#------------------------------------------------------------------------------
#$Date: 2016-03-26 14:59:58 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180283 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/69/7116939.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7116939
loop_
_publ_author_name
'F. Deiser'
'F. Kraus'
'H. Schmidbaur'
_publ_section_title
;
 Bis(triphenylphosphine)silver(I) perrhenate, a cyclic dimer
;
_journal_name_full               Chem.Commun.
_journal_page_first              6746
_journal_paper_doi               10.1039/C5cc01446H
_journal_volume                  51
_journal_year                    2015
_chemical_formula_moiety         'C72 H60 Ag O4 P4 Re'
_chemical_formula_sum            'C72 H60 Ag O4 P4 Re'
_chemical_formula_weight         1407.15
_chemical_melting_point          ?
_chemical_name_common
'Tetrakis triphenylphosphane silver(I) perrhenate(VII)'
_chemical_name_systematic
;
Tetrakis triphenylphosphane silver(I) perrhenate(VII)
;
_space_group_crystal_system      trigonal
_space_group_IT_number           146
_space_group_name_Hall           'R 3'
_space_group_name_H-M_alt        'R 3 :H'
_symmetry_space_group_name_Hall  'R 3'
_symmetry_space_group_name_H-M   'R 3 :H'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2015-03-09 deposited with the CCDC.
2015-03-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                120
_cell_formula_units_Z            6
_cell_length_a                   14.21920(13)
_cell_length_b                   14.21920(13)
_cell_length_c                   51.1145(9)
_cell_measurement_reflns_used    61383
_cell_measurement_temperature    123(2)
_cell_measurement_theta_max      39.3341
_cell_measurement_theta_min      2.8598
_cell_volume                     8950.0(2)
_computing_structure_refinement  'SHELXL-2014 (Sheldrick, 2014)'
_diffrn_ambient_temperature      123(2)
_diffrn_detector_area_resol_mean 16.0238
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.975
_diffrn_measurement_device_type
'Goniometer KM4/Xcalibur, detector: Sapphire3'
_diffrn_measurement_method       ' phi- and omega-rotation '
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'Enhance (Mo) X-ray Source'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0588
_diffrn_reflns_av_unetI/netI     0.0635
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.975
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -23
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -25
_diffrn_reflns_limit_l_max       90
_diffrn_reflns_limit_l_min       -89
_diffrn_reflns_number            204674
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.975
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         39.381
_diffrn_reflns_theta_min         2.865
_exptl_absorpt_coefficient_mu    2.514
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.89770
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlis RED, Oxford Diffraction Ltd.,
Version 1.171.33.34d (release 27-02-2009 CrysAlis171 .NET)
(compiled Feb 27 2009,15:38:38)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.566
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             4236
_exptl_crystal_size_max          0.27
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.17
_refine_diff_density_max         4.270
_refine_diff_density_min         -3.421
_refine_diff_density_rms         0.117
_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.515(10)
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.922
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     496
_refine_ls_number_reflns         22832
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.922
_refine_ls_R_factor_all          0.0954
_refine_ls_R_factor_gt           0.0506
_refine_ls_shift/su_max          0.010
_refine_ls_shift/su_mean         0.002
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0729P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1280
_refine_ls_wR_factor_ref         0.1408
_reflns_Friedel_coverage         1.000
_reflns_Friedel_fraction_full    0.998
_reflns_Friedel_fraction_max     0.975
_reflns_number_gt                12209
_reflns_number_total             22832
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5cc01446h2.cif
_cod_data_source_block           2
_cod_depositor_comments
;
The following automatic conversions were performed:

'_chemical_melting_point' value 'not measured' was changed to '?' -
the value is undefined or not given.

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3105 2015-03-04 15:46:00Z robertas 
;
_cod_database_code               7116939
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelxl_version_number           2014-3
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C1 C 0.1285(8) 0.0978(8) 0.49051(14) 0.0292(18) Uani 1 1 d . . . . .
C2 C 0.2232(9) 0.1067(8) 0.48121(16) 0.040(2) Uani 1 1 d . . . . .
H2 H 0.2210 0.0627 0.4675 0.049 Uiso 1 1 calc R U . . .
C3 C 0.3202(8) 0.1795(8) 0.4920(2) 0.040(2) Uani 1 1 d . . . . .
H3 H 0.3844 0.1899 0.4846 0.048 Uiso 1 1 calc R U . . .
C4 C 0.3235(10) 0.2374(9) 0.5136(2) 0.042(2) Uani 1 1 d . . . . .
H4 H 0.3892 0.2818 0.5220 0.051 Uiso 1 1 calc R U . . .
C5 C 0.2316(10) 0.2299(9) 0.5228(2) 0.050(3) Uani 1 1 d . . . . .
H5 H 0.2358 0.2725 0.5370 0.061 Uiso 1 1 calc R U . . .
C6 C 0.1331(8) 0.1630(8) 0.51217(14) 0.035(2) Uani 1 1 d . . . . .
H6 H 0.0706 0.1598 0.5188 0.042 Uiso 1 1 calc R U . . .
C7 C 0.1821(7) 0.3157(7) 0.41847(15) 0.0268(16) Uani 1 1 d . . . . .
C8 C 0.2131(8) 0.3068(8) 0.44313(18) 0.038(2) Uani 1 1 d . . . . .
H8 H 0.1749 0.2420 0.4523 0.046 Uiso 1 1 calc R U . . .
C9 C 0.3062(8) 0.3991(8) 0.45496(19) 0.040(2) Uani 1 1 d . . . . .
H9 H 0.3295 0.3952 0.4717 0.048 Uiso 1 1 calc R U . . .
C10 C 0.3590(8) 0.4931(8) 0.4402(2) 0.040(2) Uani 1 1 d . . . . .
H10 H 0.4164 0.5546 0.4478 0.048 Uiso 1 1 calc R U . . .
C11 C 0.3299(8) 0.4997(8) 0.41456(18) 0.040(2) Uani 1 1 d . . . . .
H11 H 0.3698 0.5617 0.4045 0.048 Uiso 1 1 calc R U . . .
C12 C 0.2391(8) 0.4097(8) 0.40481(18) 0.040(2) Uani 1 1 d . . . . .
H12 H 0.2156 0.4136 0.3881 0.048 Uiso 1 1 calc R U . . .
C13 C -0.0449(7) 0.2340(7) 0.41538(16) 0.0332(18) Uani 1 1 d . . . . .
C14 C -0.0206(7) 0.3329(7) 0.42663(15) 0.0271(17) Uani 1 1 d . . . . .
H14 H 0.0512 0.3884 0.4281 0.033 Uiso 1 1 calc R U . . .
C15 C -0.1032(8) 0.3479(8) 0.43551(19) 0.040(2) Uani 1 1 d . . . . .
H15 H -0.0860 0.4116 0.4444 0.048 Uiso 1 1 calc R U . . .
C16 C -0.2128(9) 0.2703(10) 0.4316(2) 0.045(3) Uani 1 1 d . . . . .
H16 H -0.2674 0.2845 0.4365 0.054 Uiso 1 1 calc R U . . .
C17 C -0.2373(7) 0.1754(8) 0.4205(2) 0.048(3) Uani 1 1 d . . . . .
H17 H -0.3099 0.1227 0.4184 0.057 Uiso 1 1 calc R U . . .
C18 C -0.1561(6) 0.1530(7) 0.41193(18) 0.0312(18) Uani 1 1 d . . . . .
H18 H -0.1747 0.0867 0.4042 0.037 Uiso 1 1 calc R U . . .
C19 C 0.0741(7) 0.2195(7) 0.37096(14) 0.0271(17) Uani 1 1 d . . . . .
C20 C 0.0447(10) 0.2859(10) 0.35847(17) 0.054(3) Uani 1 1 d . . . . .
H20 H 0.0102 0.3167 0.3676 0.064 Uiso 1 1 calc R U . . .
C21 C 0.0666(13) 0.3063(14) 0.3326(3) 0.088(5) Uani 1 1 d . . . . .
H21 H 0.0538 0.3571 0.3243 0.105 Uiso 1 1 calc R U . . .
C22 C 0.1102(10) 0.2488(12) 0.31775(17) 0.063(3) Uani 1 1 d . . . . .
H22 H 0.1218 0.2595 0.2998 0.075 Uiso 1 1 calc R U . . .
C23 C 0.1320(8) 0.1834(10) 0.32986(18) 0.050(3) Uani 1 1 d . . . . .
H23 H 0.1589 0.1459 0.3204 0.060 Uiso 1 1 calc R U . . .
C24 C 0.1167(7) 0.1663(8) 0.35696(15) 0.0314(18) Uani 1 1 d . . . . .
H24 H 0.1349 0.1197 0.3654 0.038 Uiso 1 1 calc R U . . .
C25 C 0.4300(7) 0.6386(7) 0.52780(14) 0.0248(16) Uani 1 1 d . . . . .
C26 C 0.4409(7) 0.5513(7) 0.53752(14) 0.0291(17) Uani 1 1 d . . . . .
H26 H 0.4015 0.5133 0.5522 0.035 Uiso 1 1 calc R U . . .
C27 C 0.5106(9) 0.5214(8) 0.52532(18) 0.040(2) Uani 1 1 d . . . . .
H27 H 0.5126 0.4601 0.5309 0.048 Uiso 1 1 calc R U . . .
C28 C 0.5765(10) 0.5844(10) 0.5049(2) 0.047(3) Uani 1 1 d . . . . .
H28 H 0.6270 0.5684 0.4977 0.057 Uiso 1 1 calc R U . . .
C29 C 0.5678(9) 0.6714(9) 0.49498(18) 0.045(3) Uani 1 1 d . . . . .
H29 H 0.6095 0.7120 0.4808 0.054 Uiso 1 1 calc R U . . .
C30 C 0.4926(8) 0.6954(9) 0.50735(17) 0.041(2) Uani 1 1 d . . . . .
H30 H 0.4864 0.7534 0.5010 0.049 Uiso 1 1 calc R U . . .
C31 C 0.1534(7) 0.3533(6) 0.59937(15) 0.0231(15) Uani 1 1 d . . . . .
C32 C 0.1173(7) 0.3543(7) 0.57354(14) 0.0277(16) Uani 1 1 d . . . . .
H32 H 0.1548 0.4169 0.5635 0.033 Uiso 1 1 calc R U . . .
C33 C 0.0323(8) 0.2692(8) 0.56340(18) 0.040(2) Uani 1 1 d . . . . .
H33 H 0.0128 0.2737 0.5463 0.048 Uiso 1 1 calc R U . . .
C34 C -0.0288(8) 0.1745(9) 0.5768(2) 0.044(2) Uani 1 1 d . . . . .
H34 H -0.0901 0.1169 0.5693 0.053 Uiso 1 1 calc R U . . .
C35 C 0.0030(9) 0.1674(8) 0.6013(2) 0.047(3) Uani 1 1 d . . . . .
H35 H -0.0347 0.1016 0.6101 0.056 Uiso 1 1 calc R U . . .
C36 C 0.0917(7) 0.2567(6) 0.61421(16) 0.034(2) Uani 1 1 d . . . . .
H36 H 0.1086 0.2519 0.6316 0.041 Uiso 1 1 calc R U . . .
C37 C 0.2674(7) 0.4538(7) 0.64675(15) 0.0272(16) Uani 1 1 d . . . . .
C38 C 0.2220(8) 0.5039(8) 0.66105(17) 0.036(2) Uani 1 1 d . . . . .
H38 H 0.2055 0.5516 0.6525 0.043 Uiso 1 1 calc R U . . .
C39 C 0.2007(9) 0.4859(9) 0.68717(19) 0.046(2) Uani 1 1 d . . . . .
H39 H 0.1707 0.5206 0.6965 0.055 Uiso 1 1 calc R U . . .
C40 C 0.2270(8) 0.4091(11) 0.69989(17) 0.061(3) Uani 1 1 d . . . . .
H40 H 0.2127 0.3943 0.7176 0.073 Uiso 1 1 calc R U . . .
C41 C 0.2694(9) 0.3621(10) 0.68693(12) 0.053(3) Uani 1 1 d . . . . .
H41 H 0.2858 0.3145 0.6956 0.064 Uiso 1 1 calc R U . . .
C42 C 0.2915(8) 0.3807(8) 0.66028(16) 0.042(2) Uani 1 1 d . . . . .
H42 H 0.3219 0.3454 0.6513 0.050 Uiso 1 1 calc R U . . .
C43 C 0.3805(5) 0.4345(6) 0.60276(11) 0.0179(12) Uani 1 1 d . . . . .
C44 C 0.4872(8) 0.5093(7) 0.60703(17) 0.036(2) Uani 1 1 d . . . . .
H44 H 0.5042 0.5733 0.6158 0.043 Uiso 1 1 calc R U . . .
C45 C 0.5682(7) 0.4935(7) 0.59902(15) 0.036(2) Uani 1 1 d . . . . .
H45 H 0.6400 0.5468 0.6019 0.043 Uiso 1 1 calc R U . . .
C46 C 0.5448(7) 0.3965(8) 0.58626(16) 0.033(2) Uani 1 1 d . . . . .
H46 H 0.6010 0.3870 0.5801 0.040 Uiso 1 1 calc R U . . .
C47 C 0.4398(8) 0.3167(8) 0.58298(17) 0.035(2) Uani 1 1 d . . . . .
H47 H 0.4237 0.2502 0.5758 0.042 Uiso 1 1 calc R U . . .
C48 C 0.3553(7) 0.3363(8) 0.59073(15) 0.0295(17) Uani 1 1 d . . . . .
H48 H 0.2831 0.2839 0.5878 0.035 Uiso 1 1 calc R U . . .
O1 O 0.4316(7) 0.6455(7) 0.35936(19) 0.134(3) Uani 1 1 d . . . . .
O2 O 0.3333 0.6667 0.3137(2) 0.201(10) Uani 1 3 d S T P . .
O3A O 0.5432(4) 0.2569(5) 0.53043(11) 0.0754(15) Uani 1 1 d . . . . .
O4A O 0.6667 0.3333 0.4906(8) 0.38(3) Uiso 1 3 d S . P . .
P1 P 0.0000 0.0000 0.47485(7) 0.0289(9) Uani 1 3 d S T P . .
P2 P 0.05700(18) 0.19700(17) 0.40654(4) 0.0223(4) Uani 1 1 d . . . . .
P3 P 0.3333 0.6667 0.54344(6) 0.0214(7) Uani 1 3 d S T P . .
P4 P 0.27718(18) 0.46932(17) 0.61169(4) 0.0211(4) Uani 1 1 d . . . . .
Ag1 Ag 0.0000 0.0000 0.42352(2) 0.0218(2) Uani 1 3 d S T P . .
Ag2 Ag 0.3333 0.6667 0.59474(2) 0.01836(18) Uani 1 3 d S T P . .
Re1 Re 0.3333 0.6667 0.34260(3) 0.06506(12) Uani 1 3 d S T P . .
Re2A Re 0.6667 0.3333 0.50602(5) 0.0633(5) Uani 0.746(6) 3 d S T P . .
Re2B Re 0.6667 0.3333 0.51722(4) 0.0203(6) Uiso 0.254(6) 3 d S . P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Re Re -1.0185 7.2310 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C2 C1 C6 119.1(9) . .
C2 C1 P1 118.5(7) . .
C6 C1 P1 122.4(7) . .
C3 C2 C1 120.3(9) . .
C2 C3 C4 120.2(10) . .
C5 C4 C3 119.7(10) . .
C4 C5 C6 122.8(10) . .
C5 C6 C1 117.6(9) . .
C12 C7 C8 120.4(9) . .
C12 C7 P2 124.0(7) . .
C8 C7 P2 115.5(7) . .
C7 C8 C9 119.6(9) . .
C10 C9 C8 117.1(9) . .
C9 C10 C11 122.8(9) . .
C12 C11 C10 116.8(9) . .
C7 C12 C11 123.2(9) . .
C14 C13 C18 118.8(8) . .
C14 C13 P2 124.1(7) . .
C18 C13 P2 117.0(6) . .
C15 C14 C13 119.6(9) . .
C14 C15 C16 122.1(9) . .
C17 C16 C15 118.7(9) . .
C16 C17 C18 121.9(9) . .
C17 C18 C13 118.7(8) . .
C20 C19 C24 120.3(7) . .
C20 C19 P2 121.5(7) . .
C24 C19 P2 118.2(7) . .
C21 C20 C19 119.2(11) . .
C20 C21 C22 120.2(12) . .
C23 C22 C21 118.7(9) . .
C22 C23 C24 122.0(10) . .
C19 C24 C23 119.3(9) . .
C30 C25 C26 117.9(8) . .
C30 C25 P3 124.1(7) . .
C26 C25 P3 118.0(5) . .
C27 C26 C25 120.8(7) . .
C28 C27 C26 119.3(9) . .
C27 C28 C29 120.9(10) . .
C28 C29 C30 117.5(9) . .
C25 C30 C29 123.4(9) . .
C32 C31 C36 117.0(8) . .
C32 C31 P4 120.2(6) . .
C36 C31 P4 122.7(6) . .
C33 C32 C31 121.8(8) . .
C32 C33 C34 123.2(9) . .
C35 C34 C33 117.8(9) . .
C34 C35 C36 122.8(9) . .
C31 C36 C35 117.1(8) . .
C38 C37 C42 117.5(8) . .
C38 C37 P4 119.3(7) . .
C42 C37 P4 122.7(7) . .
C39 C38 C37 122.5(10) . .
C38 C39 C40 117.1(10) . .
C41 C40 C39 121.2(8) . .
C40 C41 C42 121.7(9) . .
C41 C42 C37 119.9(9) . .
C44 C43 C48 118.6(7) . .
C44 C43 P4 118.6(6) . .
C48 C43 P4 122.7(6) . .
C45 C44 C43 122.1(8) . .
C44 C45 C46 120.2(9) . .
C47 C46 C45 119.9(8) . .
C46 C47 C48 119.1(9) . .
C43 C48 C47 119.9(8) . .
Re2B O3A Re2A 15.36(9) . .
Re2A O4A Re2B 0.000(1) . .
C1 P1 C1 102.4(3) . 3
C1 P1 C1 102.4(3) . 2
C1 P1 C1 102.4(3) 3 2
C1 P1 Ag1 115.8(3) . .
C1 P1 Ag1 115.8(3) 3 .
C1 P1 Ag1 115.8(3) 2 .
C13 P2 C7 101.3(4) . .
C13 P2 C19 104.4(4) . .
C7 P2 C19 100.7(4) . .
C13 P2 Ag1 110.9(3) . .
C7 P2 Ag1 120.5(3) . .
C19 P2 Ag1 116.9(3) . .
C25 P3 C25 101.7(3) . 3_565
C25 P3 C25 101.7(3) . 2_665
C25 P3 C25 101.7(3) 3_565 2_665
C25 P3 Ag2 116.4(2) . .
C25 P3 Ag2 116.4(2) 3_565 .
C25 P3 Ag2 116.4(2) 2_665 .
C37 P4 C31 104.6(4) . .
C37 P4 C43 103.8(4) . .
C31 P4 C43 102.2(3) . .
C37 P4 Ag2 114.8(3) . .
C31 P4 Ag2 119.3(2) . .
C43 P4 Ag2 110.4(2) . .
P1 Ag1 P2 109.16(5) . 2
P1 Ag1 P2 109.16(5) . 3
P2 Ag1 P2 109.78(5) 2 3
P1 Ag1 P2 109.16(5) . .
P2 Ag1 P2 109.78(5) 2 .
P2 Ag1 P2 109.78(5) 3 .
P3 Ag2 P4 109.08(5) . 3_565
P3 Ag2 P4 109.08(5) . .
P4 Ag2 P4 109.86(5) 3_565 .
P3 Ag2 P4 109.08(5) . 2_665
P4 Ag2 P4 109.86(5) 3_565 2_665
P4 Ag2 P4 109.86(5) . 2_665
O2 Re1 O1 118.6(3) . .
O2 Re1 O1 118.6(3) . 3_565
O1 Re1 O1 98.9(4) . 3_565
O2 Re1 O1 118.6(3) . 2_665
O1 Re1 O1 98.9(4) . 2_665
O1 Re1 O1 98.9(4) 3_565 2_665
Re2B Re2A O4A 180.00(3) . .
Re2B Re2A O3A 50.91(18) . 2_655
O4A Re2A O3A 129.09(18) . 2_655
Re2B Re2A O3A 50.91(18) . 3_665
O4A Re2A O3A 129.09(19) . 3_665
O3A Re2A O3A 84.5(3) 2_655 3_665
Re2B Re2A O3A 50.91(19) . .
O4A Re2A O3A 129.09(19) . .
O3A Re2A O3A 84.5(3) 2_655 .
O3A Re2A O3A 84.5(3) 3_665 .
Re2A Re2B O4A 0.000(10) . .
Re2A Re2B O3A 113.7(2) . .
O4A Re2B O3A 113.7(2) . .
Re2A Re2B O3A 113.7(2) . 2_655
O4A Re2B O3A 113.7(2) . 2_655
O3A Re2B O3A 104.9(2) . 2_655
Re2A Re2B O3A 113.7(2) . 3_665
O4A Re2B O3A 113.7(2) . 3_665
O3A Re2B O3A 104.9(2) . 3_665
O3A Re2B O3A 104.9(3) 2_655 3_665
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
C1 C2 1.372(13) .
C1 C6 1.425(11) .
C1 P1 1.836(9) .
C2 C3 1.360(13) .
C3 C4 1.366(14) .
C4 C5 1.340(16) .
C5 C6 1.352(14) .
C7 C12 1.359(13) .
C7 C8 1.362(12) .
C7 P2 1.839(9) .
C8 C9 1.450(12) .
C9 C10 1.384(14) .
C10 C11 1.392(14) .
C11 C12 1.379(13) .
C13 C14 1.393(12) .
C13 C18 1.427(11) .
C13 P2 1.828(9) .
C14 C15 1.373(12) .
C15 C16 1.403(15) .
C16 C17 1.339(14) .
C17 C18 1.413(11) .
C19 C20 1.367(13) .
C19 C24 1.382(12) .
C19 P2 1.842(8) .
C20 C21 1.354(15) .
C21 C22 1.464(18) .
C22 C23 1.278(16) .
C23 C24 1.404(12) .
C25 C30 1.349(11) .
C25 C26 1.416(11) .
C25 P3 1.799(9) .
C26 C27 1.404(12) .
C27 C28 1.390(14) .
C28 C29 1.398(14) .
C29 C30 1.423(12) .
C31 C32 1.419(11) .
C31 C36 1.424(9) .
C31 P4 1.820(9) .
C32 C33 1.316(13) .
C33 C34 1.365(14) .
C34 C35 1.353(15) .
C35 C36 1.427(13) .
C37 C38 1.384(12) .
C37 C42 1.425(11) .
C37 P4 1.803(8) .
C38 C39 1.365(12) .
C39 C40 1.471(16) .
C40 C41 1.285(15) .
C41 C42 1.393(10) .
C43 C44 1.367(12) .
C43 C48 1.398(11) .
C43 P4 1.827(6) .
C44 C45 1.344(12) .
C45 C46 1.406(12) .
C46 C47 1.360(14) .
C47 C48 1.420(12) .
O1 Re1 1.788(8) .
O2 Re1 1.478(12) .
O3A Re2B 1.677(5) .
O3A Re2A 1.978(5) .
O4A Re2A 0.79(4) .
O4A Re2B 1.36(4) .
P1 C1 1.836(9) 3
P1 C1 1.836(9) 2
P1 Ag1 2.624(4) .
P2 Ag1 2.643(2) .
P3 C25 1.799(9) 3_565
P3 C25 1.799(9) 2_665
P3 Ag2 2.622(3) .
P4 Ag2 2.650(2) .
Ag1 P2 2.643(2) 2
Ag1 P2 2.643(2) 3
Ag2 P4 2.650(2) 3_565
Ag2 P4 2.650(2) 2_665
Re1 O1 1.788(8) 3_565
Re1 O1 1.788(8) 2_665
Re2A Re2B 0.572(2) .
Re2A O3A 1.978(5) 2_655
Re2A O3A 1.978(5) 3_665
Re2B O3A 1.677(5) 2_655
Re2B O3A 1.677(5) 3_665
