#------------------------------------------------------------------------------
#$Date: 2016-03-26 12:46:26 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180215 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/01/7110167.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7110167
loop_
_publ_author_name
'Pengfei Ai'
'Andreas A. Danopoulos'
'Pierre Braunstein'
'Kirill Yu. Monakhovc'
_publ_section_title
;
 A novel, rigid diphosphine with an active NHC spacer; di- and trinuclear
 complexes of d10 coinage metals
;
_journal_name_full               Chem.Commun.
_journal_page_first              103
_journal_paper_doi               10.1039/c3cc47370h
_journal_volume                  50
_journal_year                    2013
_chemical_formula_moiety         'C38 H76 Au3 N4 P4, 3(C F3 O3 S), 2(C2 H3 N)'
_chemical_formula_sum            'C45 H82 Au3 F9 N6 O9 P4 S3'
_chemical_formula_weight         1833.13
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.0060(10)
_cell_angle_beta                 103.5620(10)
_cell_angle_gamma                116.8880(10)
_cell_formula_units_Z            2
_cell_length_a                   12.0469(6)
_cell_length_b                   12.6938(6)
_cell_length_c                   24.4780(12)
_cell_measurement_reflns_used    9319
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      31.04
_cell_measurement_theta_min      2.41
_cell_volume                     3221.0(3)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0313
_diffrn_reflns_av_sigmaI/netI    0.0405
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            59662
_diffrn_reflns_theta_full        31.24
_diffrn_reflns_theta_max         31.24
_diffrn_reflns_theta_min         1.72
_exptl_absorpt_coefficient_mu    7.090
_exptl_absorpt_correction_T_max  0.4833
_exptl_absorpt_correction_T_min  0.3313
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.890
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1784
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_refine_diff_density_max         3.030
_refine_diff_density_min         -4.035
_refine_diff_density_rms         0.165
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.064
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     750
_refine_ls_number_reflns         20683
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.064
_refine_ls_R_factor_all          0.0593
_refine_ls_R_factor_gt           0.0372
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0170P)²+16.8627P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0713
_refine_ls_wR_factor_ref         0.0782
_reflns_number_gt                15900
_reflns_number_total             20683
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            c3cc47370h.txt
_cod_data_source_block           pbad130719
_cod_database_code               7110167
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.6985(5) 0.0936(4) 0.03002(17) 0.0235(10) Uani 1 1 d . . .
C2 C 0.8934(6) 0.1844(6) 0.0901(2) 0.0472(16) Uani 1 1 d . . .
H2 H 0.9610 0.2152 0.1241 0.057 Uiso 1 1 calc R . .
C3 C 0.9077(6) 0.1942(6) 0.0382(2) 0.0415(14) Uani 1 1 d . . .
H3 H 0.9869 0.2340 0.0280 0.050 Uiso 1 1 calc R . .
C4 C 0.7435(7) 0.2408(6) 0.1785(3) 0.0536(19) Uani 1 1 d . . .
C5 C 0.8841(7) 0.3153(7) 0.2076(4) 0.066(2) Uani 1 1 d . . .
H5A H 0.8999 0.3949 0.2208 0.099 Uiso 1 1 calc R . .
H5B H 0.9356 0.3215 0.1810 0.099 Uiso 1 1 calc R . .
H5C H 0.9087 0.2779 0.2401 0.099 Uiso 1 1 calc R . .
C6 C 0.7036(15) 0.3057(10) 0.1305(4) 0.153(7) Uani 1 1 d . . .
H6A H 0.7310 0.3878 0.1455 0.229 Uiso 1 1 calc R . .
H6B H 0.6097 0.2644 0.1152 0.229 Uiso 1 1 calc R . .
H6C H 0.7449 0.3063 0.1004 0.229 Uiso 1 1 calc R . .
C7 C 0.6672(9) 0.2248(9) 0.2206(5) 0.107(4) Uani 1 1 d . . .
H7A H 0.6926 0.1834 0.2510 0.161 Uiso 1 1 calc R . .
H7B H 0.5751 0.1777 0.2019 0.161 Uiso 1 1 calc R . .
H7C H 0.6838 0.3029 0.2367 0.161 Uiso 1 1 calc R . .
C8 C 0.7606(6) -0.0034(6) 0.1835(2) 0.0411(14) Uani 1 1 d . . .
C9 C 0.6992(12) -0.0391(12) 0.2321(4) 0.114(5) Uani 1 1 d . . .
H9A H 0.6053 -0.0731 0.2177 0.170 Uiso 1 1 calc R . .
H9B H 0.7316 0.0310 0.2596 0.170 Uiso 1 1 calc R . .
H9C H 0.7207 -0.0985 0.2505 0.170 Uiso 1 1 calc R . .
C10 C 0.7176(7) -0.1113(6) 0.1413(3) 0.0567(19) Uani 1 1 d . . .
H10A H 0.7460 -0.1665 0.1600 0.085 Uiso 1 1 calc R . .
H10B H 0.7558 -0.0855 0.1094 0.085 Uiso 1 1 calc R . .
H10C H 0.6233 -0.1513 0.1274 0.085 Uiso 1 1 calc R . .
C11 C 0.9078(8) 0.0546(8) 0.2061(4) 0.084(3) Uani 1 1 d . . .
H11A H 0.9377 0.1262 0.2323 0.126 Uiso 1 1 calc R . .
H11B H 0.9475 0.0764 0.1745 0.126 Uiso 1 1 calc R . .
H11C H 0.9322 -0.0018 0.2261 0.126 Uiso 1 1 calc R . .
C12 C 0.1784(6) -0.0271(5) 0.0898(2) 0.0348(12) Uani 1 1 d . . .
C13 C 0.2401(7) 0.0865(5) 0.0614(3) 0.0468(15) Uani 1 1 d . . .
H13A H 0.2095 0.0666 0.0202 0.070 Uiso 1 1 calc R . .
H13B H 0.3342 0.1196 0.0731 0.070 Uiso 1 1 calc R . .
H13C H 0.2157 0.1452 0.0730 0.070 Uiso 1 1 calc R . .
C14 C 0.0318(6) -0.0810(6) 0.0703(3) 0.0478(16) Uani 1 1 d . . .
H14A H -0.0069 -0.1498 0.0904 0.072 Uiso 1 1 calc R . .
H14B H 0.0026 -0.1066 0.0295 0.072 Uiso 1 1 calc R . .
H14C H 0.0056 -0.0214 0.0786 0.072 Uiso 1 1 calc R . .
C15 C 0.2220(6) 0.0049(6) 0.1545(2) 0.0438(15) Uani 1 1 d . . .
H15A H 0.1973 0.0643 0.1648 0.066 Uiso 1 1 calc R . .
H15B H 0.3159 0.0375 0.1676 0.066 Uiso 1 1 calc R . .
H15C H 0.1806 -0.0668 0.1724 0.066 Uiso 1 1 calc R . .
C16 C 0.1852(7) -0.2763(5) 0.0901(2) 0.0421(14) Uani 1 1 d . . .
C17 C 0.0390(8) -0.3468(7) 0.0790(3) 0.065(2) Uani 1 1 d . . .
H17A H 0.0158 -0.4277 0.0888 0.098 Uiso 1 1 calc R . .
H17B H -0.0016 -0.3506 0.0389 0.098 Uiso 1 1 calc R . .
H17C H 0.0090 -0.3076 0.1022 0.098 Uiso 1 1 calc R . .
C18 C 0.2438(8) -0.2696(6) 0.1538(3) 0.0575(19) Uani 1 1 d . . .
H18A H 0.2149 -0.2265 0.1754 0.086 Uiso 1 1 calc R . .
H18B H 0.3381 -0.2279 0.1621 0.086 Uiso 1 1 calc R . .
H18C H 0.2157 -0.3504 0.1644 0.086 Uiso 1 1 calc R . .
C19 C 0.2368(9) -0.3369(7) 0.0558(3) 0.067(2) Uani 1 1 d . . .
H19A H 0.2157 -0.4166 0.0668 0.101 Uiso 1 1 calc R . .
H19B H 0.3307 -0.2895 0.0635 0.101 Uiso 1 1 calc R . .
H19C H 0.1971 -0.3432 0.0154 0.101 Uiso 1 1 calc R . .
C20 C 0.5207(4) 0.3491(3) 0.49590(16) 0.0130(7) Uani 1 1 d . . .
C21 C 0.5053(4) 0.1764(4) 0.46418(19) 0.0226(9) Uani 1 1 d . . .
H21 H 0.4781 0.1048 0.4409 0.027 Uiso 1 1 calc R . .
C22 C 0.5948(4) 0.2164(4) 0.5133(2) 0.0247(10) Uani 1 1 d . . .
H22 H 0.6432 0.1783 0.5314 0.030 Uiso 1 1 calc R . .
C23 C 0.3725(6) 0.2167(5) 0.3311(2) 0.0331(12) Uani 1 1 d . . .
C24 C 0.5051(7) 0.3183(7) 0.3353(3) 0.0588(19) Uani 1 1 d . . .
H24A H 0.5681 0.3117 0.3668 0.088 Uiso 1 1 calc R . .
H24B H 0.5044 0.3942 0.3419 0.088 Uiso 1 1 calc R . .
H24C H 0.5286 0.3150 0.2999 0.088 Uiso 1 1 calc R . .
C25 C 0.2744(7) 0.2271(6) 0.2812(2) 0.0466(15) Uani 1 1 d . . .
H25A H 0.2698 0.3008 0.2886 0.070 Uiso 1 1 calc R . .
H25B H 0.1892 0.1588 0.2767 0.070 Uiso 1 1 calc R . .
H25C H 0.3017 0.2285 0.2464 0.070 Uiso 1 1 calc R . .
C26 C 0.3686(10) 0.0964(7) 0.3197(3) 0.078(3) Uani 1 1 d . . .
H26A H 0.3927 0.0932 0.2845 0.117 Uiso 1 1 calc R . .
H26B H 0.2812 0.0324 0.3163 0.117 Uiso 1 1 calc R . .
H26C H 0.4294 0.0867 0.3511 0.117 Uiso 1 1 calc R . .
C27 C 0.1874(5) 0.1153(4) 0.4118(2) 0.0276(10) Uani 1 1 d . . .
C28 C 0.1751(6) 0.1593(6) 0.4670(3) 0.0503(17) Uani 1 1 d . . .
H28A H 0.1678 0.2328 0.4626 0.075 Uiso 1 1 calc R . .
H28B H 0.2516 0.1749 0.4975 0.075 Uiso 1 1 calc R . .
H28C H 0.0980 0.0985 0.4762 0.075 Uiso 1 1 calc R . .
C29 C 0.0681(5) 0.0926(5) 0.3643(3) 0.0419(14) Uani 1 1 d . . .
H29A H -0.0098 0.0442 0.3766 0.063 Uiso 1 1 calc R . .
H29B H 0.0671 0.0504 0.3305 0.063 Uiso 1 1 calc R . .
H29C H 0.0706 0.1688 0.3554 0.063 Uiso 1 1 calc R . .
C30 C 0.1977(6) -0.0005(5) 0.4182(4) 0.062(2) Uani 1 1 d . . .
H30A H 0.2729 0.0138 0.4493 0.093 Uiso 1 1 calc R . .
H30B H 0.2071 -0.0277 0.3829 0.093 Uiso 1 1 calc R . .
H30C H 0.1194 -0.0616 0.4266 0.093 Uiso 1 1 calc R . .
C31 C 0.6352(6) 0.3186(4) 0.6523(2) 0.0366(13) Uani 1 1 d . . .
C32 C 0.6421(11) 0.2010(6) 0.6554(3) 0.083(3) Uani 1 1 d . . .
H32A H 0.7325 0.2174 0.6652 0.125 Uiso 1 1 calc R . .
H32B H 0.5967 0.1518 0.6187 0.125 Uiso 1 1 calc R . .
H32C H 0.6014 0.1586 0.6845 0.125 Uiso 1 1 calc R . .
C33 C 0.4952(6) 0.2953(6) 0.6381(3) 0.059(2) Uani 1 1 d . . .
H33A H 0.4547 0.2528 0.6672 0.089 Uiso 1 1 calc R . .
H33B H 0.4484 0.2469 0.6012 0.089 Uiso 1 1 calc R . .
H33C H 0.4924 0.3713 0.6368 0.089 Uiso 1 1 calc R . .
C34 C 0.7059(7) 0.3937(6) 0.7104(2) 0.0454(15) Uani 1 1 d . . .
H34A H 0.6572 0.3559 0.7380 0.068 Uiso 1 1 calc R . .
H34B H 0.7135 0.4736 0.7077 0.068 Uiso 1 1 calc R . .
H34C H 0.7922 0.3995 0.7227 0.068 Uiso 1 1 calc R . .
C35 C 0.8706(5) 0.4404(5) 0.5971(2) 0.0361(13) Uani 1 1 d . . .
C36 C 0.9614(5) 0.5191(5) 0.6522(2) 0.0387(13) Uani 1 1 d . . .
H36A H 1.0505 0.5548 0.6493 0.058 Uiso 1 1 calc R . .
H36B H 0.9528 0.4708 0.6837 0.058 Uiso 1 1 calc R . .
H36C H 0.9390 0.5823 0.6591 0.058 Uiso 1 1 calc R . .
C37 C 0.8979(6) 0.5106(8) 0.5477(3) 0.068(2) Uani 1 1 d . . .
H37A H 0.8808 0.5785 0.5510 0.102 Uiso 1 1 calc R . .
H37B H 0.8422 0.4593 0.5122 0.102 Uiso 1 1 calc R . .
H37C H 0.9885 0.5394 0.5479 0.102 Uiso 1 1 calc R . .
C38 C 0.8933(7) 0.3317(7) 0.5924(6) 0.118(5) Uani 1 1 d . . .
H38A H 0.8514 0.2898 0.5539 0.177 Uiso 1 1 calc R . .
H38B H 0.8569 0.2781 0.6195 0.177 Uiso 1 1 calc R . .
H38C H 0.9862 0.3578 0.6009 0.177 Uiso 1 1 calc R . .
C39 C 0.3983(7) 0.4547(7) 0.1555(3) 0.0571(18) Uani 1 1 d . . .
C40 C 0.1963(10) 0.3670(7) 0.7598(4) 0.087(3) Uani 1 1 d . . .
C41 C 0.8213(10) 0.1953(9) 0.4219(5) 0.0326(16) Uani 0.50 1 d P A 1
C41B C 0.7557(10) 0.1661(9) 0.3824(5) 0.0326(16) Uani 0.50 1 d P A 2
C42 C 0.7810(6) 0.6485(6) 0.4113(3) 0.0435(14) Uani 1 1 d . . .
C43 C 0.8440(11) 0.7624(7) 0.3939(6) 0.122(5) Uani 1 1 d . . .
H43A H 0.7801 0.7797 0.3683 0.184 Uiso 1 1 calc R . .
H43B H 0.9067 0.7638 0.3743 0.184 Uiso 1 1 calc R . .
H43C H 0.8888 0.8227 0.4272 0.184 Uiso 1 1 calc R . .
C44 C 0.5904(9) 0.6749(8) 0.0223(4) 0.068(2) Uani 1 1 d . . .
C45 C 0.6742(9) 0.6222(9) 0.0453(4) 0.083(3) Uani 1 1 d . . .
H45A H 0.6223 0.5421 0.0542 0.125 Uiso 1 1 calc R . .
H45B H 0.7380 0.6717 0.0799 0.125 Uiso 1 1 calc R . .
H45C H 0.7187 0.6175 0.0174 0.125 Uiso 1 1 calc R . .
N1 N 0.7615(5) 0.1207(4) 0.08644(17) 0.0372(11) Uani 1 1 d . . .
N2 N 0.7837(4) 0.1349(4) 0.00059(17) 0.0315(10) Uani 1 1 d . . .
N3 N 0.4582(3) 0.2589(3) 0.45300(15) 0.0175(7) Uani 1 1 d . . .
N4 N 0.6054(4) 0.3246(3) 0.53368(16) 0.0206(8) Uani 1 1 d . . .
N5 N 0.7302(9) 0.5604(7) 0.4257(3) 0.088(2) Uani 1 1 d . . .
N6 N 0.5236(9) 0.7138(8) 0.0044(4) 0.094(3) Uani 1 1 d . . .
O1 O 0.1787(5) 0.4437(4) 0.1517(2) 0.0599(13) Uani 1 1 d . . .
O2 O 0.2057(5) 0.3668(4) 0.06883(19) 0.0528(12) Uani 1 1 d . . .
O3 O 0.1889(5) 0.2600(4) 0.1501(2) 0.0613(14) Uani 1 1 d . . .
O4 O -0.0230(11) 0.3348(11) 0.7623(3) 0.170(5) Uani 1 1 d . . .
O5 O 0.0557(7) 0.2114(6) 0.8134(3) 0.0867(19) Uani 1 1 d . . .
O6 O -0.0059(6) 0.1806(6) 0.7126(3) 0.104(3) Uani 1 1 d . . .
O7 O 0.7749(5) -0.0237(4) 0.4088(3) 0.0672(16) Uani 1 1 d . . .
O8 O 0.6393(5) 0.0274(4) 0.4481(2) 0.0514(12) Uani 1 1 d . . .
O9 O 0.6408(9) 0.0297(8) 0.3455(4) 0.0503(16) Uani 0.50 1 d P A 1
O9B O 0.8919(9) 0.1443(9) 0.4738(4) 0.0503(16) Uani 0.50 1 d P A 2
F1 F 0.4523(6) 0.3968(6) 0.1379(3) 0.117(2) Uani 1 1 d . . .
F2 F 0.4343(5) 0.4697(5) 0.21190(19) 0.0830(15) Uani 1 1 d . . .
F3 F 0.4450(4) 0.5602(5) 0.1393(2) 0.0927(18) Uani 1 1 d . . .
F4 F 0.2661(5) 0.3152(6) 0.7551(4) 0.141(3) Uani 1 1 d . . .
F5 F 0.1950(7) 0.4294(5) 0.7169(3) 0.121(2) Uani 1 1 d . . .
F6 F 0.2579(11) 0.4417(6) 0.8052(3) 0.227(6) Uani 1 1 d . . .
F7 F 0.7636(4) 0.2643(3) 0.4094(2) 0.0583(11) Uani 1 1 d . . .
F8 F 0.9038(7) 0.2259(7) 0.3898(4) 0.0516(10) Uani 0.50 1 d P A 1
F9 F 0.8885(7) 0.2194(7) 0.4753(3) 0.0516(10) Uani 0.50 1 d P A 1
F8B F 0.8534(7) 0.2020(7) 0.3570(4) 0.0516(10) Uani 0.50 1 d P A 2
F9B F 0.6438(7) 0.1103(7) 0.3420(3) 0.0516(10) Uani 0.50 1 d P A 2
P1 P 0.69443(14) 0.09012(14) 0.14397(5) 0.0334(3) Uani 1 1 d . . .
P2 P 0.25072(14) -0.12082(12) 0.07367(5) 0.0293(3) Uani 1 1 d . . .
P3 P 0.32885(11) 0.24100(9) 0.39622(4) 0.0173(2) Uani 1 1 d . . .
P4 P 0.70527(11) 0.40998(10) 0.59862(5) 0.0215(2) Uani 1 1 d . . .
S1 S 0.22452(15) 0.37252(11) 0.12873(6) 0.0375(3) Uani 1 1 d . . .
S2 S 0.0351(2) 0.2599(2) 0.76159(7) 0.0619(5) Uani 1 1 d . . .
S3 S 0.7024(2) 0.0374(2) 0.40430(11) 0.0265(3) Uani 0.50 1 d P A 1
S3B S 0.7690(2) 0.0674(2) 0.43397(11) 0.0265(3) Uani 0.50 1 d P A 2
Au1 Au 0.5000 0.0000 0.0000 0.02885(6) Uani 1 2 d S . .
Au2 Au 0.47283(2) -0.01731(2) 0.108925(8) 0.03558(6) Uani 1 1 d . . .
Au3 Au 0.5000 0.5000 0.5000 0.01436(5) Uani 1 2 d S . .
Au4 Au 0.311031(16) 0.415082(13) 0.398620(7) 0.01756(4) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 C1 N1 108.9(4) . .
N2 C1 Au1 127.8(3) . .
N1 C1 Au1 123.3(4) . .
C3 C2 N1 108.2(5) . .
C3 C2 H2 125.9 . .
N1 C2 H2 125.9 . .
C2 C3 N2 107.3(6) . .
C2 C3 H3 126.3 . .
N2 C3 H3 126.3 . .
C7 C4 C5 108.8(6) . .
C7 C4 C6 109.7(9) . .
C5 C4 C6 108.9(9) . .
C7 C4 P1 107.4(6) . .
C5 C4 P1 116.7(5) . .
C6 C4 P1 105.2(4) . .
C4 C5 H5A 109.5 . .
C4 C5 H5B 109.5 . .
H5A C5 H5B 109.5 . .
C4 C5 H5C 109.5 . .
H5A C5 H5C 109.5 . .
H5B C5 H5C 109.5 . .
C4 C6 H6A 109.5 . .
C4 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C4 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C4 C7 H7A 109.5 . .
C4 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C4 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C9 C8 C10 110.9(8) . .
C9 C8 C11 109.5(7) . .
C10 C8 C11 108.3(6) . .
C9 C8 P1 106.8(5) . .
C10 C8 P1 105.2(4) . .
C11 C8 P1 116.1(5) . .
C8 C9 H9A 109.5 . .
C8 C9 H9B 109.5 . .
H9A C9 H9B 109.5 . .
C8 C9 H9C 109.5 . .
H9A C9 H9C 109.5 . .
H9B C9 H9C 109.5 . .
C8 C10 H10A 109.5 . .
C8 C10 H10B 109.5 . .
H10A C10 H10B 109.5 . .
C8 C10 H10C 109.5 . .
H10A C10 H10C 109.5 . .
H10B C10 H10C 109.5 . .
C8 C11 H11A 109.5 . .
C8 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C8 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C14 C12 C15 108.8(5) . .
C14 C12 C13 109.7(5) . .
C15 C12 C13 109.5(5) . .
C14 C12 P2 117.0(4) . .
C15 C12 P2 106.3(4) . .
C13 C12 P2 105.3(4) . .
C12 C13 H13A 109.5 . .
C12 C13 H13B 109.5 . .
H13A C13 H13B 109.5 . .
C12 C13 H13C 109.5 . .
H13A C13 H13C 109.5 . .
H13B C13 H13C 109.5 . .
C12 C14 H14A 109.5 . .
C12 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C12 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C12 C15 H15A 109.5 . .
C12 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C12 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C17 C16 C18 107.4(6) . .
C17 C16 C19 111.1(6) . .
C18 C16 C19 109.8(5) . .
C17 C16 P2 116.8(4) . .
C18 C16 P2 106.1(4) . .
C19 C16 P2 105.4(5) . .
C16 C17 H17A 109.5 . .
C16 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C16 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C16 C18 H18A 109.5 . .
C16 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C16 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C16 C19 H19A 109.5 . .
C16 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C16 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
N3 C20 N4 107.3(3) . .
N3 C20 Au3 126.2(3) . .
N4 C20 Au3 126.4(3) . .
C22 C21 N3 107.6(4) . .
C22 C21 H21 126.2 . .
N3 C21 H21 126.2 . .
C21 C22 N4 107.9(4) . .
C21 C22 H22 126.0 . .
N4 C22 H22 126.0 . .
C24 C23 C26 111.2(6) . .
C24 C23 C25 109.1(5) . .
C26 C23 C25 107.5(5) . .
C24 C23 P3 106.2(4) . .
C26 C23 P3 116.4(4) . .
C25 C23 P3 106.3(4) . .
C23 C24 H24A 109.5 . .
C23 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C23 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C23 C25 H25A 109.5 . .
C23 C25 H25B 109.5 . .
H25A C25 H25B 109.5 . .
C23 C25 H25C 109.5 . .
H25A C25 H25C 109.5 . .
H25B C25 H25C 109.5 . .
C23 C26 H26A 109.5 . .
C23 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C23 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C28 C27 C29 108.9(5) . .
C28 C27 C30 109.7(5) . .
C29 C27 C30 109.7(4) . .
C28 C27 P3 105.4(3) . .
C29 C27 P3 107.9(4) . .
C30 C27 P3 115.0(4) . .
C27 C28 H28A 109.5 . .
C27 C28 H28B 109.5 . .
H28A C28 H28B 109.5 . .
C27 C28 H28C 109.5 . .
H28A C28 H28C 109.5 . .
H28B C28 H28C 109.5 . .
C27 C29 H29A 109.5 . .
C27 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
C27 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
C27 C30 H30A 109.5 . .
C27 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
C27 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
C33 C31 C32 110.4(6) . .
C33 C31 C34 108.5(5) . .
C32 C31 C34 108.5(5) . .
C33 C31 P4 105.7(4) . .
C32 C31 P4 115.6(5) . .
C34 C31 P4 107.9(4) . .
C31 C32 H32A 109.5 . .
C31 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C31 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C31 C33 H33A 109.5 . .
C31 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
C31 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
C31 C34 H34A 109.5 . .
C31 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
C31 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
C37 C35 C36 109.3(5) . .
C37 C35 C38 110.7(7) . .
C36 C35 C38 108.2(5) . .
C37 C35 P4 105.5(4) . .
C36 C35 P4 106.4(4) . .
C38 C35 P4 116.4(5) . .
C35 C36 H36A 109.5 . .
C35 C36 H36B 109.5 . .
H36A C36 H36B 109.5 . .
C35 C36 H36C 109.5 . .
H36A C36 H36C 109.5 . .
H36B C36 H36C 109.5 . .
C35 C37 H37A 109.5 . .
C35 C37 H37B 109.5 . .
H37A C37 H37B 109.5 . .
C35 C37 H37C 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
C35 C38 H38A 109.5 . .
C35 C38 H38B 109.5 . .
H38A C38 H38B 109.5 . .
C35 C38 H38C 109.5 . .
H38A C38 H38C 109.5 . .
H38B C38 H38C 109.5 . .
F3 C39 F1 108.4(7) . .
F3 C39 F2 106.9(6) . .
F1 C39 F2 107.7(7) . .
F3 C39 S1 112.2(5) . .
F1 C39 S1 110.0(6) . .
F2 C39 S1 111.5(6) . .
F6 C40 F4 106.2(10) . .
F6 C40 F5 107.1(7) . .
F4 C40 F5 107.4(10) . .
F6 C40 S2 112.6(10) . .
F4 C40 S2 111.6(5) . .
F5 C40 S2 111.7(7) . .
F9 C41 F8 107.9(9) . .
F9 C41 F7 111.6(9) . .
F8 C41 F7 104.2(9) . .
F9 C41 S3 111.4(8) . .
F8 C41 S3 111.0(8) . .
F7 C41 S3 110.5(7) . .
F9B C41B F8B 108.1(10) . .
F9B C41B F7 110.4(8) . .
F8B C41B F7 108.3(8) . .
F9B C41B S3B 110.5(7) . .
F8B C41B S3B 110.5(7) . .
F7 C41B S3B 109.0(7) . .
N5 C42 C43 178.2(9) . .
C42 C43 H43A 109.5 . .
C42 C43 H43B 109.5 . .
H43A C43 H43B 109.5 . .
C42 C43 H43C 109.5 . .
H43A C43 H43C 109.5 . .
H43B C43 H43C 109.5 . .
N6 C44 C45 178.8(10) . .
C44 C45 H45A 109.5 . .
C44 C45 H45B 109.5 . .
H45A C45 H45B 109.5 . .
C44 C45 H45C 109.5 . .
H45A C45 H45C 109.5 . .
H45B C45 H45C 109.5 . .
C1 N1 C2 106.8(5) . .
C1 N1 P1 127.9(4) . .
C2 N1 P1 125.1(3) . .
C1 N2 C3 108.8(4) . .
C1 N2 P2 125.7(3) . 2_655
C3 N2 P2 125.5(4) . 2_655
C20 N3 C21 108.8(3) . .
C20 N3 P3 125.5(3) . .
C21 N3 P3 125.4(3) . .
C20 N4 C22 108.4(3) . .
C20 N4 P4 125.8(3) . .
C22 N4 P4 125.8(3) . .
C41 F7 C41B 45.1(6) . .
N1 P1 C4 103.2(3) . .
N1 P1 C8 104.3(3) . .
C4 P1 C8 118.3(3) . .
N1 P1 Au2 107.77(15) . .
C4 P1 Au2 111.6(2) . .
C8 P1 Au2 110.6(2) . .
N2 P2 C16 104.0(2) 2_655 .
N2 P2 C12 103.3(2) 2_655 .
C16 P2 C12 119.8(3) . .
N2 P2 Au2 107.53(17) 2_655 .
C16 P2 Au2 111.8(2) . .
C12 P2 Au2 109.34(19) . .
N3 P3 C27 103.7(2) . .
N3 P3 C23 105.9(2) . .
C27 P3 C23 116.8(2) . .
N3 P3 Au4 107.76(11) . .
C27 P3 Au4 111.12(16) . .
C23 P3 Au4 110.82(17) . .
N4 P4 C31 104.4(2) . .
N4 P4 C35 104.9(2) . .
C31 P4 C35 117.9(3) . .
N4 P4 Au4 107.46(12) . 2_666
C31 P4 Au4 110.51(18) . 2_666
C35 P4 Au4 110.87(17) . 2_666
O1 S1 O2 114.7(3) . .
O1 S1 O3 113.6(3) . .
O2 S1 O3 114.5(3) . .
O1 S1 C39 104.1(3) . .
O2 S1 C39 103.0(3) . .
O3 S1 C39 105.2(3) . .
O6 S2 O4 118.1(6) . .
O6 S2 O5 114.5(5) . .
O4 S2 O5 114.3(4) . .
O6 S2 C40 102.5(4) . .
O4 S2 C40 101.0(6) . .
O5 S2 C40 103.3(4) . .
O7 S3 O8 115.6(3) . .
O7 S3 O9 108.6(5) . .
O8 S3 O9 122.9(5) . .
O7 S3 C41 105.2(4) . .
O8 S3 C41 98.6(4) . .
O9 S3 C41 102.9(6) . .
O7 S3B O9B 110.4(5) . .
O7 S3B O8 111.8(3) . .
O9B S3B O8 122.7(5) . .
O7 S3B C41B 109.4(5) . .
O9B S3B C41B 101.8(5) . .
O8 S3B C41B 98.8(4) . .
C1 Au1 C1 180.00(19) . 2_655
C1 Au1 Au2 91.10(13) . .
C1 Au1 Au2 88.90(13) 2_655 .
C1 Au1 Au2 88.90(13) . 2_655
C1 Au1 Au2 91.10(13) 2_655 2_655
Au2 Au1 Au2 180.000(19) . 2_655
P1 Au2 P2 178.69(5) . .
P1 Au2 Au1 89.80(4) . .
P2 Au2 Au1 90.09(3) . .
C20 Au3 C20 180.000(2) 2_666 .
C20 Au3 Au4 90.14(10) 2_666 2_666
C20 Au3 Au4 89.86(10) . 2_666
C20 Au3 Au4 89.86(10) 2_666 .
C20 Au3 Au4 90.14(10) . .
Au4 Au3 Au4 180.0 2_666 .
P3 Au4 P4 179.59(4) . 2_666
P3 Au4 Au3 89.65(3) . .
P4 Au4 Au3 89.99(3) 2_666 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 N2 1.307(7) .
C1 N1 1.369(5) .
C1 Au1 2.068(5) .
C2 C3 1.322(8) .
C2 N1 1.399(8) .
C2 H2 0.9500 .
C3 N2 1.408(7) .
C3 H3 0.9500 .
C4 C7 1.491(11) .
C4 C5 1.503(10) .
C4 C6 1.544(11) .
C4 P1 1.861(6) .
C5 H5A 0.9800 .
C5 H5B 0.9800 .
C5 H5C 0.9800 .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C6 H6C 0.9800 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 C9 1.510(10) .
C8 C10 1.522(8) .
C8 C11 1.534(9) .
C8 P1 1.863(6) .
C9 H9A 0.9800 .
C9 H9B 0.9800 .
C9 H9C 0.9800 .
C10 H10A 0.9800 .
C10 H10B 0.9800 .
C10 H10C 0.9800 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 C14 1.525(8) .
C12 C15 1.540(7) .
C12 C13 1.544(9) .
C12 P2 1.852(5) .
C13 H13A 0.9800 .
C13 H13B 0.9800 .
C13 H13C 0.9800 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 C17 1.525(10) .
C16 C18 1.536(8) .
C16 C19 1.537(9) .
C16 P2 1.849(6) .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 N3 1.353(5) .
C20 N4 1.356(5) .
C20 Au3 2.045(4) .
C21 C22 1.328(6) .
C21 N3 1.398(5) .
C21 H21 0.9500 .
C22 N4 1.401(5) .
C22 H22 0.9500 .
C23 C24 1.512(9) .
C23 C26 1.530(8) .
C23 C25 1.541(8) .
C23 P3 1.857(5) .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 H25A 0.9800 .
C25 H25B 0.9800 .
C25 H25C 0.9800 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 C28 1.526(8) .
C27 C29 1.530(7) .
C27 C30 1.535(7) .
C27 P3 1.854(5) .
C28 H28A 0.9800 .
C28 H28B 0.9800 .
C28 H28C 0.9800 .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 C33 1.526(9) .
C31 C32 1.533(8) .
C31 C34 1.533(7) .
C31 P4 1.850(6) .
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
C33 H33A 0.9800 .
C33 H33B 0.9800 .
C33 H33C 0.9800 .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
C35 C37 1.512(10) .
C35 C36 1.529(7) .
C35 C38 1.532(8) .
C35 P4 1.859(5) .
C36 H36A 0.9800 .
C36 H36B 0.9800 .
C36 H36C 0.9800 .
C37 H37A 0.9800 .
C37 H37B 0.9800 .
C37 H37C 0.9800 .
C38 H38A 0.9800 .
C38 H38B 0.9800 .
C38 H38C 0.9800 .
C39 F3 1.300(9) .
C39 F1 1.309(9) .
C39 F2 1.332(8) .
C39 S1 1.812(8) .
C40 F6 1.287(10) .
C40 F4 1.303(12) .
C40 F5 1.318(10) .
C40 S2 1.809(11) .
C41 F9 1.318(13) .
C41 F8 1.331(13) .
C41 F7 1.340(11) .
C41 S3 1.835(11) .
C41B F9B 1.344(13) .
C41B F8B 1.355(13) .
C41B F7 1.365(11) .
C41B S3B 1.810(11) .
C42 N5 1.110(9) .
C42 C43 1.416(10) .
C43 H43A 0.9800 .
C43 H43B 0.9800 .
C43 H43C 0.9800 .
C44 N6 1.130(12) .
C44 C45 1.459(14) .
C45 H45A 0.9800 .
C45 H45B 0.9800 .
C45 H45C 0.9800 .
N1 P1 1.743(5) .
N2 P2 1.757(4) 2_655
N3 P3 1.754(4) .
N4 P4 1.753(4) .
O1 S1 1.426(5) .
O2 S1 1.427(5) .
O3 S1 1.431(4) .
O4 S2 1.414(6) .
O5 S2 1.429(6) .
O6 S2 1.402(6) .
O7 S3B 1.347(5) .
O7 S3 1.395(5) .
O8 S3 1.428(5) .
O8 S3B 1.535(5) .
O9 S3 1.436(9) .
O9B S3B 1.453(9) .
P1 Au2 2.3141(15) .
P2 N2 1.757(4) 2_655
P2 Au2 2.3168(14) .
P3 Au4 2.3168(10) .
P4 Au4 2.3183(11) 2_666
Au1 C1 2.068(5) 2_655
Au1 Au2 2.7584(2) .
Au1 Au2 2.7584(2) 2_655
Au3 C20 2.045(4) 2_666
Au3 Au4 2.76278(19) 2_666
Au3 Au4 2.76278(19) .
Au4 P4 2.3183(11) 2_666
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
N1 C2 C3 N2 -0.8(7) . .
N3 C21 C22 N4 -0.1(6) . .
N2 C1 N1 C2 1.1(6) . .
Au1 C1 N1 C2 -179.7(4) . .
N2 C1 N1 P1 178.1(4) . .
Au1 C1 N1 P1 -2.6(6) . .
C3 C2 N1 C1 -0.1(7) . .
C3 C2 N1 P1 -177.3(4) . .
N1 C1 N2 C3 -1.6(6) . .
Au1 C1 N2 C3 179.2(4) . .
N1 C1 N2 P2 179.4(3) . 2_655
Au1 C1 N2 P2 0.2(6) . 2_655
C2 C3 N2 C1 1.5(7) . .
C2 C3 N2 P2 -179.5(4) . 2_655
N4 C20 N3 C21 -0.2(5) . .
Au3 C20 N3 C21 175.8(3) . .
N4 C20 N3 P3 174.2(3) . .
Au3 C20 N3 P3 -9.8(5) . .
C22 C21 N3 C20 0.2(5) . .
C22 C21 N3 P3 -174.2(4) . .
N3 C20 N4 C22 0.1(5) . .
Au3 C20 N4 C22 -175.9(3) . .
N3 C20 N4 P4 -176.9(3) . .
Au3 C20 N4 P4 7.1(6) . .
C21 C22 N4 C20 0.0(6) . .
C21 C22 N4 P4 177.0(4) . .
F9 C41 F7 C41B -169.6(14) . .
F8 C41 F7 C41B 74.2(10) . .
S3 C41 F7 C41B -45.0(8) . .
F9B C41B F7 C41 159.6(14) . .
F8B C41B F7 C41 -82.3(11) . .
S3B C41B F7 C41 38.0(8) . .
C1 N1 P1 C4 -115.0(5) . .
C2 N1 P1 C4 61.6(5) . .
C1 N1 P1 C8 120.8(5) . .
C2 N1 P1 C8 -62.6(6) . .
C1 N1 P1 Au2 3.3(5) . .
C2 N1 P1 Au2 179.8(5) . .
C7 C4 P1 N1 167.7(6) . .
C5 C4 P1 N1 -69.9(6) . .
C6 C4 P1 N1 50.9(8) . .
C7 C4 P1 C8 -77.8(7) . .
C5 C4 P1 C8 44.6(7) . .
C6 C4 P1 C8 165.4(8) . .
C7 C4 P1 Au2 52.3(6) . .
C5 C4 P1 Au2 174.7(5) . .
C6 C4 P1 Au2 -64.6(8) . .
C9 C8 P1 N1 -176.6(6) . .
C10 C8 P1 N1 -58.7(5) . .
C11 C8 P1 N1 61.0(6) . .
C9 C8 P1 C4 69.5(7) . .
C10 C8 P1 C4 -172.5(5) . .
C11 C8 P1 C4 -52.9(7) . .
C9 C8 P1 Au2 -61.0(6) . .
C10 C8 P1 Au2 56.9(5) . .
C11 C8 P1 Au2 176.6(5) . .
C17 C16 P2 N2 -75.3(5) . 2_655
C18 C16 P2 N2 165.1(4) . 2_655
C19 C16 P2 N2 48.7(5) . 2_655
C17 C16 P2 C12 39.2(6) . .
C18 C16 P2 C12 -80.4(5) . .
C19 C16 P2 C12 163.2(4) . .
C17 C16 P2 Au2 169.0(4) . .
C18 C16 P2 Au2 49.4(5) . .
C19 C16 P2 Au2 -67.0(4) . .
C14 C12 P2 N2 66.5(5) . 2_655
C15 C12 P2 N2 -171.8(4) . 2_655
C13 C12 P2 N2 -55.6(4) . 2_655
C14 C12 P2 C16 -48.4(5) . .
C15 C12 P2 C16 73.4(5) . .
C13 C12 P2 C16 -170.5(4) . .
C14 C12 P2 Au2 -179.3(4) . .
C15 C12 P2 Au2 -57.5(4) . .
C13 C12 P2 Au2 58.6(4) . .
C20 N3 P3 C27 -107.2(4) . .
C21 N3 P3 C27 66.2(4) . .
C20 N3 P3 C23 129.3(4) . .
C21 N3 P3 C23 -57.2(4) . .
C20 N3 P3 Au4 10.7(4) . .
C21 N3 P3 Au4 -175.9(3) . .
C28 C27 P3 N3 63.5(4) . .
C29 C27 P3 N3 179.8(3) . .
C30 C27 P3 N3 -57.4(5) . .
C28 C27 P3 C23 179.5(4) . .
C29 C27 P3 C23 -64.2(4) . .
C30 C27 P3 C23 58.6(5) . .
C28 C27 P3 Au4 -52.0(4) . .
C29 C27 P3 Au4 64.3(4) . .
C30 C27 P3 Au4 -173.0(4) . .
C24 C23 P3 N3 -52.4(4) . .
C26 C23 P3 N3 71.9(6) . .
C25 C23 P3 N3 -168.4(4) . .
C24 C23 P3 C27 -167.3(4) . .
C26 C23 P3 C27 -42.9(6) . .
C25 C23 P3 C27 76.7(4) . .
C24 C23 P3 Au4 64.2(4) . .
C26 C23 P3 Au4 -171.5(5) . .
C25 C23 P3 Au4 -51.9(4) . .
C20 N4 P4 C31 108.8(4) . .
C22 N4 P4 C31 -67.7(5) . .
C20 N4 P4 C35 -126.6(4) . .
C22 N4 P4 C35 56.9(5) . .
C20 N4 P4 Au4 -8.6(4) . 2_666
C22 N4 P4 Au4 174.9(4) . 2_666
C33 C31 P4 N4 -56.7(4) . .
C32 C31 P4 N4 65.7(6) . .
C34 C31 P4 N4 -172.6(4) . .
C33 C31 P4 C35 -172.5(4) . .
C32 C31 P4 C35 -50.1(6) . .
C34 C31 P4 C35 71.6(4) . .
C33 C31 P4 Au4 58.5(4) . 2_666
C32 C31 P4 Au4 -179.0(5) . 2_666
C34 C31 P4 Au4 -57.3(4) . 2_666
C37 C35 P4 N4 61.7(4) . .
C36 C35 P4 N4 177.8(4) . .
C38 C35 P4 N4 -61.6(7) . .
C37 C35 P4 C31 177.3(4) . .
C36 C35 P4 C31 -66.6(4) . .
C38 C35 P4 C31 54.0(7) . .
C37 C35 P4 Au4 -54.0(4) . 2_666
C36 C35 P4 Au4 62.1(4) . 2_666
C38 C35 P4 Au4 -177.3(6) . 2_666
F3 C39 S1 O1 -60.2(6) . .
F1 C39 S1 O1 179.0(6) . .
F2 C39 S1 O1 59.5(6) . .
F3 C39 S1 O2 59.8(6) . .
F1 C39 S1 O2 -61.0(6) . .
F2 C39 S1 O2 179.6(5) . .
F3 C39 S1 O3 180.0(6) . .
F1 C39 S1 O3 59.2(7) . .
F2 C39 S1 O3 -60.2(6) . .
F6 C40 S2 O6 -172.7(8) . .
F4 C40 S2 O6 -53.3(8) . .
F5 C40 S2 O6 66.8(8) . .
F6 C40 S2 O4 65.1(8) . .
F4 C40 S2 O4 -175.6(7) . .
F5 C40 S2 O4 -55.4(8) . .
F6 C40 S2 O5 -53.4(8) . .
F4 C40 S2 O5 65.9(8) . .
F5 C40 S2 O5 -173.9(7) . .
S3B O7 S3 O8 -66.1(4) . .
S3B O7 S3 O9 151.0(5) . .
S3B O7 S3 C41 41.5(5) . .
S3B O8 S3 O7 59.8(4) . .
S3B O8 S3 O9 -163.2(6) . .
S3B O8 S3 C41 -51.7(4) . .
F9 C41 S3 O7 -66.3(8) . .
F8 C41 S3 O7 54.0(9) . .
F7 C41 S3 O7 169.1(7) . .
F9 C41 S3 O8 53.4(8) . .
F8 C41 S3 O8 173.7(8) . .
F7 C41 S3 O8 -71.3(8) . .
F9 C41 S3 O9 -179.9(8) . .
F8 C41 S3 O9 -59.6(9) . .
F7 C41 S3 O9 55.4(9) . .
S3 O7 S3B O9B -163.9(5) . .
S3 O7 S3B O8 55.7(3) . .
S3 O7 S3B C41B -52.7(4) . .
S3 O8 S3B O7 -60.4(4) . .
S3 O8 S3B O9B 164.8(6) . .
S3 O8 S3B C41B 54.6(4) . .
F9B C41B S3B O7 64.8(8) . .
F8B C41B S3B O7 -54.7(8) . .
F7 C41B S3B O7 -173.6(6) . .
F9B C41B S3B O9B -178.4(8) . .
F8B C41B S3B O9B 62.1(9) . .
F7 C41B S3B O9B -56.8(8) . .
F9B C41B S3B O8 -52.1(8) . .
F8B C41B S3B O8 -171.7(7) . .
F7 C41B S3B O8 69.4(7) . .
N2 C1 Au1 Au2 179.6(4) . .
N1 C1 Au1 Au2 0.5(4) . .
N2 C1 Au1 Au2 -0.4(4) . 2_655
N1 C1 Au1 Au2 -179.5(4) . 2_655
N1 P1 Au2 Au1 -1.96(17) . .
C4 P1 Au2 Au1 110.7(3) . .
C8 P1 Au2 Au1 -115.38(19) . .
N2 P2 Au2 Au1 0.36(15) 2_655 .
C16 P2 Au2 Au1 113.9(2) . .
C12 P2 Au2 Au1 -111.1(2) . .
C1 Au1 Au2 P1 0.95(12) . .
C1 Au1 Au2 P1 -179.05(12) 2_655 .
C1 Au1 Au2 P2 179.65(12) . .
C1 Au1 Au2 P2 -0.35(12) 2_655 .
N3 C20 Au3 Au4 -176.8(4) . 2_666
N4 C20 Au3 Au4 -1.6(4) . 2_666
N3 C20 Au3 Au4 3.2(4) . .
N4 C20 Au3 Au4 178.4(4) . .
N3 P3 Au4 Au3 -5.95(14) . .
C27 P3 Au4 Au3 107.07(17) . .
C23 P3 Au4 Au3 -121.3(2) . .
C20 Au3 Au4 P3 -177.73(12) 2_666 .
C20 Au3 Au4 P3 2.27(12) . .
C20 Au3 Au4 P4 2.47(12) 2_666 2_666
C20 Au3 Au4 P4 -177.53(12) . 2_666
