#------------------------------------------------------------------------------
#$Date: 2017-04-05 12:17:29 +0300 (Wed, 05 Apr 2017) $
#$Revision: 194974 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/11/97/7119772.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7119772
loop_
_publ_author_name
'Zhang, Fan'
'Adolf, Cyril R. R.'
'Zigon, Nicolas'
'Ferlay, Sylvie'
'Kyritsakas, Nathalie'
'Hosseini, Mir Wais'
_publ_section_title
;
 Molecular tectonics: hierarchical organization of heterobimetallic
 coordination networks into heterotrimetallic core-shell crystals.
;
_journal_issue                   25
_journal_name_full
'Chemical communications (Cambridge, England)'
_journal_page_first              3587
_journal_page_last               3590
_journal_paper_doi               10.1039/c7cc01455d
_journal_volume                  53
_journal_year                    2017
_chemical_formula_moiety         'C50 H38 Br2 Co N2 P2 Pt'
_chemical_formula_sum            'C50 H38 Br2 Co N2 P2 Pt'
_chemical_formula_weight         1142.60
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2017-02-22 deposited with the CCDC.
2017-03-07 downloaded from the CCDC.
;
_cell_angle_alpha                95.1270(10)
_cell_angle_beta                 91.4850(10)
_cell_angle_gamma                98.3100(11)
_cell_formula_units_Z            2
_cell_length_a                   9.5894(3)
_cell_length_b                   9.6957(4)
_cell_length_c                   24.1720(9)
_cell_measurement_reflns_used    33900
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.54
_cell_measurement_theta_min      2.57
_cell_volume                     2213.20(14)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2013)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2013)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.958
_diffrn_measured_fraction_theta_max 0.911
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0373
_diffrn_reflns_av_unetI/netI     0.0412
_diffrn_reflns_Laue_measured_fraction_full 0.958
_diffrn_reflns_Laue_measured_fraction_max 0.911
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -34
_diffrn_reflns_number            33971
_diffrn_reflns_point_group_measured_fraction_full 0.958
_diffrn_reflns_point_group_measured_fraction_max 0.911
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.143
_diffrn_reflns_theta_min         2.132
_exptl_absorpt_coefficient_mu    5.446
_exptl_absorpt_correction_T_max  0.772
_exptl_absorpt_correction_T_min  0.736
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.715
_exptl_crystal_density_meas      ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             1114
_exptl_crystal_size_max          0.060
_exptl_crystal_size_mid          0.050
_exptl_crystal_size_min          0.050
_refine_diff_density_max         2.188
_refine_diff_density_min         -2.024
_refine_diff_density_rms         0.129
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.020
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     526
_refine_ls_number_reflns         11919
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.020
_refine_ls_R_factor_all          0.0422
_refine_ls_R_factor_gt           0.0326
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0351P)²+3.6329P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0769
_refine_ls_wR_factor_ref         0.0811
_reflns_Friedel_coverage         0.000
_reflns_number_gt                10078
_reflns_number_total             11919
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7cc01455d2.cif
_cod_data_source_block           e3195a_a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 

 Adding full bibliography for 7119770--7119773.cif.
;
_cod_database_code               7119772
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.736
_shelx_estimated_absorpt_t_max   0.772
_shelxl_version_number           2014-3
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Pt1 Pt 1.0000 1.0000 0.5000 0.01677(5) Uani 1 2 d S . P
P1 P 0.84458(9) 0.84483(8) 0.44156(3) 0.01697(16) Uani 1 1 d . . .
C1 C 0.9090(4) 0.8158(3) 0.37151(12) 0.0202(6) Uani 1 1 d . . .
C2 C 1.0531(4) 0.8320(4) 0.36411(14) 0.0272(7) Uani 1 1 d . . .
H2 H 1.1169 0.8536 0.3954 0.033 Uiso 1 1 calc R U .
C3 C 1.1048(4) 0.8168(5) 0.31098(16) 0.0339(9) Uani 1 1 d . . .
H3 H 1.2037 0.8285 0.3062 0.041 Uiso 1 1 calc R U .
C4 C 1.0139(5) 0.7852(4) 0.26552(15) 0.0336(9) Uani 1 1 d . . .
H4 H 1.0499 0.7762 0.2293 0.040 Uiso 1 1 calc R U .
C5 C 0.8691(5) 0.7662(5) 0.27223(15) 0.0364(9) Uani 1 1 d . . .
H5 H 0.8059 0.7431 0.2407 0.044 Uiso 1 1 calc R U .
C6 C 0.8170(4) 0.7811(4) 0.32536(14) 0.0288(8) Uani 1 1 d . . .
H6 H 0.7180 0.7676 0.3301 0.035 Uiso 1 1 calc R U .
C7 C 0.6755(4) 0.9053(3) 0.43073(13) 0.0209(6) Uani 1 1 d . . .
C8 C 0.5547(4) 0.8108(4) 0.41322(15) 0.0259(7) Uani 1 1 d . . .
H8 H 0.5587 0.7131 0.4091 0.031 Uiso 1 1 calc R U .
C9 C 0.4301(4) 0.8595(4) 0.40204(16) 0.0309(8) Uani 1 1 d . . .
H9 H 0.3484 0.7952 0.3900 0.037 Uiso 1 1 calc R U .
C10 C 0.4229(4) 1.0026(4) 0.40829(17) 0.0341(9) Uani 1 1 d . . .
H10 H 0.3366 1.0358 0.4007 0.041 Uiso 1 1 calc R U .
C11 C 0.5425(4) 1.0959(4) 0.42563(18) 0.0350(9) Uani 1 1 d . . .
H11 H 0.5382 1.1935 0.4298 0.042 Uiso 1 1 calc R U .
C12 C 0.6682(4) 1.0481(4) 0.43693(15) 0.0277(7) Uani 1 1 d . . .
H12 H 0.7497 1.1128 0.4489 0.033 Uiso 1 1 calc R U .
C13 C 0.7997(3) 0.6722(3) 0.46549(12) 0.0182(6) Uani 1 1 d . . .
C14 C 0.8682(4) 0.5618(4) 0.44614(14) 0.0266(7) Uani 1 1 d . . .
H14 H 0.9338 0.5734 0.4175 0.032 Uiso 1 1 calc R U .
C15 C 0.8403(5) 0.4338(4) 0.46880(16) 0.0343(9) Uani 1 1 d . . .
H15 H 0.8887 0.3589 0.4561 0.041 Uiso 1 1 calc R U .
C16 C 0.7435(4) 0.4154(4) 0.50931(15) 0.0314(8) Uani 1 1 d . . .
H16 H 0.7238 0.3272 0.5239 0.038 Uiso 1 1 calc R U .
C17 C 0.6745(4) 0.5246(4) 0.52892(16) 0.0316(8) Uani 1 1 d . . .
H17 H 0.6079 0.5117 0.5571 0.038 Uiso 1 1 calc R U .
C18 C 0.7029(4) 0.6527(4) 0.50742(15) 0.0266(7) Uani 1 1 d . . .
H18 H 0.6563 0.7280 0.5212 0.032 Uiso 1 1 calc R U .
C19 C 0.9675(3) 0.8799(3) 0.56324(14) 0.0209(6) Uani 1 1 d . . .
C20 C 0.9524(4) 0.8119(4) 0.60015(14) 0.0246(7) Uani 1 1 d . . .
C21 C 0.9283(4) 0.7187(4) 0.64440(14) 0.0234(7) Uani 1 1 d . . .
C22 C 1.0331(4) 0.6544(4) 0.66751(15) 0.0274(7) Uani 1 1 d . . .
H22 H 1.1269 0.6724 0.6554 0.033 Uiso 1 1 calc R U .
C23 C 1.0020(4) 0.5650(4) 0.70779(16) 0.0315(8) Uani 1 1 d . . .
H23 H 1.0733 0.5193 0.7230 0.038 Uiso 1 1 calc R U .
C24 C 0.8660(4) 0.5420(4) 0.72604(15) 0.0305(8) Uani 1 1 d . . .
H24 H 0.8448 0.4809 0.7543 0.037 Uiso 1 1 calc R U .
N1 N 0.7635(3) 0.6040(3) 0.70480(12) 0.0258(6) Uani 1 1 d . . .
C25 C 0.7935(4) 0.6890(4) 0.66466(14) 0.0256(7) Uani 1 1 d . . .
H25 H 0.7196 0.7309 0.6493 0.031 Uiso 1 1 calc R U .
Co1 Co 0.56670(5) 0.59661(5) 0.73489(2) 0.02532(10) Uani 1 1 d . . .
Br1 Br 0.53602(6) 0.43241(5) 0.80220(2) 0.04783(12) Uani 1 1 d . . .
Br2 Br 0.40244(5) 0.57343(5) 0.65952(2) 0.03966(10) Uani 1 1 d . . .
N2 N 0.5886(3) 0.7984(3) 0.77089(12) 0.0261(6) Uani 1 1 d . . .
C26 C 0.5393(4) 0.9031(4) 0.74706(14) 0.0294(8) Uani 1 1 d . . .
H26 H 0.4842 0.8823 0.7133 0.035 Uiso 1 1 calc R U .
C27 C 0.5672(4) 1.0401(4) 0.77056(15) 0.0322(8) Uani 1 1 d . . .
H27 H 0.5308 1.1122 0.7532 0.039 Uiso 1 1 calc R U .
C28 C 0.6480(4) 1.0719(4) 0.81930(15) 0.0288(8) Uani 1 1 d . . .
H28 H 0.6678 1.1658 0.8356 0.035 Uiso 1 1 calc R U .
C29 C 0.7008(4) 0.9643(4) 0.84475(13) 0.0240(7) Uani 1 1 d . . .
C30 C 0.6662(4) 0.8289(4) 0.81813(14) 0.0249(7) Uani 1 1 d . . .
H30 H 0.7000 0.7542 0.8347 0.030 Uiso 1 1 calc R U .
C31 C 0.7878(4) 0.9852(4) 0.89519(15) 0.0262(7) Uani 1 1 d . . .
C32 C 0.8631(4) 0.9912(4) 0.93520(14) 0.0240(7) Uani 1 1 d . . .
Pt2 Pt 1.0000 1.0000 1.0000 0.01908(5) Uani 1 2 d S . P
P2 P 1.16065(9) 1.12323(9) 0.94692(3) 0.01907(17) Uani 1 1 d . . .
C33 C 1.1944(4) 1.0050(3) 0.88778(13) 0.0215(7) Uani 1 1 d . . .
C34 C 1.2803(4) 0.9027(4) 0.89577(15) 0.0279(8) Uani 1 1 d . . .
H34 H 1.3245 0.8996 0.9312 0.033 Uiso 1 1 calc R U .
C35 C 1.3005(5) 0.8063(4) 0.85226(17) 0.0334(8) Uani 1 1 d . . .
H35 H 1.3608 0.7386 0.8577 0.040 Uiso 1 1 calc R U .
C36 C 1.2339(5) 0.8074(4) 0.80076(16) 0.0348(9) Uani 1 1 d . . .
H36 H 1.2485 0.7408 0.7710 0.042 Uiso 1 1 calc R U .
C37 C 1.1465(5) 0.9054(4) 0.79297(16) 0.0359(9) Uani 1 1 d . . .
H37 H 1.1000 0.9059 0.7578 0.043 Uiso 1 1 calc R U .
C38 C 1.1260(4) 1.0042(4) 0.83657(14) 0.0284(8) Uani 1 1 d . . .
H38 H 1.0648 1.0710 0.8311 0.034 Uiso 1 1 calc R U .
C39 C 1.3337(4) 1.2013(4) 0.97690(13) 0.0220(7) Uani 1 1 d . . .
C40 C 1.3396(4) 1.2820(4) 1.02783(14) 0.0288(8) Uani 1 1 d . . .
H40 H 1.2562 1.2870 1.0478 0.035 Uiso 1 1 calc R U .
C41 C 1.4680(5) 1.3555(4) 1.04936(16) 0.0340(9) Uani 1 1 d . . .
H41 H 1.4717 1.4117 1.0838 0.041 Uiso 1 1 calc R U .
C42 C 1.5897(5) 1.3468(5) 1.02090(18) 0.0394(10) Uani 1 1 d . . .
H42 H 1.6770 1.3967 1.0359 0.047 Uiso 1 1 calc R U .
C43 C 1.5855(5) 1.2667(5) 0.97100(19) 0.0425(10) Uani 1 1 d . . .
H43 H 1.6697 1.2608 0.9517 0.051 Uiso 1 1 calc R U .
C44 C 1.4578(4) 1.1941(5) 0.94861(16) 0.0353(9) Uani 1 1 d . . .
H44 H 1.4551 1.1394 0.9139 0.042 Uiso 1 1 calc R U .
C45 C 1.1015(4) 1.2747(3) 0.91899(13) 0.0233(7) Uani 1 1 d . . .
C46 C 1.1805(5) 1.3444(4) 0.87939(15) 0.0307(8) Uani 1 1 d . . .
H46 H 1.2626 1.3105 0.8660 0.037 Uiso 1 1 calc R U .
C47 C 1.1399(5) 1.4623(4) 0.85963(17) 0.0395(10) Uani 1 1 d . . .
H47 H 1.1920 1.5073 0.8317 0.047 Uiso 1 1 calc R U .
C48 C 1.0240(6) 1.5148(5) 0.8803(2) 0.0496(12) Uani 1 1 d . . .
H48 H 0.9971 1.5970 0.8671 0.059 Uiso 1 1 calc R U .
C49 C 0.9466(6) 1.4484(5) 0.9201(2) 0.0513(12) Uani 1 1 d . . .
H49 H 0.8666 1.4850 0.9343 0.062 Uiso 1 1 calc R U .
C50 C 0.9851(4) 1.3276(4) 0.93973(18) 0.0356(9) Uani 1 1 d . . .
H50 H 0.9316 1.2821 0.9672 0.043 Uiso 1 1 calc R U .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C19 Pt1 C19 180.0 2_776 .
C19 Pt1 P1 91.92(9) 2_776 2_776
C19 Pt1 P1 88.08(9) . 2_776
C19 Pt1 P1 88.08(9) 2_776 .
C19 Pt1 P1 91.92(9) . .
P1 Pt1 P1 180.0 2_776 .
C13 P1 C7 104.69(15) . .
C13 P1 C1 105.87(15) . .
C7 P1 C1 104.36(15) . .
C13 P1 Pt1 114.80(10) . .
C7 P1 Pt1 113.02(11) . .
C1 P1 Pt1 113.14(11) . .
C2 C1 C6 119.2(3) . .
C2 C1 P1 119.2(2) . .
C6 C1 P1 121.6(3) . .
C1 C2 C3 120.3(3) . .
C1 C2 H2 119.8 . .
C3 C2 H2 119.8 . .
C4 C3 C2 120.4(4) . .
C4 C3 H3 119.8 . .
C2 C3 H3 119.8 . .
C3 C4 C5 120.1(3) . .
C3 C4 H4 120.0 . .
C5 C4 H4 120.0 . .
C4 C5 C6 119.7(4) . .
C4 C5 H5 120.2 . .
C6 C5 H5 120.2 . .
C1 C6 C5 120.3(4) . .
C1 C6 H6 119.8 . .
C5 C6 H6 119.8 . .
C12 C7 C8 119.5(3) . .
C12 C7 P1 119.5(3) . .
C8 C7 P1 120.9(3) . .
C9 C8 C7 119.9(3) . .
C9 C8 H8 120.0 . .
C7 C8 H8 120.0 . .
C8 C9 C10 120.5(4) . .
C8 C9 H9 119.8 . .
C10 C9 H9 119.8 . .
C11 C10 C9 119.5(4) . .
C11 C10 H10 120.3 . .
C9 C10 H10 120.3 . .
C12 C11 C10 120.5(4) . .
C12 C11 H11 119.8 . .
C10 C11 H11 119.8 . .
C11 C12 C7 120.1(4) . .
C11 C12 H12 120.0 . .
C7 C12 H12 120.0 . .
C14 C13 C18 119.2(3) . .
C14 C13 P1 121.1(3) . .
C18 C13 P1 119.5(3) . .
C13 C14 C15 119.8(3) . .
C13 C14 H14 120.1 . .
C15 C14 H14 120.1 . .
C16 C15 C14 120.5(4) . .
C16 C15 H15 119.8 . .
C14 C15 H15 119.8 . .
C15 C16 C17 120.2(3) . .
C15 C16 H16 119.9 . .
C17 C16 H16 119.9 . .
C16 C17 C18 119.8(4) . .
C16 C17 H17 120.1 . .
C18 C17 H17 120.1 . .
C17 C18 C13 120.5(3) . .
C17 C18 H18 119.8 . .
C13 C18 H18 119.8 . .
C20 C19 Pt1 178.2(3) . .
C19 C20 C21 176.4(4) . .
C22 C21 C25 116.8(3) . .
C22 C21 C20 123.5(3) . .
C25 C21 C20 119.7(3) . .
C23 C22 C21 120.3(4) . .
C23 C22 H22 119.8 . .
C21 C22 H22 119.8 . .
C22 C23 C24 119.4(4) . .
C22 C23 H23 120.3 . .
C24 C23 H23 120.3 . .
N1 C24 C23 121.4(3) . .
N1 C24 H24 119.3 . .
C23 C24 H24 119.3 . .
C24 N1 C25 119.1(3) . .
C24 N1 Co1 124.5(2) . .
C25 N1 Co1 116.0(2) . .
N1 C25 C21 123.0(3) . .
N1 C25 H25 118.5 . .
C21 C25 H25 118.5 . .
N1 Co1 N2 97.56(13) . .
N1 Co1 Br2 108.65(9) . .
N2 Co1 Br2 108.43(9) . .
N1 Co1 Br1 109.56(9) . .
N2 Co1 Br1 111.65(8) . .
Br2 Co1 Br1 118.84(3) . .
C30 N2 C26 118.7(3) . .
C30 N2 Co1 117.6(2) . .
C26 N2 Co1 123.5(2) . .
N2 C26 C27 121.5(3) . .
N2 C26 H26 119.2 . .
C27 C26 H26 119.2 . .
C28 C27 C26 119.9(3) . .
C28 C27 H27 120.1 . .
C26 C27 H27 120.1 . .
C27 C28 C29 119.5(3) . .
C27 C28 H28 120.2 . .
C29 C28 H28 120.2 . .
C30 C29 C28 116.5(3) . .
C30 C29 C31 119.1(3) . .
C28 C29 C31 124.4(3) . .
N2 C30 C29 123.9(3) . .
N2 C30 H30 118.0 . .
C29 C30 H30 118.0 . .
C32 C31 C29 174.1(4) . .
C31 C32 Pt2 176.7(3) . .
C32 Pt2 C32 180.0 . 2_777
C32 Pt2 P2 93.83(10) . 2_777
C32 Pt2 P2 86.17(10) 2_777 2_777
C32 Pt2 P2 86.17(10) . .
C32 Pt2 P2 93.83(10) 2_777 .
P2 Pt2 P2 180.00(3) 2_777 .
C33 P2 C39 105.77(17) . .
C33 P2 C45 106.87(15) . .
C39 P2 C45 100.71(16) . .
C33 P2 Pt2 107.42(11) . .
C39 P2 Pt2 120.20(11) . .
C45 P2 Pt2 114.89(12) . .
C38 C33 C34 119.2(3) . .
C38 C33 P2 121.5(3) . .
C34 C33 P2 119.0(2) . .
C35 C34 C33 120.0(3) . .
C35 C34 H34 120.0 . .
C33 C34 H34 120.0 . .
C34 C35 C36 120.6(4) . .
C34 C35 H35 119.7 . .
C36 C35 H35 119.7 . .
C37 C36 C35 119.7(4) . .
C37 C36 H36 120.2 . .
C35 C36 H36 120.2 . .
C36 C37 C38 120.2(4) . .
C36 C37 H37 119.9 . .
C38 C37 H37 119.9 . .
C33 C38 C37 120.2(4) . .
C33 C38 H38 119.9 . .
C37 C38 H38 119.9 . .
C40 C39 C44 119.1(3) . .
C40 C39 P2 118.1(3) . .
C44 C39 P2 122.6(3) . .
C41 C40 C39 119.9(4) . .
C41 C40 H40 120.1 . .
C39 C40 H40 120.1 . .
C42 C41 C40 120.3(4) . .
C42 C41 H41 119.9 . .
C40 C41 H41 119.9 . .
C43 C42 C41 120.4(4) . .
C43 C42 H42 119.8 . .
C41 C42 H42 119.8 . .
C42 C43 C44 120.1(4) . .
C42 C43 H43 120.0 . .
C44 C43 H43 120.0 . .
C43 C44 C39 120.4(4) . .
C43 C44 H44 119.8 . .
C39 C44 H44 119.8 . .
C50 C45 C46 119.5(3) . .
C50 C45 P2 120.5(3) . .
C46 C45 P2 119.9(3) . .
C47 C46 C45 120.3(4) . .
C47 C46 H46 119.8 . .
C45 C46 H46 119.8 . .
C48 C47 C46 120.1(4) . .
C48 C47 H47 120.0 . .
C46 C47 H47 120.0 . .
C47 C48 C49 120.1(4) . .
C47 C48 H48 120.0 . .
C49 C48 H48 120.0 . .
C48 C49 C50 120.4(5) . .
C48 C49 H49 119.8 . .
C50 C49 H49 119.8 . .
C45 C50 C49 119.6(4) . .
C45 C50 H50 120.2 . .
C49 C50 H50 120.2 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pt1 C19 2.007(3) 2_776
Pt1 C19 2.007(3) .
Pt1 P1 2.3116(8) 2_776
Pt1 P1 2.3116(8) .
P1 C13 1.816(3) .
P1 C7 1.822(4) .
P1 C1 1.830(3) .
C1 C2 1.386(5) .
C1 C6 1.390(5) .
C2 C3 1.392(5) .
C2 H2 0.9500 .
C3 C4 1.369(6) .
C3 H3 0.9500 .
C4 C5 1.390(6) .
C4 H4 0.9500 .
C5 C6 1.393(5) .
C5 H5 0.9500 .
C6 H6 0.9500 .
C7 C12 1.391(5) .
C7 C8 1.400(5) .
C8 C9 1.376(5) .
C8 H8 0.9500 .
C9 C10 1.394(6) .
C9 H9 0.9500 .
C10 C11 1.385(6) .
C10 H10 0.9500 .
C11 C12 1.381(6) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 C14 1.387(5) .
C13 C18 1.399(5) .
C14 C15 1.394(5) .
C14 H14 0.9500 .
C15 C16 1.372(6) .
C15 H15 0.9500 .
C16 C17 1.383(6) .
C16 H16 0.9500 .
C17 C18 1.382(5) .
C17 H17 0.9500 .
C18 H18 0.9500 .
C19 C20 1.156(5) .
C20 C21 1.462(5) .
C21 C22 1.388(5) .
C21 C25 1.395(5) .
C22 C23 1.371(5) .
C22 H22 0.9500 .
C23 C24 1.382(6) .
C23 H23 0.9500 .
C24 N1 1.338(5) .
C24 H24 0.9500 .
N1 C25 1.339(4) .
N1 Co1 2.034(3) .
C25 H25 0.9500 .
Co1 N2 2.048(3) .
Co1 Br2 2.3509(6) .
Co1 Br1 2.3708(6) .
N2 C30 1.333(4) .
N2 C26 1.347(5) .
C26 C27 1.383(5) .
C26 H26 0.9500 .
C27 C28 1.379(5) .
C27 H27 0.9500 .
C28 C29 1.405(5) .
C28 H28 0.9500 .
C29 C30 1.400(5) .
C29 C31 1.442(5) .
C30 H30 0.9500 .
C31 C32 1.184(5) .
C32 Pt2 2.005(4) .
Pt2 C32 2.005(4) 2_777
Pt2 P2 2.3003(8) 2_777
Pt2 P2 2.3004(8) .
P2 C33 1.817(3) .
P2 C39 1.824(4) .
P2 C45 1.825(3) .
C33 C38 1.385(5) .
C33 C34 1.400(5) .
C34 C35 1.380(5) .
C34 H34 0.9500 .
C35 C36 1.386(6) .
C35 H35 0.9500 .
C36 C37 1.377(6) .
C36 H36 0.9500 .
C37 C38 1.397(5) .
C37 H37 0.9500 .
C38 H38 0.9500 .
C39 C40 1.394(5) .
C39 C44 1.395(5) .
C40 C41 1.394(5) .
C40 H40 0.9500 .
C41 C42 1.379(6) .
C41 H41 0.9500 .
C42 C43 1.371(6) .
C42 H42 0.9500 .
C43 C44 1.391(6) .
C43 H43 0.9500 .
C44 H44 0.9500 .
C45 C50 1.382(6) .
C45 C46 1.397(5) .
C46 C47 1.380(5) .
C46 H46 0.9500 .
C47 C48 1.375(7) .
C47 H47 0.9500 .
C48 C49 1.379(7) .
C48 H48 0.9500 .
C49 C50 1.395(6) .
C49 H49 0.9500 .
C50 H50 0.9500 .
