#------------------------------------------------------------------------------
#$Date: 2016-03-26 03:33:53 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180187 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/83/7108395.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7108395
loop_
_publ_author_name
'Cameron Jones'
'Anastas Sidiropoulos'
'Nicole Holzmann'
'Gernot Frenking'
'Andreas Stasch'
_publ_section_title
;
 An N-heterocyclic carbene adduct of diatomic tin, :Sn[double bond, length
 as m-dash]Sn:
;
_journal_name_full               Chem.Commun.
_journal_page_first              9855
_journal_paper_doi               10.1039/c2cc35228a
_journal_volume                  48
_journal_year                    2012
_chemical_formula_sum            'C66 H84 Ge2 N4'
_chemical_formula_weight         1078.55
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                92.4670(10)
_cell_angle_beta                 93.1220(10)
_cell_angle_gamma                116.6340(10)
_cell_formula_units_Z            2
_cell_length_a                   12.2068(2)
_cell_length_b                   13.3207(3)
_cell_length_c                   20.7196(4)
_cell_measurement_reflns_used    5672
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      25.33
_cell_measurement_theta_min      2.71
_cell_volume                     2998.50(11)
_computing_cell_refinement       'Apex2 v2012.2.0 (Bruker AXS, 2012)'
_computing_data_collection       'Apex2 v2012.2.0 (Bruker AXS, 2012)'
_computing_data_reduction        'Apex2 v2012.2.0 (Bruker AXS, 2012)'
_computing_molecular_graphics    'X-Seed (Barbour, 2001)'
_computing_publication_material  'CIFTAB (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      123(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker Apex X8'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0461
_diffrn_reflns_av_sigmaI/netI    0.0519
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       -29
_diffrn_reflns_number            99544
_diffrn_reflns_theta_full        30.00
_diffrn_reflns_theta_max         30.00
_diffrn_reflns_theta_min         2.83
_exptl_absorpt_coefficient_mu    1.044
_exptl_absorpt_correction_T_max  0.834
_exptl_absorpt_correction_T_min  0.742
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Sortav (Blessing, 1995)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.195
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1144
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.585
_refine_diff_density_min         -0.530
_refine_diff_density_rms         0.066
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     665
_refine_ls_number_reflns         17459
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.035
_refine_ls_R_factor_all          0.0658
_refine_ls_R_factor_gt           0.0381
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0336P)²+1.0138P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0772
_refine_ls_wR_factor_ref         0.0859
_reflns_number_gt                12679
_reflns_number_total             17459
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2cc35228a.cif
_cod_data_source_block           compound2(benzene)2
_cod_original_cell_volume        2998.50(10)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7108395
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Ge1 Ge 0.404843(15) 0.421717(13) 0.503129(8) 0.01795(5) Uani 1 1 d .
N1 N 0.49268(12) 0.25668(10) 0.44641(6) 0.0163(3) Uani 1 1 d .
C1 C 0.44178(13) 0.32788(12) 0.43648(7) 0.0151(3) Uani 1 1 d .
Ge2 Ge 0.590000(15) 0.020687(14) 0.032433(9) 0.01982(5) Uani 1 1 d .
N2 N 0.40563(12) 0.30958(11) 0.37187(6) 0.0165(3) Uani 1 1 d .
C2 C 0.48616(15) 0.19486(14) 0.38950(8) 0.0209(3) Uani 1 1 d .
H2 H 0.5145 0.1394 0.3845 0.025 Uiso 1 1 calc R
N3 N 0.57600(12) 0.21587(11) 0.10953(6) 0.0169(3) Uani 1 1 d .
C3 C 0.43214(15) 0.22831(14) 0.34289(8) 0.0209(3) Uani 1 1 d .
H3 H 0.4153 0.2014 0.2985 0.025 Uiso 1 1 calc R
N4 N 0.69207(12) 0.27637(11) 0.03152(6) 0.0169(3) Uani 1 1 d .
C4 C 0.52970(14) 0.23566(13) 0.50972(8) 0.0178(3) Uani 1 1 d .
C5 C 0.44100(15) 0.15101(13) 0.54229(8) 0.0216(4) Uani 1 1 d .
C6 C 0.47682(18) 0.13342(15) 0.60393(9) 0.0294(4) Uani 1 1 d .
H6 H 0.4189 0.0766 0.6276 0.035 Uiso 1 1 calc R
C7 C 0.59506(19) 0.19724(16) 0.63114(9) 0.0329(4) Uani 1 1 d .
H7 H 0.6174 0.1849 0.6736 0.039 Uiso 1 1 calc R
C8 C 0.68158(17) 0.27905(15) 0.59734(9) 0.0287(4) Uani 1 1 d .
H8 H 0.7630 0.3216 0.6167 0.034 Uiso 1 1 calc R
C9 C 0.65145(15) 0.30016(13) 0.53545(8) 0.0212(3) Uani 1 1 d .
C10 C 0.31003(16) 0.08014(14) 0.51339(9) 0.0277(4) Uani 1 1 d .
H10 H 0.3038 0.1030 0.4685 0.033 Uiso 1 1 calc R
C11 C 0.21862(18) 0.10083(17) 0.55188(12) 0.0448(6) Uani 1 1 d .
H11A H 0.2208 0.0767 0.5957 0.067 Uiso 1 1 calc R
H11B H 0.1357 0.0578 0.5304 0.067 Uiso 1 1 calc R
H11C H 0.2404 0.1813 0.5543 0.067 Uiso 1 1 calc R
C12 C 0.2783(2) -0.04470(16) 0.50819(12) 0.0452(6) Uani 1 1 d .
H12A H 0.3394 -0.0558 0.4841 0.068 Uiso 1 1 calc R
H12B H 0.1965 -0.0879 0.4854 0.068 Uiso 1 1 calc R
H12C H 0.2786 -0.0705 0.5517 0.068 Uiso 1 1 calc R
C13 C 0.74717(15) 0.38659(14) 0.49729(9) 0.0235(4) Uani 1 1 d .
H13 H 0.7041 0.4169 0.4674 0.028 Uiso 1 1 calc R
C14 C 0.80746(17) 0.33095(16) 0.45576(10) 0.0327(4) Uani 1 1 d .
H14A H 0.8506 0.3005 0.4839 0.049 Uiso 1 1 calc R
H14B H 0.8663 0.3869 0.4297 0.049 Uiso 1 1 calc R
H14C H 0.7441 0.2697 0.4270 0.049 Uiso 1 1 calc R
C15 C 0.84518(17) 0.48578(15) 0.54024(10) 0.0343(5) Uani 1 1 d .
H15A H 0.8053 0.5169 0.5692 0.051 Uiso 1 1 calc R
H15B H 0.8973 0.5441 0.5130 0.051 Uiso 1 1 calc R
H15C H 0.8959 0.4599 0.5661 0.051 Uiso 1 1 calc R
C16 C 0.33536(15) 0.35810(14) 0.33925(8) 0.0194(3) Uani 1 1 d .
C17 C 0.20701(16) 0.29797(15) 0.33597(9) 0.0256(4) Uani 1 1 d .
C18 C 0.14106(18) 0.34392(18) 0.30197(10) 0.0345(5) Uani 1 1 d .
H18 H 0.0538 0.3050 0.2980 0.041 Uiso 1 1 calc R
C19 C 0.19940(19) 0.44439(18) 0.27402(10) 0.0362(5) Uani 1 1 d .
H19 H 0.1522 0.4741 0.2513 0.043 Uiso 1 1 calc R
C20 C 0.32604(18) 0.50220(16) 0.27889(9) 0.0299(4) Uani 1 1 d .
H20 H 0.3651 0.5720 0.2598 0.036 Uiso 1 1 calc R
C21 C 0.39744(16) 0.45992(14) 0.31122(8) 0.0208(3) Uani 1 1 d .
C22 C 0.14044(16) 0.18889(16) 0.36760(10) 0.0326(4) Uani 1 1 d .
H22 H 0.2034 0.1755 0.3937 0.039 Uiso 1 1 calc R
C23 C 0.0752(2) 0.08985(18) 0.31671(12) 0.0511(6) Uani 1 1 d .
H23A H 0.0134 0.1012 0.2901 0.077 Uiso 1 1 calc R
H23B H 0.0349 0.0199 0.3384 0.077 Uiso 1 1 calc R
H23C H 0.1354 0.0849 0.2890 0.077 Uiso 1 1 calc R
C24 C 0.0504(2) 0.19531(19) 0.41368(13) 0.0533(6) Uani 1 1 d .
H24A H 0.0939 0.2598 0.4455 0.080 Uiso 1 1 calc R
H24B H 0.0143 0.1259 0.4362 0.080 Uiso 1 1 calc R
H24C H -0.0150 0.2043 0.3890 0.080 Uiso 1 1 calc R
C25 C 0.53648(16) 0.51950(14) 0.31343(8) 0.0222(4) Uani 1 1 d .
H25 H 0.5694 0.5006 0.3539 0.027 Uiso 1 1 calc R
C26 C 0.57866(18) 0.47427(16) 0.25570(9) 0.0302(4) Uani 1 1 d .
H26A H 0.5469 0.3925 0.2566 0.045 Uiso 1 1 calc R
H26B H 0.6687 0.5099 0.2583 0.045 Uiso 1 1 calc R
H26C H 0.5473 0.4914 0.2153 0.045 Uiso 1 1 calc R
C27 C 0.59010(18) 0.64744(15) 0.31495(10) 0.0319(4) Uani 1 1 d .
H27A H 0.5669 0.6688 0.2736 0.048 Uiso 1 1 calc R
H27B H 0.6799 0.6811 0.3219 0.048 Uiso 1 1 calc R
H27C H 0.5579 0.6747 0.3503 0.048 Uiso 1 1 calc R
C28 C 0.61571(13) 0.17944(13) 0.05732(7) 0.0155(3) Uani 1 1 d .
C29 C 0.62787(16) 0.33241(14) 0.11574(8) 0.0243(4) Uani 1 1 d .
H29 H 0.6144 0.3771 0.1483 0.029 Uiso 1 1 calc R
C30 C 0.70047(16) 0.37008(14) 0.06715(8) 0.0246(4) Uani 1 1 d .
H30 H 0.7485 0.4466 0.0588 0.030 Uiso 1 1 calc R
C31 C 0.50474(14) 0.14260(13) 0.15686(8) 0.0177(3) Uani 1 1 d .
C32 C 0.56811(15) 0.11495(14) 0.20556(8) 0.0204(3) Uani 1 1 d .
C33 C 0.49806(17) 0.04116(15) 0.24958(9) 0.0264(4) Uani 1 1 d .
H33 H 0.5381 0.0208 0.2835 0.032 Uiso 1 1 calc R
C34 C 0.37189(17) -0.00286(14) 0.24490(9) 0.0275(4) Uani 1 1 d .
H34 H 0.3259 -0.0540 0.2751 0.033 Uiso 1 1 calc R
C35 C 0.31171(16) 0.02658(14) 0.19688(9) 0.0251(4) Uani 1 1 d .
H35 H 0.2246 -0.0042 0.1946 0.030 Uiso 1 1 calc R
C36 C 0.37646(15) 0.10074(13) 0.15169(8) 0.0194(3) Uani 1 1 d .
C37 C 0.70723(16) 0.16516(16) 0.21176(9) 0.0276(4) Uani 1 1 d .
H37 H 0.7362 0.1927 0.1687 0.033 Uiso 1 1 calc R
C38 C 0.7537(2) 0.0806(2) 0.22764(14) 0.0568(7) Uani 1 1 d .
H38A H 0.8431 0.1153 0.2259 0.085 Uiso 1 1 calc R
H38B H 0.7150 0.0150 0.1961 0.085 Uiso 1 1 calc R
H38C H 0.7331 0.0566 0.2713 0.085 Uiso 1 1 calc R
C39 C 0.7625(2) 0.2661(2) 0.26071(14) 0.0618(8) Uani 1 1 d .
H39A H 0.7393 0.2416 0.3040 0.093 Uiso 1 1 calc R
H39B H 0.7316 0.3200 0.2493 0.093 Uiso 1 1 calc R
H39C H 0.8523 0.3021 0.2605 0.093 Uiso 1 1 calc R
C40 C 0.31057(15) 0.13597(15) 0.10051(9) 0.0253(4) Uani 1 1 d .
H40 H 0.3612 0.1558 0.0624 0.030 Uiso 1 1 calc R
C41 C 0.3015(2) 0.24163(18) 0.12575(11) 0.0423(5) Uani 1 1 d .
H41A H 0.2536 0.2250 0.1638 0.063 Uiso 1 1 calc R
H41B H 0.2607 0.2650 0.0918 0.063 Uiso 1 1 calc R
H41C H 0.3842 0.3024 0.1378 0.063 Uiso 1 1 calc R
C42 C 0.18317(17) 0.04251(17) 0.07711(10) 0.0353(5) Uani 1 1 d .
H42A H 0.1895 -0.0264 0.0645 0.053 Uiso 1 1 calc R
H42B H 0.1500 0.0658 0.0397 0.053 Uiso 1 1 calc R
H42C H 0.1283 0.0282 0.1121 0.053 Uiso 1 1 calc R
C43 C 0.76421(14) 0.28169(13) -0.02236(8) 0.0184(3) Uani 1 1 d .
C44 C 0.87971(15) 0.28568(14) -0.00884(8) 0.0220(4) Uani 1 1 d .
C45 C 0.94745(16) 0.28984(15) -0.06121(9) 0.0287(4) Uani 1 1 d .
H45 H 1.0256 0.2912 -0.0541 0.034 Uiso 1 1 calc R
C46 C 0.90297(17) 0.29207(17) -0.12350(10) 0.0334(4) Uani 1 1 d .
H46 H 0.9507 0.2949 -0.1587 0.040 Uiso 1 1 calc R
C47 C 0.78973(17) 0.29023(16) -0.13493(9) 0.0292(4) Uani 1 1 d .
H47 H 0.7610 0.2930 -0.1780 0.035 Uiso 1 1 calc R
C48 C 0.71647(15) 0.28435(13) -0.08451(8) 0.0212(3) Uani 1 1 d .
C49 C 0.93261(16) 0.28770(15) 0.05921(9) 0.0271(4) Uani 1 1 d .
H49 H 0.8690 0.2802 0.0897 0.032 Uiso 1 1 calc R
C50 C 0.9649(2) 0.19177(19) 0.06749(12) 0.0490(6) Uani 1 1 d .
H50A H 0.8916 0.1200 0.0563 0.074 Uiso 1 1 calc R
H50B H 0.9951 0.1944 0.1126 0.074 Uiso 1 1 calc R
H50C H 1.0289 0.1986 0.0389 0.074 Uiso 1 1 calc R
C51 C 1.0460(3) 0.4001(2) 0.07746(13) 0.0700(9) Uani 1 1 d .
H51A H 1.1099 0.4091 0.0483 0.105 Uiso 1 1 calc R
H51B H 1.0771 0.4014 0.1223 0.105 Uiso 1 1 calc R
H51C H 1.0237 0.4618 0.0735 0.105 Uiso 1 1 calc R
C52 C 0.59383(15) 0.28564(15) -0.09719(8) 0.0236(4) Uani 1 1 d .
H52 H 0.5434 0.2512 -0.0604 0.028 Uiso 1 1 calc R
C53 C 0.52237(17) 0.21638(16) -0.15954(9) 0.0309(4) Uani 1 1 d .
H53A H 0.5665 0.2518 -0.1969 0.046 Uiso 1 1 calc R
H53B H 0.4404 0.2130 -0.1631 0.046 Uiso 1 1 calc R
H53C H 0.5144 0.1399 -0.1586 0.046 Uiso 1 1 calc R
C54 C 0.61151(18) 0.40659(16) -0.09825(10) 0.0335(4) Uani 1 1 d .
H54A H 0.6489 0.4472 -0.0560 0.050 Uiso 1 1 calc R
H54B H 0.5315 0.4059 -0.1073 0.050 Uiso 1 1 calc R
H54C H 0.6655 0.4442 -0.1321 0.050 Uiso 1 1 calc R
C55 C 0.0696(2) 0.7148(2) 0.30194(10) 0.0468(6) Uani 1 1 d .
H55 H 0.1315 0.7343 0.2724 0.056 Uiso 1 1 calc R
C56 C -0.0196(3) 0.6057(2) 0.30130(12) 0.0566(7) Uani 1 1 d .
H56 H -0.0195 0.5497 0.2714 0.068 Uiso 1 1 calc R
C57 C -0.1096(2) 0.5774(2) 0.34429(14) 0.0560(7) Uani 1 1 d .
H57 H -0.1712 0.5017 0.3444 0.067 Uiso 1 1 calc R
C58 C -0.1099(2) 0.6584(2) 0.38661(12) 0.0524(6) Uani 1 1 d .
H58 H -0.1721 0.6396 0.4160 0.063 Uiso 1 1 calc R
C59 C -0.0205(2) 0.7667(2) 0.38669(11) 0.0473(6) Uani 1 1 d .
H59 H -0.0207 0.8230 0.4163 0.057 Uiso 1 1 calc R
C60 C 0.06981(19) 0.7951(2) 0.34450(11) 0.0435(5) Uani 1 1 d .
H60 H 0.1322 0.8706 0.3451 0.052 Uiso 1 1 calc R
C61 C 0.2694(3) 0.2418(3) -0.06995(13) 0.0613(7) Uani 1 1 d .
H61 H 0.3140 0.2470 -0.0299 0.074 Uiso 1 1 calc R
C62 C 0.2064(3) 0.1406(2) -0.10226(18) 0.0701(9) Uani 1 1 d .
H62 H 0.2038 0.0748 -0.0849 0.084 Uiso 1 1 calc R
C63 C 0.1440(3) 0.1345(3) -0.1629(2) 0.0915(13) Uani 1 1 d .
H63 H 0.0977 0.0651 -0.1880 0.110 Uiso 1 1 calc R
C64 C 0.1546(3) 0.2390(4) -0.18426(13) 0.0780(11) Uani 1 1 d .
H64 H 0.1175 0.2415 -0.2253 0.094 Uiso 1 1 calc R
C65 C 0.2170(3) 0.3323(3) -0.14585(17) 0.0636(8) Uani 1 1 d .
H65 H 0.2211 0.4010 -0.1595 0.076 Uiso 1 1 calc R
C66 C 0.2718(2) 0.3337(2) -0.09138(17) 0.0641(8) Uani 1 1 d .
H66 H 0.3155 0.4029 -0.0658 0.077 Uiso 1 1 calc R
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C1 Ge1 Ge1 92.48(4) 2_666
C1 N1 C2 111.23(13) .
C1 N1 C4 123.73(13) .
C2 N1 C4 124.32(13) .
N2 C1 N1 103.71(13) .
N2 C1 Ge1 127.24(11) .
N1 C1 Ge1 128.49(11) .
C28 Ge2 Ge2 92.03(4) 2_655
C1 N2 C3 111.34(13) .
C1 N2 C16 124.42(13) .
C3 N2 C16 123.83(13) .
C3 C2 N1 106.85(14) .
C28 N3 C29 110.94(13) .
C28 N3 C31 123.50(13) .
C29 N3 C31 124.92(13) .
C2 C3 N2 106.87(14) .
C28 N4 C30 111.33(13) .
C28 N4 C43 124.55(13) .
C30 N4 C43 123.88(13) .
C5 C4 C9 123.25(15) .
C5 C4 N1 117.69(14) .
C9 C4 N1 119.06(14) .
C6 C5 C4 117.21(16) .
C6 C5 C10 119.99(16) .
C4 C5 C10 122.80(15) .
C7 C6 C5 120.87(17) .
C6 C7 C8 120.70(17) .
C7 C8 C9 121.08(17) .
C8 C9 C4 116.86(16) .
C8 C9 C13 121.21(15) .
C4 C9 C13 121.91(15) .
C5 C10 C11 111.48(16) .
C5 C10 C12 110.99(16) .
C11 C10 C12 110.89(16) .
C9 C13 C14 110.23(14) .
C9 C13 C15 112.96(15) .
C14 C13 C15 110.18(15) .
C21 C16 C17 123.31(16) .
C21 C16 N2 119.06(14) .
C17 C16 N2 117.60(15) .
C18 C17 C16 116.66(17) .
C18 C17 C22 120.35(16) .
C16 C17 C22 122.99(16) .
C19 C18 C17 121.49(18) .
C18 C19 C20 120.34(18) .
C19 C20 C21 121.06(18) .
C20 C21 C16 117.12(16) .
C20 C21 C25 121.34(16) .
C16 C21 C25 121.49(15) .
C17 C22 C24 111.65(17) .
C17 C22 C23 110.99(17) .
C24 C22 C23 110.83(17) .
C21 C25 C27 113.64(15) .
C21 C25 C26 109.34(14) .
C27 C25 C26 110.40(15) .
N4 C28 N3 103.80(13) .
N4 C28 Ge2 127.48(11) .
N3 C28 Ge2 128.03(11) .
C30 C29 N3 107.07(14) .
C29 C30 N4 106.85(14) .
C32 C31 C36 122.93(15) .
C32 C31 N3 117.60(14) .
C36 C31 N3 119.46(14) .
C33 C32 C31 117.09(15) .
C33 C32 C37 121.00(16) .
C31 C32 C37 121.89(15) .
C34 C33 C32 121.20(17) .
C33 C34 C35 120.60(16) .
C34 C35 C36 121.04(16) .
C35 C36 C31 117.12(16) .
C35 C36 C40 120.90(15) .
C31 C36 C40 121.96(15) .
C38 C37 C39 110.84(18) .
C38 C37 C32 113.18(16) .
C39 C37 C32 110.79(16) .
C36 C40 C42 112.99(15) .
C36 C40 C41 110.13(15) .
C42 C40 C41 110.36(15) .
C48 C43 C44 123.61(15) .
C48 C43 N4 118.62(14) .
C44 C43 N4 117.76(14) .
C45 C44 C43 117.04(16) .
C45 C44 C49 119.95(16) .
C43 C44 C49 123.00(15) .
C46 C45 C44 121.00(17) .
C47 C46 C45 120.41(17) .
C46 C47 C48 121.35(17) .
C43 C48 C47 116.58(15) .
C43 C48 C52 122.34(15) .
C47 C48 C52 121.04(16) .
C50 C49 C44 112.33(16) .
C50 C49 C51 109.90(18) .
C44 C49 C51 110.41(16) .
C48 C52 C53 112.63(15) .
C48 C52 C54 110.49(14) .
C53 C52 C54 110.67(15) .
C60 C55 C56 120.3(2) .
C55 C56 C57 119.8(2) .
C58 C57 C56 119.8(2) .
C57 C58 C59 119.8(2) .
C58 C59 C60 120.7(2) .
C55 C60 C59 119.6(2) .
C66 C61 C62 122.6(3) .
C61 C62 C63 118.2(3) .
C62 C63 C64 116.1(3) .
C65 C64 C63 118.9(3) .
C66 C65 C64 122.7(3) .
C65 C66 C61 121.5(3) .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ge1 C1 2.0241(16) .
Ge1 Ge1 2.3400(3) 2_666
N1 C1 1.364(2) .
N1 C2 1.386(2) .
N1 C4 1.443(2) .
C1 N2 1.363(2) .
Ge2 C28 2.0322(15) .
Ge2 Ge2 2.3381(3) 2_655
N2 C3 1.385(2) .
N2 C16 1.443(2) .
C2 C3 1.341(2) .
N3 C28 1.365(2) .
N3 C29 1.386(2) .
N3 C31 1.444(2) .
N4 C28 1.362(2) .
N4 C30 1.383(2) .
N4 C43 1.444(2) .
C4 C5 1.396(2) .
C4 C9 1.400(2) .
C5 C6 1.391(2) .
C5 C10 1.516(2) .
C6 C7 1.376(3) .
C7 C8 1.381(3) .
C8 C9 1.390(2) .
C9 C13 1.513(2) .
C10 C11 1.520(3) .
C10 C12 1.526(3) .
C13 C14 1.528(3) .
C13 C15 1.528(2) .
C16 C21 1.395(2) .
C16 C17 1.400(2) .
C17 C18 1.392(3) .
C17 C22 1.511(3) .
C18 C19 1.375(3) .
C19 C20 1.379(3) .
C20 C21 1.391(2) .
C21 C25 1.514(2) .
C22 C24 1.523(3) .
C22 C23 1.528(3) .
C25 C27 1.525(2) .
C25 C26 1.530(2) .
C29 C30 1.339(2) .
C31 C32 1.398(2) .
C31 C36 1.403(2) .
C32 C33 1.392(2) .
C32 C37 1.516(2) .
C33 C34 1.376(3) .
C34 C35 1.377(3) .
C35 C36 1.392(2) .
C36 C40 1.510(2) .
C37 C38 1.511(3) .
C37 C39 1.512(3) .
C40 C42 1.528(2) .
C40 C41 1.533(3) .
C43 C48 1.393(2) .
C43 C44 1.399(2) .
C44 C45 1.388(2) .
C44 C49 1.513(2) .
C45 C46 1.379(3) .
C46 C47 1.379(3) .
C47 C48 1.394(2) .
C48 C52 1.514(2) .
C49 C50 1.510(3) .
C49 C51 1.529(3) .
C52 C53 1.528(2) .
C52 C54 1.528(3) .
C55 C60 1.355(3) .
C55 C56 1.370(4) .
C56 C57 1.381(4) .
C57 C58 1.362(4) .
C58 C59 1.363(3) .
C59 C60 1.372(3) .
C61 C66 1.309(4) .
C61 C62 1.339(4) .
C62 C63 1.413(5) .
C63 C64 1.431(5) .
C64 C65 1.326(4) .
C65 C66 1.275(4) .
