#------------------------------------------------------------------------------
#$Date: 2016-03-26 03:35:16 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180188 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/84/7108432.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7108432
loop_
_publ_author_name
'Han-Yuan Gong'
'Brett M. Rambo'
'Cory Nelson'
'Vincent M. Lynch'
'Xiaoyang Zhu'
'Jonathan L. Sessler'
_publ_section_title
;
 Rare-earth cation effects on three-dimensional metal-organic rotaxane
 framework (MORF) self assembly
;
_journal_name_full               Chem.Commun.
_journal_page_first              10186
_journal_page_last               10188
_journal_paper_doi               10.1039/C2CC34200F
_journal_volume                  48
_journal_year                    2012
_chemical_formula_sum            'C78 H92 Eu2 N10 O39'
_chemical_formula_weight         2097.54
_chemical_name_common
;
cyclo(2)(2,6-di(1H-imidazol-1-yl)pyridine)(2)(1,4-
dimethylenebenzene)_ 5 terephthalate dianion_ 2 europium(iii)_19 H2O
;
_chemical_name_systematic
;
?
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 130.442(19)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   23.198(5)
_cell_length_b                   15.455(3)
_cell_length_c                   34.046(10)
_cell_measurement_reflns_used    15932
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      25.00
_cell_measurement_theta_min      1.15
_cell_volume                     9290(5)
_computing_cell_refinement       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_collection       'CrystalClear (Rigaku Inc., 2008)'
_computing_data_reduction        'CrystalClear (Rigaku Inc., 2008)'
_computing_molecular_graphics
;
XP, Shelxtl-Plus Version 5.1, Bruker AXS, 1998.
;
_computing_publication_material
;
XCIF, Shelxtl-Plus Version 5.1, Bruker AXS, 1998.
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 28.5714
_diffrn_measured_fraction_theta_full 0.975
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measurement_device_type
;
Saturn724+ (2x2 bin mode)
;
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.1061
_diffrn_reflns_av_sigmaI/netI    0.1267
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            70080
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.15
_exptl_absorpt_coefficient_mu    1.430
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.6570
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
Sheldrick, G. M. (1996). SADABS. University of Göttingen, Germany.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.500
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             4272
_exptl_crystal_size_max          0.12
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.03
_platon_squeeze_details
;
;
_refine_diff_density_max         1.455
_refine_diff_density_min         -1.847
_refine_diff_density_rms         0.156
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     976
_refine_ls_number_reflns         15932
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.007
_refine_ls_R_factor_all          0.1312
_refine_ls_R_factor_gt           0.0856
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0500P)²+60.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1906
_refine_ls_wR_factor_ref         0.2092
_reflns_number_gt                9392
_reflns_number_total             15932
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c2cc34200f.txt
_cod_data_source_block           MORF_Eu
_cod_original_cell_volume        9290(4)
_cod_original_sg_symbol_H-M      P21/c
_cod_database_code               7108432
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.45499(3) 0.25785(3) 0.58695(2) 0.04633(18) Uani 1 1 d .
Eu2 Eu 0.02036(3) 0.23500(4) 0.14573(2) 0.05212(19) Uani 1 1 d .
O1 O 0.4127(4) 0.2668(4) 0.5005(3) 0.0486(18) Uani 1 1 d .
O1W O 0.5520(4) 0.2532(5) 0.6812(3) 0.060(2) Uani 1 1 d .
O2 O 0.3228(4) 0.2629(4) 0.5049(3) 0.0531(19) Uani 1 1 d .
O2W O 0.0195(4) 0.3922(5) 0.1552(4) 0.078(3) Uani 1 1 d .
O3 O 0.4485(4) 0.1125(4) 0.5692(3) 0.062(2) Uani 1 1 d .
O3W O -0.0708(4) 0.2668(4) 0.0526(3) 0.062(2) Uani 1 1 d .
O4 O 0.4871(5) -0.0193(5) 0.6017(3) 0.068(2) Uani 1 1 d .
O5 O 0.4852(4) 0.4019(4) 0.5903(3) 0.062(2) Uani 1 1 d .
O6 O 0.5043(5) 0.5405(4) 0.6092(3) 0.064(2) Uani 1 1 d .
O7 O 0.5699(4) 0.2353(5) 0.6037(3) 0.062(2) Uani 1 1 d .
O8 O 0.6697(5) 0.2320(6) 0.6871(4) 0.085(3) Uani 1 1 d .
O9 O 0.9032(4) 0.2479(6) 0.6258(3) 0.0786(19) Uani 1 1 d .
O10 O 0.8025(4) 0.2549(6) 0.5412(4) 0.0786(19) Uani 1 1 d .
O11 O 0.3826(4) 0.3349(4) 0.6080(3) 0.053(2) Uani 1 1 d .
O12 O 0.3807(4) 0.1960(4) 0.6080(3) 0.052(2) Uani 1 1 d .
O13 O 0.1148(4) 0.3395(4) 0.6434(3) 0.0529(19) Uani 1 1 d .
O14 O 0.0964(4) 0.2033(4) 0.6257(3) 0.056(2) Uani 1 1 d .
O15 O 0.0520(4) 0.2579(5) 0.2319(3) 0.061(2) Uani 1 1 d .
O16 O 0.1472(3) 0.2501(4) 0.2319(3) 0.0485(17) Uani 1 1 d .
O17 O 0.0283(4) 0.0971(5) 0.1830(3) 0.0668(16) Uani 1 1 d .
O18 O -0.0329(4) 0.0902(5) 0.1004(3) 0.0668(16) Uani 1 1 d .
O19 O 0.0643(8) -0.3525(6) 0.2001(6) 0.155(6) Uani 1 1 d .
O20 O 0.1069(9) -0.3381(7) 0.1605(6) 0.154(6) Uani 1 1 d .
N1 N 0.2262(5) 0.4929(6) 0.2802(4) 0.068(3) Uani 1 1 d .
N2 N 0.3013(5) 0.4413(7) 0.2693(4) 0.063(3) Uani 1 1 d .
N3 N 0.3217(5) 0.3012(6) 0.2620(3) 0.055(2) Uani 1 1 d .
N4 N 0.3344(4) 0.1526(6) 0.2576(3) 0.058(3) Uani 1 1 d .
N5 N 0.2712(5) 0.0469(6) 0.2533(3) 0.049(2) Uani 1 1 d .
N6 N 0.2183(6) 0.0352(5) 0.4465(4) 0.057(3) Uani 1 1 d .
N7 N 0.1463(5) 0.1046(6) 0.4576(3) 0.054(2) Uani 1 1 d .
N8 N 0.1541(5) 0.2425(6) 0.4815(3) 0.051(2) Uani 1 1 d .
N9 N 0.1679(5) 0.3880(5) 0.5027(4) 0.052(2) Uani 1 1 d .
N10 N 0.2379(4) 0.4835(5) 0.5050(3) 0.051(2) Uani 1 1 d .
C1 C 0.2453(6) 0.4212(8) 0.2686(5) 0.069(4) Uani 1 1 d .
H1A H 0.2230 0.3670 0.2614 0.082 Uiso 1 1 calc R
C2 C 0.2744(7) 0.5605(7) 0.2895(5) 0.062(3) Uani 1 1 d .
H2A H 0.2741 0.6170 0.2988 0.074 Uiso 1 1 calc R
C3 C 0.3196(7) 0.5293(9) 0.2827(5) 0.074(4) Uani 1 1 d .
H3A H 0.3573 0.5596 0.2860 0.089 Uiso 1 1 calc R
C4 C 0.3386(6) 0.3818(6) 0.2612(4) 0.048(3) Uani 1 1 d .
C5 C 0.3882(7) 0.4038(9) 0.2550(5) 0.075(4) Uani 1 1 d .
H5A H 0.3968 0.4620 0.2536 0.090 Uiso 1 1 calc R
C6 C 0.4259(6) 0.3432(10) 0.2506(5) 0.075(4) Uani 1 1 d .
H6A H 0.4613 0.3592 0.2474 0.090 Uiso 1 1 calc R
C7 C 0.4101(6) 0.2550(8) 0.2511(4) 0.060(3) Uani 1 1 d .
H7A H 0.4336 0.2099 0.2481 0.072 Uiso 1 1 calc R
C8 C 0.3556(6) 0.2418(7) 0.2565(4) 0.053(3) Uani 1 1 d .
C9 C 0.2745(5) 0.1315(7) 0.2510(4) 0.048(3) Uani 1 1 d .
H9A H 0.2393 0.1704 0.2456 0.058 Uiso 1 1 calc R
C10 C 0.3740(8) 0.0796(10) 0.2622(5) 0.083(4) Uani 1 1 d .
H10A H 0.4171 0.0760 0.2657 0.099 Uiso 1 1 calc R
C11 C 0.3303(7) 0.0120(8) 0.2602(5) 0.068(4) Uani 1 1 d .
H11A H 0.3409 -0.0468 0.2632 0.082 Uiso 1 1 calc R
C12 C 0.2144(6) 0.0016(6) 0.2511(4) 0.054(3) Uani 1 1 d .
H12A H 0.2131 -0.0586 0.2424 0.064 Uiso 1 1 calc R
H12B H 0.1651 0.0266 0.2240 0.064 Uiso 1 1 calc R
C13 C 0.2303(7) 0.0064(6) 0.3011(5) 0.050(3) Uani 1 1 d .
C14 C 0.2996(7) -0.0246(6) 0.3481(5) 0.057(3) Uani 1 1 d .
H14A H 0.3357 -0.0488 0.3476 0.069 Uiso 1 1 calc R
C15 C 0.3141(7) -0.0195(6) 0.3937(4) 0.053(3) Uani 1 1 d .
H15A H 0.3600 -0.0387 0.4241 0.063 Uiso 1 1 calc R
C16 C 0.2598(8) 0.0144(7) 0.3935(6) 0.070(4) Uani 1 1 d .
C17 C 0.1906(7) 0.0418(6) 0.3489(6) 0.068(4) Uani 1 1 d .
H17A H 0.1536 0.0627 0.3495 0.081 Uiso 1 1 calc R
C18 C 0.1783(8) 0.0373(7) 0.3041(5) 0.071(4) Uani 1 1 d .
H18A H 0.1320 0.0564 0.2739 0.085 Uiso 1 1 calc R
C19 C 0.2790(8) 0.0156(7) 0.4470(5) 0.072(4) Uani 1 1 d .
H19A H 0.2992 -0.0407 0.4630 0.086 Uiso 1 1 calc R
H19B H 0.3190 0.0576 0.4689 0.086 Uiso 1 1 calc R
C20 C 0.2126(7) 0.1072(8) 0.4665(5) 0.067(2) Uani 1 1 d .
H20A H 0.2483 0.1514 0.4835 0.081 Uiso 1 1 calc R
C21 C 0.1553(7) -0.0160(8) 0.4256(5) 0.067(2) Uani 1 1 d .
H21A H 0.1466 -0.0706 0.4113 0.081 Uiso 1 1 calc R
C22 C 0.1069(7) 0.0286(7) 0.4299(5) 0.067(2) Uani 1 1 d .
H22A H 0.0590 0.0116 0.4172 0.081 Uiso 1 1 calc R
C23 C 0.1214(6) 0.1644(8) 0.4736(5) 0.061(3) Uani 1 1 d .
C24 C 0.0706(7) 0.1448(7) 0.4780(5) 0.066(3) Uani 1 1 d .
H24A H 0.0499 0.0898 0.4714 0.079 Uiso 1 1 calc R
C25 C 0.0493(7) 0.2170(9) 0.4940(5) 0.079(4) Uani 1 1 d .
H25A H 0.0140 0.2081 0.4983 0.094 Uiso 1 1 calc R
C26 C 0.0808(7) 0.2983(9) 0.5030(5) 0.074(4) Uani 1 1 d .
H26A H 0.0672 0.3444 0.5131 0.089 Uiso 1 1 calc R
C27 C 0.1336(6) 0.3080(7) 0.4964(4) 0.052(3) Uani 1 1 d .
C28 C 0.2215(5) 0.3978(7) 0.4993(4) 0.051(3) Uani 1 1 d .
H28A H 0.2435 0.3543 0.4940 0.061 Uiso 1 1 calc R
C29 C 0.1526(7) 0.4702(7) 0.5130(5) 0.061(3) Uani 1 1 d .
H29A H 0.1194 0.4826 0.5188 0.073 Uiso 1 1 calc R
C30 C 0.1936(6) 0.5221(8) 0.5126(4) 0.060(3) Uani 1 1 d .
H30A H 0.1936 0.5814 0.5172 0.071 Uiso 1 1 calc R
C31 C 0.2900(6) 0.5195(7) 0.4977(5) 0.062(3) Uani 1 1 d .
H31A H 0.2997 0.5799 0.5078 0.074 Uiso 1 1 calc R
H31B H 0.3380 0.4890 0.5202 0.074 Uiso 1 1 calc R
C32 C 0.2604(7) 0.5127(6) 0.4459(5) 0.055(3) Uani 1 1 d .
C33 C 0.3045(8) 0.4808(7) 0.4335(6) 0.070(4) Uani 1 1 d .
H33A H 0.3537 0.4621 0.4599 0.083 Uiso 1 1 calc R
C34 C 0.2763(7) 0.4769(7) 0.3838(6) 0.068(4) Uani 1 1 d .
H34A H 0.3076 0.4558 0.3780 0.081 Uiso 1 1 calc R
C35 C 0.2018(6) 0.5033(7) 0.3403(6) 0.074(4) Uani 1 1 d .
C36 C 0.1594(7) 0.5363(8) 0.3541(6) 0.075(4) Uani 1 1 d .
H36A H 0.1109 0.5567 0.3274 0.090 Uiso 1 1 calc R
C37 C 0.1832(7) 0.5402(7) 0.4014(5) 0.065(3) Uani 1 1 d .
H37A H 0.1509 0.5606 0.4065 0.078 Uiso 1 1 calc R
C38 C 0.1691(6) 0.4975(7) 0.2868(5) 0.056(3) Uani 1 1 d .
H38A H 0.1372 0.5477 0.2683 0.067 Uiso 1 1 calc R
H38B H 0.1372 0.4465 0.2714 0.067 Uiso 1 1 calc R
C39 C 0.3430(5) 0.2656(5) 0.4777(4) 0.040(2) Uani 1 1 d .
C40 C 0.2865(6) 0.2627(6) 0.4223(4) 0.046(3) Uani 1 1 d .
C41 C 0.2077(6) 0.2688(6) 0.3959(5) 0.056(3) Uani 1 1 d .
H41A H 0.1909 0.2738 0.4142 0.067 Uiso 1 1 calc R
C42 C 0.3098(6) 0.2521(5) 0.3937(5) 0.052(3) Uani 1 1 d .
H42A H 0.3611 0.2465 0.4106 0.062 Uiso 1 1 calc R
C43 C 0.4756(6) 0.0377(7) 0.5732(6) 0.063(4) Uani 1 1 d .
C44 C 0.4861(7) 0.0178(7) 0.5339(5) 0.068(2) Uani 1 1 d .
C45 C 0.4968(7) -0.0635(7) 0.5253(5) 0.068(2) Uani 1 1 d .
H45A H 0.4952 -0.1087 0.5427 0.082 Uiso 1 1 calc R
C46 C 0.4901(7) 0.0830(7) 0.5075(5) 0.068(2) Uani 1 1 d .
H46A H 0.4839 0.1404 0.5122 0.082 Uiso 1 1 calc R
C47 C 0.4986(6) 0.4773(7) 0.5846(5) 0.053(3) Uani 1 1 d .
C48 C 0.5004(5) 0.4906(5) 0.5413(4) 0.042(3) Uani 1 1 d .
C49 C 0.4867(5) 0.5704(7) 0.5192(4) 0.047(3) Uani 1 1 d .
H49A H 0.4793 0.6177 0.5324 0.056 Uiso 1 1 calc R
C50 C 0.5163(5) 0.4186(6) 0.5223(4) 0.048(3) Uani 1 1 d .
H50A H 0.5286 0.3648 0.5382 0.057 Uiso 1 1 calc R
C51 C 0.6401(6) 0.2342(7) 0.6400(5) 0.056(3) Uani 1 1 d .
C52 C 0.6904(6) 0.2369(7) 0.6262(5) 0.052(3) Uani 1 1 d .
C53 C 0.7695(5) 0.2370(8) 0.6651(5) 0.066(4) Uani 1 1 d .
H53A H 0.7913 0.2360 0.6996 0.079 Uiso 1 1 calc R
C54 C 0.8147(6) 0.2384(8) 0.6524(5) 0.063(3) Uani 1 1 d .
H54A H 0.8670 0.2358 0.6784 0.076 Uiso 1 1 calc R
C55 C 0.7836(6) 0.2437(7) 0.6018(5) 0.063(3) Uani 1 1 d .
C56 C 0.7024(5) 0.2446(6) 0.5621(5) 0.052(3) Uani 1 1 d .
H56A H 0.6809 0.2470 0.5276 0.062 Uiso 1 1 calc R
C57 C 0.6570(6) 0.2419(6) 0.5739(5) 0.053(3) Uani 1 1 d .
H57A H 0.6046 0.2433 0.5480 0.064 Uiso 1 1 calc R
C58 C 0.8344(7) 0.2492(8) 0.5898(6) 0.071(4) Uani 1 1 d .
C59 C 0.3604(6) 0.2673(7) 0.6130(4) 0.048(3) Uani 1 1 d .
C60 C 0.3025(5) 0.2708(6) 0.6190(4) 0.044(2) Uani 1 1 d .
C61 C 0.2796(5) 0.3460(6) 0.6275(4) 0.036(2) Uani 1 1 d .
H61A H 0.3012 0.3984 0.6296 0.043 Uiso 1 1 calc R
C62 C 0.2280(6) 0.3455(6) 0.6329(4) 0.044(3) Uani 1 1 d .
H62A H 0.2148 0.3981 0.6385 0.052 Uiso 1 1 calc R
C63 C 0.1927(5) 0.2718(6) 0.6308(4) 0.042(2) Uani 1 1 d .
C64 C 0.2139(5) 0.1944(6) 0.6227(4) 0.043(3) Uani 1 1 d .
H64A H 0.1912 0.1431 0.6206 0.052 Uiso 1 1 calc R
C65 C 0.2687(6) 0.1929(6) 0.6177(4) 0.051(3) Uani 1 1 d .
H65A H 0.2836 0.1402 0.6136 0.061 Uiso 1 1 calc R
C66 C 0.1300(5) 0.2739(7) 0.6334(4) 0.050(3) Uani 1 1 d .
C67 C 0.1219(6) 0.2550(6) 0.2550(4) 0.045(3) Uani 1 1 d .
C68 C 0.1795(6) 0.2593(6) 0.3139(5) 0.049(3) Uani 1 1 d .
C69 C 0.1555(6) 0.2673(6) 0.3414(5) 0.053(3) Uani 1 1 d .
H69A H 0.1040 0.2717 0.3238 0.063 Uiso 1 1 calc R
C70 C 0.2560(6) 0.2498(6) 0.3391(5) 0.052(3) Uani 1 1 d .
H70A H 0.2718 0.2420 0.3203 0.062 Uiso 1 1 calc R
C71 C -0.0009(7) 0.0577(8) 0.1433(6) 0.0668(16) Uani 1 1 d .
C72 C 0.0113(6) -0.0402(7) 0.1466(5) 0.058(3) Uani 1 1 d .
C73 C 0.0215(9) -0.0831(10) 0.1874(6) 0.093(5) Uani 1 1 d .
H73A H 0.0174 -0.0532 0.2092 0.111 Uiso 1 1 calc R
C74 C 0.0379(8) -0.1714(9) 0.1942(6) 0.093(5) Uani 1 1 d .
H74A H 0.0403 -0.2002 0.2192 0.111 Uiso 1 1 calc R
C75 C 0.0507(7) -0.2183(8) 0.1662(5) 0.065(4) Uani 1 1 d .
C76 C 0.0386(7) -0.1710(10) 0.1276(5) 0.080(4) Uani 1 1 d .
H76A H 0.0427 -0.2004 0.1056 0.096 Uiso 1 1 calc R
C77 C 0.0207(8) -0.0828(9) 0.1175(5) 0.076(4) Uani 1 1 d .
H77A H 0.0157 -0.0552 0.0912 0.091 Uiso 1 1 calc R
C78 C 0.0715(8) -0.3070(10) 0.1747(7) 0.087(5) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O3 Eu1 O5 156.4(3) . .
O3 Eu1 O7 77.9(2) . .
O5 Eu1 O7 82.6(3) . .
O3 Eu1 O1 80.3(2) . .
O5 Eu1 O1 82.9(2) . .
O7 Eu1 O1 78.8(3) . .
O3 Eu1 O1W 99.4(3) . .
O5 Eu1 O1W 88.4(3) . .
O7 Eu1 O1W 75.3(3) . .
O1 Eu1 O1W 153.5(2) . .
O3 Eu1 O12 76.0(2) . .
O5 Eu1 O12 127.5(2) . .
O7 Eu1 O12 140.3(2) . .
O1 Eu1 O12 124.7(2) . .
O1W Eu1 O12 80.1(2) . .
O3 Eu1 O2 85.0(3) . .
O5 Eu1 O2 98.0(2) . .
O7 Eu1 O2 131.0(3) . .
O1 Eu1 O2 53.0(2) . .
O1W Eu1 O2 153.4(2) . .
O12 Eu1 O2 75.5(2) . .
O3 Eu1 O11 126.5(2) . .
O5 Eu1 O11 76.5(2) . .
O7 Eu1 O11 149.3(3) . .
O1 Eu1 O11 119.9(2) . .
O1W Eu1 O11 81.7(2) . .
O12 Eu1 O11 51.3(2) . .
O2 Eu1 O11 74.8(2) . .
O3 Eu1 C39 81.3(3) . .
O5 Eu1 C39 90.8(3) . .
O7 Eu1 C39 104.6(3) . .
O1 Eu1 C39 26.2(2) . .
O1W Eu1 C39 179.2(3) . .
O12 Eu1 C39 100.4(3) . .
O2 Eu1 C39 26.8(2) . .
O11 Eu1 C39 98.1(3) . .
O3 Eu1 C59 101.5(3) . .
O5 Eu1 C59 101.8(3) . .
O7 Eu1 C59 155.1(3) . .
O1 Eu1 C59 125.9(3) . .
O1W Eu1 C59 80.3(3) . .
O12 Eu1 C59 25.9(2) . .
O2 Eu1 C59 73.1(3) . .
O11 Eu1 C59 25.4(2) . .
C39 Eu1 C59 99.9(3) . .
O9 Eu2 O17 86.1(3) 4_465 .
O9 Eu2 O2W 79.6(3) 4_465 .
O17 Eu2 O2W 143.7(3) . .
O9 Eu2 O14 141.2(3) 4_465 4_565
O17 Eu2 O14 131.4(2) . 4_565
O2W Eu2 O14 73.8(3) . 4_565
O9 Eu2 O3W 74.9(3) 4_465 .
O17 Eu2 O3W 124.0(3) . .
O2W Eu2 O3W 84.2(3) . .
O14 Eu2 O3W 74.7(2) 4_565 .
O9 Eu2 O16 126.5(3) 4_465 .
O17 Eu2 O16 80.5(2) . .
O2W Eu2 O16 81.7(2) . .
O14 Eu2 O16 77.1(2) 4_565 .
O3W Eu2 O16 151.1(2) . .
O9 Eu2 O13 155.2(3) 4_465 4_565
O17 Eu2 O13 80.9(3) . 4_565
O2W Eu2 O13 122.6(2) . 4_565
O14 Eu2 O13 51.3(2) 4_565 4_565
O3W Eu2 O13 95.1(2) . 4_565
O16 Eu2 O13 72.0(2) . 4_565
O9 Eu2 O18 84.7(3) 4_465 .
O17 Eu2 O18 52.1(3) . .
O2W Eu2 O18 155.7(3) . .
O14 Eu2 O18 109.0(3) 4_565 .
O3W Eu2 O18 73.7(2) . .
O16 Eu2 O18 122.7(2) . .
O13 Eu2 O18 70.6(2) 4_565 .
O9 Eu2 O15 74.5(3) 4_465 .
O17 Eu2 O15 69.7(3) . .
O2W Eu2 O15 74.4(3) . .
O14 Eu2 O15 122.9(2) 4_565 .
O3W Eu2 O15 145.2(2) . .
O16 Eu2 O15 52.2(2) . .
O13 Eu2 O15 119.5(2) 4_565 .
O18 Eu2 O15 119.2(3) . .
O9 Eu2 C71 87.3(3) 4_465 .
O17 Eu2 C71 25.9(3) . .
O2W Eu2 C71 164.9(3) . .
O14 Eu2 C71 121.3(3) 4_565 .
O3W Eu2 C71 99.8(3) . .
O16 Eu2 C71 100.4(3) . .
O13 Eu2 C71 71.9(3) 4_565 .
O18 Eu2 C71 26.4(3) . .
O15 Eu2 C71 94.9(4) . .
O9 Eu2 C66 160.4(3) 4_465 4_565
O17 Eu2 C66 105.3(3) . 4_565
O2W Eu2 C66 98.8(3) . 4_565
O14 Eu2 C66 26.5(2) 4_565 4_565
O3W Eu2 C66 85.6(3) . 4_565
O16 Eu2 C66 71.9(3) . 4_565
O13 Eu2 C66 24.8(2) 4_565 4_565
O18 Eu2 C66 89.8(3) . 4_565
O15 Eu2 C66 124.1(3) . 4_565
C71 Eu2 C66 96.1(4) . 4_565
O9 Eu2 C67 100.8(3) 4_465 .
O17 Eu2 C67 72.2(3) . .
O2W Eu2 C67 77.9(3) . .
O14 Eu2 C67 100.7(3) 4_565 .
O3W Eu2 C67 162.1(3) . .
O16 Eu2 C67 26.0(2) . .
O13 Eu2 C67 95.2(3) 4_565 .
O18 Eu2 C67 123.7(3) . .
O15 Eu2 C67 26.3(2) . .
C71 Eu2 C67 97.3(4) . .
C66 Eu2 C67 97.9(3) 4_565 .
C39 O1 Eu1 95.5(6) . .
C39 O2 Eu1 92.9(5) . .
C43 O3 Eu1 155.2(7) . .
C47 O5 Eu1 169.8(8) . .
C51 O7 Eu1 141.4(8) . .
C58 O9 Eu2 142.8(9) . 4_666
C59 O11 Eu1 93.2(6) . .
C59 O12 Eu1 95.4(6) . .
C66 O13 Eu2 92.6(6) . 4_566
C66 O14 Eu2 93.6(6) . 4_566
C67 O15 Eu2 90.4(7) . .
C67 O16 Eu2 94.0(6) . .
C71 O17 Eu2 93.5(8) . .
C71 O18 Eu2 87.6(8) . .
C1 N1 C2 108.3(10) . .
C1 N1 C38 125.6(9) . .
C2 N1 C38 125.9(9) . .
C1 N2 C4 124.4(10) . .
C1 N2 C3 108.7(10) . .
C4 N2 C3 126.8(9) . .
C8 N3 C4 116.8(10) . .
C9 N4 C10 111.7(11) . .
C9 N4 C8 124.7(9) . .
C10 N4 C8 123.5(11) . .
C9 N5 C11 108.5(9) . .
C9 N5 C12 124.3(8) . .
C11 N5 C12 127.1(10) . .
C20 N6 C21 108.2(11) . .
C20 N6 C19 125.7(10) . .
C21 N6 C19 126.1(10) . .
C20 N7 C23 126.5(10) . .
C20 N7 C22 108.8(10) . .
C23 N7 C22 124.6(10) . .
C27 N8 C23 116.9(10) . .
C28 N9 C27 123.7(9) . .
C28 N9 C29 108.5(9) . .
C27 N9 C29 127.8(9) . .
C30 N10 C28 106.3(9) . .
C30 N10 C31 131.9(10) . .
C28 N10 C31 121.5(9) . .
N2 C1 N1 107.9(10) . .
N2 C1 H1A 126.0 . .
N1 C1 H1A 126.0 . .
C3 C2 N1 107.3(11) . .
C3 C2 H2A 126.4 . .
N1 C2 H2A 126.4 . .
C2 C3 N2 107.8(10) . .
C2 C3 H3A 126.1 . .
N2 C3 H3A 126.1 . .
N3 C4 C5 122.8(11) . .
N3 C4 N2 112.8(10) . .
C5 C4 N2 124.4(10) . .
C4 C5 C6 121.6(12) . .
C4 C5 H5A 119.2 . .
C6 C5 H5A 119.2 . .
C5 C6 C7 118.3(11) . .
C5 C6 H6A 120.9 . .
C7 C6 H6A 120.9 . .
C8 C7 C6 113.8(10) . .
C8 C7 H7A 123.1 . .
C6 C7 H7A 123.1 . .
N3 C8 C7 126.7(11) . .
N3 C8 N4 114.4(10) . .
C7 C8 N4 118.9(10) . .
N4 C9 N5 109.6(9) . .
N4 C9 H9A 125.2 . .
N5 C9 H9A 125.2 . .
N4 C10 C11 101.0(11) . .
N4 C10 H10A 129.5 . .
C11 C10 H10A 129.5 . .
N5 C11 C10 109.1(11) . .
N5 C11 H11A 125.4 . .
C10 C11 H11A 125.4 . .
N5 C12 C13 111.9(9) . .
N5 C12 H12A 109.2 . .
C13 C12 H12A 109.2 . .
N5 C12 H12B 109.2 . .
C13 C12 H12B 109.2 . .
H12A C12 H12B 107.9 . .
C18 C13 C14 116.2(11) . .
C18 C13 C12 121.9(11) . .
C14 C13 C12 121.8(9) . .
C15 C14 C13 121.8(11) . .
C15 C14 H14A 119.1 . .
C13 C14 H14A 119.1 . .
C14 C15 C16 118.3(12) . .
C14 C15 H15A 120.9 . .
C16 C15 H15A 120.9 . .
C15 C16 C17 122.4(13) . .
C15 C16 C19 115.8(13) . .
C17 C16 C19 121.7(12) . .
C18 C17 C16 117.9(13) . .
C18 C17 H17A 121.1 . .
C16 C17 H17A 121.1 . .
C13 C18 C17 123.4(13) . .
C13 C18 H18A 118.3 . .
C17 C18 H18A 118.3 . .
N6 C19 C16 116.9(11) . .
N6 C19 H19A 108.1 . .
C16 C19 H19A 108.1 . .
N6 C19 H19B 108.1 . .
C16 C19 H19B 108.1 . .
H19A C19 H19B 107.3 . .
N6 C20 N7 109.1(11) . .
N6 C20 H20A 125.4 . .
N7 C20 H20A 125.4 . .
N6 C21 C22 108.4(10) . .
N6 C21 H21A 125.8 . .
C22 C21 H21A 125.8 . .
C21 C22 N7 105.3(11) . .
C21 C22 H22A 127.4 . .
N7 C22 H22A 127.4 . .
C24 C23 N8 127.5(12) . .
C24 C23 N7 121.9(11) . .
N8 C23 N7 110.5(11) . .
C23 C24 C25 114.3(11) . .
C23 C24 H24A 122.8 . .
C25 C24 H24A 122.8 . .
C26 C25 C24 121.3(12) . .
C26 C25 H25A 119.4 . .
C24 C25 H25A 119.4 . .
C25 C26 C27 117.1(12) . .
C25 C26 H26A 121.5 . .
C27 C26 H26A 121.5 . .
N8 C27 C26 123.0(11) . .
N8 C27 N9 114.2(10) . .
C26 C27 N9 122.7(11) . .
N9 C28 N10 106.9(8) . .
N9 C28 H28A 126.6 . .
N10 C28 H28A 126.6 . .
C30 C29 N9 104.8(11) . .
C30 C29 H29A 127.6 . .
N9 C29 H29A 127.6 . .
C29 C30 N10 113.4(11) . .
C29 C30 H30A 123.3 . .
N10 C30 H30A 123.3 . .
C32 C31 N10 112.8(9) . .
C32 C31 H31A 109.0 . .
N10 C31 H31A 109.0 . .
C32 C31 H31B 109.0 . .
N10 C31 H31B 109.0 . .
H31A C31 H31B 107.8 . .
C31 C32 C33 122.2(12) . .
C31 C32 C37 122.9(11) . .
C33 C32 C37 114.9(12) . .
C34 C33 C32 121.6(13) . .
C34 C33 H33A 119.2 . .
C32 C33 H33A 119.2 . .
C33 C34 C35 124.1(13) . .
C33 C34 H34A 117.9 . .
C35 C34 H34A 117.9 . .
C34 C35 C36 112.9(14) . .
C34 C35 C38 125.5(13) . .
C36 C35 C38 121.6(11) . .
C37 C36 C35 125.6(13) . .
C37 C36 H36A 117.2 . .
C35 C36 H36A 117.2 . .
C36 C37 C32 120.7(12) . .
C36 C37 H37A 119.7 . .
C32 C37 H37A 119.7 . .
C35 C38 N1 113.8(10) . .
C35 C38 H38A 108.8 . .
N1 C38 H38A 108.8 . .
C35 C38 H38B 108.8 . .
N1 C38 H38B 108.8 . .
H38A C38 H38B 107.7 . .
O1 C39 O2 118.5(9) . .
O1 C39 C40 121.5(10) . .
O2 C39 C40 119.9(9) . .
O1 C39 Eu1 58.3(5) . .
O2 C39 Eu1 60.3(5) . .
C40 C39 Eu1 175.8(6) . .
C42 C40 C41 119.2(11) . .
C42 C40 C39 118.9(9) . .
C41 C40 C39 122.0(10) . .
C69 C41 C40 118.9(10) . .
C69 C41 H41A 120.6 . .
C40 C41 H41A 120.6 . .
C40 C42 C70 120.5(10) . .
C40 C42 H42A 119.7 . .
C70 C42 H42A 119.7 . .
O4 C43 O3 125.5(12) . .
O4 C43 C44 118.5(9) . .
O3 C43 C44 115.7(12) . .
C45 C44 C46 115.8(11) . .
C45 C44 C43 122.0(11) . .
C46 C44 C43 122.1(10) . .
C44 C45 C46 123.5(12) . 3_656
C44 C45 H45A 118.3 . .
C46 C45 H45A 118.3 3_656 .
C45 C46 C44 120.7(11) 3_656 .
C45 C46 H46A 119.6 3_656 .
C44 C46 H46A 119.6 . .
O6 C47 O5 123.9(11) . .
O6 C47 C48 119.5(9) . .
O5 C47 C48 116.4(10) . .
C49 C48 C50 118.8(10) . .
C49 C48 C47 120.9(9) . .
C50 C48 C47 120.3(8) . .
C48 C49 C50 120.9(9) . 3_666
C48 C49 H49A 119.6 . .
C50 C49 H49A 119.6 3_666 .
C49 C50 C48 120.2(9) 3_666 .
C49 C50 H50A 119.9 3_666 .
C48 C50 H50A 119.9 . .
O7 C51 O8 122.6(10) . .
O7 C51 C52 117.5(12) . .
O8 C51 C52 119.9(10) . .
C53 C52 C57 120.2(10) . .
C53 C52 C51 120.3(11) . .
C57 C52 C51 119.5(10) . .
C54 C53 C52 120.1(12) . .
C54 C53 H53A 119.9 . .
C52 C53 H53A 119.9 . .
C53 C54 C55 120.7(11) . .
C53 C54 H54A 119.6 . .
C55 C54 H54A 119.6 . .
C54 C55 C56 118.9(10) . .
C54 C55 C58 119.1(11) . .
C56 C55 C58 122.0(12) . .
C57 C56 C55 121.1(11) . .
C57 C56 H56A 119.4 . .
C55 C56 H56A 119.4 . .
C56 C57 C52 118.9(10) . .
C56 C57 H57A 120.5 . .
C52 C57 H57A 120.5 . .
O9 C58 O10 124.6(12) . .
O9 C58 C55 118.3(13) . .
O10 C58 C55 117.1(11) . .
O11 C59 O12 120.1(9) . .
O11 C59 C60 119.2(9) . .
O12 C59 C60 120.3(9) . .
O11 C59 Eu1 61.5(5) . .
O12 C59 Eu1 58.7(5) . .
C60 C59 Eu1 172.2(7) . .
C61 C60 C65 116.0(9) . .
C61 C60 C59 124.3(9) . .
C65 C60 C59 119.7(9) . .
C62 C61 C60 121.9(9) . .
C62 C61 H61A 119.0 . .
C60 C61 H61A 119.0 . .
C61 C62 C63 123.8(9) . .
C61 C62 H62A 118.1 . .
C63 C62 H62A 118.1 . .
C62 C63 C64 116.8(9) . .
C62 C63 C66 122.6(9) . .
C64 C63 C66 120.5(9) . .
C65 C64 C63 120.6(9) . .
C65 C64 H64A 119.7 . .
C63 C64 H64A 119.7 . .
C64 C65 C60 120.8(9) . .
C64 C65 H65A 119.6 . .
C60 C65 H65A 119.6 . .
O13 C66 O14 122.4(10) . .
O13 C66 C63 120.6(10) . .
O14 C66 C63 117.0(9) . .
O13 C66 Eu2 62.6(6) . 4_566
O14 C66 Eu2 59.9(5) . 4_566
C63 C66 Eu2 174.4(8) . 4_566
O16 C67 O15 123.1(11) . .
O16 C67 C68 117.3(8) . .
O15 C67 C68 119.6(10) . .
O16 C67 Eu2 60.0(5) . .
O15 C67 Eu2 63.3(6) . .
C68 C67 Eu2 175.4(7) . .
C69 C68 C70 120.6(11) . .
C69 C68 C67 120.1(9) . .
C70 C68 C67 119.2(10) . .
C68 C69 C41 121.1(10) . .
C68 C69 H69A 119.4 . .
C41 C69 H69A 119.4 . .
C68 C70 C42 119.7(10) . .
C68 C70 H70A 120.2 . .
C42 C70 H70A 120.2 . .
O17 C71 O18 125.9(12) . .
O17 C71 C72 118.1(12) . .
O18 C71 C72 115.5(13) . .
O17 C71 Eu2 60.7(6) . .
O18 C71 Eu2 66.0(6) . .
C72 C71 Eu2 162.5(8) . .
C77 C72 C73 120.0(12) . .
C77 C72 C71 123.4(12) . .
C73 C72 C71 116.2(13) . .
C74 C73 C72 118.5(13) . .
C74 C73 H73A 120.8 . .
C72 C73 H73A 120.8 . .
C75 C74 C73 123.9(12) . .
C75 C74 H74A 118.0 . .
C73 C74 H74A 118.0 . .
C76 C75 C74 112.6(12) . .
C76 C75 C78 122.9(15) . .
C74 C75 C78 124.4(13) . .
C75 C76 C77 126.9(13) . .
C75 C76 H76A 116.6 . .
C77 C76 H76A 116.6 . .
C72 C77 C76 117.9(13) . .
C72 C77 H77A 121.0 . .
C76 C77 H77A 121.0 . .
O19 C78 O20 118.0(15) . .
O19 C78 C75 121.5(17) . .
O20 C78 C75 120.0(14) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O3 2.305(6) .
Eu1 O5 2.314(7) .
Eu1 O7 2.361(6) .
Eu1 O1 2.428(7) .
Eu1 O1W 2.449(7) .
Eu1 O12 2.451(7) .
Eu1 O2 2.469(7) .
Eu1 O11 2.512(7) .
Eu1 C39 2.840(10) .
Eu1 C59 2.855(10) .
Eu2 O9 2.350(7) 4_465
Eu2 O17 2.425(7) .
Eu2 O2W 2.454(7) .
Eu2 O14 2.460(7) 4_565
Eu2 O3W 2.463(8) .
Eu2 O16 2.473(6) .
Eu2 O13 2.521(6) 4_565
Eu2 O18 2.538(8) .
Eu2 O15 2.546(8) .
Eu2 C71 2.776(12) .
Eu2 C66 2.837(10) 4_565
Eu2 C67 2.849(11) .
O1 C39 1.260(11) .
O2 C39 1.284(12) .
O3 C43 1.281(11) .
O4 C43 1.208(14) .
O5 C47 1.253(12) .
O6 C47 1.237(12) .
O7 C51 1.254(13) .
O8 C51 1.269(14) .
O9 C58 1.229(13) .
O9 Eu2 2.350(7) 4_666
O10 C58 1.305(15) .
O11 C59 1.225(11) .
O12 C59 1.253(11) .
O13 C66 1.193(11) .
O13 Eu2 2.521(6) 4_566
O14 C66 1.267(12) .
O14 Eu2 2.460(6) 4_566
O15 C67 1.262(11) .
O16 C67 1.252(11) .
O17 C71 1.213(15) .
O18 C71 1.237(14) .
O19 C78 1.206(16) .
O20 C78 1.288(18) .
N1 C1 1.342(14) .
N1 C2 1.409(13) .
N1 C38 1.482(13) .
N2 C1 1.321(13) .
N2 C4 1.408(14) .
N2 C3 1.409(15) .
N3 C8 1.299(13) .
N3 C4 1.312(12) .
N4 C9 1.298(12) .
N4 C10 1.398(14) .
N4 C8 1.472(14) .
N5 C9 1.315(12) .
N5 C11 1.345(12) .
N5 C12 1.450(13) .
N6 C20 1.354(14) .
N6 C21 1.386(14) .
N6 C19 1.429(14) .
N7 C20 1.363(14) .
N7 C23 1.376(14) .
N7 C22 1.409(13) .
N8 C27 1.351(13) .
N8 C23 1.357(13) .
N9 C28 1.330(12) .
N9 C27 1.410(13) .
N9 C29 1.425(13) .
N10 C30 1.353(13) .
N10 C28 1.357(13) .
N10 C31 1.489(13) .
C1 H1A 0.9300 .
C2 C3 1.306(15) .
C2 H2A 0.9300 .
C3 H3A 0.9300 .
C4 C5 1.341(15) .
C5 C6 1.354(16) .
C5 H5A 0.9300 .
C6 C7 1.416(16) .
C6 H6A 0.9300 .
C7 C8 1.406(14) .
C7 H7A 0.9300 .
C9 H9A 0.9300 .
C10 C11 1.426(18) .
C10 H10A 0.9300 .
C11 H11A 0.9300 .
C12 C13 1.494(15) .
C12 H12A 0.9700 .
C12 H12B 0.9700 .
C13 C18 1.360(15) .
C13 C14 1.427(15) .
C14 C15 1.357(14) .
C14 H14A 0.9300 .
C15 C16 1.363(15) .
C15 H15A 0.9300 .
C16 C17 1.378(17) .
C16 C19 1.570(17) .
C17 C18 1.361(16) .
C17 H17A 0.9300 .
C18 H18A 0.9300 .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 H20A 0.9300 .
C21 C22 1.402(16) .
C21 H21A 0.9300 .
C22 H22A 0.9300 .
C23 C24 1.317(15) .
C24 C25 1.460(17) .
C24 H24A 0.9300 .
C25 C26 1.384(17) .
C25 H25A 0.9300 .
C26 C27 1.389(15) .
C26 H26A 0.9300 .
C28 H28A 0.9300 .
C29 C30 1.251(15) .
C29 H29A 0.9300 .
C30 H30A 0.9300 .
C31 C32 1.422(16) .
C31 H31A 0.9700 .
C31 H31B 0.9700 .
C32 C33 1.423(15) .
C32 C37 1.472(16) .
C33 C34 1.362(17) .
C33 H33A 0.9300 .
C34 C35 1.423(17) .
C34 H34A 0.9300 .
C35 C36 1.429(17) .
C35 C38 1.453(18) .
C36 C37 1.322(17) .
C36 H36A 0.9300 .
C37 H37A 0.9300 .
C38 H38A 0.9700 .
C38 H38B 0.9700 .
C39 C40 1.439(14) .
C40 C42 1.395(14) .
C40 C41 1.424(13) .
C41 C69 1.413(15) .
C41 H41A 0.9300 .
C42 C70 1.414(15) .
C42 H42A 0.9300 .
C43 C44 1.536(17) .
C44 C45 1.349(15) .
C44 C46 1.394(16) .
C45 C46 1.367(15) 3_656
C45 H45A 0.9300 .
C46 C45 1.367(15) 3_656
C46 H46A 0.9300 .
C47 C48 1.516(15) .
C48 C49 1.369(13) .
C48 C50 1.451(13) .
C49 C50 1.379(14) 3_666
C49 H49A 0.9300 .
C50 C49 1.379(14) 3_666
C50 H50A 0.9300 .
C51 C52 1.516(14) .
C52 C53 1.404(14) .
C52 C57 1.409(15) .
C53 C54 1.368(14) .
C53 H53A 0.9300 .
C54 C55 1.372(16) .
C54 H54A 0.9300 .
C55 C56 1.439(14) .
C55 C58 1.482(16) .
C56 C57 1.350(13) .
C56 H56A 0.9300 .
C57 H57A 0.9300 .
C59 C60 1.484(13) .
C60 C61 1.384(12) .
C60 C65 1.423(13) .
C61 C62 1.324(12) .
C61 H61A 0.9300 .
C62 C63 1.376(13) .
C62 H62A 0.9300 .
C63 C64 1.387(13) .
C63 C66 1.516(13) .
C64 C65 1.386(13) .
C64 H64A 0.9300 .
C65 H65A 0.9300 .
C66 Eu2 2.837(10) 4_566
C67 C68 1.527(15) .
C68 C69 1.371(14) .
C68 C70 1.389(14) .
C69 H69A 0.9300 .
C70 H70A 0.9300 .
C71 C72 1.530(16) .
C72 C77 1.321(16) .
C72 C73 1.413(17) .
C73 C74 1.394(17) .
C73 H73A 0.9300 .
C74 C75 1.375(18) .
C74 H74A 0.9300 .
C75 C76 1.366(16) .
C75 C78 1.420(18) .
C76 C77 1.400(17) .
C76 H76A 0.9300 .
C77 H77A 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O3 Eu1 O1 C39 90.0(5) . .
O5 Eu1 O1 C39 -106.7(5) . .
O7 Eu1 O1 C39 169.5(5) . .
O1W Eu1 O1 C39 -178.4(5) . .
O12 Eu1 O1 C39 24.6(6) . .
O2 Eu1 O1 C39 -1.0(5) . .
O11 Eu1 O1 C39 -36.7(6) . .
C59 Eu1 O1 C39 -7.2(6) . .
O3 Eu1 O2 C39 -80.6(5) . .
O5 Eu1 O2 C39 75.8(5) . .
O7 Eu1 O2 C39 -11.4(6) . .
O1 Eu1 O2 C39 1.0(5) . .
O1W Eu1 O2 C39 178.4(5) . .
O12 Eu1 O2 C39 -157.4(5) . .
O11 Eu1 O2 C39 149.4(5) . .
C59 Eu1 O2 C39 175.7(6) . .
O5 Eu1 O3 C43 61(2) . .
O7 Eu1 O3 C43 26(2) . .
O1 Eu1 O3 C43 106(2) . .
O1W Eu1 O3 C43 -47(2) . .
O12 Eu1 O3 C43 -124(2) . .
O2 Eu1 O3 C43 160(2) . .
O11 Eu1 O3 C43 -133(2) . .
C39 Eu1 O3 C43 133(2) . .
C59 Eu1 O3 C43 -129(2) . .
O3 Eu1 O5 C47 37(4) . .
O7 Eu1 O5 C47 72(4) . .
O1 Eu1 O5 C47 -8(4) . .
O1W Eu1 O5 C47 147(4) . .
O12 Eu1 O5 C47 -136(4) . .
O2 Eu1 O5 C47 -59(4) . .
O11 Eu1 O5 C47 -131(4) . .
C39 Eu1 O5 C47 -33(4) . .
C59 Eu1 O5 C47 -133(4) . .
O3 Eu1 O7 C51 -112.1(12) . .
O5 Eu1 O7 C51 81.4(12) . .
O1 Eu1 O7 C51 165.5(12) . .
O1W Eu1 O7 C51 -8.9(11) . .
O12 Eu1 O7 C51 -62.3(13) . .
O2 Eu1 O7 C51 175.6(11) . .
O11 Eu1 O7 C51 34.0(14) . .
C39 Eu1 O7 C51 170.3(11) . .
C59 Eu1 O7 C51 -20.8(15) . .
O3 Eu1 O11 C59 10.8(8) . .
O5 Eu1 O11 C59 -175.2(7) . .
O7 Eu1 O11 C59 -126.5(7) . .
O1 Eu1 O11 C59 111.4(6) . .
O1W Eu1 O11 C59 -84.8(7) . .
O12 Eu1 O11 C59 -1.0(6) . .
O2 Eu1 O11 C59 82.5(7) . .
C39 Eu1 O11 C59 95.9(7) . .
O3 Eu1 O12 C59 -169.4(7) . .
O5 Eu1 O12 C59 8.0(7) . .
O7 Eu1 O12 C59 140.3(6) . .
O1 Eu1 O12 C59 -101.9(6) . .
O1W Eu1 O12 C59 88.3(6) . .
O2 Eu1 O12 C59 -81.0(6) . .
O11 Eu1 O12 C59 0.9(6) . .
C39 Eu1 O12 C59 -91.1(6) . .
O9 Eu2 O15 C67 -177.6(6) 4_465 .
O17 Eu2 O15 C67 90.9(6) . .
O2W Eu2 O15 C67 -94.3(6) . .
O14 Eu2 O15 C67 -36.0(7) 4_565 .
O3W Eu2 O15 C67 -148.4(5) . .
O16 Eu2 O15 C67 -2.8(5) . .
O13 Eu2 O15 C67 24.6(6) 4_565 .
O18 Eu2 O15 C67 107.7(6) . .
C71 Eu2 O15 C67 96.6(6) . .
C66 Eu2 O15 C67 -4.2(7) 4_565 .
O9 Eu2 O16 C67 9.1(7) 4_465 .
O17 Eu2 O16 C67 -68.8(6) . .
O2W Eu2 O16 C67 79.5(6) . .
O14 Eu2 O16 C67 154.7(6) 4_565 .
O3W Eu2 O16 C67 141.0(6) . .
O13 Eu2 O16 C67 -152.2(6) 4_565 .
O18 Eu2 O16 C67 -100.8(6) . .
O15 Eu2 O16 C67 2.8(5) . .
C71 Eu2 O16 C67 -85.3(6) . .
C66 Eu2 O16 C67 -178.4(6) 4_565 .
O9 Eu2 O17 C71 91.9(7) 4_465 .
O2W Eu2 O17 C71 158.4(7) . .
O14 Eu2 O17 C71 -76.7(8) 4_565 .
O3W Eu2 O17 C71 23.2(8) . .
O16 Eu2 O17 C71 -140.0(7) . .
O13 Eu2 O17 C71 -66.9(7) 4_565 .
O18 Eu2 O17 C71 5.5(7) . .
O15 Eu2 O17 C71 166.8(8) . .
C66 Eu2 O17 C71 -71.9(8) 4_565 .
C67 Eu2 O17 C71 -165.5(8) . .
O9 Eu2 O18 C71 -94.5(7) 4_465 .
O17 Eu2 O18 C71 -5.4(7) . .
O2W Eu2 O18 C71 -144.6(8) . .
O14 Eu2 O18 C71 122.8(7) 4_565 .
O3W Eu2 O18 C71 -170.2(7) . .
O16 Eu2 O18 C71 36.1(8) . .
O13 Eu2 O18 C71 88.1(7) 4_565 .
O15 Eu2 O18 C71 -25.5(8) . .
C66 Eu2 O18 C71 104.3(7) 4_565 .
C67 Eu2 O18 C71 4.9(8) . .
C4 N2 C1 N1 177.1(10) . .
C3 N2 C1 N1 0.9(14) . .
C2 N1 C1 N2 -1.2(14) . .
C38 N1 C1 N2 -175.9(11) . .
C1 N1 C2 C3 1.0(15) . .
C38 N1 C2 C3 175.7(12) . .
N1 C2 C3 N2 -0.4(15) . .
C1 N2 C3 C2 -0.3(15) . .
C4 N2 C3 C2 -176.4(11) . .
C8 N3 C4 C5 0.0(16) . .
C8 N3 C4 N2 -177.9(9) . .
C1 N2 C4 N3 -11.6(16) . .
C3 N2 C4 N3 163.9(11) . .
C1 N2 C4 C5 170.6(12) . .
C3 N2 C4 C5 -13.9(19) . .
N3 C4 C5 C6 -2(2) . .
N2 C4 C5 C6 175.7(12) . .
C4 C5 C6 C7 2(2) . .
C5 C6 C7 C8 -0.3(17) . .
C4 N3 C8 C7 1.9(16) . .
C4 N3 C8 N4 -179.9(9) . .
C6 C7 C8 N3 -1.7(17) . .
C6 C7 C8 N4 -179.9(10) . .
C9 N4 C8 N3 17.4(15) . .
C10 N4 C8 N3 -167.4(10) . .
C9 N4 C8 C7 -164.2(11) . .
C10 N4 C8 C7 11.0(16) . .
C10 N4 C9 N5 3.1(13) . .
C8 N4 C9 N5 178.8(9) . .
C11 N5 C9 N4 -1.7(13) . .
C12 N5 C9 N4 175.6(10) . .
C9 N4 C10 C11 -3.1(13) . .
C8 N4 C10 C11 -178.8(10) . .
C9 N5 C11 C10 -0.3(14) . .
C12 N5 C11 C10 -177.5(10) . .
N4 C10 C11 N5 1.9(13) . .
C9 N5 C12 C13 -76.9(12) . .
C11 N5 C12 C13 99.9(12) . .
N5 C12 C13 C18 124.6(11) . .
N5 C12 C13 C14 -58.0(12) . .
C18 C13 C14 C15 -3.0(15) . .
C12 C13 C14 C15 179.5(9) . .
C13 C14 C15 C16 1.5(15) . .
C14 C15 C16 C17 1.3(16) . .
C14 C15 C16 C19 178.1(9) . .
C15 C16 C17 C18 -2.5(17) . .
C19 C16 C17 C18 -179.0(10) . .
C14 C13 C18 C17 1.8(17) . .
C12 C13 C18 C17 179.3(10) . .
C16 C17 C18 C13 0.8(18) . .
C20 N6 C19 C16 -112.9(13) . .
C21 N6 C19 C16 67.3(15) . .
C15 C16 C19 N6 -168.5(9) . .
C17 C16 C19 N6 8.3(16) . .
C21 N6 C20 N7 -1.8(13) . .
C19 N6 C20 N7 178.4(10) . .
C23 N7 C20 N6 177.4(10) . .
C22 N7 C20 N6 -1.1(13) . .
C20 N6 C21 C22 4.0(14) . .
C19 N6 C21 C22 -176.2(11) . .
N6 C21 C22 N7 -4.5(13) . .
C20 N7 C22 C21 3.5(13) . .
C23 N7 C22 C21 -175.1(11) . .
C27 N8 C23 C24 1.2(19) . .
C27 N8 C23 N7 178.7(9) . .
C20 N7 C23 C24 -158.1(12) . .
C22 N7 C23 C24 20.3(18) . .
C20 N7 C23 N8 24.3(16) . .
C22 N7 C23 N8 -157.4(10) . .
N8 C23 C24 C25 -1(2) . .
N7 C23 C24 C25 -178.3(11) . .
C23 C24 C25 C26 0.5(19) . .
C24 C25 C26 C27 -0.3(19) . .
C23 N8 C27 C26 -0.9(16) . .
C23 N8 C27 N9 -178.4(9) . .
C25 C26 C27 N8 0.5(18) . .
C25 C26 C27 N9 177.8(11) . .
C28 N9 C27 N8 -6.2(15) . .
C29 N9 C27 N8 173.4(10) . .
C28 N9 C27 C26 176.2(11) . .
C29 N9 C27 C26 -4.2(18) . .
C27 N9 C28 N10 177.2(9) . .
C29 N9 C28 N10 -2.5(12) . .
C30 N10 C28 N9 1.1(12) . .
C31 N10 C28 N9 -173.4(9) . .
C28 N9 C29 C30 3.0(13) . .
C27 N9 C29 C30 -176.6(11) . .
N9 C29 C30 N10 -2.4(14) . .
C28 N10 C30 C29 0.9(14) . .
C31 N10 C30 C29 174.6(11) . .
C30 N10 C31 C32 -106.7(13) . .
C28 N10 C31 C32 66.1(13) . .
N10 C31 C32 C33 -132.8(10) . .
N10 C31 C32 C37 49.1(13) . .
C31 C32 C33 C34 -178.0(10) . .
C37 C32 C33 C34 0.2(15) . .
C32 C33 C34 C35 -0.3(18) . .
C33 C34 C35 C36 1.2(16) . .
C33 C34 C35 C38 -177.9(11) . .
C34 C35 C36 C37 -2.4(18) . .
C38 C35 C36 C37 176.7(12) . .
C35 C36 C37 C32 3(2) . .
C31 C32 C37 C36 176.9(11) . .
C33 C32 C37 C36 -1.4(16) . .
C34 C35 C38 N1 -21.8(15) . .
C36 C35 C38 N1 159.1(10) . .
C1 N1 C38 C35 104.1(14) . .
C2 N1 C38 C35 -69.7(15) . .
Eu1 O1 C39 O2 1.8(8) . .
Eu1 O1 C39 C40 -175.1(7) . .
Eu1 O2 C39 O1 -1.7(8) . .
Eu1 O2 C39 C40 175.2(7) . .
O3 Eu1 C39 O1 -85.7(5) . .
O5 Eu1 C39 O1 72.0(5) . .
O7 Eu1 C39 O1 -10.7(5) . .
O1W Eu1 C39 O1 71(21) . .
O12 Eu1 C39 O1 -159.6(5) . .
O2 Eu1 C39 O1 178.2(8) . .
O11 Eu1 C39 O1 148.5(5) . .
C59 Eu1 C39 O1 174.1(5) . .
O3 Eu1 C39 O2 96.1(5) . .
O5 Eu1 C39 O2 -106.3(5) . .
O7 Eu1 C39 O2 171.1(5) . .
O1 Eu1 C39 O2 -178.2(8) . .
O1W Eu1 C39 O2 -107(20) . .
O12 Eu1 C39 O2 22.2(5) . .
O11 Eu1 C39 O2 -29.8(5) . .
C59 Eu1 C39 O2 -4.1(5) . .
O3 Eu1 C39 C40 3(10) . .
O5 Eu1 C39 C40 161(10) . .
O7 Eu1 C39 C40 78(10) . .
O1 Eu1 C39 C40 89(10) . .
O1W Eu1 C39 C40 160(16) . .
O12 Eu1 C39 C40 -71(10) . .
O2 Eu1 C39 C40 -93(10) . .
O11 Eu1 C39 C40 -123(10) . .
C59 Eu1 C39 C40 -97(10) . .
O1 C39 C40 C42 6.7(13) . .
O2 C39 C40 C42 -170.2(8) . .
Eu1 C39 C40 C42 -80(10) . .
O1 C39 C40 C41 -174.4(8) . .
O2 C39 C40 C41 8.8(13) . .
Eu1 C39 C40 C41 99(10) . .
C42 C40 C41 C69 -2.4(14) . .
C39 C40 C41 C69 178.7(9) . .
C41 C40 C42 C70 1.7(14) . .
C39 C40 C42 C70 -179.4(8) . .
Eu1 O3 C43 O4 95.2(19) . .
Eu1 O3 C43 C44 -92(2) . .
O4 C43 C44 C45 9.7(18) . .
O3 C43 C44 C45 -164.1(11) . .
O4 C43 C44 C46 -166.0(12) . .
O3 C43 C44 C46 20.2(17) . .
C46 C44 C45 C46 -1(2) . 3_656
C43 C44 C45 C46 -176.8(11) . 3_656
C45 C44 C46 C45 1(2) . 3_656
C43 C44 C46 C45 176.7(11) . 3_656
Eu1 O5 C47 O6 164(3) . .
Eu1 O5 C47 C48 -11(5) . .
O6 C47 C48 C49 -18.8(15) . .
O5 C47 C48 C49 155.8(10) . .
O6 C47 C48 C50 161.7(10) . .
O5 C47 C48 C50 -23.8(14) . .
C50 C48 C49 C50 3.7(16) . 3_666
C47 C48 C49 C50 -175.9(9) . 3_666
C49 C48 C50 C49 -3.6(16) . 3_666
C47 C48 C50 C49 175.9(9) . 3_666
Eu1 O7 C51 O8 14(2) . .
Eu1 O7 C51 C52 -165.1(7) . .
O7 C51 C52 C53 179.2(10) . .
O8 C51 C52 C53 0.1(17) . .
O7 C51 C52 C57 0.9(15) . .
O8 C51 C52 C57 -178.2(11) . .
C57 C52 C53 C54 -2.5(17) . .
C51 C52 C53 C54 179.2(11) . .
C52 C53 C54 C55 2.9(19) . .
C53 C54 C55 C56 -2.3(18) . .
C53 C54 C55 C58 177.2(11) . .
C54 C55 C56 C57 1.3(17) . .
C58 C55 C56 C57 -178.2(10) . .
C55 C56 C57 C52 -0.9(16) . .
C53 C52 C57 C56 1.5(16) . .
C51 C52 C57 C56 179.8(9) . .
Eu2 O9 C58 O10 8(2) 4_666 .
Eu2 O9 C58 C55 -172.2(9) 4_666 .
C54 C55 C58 O9 0.7(18) . .
C56 C55 C58 O9 -179.8(11) . .
C54 C55 C58 O10 -179.4(11) . .
C56 C55 C58 O10 0.1(17) . .
Eu1 O11 C59 O12 1.7(11) . .
Eu1 O11 C59 C60 -171.1(9) . .
Eu1 O12 C59 O11 -1.7(11) . .
Eu1 O12 C59 C60 171.0(8) . .
O3 Eu1 C59 O11 -171.2(6) . .
O5 Eu1 C59 O11 4.8(7) . .
O7 Eu1 C59 O11 102.8(8) . .
O1 Eu1 C59 O11 -84.9(7) . .
O1W Eu1 C59 O11 91.1(6) . .
O12 Eu1 C59 O11 178.3(11) . .
O2 Eu1 C59 O11 -90.1(6) . .
C39 Eu1 C59 O11 -88.2(6) . .
O3 Eu1 C59 O12 10.5(7) . .
O5 Eu1 C59 O12 -173.5(6) . .
O7 Eu1 C59 O12 -75.5(9) . .
O1 Eu1 C59 O12 96.8(6) . .
O1W Eu1 C59 O12 -87.2(6) . .
O2 Eu1 C59 O12 91.6(6) . .
O11 Eu1 C59 O12 -178.3(11) . .
C39 Eu1 C59 O12 93.6(6) . .
O3 Eu1 C59 C60 -74(5) . .
O5 Eu1 C59 C60 102(5) . .
O7 Eu1 C59 C60 -160(5) . .
O1 Eu1 C59 C60 12(5) . .
O1W Eu1 C59 C60 -172(5) . .
O12 Eu1 C59 C60 -85(5) . .
O2 Eu1 C59 C60 7(5) . .
O11 Eu1 C59 C60 97(5) . .
C39 Eu1 C59 C60 9(5) . .
O11 C59 C60 C61 -10.9(16) . .
O12 C59 C60 C61 176.3(10) . .
Eu1 C59 C60 C61 -104(5) . .
O11 C59 C60 C65 171.4(10) . .
O12 C59 C60 C65 -1.4(15) . .
Eu1 C59 C60 C65 79(5) . .
C65 C60 C61 C62 -1.7(15) . .
C59 C60 C61 C62 -179.5(10) . .
C60 C61 C62 C63 0.2(17) . .
C61 C62 C63 C64 0.3(16) . .
C61 C62 C63 C66 -175.7(10) . .
C62 C63 C64 C65 0.7(15) . .
C66 C63 C64 C65 176.8(10) . .
C63 C64 C65 C60 -2.3(16) . .
C61 C60 C65 C64 2.7(15) . .
C59 C60 C65 C64 -179.4(10) . .
Eu2 O13 C66 O14 3.7(12) 4_566 .
Eu2 O13 C66 C63 -174.7(9) 4_566 .
Eu2 O14 C66 O13 -3.8(12) 4_566 .
Eu2 O14 C66 C63 174.7(8) 4_566 .
C62 C63 C66 O13 -8.7(16) . .
C64 C63 C66 O13 175.4(10) . .
C62 C63 C66 O14 172.8(10) . .
C64 C63 C66 O14 -3.1(15) . .
C62 C63 C66 Eu2 -132(7) . 4_566
C64 C63 C66 Eu2 53(8) . 4_566
Eu2 O16 C67 O15 -5.4(10) . .
Eu2 O16 C67 C68 175.8(7) . .
Eu2 O15 C67 O16 5.2(10) . .
Eu2 O15 C67 C68 -176.0(8) . .
O9 Eu2 C67 O16 -172.6(5) 4_465 .
O17 Eu2 C67 O16 105.1(6) . .
O2W Eu2 C67 O16 -95.8(6) . .
O14 Eu2 C67 O16 -25.1(6) 4_565 .
O3W Eu2 C67 O16 -98.7(9) . .
O13 Eu2 C67 O16 26.4(6) 4_565 .
O18 Eu2 C67 O16 96.6(6) . .
O15 Eu2 C67 O16 -175.0(9) . .
C71 Eu2 C67 O16 98.8(6) . .
C66 Eu2 C67 O16 1.5(6) 4_565 .
O9 Eu2 C67 O15 2.4(6) 4_465 .
O17 Eu2 C67 O15 -79.9(6) . .
O2W Eu2 C67 O15 79.2(6) . .
O14 Eu2 C67 O15 149.8(6) 4_565 .
O3W Eu2 C67 O15 76.3(10) . .
O16 Eu2 C67 O15 175.0(9) . .
O13 Eu2 C67 O15 -158.6(6) 4_565 .
O18 Eu2 C67 O15 -88.5(6) . .
C71 Eu2 C67 O15 -86.3(6) . .
C66 Eu2 C67 O15 176.5(6) 4_565 .
O9 Eu2 C67 C68 133(9) 4_465 .
O17 Eu2 C67 C68 50(9) . .
O2W Eu2 C67 C68 -151(9) . .
O14 Eu2 C67 C68 -80(9) 4_565 .
O3W Eu2 C67 C68 -153(8) . .
O16 Eu2 C67 C68 -55(8) . .
O13 Eu2 C67 C68 -28(9) 4_565 .
O18 Eu2 C67 C68 42(9) . .
O15 Eu2 C67 C68 130(9) . .
C71 Eu2 C67 C68 44(9) . .
C66 Eu2 C67 C68 -53(9) 4_565 .
O16 C67 C68 C69 178.1(9) . .
O15 C67 C68 C69 -0.7(14) . .
Eu2 C67 C68 C69 -129(8) . .
O16 C67 C68 C70 -5.8(13) . .
O15 C67 C68 C70 175.4(9) . .
Eu2 C67 C68 C70 47(9) . .
C70 C68 C69 C41 2.1(15) . .
C67 C68 C69 C41 178.1(9) . .
C40 C41 C69 C68 0.5(15) . .
C69 C68 C70 C42 -2.7(14) . .
C67 C68 C70 C42 -178.8(8) . .
C40 C42 C70 C68 0.8(14) . .
Eu2 O17 C71 O18 -11.1(14) . .
Eu2 O17 C71 C72 160.0(9) . .
Eu2 O18 C71 O17 10.6(13) . .
Eu2 O18 C71 C72 -160.7(9) . .
O9 Eu2 C71 O17 -86.6(7) 4_465 .
O2W Eu2 C71 O17 -56.4(16) . .
O14 Eu2 C71 O17 121.3(7) 4_565 .
O3W Eu2 C71 O17 -160.7(7) . .
O16 Eu2 C71 O17 40.1(7) . .
O13 Eu2 C71 O17 107.1(7) 4_565 .
O18 Eu2 C71 O17 -170.2(12) . .
O15 Eu2 C71 O17 -12.4(7) . .
C66 Eu2 C71 O17 112.8(7) 4_565 .
C67 Eu2 C71 O17 14.0(7) . .
O9 Eu2 C71 O18 83.6(7) 4_465 .
O17 Eu2 C71 O18 170.2(12) . .
O2W Eu2 C71 O18 113.7(14) . .
O14 Eu2 C71 O18 -68.5(7) 4_565 .
O3W Eu2 C71 O18 9.5(7) . .
O16 Eu2 C71 O18 -149.7(6) . .
O13 Eu2 C71 O18 -82.7(7) 4_565 .
O15 Eu2 C71 O18 157.8(7) . .
C66 Eu2 C71 O18 -77.1(7) 4_565 .
C67 Eu2 C71 O18 -175.9(7) . .
O9 Eu2 C71 C72 -178(3) 4_465 .
O17 Eu2 C71 C72 -91(3) . .
O2W Eu2 C71 C72 -147(3) . .
O14 Eu2 C71 C72 30(4) 4_565 .
O3W Eu2 C71 C72 108(3) . .
O16 Eu2 C71 C72 -51(3) . .
O13 Eu2 C71 C72 16(3) 4_565 .
O18 Eu2 C71 C72 99(4) . .
O15 Eu2 C71 C72 -103(3) . .
C66 Eu2 C71 C72 22(3) 4_565 .
C67 Eu2 C71 C72 -77(3) . .
O17 C71 C72 C77 -142.3(14) . .
O18 C71 C72 C77 29.7(17) . .
Eu2 C71 C72 C77 -61(4) . .
O17 C71 C72 C73 30.0(16) . .
O18 C71 C72 C73 -158.0(12) . .
Eu2 C71 C72 C73 111(3) . .
C77 C72 C73 C74 -3(2) . .
C71 C72 C73 C74 -175.7(12) . .
C72 C73 C74 C75 5(2) . .
C73 C74 C75 C76 -6(2) . .
C73 C74 C75 C78 176.4(14) . .
C74 C75 C76 C77 5(2) . .
C78 C75 C76 C77 -177.5(13) . .
C73 C72 C77 C76 2(2) . .
C71 C72 C77 C76 174.0(11) . .
C75 C76 C77 C72 -3(2) . .
C76 C75 C78 O19 -161.9(16) . .
C74 C75 C78 O19 16(2) . .
C76 C75 C78 O20 26(2) . .
C74 C75 C78 O20 -156.2(17) . .
loop_
_platon_squeeze_void_nr
_platon_squeeze_void_average_x
_platon_squeeze_void_average_y
_platon_squeeze_void_average_z
_platon_squeeze_void_volume
_platon_squeeze_void_count_electrons
_platon_squeeze_void_content
1 -0.003 -0.013 -0.002 2390 5103 ' '
2 0.027 0.001 0.285 41 209 ' '
3 0.973 -0.001 0.715 41 162 ' '
4 0.027 0.499 0.785 41 198 ' '
5 0.973 0.501 0.215 41 180 ' '
