_theta_min         3.29
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.768
_exptl_absorpt_correction_T_max  1.00
_exptl_absorpt_correction_T_min  0.89
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   'Blessing, 1995'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.149
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'hexangonal rods'
_exptl_crystal_F_000             1072
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.408
_refine_diff_density_min         -0.300
_refine_diff_density_rms         0.056
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.033
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     141
_refine_ls_number_reflns         2931
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.033
_refine_ls_R_factor_all          0.1017
_refine_ls_R_factor_gt           0.0528
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1000P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1429
_refine_ls_wR_factor_ref         0.1668
_reflns_number_gt                1747
_reflns_number_total             2931
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            b804754e.txt
_cod_data_source_block           wac6167cxs
_cod_original_sg_symbol_H-M      Pnma
_cod_database_code               7103281
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z'
'x+1/2, -y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z'
'-x-1/2, y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Co1 Co 0.16502(4) 0.2500 0.61148(6) 0.0533(3) Uani 1 2 d S . .
P1 P 0.11834(7) 0.35248(5) 0.71398(10) 0.0696(3) Uani 1 1 d . . .
Si1 Si 0.10410(12) 0.2500 0.38802(15) 0.1034(8) Uani 1 2 d S . .
N1 N 0.2069(3) 0.2500 0.4503(4) 0.0748(13) Uani 1 2 d S . .
N2 N 0.0341(3) 0.2500 0.5165(4) 0.0735(12) Uani 1 2 d S . .
C1 C 0.2975(4) 0.2500 0.4008(5) 0.101(2) Uani 1 2 d S . .
C2 C 0.3655(5) 0.2500 0.4907(7) 0.133(3) Uani 1 2 d SD . .
H2A H 0.4298(10) 0.2500 0.478(6) 0.180 Uiso 1 2 d SD . .
H2B H 0.350(3) 0.285(3) 0.554(4) 0.180 Uiso 1 1 d D . .
C3 C 0.3103(5) 0.3200(7) 0.3242(9) 0.337(9) Uani 1 1 d . . .
H3A H 0.3713 0.3199 0.2918 0.505 Uiso 1 1 calc R . .
H3B H 0.3014 0.3668 0.3711 0.505 Uiso 1 1 calc R . .
H3C H 0.2667 0.3189 0.2598 0.505 Uiso 1 1 calc R . .
C4 C 0.0749(4) 0.3359(5) 0.2908(5) 0.176(3) Uani 1 1 d . . .
H4A H 0.0543 0.3174 0.2140 0.264 Uiso 1 1 calc R . .
H4B H 0.1282 0.3684 0.2804 0.264 Uiso 1 1 calc R . .
H4C H 0.0271 0.3662 0.3280 0.264 Uiso 1 1 calc R . .
C5 C -0.0161(3) 0.3226(3) 0.5489(5) 0.0951(15) Uani 1 1 d . . .
H5A H -0.0810 0.3131 0.5374 0.114 Uiso 1 1 calc R . .
H5B H 0.0018 0.3639 0.4935 0.114 Uiso 1 1 calc R . .
C6 C -0.0020(3) 0.3518(3) 0.6727(5) 0.0929(14) Uani 1 1 d . . .
H6A H -0.0355 0.3186 0.7282 0.112 Uiso 1 1 calc R . .
H6B H -0.0263 0.4048 0.6792 0.112 Uiso 1 1 calc R . .
C7 C 0.1619(4) 0.4509(3) 0.6768(6) 0.1153(19) Uani 1 1 d . . .
H7A H 0.1382 0.4859 0.7395 0.138 Uiso 1 1 calc R . .
C8 C 0.2631(4) 0.4535(3) 0.6890(7) 0.153(2) Uani 1 1 d . . .
H8A H 0.2846 0.5057 0.6710 0.230 Uiso 1 1 calc R . .
H8B H 0.2903 0.4166 0.6344 0.230 Uiso 1 1 calc R . .
H8C H 0.2799 0.4400 0.7697 0.230 Uiso 1 1 calc R . .
C9 C 0.1317(6) 0.4826(5) 0.5699(10) 0.280(7) Uani 1 1 d . . .
H9A H 0.1571 0.5344 0.5600 0.420 Uiso 1 1 calc R . .
H9B H 0.0660 0.4860 0.5708 0.420 Uiso 1 1 calc R . .
H9C H 0.1509 0.4496 0.5047 0.420 Uiso 1 1 calc R . .
C10 C 0.1081(4) 0.3579(3) 0.8817(5) 0.1062(18) Uani 1 1 d . . .
H10A H 0.0761 0.3097 0.9060 0.127 Uiso 1 1 calc R . .
C11 C 0.0525(5) 0.4241(4) 0.9289(6) 0.154(3) Uani 1 1 d . . .
H11A H 0.0507 0.4214 1.0149 0.231 Uiso 1 1 calc R . .
H11B H -0.0087 0.4206 0.8978 0.231 Uiso 1 1 calc R . .
H11C H 0.0794 0.4732 0.9046 0.231 Uiso 1 1 calc R . .
C12 C 0.2013(5) 0.3539(4) 0.9399(6) 0.149(2) Uani 1 1 d . . .
H12A H 0.1946 0.3562 1.0255 0.223 Uiso 1 1 calc R . .
H12B H 0.2378 0.3976 0.9133 0.223 Uiso 1 1 calc R . .
H12C H 0.2309 0.3055 0.9179 0.223 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Co1 N2 79.76(18) . . ?
N1 Co1 P1 126.46(4) . 7_565 ?
N2 Co1 P1 88.91(8) . 7_565 ?
N1 Co1 P1 126.46(4) . . ?
N2 Co1 P1 88.91(8) . . ?
P1 Co1 P1 105.17(6) 7_565 . ?
N1 Co1 Si1 38.40(14) . . ?
N2 Co1 Si1 41.36(12) . . ?
P1 Co1 Si1 112.77(4) 7_565 . ?
P1 Co1 Si1 112.77(4) . . ?
C6 P1 C7 106.4(2) . . ?
C6 P1 C10 100.1(3) . . ?
C7 P1 C10 102.0(3) . . ?
C6 P1 Co1 99.42(16) . . ?
C7 P1 Co1 119.8(2) . . ?
C10 P1 Co1 125.67(17) . . ?
N1 Si1 N2 100.7(2) . . ?
N1 Si1 C4 116.8(2) . 7_565 ?
N2 Si1 C4 109.9(2) . 7_565 ?
N1 Si1 C4 116.8(2) . . ?
N2 Si1 C4 109.9(2) . . ?
C4 Si1 C4 102.8(5) 7_565 . ?
N1 Si1 Co1 45.51(15) . . ?
N2 Si1 Co1 55.14(14) . . ?
C4 Si1 Co1 128.6(2) 7_565 . ?
C4 Si1 Co1 128.6(2) . . ?
C1 N1 Si1 132.5(4) . . ?
C1 N1 Co1 131.4(4) . . ?
Si1 N1 Co1 96.1(2) . . ?
C5 N2 C5 113.0(4) . 7_565 ?
C5 N2 Si1 119.1(3) . . ?
C5 N2 Si1 119.1(3) 7_565 . ?
C5 N2 Co1 108.3(3) . . ?
C5 N2 Co1 108.3(3) 7_565 . ?
Si1 N2 Co1 83.49(16) . . ?
C2 C1 N1 112.1(5) . . ?
C2 C1 C3 108.8(6) . . ?
N1 C1 C3 109.9(4) . . ?
C2 C1 C3 108.8(6) . 7_565 ?
N1 C1 C3 109.9(4) . 7_565 ?
C3 C1 C3 107.3(11) . 7_565 ?
C1 C2 H2A 126(4) . . ?
C1 C2 H2B 111(3) . . ?
H2A C2 H2B 109.6(12) . . ?
C1 C3 H3A 109.5 . . ?
C1 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C1 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
Si1 C4 H4A 109.5 . . ?
Si1 C4 H4B 109.5 . . ?
H4A C4 H4B 109.5 . . ?
Si1 C4 H4C 109.5 . . ?
H4A C4 H4C 109.5 . . ?
H4B C4 H4C 109.5 . . ?
N2 C5 C6 116.0(4) . . ?
N2 C5 H5A 108.3 . . ?
C6 C5 H5A 108.3 . . ?
N2 C5 H5B 108.3 . . ?
C6 C5 H5B 108.3 . . ?
H5A C5 H5B 107.4 . . ?
C5 C6 P1 111.9(3) . . ?
C5 C6 H6A 109.2 . . ?
P1 C6 H6A 109.2 . . ?
C5 C6 H6B 109.2 . . ?
P1 C6 H6B 109.2 . . ?
H6A C6 H6B 107.9 . . ?
C9 C7 C8 112.7(6) . . ?
C9 C7 P1 116.1(5) . . ?
C8 C7 P1 110.5(4) . . ?
C9 C7 H7A 105.5 . . ?
C8 C7 H7A 105.5 . . ?
P1 C7 H7A 105.5 . . ?
C7 C8 H8A 109.5 . . ?
C7 C8 H8B 109.5 . . ?
H8A C8 H8B 109.5 . . ?
C7 C8 H8C 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
C7 C9 H9A 109.5 . . ?
C7 C9 H9B 109.5 . . ?
H9A C9 H9B 109.5 . . ?
C7 C9 H9C 109.5 . . ?
H9A C9 H9C 109.5 . . ?
H9B C9 H9C 109.5 . . ?
C11 C10 C12 112.0(5) . . ?
C11 C10 P1 115.7(5) . . ?
C12 C10 P1 110.7(4) . . ?
C11 C10 H10A 105.9 . . ?
C12 C10 H10A 105.9 . . ?
P1 C10 H10A 105.9 . . ?
C10 C11 H11A 109.5 . . ?
C10 C11 H11B 109.5 . . ?
H11A C11 H11B 109.5 . . ?
C10 C11 H11C 109.5 . . ?
H11A C11 H11C 109.5 . . ?
H11B C11 H11C 109.5 . . ?
C10 C12 H12A 109.5 . . ?
C10 C12 H12B 109.5 . . ?
H12A C12 H12B 109.5 . . ?
C10 C12 H12C 109.5 . . ?
H12A C12 H12C 109.5 . . ?
H12B C12 H12C 109.5 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Co1 N1 1.917(4) . ?
Co1 N2 2.207(4) . ?
Co1 P1 2.2124(11) 7_565 ?
Co1 P1 2.2124(11) . ?
Co1 Si1 2.6726(19) . ?
P1 C6 1.833(5) . ?
P1 C7 1.854(5) . ?
P1 C10 1.897(5) . ?
Si1 N1 1.669(5) . ?
Si1 N2 1.777(5) . ?
Si1 C4 1.886(6) 7_565 ?
Si1 C4 1.886(6) . ?
N1 C1 1.448(7) . ?
N2 C5 1.492(5) . ?
N2 C5 1.492(5) 7_565 ?
C1 C2 1.424(9) . ?
C1 C3 1.491(8) . ?
C1 C3 1.491(8) 7_565 ?
C2 H2A 0.959(5) . ?
C2 H2B 0.960(5) . ?
C3 H3A 0.9700 . ?
C3 H3B 0.9700 . ?
C3 H3C 0.9700 . ?
C4 H4A 0.9700 . ?
C4 H4B 0.9700 . ?
C4 H4C 0.9700 . ?
C5 C6 1.497(7) . ?
C5 H5A 0.9800 . ?
C5 H5B 0.9800 . ?
C6 H6A 0.9800 . ?
C6 H6B 0.9800 . ?
C7 C9 1.393(10) . ?
C7 C8 1.499(7) . ?
C7 H7A 0.9900 . ?
C8 H8A 0.9700 . ?
C8 H8B 0.9700 . ?
C8 H8C 0.9700 . ?
C9 H9A 0.9700 . ?
C9 H9B 0.9700 . ?
C9 H9C 0.9700 . ?
C10 C11 1.498(7) . ?
C10 C12 1.524(9) . ?
C10 H10A 0.9900 . ?
C11 H11A 0.9700 . ?
C11 H11B 0.9700 . ?
C11 H11C 0.9700 . ?
C12 H12A 0.9700 . ?
C12 H12B 0.9700 . ?
C12 H12C 0.9700 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
N1 Co1 P1 C6 88.1(2) . . . . ?
N2 Co1 P1 C6 11.7(2) . . . . ?
P1 Co1 P1 C6 -76.87(18) 7_565 . . . ?
Si1 Co1 P1 C6 46.41(18) . . . . ?
N1 Co1 P1 C7 -27.1(3) . . . . ?
N2 Co1 P1 C7 -103.5(2) . . . . ?
P1 Co1 P1 C7 167.9(2) 7_565 . . . ?
Si1 Co1 P1 C7 -68.8(2) . . . . ?
N1 Co1 P1 C10 -162.1(3) . . . . ?
N2 Co1 P1 C10 121.5(3) . . . . ?
P1 Co1 P1 C10 32.9(2) 7_565 . . . ?
Si1 Co1 P1 C10 156.2(2) . . . . ?
N2 Co1 Si1 N1 180.0 . . . . ?
P1 Co1 Si1 N1 -120.52(4) 7_565 . . . ?
P1 Co1 Si1 N1 120.52(4) . . . . ?
N1 Co1 Si1 N2 180.0 . . . . ?
P1 Co1 Si1 N2 59.48(4) 7_565 . . . ?
P1 Co1 Si1 N2 -59.48(4) . . . . ?
N1 Co1 Si1 C4 91.5(3) . . . 7_565 ?
N2 Co1 Si1 C4 -88.5(3) . . . 7_565 ?
P1 Co1 Si1 C4 -29.1(3) 7_565 . . 7_565 ?
P1 Co1 Si1 C4 -148.0(3) . . . 7_565 ?
N1 Co1 Si1 C4 -91.5(3) . . . . ?
N2 Co1 Si1 C4 88.5(3) . . . . ?
P1 Co1 Si1 C4 148.0(3) 7_565 . . . ?
P1 Co1 Si1 C4 29.1(3) . . . . ?
N2 Si1 N1 C1 180.0 . . . . ?
C4 Si1 N1 C1 61.1(3) 7_565 . . . ?
C4 Si1 N1 C1 -61.1(3) . . . . ?
Co1 Si1 N1 C1 180.0 . . . . ?
N2 Si1 N1 Co1 0.0 . . . . ?
C4 Si1 N1 Co1 -118.9(3) 7_565 . . . ?
C4 Si1 N1 Co1 118.9(3) . . . . ?
N2 Co1 N1 C1 180.0 . . . . ?
P1 Co1 N1 C1 -99.06(10) 7_565 . . . ?
P1 Co1 N1 C1 99.06(10) . . . . ?
Si1 Co1 N1 C1 180.0 . . . . ?
N2 Co1 N1 Si1 0.0 . . . . ?
P1 Co1 N1 Si1 80.94(10) 7_565 . . . ?
P1 Co1 N1 Si1 -80.94(10) . . . . ?
N1 Si1 N2 C5 107.4(3) . . . . ?
C4 Si1 N2 C5 -128.8(4) 7_565 . . . ?
C4 Si1 N2 C5 -16.4(4) . . . . ?
Co1 Si1 N2 C5 107.4(3) . . . . ?
N1 Si1 N2 C5 -107.4(3) . . . 7_565 ?
C4 Si1 N2 C5 16.4(4) 7_565 . . 7_565 ?
C4 Si1 N2 C5 128.8(4) . . . 7_565 ?
Co1 Si1 N2 C5 -107.4(3) . . . 7_565 ?
N1 Si1 N2 Co1 0.0 . . . . ?
C4 Si1 N2 Co1 123.8(3) 7_565 . . . ?
C4 Si1 N2 Co1 -123.8(3) . . . . ?
N1 Co1 N2 C5 -118.6(3) . . . . ?
P1 Co1 N2 C5 114.0(3) 7_565 . . . ?
P1 Co1 N2 C5 8.8(3) . . . . ?
Si1 Co1 N2 C5 -118.6(3) . . . . ?
N1 Co1 N2 C5 118.6(3) . . . 7_565 ?
P1 Co1 N2 C5 -8.8(3) 7_565 . . 7_565 ?
P1 Co1 N2 C5 -114.0(3) . . . 7_565 ?
Si1 Co1 N2 C5 118.6(3) . . . 7_565 ?
N1 Co1 N2 Si1 0.0 . . . . ?
P1 Co1 N2 Si1 -127.40(3) 7_565 . . . ?
P1 Co1 N2 Si1 127.40(3) . . . . ?
Si1 N1 C1 C2 180.0 . . . . ?
Co1 N1 C1 C2 0.0 . . . . ?
Si1 N1 C1 C3 58.9(6) . . . . ?
Co1 N1 C1 C3 -121.1(6) . . . . ?
Si1 N1 C1 C3 -58.9(6) . . . 7_565 ?
Co1 N1 C1 C3 121.1(6) . . . 7_565 ?
C5 N2 C5 C6 86.5(5) 7_565 . . . ?
Si1 N2 C5 C6 -126.3(4) . . . . ?
Co1 N2 C5 C6 -33.5(4) . . . . ?
N2 C5 C6 P1 46.4(5) . . . . ?
C7 P1 C6 C5 92.4(4) . . . . ?
C10 P1 C6 C5 -161.7(3) . . . . ?
Co1 P1 C6 C5 -32.7(4) . . . . ?
C6 P1 C7 C9 -41.0(7) . . . . ?
C10 P1 C7 C9 -145.5(7) . . . . ?
Co1 P1 C7 C9 70.5(7) . . . . ?
C6 P1 C7 C8 -171.0(5) . . . . ?
C10 P1 C7 C8 84.5(6) . . . . ?
Co1 P1 C7 C8 -59.5(6) . . . . ?
C6 P1 C10 C11 -54.8(5) . . . . ?
C7 P1 C10 C11 54.5(5) . . . . ?
Co1 P1 C10 C11 -164.3(4) . . . . ?
C6 P1 C10 C12 176.4(4) . . . . ?
C7 P1 C10 C12 -74.3(4) . . . . ?
Co1 P1 C10 C12 66.9(4) . . . . ?
