#------------------------------------------------------------------------------
#$Date: 2016-03-26 22:17:28 +0200 (Sat, 26 Mar 2016) $
#$Revision: 180498 $
#$URL: svn://www.crystallography.net/cod/cif/7/21/67/7216747.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7216747
loop_
_publ_author_name
'Liu, Qi'
'Wan, Fang'
'Qiu, Li-Xia'
'Sun, Yan-Qiong'
'Chen, Yi-Ping'
_publ_section_title
;
 Four 2D Ln--Cd heterometal--organic coordination polymers based on
 tetranuclear Ln--Cd oxo-cluster with highly selective luminescent sensing
 of organic molecules and metal cations
;
_journal_issue                   51
_journal_name_full               'RSC Advances'
_journal_page_first              27013
_journal_paper_doi               10.1039/c4ra02953d
_journal_volume                  4
_journal_year                    2014
_chemical_formula_moiety         'C28 H52 Cd2 Eu2 N6 O24,4(O)'
_chemical_formula_sum            'C28 H52 Cd2 Eu2 N6 O28'
_chemical_formula_weight         1449.48
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                100.683(12)
_cell_angle_beta                 92.766(9)
_cell_angle_gamma                91.801(11)
_cell_formula_units_Z            2
_cell_length_a                   9.804(3)
_cell_length_b                   10.912(4)
_cell_length_c                   20.446(6)
_cell_measurement_reflns_used    8910
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      55.02
_cell_measurement_theta_min      5.97
_cell_volume                     2145.1(12)
_computing_cell_refinement       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_collection       'CrystalClear (Rigaku Corp., 2000)'
_computing_data_reduction        'CrystalClear (Rigaku Corp., 2000)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 28.5714
_diffrn_measured_fraction_theta_full 0.920
_diffrn_measured_fraction_theta_max 0.920
_diffrn_measurement_device_type  'Saturn724 (2x2 bin mode)'
_diffrn_measurement_method       dtprofit.ref
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0299
_diffrn_reflns_av_sigmaI/netI    0.0255
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            14537
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.99
_exptl_absorpt_coefficient_mu    3.966
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    2.244
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1416
_exptl_crystal_size_max          0.2
_exptl_crystal_size_mid          0.2
_exptl_crystal_size_min          0.2
_refine_diff_density_max         1.126
_refine_diff_density_min         -0.627
_refine_diff_density_rms         0.115
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.007
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     595
_refine_ls_number_reflns         6950
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.007
_refine_ls_R_factor_all          0.0315
_refine_ls_R_factor_gt           0.0267
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0368P)²+5.4160P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0661
_refine_ls_wR_factor_ref         0.0680
_reflns_number_gt                6255
_reflns_number_total             6950
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c4ra02953d2.cif
_cod_data_source_block           1
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               7216747
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
Eu1 Eu 0.19500(2) 0.30912(2) 0.857953(9) 0.01661(7) Uani 1 1 d .
Eu2 Eu 0.62458(2) 0.29579(2) 0.337863(10) 0.01645(7) Uani 1 1 d .
Cd1 Cd 0.36062(3) 0.27256(3) 0.681545(14) 0.01576(8) Uani 1 1 d .
Cd2 Cd 0.79760(3) 0.26359(3) 0.163440(14) 0.01584(8) Uani 1 1 d .
O1 O 0.5997(3) 0.2160(3) 0.44739(15) 0.0309(8) Uani 1 1 d .
O1W O 0.3257(3) 0.1756(3) 0.91962(15) 0.0273(7) Uani 1 1 d .
H1WA H 0.3136 0.1961 0.9617 0.041 Uiso 1 1 d R
H1WB H 0.2990 0.0986 0.9061 0.041 Uiso 1 1 d R
O2 O 0.4814(3) 0.3760(3) 0.43012(15) 0.0276(7) Uani 1 1 d .
O2W O -0.0237(3) 0.4027(4) 0.84425(16) 0.0344(8) Uani 1 1 d .
H2WA H -0.0522 0.3931 0.8009 0.052 Uiso 1 1 d R
H2WB H -0.0901 0.3687 0.8651 0.052 Uiso 1 1 d R
O3 O 0.4176(3) 0.4865(3) 0.68685(15) 0.0222(7) Uani 1 1 d .
O3W O 0.4481(3) 0.1265(3) 0.32170(16) 0.0272(7) Uani 1 1 d .
H3WA H 0.4844 0.0530 0.3237 0.041 Uiso 1 1 d R
H3WB H 0.3865 0.1398 0.3530 0.041 Uiso 1 1 d R
O4 O 0.5880(3) 0.6269(3) 0.71002(16) 0.0278(7) Uani 1 1 d .
O4W O 0.7773(3) 0.4297(4) 0.41939(16) 0.0353(8) Uani 1 1 d .
H4WA H 0.8605 0.4139 0.4109 0.053 Uiso 1 1 d R
H4WB H 0.7754 0.4526 0.4614 0.053 Uiso 1 1 d R
O5 O 0.3665(3) 0.0519(3) 0.67560(15) 0.0242(7) Uani 1 1 d .
O5W O 0.1820(6) 0.1394(6) 0.3823(3) 0.0966(19) Uiso 1 1 d .
O6 O 0.2314(3) -0.1205(3) 0.66309(15) 0.0247(7) Uani 1 1 d .
O6W O 0.2337(4) 0.4911(4) 0.44523(19) 0.0501(11) Uani 1 1 d G
H6WA H 0.1648 0.4563 0.4213 0.075 Uiso 1 1 d G
H6WB H 0.3111 0.4588 0.4395 0.075 Uiso 1 1 d G
O7 O 0.1611(3) 0.3249(3) 0.73729(13) 0.0196(6) Uani 1 1 d .
O7W O 0.2611(4) 0.5436(4) 0.0882(2) 0.0487(10) Uani 1 1 d G
H7WA H 0.3422 0.5726 0.0868 0.073 Uiso 1 1 d G
H7WB H 0.2371 0.4968 0.0511 0.073 Uiso 1 1 d G
O8 O -0.0533(3) 0.3736(4) 0.71489(17) 0.0420(10) Uani 1 1 d .
O8W O 0.905(3) 0.207(3) 0.4823(14) 0.506(16) Uiso 1 1 d .
O9 O 0.4028(3) 0.2621(3) 0.79497(14) 0.0237(7) Uani 1 1 d .
O10 O 0.5599(3) 0.2017(4) 0.86393(16) 0.0381(9) Uani 1 1 d .
O11 O 0.8397(3) 0.3373(3) 0.28056(14) 0.0206(6) Uani 1 1 d .
O12 O 1.0076(3) 0.3790(4) 0.36056(17) 0.0460(11) Uani 1 1 d .
O13 O 0.7972(3) 0.0392(3) 0.15228(15) 0.0244(7) Uani 1 1 d .
O14 O 0.8872(3) -0.1085(3) 0.20137(14) 0.0246(7) Uani 1 1 d .
O15 O 1.1336(3) 0.3950(3) -0.02753(15) 0.0287(7) Uani 1 1 d .
O16 O 1.0316(3) 0.2145(3) -0.07136(15) 0.0305(8) Uani 1 1 d .
O17 O 0.4026(3) 0.1022(4) 0.19353(16) 0.0337(8) Uani 1 1 d .
O18 O 0.5976(3) 0.2178(3) 0.21503(14) 0.0217(7) Uani 1 1 d .
O19 O 0.7415(3) 0.4622(3) 0.14016(15) 0.0233(7) Uani 1 1 d .
O20 O 0.5995(3) 0.5607(3) 0.08319(16) 0.0301(7) Uani 1 1 d .
N1 N 0.4545(3) 0.2152(3) 0.57102(16) 0.0177(7) Uani 1 1 d .
N2 N 0.1720(3) 0.1779(3) 0.61241(16) 0.0173(7) Uani 1 1 d .
N3 N 0.5984(3) 0.2949(3) 0.70650(16) 0.0174(7) Uani 1 1 d .
N4 N 0.9077(4) 0.2113(3) 0.05697(17) 0.0198(8) Uani 1 1 d .
N5 N 0.6107(3) 0.2332(3) 0.08230(16) 0.0184(7) Uani 1 1 d .
N6 N 1.0187(3) 0.2064(3) 0.19498(16) 0.0176(7) Uani 1 1 d .
C1 C 0.4662(4) 0.3221(4) 0.5369(2) 0.0199(9) Uani 1 1 d .
H1A H 0.5259 0.3855 0.5647 0.024 Uiso 1 1 calc R
H1B H 0.3766 0.3567 0.5344 0.024 Uiso 1 1 calc R
C2 C 0.5192(4) 0.2994(4) 0.4670(2) 0.0225(10) Uani 1 1 d .
C3 C 0.5885(4) 0.1653(4) 0.5900(2) 0.0206(9) Uani 1 1 d .
H3A H 0.6415 0.1464 0.5507 0.025 Uiso 1 1 calc R
H3B H 0.5718 0.0882 0.6060 0.025 Uiso 1 1 calc R
C4 C 0.3578(4) 0.1171(4) 0.5333(2) 0.0206(9) Uani 1 1 d .
H4A H 0.3709 0.0395 0.5490 0.025 Uiso 1 1 calc R
H4B H 0.3767 0.1034 0.4864 0.025 Uiso 1 1 calc R
C5 C 0.2098(4) 0.1543(5) 0.5415(2) 0.0226(10) Uani 1 1 d .
H5A H 0.1959 0.2292 0.5232 0.027 Uiso 1 1 calc R
H5B H 0.1495 0.0884 0.5162 0.027 Uiso 1 1 calc R
C6 C 0.6707(4) 0.2574(5) 0.6436(2) 0.0242(10) Uani 1 1 d .
H6A H 0.7557 0.2204 0.6540 0.029 Uiso 1 1 calc R
H6B H 0.6932 0.3316 0.6259 0.029 Uiso 1 1 calc R
C7 C 0.6278(4) 0.2160(4) 0.7559(2) 0.0201(9) Uani 1 1 d .
H7A H 0.7180 0.2392 0.7769 0.024 Uiso 1 1 calc R
H7B H 0.6285 0.1297 0.7332 0.024 Uiso 1 1 calc R
C8 C 0.5231(4) 0.2274(4) 0.8098(2) 0.0214(9) Uani 1 1 d .
C9 C 0.6298(4) 0.4281(4) 0.7367(2) 0.0236(10) Uani 1 1 d .
H9A H 0.7245 0.4482 0.7298 0.028 Uiso 1 1 calc R
H9B H 0.6197 0.4391 0.7843 0.028 Uiso 1 1 calc R
C10 C 0.5401(4) 0.5193(4) 0.70872(19) 0.0185(9) Uani 1 1 d .
C11 C 0.1336(4) 0.0606(4) 0.6349(2) 0.0210(9) Uani 1 1 d .
H11A H 0.0844 0.0050 0.5982 0.025 Uiso 1 1 calc R
H11B H 0.0717 0.0797 0.6707 0.025 Uiso 1 1 calc R
C12 C 0.2542(4) -0.0080(4) 0.65947(19) 0.0193(9) Uani 1 1 d .
C13 C 0.0632(4) 0.2686(5) 0.6244(2) 0.0245(10) Uani 1 1 d .
H13A H -0.0240 0.2270 0.6079 0.029 Uiso 1 1 calc R
H13B H 0.0797 0.3345 0.5994 0.029 Uiso 1 1 calc R
C14 C 0.0551(4) 0.3263(4) 0.6980(2) 0.0219(9) Uani 1 1 d .
C15 C 0.7986(4) 0.1365(4) 0.0127(2) 0.0227(10) Uani 1 1 d .
H15A H 0.7862 0.0563 0.0261 0.027 Uiso 1 1 calc R
H15B H 0.8277 0.1212 -0.0327 0.027 Uiso 1 1 calc R
C16 C 0.6625(4) 0.1998(5) 0.0143(2) 0.0244(10) Uani 1 1 d .
H16A H 0.6726 0.2751 -0.0041 0.029 Uiso 1 1 calc R
H16B H 0.5953 0.1447 -0.0140 0.029 Uiso 1 1 calc R
C17 C 1.0253(4) 0.1365(4) 0.0718(2) 0.0226(9) Uani 1 1 d .
H17A H 1.0858 0.1278 0.0352 0.027 Uiso 1 1 calc R
H17B H 0.9922 0.0536 0.0758 0.027 Uiso 1 1 calc R
C18 C 1.1049(4) 0.1973(5) 0.1361(2) 0.0247(10) Uani 1 1 d .
H18A H 1.1837 0.1486 0.1430 0.030 Uiso 1 1 calc R
H18B H 1.1377 0.2802 0.1322 0.030 Uiso 1 1 calc R
C19 C 0.9561(4) 0.3251(4) 0.0341(2) 0.0218(9) Uani 1 1 d .
H19A H 1.0062 0.3784 0.0714 0.026 Uiso 1 1 calc R
H19B H 0.8766 0.3693 0.0230 0.026 Uiso 1 1 calc R
C20 C 1.0465(4) 0.3085(4) -0.0253(2) 0.0231(10) Uani 1 1 d .
C21 C 0.5215(4) 0.1355(4) 0.1001(2) 0.0201(9) Uani 1 1 d .
H21A H 0.5595 0.0548 0.0849 0.024 Uiso 1 1 calc R
H21B H 0.4324 0.1357 0.0774 0.024 Uiso 1 1 calc R
C22 C 0.5045(4) 0.1533(4) 0.1754(2) 0.0204(9) Uani 1 1 d .
C23 C 0.5359(4) 0.3505(4) 0.0882(2) 0.0245(10) Uani 1 1 d .
H23A H 0.4719 0.3535 0.1232 0.029 Uiso 1 1 calc R
H23B H 0.4838 0.3510 0.0467 0.029 Uiso 1 1 calc R
C24 C 0.6319(4) 0.4649(4) 0.1040(2) 0.0199(9) Uani 1 1 d .
C25 C 1.0078(4) 0.0863(4) 0.2192(2) 0.0239(10) Uani 1 1 d .
H25A H 0.9998 0.1044 0.2671 0.029 Uiso 1 1 calc R
H25B H 1.0919 0.0430 0.2106 0.029 Uiso 1 1 calc R
C26 C 0.8879(4) -0.0008(4) 0.1877(2) 0.0187(9) Uani 1 1 d .
C27 C 1.0717(4) 0.3072(4) 0.2501(2) 0.0230(10) Uani 1 1 d .
H27A H 1.0984 0.3799 0.2319 0.028 Uiso 1 1 calc R
H27B H 1.1523 0.2796 0.2716 0.028 Uiso 1 1 calc R
C28 C 0.9657(4) 0.3435(4) 0.3016(2) 0.0218(9) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O14 Eu1 O2W 93.05(12) 2_656 .
O14 Eu1 O1W 80.31(11) 2_656 .
O2W Eu1 O1W 145.33(11) . .
O14 Eu1 O15 122.92(11) 2_656 1_456
O2W Eu1 O15 75.36(11) . 1_456
O1W Eu1 O15 79.93(11) . 1_456
O14 Eu1 O9 84.18(11) 2_656 .
O2W Eu1 O9 138.61(10) . .
O1W Eu1 O9 74.96(10) . .
O15 Eu1 O9 139.01(10) 1_456 .
O14 Eu1 O7 72.71(10) 2_656 .
O2W Eu1 O7 72.67(10) . .
O1W Eu1 O7 134.93(10) . .
O15 Eu1 O7 145.14(10) 1_456 .
O9 Eu1 O7 67.09(9) . .
O14 Eu1 O16 70.90(10) 2_656 1_456
O2W Eu1 O16 73.38(12) . 1_456
O1W Eu1 O16 72.29(11) . 1_456
O15 Eu1 O16 52.11(11) 1_456 1_456
O9 Eu1 O16 141.49(11) . 1_456
O7 Eu1 O16 127.88(10) . 1_456
O14 Eu1 O19 150.31(10) 2_656 2_666
O2W Eu1 O19 76.11(11) . 2_666
O1W Eu1 O19 123.87(10) . 2_666
O15 Eu1 O19 81.55(10) 1_456 2_666
O9 Eu1 O19 86.16(10) . 2_666
O7 Eu1 O19 77.66(10) . 2_666
O16 Eu1 O19 129.27(10) 1_456 2_666
O14 Eu1 O20 145.97(11) 2_656 2_666
O2W Eu1 O20 120.93(12) . 2_666
O1W Eu1 O20 72.63(11) . 2_666
O15 Eu1 O20 72.53(11) 1_456 2_666
O9 Eu1 O20 69.33(11) . 2_666
O7 Eu1 O20 113.21(10) . 2_666
O16 Eu1 O20 117.94(11) 1_456 2_666
O19 Eu1 O20 51.28(10) 2_666 2_666
O14 Eu1 C20 97.00(12) 2_656 1_456
O2W Eu1 C20 70.95(12) . 1_456
O1W Eu1 C20 76.13(12) . 1_456
O15 Eu1 C20 26.10(12) 1_456 1_456
O9 Eu1 C20 150.43(11) . 1_456
O7 Eu1 C20 141.50(11) . 1_456
O16 Eu1 C20 26.10(12) 1_456 1_456
O19 Eu1 C20 105.07(12) 2_666 1_456
O20 Eu1 C20 96.14(12) 2_666 1_456
O14 Eu1 C24 159.78(10) 2_656 2_666
O2W Eu1 C24 99.31(13) . 2_666
O1W Eu1 C24 97.87(12) . 2_666
O15 Eu1 C24 76.02(11) 1_456 2_666
O9 Eu1 C24 75.96(11) . 2_666
O7 Eu1 C24 95.70(11) . 2_666
O16 Eu1 C24 128.01(11) 1_456 2_666
O19 Eu1 C24 26.05(11) 2_666 2_666
O20 Eu1 C24 25.24(11) 2_666 2_666
C20 Eu1 C24 102.12(13) 1_456 2_666
O14 Eu1 Cd1 75.15(7) 2_656 .
O2W Eu1 Cd1 105.86(8) . .
O1W Eu1 Cd1 105.17(7) . .
O15 Eu1 Cd1 161.93(8) 1_456 .
O9 Eu1 Cd1 33.61(7) . .
O7 Eu1 Cd1 33.50(6) . .
O16 Eu1 Cd1 145.92(7) 1_456 .
O19 Eu1 Cd1 81.31(7) 2_666 .
O20 Eu1 Cd1 92.19(8) 2_666 .
C20 Eu1 Cd1 171.54(10) 1_456 .
C24 Eu1 Cd1 86.05(8) 2_666 .
O6 Eu2 O4W 91.99(12) 2_656 .
O6 Eu2 O2 123.62(10) 2_656 .
O4W Eu2 O2 74.99(11) . .
O6 Eu2 O3W 80.57(11) 2_656 .
O4W Eu2 O3W 144.58(11) . .
O2 Eu2 O3W 80.54(11) . .
O6 Eu2 O4 145.82(11) 2_656 2_666
O4W Eu2 O4 122.18(12) . 2_666
O2 Eu2 O4 71.94(11) . 2_666
O3W Eu2 O4 71.96(11) . 2_666
O6 Eu2 O18 84.26(10) 2_656 .
O4W Eu2 O18 139.89(10) . .
O2 Eu2 O18 138.46(10) . .
O3W Eu2 O18 74.19(10) . .
O4 Eu2 O18 69.16(10) 2_666 .
O6 Eu2 O11 71.77(10) 2_656 .
O4W Eu2 O11 72.52(10) . .
O2 Eu2 O11 144.49(11) . .
O3W Eu2 O11 134.95(10) . .
O4 Eu2 O11 114.75(10) 2_666 .
O18 Eu2 O11 68.38(9) . .
O6 Eu2 O3 150.74(10) 2_656 2_666
O4W Eu2 O3 77.07(11) . 2_666
O2 Eu2 O3 80.12(10) . 2_666
O3W Eu2 O3 123.55(10) . 2_666
O4 Eu2 O3 51.65(10) 2_666 2_666
O18 Eu2 O3 86.99(10) . 2_666
O11 Eu2 O3 79.04(9) . 2_666
O6 Eu2 O1 71.74(10) 2_656 .
O4W Eu2 O1 74.45(12) . .
O2 Eu2 O1 51.88(10) . .
O3W Eu2 O1 70.31(11) . .
O4 Eu2 O1 115.53(11) 2_666 .
O18 Eu2 O1 139.66(11) . .
O11 Eu2 O1 129.02(10) . .
O3 Eu2 O1 128.81(10) 2_666 .
O6 Eu2 C2 97.41(12) 2_656 .
O4W Eu2 C2 72.27(12) . .
O2 Eu2 C2 26.23(11) . .
O3W Eu2 C2 74.43(12) . .
O4 Eu2 C2 94.45(12) 2_666 .
O18 Eu2 C2 147.84(11) . .
O11 Eu2 C2 142.65(11) . .
O3 Eu2 C2 104.69(11) 2_666 .
O1 Eu2 C2 25.67(12) . .
O6 Eu2 C10 160.66(11) 2_656 2_666
O4W Eu2 C10 100.25(13) . 2_666
O2 Eu2 C10 74.45(10) . 2_666
O3W Eu2 C10 97.35(12) . 2_666
O4 Eu2 C10 25.42(11) 2_666 2_666
O18 Eu2 C10 76.72(11) . 2_666
O11 Eu2 C10 97.56(11) . 2_666
O3 Eu2 C10 26.23(11) 2_666 2_666
O1 Eu2 C10 125.90(10) . 2_666
C2 Eu2 C10 100.55(12) . 2_666
O6 Eu2 Cd2 76.56(7) 2_656 .
O4W Eu2 Cd2 106.75(8) . .
O2 Eu2 Cd2 159.82(7) . .
O3W Eu2 Cd2 105.06(7) . .
O4 Eu2 Cd2 91.11(8) 2_666 .
O18 Eu2 Cd2 33.60(7) . .
O11 Eu2 Cd2 34.80(6) . .
O3 Eu2 Cd2 80.74(7) 2_666 .
O1 Eu2 Cd2 148.30(7) . .
C2 Eu2 Cd2 173.91(9) . .
C10 Eu2 Cd2 85.54(8) 2_666 .
O7 Cd1 N3 137.14(11) . .
O7 Cd1 O9 71.78(10) . .
N3 Cd1 O9 71.58(11) . .
O7 Cd1 N2 71.87(11) . .
N3 Cd1 N2 150.19(11) . .
O9 Cd1 N2 125.92(11) . .
O7 Cd1 O3 90.27(10) . .
N3 Cd1 O3 74.39(11) . .
O9 Cd1 O3 99.05(11) . .
N2 Cd1 O3 119.68(11) . .
O7 Cd1 O5 103.08(11) . .
N3 Cd1 O5 90.97(11) . .
O9 Cd1 O5 79.00(11) . .
N2 Cd1 O5 71.89(11) . .
O3 Cd1 O5 164.96(10) . .
O7 Cd1 N1 144.21(11) . .
N3 Cd1 N1 77.35(11) . .
O9 Cd1 N1 142.60(11) . .
N2 Cd1 N1 76.09(11) . .
O3 Cd1 N1 91.98(11) . .
O5 Cd1 N1 81.27(11) . .
O7 Cd1 Eu1 36.26(7) . .
N3 Cd1 Eu1 105.00(8) . .
O9 Cd1 Eu1 35.55(7) . .
N2 Cd1 Eu1 99.37(8) . .
O3 Cd1 Eu1 96.89(7) . .
O5 Cd1 Eu1 90.10(7) . .
N1 Cd1 Eu1 171.13(9) . .
O18 Cd2 N6 124.19(11) . .
O18 Cd2 O19 98.90(10) . .
N6 Cd2 O19 125.33(11) . .
O18 Cd2 N5 71.22(11) . .
N6 Cd2 N5 147.69(11) . .
O19 Cd2 N5 72.05(11) . .
O18 Cd2 O11 73.05(10) . .
N6 Cd2 O11 71.39(10) . .
O19 Cd2 O11 94.58(11) . .
N5 Cd2 O11 139.03(10) . .
O18 Cd2 O13 77.05(10) . .
N6 Cd2 O13 71.36(11) . .
O19 Cd2 O13 159.06(10) . .
N5 Cd2 O13 87.32(11) . .
O11 Cd2 O13 103.61(11) . .
O18 Cd2 N4 141.06(11) . .
N6 Cd2 N4 76.45(12) . .
O19 Cd2 N4 90.84(11) . .
N5 Cd2 N4 76.31(12) . .
O11 Cd2 N4 143.94(11) . .
O13 Cd2 N4 80.59(11) . .
O18 Cd2 Eu2 35.94(7) . .
N6 Cd2 Eu2 99.79(8) . .
O19 Cd2 Eu2 97.44(7) . .
N5 Cd2 Eu2 104.73(8) . .
O11 Cd2 Eu2 37.13(7) . .
O13 Cd2 Eu2 91.08(7) . .
N4 Cd2 Eu2 171.58(9) . .
C2 O1 Eu2 91.1(3) . .
Eu1 O1W H1WA 110.1 . .
Eu1 O1W H1WB 109.8 . .
H1WA O1W H1WB 109.0 . .
C2 O2 Eu2 95.7(2) . .
Eu1 O2W H2WA 111.7 . .
Eu1 O2W H2WB 112.2 . .
H2WA O2W H2WB 107.0 . .
C10 O3 Cd1 114.3(3) . .
C10 O3 Eu2 91.4(3) . 2_666
Cd1 O3 Eu2 153.85(13) . 2_666
Eu2 O3W H3WA 111.4 . .
Eu2 O3W H3WB 111.6 . .
H3WA O3W H3WB 107.3 . .
C10 O4 Eu2 95.3(3) . 2_666
Eu2 O4W H4WA 109.6 . .
Eu2 O4W H4WB 132.3 . .
H4WA O4W H4WB 107.0 . .
C12 O5 Cd1 115.6(3) . .
C12 O6 Eu2 133.6(3) . 2_656
H6WA O6W H6WB 118.6 . .
C14 O7 Cd1 113.7(2) . .
C14 O7 Eu1 133.7(3) . .
Cd1 O7 Eu1 110.23(11) . .
H7WA O7W H7WB 109.5 . .
C8 O9 Cd1 114.8(2) . .
C8 O9 Eu1 134.3(3) . .
Cd1 O9 Eu1 110.85(11) . .
C28 O11 Cd2 115.4(2) . .
C28 O11 Eu2 130.6(3) . .
Cd2 O11 Eu2 108.07(11) . .
C26 O13 Cd2 115.1(3) . .
C26 O14 Eu1 133.5(3) . 2_656
C20 O15 Eu1 94.5(3) . 1_654
C20 O16 Eu1 91.7(3) . 1_654
C22 O18 Cd2 114.6(2) . .
C22 O18 Eu2 134.8(3) . .
Cd2 O18 Eu2 110.46(11) . .
C24 O19 Cd2 116.0(3) . .
C24 O19 Eu1 93.1(3) . 2_666
Cd2 O19 Eu1 150.46(13) . 2_666
C24 O20 Eu1 94.0(3) . 2_666
C1 N1 C4 111.0(3) . .
C1 N1 C3 114.4(3) . .
C4 N1 C3 113.0(3) . .
C1 N1 Cd1 112.3(2) . .
C4 N1 Cd1 105.0(2) . .
C3 N1 Cd1 100.3(2) . .
C13 N2 C11 110.9(3) . .
C13 N2 C5 112.0(3) . .
C11 N2 C5 111.8(3) . .
C13 N2 Cd1 104.7(3) . .
C11 N2 Cd1 107.5(2) . .
C5 N2 Cd1 109.5(2) . .
C7 N3 C9 109.9(3) . .
C7 N3 C6 113.2(3) . .
C9 N3 C6 111.3(3) . .
C7 N3 Cd1 106.0(2) . .
C9 N3 Cd1 107.2(2) . .
C6 N3 Cd1 108.9(2) . .
C19 N4 C15 114.5(3) . .
C19 N4 C17 110.3(3) . .
C15 N4 C17 113.1(4) . .
C19 N4 Cd2 111.2(2) . .
C15 N4 Cd2 102.6(2) . .
C17 N4 Cd2 104.4(2) . .
C21 N5 C23 109.1(3) . .
C21 N5 C16 113.6(3) . .
C23 N5 C16 109.8(3) . .
C21 N5 Cd2 105.6(2) . .
C23 N5 Cd2 108.8(2) . .
C16 N5 Cd2 109.8(2) . .
C27 N6 C25 109.8(3) . .
C27 N6 C18 111.3(3) . .
C25 N6 C18 111.9(3) . .
C27 N6 Cd2 106.0(2) . .
C25 N6 Cd2 109.2(2) . .
C18 N6 Cd2 108.4(2) . .
N1 C1 C2 118.0(3) . .
N1 C1 H1A 107.8 . .
C2 C1 H1A 107.8 . .
N1 C1 H1B 107.8 . .
C2 C1 H1B 107.8 . .
H1A C1 H1B 107.1 . .
O1 C2 O2 121.3(4) . .
O1 C2 C1 123.0(4) . .
O2 C2 C1 115.6(4) . .
O1 C2 Eu2 63.3(2) . .
O2 C2 Eu2 58.1(2) . .
C1 C2 Eu2 171.6(3) . .
N1 C3 C6 112.2(3) . .
N1 C3 H3A 109.2 . .
C6 C3 H3A 109.2 . .
N1 C3 H3B 109.2 . .
C6 C3 H3B 109.2 . .
H3A C3 H3B 107.9 . .
N1 C4 C5 111.2(3) . .
N1 C4 H4A 109.4 . .
C5 C4 H4A 109.4 . .
N1 C4 H4B 109.4 . .
C5 C4 H4B 109.4 . .
H4A C4 H4B 108.0 . .
N2 C5 C4 113.0(3) . .
N2 C5 H5A 109.0 . .
C4 C5 H5A 109.0 . .
N2 C5 H5B 109.0 . .
C4 C5 H5B 109.0 . .
H5A C5 H5B 107.8 . .
N3 C6 C3 114.1(3) . .
N3 C6 H6A 108.7 . .
C3 C6 H6A 108.7 . .
N3 C6 H6B 108.7 . .
C3 C6 H6B 108.7 . .
H6A C6 H6B 107.6 . .
N3 C7 C8 112.7(3) . .
N3 C7 H7A 109.0 . .
C8 C7 H7A 109.0 . .
N3 C7 H7B 109.0 . .
C8 C7 H7B 109.0 . .
H7A C7 H7B 107.8 . .
O10 C8 O9 124.9(4) . .
O10 C8 C7 117.5(4) . .
O9 C8 C7 117.6(4) . .
N3 C9 C10 114.3(3) . .
N3 C9 H9A 108.7 . .
C10 C9 H9A 108.7 . .
N3 C9 H9B 108.7 . .
C10 C9 H9B 108.7 . .
H9A C9 H9B 107.6 . .
O4 C10 O3 121.6(4) . .
O4 C10 C9 118.2(4) . .
O3 C10 C9 120.1(4) . .
O4 C10 Eu2 59.3(2) . 2_666
O3 C10 Eu2 62.3(2) . 2_666
C9 C10 Eu2 176.6(3) . 2_666
N2 C11 C12 114.7(3) . .
N2 C11 H11A 108.6 . .
C12 C11 H11A 108.6 . .
N2 C11 H11B 108.6 . .
C12 C11 H11B 108.6 . .
H11A C11 H11B 107.6 . .
O6 C12 O5 125.1(4) . .
O6 C12 C11 116.5(4) . .
O5 C12 C11 118.4(4) . .
N2 C13 C14 112.8(3) . .
N2 C13 H13A 109.0 . .
C14 C13 H13A 109.0 . .
N2 C13 H13B 109.0 . .
C14 C13 H13B 109.0 . .
H13A C13 H13B 107.8 . .
O8 C14 O7 124.9(4) . .
O8 C14 C13 116.6(4) . .
O7 C14 C13 118.4(4) . .
N4 C15 C16 113.1(4) . .
N4 C15 H15A 109.0 . .
C16 C15 H15A 109.0 . .
N4 C15 H15B 109.0 . .
C16 C15 H15B 109.0 . .
H15A C15 H15B 107.8 . .
N5 C16 C15 113.7(3) . .
N5 C16 H16A 108.8 . .
C15 C16 H16A 108.8 . .
N5 C16 H16B 108.8 . .
C15 C16 H16B 108.8 . .
H16A C16 H16B 107.7 . .
N4 C17 C18 111.5(3) . .
N4 C17 H17A 109.3 . .
C18 C17 H17A 109.3 . .
N4 C17 H17B 109.3 . .
C18 C17 H17B 109.3 . .
H17A C17 H17B 108.0 . .
N6 C18 C17 111.7(3) . .
N6 C18 H18A 109.3 . .
C17 C18 H18A 109.3 . .
N6 C18 H18B 109.3 . .
C17 C18 H18B 109.3 . .
H18A C18 H18B 107.9 . .
N4 C19 C20 117.6(3) . .
N4 C19 H19A 107.9 . .
C20 C19 H19A 107.9 . .
N4 C19 H19B 107.9 . .
C20 C19 H19B 107.9 . .
H19A C19 H19B 107.2 . .
O16 C20 O15 121.3(4) . .
O16 C20 C19 121.3(4) . .
O15 C20 C19 117.3(4) . .
O16 C20 Eu1 62.2(2) . 1_654
O15 C20 Eu1 59.4(2) . 1_654
C19 C20 Eu1 171.2(3) . 1_654
N5 C21 C22 112.4(3) . .
N5 C21 H21A 109.1 . .
C22 C21 H21A 109.1 . .
N5 C21 H21B 109.1 . .
C22 C21 H21B 109.1 . .
H21A C21 H21B 107.9 . .
O17 C22 O18 124.8(4) . .
O17 C22 C21 116.8(4) . .
O18 C22 C21 118.4(4) . .
N5 C23 C24 111.9(3) . .
N5 C23 H23A 109.2 . .
C24 C23 H23A 109.2 . .
N5 C23 H23B 109.2 . .
C24 C23 H23B 109.2 . .
H23A C23 H23B 107.9 . .
O20 C24 O19 121.6(4) . .
O20 C24 C23 118.9(4) . .
O19 C24 C23 119.4(4) . .
O20 C24 Eu1 60.7(2) . 2_666
O19 C24 Eu1 60.9(2) . 2_666
C23 C24 Eu1 176.0(3) . 2_666
N6 C25 C26 114.9(4) . .
N6 C25 H25A 108.5 . .
C26 C25 H25A 108.5 . .
N6 C25 H25B 108.5 . .
C26 C25 H25B 108.5 . .
H25A C25 H25B 107.5 . .
O14 C26 O13 125.1(4) . .
O14 C26 C25 115.5(4) . .
O13 C26 C25 119.3(4) . .
N6 C27 C28 112.0(3) . .
N6 C27 H27A 109.2 . .
C28 C27 H27A 109.2 . .
N6 C27 H27B 109.2 . .
C28 C27 H27B 109.2 . .
H27A C27 H27B 107.9 . .
O12 C28 O11 124.8(4) . .
O12 C28 C27 117.8(4) . .
O11 C28 C27 117.4(4) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O14 2.392(3) 2_656
Eu1 O2W 2.430(3) .
Eu1 O1W 2.449(3) .
Eu1 O15 2.466(3) 1_456
Eu1 O9 2.479(3) .
Eu1 O7 2.512(3) .
Eu1 O16 2.529(3) 1_456
Eu1 O19 2.545(3) 2_666
Eu1 O20 2.545(3) 2_666
Eu1 C20 2.857(4) 1_456
Eu1 C24 2.910(5) 2_666
Eu1 Cd1 3.9847(11) .
Eu2 O6 2.410(3) 2_656
Eu2 O4W 2.424(3) .
Eu2 O2 2.453(3) .
Eu2 O3W 2.456(3) .
Eu2 O4 2.496(3) 2_666
Eu2 O18 2.496(3) .
Eu2 O11 2.530(3) .
Eu2 O3 2.560(3) 2_666
Eu2 O1 2.568(3) .
Eu2 C2 2.875(4) .
Eu2 C10 2.890(4) 2_666
Eu2 Cd2 3.9844(11) .
Cd1 O7 2.344(3) .
Cd1 N3 2.358(3) .
Cd1 O9 2.360(3) .
Cd1 N2 2.360(4) .
Cd1 O3 2.365(3) .
Cd1 O5 2.391(3) .
Cd1 N1 2.461(3) .
Cd2 O18 2.354(3) .
Cd2 N6 2.367(3) .
Cd2 O19 2.379(3) .
Cd2 N5 2.384(3) .
Cd2 O11 2.392(3) .
Cd2 O13 2.417(3) .
Cd2 N4 2.456(3) .
O1 C2 1.246(5) .
O1W H1WA 0.8625 .
O1W H1WB 0.8624 .
O2 C2 1.277(5) .
O2W H2WA 0.9019 .
O2W H2WB 0.9026 .
O3 C10 1.278(5) .
O3 Eu2 2.560(3) 2_666
O3W H3WA 0.8953 .
O3W H3WB 0.8964 .
O4 C10 1.246(6) .
O4 Eu2 2.496(3) 2_666
O4W H4WA 0.8581 .
O4W H4WB 0.8508 .
O5 C12 1.260(5) .
O6 C12 1.257(5) .
O6 Eu2 2.410(3) 2_656
O6W H6WA 0.8501 .
O6W H6WB 0.8504 .
O7 C14 1.284(5) .
O7W H7WA 0.8501 .
O7W H7WB 0.8500 .
O8 C14 1.232(5) .
O9 C8 1.290(5) .
O10 C8 1.231(5) .
O11 C28 1.285(5) .
O12 C28 1.241(5) .
O13 C26 1.259(5) .
O14 C26 1.258(5) .
O14 Eu1 2.392(3) 2_656
O15 C20 1.261(6) .
O15 Eu1 2.466(3) 1_654
O16 C20 1.257(6) .
O16 Eu1 2.529(3) 1_654
O17 C22 1.235(5) .
O18 C22 1.289(5) .
O19 C24 1.280(5) .
O19 Eu1 2.545(3) 2_666
O20 C24 1.244(5) .
O20 Eu1 2.545(3) 2_666
N1 C1 1.470(5) .
N1 C4 1.483(6) .
N1 C3 1.499(5) .
N2 C13 1.476(5) .
N2 C11 1.482(6) .
N2 C5 1.491(5) .
N3 C7 1.467(5) .
N3 C9 1.485(6) .
N3 C6 1.495(5) .
N4 C19 1.477(6) .
N4 C15 1.486(6) .
N4 C17 1.486(5) .
N5 C21 1.467(5) .
N5 C23 1.484(5) .
N5 C16 1.488(5) .
N6 C27 1.481(5) .
N6 C25 1.487(6) .
N6 C18 1.493(5) .
C1 C2 1.525(5) .
C1 H1A 0.9700 .
C1 H1B 0.9700 .
C3 C6 1.521(6) .
C3 H3A 0.9700 .
C3 H3B 0.9700 .
C4 C5 1.528(6) .
C4 H4A 0.9700 .
C4 H4B 0.9700 .
C5 H5A 0.9700 .
C5 H5B 0.9700 .
C6 H6A 0.9700 .
C6 H6B 0.9700 .
C7 C8 1.534(6) .
C7 H7A 0.9700 .
C7 H7B 0.9700 .
C9 C10 1.519(6) .
C9 H9A 0.9700 .
C9 H9B 0.9700 .
C10 Eu2 2.890(4) 2_666
C11 C12 1.532(6) .
C11 H11A 0.9700 .
C11 H11B 0.9700 .
C13 C14 1.528(6) .
C13 H13A 0.9700 .
C13 H13B 0.9700 .
C15 C16 1.521(6) .
C15 H15A 0.9700 .
C15 H15B 0.9700 .
C16 H16A 0.9700 .
C16 H16B 0.9700 .
C17 C18 1.524(6) .
C17 H17A 0.9700 .
C17 H17B 0.9700 .
C18 H18A 0.9700 .
C18 H18B 0.9700 .
C19 C20 1.525(6) .
C19 H19A 0.9700 .
C19 H19B 0.9700 .
C20 Eu1 2.857(4) 1_654
C21 C22 1.533(6) .
C21 H21A 0.9700 .
C21 H21B 0.9700 .
C23 C24 1.516(6) .
C23 H23A 0.9700 .
C23 H23B 0.9700 .
C24 Eu1 2.910(5) 2_666
C25 C26 1.527(6) .
C25 H25A 0.9700 .
C25 H25B 0.9700 .
C27 C28 1.525(6) .
C27 H27A 0.9700 .
C27 H27B 0.9700 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O14 Eu1 Cd1 O7 80.99(15) 2_656 .
O2W Eu1 Cd1 O7 -7.97(16) . .
O1W Eu1 Cd1 O7 156.37(15) . .
O15 Eu1 Cd1 O7 -99.4(3) 1_456 .
O9 Eu1 Cd1 O7 -176.94(19) . .
O16 Eu1 Cd1 O7 75.7(2) 1_456 .
O19 Eu1 Cd1 O7 -80.76(15) 2_666 .
O20 Eu1 Cd1 O7 -131.04(15) 2_666 .
C20 Eu1 Cd1 O7 58.7(6) 1_456 .
C24 Eu1 Cd1 O7 -106.54(15) 2_666 .
O14 Eu1 Cd1 N3 -122.40(12) 2_656 .
O2W Eu1 Cd1 N3 148.64(13) . .
O1W Eu1 Cd1 N3 -47.02(12) . .
O15 Eu1 Cd1 N3 57.3(3) 1_456 .
O9 Eu1 Cd1 N3 -20.33(17) . .
O7 Eu1 Cd1 N3 156.61(16) . .
O16 Eu1 Cd1 N3 -127.71(17) 1_456 .
O19 Eu1 Cd1 N3 75.85(11) 2_666 .
O20 Eu1 Cd1 N3 25.57(12) 2_666 .
C20 Eu1 Cd1 N3 -144.7(6) 1_456 .
C24 Eu1 Cd1 N3 50.07(12) 2_666 .
O14 Eu1 Cd1 O9 -102.08(16) 2_656 .
O2W Eu1 Cd1 O9 168.96(17) . .
O1W Eu1 Cd1 O9 -26.69(16) . .
O15 Eu1 Cd1 O9 77.6(3) 1_456 .
O7 Eu1 Cd1 O9 176.94(19) . .
O16 Eu1 Cd1 O9 -107.4(2) 1_456 .
O19 Eu1 Cd1 O9 96.18(16) 2_666 .
O20 Eu1 Cd1 O9 45.90(16) 2_666 .
C20 Eu1 Cd1 O9 -124.4(6) 1_456 .
C24 Eu1 Cd1 O9 70.40(17) 2_666 .
O14 Eu1 Cd1 N2 40.28(12) 2_656 .
O2W Eu1 Cd1 N2 -48.68(13) . .
O1W Eu1 Cd1 N2 115.66(12) . .
O15 Eu1 Cd1 N2 -140.1(3) 1_456 .
O9 Eu1 Cd1 N2 142.36(17) . .
O7 Eu1 Cd1 N2 -40.71(16) . .
O16 Eu1 Cd1 N2 34.97(17) 1_456 .
O19 Eu1 Cd1 N2 -121.47(11) 2_666 .
O20 Eu1 Cd1 N2 -171.75(11) 2_666 .
C20 Eu1 Cd1 N2 18.0(6) 1_456 .
C24 Eu1 Cd1 N2 -147.25(12) 2_666 .
O14 Eu1 Cd1 O3 161.97(10) 2_656 .
O2W Eu1 Cd1 O3 73.01(12) . .
O1W Eu1 Cd1 O3 -122.64(11) . .
O15 Eu1 Cd1 O3 -18.4(3) 1_456 .
O9 Eu1 Cd1 O3 -95.95(16) . .
O7 Eu1 Cd1 O3 80.99(15) . .
O16 Eu1 Cd1 O3 156.66(16) 1_456 .
O19 Eu1 Cd1 O3 0.23(9) 2_666 .
O20 Eu1 Cd1 O3 -50.05(10) 2_666 .
C20 Eu1 Cd1 O3 139.7(6) 1_456 .
C24 Eu1 Cd1 O3 -25.55(11) 2_666 .
O14 Eu1 Cd1 O5 -31.38(11) 2_656 .
O2W Eu1 Cd1 O5 -120.34(12) . .
O1W Eu1 Cd1 O5 44.01(11) . .
O15 Eu1 Cd1 O5 148.3(3) 1_456 .
O9 Eu1 Cd1 O5 70.70(16) . .
O7 Eu1 Cd1 O5 -112.36(15) . .
O16 Eu1 Cd1 O5 -36.69(17) 1_456 .
O19 Eu1 Cd1 O5 166.88(10) 2_666 .
O20 Eu1 Cd1 O5 116.60(11) 2_666 .
C20 Eu1 Cd1 O5 -53.7(6) 1_456 .
C24 Eu1 Cd1 O5 141.10(11) 2_666 .
O14 Eu1 Cd1 N1 -18.2(5) 2_656 .
O2W Eu1 Cd1 N1 -107.1(5) . .
O1W Eu1 Cd1 N1 57.2(5) . .
O15 Eu1 Cd1 N1 161.5(6) 1_456 .
O9 Eu1 Cd1 N1 83.9(5) . .
O7 Eu1 Cd1 N1 -99.2(5) . .
O16 Eu1 Cd1 N1 -23.5(5) 1_456 .
O19 Eu1 Cd1 N1 -179.9(5) 2_666 .
O20 Eu1 Cd1 N1 129.8(5) 2_666 .
C20 Eu1 Cd1 N1 -40.5(8) 1_456 .
C24 Eu1 Cd1 N1 154.3(5) 2_666 .
O6 Eu2 Cd2 O18 100.01(15) 2_656 .
O4W Eu2 Cd2 O18 -171.97(16) . .
O2 Eu2 Cd2 O18 -80.0(3) . .
O3W Eu2 Cd2 O18 23.83(15) . .
O4 Eu2 Cd2 O18 -47.77(15) 2_666 .
O11 Eu2 Cd2 O18 177.33(18) . .
O3 Eu2 Cd2 O18 -98.58(15) 2_666 .
O1 Eu2 Cd2 O18 100.6(2) . .
C2 Eu2 Cd2 O18 108.2(9) . .
C10 Eu2 Cd2 O18 -72.60(16) 2_666 .
O6 Eu2 Cd2 N6 -37.17(12) 2_656 .
O4W Eu2 Cd2 N6 50.84(13) . .
O2 Eu2 Cd2 N6 142.8(3) . .
O3W Eu2 Cd2 N6 -113.36(12) . .
O4 Eu2 Cd2 N6 175.04(12) 2_666 .
O18 Eu2 Cd2 N6 -137.18(16) . .
O11 Eu2 Cd2 N6 40.14(15) . .
O3 Eu2 Cd2 N6 124.23(11) 2_666 .
O1 Eu2 Cd2 N6 -36.56(18) . .
C2 Eu2 Cd2 N6 -29.0(9) . .
C10 Eu2 Cd2 N6 150.22(13) 2_666 .
O6 Eu2 Cd2 O19 -165.08(11) 2_656 .
O4W Eu2 Cd2 O19 -77.06(12) . .
O2 Eu2 Cd2 O19 14.9(2) . .
O3W Eu2 Cd2 O19 118.74(11) . .
O4 Eu2 Cd2 O19 47.14(11) 2_666 .
O18 Eu2 Cd2 O19 94.91(15) . .
O11 Eu2 Cd2 O19 -87.76(14) . .
O3 Eu2 Cd2 O19 -3.67(9) 2_666 .
O1 Eu2 Cd2 O19 -164.46(17) . .
C2 Eu2 Cd2 O19 -156.9(9) . .
C10 Eu2 Cd2 O19 22.31(11) 2_666 .
O6 Eu2 Cd2 N5 121.61(12) 2_656 .
O4W Eu2 Cd2 N5 -150.38(13) . .
O2 Eu2 Cd2 N5 -58.4(3) . .
O3W Eu2 Cd2 N5 45.42(12) . .
O4 Eu2 Cd2 N5 -26.18(12) 2_666 .
O18 Eu2 Cd2 N5 21.59(16) . .
O11 Eu2 Cd2 N5 -161.08(15) . .
O3 Eu2 Cd2 N5 -76.99(11) 2_666 .
O1 Eu2 Cd2 N5 122.22(18) . .
C2 Eu2 Cd2 N5 129.8(9) . .
C10 Eu2 Cd2 N5 -51.00(13) 2_666 .
O6 Eu2 Cd2 O11 -77.32(15) 2_656 .
O4W Eu2 Cd2 O11 10.70(15) . .
O2 Eu2 Cd2 O11 102.7(3) . .
O3W Eu2 Cd2 O11 -153.50(15) . .
O4 Eu2 Cd2 O11 134.90(15) 2_666 .
O18 Eu2 Cd2 O11 -177.33(18) . .
O3 Eu2 Cd2 O11 84.09(14) 2_666 .
O1 Eu2 Cd2 O11 -76.7(2) . .
C2 Eu2 Cd2 O11 -69.1(9) . .
C10 Eu2 Cd2 O11 110.08(15) 2_666 .
O6 Eu2 Cd2 O13 34.09(10) 2_656 .
O4W Eu2 Cd2 O13 122.11(12) . .
O2 Eu2 Cd2 O13 -145.9(2) . .
O3W Eu2 Cd2 O13 -42.09(11) . .
O4 Eu2 Cd2 O13 -113.69(10) 2_666 .
O18 Eu2 Cd2 O13 -65.92(15) . .
O11 Eu2 Cd2 O13 111.41(14) . .
O3 Eu2 Cd2 O13 -164.50(10) 2_666 .
O1 Eu2 Cd2 O13 34.71(17) . .
C2 Eu2 Cd2 O13 42.3(9) . .
C10 Eu2 Cd2 O13 -138.52(11) 2_666 .
O6 Eu2 Cd2 N4 25.6(6) 2_656 .
O4W Eu2 Cd2 N4 113.6(6) . .
O2 Eu2 Cd2 N4 -154.4(6) . .
O3W Eu2 Cd2 N4 -50.6(6) . .
O4 Eu2 Cd2 N4 -122.2(6) 2_666 .
O18 Eu2 Cd2 N4 -74.4(6) . .
O11 Eu2 Cd2 N4 102.9(6) . .
O3 Eu2 Cd2 N4 -173.0(6) 2_666 .
O1 Eu2 Cd2 N4 26.2(6) . .
C2 Eu2 Cd2 N4 33.7(10) . .
C10 Eu2 Cd2 N4 -147.0(6) 2_666 .
O6 Eu2 O1 C2 178.8(3) 2_656 .
O4W Eu2 O1 C2 81.3(3) . .
O2 Eu2 O1 C2 -1.6(3) . .
O3W Eu2 O1 C2 -95.0(3) . .
O4 Eu2 O1 C2 -37.3(3) 2_666 .
O18 Eu2 O1 C2 -124.7(3) . .
O11 Eu2 O1 C2 132.5(3) . .
O3 Eu2 O1 C2 22.8(3) 2_666 .
C10 Eu2 O1 C2 -10.2(3) 2_666 .
Cd2 Eu2 O1 C2 178.2(2) . .
O6 Eu2 O2 C2 2.0(3) 2_656 .
O4W Eu2 O2 C2 -80.3(3) . .
O3W Eu2 O2 C2 73.9(3) . .
O4 Eu2 O2 C2 147.9(3) 2_666 .
O18 Eu2 O2 C2 126.7(3) . .
O11 Eu2 O2 C2 -104.6(3) . .
O3 Eu2 O2 C2 -159.4(3) 2_666 .
O1 Eu2 O2 C2 1.6(3) . .
C10 Eu2 O2 C2 174.3(3) 2_666 .
Cd2 Eu2 O2 C2 -178.0(2) . .
O7 Cd1 O3 C10 130.6(3) . .
N3 Cd1 O3 C10 -8.9(3) . .
O9 Cd1 O3 C10 59.0(3) . .
N2 Cd1 O3 C10 -160.3(3) . .
O5 Cd1 O3 C10 -22.3(6) . .
N1 Cd1 O3 C10 -85.2(3) . .
Eu1 Cd1 O3 C10 94.8(3) . .
O7 Cd1 O3 Eu2 -60.6(3) . 2_666
N3 Cd1 O3 Eu2 159.9(3) . 2_666
O9 Cd1 O3 Eu2 -132.2(3) . 2_666
N2 Cd1 O3 Eu2 8.5(3) . 2_666
O5 Cd1 O3 Eu2 146.5(3) . 2_666
N1 Cd1 O3 Eu2 83.6(3) . 2_666
Eu1 Cd1 O3 Eu2 -96.4(3) . 2_666
O7 Cd1 O5 C12 43.7(3) . .
N3 Cd1 O5 C12 -177.1(3) . .
O9 Cd1 O5 C12 111.9(3) . .
N2 Cd1 O5 C12 -21.9(3) . .
O3 Cd1 O5 C12 -164.2(3) . .
N1 Cd1 O5 C12 -100.0(3) . .
Eu1 Cd1 O5 C12 77.9(3) . .
N3 Cd1 O7 C14 160.6(3) . .
O9 Cd1 O7 C14 -166.9(3) . .
N2 Cd1 O7 C14 -27.7(3) . .
O3 Cd1 O7 C14 93.6(3) . .
O5 Cd1 O7 C14 -93.3(3) . .
N1 Cd1 O7 C14 -0.1(4) . .
Eu1 Cd1 O7 C14 -165.0(4) . .
N3 Cd1 O7 Eu1 -34.3(2) . .
O9 Cd1 O7 Eu1 -1.87(11) . .
N2 Cd1 O7 Eu1 137.38(15) . .
O3 Cd1 O7 Eu1 -101.32(13) . .
O5 Cd1 O7 Eu1 71.70(13) . .
N1 Cd1 O7 Eu1 164.91(15) . .
O14 Eu1 O7 C14 71.8(4) 2_656 .
O2W Eu1 O7 C14 -27.1(4) . .
O1W Eu1 O7 C14 127.8(4) . .
O15 Eu1 O7 C14 -51.5(5) 1_456 .
O9 Eu1 O7 C14 162.8(4) . .
O16 Eu1 O7 C14 24.4(4) 1_456 .
O19 Eu1 O7 C14 -106.2(4) 2_666 .
O20 Eu1 O7 C14 -144.0(4) 2_666 .
C20 Eu1 O7 C14 -7.4(5) 1_456 .
C24 Eu1 O7 C14 -125.1(4) 2_666 .
Cd1 Eu1 O7 C14 160.9(5) . .
O14 Eu1 O7 Cd1 -89.09(13) 2_656 .
O2W Eu1 O7 Cd1 171.96(16) . .
O1W Eu1 O7 Cd1 -33.1(2) . .
O15 Eu1 O7 Cd1 147.62(14) 1_456 .
O9 Eu1 O7 Cd1 1.84(11) . .
O16 Eu1 O7 Cd1 -136.53(12) 1_456 .
O19 Eu1 O7 Cd1 92.87(13) 2_666 .
O20 Eu1 O7 Cd1 55.09(15) 2_666 .
C20 Eu1 O7 Cd1 -168.36(16) 1_456 .
C24 Eu1 O7 Cd1 73.96(14) 2_666 .
O7 Cd1 O9 C8 178.4(3) . .
N3 Cd1 O9 C8 -24.3(3) . .
N2 Cd1 O9 C8 128.4(3) . .
O3 Cd1 O9 C8 -94.4(3) . .
O5 Cd1 O9 C8 70.5(3) . .
N1 Cd1 O9 C8 11.1(4) . .
Eu1 Cd1 O9 C8 176.4(4) . .
O7 Cd1 O9 Eu1 1.91(12) . .
N3 Cd1 O9 Eu1 159.29(17) . .
N2 Cd1 O9 Eu1 -48.08(19) . .
O3 Cd1 O9 Eu1 89.19(13) . .
O5 Cd1 O9 Eu1 -105.96(14) . .
N1 Cd1 O9 Eu1 -165.38(14) . .
O14 Eu1 O9 C8 -103.7(4) 2_656 .
O2W Eu1 O9 C8 168.3(4) . .
O1W Eu1 O9 C8 -22.2(4) . .
O15 Eu1 O9 C8 32.0(5) 1_456 .
O7 Eu1 O9 C8 -177.3(4) . .
O16 Eu1 O9 C8 -54.7(5) 1_456 .
O19 Eu1 O9 C8 104.5(4) 2_666 .
O20 Eu1 O9 C8 54.6(4) 2_666 .
C20 Eu1 O9 C8 -9.7(6) 1_456 .
C24 Eu1 O9 C8 80.1(4) 2_666 .
Cd1 Eu1 O9 C8 -175.5(5) . .
O14 Eu1 O9 Cd1 71.83(14) 2_656 .
O2W Eu1 O9 Cd1 -16.2(2) . .
O1W Eu1 O9 Cd1 153.32(16) . .
O15 Eu1 O9 Cd1 -152.49(13) 1_456 .
O7 Eu1 O9 Cd1 -1.84(11) . .
O16 Eu1 O9 Cd1 120.81(16) 1_456 .
O19 Eu1 O9 Cd1 -80.06(14) 2_666 .
O20 Eu1 O9 Cd1 -129.92(16) 2_666 .
C20 Eu1 O9 Cd1 165.8(2) 1_456 .
C24 Eu1 O9 Cd1 -104.36(15) 2_666 .
O18 Cd2 O11 C28 154.2(3) . .
N6 Cd2 O11 C28 17.9(3) . .
O19 Cd2 O11 C28 -107.9(3) . .
N5 Cd2 O11 C28 -175.6(3) . .
O13 Cd2 O11 C28 82.5(3) . .
N4 Cd2 O11 C28 -10.1(4) . .
Eu2 Cd2 O11 C28 155.8(4) . .
O18 Cd2 O11 Eu2 -1.64(11) . .
N6 Cd2 O11 Eu2 -137.90(15) . .
O19 Cd2 O11 Eu2 96.28(12) . .
N5 Cd2 O11 Eu2 28.6(2) . .
O13 Cd2 O11 Eu2 -73.28(13) . .
N4 Cd2 O11 Eu2 -165.96(15) . .
O6 Eu2 O11 C28 -58.3(4) 2_656 .
O4W Eu2 O11 C28 39.9(4) . .
O2 Eu2 O11 C28 64.6(4) . .
O3W Eu2 O11 C28 -113.3(4) . .
O4 Eu2 O11 C28 157.9(3) 2_666 .
O18 Eu2 O11 C28 -149.3(4) . .
O3 Eu2 O11 C28 119.6(4) 2_666 .
O1 Eu2 O11 C28 -12.0(4) . .
C2 Eu2 O11 C28 19.7(5) . .
C10 Eu2 O11 C28 138.3(4) 2_666 .
Cd2 Eu2 O11 C28 -150.9(4) . .
O6 Eu2 O11 Cd2 92.58(13) 2_656 .
O4W Eu2 O11 Cd2 -169.26(15) . .
O2 Eu2 O11 Cd2 -144.59(14) . .
O3W Eu2 O11 Cd2 37.51(19) . .
O4 Eu2 O11 Cd2 -51.25(15) 2_666 .
O18 Eu2 O11 Cd2 1.59(11) . .
O3 Eu2 O11 Cd2 -89.51(12) 2_666 .
O1 Eu2 O11 Cd2 138.83(12) . .
C2 Eu2 O11 Cd2 170.59(16) . .
C10 Eu2 O11 Cd2 -70.84(13) 2_666 .
O18 Cd2 O13 C26 -109.7(3) . .
N6 Cd2 O13 C26 23.7(3) . .
O19 Cd2 O13 C26 169.4(3) . .
N5 Cd2 O13 C26 179.0(3) . .
O11 Cd2 O13 C26 -41.0(3) . .
N4 Cd2 O13 C26 102.4(3) . .
Eu2 Cd2 O13 C26 -76.3(3) . .
N6 Cd2 O18 C22 -122.0(3) . .
O19 Cd2 O18 C22 93.5(3) . .
N5 Cd2 O18 C22 26.0(3) . .
O11 Cd2 O18 C22 -174.4(3) . .
O13 Cd2 O18 C22 -65.5(3) . .
N4 Cd2 O18 C22 -9.0(4) . .
Eu2 Cd2 O18 C22 -176.0(4) . .
N6 Cd2 O18 Eu2 54.06(18) . .
O19 Cd2 O18 Eu2 -90.42(13) . .
N5 Cd2 O18 Eu2 -157.92(16) . .
O11 Cd2 O18 Eu2 1.69(11) . .
O13 Cd2 O18 Eu2 110.51(13) . .
N4 Cd2 O18 Eu2 167.02(14) . .
O6 Eu2 O18 C22 100.6(4) 2_656 .
O4W Eu2 O18 C22 -173.1(4) . .
O2 Eu2 O18 C22 -35.9(5) . .
O3W Eu2 O18 C22 18.8(4) . .
O4 Eu2 O18 C22 -57.5(4) 2_666 .
O11 Eu2 O18 C22 173.3(4) . .
O3 Eu2 O18 C22 -107.3(4) 2_666 .
O1 Eu2 O18 C22 47.9(5) . .
C2 Eu2 O18 C22 5.8(5) . .
C10 Eu2 O18 C22 -82.9(4) 2_666 .
Cd2 Eu2 O18 C22 174.9(5) . .
O6 Eu2 O18 Cd2 -74.29(13) 2_656 .
O4W Eu2 O18 Cd2 12.0(2) . .
O2 Eu2 O18 Cd2 149.18(13) . .
O3W Eu2 O18 Cd2 -156.08(15) . .
O4 Eu2 O18 Cd2 127.61(15) 2_666 .
O11 Eu2 O18 Cd2 -1.64(11) . .
O3 Eu2 O18 Cd2 77.75(13) 2_666 .
O1 Eu2 O18 Cd2 -127.07(14) . .
C2 Eu2 O18 Cd2 -169.08(17) . .
C10 Eu2 O18 Cd2 102.18(14) 2_666 .
O18 Cd2 O19 C24 -58.1(3) . .
N6 Cd2 O19 C24 158.0(3) . .
N5 Cd2 O19 C24 8.7(3) . .
O11 Cd2 O19 C24 -131.7(3) . .
O13 Cd2 O19 C24 18.8(4) . .
N4 Cd2 O19 C24 84.0(3) . .
Eu2 Cd2 O19 C24 -94.4(3) . .
O18 Cd2 O19 Eu1 132.4(3) . 2_666
N6 Cd2 O19 Eu1 -11.5(3) . 2_666
N5 Cd2 O19 Eu1 -160.7(3) . 2_666
O11 Cd2 O19 Eu1 58.9(3) . 2_666
O13 Cd2 O19 Eu1 -150.6(2) . 2_666
N4 Cd2 O19 Eu1 -85.4(3) . 2_666
Eu2 Cd2 O19 Eu1 96.1(3) . 2_666
O7 Cd1 N1 C1 73.4(3) . .
N3 Cd1 N1 C1 -93.3(3) . .
O9 Cd1 N1 C1 -127.5(3) . .
N2 Cd1 N1 C1 100.3(3) . .
O3 Cd1 N1 C1 -19.8(3) . .
O5 Cd1 N1 C1 173.7(3) . .
Eu1 Cd1 N1 C1 160.4(4) . .
O7 Cd1 N1 C4 -47.3(3) . .
N3 Cd1 N1 C4 146.0(3) . .
O9 Cd1 N1 C4 111.8(3) . .
N2 Cd1 N1 C4 -20.4(2) . .
O3 Cd1 N1 C4 -140.5(3) . .
O5 Cd1 N1 C4 53.0(3) . .
Eu1 Cd1 N1 C4 39.7(7) . .
O7 Cd1 N1 C3 -164.6(2) . .
N3 Cd1 N1 C3 28.6(3) . .
O9 Cd1 N1 C3 -5.6(4) . .
N2 Cd1 N1 C3 -137.7(3) . .
O3 Cd1 N1 C3 102.2(3) . .
O5 Cd1 N1 C3 -64.3(3) . .
Eu1 Cd1 N1 C3 -77.7(6) . .
O7 Cd1 N2 C13 35.7(2) . .
N3 Cd1 N2 C13 -155.7(3) . .
O9 Cd1 N2 C13 85.6(3) . .
O3 Cd1 N2 C13 -43.9(3) . .
O5 Cd1 N2 C13 146.6(3) . .
N1 Cd1 N2 C13 -128.2(3) . .
Eu1 Cd1 N2 C13 59.6(3) . .
O7 Cd1 N2 C11 -82.4(2) . .
N3 Cd1 N2 C11 86.2(3) . .
O9 Cd1 N2 C11 -32.4(3) . .
O3 Cd1 N2 C11 -161.9(2) . .
O5 Cd1 N2 C11 28.6(2) . .
N1 Cd1 N2 C11 113.8(3) . .
Eu1 Cd1 N2 C11 -58.4(2) . .
O7 Cd1 N2 C5 155.9(3) . .
N3 Cd1 N2 C5 -35.5(4) . .
O9 Cd1 N2 C5 -154.1(2) . .
O3 Cd1 N2 C5 76.4(3) . .
O5 Cd1 N2 C5 -93.1(3) . .
N1 Cd1 N2 C5 -7.9(3) . .
Eu1 Cd1 N2 C5 179.9(3) . .
O7 Cd1 N3 C7 66.8(3) . .
O9 Cd1 N3 C7 34.3(2) . .
N2 Cd1 N3 C7 -97.1(3) . .
O3 Cd1 N3 C7 139.7(3) . .
O5 Cd1 N3 C7 -43.7(2) . .
N1 Cd1 N3 C7 -124.6(3) . .
Eu1 Cd1 N3 C7 46.6(2) . .
O7 Cd1 N3 C9 -50.5(3) . .
O9 Cd1 N3 C9 -83.0(3) . .
N2 Cd1 N3 C9 145.5(3) . .
O3 Cd1 N3 C9 22.4(2) . .
O5 Cd1 N3 C9 -161.1(3) . .
N1 Cd1 N3 C9 118.1(3) . .
Eu1 Cd1 N3 C9 -70.7(3) . .
O7 Cd1 N3 C6 -171.1(2) . .
O9 Cd1 N3 C6 156.4(3) . .
N2 Cd1 N3 C6 24.9(4) . .
O3 Cd1 N3 C6 -98.2(3) . .
O5 Cd1 N3 C6 78.4(3) . .
N1 Cd1 N3 C6 -2.5(3) . .
Eu1 Cd1 N3 C6 168.7(3) . .
O18 Cd2 N4 C19 130.9(3) . .
N6 Cd2 N4 C19 -100.7(3) . .
O19 Cd2 N4 C19 25.6(3) . .
N5 Cd2 N4 C19 96.9(3) . .
O11 Cd2 N4 C19 -73.4(3) . .
O13 Cd2 N4 C19 -173.6(3) . .
Eu2 Cd2 N4 C19 -164.9(4) . .
O18 Cd2 N4 C15 8.0(4) . .
N6 Cd2 N4 C15 136.4(3) . .
O19 Cd2 N4 C15 -97.3(3) . .
N5 Cd2 N4 C15 -26.0(3) . .
O11 Cd2 N4 C15 163.7(2) . .
O13 Cd2 N4 C15 63.5(3) . .
Eu2 Cd2 N4 C15 72.1(7) . .
O18 Cd2 N4 C17 -110.1(3) . .
N6 Cd2 N4 C17 18.3(3) . .
O19 Cd2 N4 C17 144.6(3) . .
N5 Cd2 N4 C17 -144.2(3) . .
O11 Cd2 N4 C17 45.6(4) . .
O13 Cd2 N4 C17 -54.6(3) . .
Eu2 Cd2 N4 C17 -46.0(7) . .
O18 Cd2 N5 C21 -35.1(2) . .
N6 Cd2 N5 C21 89.8(3) . .
O19 Cd2 N5 C21 -141.5(3) . .
O11 Cd2 N5 C21 -65.7(3) . .
O13 Cd2 N5 C21 42.1(2) . .
N4 Cd2 N5 C21 123.1(3) . .
Eu2 Cd2 N5 C21 -48.3(2) . .
O18 Cd2 N5 C23 81.9(3) . .
N6 Cd2 N5 C23 -153.2(3) . .
O19 Cd2 N5 C23 -24.5(3) . .
O11 Cd2 N5 C23 51.3(3) . .
O13 Cd2 N5 C23 159.1(3) . .
N4 Cd2 N5 C23 -119.9(3) . .
Eu2 Cd2 N5 C23 68.7(3) . .
O18 Cd2 N5 C16 -157.9(3) . .
N6 Cd2 N5 C16 -33.0(4) . .
O19 Cd2 N5 C16 95.7(3) . .
O11 Cd2 N5 C16 171.5(2) . .
O13 Cd2 N5 C16 -80.7(3) . .
N4 Cd2 N5 C16 0.3(3) . .
Eu2 Cd2 N5 C16 -171.1(3) . .
O18 Cd2 N6 C27 -85.7(3) . .
O19 Cd2 N6 C27 49.6(3) . .
N5 Cd2 N6 C27 164.0(3) . .
O11 Cd2 N6 C27 -32.7(2) . .
O13 Cd2 N6 C27 -144.7(3) . .
N4 Cd2 N6 C27 130.8(3) . .
Eu2 Cd2 N6 C27 -56.9(3) . .
O18 Cd2 N6 C25 32.5(3) . .
O19 Cd2 N6 C25 167.8(2) . .
N5 Cd2 N6 C25 -77.7(3) . .
O11 Cd2 N6 C25 85.6(3) . .
O13 Cd2 N6 C25 -26.5(2) . .
N4 Cd2 N6 C25 -110.9(3) . .
Eu2 Cd2 N6 C25 61.4(3) . .
O18 Cd2 N6 C18 154.7(3) . .
O19 Cd2 N6 C18 -70.0(3) . .
N5 Cd2 N6 C18 44.5(4) . .
O11 Cd2 N6 C18 -152.2(3) . .
O13 Cd2 N6 C18 95.7(3) . .
N4 Cd2 N6 C18 11.2(3) . .
Eu2 Cd2 N6 C18 -176.5(3) . .
C4 N1 C1 C2 -61.1(5) . .
C3 N1 C1 C2 68.2(5) . .
Cd1 N1 C1 C2 -178.3(3) . .
Eu2 O1 C2 O2 2.8(5) . .
Eu2 O1 C2 C1 -173.5(4) . .
Eu2 O2 C2 O1 -3.0(5) . .
Eu2 O2 C2 C1 173.6(3) . .
N1 C1 C2 O1 -28.9(6) . .
N1 C1 C2 O2 154.6(4) . .
N1 C1 C2 Eu2 -165.1(18) . .
O6 Eu2 C2 O1 -1.2(3) 2_656 .
O4W Eu2 C2 O1 -90.9(3) . .
O2 Eu2 C2 O1 177.2(5) . .
O3W Eu2 C2 O1 76.8(3) . .
O4 Eu2 C2 O1 146.7(3) 2_666 .
O18 Eu2 C2 O1 89.8(3) . .
O11 Eu2 C2 O1 -70.7(3) . .
O3 Eu2 C2 O1 -161.8(3) 2_666 .
C10 Eu2 C2 O1 171.6(3) 2_666 .
Cd2 Eu2 C2 O1 -9.2(11) . .
O6 Eu2 C2 O2 -178.3(3) 2_656 .
O4W Eu2 C2 O2 91.9(3) . .
O3W Eu2 C2 O2 -100.3(3) . .
O4 Eu2 C2 O2 -30.5(3) 2_666 .
O18 Eu2 C2 O2 -87.4(3) . .
O11 Eu2 C2 O2 112.1(3) . .
O3 Eu2 C2 O2 21.0(3) 2_666 .
O1 Eu2 C2 O2 -177.2(5) . .
C10 Eu2 C2 O2 -5.6(3) 2_666 .
Cd2 Eu2 C2 O2 173.6(7) . .
O6 Eu2 C2 C1 138(2) 2_656 .
O4W Eu2 C2 C1 49(2) . .
O2 Eu2 C2 C1 -43(2) . .
O3W Eu2 C2 C1 -144(2) . .
O4 Eu2 C2 C1 -74(2) 2_666 .
O18 Eu2 C2 C1 -131(2) . .
O11 Eu2 C2 C1 69(2) . .
O3 Eu2 C2 C1 -22(2) 2_666 .
O1 Eu2 C2 C1 140(2) . .
C10 Eu2 C2 C1 -49(2) 2_666 .
Cd2 Eu2 C2 C1 130.3(18) . .
C1 N1 C3 C6 67.2(4) . .
C4 N1 C3 C6 -164.5(3) . .
Cd1 N1 C3 C6 -53.2(4) . .
C1 N1 C4 C5 -75.3(4) . .
C3 N1 C4 C5 154.6(3) . .
Cd1 N1 C4 C5 46.3(4) . .
C13 N2 C5 C4 151.8(4) . .
C11 N2 C5 C4 -83.0(4) . .
Cd1 N2 C5 C4 36.1(4) . .
N1 C4 C5 N2 -58.8(5) . .
C7 N3 C6 C3 91.8(4) . .
C9 N3 C6 C3 -143.8(4) . .
Cd1 N3 C6 C3 -25.8(4) . .
N1 C3 C6 N3 58.2(5) . .
C9 N3 C7 C8 72.5(4) . .
C6 N3 C7 C8 -162.3(4) . .
Cd1 N3 C7 C8 -43.0(4) . .
Cd1 O9 C8 O10 -170.8(4) . .
Eu1 O9 C8 O10 4.5(8) . .
Cd1 O9 C8 C7 8.5(5) . .
Eu1 O9 C8 C7 -176.2(3) . .
N3 C7 C8 O10 -155.8(4) . .
N3 C7 C8 O9 24.8(6) . .
C7 N3 C9 C10 -148.8(3) . .
C6 N3 C9 C10 84.9(4) . .
Cd1 N3 C9 C10 -34.1(4) . .
Eu2 O4 C10 O3 0.1(4) 2_666 .
Eu2 O4 C10 C9 -177.4(3) 2_666 .
Cd1 O3 C10 O4 175.0(3) . .
Eu2 O3 C10 O4 -0.1(4) 2_666 .
Cd1 O3 C10 C9 -7.6(4) . .
Eu2 O3 C10 C9 177.4(3) 2_666 .
Cd1 O3 C10 Eu2 175.1(2) . 2_666
N3 C9 C10 O4 -152.5(4) . .
N3 C9 C10 O3 30.0(5) . .
N3 C9 C10 Eu2 166(5) . 2_666
C13 N2 C11 C12 -149.3(3) . .
C5 N2 C11 C12 84.9(4) . .
Cd1 N2 C11 C12 -35.4(4) . .
Eu2 O6 C12 O5 -24.6(6) 2_656 .
Eu2 O6 C12 C11 156.9(3) 2_656 .
Cd1 O5 C12 O6 -169.0(3) . .
Cd1 O5 C12 C11 9.6(4) . .
N2 C11 C12 O6 -162.8(3) . .
N2 C11 C12 O5 18.6(5) . .
C11 N2 C13 C14 73.1(5) . .
C5 N2 C13 C14 -161.1(4) . .
Cd1 N2 C13 C14 -42.5(4) . .
Cd1 O7 C14 O8 -165.3(4) . .
Eu1 O7 C14 O8 34.2(7) . .
Cd1 O7 C14 C13 13.0(5) . .
Eu1 O7 C14 C13 -147.4(3) . .
N2 C13 C14 O8 -159.8(4) . .
N2 C13 C14 O7 21.8(6) . .
C19 N4 C15 C16 -70.2(4) . .
C17 N4 C15 C16 162.3(4) . .
Cd2 N4 C15 C16 50.5(4) . .
C21 N5 C16 C15 -91.3(4) . .
C23 N5 C16 C15 146.2(4) . .
Cd2 N5 C16 C15 26.7(4) . .
N4 C15 C16 N5 -56.0(5) . .
C19 N4 C17 C18 73.2(4) . .
C15 N4 C17 C18 -157.1(4) . .
Cd2 N4 C17 C18 -46.4(4) . .
C27 N6 C18 C17 -156.5(4) . .
C25 N6 C18 C17 80.2(4) . .
Cd2 N6 C18 C17 -40.3(4) . .
N4 C17 C18 N6 62.2(5) . .
C15 N4 C19 C20 -73.7(5) . .
C17 N4 C19 C20 55.2(5) . .
Cd2 N4 C19 C20 170.5(3) . .
Eu1 O16 C20 O15 -6.6(5) 1_654 .
Eu1 O16 C20 C19 170.8(4) 1_654 .
Eu1 O15 C20 O16 6.8(5) 1_654 .
Eu1 O15 C20 C19 -170.7(3) 1_654 .
N4 C19 C20 O16 32.8(6) . .
N4 C19 C20 O15 -149.7(4) . .
N4 C19 C20 Eu1 144.4(19) . 1_654
C23 N5 C21 C22 -74.2(4) . .
C16 N5 C21 C22 162.8(3) . .
Cd2 N5 C21 C22 42.5(4) . .
Cd2 O18 C22 O17 167.5(4) . .
Eu2 O18 C22 O17 -7.3(7) . .
Cd2 O18 C22 C21 -11.1(5) . .
Eu2 O18 C22 C21 174.1(3) . .
N5 C21 C22 O17 158.3(4) . .
N5 C21 C22 O18 -23.0(5) . .
C21 N5 C23 C24 152.2(3) . .
C16 N5 C23 C24 -82.6(4) . .
Cd2 N5 C23 C24 37.5(4) . .
Eu1 O20 C24 O19 -2.0(4) 2_666 .
Eu1 O20 C24 C23 175.5(3) 2_666 .
Cd2 O19 C24 O20 -172.8(3) . .
Eu1 O19 C24 O20 2.0(4) 2_666 .
Cd2 O19 C24 C23 9.7(5) . .
Eu1 O19 C24 C23 -175.4(3) 2_666 .
Cd2 O19 C24 Eu1 -174.8(2) . 2_666
N5 C23 C24 O20 149.3(4) . .
N5 C23 C24 O19 -33.2(5) . .
N5 C23 C24 Eu1 -126(4) . 2_666
C27 N6 C25 C26 145.6(3) . .
C18 N6 C25 C26 -90.3(4) . .
Cd2 N6 C25 C26 29.7(4) . .
Eu1 O14 C26 O13 32.7(6) 2_656 .
Eu1 O14 C26 C25 -149.2(3) 2_656 .
Cd2 O13 C26 O14 162.8(3) . .
Cd2 O13 C26 C25 -15.3(5) . .
N6 C25 C26 O14 171.5(3) . .
N6 C25 C26 O13 -10.3(6) . .
C25 N6 C27 C28 -72.0(4) . .
C18 N6 C27 C28 163.4(4) . .
Cd2 N6 C27 C28 45.8(4) . .
Cd2 O11 C28 O12 -179.8(4) . .
Eu2 O11 C28 O12 -30.7(7) . .
Cd2 O11 C28 C27 1.7(5) . .
Eu2 O11 C28 C27 150.8(3) . .
N6 C27 C28 O12 147.8(4) . .
N6 C27 C28 O11 -33.6(6) . .
