#------------------------------------------------------------------------------
#$Date: 2016-02-13 14:50:18 +0200 (Sat, 13 Feb 2016) $
#$Revision: 176428 $
#$URL: svn://www.crystallography.net/cod/cif/7/11/72/7117242.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7117242
loop_
_publ_author_name
'Christopher J. Adams'
'Matteo Lusi'
'Emily M. Mutambi'
'A. Guy Orpen'
_publ_section_title
;
 Two-step solid-state synthesis of PEPPSI-type compounds
;
_journal_name_full               Chem.Commun.
_journal_page_first              9632
_journal_paper_doi               10.1039/C5cc02924D
_journal_volume                  51
_journal_year                    2015
_chemical_formula_moiety         'C27 H37 N2, C5 H5 Cl3 N Pt'
_chemical_formula_sum            'C32 H42 Cl3 N3 Pt'
_chemical_formula_weight         770.13
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-04-08 deposited with the CCDC.
2015-05-06 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 115.1620(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.3227(2)
_cell_length_b                   21.1418(5)
_cell_length_c                   18.1068(4)
_cell_measurement_reflns_used    9936
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      27.47
_cell_measurement_theta_min      2.29
_cell_volume                     3230.18(13)
_computing_cell_refinement       'Bruker SMART'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'Bruker SHELXTL'
_computing_structure_solution    'Bruker SHELXTL'
_diffrn_ambient_temperature      100(2)
_diffrn_detector_area_resol_mean 9.091
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0481
_diffrn_reflns_av_sigmaI/netI    0.0222
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       27
_diffrn_reflns_limit_k_min       -27
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            81582
_diffrn_reflns_theta_full        27.57
_diffrn_reflns_theta_max         27.57
_diffrn_reflns_theta_min         1.93
_exptl_absorpt_coefficient_mu    4.617
_exptl_absorpt_correction_T_max  0.892
_exptl_absorpt_correction_T_min  0.756
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            gold
_exptl_crystal_density_diffrn    1.584
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1536
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.13
_exptl_crystal_size_min          0.09
_refine_diff_density_max         2.370
_refine_diff_density_min         -1.140
_refine_diff_density_rms         0.104
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.102
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     360
_refine_ls_number_reflns         7456
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.102
_refine_ls_R_factor_all          0.0340
_refine_ls_R_factor_gt           0.0279
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0168P)²+10.9219P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0615
_refine_ls_wR_factor_ref         0.0640
_reflns_number_gt                6645
_reflns_number_total             7456
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c5cc02924d2.cif
_cod_data_source_block           4c
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3392 2015-05-12 13:50:21Z andrius 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7117242
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt 0.083172(15) 0.858720(6) 0.235881(8) 0.01899(4) Uani 1 1 d . . .
Cl1 Cl -0.10172(12) 0.85099(5) 0.10185(6) 0.0349(2) Uani 1 1 d . . .
Cl2 Cl 0.27494(13) 0.86505(5) 0.36722(6) 0.0362(2) Uani 1 1 d . . .
Cl3 Cl 0.12394(13) 0.96355(5) 0.21686(7) 0.0352(2) Uani 1 1 d . . .
N1 N 0.5487(3) 0.92831(13) 0.19294(17) 0.0168(5) Uani 1 1 d . . .
N2 N 0.6872(3) 0.92729(13) 0.32340(17) 0.0166(5) Uani 1 1 d . . .
N3 N 0.0359(4) 0.76841(17) 0.2519(2) 0.0335(8) Uani 1 1 d . . .
C1 C 0.5402(4) 0.92547(15) 0.2645(2) 0.0170(6) Uani 1 1 d . . .
H1 H 0.4457 0.9227 0.2722 0.020 Uiso 1 1 calc R . .
C2 C 0.7063(4) 0.93177(17) 0.2065(2) 0.0208(7) Uani 1 1 d . . .
H2 H 0.7458 0.9342 0.1661 0.025 Uiso 1 1 calc R . .
C3 C 0.7927(4) 0.93096(17) 0.2878(2) 0.0215(7) Uani 1 1 d . . .
H3 H 0.9050 0.9326 0.3157 0.026 Uiso 1 1 calc R . .
C4 C 0.7294(4) 0.92570(17) 0.4103(2) 0.0188(7) Uani 1 1 d . . .
C5 C 0.7635(4) 0.86717(17) 0.4494(2) 0.0220(7) Uani 1 1 d . . .
C6 C 0.8023(5) 0.8675(2) 0.5330(2) 0.0291(8) Uani 1 1 d . . .
H6 H 0.8261 0.8288 0.5626 0.035 Uiso 1 1 calc R . .
C7 C 0.8063(5) 0.9238(2) 0.5729(2) 0.0349(9) Uani 1 1 d . . .
H7 H 0.8329 0.9232 0.6297 0.042 Uiso 1 1 calc R . .
C8 C 0.7721(5) 0.9811(2) 0.5317(2) 0.0309(9) Uani 1 1 d . . .
H8 H 0.7757 1.0191 0.5605 0.037 Uiso 1 1 calc R . .
C9 C 0.7326(4) 0.98337(18) 0.4486(2) 0.0229(7) Uani 1 1 d . . .
C10 C 0.6906(5) 1.04562(18) 0.4026(2) 0.0271(8) Uani 1 1 d . . .
H10 H 0.6913 1.0389 0.3481 0.032 Uiso 1 1 calc R . .
C11 C 0.8093(5) 1.0974(2) 0.4465(3) 0.0376(10) Uani 1 1 d . . .
H11A H 0.7998 1.1091 0.4966 0.056 Uiso 1 1 calc R . .
H11B H 0.7877 1.1346 0.4109 0.056 Uiso 1 1 calc R . .
H11C H 0.9168 1.0821 0.4602 0.056 Uiso 1 1 calc R . .
C12 C 0.5232(5) 1.0659(2) 0.3885(3) 0.0456(12) Uani 1 1 d . . .
H12A H 0.4472 1.0332 0.3571 0.068 Uiso 1 1 calc R . .
H12B H 0.4965 1.1058 0.3583 0.068 Uiso 1 1 calc R . .
H12C H 0.5189 1.0715 0.4413 0.068 Uiso 1 1 calc R . .
C13 C 0.7598(5) 0.80609(17) 0.4052(2) 0.0252(8) Uani 1 1 d . . .
H13 H 0.7262 0.8164 0.3463 0.030 Uiso 1 1 calc R . .
C14 C 0.6368(6) 0.7604(2) 0.4109(4) 0.0512(13) Uani 1 1 d . . .
H14A H 0.6728 0.7459 0.4674 0.077 Uiso 1 1 calc R . .
H14B H 0.6242 0.7240 0.3752 0.077 Uiso 1 1 calc R . .
H14C H 0.5350 0.7823 0.3939 0.077 Uiso 1 1 calc R . .
C15 C 0.9206(5) 0.7741(2) 0.4363(3) 0.0445(11) Uani 1 1 d . . .
H15A H 0.9970 0.8027 0.4297 0.067 Uiso 1 1 calc R . .
H15B H 0.9120 0.7353 0.4051 0.067 Uiso 1 1 calc R . .
H15C H 0.9566 0.7636 0.4942 0.067 Uiso 1 1 calc R . .
C16 C 0.4107(4) 0.92990(17) 0.1145(2) 0.0185(7) Uani 1 1 d . . .
C17 C 0.3503(4) 0.98920(17) 0.0825(2) 0.0206(7) Uani 1 1 d . . .
C18 C 0.2131(4) 0.99013(18) 0.0099(2) 0.0254(8) Uani 1 1 d . . .
H18 H 0.1677 1.0294 -0.0143 0.030 Uiso 1 1 calc R . .
C19 C 0.1428(4) 0.9343(2) -0.0271(2) 0.0291(8) Uani 1 1 d . . .
H19 H 0.0474 0.9356 -0.0758 0.035 Uiso 1 1 calc R . .
C20 C 0.2083(5) 0.87612(19) 0.0053(2) 0.0274(8) Uani 1 1 d . . .
H20 H 0.1584 0.8384 -0.0221 0.033 Uiso 1 1 calc R . .
C21 C 0.3464(4) 0.87245(17) 0.0774(2) 0.0210(7) Uani 1 1 d . . .
C22 C 0.4235(5) 0.80894(17) 0.1126(2) 0.0248(8) Uani 1 1 d . . .
H22 H 0.5351 0.8176 0.1526 0.030 Uiso 1 1 calc R . .
C23 C 0.3403(6) 0.7767(2) 0.1587(3) 0.0365(10) Uani 1 1 d . . .
H23A H 0.3421 0.8047 0.2023 0.055 Uiso 1 1 calc R . .
H23B H 0.3950 0.7371 0.1826 0.055 Uiso 1 1 calc R . .
H23C H 0.2302 0.7676 0.1210 0.055 Uiso 1 1 calc R . .
C24 C 0.4301(7) 0.7653(2) 0.0470(3) 0.0452(12) Uani 1 1 d . . .
H24A H 0.4920 0.7275 0.0728 0.068 Uiso 1 1 calc R . .
H24B H 0.4802 0.7875 0.0166 0.068 Uiso 1 1 calc R . .
H24C H 0.3223 0.7528 0.0095 0.068 Uiso 1 1 calc R . .
C25 C 0.4283(5) 1.05051(17) 0.1238(2) 0.0251(8) Uani 1 1 d . . .
H25 H 0.5245 1.0397 0.1745 0.030 Uiso 1 1 calc R . .
C26 C 0.3172(6) 1.0895(2) 0.1480(3) 0.0451(12) Uani 1 1 d . . .
H26A H 0.2283 1.1050 0.0988 0.068 Uiso 1 1 calc R . .
H26B H 0.3752 1.1256 0.1814 0.068 Uiso 1 1 calc R . .
H26C H 0.2768 1.0631 0.1794 0.068 Uiso 1 1 calc R . .
C27 C 0.4816(5) 1.0889(2) 0.0681(3) 0.0322(9) Uani 1 1 d . . .
H27A H 0.5552 1.0636 0.0545 0.048 Uiso 1 1 calc R . .
H27B H 0.5346 1.1276 0.0962 0.048 Uiso 1 1 calc R . .
H27C H 0.3889 1.1000 0.0178 0.048 Uiso 1 1 calc R . .
C28 C -0.1165(5) 0.7497(2) 0.2251(3) 0.0375(10) Uani 1 1 d . . .
H28 H -0.1982 0.7798 0.1992 0.045 Uiso 1 1 calc R . .
C29 C -0.1579(6) 0.6883(2) 0.2341(3) 0.0435(11) Uani 1 1 d . . .
H29 H -0.2661 0.6766 0.2152 0.052 Uiso 1 1 calc R . .
C30 C -0.0399(6) 0.6445(2) 0.2708(3) 0.0454(12) Uani 1 1 d . . .
H30 H -0.0650 0.6019 0.2774 0.055 Uiso 1 1 calc R . .
C31 C 0.1169(6) 0.6636(2) 0.2982(3) 0.0466(12) Uani 1 1 d . . .
H31 H 0.2009 0.6343 0.3241 0.056 Uiso 1 1 calc R . .
C32 C 0.1493(5) 0.7270(2) 0.2869(3) 0.0394(10) Uani 1 1 d . . .
H32 H 0.2564 0.7402 0.3053 0.047 Uiso 1 1 calc R . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N3 Pt1 Cl2 91.61(10) . .
N3 Pt1 Cl3 176.91(11) . .
Cl2 Pt1 Cl3 89.62(4) . .
N3 Pt1 Cl1 88.44(10) . .
Cl2 Pt1 Cl1 177.54(4) . .
Cl3 Pt1 Cl1 90.45(4) . .
C1 N1 C2 109.1(3) . .
C1 N1 C16 123.7(3) . .
C2 N1 C16 127.1(3) . .
C1 N2 C3 108.7(3) . .
C1 N2 C4 125.4(3) . .
C3 N2 C4 125.9(3) . .
C32 N3 C28 119.2(4) . .
C32 N3 Pt1 121.5(3) . .
C28 N3 Pt1 119.2(3) . .
N2 C1 N1 108.0(3) . .
N2 C1 H1 126.0 . .
N1 C1 H1 126.0 . .
C3 C2 N1 106.9(3) . .
C3 C2 H2 126.6 . .
N1 C2 H2 126.6 . .
C2 C3 N2 107.2(3) . .
C2 C3 H3 126.4 . .
N2 C3 H3 126.4 . .
C5 C4 C9 124.8(3) . .
C5 C4 N2 118.0(3) . .
C9 C4 N2 117.2(3) . .
C4 C5 C6 116.3(3) . .
C4 C5 C13 122.7(3) . .
C6 C5 C13 120.9(3) . .
C7 C6 C5 120.4(4) . .
C7 C6 H6 119.8 . .
C5 C6 H6 119.8 . .
C6 C7 C8 121.5(4) . .
C6 C7 H7 119.3 . .
C8 C7 H7 119.3 . .
C7 C8 C9 120.5(4) . .
C7 C8 H8 119.8 . .
C9 C8 H8 119.8 . .
C8 C9 C4 116.6(4) . .
C8 C9 C10 120.8(3) . .
C4 C9 C10 122.5(3) . .
C9 C10 C11 112.2(3) . .
C9 C10 C12 109.9(3) . .
C11 C10 C12 110.4(3) . .
C9 C10 H10 108.1 . .
C11 C10 H10 108.1 . .
C12 C10 H10 108.1 . .
C10 C11 H11A 109.5 . .
C10 C11 H11B 109.5 . .
H11A C11 H11B 109.5 . .
C10 C11 H11C 109.5 . .
H11A C11 H11C 109.5 . .
H11B C11 H11C 109.5 . .
C10 C12 H12A 109.5 . .
C10 C12 H12B 109.5 . .
H12A C12 H12B 109.5 . .
C10 C12 H12C 109.5 . .
H12A C12 H12C 109.5 . .
H12B C12 H12C 109.5 . .
C5 C13 C15 112.8(3) . .
C5 C13 C14 110.5(3) . .
C15 C13 C14 110.0(4) . .
C5 C13 H13 107.8 . .
C15 C13 H13 107.8 . .
C14 C13 H13 107.8 . .
C13 C14 H14A 109.5 . .
C13 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
C13 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
C13 C15 H15A 109.5 . .
C13 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C13 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C21 C16 C17 124.6(3) . .
C21 C16 N1 118.1(3) . .
C17 C16 N1 117.3(3) . .
C18 C17 C16 116.9(3) . .
C18 C17 C25 120.6(3) . .
C16 C17 C25 122.6(3) . .
C19 C18 C17 120.2(3) . .
C19 C18 H18 119.9 . .
C17 C18 H18 119.9 . .
C18 C19 C20 121.5(3) . .
C18 C19 H19 119.3 . .
C20 C19 H19 119.3 . .
C19 C20 C21 120.7(4) . .
C19 C20 H20 119.6 . .
C21 C20 H20 119.6 . .
C20 C21 C16 116.1(3) . .
C20 C21 C22 121.6(3) . .
C16 C21 C22 122.3(3) . .
C23 C22 C24 110.8(3) . .
C23 C22 C21 111.3(3) . .
C24 C22 C21 112.0(3) . .
C23 C22 H22 107.5 . .
C24 C22 H22 107.5 . .
C21 C22 H22 107.5 . .
C22 C23 H23A 109.5 . .
C22 C23 H23B 109.5 . .
H23A C23 H23B 109.5 . .
C22 C23 H23C 109.5 . .
H23A C23 H23C 109.5 . .
H23B C23 H23C 109.5 . .
C22 C24 H24A 109.5 . .
C22 C24 H24B 109.5 . .
H24A C24 H24B 109.5 . .
C22 C24 H24C 109.5 . .
H24A C24 H24C 109.5 . .
H24B C24 H24C 109.5 . .
C17 C25 C26 111.1(3) . .
C17 C25 C27 110.5(3) . .
C26 C25 C27 110.6(3) . .
C17 C25 H25 108.2 . .
C26 C25 H25 108.2 . .
C27 C25 H25 108.2 . .
C25 C26 H26A 109.5 . .
C25 C26 H26B 109.5 . .
H26A C26 H26B 109.5 . .
C25 C26 H26C 109.5 . .
H26A C26 H26C 109.5 . .
H26B C26 H26C 109.5 . .
C25 C27 H27A 109.5 . .
C25 C27 H27B 109.5 . .
H27A C27 H27B 109.5 . .
C25 C27 H27C 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
N3 C28 C29 122.4(5) . .
N3 C28 H28 118.8 . .
C29 C28 H28 118.8 . .
C30 C29 C28 118.9(5) . .
C30 C29 H29 120.6 . .
C28 C29 H29 120.6 . .
C29 C30 C31 118.8(4) . .
C29 C30 H30 120.6 . .
C31 C30 H30 120.6 . .
C30 C31 C32 118.9(5) . .
C30 C31 H31 120.6 . .
C32 C31 H31 120.6 . .
N3 C32 C31 121.8(4) . .
N3 C32 H32 119.1 . .
C31 C32 H32 119.1 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 N3 2.008(3) .
Pt1 Cl2 2.2922(10) .
Pt1 Cl3 2.2992(10) .
Pt1 Cl1 2.3088(10) .
N1 C1 1.334(4) .
N1 C2 1.384(4) .
N1 C16 1.456(4) .
N2 C1 1.332(4) .
N2 C3 1.388(4) .
N2 C4 1.450(4) .
N3 C32 1.310(6) .
N3 C28 1.350(6) .
C1 H1 0.9500 .
C2 C3 1.344(5) .
C2 H2 0.9500 .
C3 H3 0.9500 .
C4 C5 1.394(5) .
C4 C9 1.397(5) .
C5 C6 1.399(5) .
C5 C13 1.512(5) .
C6 C7 1.385(6) .
C6 H6 0.9500 .
C7 C8 1.386(6) .
C7 H7 0.9500 .
C8 C9 1.390(5) .
C8 H8 0.9500 .
C9 C10 1.517(5) .
C10 C11 1.519(5) .
C10 C12 1.531(6) .
C10 H10 1.0000 .
C11 H11A 0.9800 .
C11 H11B 0.9800 .
C11 H11C 0.9800 .
C12 H12A 0.9800 .
C12 H12B 0.9800 .
C12 H12C 0.9800 .
C13 C15 1.518(6) .
C13 C14 1.535(6) .
C13 H13 1.0000 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 C21 1.394(5) .
C16 C17 1.395(5) .
C17 C18 1.392(5) .
C17 C25 1.518(5) .
C18 C19 1.378(6) .
C18 H18 0.9500 .
C19 C20 1.387(6) .
C19 H19 0.9500 .
C20 C21 1.392(5) .
C20 H20 0.9500 .
C21 C22 1.529(5) .
C22 C23 1.521(5) .
C22 C24 1.526(5) .
C22 H22 1.0000 .
C23 H23A 0.9800 .
C23 H23B 0.9800 .
C23 H23C 0.9800 .
C24 H24A 0.9800 .
C24 H24B 0.9800 .
C24 H24C 0.9800 .
C25 C26 1.528(6) .
C25 C27 1.532(5) .
C25 H25 1.0000 .
C26 H26A 0.9800 .
C26 H26B 0.9800 .
C26 H26C 0.9800 .
C27 H27A 0.9800 .
C27 H27B 0.9800 .
C27 H27C 0.9800 .
C28 C29 1.385(6) .
C28 H28 0.9500 .
C29 C30 1.374(7) .
C29 H29 0.9500 .
C30 C31 1.389(7) .
C30 H30 0.9500 .
C31 C32 1.409(7) .
C31 H31 0.9500 .
C32 H32 0.9500 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
Cl2 Pt1 N3 C32 -46.1(3) . . . .
Cl1 Pt1 N3 C32 131.5(3) . . . .
Cl2 Pt1 N3 C28 134.7(3) . . . .
Cl1 Pt1 N3 C28 -47.8(3) . . . .
C3 N2 C1 N1 -0.4(4) . . . .
C4 N2 C1 N1 179.6(3) . . . .
C2 N1 C1 N2 0.3(4) . . . .
C16 N1 C1 N2 -177.5(3) . . . .
C1 N1 C2 C3 0.0(4) . . . .
C16 N1 C2 C3 177.7(3) . . . .
N1 C2 C3 N2 -0.3(4) . . . .
C1 N2 C3 C2 0.4(4) . . . .
C4 N2 C3 C2 -179.6(3) . . . .
C1 N2 C4 C5 93.5(4) . . . .
C3 N2 C4 C5 -86.5(4) . . . .
C1 N2 C4 C9 -86.5(4) . . . .
C3 N2 C4 C9 93.5(4) . . . .
C9 C4 C5 C6 0.5(5) . . . .
N2 C4 C5 C6 -179.5(3) . . . .
C9 C4 C5 C13 -179.4(3) . . . .
N2 C4 C5 C13 0.6(5) . . . .
C4 C5 C6 C7 -0.3(5) . . . .
C13 C5 C6 C7 179.6(4) . . . .
C5 C6 C7 C8 0.1(6) . . . .
C6 C7 C8 C9 0.0(6) . . . .
C7 C8 C9 C4 0.1(6) . . . .
C7 C8 C9 C10 178.3(4) . . . .
C5 C4 C9 C8 -0.4(5) . . . .
N2 C4 C9 C8 179.5(3) . . . .
C5 C4 C9 C10 -178.5(3) . . . .
N2 C4 C9 C10 1.4(5) . . . .
C8 C9 C10 C11 47.9(5) . . . .
C4 C9 C10 C11 -134.1(4) . . . .
C8 C9 C10 C12 -75.4(5) . . . .
C4 C9 C10 C12 102.6(4) . . . .
C4 C5 C13 C15 116.9(4) . . . .
C6 C5 C13 C15 -63.0(5) . . . .
C4 C5 C13 C14 -119.4(4) . . . .
C6 C5 C13 C14 60.7(5) . . . .
C1 N1 C16 C21 -88.3(4) . . . .
C2 N1 C16 C21 94.4(4) . . . .
C1 N1 C16 C17 90.6(4) . . . .
C2 N1 C16 C17 -86.7(4) . . . .
C21 C16 C17 C18 2.4(5) . . . .
N1 C16 C17 C18 -176.5(3) . . . .
C21 C16 C17 C25 -177.6(3) . . . .
N1 C16 C17 C25 3.6(5) . . . .
C16 C17 C18 C19 0.2(5) . . . .
C25 C17 C18 C19 -179.9(3) . . . .
C17 C18 C19 C20 -1.9(6) . . . .
C18 C19 C20 C21 1.2(6) . . . .
C19 C20 C21 C16 1.2(5) . . . .
C19 C20 C21 C22 -178.0(3) . . . .
C17 C16 C21 C20 -3.0(5) . . . .
N1 C16 C21 C20 175.8(3) . . . .
C17 C16 C21 C22 176.1(3) . . . .
N1 C16 C21 C22 -5.0(5) . . . .
C20 C21 C22 C23 -80.2(4) . . . .
C16 C21 C22 C23 100.6(4) . . . .
C20 C21 C22 C24 44.4(5) . . . .
C16 C21 C22 C24 -134.7(4) . . . .
C18 C17 C25 C26 61.6(5) . . . .
C16 C17 C25 C26 -118.5(4) . . . .
C18 C17 C25 C27 -61.6(4) . . . .
C16 C17 C25 C27 118.3(4) . . . .
C32 N3 C28 C29 0.7(7) . . . .
Pt1 N3 C28 C29 -180.0(3) . . . .
N3 C28 C29 C30 -0.7(7) . . . .
C28 C29 C30 C31 0.5(7) . . . .
C29 C30 C31 C32 -0.4(7) . . . .
C28 N3 C32 C31 -0.6(7) . . . .
Pt1 N3 C32 C31 -179.9(4) . . . .
C30 C31 C32 N3 0.4(7) . . . .
