#------------------------------------------------------------------------------
#$Date: 2016-02-05 00:31:12 +0200 (Fri, 05 Feb 2016) $
#$Revision: 175967 $
#$URL: svn://www.crystallography.net/cod/cif/7/22/35/7223582.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7223582
loop_
_publ_author_name
'Ovsyannikov, A. S.'
'Noamane, M. H.'
'Abidi, R.'
'Ferlay, S.'
'Solovieva, S. E.'
'Antipin, I. S.'
'Konovalov, A. I.'
'Kyritsakas, N.'
'Hosseini, M. W.'
_publ_section_title
;
 Molecular tectonics: dimensionality and geometry control of silver
 coordination networks based on pyrazolyl appended thiacalixarenes
;
_journal_issue                   5
_journal_name_full               CrystEngComm
_journal_page_first              691
_journal_paper_doi               10.1039/C5CE02310F
_journal_volume                  18
_journal_year                    2016
_chemical_formula_moiety         'C34 H44 Ag N5 O3 S4.H2 O'
_chemical_formula_sum            'C34 H46 Ag N5 O4 S4'
_chemical_formula_weight         824.87
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-C 2yc'
_space_group_name_H-M_alt        'C 1 2/c 1'
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014
_audit_update_record
;
2015-11-23 deposited with the CCDC.
2015-12-21 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 121.0560(17)
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   36.0428(10)
_cell_length_b                   12.4438(3)
_cell_length_c                   20.2117(7)
_cell_measurement_reflns_used    32000
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.54
_cell_measurement_theta_min      2.54
_cell_volume                     7765.8(4)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2014)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0381
_diffrn_reflns_av_unetI/netI     0.0486
_diffrn_reflns_laue_measured_fraction_full 0.998
_diffrn_reflns_laue_measured_fraction_max 0.974
_diffrn_reflns_limit_h_max       50
_diffrn_reflns_limit_h_min       -50
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -28
_diffrn_reflns_number            32086
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.974
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         30.113
_diffrn_reflns_theta_min         2.353
_exptl_absorpt_coefficient_mu    0.776
_exptl_absorpt_correction_T_max  0.969
_exptl_absorpt_correction_T_min  0.952
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.411
_exptl_crystal_density_meas      ?
_exptl_crystal_description       prism
_exptl_crystal_F_000             3424
_exptl_crystal_size_max          0.060
_exptl_crystal_size_mid          0.060
_exptl_crystal_size_min          0.050
_refine_diff_density_max         1.264
_refine_diff_density_min         -1.360
_refine_diff_density_rms         0.114
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.048
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     433
_refine_ls_number_reflns         11147
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.050
_refine_ls_R_factor_all          0.0819
_refine_ls_R_factor_gt           0.0573
_refine_ls_shift/su_max          0.053
_refine_ls_shift/su_mean         0.061
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0771P)²+27.6748P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1489
_refine_ls_wR_factor_ref         0.1650
_reflns_Friedel_coverage         0.000
_reflns_number_gt                8179
_reflns_number_total             11147
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c5ce02310f1.cif
_cod_data_source_block           e3310a_a
_cod_depositor_comments
;
The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 

 Adding full bibliography for 7223579--7223589.cif.
;
_cod_database_code               7223582
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.955
_shelx_estimated_absorpt_t_max   0.962
_shelxl_version_number           2014-3
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
Ag1 Ag 0.31269(2) 0.53827(2) 0.14243(2) 0.03619(10) Uani 1 1 d . .
S1 S 0.37506(2) 0.65391(6) 0.15849(5) 0.01904(16) Uani 1 1 d . .
C1 C 0.41388(10) 0.7135(2) 0.24819(18) 0.0175(6) Uani 1 1 d . .
C2 C 0.44562(9) 0.6558(2) 0.31210(18) 0.0168(5) Uani 1 1 d . .
C3 C 0.47412(10) 0.7150(3) 0.37832(18) 0.0180(6) Uani 1 1 d . .
C4 C 0.46938(10) 0.8255(3) 0.38102(18) 0.0201(6) Uani 1 1 d . .
H4 H 0.4890 0.8633 0.4267 0.024 Uiso 1 1 calc R U
C5 C 0.43690(10) 0.8822(3) 0.31916(19) 0.0199(6) Uani 1 1 d . .
C6 C 0.40942(10) 0.8241(2) 0.25266(18) 0.0194(6) Uani 1 1 d . .
H6 H 0.3870 0.8608 0.2091 0.023 Uiso 1 1 calc R U
S2 S 0.44858(3) 0.51372(6) 0.30922(5) 0.02381(17) Uani 1 1 d . .
C7 C 0.40753(12) 0.4788(3) 0.3318(2) 0.0252(7) Uani 1 1 d . .
H7A H 0.4171 0.5006 0.3854 0.030 Uiso 1 1 calc R U
H7B H 0.3801 0.5167 0.2964 0.030 Uiso 1 1 calc R U
C8 C 0.40047(12) 0.3578(3) 0.3230(2) 0.0266(7) Uani 1 1 d . .
H8A H 0.4283 0.3210 0.3579 0.032 Uiso 1 1 calc R U
H8B H 0.3912 0.3371 0.2693 0.032 Uiso 1 1 calc R U
C9 C 0.36639(13) 0.3193(3) 0.3416(2) 0.0326(8) Uani 1 1 d . .
H9A H 0.3688 0.2403 0.3482 0.039 Uiso 1 1 calc R U
H9B H 0.3731 0.3512 0.3914 0.039 Uiso 1 1 calc R U
C10 C 0.31986(12) 0.3472(3) 0.2808(2) 0.0346(8) Uani 1 1 d . .
H10A H 0.3003 0.3207 0.2980 0.041 Uiso 1 1 calc R U
H10B H 0.3168 0.4263 0.2756 0.041 Uiso 1 1 calc R U
N1 N 0.30707(10) 0.3003(3) 0.20602(19) 0.0311(7) Uani 1 1 d . .
C11 C 0.29831(13) 0.1961(3) 0.1848(3) 0.0399(9) Uani 1 1 d . .
H11 H 0.2981 0.1388 0.2157 0.048 Uiso 1 1 calc R U
C12 C 0.28980(15) 0.1881(4) 0.1106(3) 0.0449(10) Uani 1 1 d . .
H12 H 0.2826 0.1252 0.0797 0.054 Uiso 1 1 calc R U
C13 C 0.29393(14) 0.2914(4) 0.0907(3) 0.0431(10) Uani 1 1 d . .
H13 H 0.2896 0.3110 0.0418 0.052 Uiso 1 1 calc R U
N2 N 0.30475(11) 0.3606(3) 0.1482(2) 0.0360(7) Uani 1 1 d . .
C14 C 0.43456(12) 1.0046(3) 0.3221(2) 0.0296(7) Uani 1 1 d . .
C15 C 0.4745(2) 1.0507(4) 0.3235(5) 0.080(2) Uani 1 1 d . .
H15A H 0.4738 1.0301 0.2760 0.120 Uiso 1 1 calc R U
H15B H 0.5008 1.0220 0.3683 0.120 Uiso 1 1 calc R U
H15C H 0.4744 1.1292 0.3271 0.120 Uiso 1 1 calc R U
C16 C 0.4358(3) 1.0387(4) 0.3945(3) 0.072(2) Uani 1 1 d . .
H16A H 0.4401 1.1167 0.4010 0.108 Uiso 1 1 calc R U
H16B H 0.4597 1.0021 0.4390 0.108 Uiso 1 1 calc R U
H16C H 0.4084 1.0197 0.3907 0.108 Uiso 1 1 calc R U
C17 C 0.39491(19) 1.0501(3) 0.2532(3) 0.0555(14) Uani 1 1 d . .
H17A H 0.3690 1.0238 0.2522 0.083 Uiso 1 1 calc R U
H17B H 0.3940 1.0276 0.2060 0.083 Uiso 1 1 calc R U
H17C H 0.3958 1.1288 0.2564 0.083 Uiso 1 1 calc R U
S3 S 0.51633(3) 0.65523(7) 0.46392(5) 0.02135(16) Uani 1 1 d . .
C18 C 0.54991(10) 0.5941(3) 0.43386(18) 0.0189(6) Uani 1 1 d . .
C19 C 0.57025(10) 0.6512(3) 0.40104(18) 0.0185(6) Uani 1 1 d . .
C20 C 0.59544(10) 0.5904(2) 0.37932(18) 0.0180(6) Uani 1 1 d . .
C21 C 0.60156(11) 0.4813(3) 0.3938(2) 0.0225(6) Uani 1 1 d . .
H21 H 0.6187 0.4428 0.3786 0.027 Uiso 1 1 calc R U
C22 C 0.58312(11) 0.4257(3) 0.4303(2) 0.0228(6) Uani 1 1 d . .
C23 C 0.55677(11) 0.4849(3) 0.44837(19) 0.0219(6) Uani 1 1 d . .
H23 H 0.5430 0.4491 0.4715 0.026 Uiso 1 1 calc R U
S4 S 0.56369(3) 0.79162(7) 0.38311(5) 0.02315(17) Uani 1 1 d . .
C24 C 0.59669(13) 0.8453(3) 0.4799(2) 0.0309(8) Uani 1 1 d . .
H24A H 0.5917 0.9238 0.4782 0.037 Uiso 1 1 calc R U
H24B H 0.5870 0.8130 0.5133 0.037 Uiso 1 1 calc R U
C25 C 0.64511(13) 0.8254(3) 0.5165(2) 0.0324(8) Uani 1 1 d . .
H25A H 0.6500 0.7474 0.5148 0.039 Uiso 1 1 calc R U
H25B H 0.6600 0.8471 0.5715 0.039 Uiso 1 1 calc R U
C26 C 0.66547(12) 0.8855(3) 0.4774(2) 0.0291(7) Uani 1 1 d . .
H26A H 0.6473 0.8767 0.4207 0.035 Uiso 1 1 calc R U
H26B H 0.6671 0.9632 0.4894 0.035 Uiso 1 1 calc R U
C27 C 0.71046(12) 0.8422(4) 0.5057(3) 0.0391(9) Uani 1 1 d . .
H27A H 0.7289 0.8570 0.5617 0.047 Uiso 1 1 calc R U
H27B H 0.7087 0.7633 0.4988 0.047 Uiso 1 1 calc R U
N3 N 0.73130(9) 0.8876(3) 0.46629(18) 0.0297(6) Uani 1 1 d . .
N4 N 0.77033(10) 0.9365(3) 0.50672(19) 0.0304(7) Uani 1 1 d . .
C28 C 0.78134(13) 0.9595(3) 0.4547(2) 0.0327(8) Uani 1 1 d . .
H28 H 0.8074 0.9947 0.4663 0.039 Uiso 1 1 calc R U
C29 C 0.75028(13) 0.9258(4) 0.3820(2) 0.0378(9) Uani 1 1 d . .
H29 H 0.7506 0.9332 0.3355 0.045 Uiso 1 1 calc R U
C30 C 0.71871(13) 0.8791(3) 0.3911(2) 0.0372(9) Uani 1 1 d . .
H30 H 0.6928 0.8467 0.3516 0.045 Uiso 1 1 calc R U
C31 C 0.59003(15) 0.3053(3) 0.4460(3) 0.0398(10) Uani 1 1 d . .
C32 C 0.6386(3) 0.2872(5) 0.5069(5) 0.0880(13) Uani 1 1 d . .
H32A H 0.6450 0.2101 0.5124 0.132 Uiso 1 1 calc R U
H32B H 0.6451 0.3167 0.5567 0.132 Uiso 1 1 calc R U
H32C H 0.6565 0.3235 0.4902 0.132 Uiso 1 1 calc R U
C33 C 0.5821(3) 0.2461(5) 0.3772(5) 0.0880(13) Uani 1 1 d . .
H33A H 0.5870 0.1692 0.3891 0.132 Uiso 1 1 calc R U
H33B H 0.6020 0.2717 0.3611 0.132 Uiso 1 1 calc R U
H33C H 0.5522 0.2577 0.3353 0.132 Uiso 1 1 calc R U
C34 C 0.5650(3) 0.2586(5) 0.4793(5) 0.0880(13) Uani 1 1 d . .
H34A H 0.5341 0.2751 0.4454 0.132 Uiso 1 1 calc R U
H34B H 0.5753 0.2896 0.5305 0.132 Uiso 1 1 calc R U
H34C H 0.5690 0.1805 0.4839 0.132 Uiso 1 1 calc R U
N5 N 0.2906(2) 0.6713(6) 0.2443(3) 0.088(2) Uani 1 1 d . .
O1 O 0.32591(17) 0.6997(5) 0.2548(3) 0.108(2) Uani 1 1 d . .
O2 O 0.2719(2) 0.5961(5) 0.1991(3) 0.0967(17) Uani 1 1 d . .
O3 O 0.2738(2) 0.7184(7) 0.2747(4) 0.162(3) Uani 1 1 d . .
O4 O 0.1925(3) 0.4933(13) 0.1783(6) 0.236(6) Uani 1 1 d D .
H4B H 0.213(2) 0.531(7) 0.211(5) 0.235 Uiso 1 1 d D U
H4C H 0.189(3) 0.439(5) 0.146(6) 0.235 Uiso 1 1 d D U
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N2 Ag1 N4 99.64(12) . 8_465
N2 Ag1 O2 98.35(17) . .
N4 Ag1 O2 108.99(16) 8_465 .
N2 Ag1 S1 132.81(9) . .
N4 Ag1 S1 94.12(8) 8_465 .
O2 Ag1 S1 119.31(17) . .
C20 S1 C1 106.96(14) 2_655 .
C20 S1 Ag1 112.18(11) 2_655 .
C1 S1 Ag1 122.90(10) . .
C6 C1 C2 120.8(3) . .
C6 C1 S1 114.9(2) . .
C2 C1 S1 124.3(2) . .
C1 C2 C3 117.2(3) . .
C1 C2 S2 121.0(2) . .
C3 C2 S2 121.8(2) . .
C4 C3 C2 120.8(3) . .
C4 C3 S3 115.9(2) . .
C2 C3 S3 123.2(2) . .
C5 C4 C3 122.1(3) . .
C5 C4 H4 118.9 . .
C3 C4 H4 118.9 . .
C4 C5 C6 117.1(3) . .
C4 C5 C14 120.7(3) . .
C6 C5 C14 122.0(3) . .
C5 C6 C1 121.8(3) . .
C5 C6 H6 119.1 . .
C1 C6 H6 119.1 . .
C2 S2 C7 99.19(14) . .
C8 C7 S2 108.4(2) . .
C8 C7 H7A 110.0 . .
S2 C7 H7A 110.0 . .
C8 C7 H7B 110.0 . .
S2 C7 H7B 110.0 . .
H7A C7 H7B 108.4 . .
C7 C8 C9 112.7(3) . .
C7 C8 H8A 109.1 . .
C9 C8 H8A 109.1 . .
C7 C8 H8B 109.0 . .
C9 C8 H8B 109.0 . .
H8A C8 H8B 107.8 . .
C10 C9 C8 114.9(3) . .
C10 C9 H9A 108.5 . .
C8 C9 H9A 108.6 . .
C10 C9 H9B 108.6 . .
C8 C9 H9B 108.5 . .
H9A C9 H9B 107.5 . .
N1 C10 C9 111.9(3) . .
N1 C10 H10A 109.2 . .
C9 C10 H10A 109.2 . .
N1 C10 H10B 109.2 . .
C9 C10 H10B 109.2 . .
H10A C10 H10B 107.9 . .
C11 N1 N2 111.0(4) . .
C11 N1 C10 127.7(3) . .
N2 N1 C10 121.3(3) . .
N1 C11 C12 107.5(4) . .
N1 C11 H11 126.3 . .
C12 C11 H11 126.2 . .
C11 C12 C13 104.7(4) . .
C11 C12 H12 127.6 . .
C13 C12 H12 127.6 . .
N2 C13 C12 112.1(4) . .
N2 C13 H13 124.0 . .
C12 C13 H13 124.0 . .
C13 N2 N1 104.7(3) . .
C13 N2 Ag1 125.5(3) . .
N1 N2 Ag1 129.7(3) . .
C17 C14 C16 109.5(4) . .
C17 C14 C5 112.6(3) . .
C16 C14 C5 110.2(3) . .
C17 C14 C15 108.1(5) . .
C16 C14 C15 108.7(5) . .
C5 C14 C15 107.6(3) . .
C14 C15 H15A 109.5 . .
C14 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
C14 C15 H15C 109.4 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
C14 C16 H16A 109.5 . .
C14 C16 H16B 109.5 . .
H16A C16 H16B 109.5 . .
C14 C16 H16C 109.5 . .
H16A C16 H16C 109.5 . .
H16B C16 H16C 109.5 . .
C14 C17 H17A 109.5 . .
C14 C17 H17B 109.5 . .
H17A C17 H17B 109.5 . .
C14 C17 H17C 109.5 . .
H17A C17 H17C 109.5 . .
H17B C17 H17C 109.5 . .
C3 S3 C18 103.79(14) . .
C23 C18 C19 121.0(3) . .
C23 C18 S3 115.2(2) . .
C19 C18 S3 123.7(2) . .
C18 C19 C20 116.7(3) . .
C18 C19 S4 123.1(2) . .
C20 C19 S4 120.2(2) . .
C21 C20 C19 121.2(3) . .
C21 C20 S1 117.5(2) . 2_655
C19 C20 S1 121.1(2) . 2_655
C20 C21 C22 121.9(3) . .
C20 C21 H21 119.1 . .
C22 C21 H21 119.1 . .
C23 C22 C21 116.8(3) . .
C23 C22 C31 121.6(3) . .
C21 C22 C31 121.5(3) . .
C18 C23 C22 122.3(3) . .
C18 C23 H23 118.8 . .
C22 C23 H23 118.8 . .
C19 S4 C24 101.45(16) . .
C25 C24 S4 114.4(2) . .
C25 C24 H24A 108.7 . .
S4 C24 H24A 108.6 . .
C25 C24 H24B 108.7 . .
S4 C24 H24B 108.7 . .
H24A C24 H24B 107.6 . .
C24 C25 C26 113.9(3) . .
C24 C25 H25A 108.8 . .
C26 C25 H25A 108.8 . .
C24 C25 H25B 108.8 . .
C26 C25 H25B 108.8 . .
H25A C25 H25B 107.7 . .
C27 C26 C25 109.8(3) . .
C27 C26 H26A 109.7 . .
C25 C26 H26A 109.7 . .
C27 C26 H26B 109.7 . .
C25 C26 H26B 109.7 . .
H26A C26 H26B 108.2 . .
N3 C27 C26 114.1(3) . .
N3 C27 H27A 108.7 . .
C26 C27 H27A 108.7 . .
N3 C27 H27B 108.7 . .
C26 C27 H27B 108.7 . .
H27A C27 H27B 107.6 . .
C30 N3 N4 110.9(3) . .
C30 N3 C27 128.0(3) . .
N4 N3 C27 120.8(3) . .
C28 N4 N3 105.1(3) . .
C28 N4 Ag1 127.4(3) . 8_566
N3 N4 Ag1 127.3(2) . 8_566
N4 C28 C29 111.6(4) . .
N4 C28 H28 124.2 . .
C29 C28 H28 124.2 . .
C30 C29 C28 105.1(4) . .
C30 C29 H29 127.4 . .
C28 C29 H29 127.4 . .
N3 C30 C29 107.3(4) . .
N3 C30 H30 126.3 . .
C29 C30 H30 126.3 . .
C33 C31 C34 111.4(5) . .
C33 C31 C22 111.4(4) . .
C34 C31 C22 113.8(4) . .
C33 C31 C32 105.5(5) . .
C34 C31 C32 106.4(5) . .
C22 C31 C32 107.7(4) . .
C31 C32 H32A 109.4 . .
C31 C32 H32B 109.5 . .
H32A C32 H32B 109.5 . .
C31 C32 H32C 109.5 . .
H32A C32 H32C 109.5 . .
H32B C32 H32C 109.5 . .
C31 C33 H33A 109.5 . .
C31 C33 H33B 109.5 . .
H33A C33 H33B 109.5 . .
C31 C33 H33C 109.5 . .
H33A C33 H33C 109.5 . .
H33B C33 H33C 109.5 . .
C31 C34 H34A 109.5 . .
C31 C34 H34B 109.5 . .
H34A C34 H34B 109.5 . .
C31 C34 H34C 109.5 . .
H34A C34 H34C 109.5 . .
H34B C34 H34C 109.5 . .
O3 N5 O1 121.1(8) . .
O3 N5 O2 120.9(8) . .
O1 N5 O2 117.9(5) . .
N5 O2 Ag1 110.1(4) . .
H4B O4 H4C 136(6) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Ag1 N2 2.239(3) .
Ag1 N4 2.373(3) 8_465
Ag1 O2 2.395(5) .
Ag1 S1 2.5451(8) .
S1 C20 1.782(3) 2_655
S1 C1 1.782(3) .
C1 C6 1.394(4) .
C1 C2 1.403(4) .
C2 C3 1.404(4) .
C2 S2 1.774(3) .
C3 C4 1.390(4) .
C3 S3 1.773(3) .
C4 C5 1.387(5) .
C4 H4 0.9500 .
C5 C6 1.392(4) .
C5 C14 1.529(5) .
C6 H6 0.9500 .
S2 C7 1.813(3) .
C7 C8 1.523(5) .
C7 H7A 0.9900 .
C7 H7B 0.9900 .
C8 C9 1.534(5) .
C8 H8A 0.9900 .
C8 H8B 0.9900 .
C9 C10 1.521(6) .
C9 H9A 0.9900 .
C9 H9B 0.9900 .
C10 N1 1.456(5) .
C10 H10A 0.9900 .
C10 H10B 0.9900 .
N1 C11 1.351(5) .
N1 N2 1.355(4) .
C11 C12 1.371(7) .
C11 H11 0.9500 .
C12 C13 1.379(6) .
C12 H12 0.9500 .
C13 N2 1.333(6) .
C13 H13 0.9500 .
C14 C17 1.500(6) .
C14 C16 1.501(6) .
C14 C15 1.536(7) .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 H16A 0.9800 .
C16 H16B 0.9800 .
C16 H16C 0.9800 .
C17 H17A 0.9800 .
C17 H17B 0.9800 .
C17 H17C 0.9800 .
S3 C18 1.781(3) .
C18 C23 1.385(5) .
C18 C19 1.409(4) .
C19 C20 1.415(4) .
C19 S4 1.776(3) .
C20 C21 1.382(4) .
C20 S1 1.782(3) 2_655
C21 C22 1.403(4) .
C21 H21 0.9500 .
C22 C23 1.391(4) .
C22 C31 1.526(5) .
C23 H23 0.9500 .
S4 C24 1.813(4) .
C24 C25 1.524(6) .
C24 H24A 0.9900 .
C24 H24B 0.9900 .
C25 C26 1.524(5) .
C25 H25A 0.9900 .
C25 H25B 0.9900 .
C26 C27 1.513(5) .
C26 H26A 0.9900 .
C26 H26B 0.9900 .
C27 N3 1.461(5) .
C27 H27A 0.9900 .
C27 H27B 0.9900 .
N3 C30 1.348(5) .
N3 N4 1.353(4) .
N4 C28 1.333(5) .
N4 Ag1 2.373(3) 8_566
C28 C29 1.375(6) .
C28 H28 0.9500 .
C29 C30 1.371(6) .
C29 H29 0.9500 .
C30 H30 0.9500 .
C31 C33 1.467(9) .
C31 C34 1.495(7) .
C31 C32 1.552(9) .
C32 H32A 0.9800 .
C32 H32B 0.9800 .
C32 H32C 0.9800 .
C33 H33A 0.9800 .
C33 H33B 0.9800 .
C33 H33C 0.9800 .
C34 H34A 0.9800 .
C34 H34B 0.9800 .
C34 H34C 0.9800 .
N5 O3 1.212(7) .
N5 O1 1.228(8) .
N5 O2 1.238(8) .
O4 H4B 0.85(3) .
O4 H4C 0.90(3) .
