#------------------------------------------------------------------------------
#$Date: 2016-03-26 03:55:00 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180202 $
#$URL: svn://www.crystallography.net/cod/cif/7/10/96/7109624.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7109624
loop_
_publ_author_name
'Ivana Jevtovikj'
'Peter Lonnecke'
'Evamarie Hey-Hawkins'
_publ_section_title
;
 1,2,3,4-Tetramesityl-1,4-bis(tri-n-butyltin)tetraphosphane: synthesis and
 molecular structure
;
_journal_name_full               Chem.Commun.
_journal_page_first              7355
_journal_paper_doi               10.1039/c3cc44571b
_journal_volume                  49
_journal_year                    2013
_chemical_formula_sum            'C60 H98 P4 Sn2'
_chemical_formula_weight         1180.64
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_conform_dict_location     ftp://ftp.iucr.org/pub/cif_core.dic
_audit_conform_dict_name         cif_core.dic
_audit_conform_dict_version      2.2
_audit_creation_date             2009-09-29T15:56:36-00:00
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                110.296(2)
_cell_angle_beta                 99.499(2)
_cell_angle_gamma                106.251(2)
_cell_formula_units_Z            1
_cell_length_a                   9.5430(2)
_cell_length_b                   13.0225(4)
_cell_length_c                   14.6643(4)
_cell_measurement_reflns_used    20723
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      32.2969
_cell_measurement_theta_min      2.856
_cell_volume                     1569.89(8)
_computing_cell_refinement
;
        CrysAlisPro, Oxford Diffraction Ltd.,
        Version 1.171.33.41 (release 06-05-2009 CrysAlis171 .NET)
        (compiled May  6 2009,17:20:42)
;
_computing_data_collection
;
        CrysAlisPro, Oxford Diffraction Ltd.,
        Version 1.171.33.41 (release 06-05-2009 CrysAlis171 .NET)
        (compiled May  6 2009,17:20:42)
;
_computing_data_reduction
;
        CrysAlisPro, Oxford Diffraction Ltd.,
        Version 1.171.33.41 (release 06-05-2009 CrysAlis171 .NET)
        (compiled May  6 2009,17:20:42)
;
_computing_molecular_graphics
;
 ORTEP3 for Windows
 L. J. Farrugia, J. Appl. Crystallogr. 1997, 30, 565.
;
_computing_publication_material
;
 WINGX
 L.J. Farrugia,
 J. Appl. Cryst., 1999, 32, 837-838.
;
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution
;
 SIR92
 A. Altomare, G. Cascarano, C. Giacovazzo and A. Guagliardi,
 J. Appl. Crystallogr. 1993, 26, 343-350.
;
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Xcalibur, Sapphire3, Gemini'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      0.0245906525
_diffrn_orient_matrix_UB_12      0.0318622794
_diffrn_orient_matrix_UB_13      -0.0286438208
_diffrn_orient_matrix_UB_21      0.0629369902
_diffrn_orient_matrix_UB_22      0.0412156623
_diffrn_orient_matrix_UB_23      0.0427771108
_diffrn_orient_matrix_UB_31      0.0446976833
_diffrn_orient_matrix_UB_32      -0.0343638282
_diffrn_orient_matrix_UB_33      -0.0159405973
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0205
_diffrn_reflns_av_unetI/netI     0.022
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            34675
_diffrn_reflns_theta_full        30.51
_diffrn_reflns_theta_max         30.51
_diffrn_reflns_theta_min         2.86
_exptl_absorpt_coefficient_mu    0.931
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.92977
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
        CrysAlisPro, Oxford Diffraction Ltd.,
        Version 1.171.33.41 (release 06-05-2009 CrysAlis171 .NET)
        (compiled May  6 2009,17:20:42)
        Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.249
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             618
_exptl_crystal_size_max          0.6
_exptl_crystal_size_mid          0.4
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.81
_refine_diff_density_min         -0.379
_refine_diff_density_rms         0.053
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.993
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     339
_refine_ls_number_reflns         9560
_refine_ls_number_restraints     16
_refine_ls_restrained_S_all      0.994
_refine_ls_R_factor_all          0.0349
_refine_ls_R_factor_gt           0.0259
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0424P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0651
_refine_ls_wR_factor_ref         0.0671
_reflns_number_gt                7798
_reflns_number_total             9560
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c3cc44571b.txt
_cod_data_source_block           x0837fin
_cod_original_cell_volume        1569.89(7)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7109624
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Sn1 Sn 0.687197(11) 0.349367(9) 0.284798(7) 0.03839(4) Uani 1 1 d D . .
P1 P 0.59811(4) 0.22764(3) 0.09540(3) 0.03474(8) Uani 1 1 d . A .
P2 P 0.47556(4) 0.04443(3) 0.07212(3) 0.03302(8) Uani 1 1 d . . .
C1 C 0.43384(17) 0.26596(12) 0.05166(11) 0.0379(3) Uani 1 1 d . . .
C2 C 0.4495(2) 0.31755(13) -0.01818(12) 0.0461(4) Uani 1 1 d . A .
C3 C 0.3254(3) 0.33836(16) -0.06304(15) 0.0594(5) Uani 1 1 d . . .
C4 C 0.1895(2) 0.31251(17) -0.04064(16) 0.0627(5) Uani 1 1 d . A .
C5 C 0.1784(2) 0.26765(18) 0.03079(16) 0.0567(5) Uani 1 1 d . . .
C6 C 0.29772(18) 0.24501(14) 0.07879(12) 0.0446(3) Uani 1 1 d . A .
C7 C 0.5955(3) 0.35245(17) -0.04522(16) 0.0614(5) Uani 1 1 d . . .
H7A H 0.5858 0.3935 -0.0893 0.092 Uiso 1 1 calc R A .
H7B H 0.6164 0.282 -0.0809 0.092 Uiso 1 1 calc R . .
H7C H 0.6796 0.4046 0.017 0.092 Uiso 1 1 calc R . .
C8 C 0.0555(3) 0.3346(2) -0.0916(2) 0.0964(9) Uani 1 1 d . . .
H8A H 0.0914 0.413 -0.0914 0.145 Uiso 1 1 calc R A .
H8B H -0.0208 0.3299 -0.0545 0.145 Uiso 1 1 calc R . .
H8C H 0.0095 0.2752 -0.1619 0.145 Uiso 1 1 calc R . .
C9 C 0.2732(2) 0.20259(19) 0.16009(15) 0.0556(4) Uani 1 1 d . . .
H9A H 0.2038 0.2344 0.1928 0.083 Uiso 1 1 calc R A .
H9B H 0.3713 0.2292 0.211 0.083 Uiso 1 1 calc R . .
H9C H 0.2287 0.1165 0.1296 0.083 Uiso 1 1 calc R . .
C10 C 0.59891(19) 0.00897(13) 0.15844(10) 0.0413(3) Uani 1 1 d . A .
C11 C 0.7535(2) 0.02682(15) 0.16983(12) 0.0514(4) Uani 1 1 d . . .
C12 C 0.8254(3) -0.0164(2) 0.23152(17) 0.0764(8) Uani 1 1 d . A .
C13 C 0.7505(4) -0.0749(2) 0.28179(17) 0.0886(9) Uani 1 1 d . . .
C14 C 0.6022(4) -0.0883(2) 0.27222(16) 0.0800(8) Uani 1 1 d . A .
C15 C 0.5216(3) -0.04867(15) 0.21174(12) 0.0557(5) Uani 1 1 d . . .
C16 C 0.8489(2) 0.08889(19) 0.11959(15) 0.0616(5) Uani 1 1 d . A .
H16A H 0.9461 0.1456 0.1696 0.092 Uiso 1 1 calc R . .
H16B H 0.7946 0.1303 0.0921 0.092 Uiso 1 1 calc R . .
H16C H 0.8683 0.0313 0.0642 0.092 Uiso 1 1 calc R . .
C17 C 0.8311(5) -0.1237(3) 0.3444(2) 0.1456(18) Uani 1 1 d . A .
H17A H 0.7991 -0.1119 0.4063 0.218 Uiso 1 1 calc R . .
H17B H 0.9416 -0.083 0.363 0.218 Uiso 1 1 calc R . .
H17C H 0.8048 -0.208 0.3047 0.218 Uiso 1 1 calc R . .
C18 C 0.3564(3) -0.07077(19) 0.20482(17) 0.0708(6) Uani 1 1 d . A .
H18A H 0.324 -0.1169 0.2432 0.106 Uiso 1 1 calc R . .
H18B H 0.295 -0.1143 0.1335 0.106 Uiso 1 1 calc R . .
H18C H 0.3425 0.0045 0.2333 0.106 Uiso 1 1 calc R . .
C19 C 0.93283(17) 0.40489(14) 0.32475(12) 0.0422(3) Uani 1 1 d D A .
H19A H 0.9759 0.4576 0.3981 0.051 Uiso 1 1 calc R . .
H19B H 0.9615 0.335 0.3133 0.051 Uiso 1 1 calc R . .
C20 C 1.00320(18) 0.46866(15) 0.26444(12) 0.0456(4) Uani 1 1 d D . .
H20A H 0.9576 0.4169 0.1911 0.055 Uiso 1 1 calc R A .
H20B H 0.977 0.5398 0.2776 0.055 Uiso 1 1 calc R . .
C21 C 1.17480(19) 0.50465(16) 0.28977(13) 0.0484(4) Uani 1 1 d D A .
H21A H 1.2011 0.4333 0.2744 0.058 Uiso 1 1 calc R . .
H21B H 1.2204 0.5545 0.3635 0.058 Uiso 1 1 calc R . .
C22 C 1.2438(2) 0.5714(2) 0.23167(16) 0.0614(5) Uani 1 1 d D . .
H22A H 1.2009 0.5219 0.1585 0.092 Uiso 1 1 calc R A .
H22B H 1.3547 0.5921 0.251 0.092 Uiso 1 1 calc R . .
H22C H 1.2207 0.6432 0.2478 0.092 Uiso 1 1 calc R . .
C23 C 0.6171(5) 0.4971(3) 0.2940(2) 0.0537(7) Uani 0.806(5) 1 d PD A 1
H23A H 0.6804 0.5431 0.2642 0.064 Uiso 0.806(5) 1 calc PR A 1
H23B H 0.5099 0.4658 0.2514 0.064 Uiso 0.806(5) 1 calc PR A 1
C24 C 0.6284(3) 0.5808(2) 0.40061(19) 0.0665(8) Uani 0.806(5) 1 d PD A 1
H24A H 0.5843 0.6393 0.3946 0.08 Uiso 0.806(5) 1 calc PR A 1
H24B H 0.5656 0.5351 0.4308 0.08 Uiso 0.806(5) 1 calc PR A 1
C25 C 0.7859(4) 0.6445(3) 0.4711(2) 0.0746(10) Uani 0.806(5) 1 d PD A 1
H25A H 0.8522 0.6788 0.4357 0.089 Uiso 0.806(5) 1 calc PR A 1
H25B H 0.8234 0.5865 0.4855 0.089 Uiso 0.806(5) 1 calc PR A 1
C26 C 0.8045(5) 0.7399(3) 0.5697(2) 0.0863(11) Uani 0.806(5) 1 d PD A 1
H26A H 0.7638 0.7965 0.557 0.129 Uiso 0.806(5) 1 calc PR A 1
H26B H 0.913 0.78 0.6077 0.129 Uiso 0.806(5) 1 calc PR A 1
H26C H 0.7489 0.7062 0.6093 0.129 Uiso 0.806(5) 1 calc PR A 1
C23F C 0.622(2) 0.4973(14) 0.3217(10) 0.0537(7) Uani 0.194(5) 1 d PD A 2
H23C H 0.6365 0.5321 0.2721 0.064 Uiso 0.194(5) 1 calc PR A 2
H23D H 0.5124 0.4732 0.3186 0.064 Uiso 0.194(5) 1 calc PR A 2
C24F C 0.716(2) 0.5861(13) 0.4265(12) 0.103(6) Uiso 0.194(5) 1 d PD A 2
H24C H 0.7013 0.5488 0.4743 0.123 Uiso 0.194(5) 1 calc PR A 2
H24D H 0.8252 0.6069 0.4282 0.123 Uiso 0.194(5) 1 calc PR A 2
C25F C 0.6855(18) 0.6946(12) 0.4633(11) 0.102(5) Uiso 0.194(5) 1 d PD A 2
H25C H 0.5801 0.6744 0.4686 0.122 Uiso 0.194(5) 1 calc PR A 2
H25D H 0.6892 0.727 0.4115 0.122 Uiso 0.194(5) 1 calc PR A 2
C26F C 0.788(2) 0.7880(14) 0.5616(10) 0.0863(11) Uani 0.194(5) 1 d PD A 2
H26D H 0.8869 0.8243 0.5532 0.129 Uiso 0.194(5) 1 calc PR A 2
H26E H 0.802 0.7541 0.611 0.129 Uiso 0.194(5) 1 calc PR A 2
H26F H 0.7431 0.8477 0.586 0.129 Uiso 0.194(5) 1 calc PR A 2
C27 C 0.6072(2) 0.26918(16) 0.38216(12) 0.0482(4) Uani 1 1 d . A .
H27A H 0.5774 0.3248 0.4335 0.058 Uiso 1 1 calc R . .
H27B H 0.5148 0.1981 0.3407 0.058 Uiso 1 1 calc R . .
C28 C 0.7231(2) 0.23457(16) 0.43669(12) 0.0480(4) Uani 1 1 d . . .
H28A H 0.8135 0.3061 0.4811 0.058 Uiso 1 1 calc R A .
H28B H 0.7569 0.182 0.3856 0.058 Uiso 1 1 calc R . .
C29 C 0.6623(3) 0.17285(19) 0.50076(14) 0.0619(5) Uani 1 1 d . A .
H29A H 0.6259 0.2243 0.5506 0.074 Uiso 1 1 calc R . .
H29B H 0.574 0.0998 0.4562 0.074 Uiso 1 1 calc R . .
C30 C 0.7808(3) 0.1423(3) 0.55696(19) 0.0856(7) Uani 1 1 d . . .
H30A H 0.8281 0.101 0.5093 0.128 Uiso 1 1 calc R A .
H30B H 0.7319 0.0915 0.5876 0.128 Uiso 1 1 calc R . .
H30C H 0.8593 0.2146 0.6104 0.128 Uiso 1 1 calc R . .
H3 H 0.343(3) 0.376(2) -0.1042(18) 0.074(7) Uiso 1 1 d . . .
H5 H 0.095(3) 0.2471(19) 0.0417(16) 0.063(7) Uiso 1 1 d . . .
H12 H 0.922(3) -0.010(2) 0.2276(18) 0.074(7) Uiso 1 1 d . . .
H14 H 0.549(3) -0.124(2) 0.304(2) 0.083(8) Uiso 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_3
C23F Sn1 C27 103.7(5) .
C23F Sn1 C19 110.1(6) .
C27 Sn1 C19 108.67(6) .
C23F Sn1 C23 10.6(4) .
C27 Sn1 C23 112.78(11) .
C19 Sn1 C23 110.38(12) .
C23F Sn1 P1 110.9(4) .
C27 Sn1 P1 118.75(5) .
C19 Sn1 P1 104.66(4) .
C23 Sn1 P1 101.08(7) .
C1 P1 P2 99.87(5) .
C1 P1 Sn1 103.16(5) .
P2 P1 Sn1 106.276(17) .
C10 P2 P1 107.47(5) .
C10 P2 P2 99.36(5) 2_655
P1 P2 P2 96.98(2) 2_655
C6 C1 C2 118.60(15) .
C6 C1 P1 126.33(12) .
C2 C1 P1 115.03(13) .
C3 C2 C1 118.94(18) .
C3 C2 C7 118.63(16) .
C1 C2 C7 122.43(16) .
C4 C3 C2 122.59(18) .
C4 C3 H3 121.5(15) .
C2 C3 H3 115.7(15) .
C5 C4 C3 117.78(17) .
C5 C4 C8 120.7(2) .
C3 C4 C8 121.5(2) .
C4 C5 C6 122.7(2) .
C4 C5 H5 118.6(16) .
C6 C5 H5 118.4(16) .
C5 C6 C1 119.22(17) .
C5 C6 C9 117.04(17) .
C1 C6 C9 123.71(14) .
C2 C7 H7A 109.5 .
C2 C7 H7B 109.5 .
H7A C7 H7B 109.5 .
C2 C7 H7C 109.5 .
H7A C7 H7C 109.5 .
H7B C7 H7C 109.5 .
C4 C8 H8A 109.5 .
C4 C8 H8B 109.5 .
H8A C8 H8B 109.5 .
C4 C8 H8C 109.5 .
H8A C8 H8C 109.5 .
H8B C8 H8C 109.5 .
C6 C9 H9A 109.5 .
C6 C9 H9B 109.5 .
H9A C9 H9B 109.5 .
C6 C9 H9C 109.5 .
H9A C9 H9C 109.5 .
H9B C9 H9C 109.5 .
C11 C10 C15 119.09(16) .
C11 C10 P2 126.49(13) .
C15 C10 P2 114.28(14) .
C10 C11 C12 118.6(2) .
C10 C11 C16 124.26(16) .
C12 C11 C16 117.1(2) .
C13 C12 C11 122.8(3) .
C13 C12 H12 124.2(16) .
C11 C12 H12 112.6(16) .
C14 C13 C12 117.7(2) .
C14 C13 C17 121.4(3) .
C12 C13 C17 120.9(3) .
C13 C14 C15 123.2(3) .
C13 C14 H14 121.4(17) .
C15 C14 H14 115.4(18) .
C14 C15 C10 118.6(2) .
C14 C15 C18 118.6(2) .
C10 C15 C18 122.80(17) .
C11 C16 H16A 109.5 .
C11 C16 H16B 109.5 .
H16A C16 H16B 109.5 .
C11 C16 H16C 109.5 .
H16A C16 H16C 109.5 .
H16B C16 H16C 109.5 .
C13 C17 H17A 109.5 .
C13 C17 H17B 109.5 .
H17A C17 H17B 109.5 .
C13 C17 H17C 109.5 .
H17A C17 H17C 109.5 .
H17B C17 H17C 109.5 .
C15 C18 H18A 109.5 .
C15 C18 H18B 109.5 .
H18A C18 H18B 109.5 .
C15 C18 H18C 109.5 .
H18A C18 H18C 109.5 .
H18B C18 H18C 109.5 .
C20 C19 Sn1 113.41(10) .
C20 C19 H19A 108.9 .
Sn1 C19 H19A 108.9 .
C20 C19 H19B 108.9 .
Sn1 C19 H19B 108.9 .
H19A C19 H19B 107.7 .
C21 C20 C19 113.73(13) .
C21 C20 H20A 108.8 .
C19 C20 H20A 108.8 .
C21 C20 H20B 108.8 .
C19 C20 H20B 108.8 .
H20A C20 H20B 107.7 .
C20 C21 C22 113.18(15) .
C20 C21 H21A 108.9 .
C22 C21 H21A 108.9 .
C20 C21 H21B 108.9 .
C22 C21 H21B 108.9 .
H21A C21 H21B 107.8 .
C21 C22 H22A 109.5 .
C21 C22 H22B 109.5 .
H22A C22 H22B 109.5 .
C21 C22 H22C 109.5 .
H22A C22 H22C 109.5 .
H22B C22 H22C 109.5 .
C24 C23 Sn1 115.94(18) .
C24 C23 H23A 108.3 .
Sn1 C23 H23A 108.3 .
C24 C23 H23B 108.3 .
Sn1 C23 H23B 108.3 .
H23A C23 H23B 107.4 .
C25 C24 C23 114.7(3) .
C25 C24 H24A 108.6 .
C23 C24 H24A 108.6 .
C25 C24 H24B 108.6 .
C23 C24 H24B 108.6 .
H24A C24 H24B 107.6 .
C24 C25 C26 116.2(3) .
C24 C25 H25A 108.2 .
C26 C25 H25A 108.2 .
C24 C25 H25B 108.2 .
C26 C25 H25B 108.2 .
H25A C25 H25B 107.4 .
C24F C23F Sn1 109.3(10) .
C24F C23F H23C 109.8 .
Sn1 C23F H23C 109.8 .
C24F C23F H23D 109.8 .
Sn1 C23F H23D 109.8 .
H23C C23F H23D 108.3 .
C25F C24F C23F 116.1(14) .
C25F C24F H24C 108.3 .
C23F C24F H24C 108.3 .
C25F C24F H24D 108.3 .
C23F C24F H24D 108.3 .
H24C C24F H24D 107.4 .
C24F C25F C26F 116.9(13) .
C24F C25F H25C 108.1 .
C26F C25F H25C 108.1 .
C24F C25F H25D 108.1 .
C26F C25F H25D 108.1 .
H25C C25F H25D 107.3 .
C25F C26F H26D 109.5 .
C25F C26F H26E 109.5 .
H26D C26F H26E 109.5 .
C25F C26F H26F 109.5 .
H26D C26F H26F 109.5 .
H26E C26F H26F 109.5 .
C28 C27 Sn1 114.30(11) .
C28 C27 H27A 108.7 .
Sn1 C27 H27A 108.7 .
C28 C27 H27B 108.7 .
Sn1 C27 H27B 108.7 .
H27A C27 H27B 107.6 .
C27 C28 C29 113.57(16) .
C27 C28 H28A 108.9 .
C29 C28 H28A 108.9 .
C27 C28 H28B 108.9 .
C29 C28 H28B 108.9 .
H28A C28 H28B 107.7 .
C30 C29 C28 112.79(19) .
C30 C29 H29A 109 .
C28 C29 H29A 109 .
C30 C29 H29B 109 .
C28 C29 H29B 109 .
H29A C29 H29B 107.8 .
C29 C30 H30A 109.5 .
C29 C30 H30B 109.5 .
H30A C30 H30B 109.5 .
C29 C30 H30C 109.5 .
H30A C30 H30C 109.5 .
H30B C30 H30C 109.5 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Sn1 C23F 2.111(13) .
Sn1 C27 2.1586(17) .
Sn1 C19 2.1599(15) .
Sn1 C23 2.177(3) .
Sn1 P1 2.5222(4) .
P1 C1 1.8562(16) .
P1 P2 2.2178(5) .
P2 C10 1.8490(16) .
P2 P2 2.2272(7) 2_655
C1 C6 1.403(2) .
C1 C2 1.412(2) .
C2 C3 1.398(3) .
C2 C7 1.503(3) .
C3 C4 1.370(3) .
C3 H3 0.91(2) .
C4 C5 1.370(3) .
C4 C8 1.522(3) .
C5 C6 1.395(2) .
C5 H5 0.82(2) .
C6 C9 1.502(2) .
C7 H7A 0.98 .
C7 H7B 0.98 .
C7 H7C 0.98 .
C8 H8A 0.98 .
C8 H8B 0.98 .
C8 H8C 0.98 .
C9 H9A 0.98 .
C9 H9B 0.98 .
C9 H9C 0.98 .
C10 C11 1.400(2) .
C10 C15 1.416(2) .
C11 C12 1.404(3) .
C11 C16 1.499(3) .
C12 C13 1.376(4) .
C12 H12 0.91(2) .
C13 C14 1.354(4) .
C13 C17 1.512(3) .
C14 C15 1.399(3) .
C14 H14 0.89(3) .
C15 C18 1.500(3) .
C16 H16A 0.98 .
C16 H16B 0.98 .
C16 H16C 0.98 .
C17 H17A 0.98 .
C17 H17B 0.98 .
C17 H17C 0.98 .
C18 H18A 0.98 .
C18 H18B 0.98 .
C18 H18C 0.98 .
C19 C20 1.522(2) .
C19 H19A 0.99 .
C19 H19B 0.99 .
C20 C21 1.513(2) .
C20 H20A 0.99 .
C20 H20B 0.99 .
C21 C22 1.514(3) .
C21 H21A 0.99 .
C21 H21B 0.99 .
C22 H22A 0.98 .
C22 H22B 0.98 .
C22 H22C 0.98 .
C23 C24 1.529(4) .
C23 H23A 0.99 .
C23 H23B 0.99 .
C24 C25 1.487(4) .
C24 H24A 0.99 .
C24 H24B 0.99 .
C25 C26 1.487(4) .
C25 H25A 0.99 .
C25 H25B 0.99 .
C26 H26A 0.98 .
C26 H26B 0.98 .
C26 H26C 0.98 .
C23F C24F 1.496(14) .
C23F H23C 0.99 .
C23F H23D 0.99 .
C24F C25F 1.460(14) .
C24F H24C 0.99 .
C24F H24D 0.99 .
C25F C26F 1.471(13) .
C25F H25C 0.99 .
C25F H25D 0.99 .
C26F H26D 0.98 .
C26F H26E 0.98 .
C26F H26F 0.98 .
C27 C28 1.518(2) .
C27 H27A 0.99 .
C27 H27B 0.99 .
C28 C29 1.519(3) .
C28 H28A 0.99 .
C28 H28B 0.99 .
C29 C30 1.513(3) .
C29 H29A 0.99 .
C29 H29B 0.99 .
C30 H30A 0.98 .
C30 H30B 0.98 .
C30 H30C 0.98 .
