#------------------------------------------------------------------------------
#$Date: 2016-08-07 11:32:52 +0300 (Sun, 07 Aug 2016) $
#$Revision: 185261 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/54/7225456.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7225456
loop_
_publ_author_name
'Dong, Ruo-Ting'
'Chen, Xin-Li'
'Cui, Xiao'
'Chen, Su-Su'
'Shen, Mo-Yuan'
'Li, Chu-Wen'
'Li, Qian-Hong'
'Hu, Ming-Yuan'
'Huang, Lan-Fen'
'Deng, Hong'
_publ_section_title
;
 Copper(i)--lanthanide(iii) heterometallic metal--organic frameworks
 constructed from 3-(3-pyridyl)acrylic acid: syntheses, structures, and
 properties
;
_journal_issue                   29
_journal_name_full               CrystEngComm
_journal_page_first              5547
_journal_paper_doi               10.1039/C6CE00637J
_journal_volume                  18
_journal_year                    2016
_chemical_formula_moiety         'C24 H24 Cl3 Cu3 Gd N3 O8, O'
_chemical_formula_sum            'C24 H24 Cl3 Cu3 Gd N3 O9'
_chemical_formula_weight         952.68
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_date             2016-05-29
_audit_creation_method
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_audit_update_record
;
2016-06-02 deposited with the CCDC.
2016-06-06 downloaded from the CCDC.
;
_cell_angle_alpha                97.405(3)
_cell_angle_beta                 98.215(3)
_cell_angle_gamma                107.290(3)
_cell_formula_units_Z            2
_cell_length_a                   9.750(2)
_cell_length_b                   13.103(3)
_cell_length_c                   13.133(3)
_cell_measurement_reflns_used    2531
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      23.72
_cell_measurement_theta_min      2.48
_cell_volume                     1559.3(6)
_computing_cell_refinement       'SAINT v7.68A (Bruker, 2009)'
_computing_data_collection       'Apex2 (Bruker, 2005)'
_computing_data_reduction        'SAINT v7.68A (Bruker, 2009)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'SHELXTL 6.12 (Bruker, 2000-2003)'
_diffrn_ambient_temperature      296.15
_diffrn_measured_fraction_theta_full 0.970
_diffrn_measured_fraction_theta_max 0.969
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0282
_diffrn_reflns_av_unetI/netI     0.0582
_diffrn_reflns_Laue_measured_fraction_full 0.970
_diffrn_reflns_Laue_measured_fraction_max 0.969
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            8109
_diffrn_reflns_point_group_measured_fraction_full 0.970
_diffrn_reflns_point_group_measured_fraction_max 0.969
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.394
_diffrn_reflns_theta_min         1.655
_diffrn_source                   'fine-focus sealed tube'
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.427
_exptl_absorpt_correction_T_max  25.394
_exptl_absorpt_correction_T_min  1.655
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'Apex2 (Bruker, 2005)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    2.025
_exptl_crystal_description       block
_exptl_crystal_F_000             922
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.20
_exptl_transmission_factor_max   0.413
_exptl_transmission_factor_min   0.359
_refine_diff_density_max         1.749
_refine_diff_density_min         -2.060
_refine_diff_density_rms         0.166
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.084
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     390
_refine_ls_number_reflns         5566
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.084
_refine_ls_R_factor_all          0.0683
_refine_ls_R_factor_gt           0.0561
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0899P)²+1.2491P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1447
_refine_ls_wR_factor_ref         0.1547
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4573
_reflns_number_total             5741
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6ce00637j2.cif
_cod_data_source_block           3
_cod_depositor_comments
'Adding full bibliography for 7225454--7225470.cif.'
_cod_database_code               7225456
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All O(H,H) groups
2.a Rotating group:
 O2W(H2WA,H2WB), O3W(H3WA,H3WB)
2.b Aromatic/amide H refined with riding coordinates:
 C2(H2), C3(H3), C18(H18), C19(H19), C15(H15), C13(H13), C16(H16), C14(H14),
 C23(H23), C22(H22), C7(H7), C6(H6), C8(H8), C10(H10), C11(H11), C5(H5),
 C21(H21), C24(H24)
;
_shelx_shelxl_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
Gd1 Gd 0.76040(4) 0.50903(3) 0.51894(3) 0.03232(16) Uani 1 1 d .
Cu1 Cu 0.16778(18) 0.20212(13) -0.21599(13) 0.0903(5) Uani 1 1 d .
Cu3 Cu 0.11156(16) 0.02197(18) 0.11296(15) 0.1048(6) Uani 1 1 d .
Cu2 Cu 0.0622(3) 0.2162(3) 0.0149(3) 0.1980(16) Uani 1 1 d .
Cl1 Cl 0.1221(3) 0.0601(3) -0.0896(2) 0.0757(8) Uani 1 1 d .
Cl2 Cl 0.1251(5) 0.2124(3) 0.1789(3) 0.1123(13) Uani 1 1 d .
Cl3 Cl 0.0071(5) 0.3146(4) -0.0886(4) 0.1194(14) Uani 1 1 d .
O2W O 0.6858(6) 0.5641(5) 0.6824(5) 0.0477(14) Uani 1 1 d .
H2WA H 0.7536 0.6217 0.7196 0.072 Uiso 1 1 d GR
H2WB H 0.6723 0.5125 0.7196 0.072 Uiso 1 1 d GR
O5 O -0.5836(6) -0.3519(4) -0.5399(5) 0.0443(14) Uani 1 1 d .
O2 O 0.8233(6) 0.5557(4) 0.3503(4) 0.0415(13) Uani 1 1 d .
O3 O 0.6046(6) 0.4386(4) 0.3400(4) 0.0416(13) Uani 1 1 d .
O3W O 0.9007(6) 0.4619(5) 0.6637(5) 0.0499(15) Uani 1 1 d .
H3WA H 0.9084 0.5053 0.7219 0.075 Uiso 1 1 d GR
H3WB H 0.9883 0.4674 0.6526 0.075 Uiso 1 1 d GR
O1 O 0.9526(6) 0.6736(5) 0.5866(5) 0.0509(15) Uani 1 1 d .
O4 O 0.8653(7) 0.3838(5) 0.4504(5) 0.0489(15) Uani 1 1 d .
N1 N 1.6889(9) 0.9819(8) 0.8486(8) 0.074(3) Uani 1 1 d .
N3 N -0.0022(9) 0.1362(6) -0.3220(7) 0.061(2) Uani 1 1 d .
N2 N 0.3681(10) 0.2850(7) -0.1498(7) 0.062(2) Uani 1 1 d .
C17 C -0.4478(8) -0.3152(6) -0.5173(6) 0.0352(17) Uani 1 1 d .
C2 C 1.1903(8) 0.7795(6) 0.6717(7) 0.046(2) Uani 1 1 d .
H2 H 1.1514 0.8280 0.7056 0.055 Uiso 1 1 calc R
C3 C 1.3319(9) 0.8002(6) 0.6926(7) 0.045(2) Uani 1 1 d .
H3 H 1.3683 0.7502 0.6584 0.054 Uiso 1 1 calc R
C18 C -0.3857(9) -0.1935(7) -0.4982(7) 0.046(2) Uani 1 1 d .
H18 H -0.4485 -0.1551 -0.5174 0.055 Uiso 1 1 calc R
C19 C -0.2506(10) -0.1382(7) -0.4569(7) 0.050(2) Uani 1 1 d .
H19 H -0.1853 -0.1767 -0.4452 0.060 Uiso 1 1 calc R
C15 C 0.4674(15) 0.3172(10) -0.2044(8) 0.082(4) Uani 1 1 d .
H15 H 0.4414 0.3009 -0.2770 0.098 Uiso 1 1 calc R
C13 C 0.6486(12) 0.4028(9) -0.0547(8) 0.069(3) Uani 1 1 d .
H13 H 0.7450 0.4415 -0.0228 0.082 Uiso 1 1 calc R
C16 C 0.4045(11) 0.3153(8) -0.0466(8) 0.057(2) Uani 1 1 d .
H16 H 0.3315 0.2957 -0.0076 0.069 Uiso 1 1 calc R
C14 C 0.6117(14) 0.3752(10) -0.1587(9) 0.084(4) Uani 1 1 d .
H14 H 0.6818 0.3946 -0.2000 0.101 Uiso 1 1 calc R
C23 C -0.0764(13) 0.1996(8) -0.3548(9) 0.070(3) Uani 1 1 d .
H23 H -0.0360 0.2742 -0.3313 0.084 Uiso 1 1 calc R
C22 C -0.2125(11) 0.1599(8) -0.4230(9) 0.068(3) Uani 1 1 d .
H22 H -0.2645 0.2058 -0.4421 0.082 Uiso 1 1 calc R
C7 C 1.6499(15) 1.0635(11) 0.8967(14) 0.108(6) Uani 1 1 d .
H7 H 1.7209 1.1221 0.9414 0.130 Uiso 1 1 calc R
C6 C 1.5099(19) 1.0611(12) 0.8809(16) 0.147(9) Uani 1 1 d .
H6 H 1.4858 1.1183 0.9150 0.177 Uiso 1 1 calc R
C4 C 1.4388(9) 0.8932(7) 0.7637(9) 0.056(2) Uani 1 1 d .
C8 C 1.5844(9) 0.9005(8) 0.7867(8) 0.054(2) Uani 1 1 d .
H8 H 1.6109 0.8431 0.7559 0.065 Uiso 1 1 calc R
C12 C 0.5427(10) 0.3734(7) 0.0055(7) 0.049(2) Uani 1 1 d .
C9 C 0.7045(8) 0.4896(6) 0.2974(6) 0.0368(17) Uani 1 1 d .
C10 C 0.6866(10) 0.4675(7) 0.1816(7) 0.047(2) Uani 1 1 d .
H10 H 0.7625 0.5048 0.1512 0.057 Uiso 1 1 calc R
C11 C 0.5695(10) 0.3981(7) 0.1202(7) 0.046(2) Uani 1 1 d .
H11 H 0.4960 0.3607 0.1524 0.055 Uiso 1 1 calc R
C1 C 1.0861(8) 0.6819(6) 0.5959(6) 0.0388(18) Uani 1 1 d .
C5 C 1.4025(14) 0.9775(10) 0.8165(13) 0.115(7) Uani 1 1 d .
H5 H 1.3058 0.9765 0.8078 0.138 Uiso 1 1 calc R
C20 C -0.1933(10) -0.0194(7) -0.4273(7) 0.050(2) Uani 1 1 d .
C21 C -0.2657(10) 0.0490(7) -0.4604(9) 0.060(3) Uani 1 1 d .
H21 H -0.3527 0.0202 -0.5093 0.071 Uiso 1 1 calc R
C24 C -0.0587(10) 0.0280(8) -0.3577(8) 0.054(2) Uani 1 1 d .
H24 H -0.0065 -0.0166 -0.3354 0.065 Uiso 1 1 calc R
O1W O 0.0216(19) 0.456(2) 0.1305(13) 0.283(14) Uani 1 1 d .
O6 O -0.3662(7) -0.3697(5) -0.5100(6) 0.0584(17) Uani 1 1 d .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Gd Gd -0.1653 3.9035 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2W Gd1 O2 147.5(2) . .
O2W Gd1 O3 128.05(18) . .
O2W Gd1 C9 145.7(2) . .
O5 Gd1 O2W 76.0(2) 2 .
O5 Gd1 O2 126.1(2) 2 .
O5 Gd1 O3 76.56(19) 2 .
O5 Gd1 O3W 80.9(2) 2 .
O5 Gd1 O1 152.0(2) 2 .
O5 Gd1 C9 100.9(2) 2 .
O2 Gd1 O3 52.33(17) . .
O2 Gd1 C9 26.28(19) . .
O3 Gd1 C9 26.12(19) . .
O3W Gd1 O2W 70.6(2) . .
O3W Gd1 O2 130.72(18) . .
O3W Gd1 O3 144.6(2) . .
O3W Gd1 C9 143.5(2) . .
O1 Gd1 O2W 80.0(2) . .
O1 Gd1 O2 81.9(2) . .
O1 Gd1 O3 130.7(2) . .
O1 Gd1 O3W 77.5(2) . .
O1 Gd1 C9 107.1(2) . .
O4 Gd1 O2W 138.9(2) . .
O4 Gd1 O5 82.5(2) . 2
O4 Gd1 O2 72.5(2) . .
O4 Gd1 O3 78.5(2) . .
O4 Gd1 O3W 71.7(2) . .
O4 Gd1 O1 107.1(2) . .
O4 Gd1 C9 72.4(2) . .
O6 Gd1 O2W 71.9(2) 1_666 .
O6 Gd1 O5 104.9(2) 1_666 2
O6 Gd1 O2 78.8(2) 1_666 .
O6 Gd1 O3 73.8(2) 1_666 .
O6 Gd1 O3W 139.2(2) 1_666 .
O6 Gd1 O1 80.9(2) 1_666 .
O6 Gd1 O4 148.5(2) 1_666 .
O6 Gd1 C9 76.2(2) 1_666 .
N3 Cu1 Cl1 99.7(3) . .
N3 Cu1 N2 160.0(4) . .
N2 Cu1 Cl1 97.4(3) . .
Cl1 Cu3 Cl2 100.77(16) 2 .
N1 Cu3 Cl1 148.8(3) 2_766 2
N1 Cu3 Cl2 105.2(3) 2_766 .
Cl2 Cu2 Cl1 106.89(19) . .
Cl3 Cu2 Cl1 108.9(2) . .
Cl3 Cu2 Cl2 142.9(3) . .
Cu3 Cl1 Cu1 108.18(14) 2 .
Cu3 Cl1 Cu2 83.80(13) 2 .
Cu2 Cl1 Cu1 79.78(12) . .
Cu2 Cl2 Cu3 83.96(18) . .
Gd1 O2W H2WA 109.9 . .
Gd1 O2W H2WB 111.1 . .
H2WA O2W H2WB 108.2 . .
C17 O5 Gd1 135.0(5) . 2
C9 O2 Gd1 93.1(5) . .
C9 O3 Gd1 92.4(5) . .
Gd1 O3W H3WA 110.4 . .
Gd1 O3W H3WB 110.4 . .
H3WA O3W H3WB 108.4 . .
C1 O1 Gd1 123.6(5) . .
C1 O4 Gd1 173.5(6) 2_766 .
C7 N1 Cu3 119.8(8) . 2_766
C8 N1 Cu3 122.2(8) . 2_766
C8 N1 C7 117.4(10) . .
C23 N3 Cu1 117.4(7) . .
C23 N3 C24 118.6(8) . .
C24 N3 Cu1 123.7(7) . .
C15 N2 Cu1 121.4(8) . .
C15 N2 C16 118.1(10) . .
C16 N2 Cu1 120.4(7) . .
O5 C17 C18 114.8(7) . .
O6 C17 O5 125.3(7) . .
O6 C17 C18 120.0(7) . .
C3 C2 H2 118.0 . .
C3 C2 C1 124.0(7) . .
C1 C2 H2 118.0 . .
C2 C3 H3 116.5 . .
C2 C3 C4 126.9(8) . .
C4 C3 H3 116.5 . .
C17 C18 H18 117.7 . .
C19 C18 C17 124.6(8) . .
C19 C18 H18 117.7 . .
C18 C19 H19 117.6 . .
C18 C19 C20 124.7(9) . .
C20 C19 H19 117.6 . .
N2 C15 H15 118.8 . .
N2 C15 C14 122.3(10) . .
C14 C15 H15 118.8 . .
C14 C13 H13 120.2 . .
C14 C13 C12 119.6(10) . .
C12 C13 H13 120.2 . .
N2 C16 H16 118.1 . .
N2 C16 C12 123.8(9) . .
C12 C16 H16 118.1 . .
C15 C14 H14 120.4 . .
C13 C14 C15 119.2(10) . .
C13 C14 H14 120.4 . .
N3 C23 H23 118.3 . .
N3 C23 C22 123.4(9) . .
C22 C23 H23 118.3 . .
C23 C22 H22 121.7 . .
C21 C22 C23 116.7(10) . .
C21 C22 H22 121.7 . .
N1 C7 H7 119.6 . .
C6 C7 N1 120.8(12) . .
C6 C7 H7 119.6 . .
C7 C6 H6 119.1 . .
C7 C6 C5 121.7(13) . .
C5 C6 H6 119.1 . .
C8 C4 C3 121.3(8) . .
C8 C4 C5 115.3(9) . .
C5 C4 C3 123.4(9) . .
N1 C8 C4 125.5(10) . .
N1 C8 H8 117.2 . .
C4 C8 H8 117.2 . .
C13 C12 C11 124.8(9) . .
C16 C12 C13 116.8(9) . .
C16 C12 C11 118.3(8) . .
O2 C9 Gd1 60.6(4) . .
O2 C9 C10 118.7(7) . .
O3 C9 Gd1 61.5(4) . .
O3 C9 O2 121.9(7) . .
O3 C9 C10 119.3(7) . .
C10 C9 Gd1 171.6(6) . .
C9 C10 H10 118.4 . .
C11 C10 C9 123.3(8) . .
C11 C10 H10 118.4 . .
C12 C11 H11 116.8 . .
C10 C11 C12 126.4(8) . .
C10 C11 H11 116.8 . .
O1 C1 C2 115.6(7) . .
O4 C1 O1 125.0(8) 2_766 .
O4 C1 C2 119.4(7) 2_766 .
C6 C5 C4 119.2(12) . .
C6 C5 H5 120.4 . .
C4 C5 H5 120.4 . .
C21 C20 C19 124.0(8) . .
C21 C20 C24 117.3(8) . .
C24 C20 C19 118.6(8) . .
C22 C21 H21 119.2 . .
C20 C21 C22 121.6(9) . .
C20 C21 H21 119.2 . .
N3 C24 C20 122.3(9) . .
N3 C24 H24 118.8 . .
C20 C24 H24 118.8 . .
C17 O6 Gd1 170.1(6) . 1_444
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Gd1 O2W 2.453(5) .
Gd1 O5 2.336(5) 2
Gd1 O2 2.484(6) .
Gd1 O3 2.504(6) .
Gd1 O3W 2.435(6) .
Gd1 O1 2.362(5) .
Gd1 O4 2.330(5) .
Gd1 C9 2.846(8) .
Gd1 O6 2.319(6) 1_666
Cu1 Cl1 2.633(3) .
Cu1 N3 1.900(8) .
Cu1 N2 1.939(9) .
Cu3 Cl1 2.168(3) 2
Cu3 Cl2 2.492(4) .
Cu3 N1 1.956(9) 2_766
Cu2 Cl1 2.574(6) .
Cu2 Cl2 2.164(6) .
Cu2 Cl3 2.111(6) .
Cl1 Cu3 2.168(3) 2
O2W H2WA 0.8726 .
O2W H2WB 0.8739 .
O5 Gd1 2.336(5) 2
O5 C17 1.242(9) .
O2 C9 1.262(9) .
O3 C9 1.254(9) .
O3W H3WA 0.8708 .
O3W H3WB 0.8705 .
O1 C1 1.260(9) .
O4 C1 1.235(9) 2_766
N1 Cu3 1.956(9) 2_766
N1 C7 1.351(16) .
N1 C8 1.315(12) .
N3 C23 1.327(13) .
N3 C24 1.350(12) .
N2 C15 1.290(15) .
N2 C16 1.327(13) .
C17 C18 1.500(11) .
C17 O6 1.220(9) .
C2 H2 0.9300 .
C2 C3 1.306(11) .
C2 C1 1.506(11) .
C3 H3 0.9300 .
C3 C4 1.454(12) .
C18 H18 0.9300 .
C18 C19 1.297(12) .
C19 H19 0.9300 .
C19 C20 1.467(12) .
C15 H15 0.9300 .
C15 C14 1.386(17) .
C13 H13 0.9300 .
C13 C14 1.335(16) .
C13 C12 1.383(13) .
C16 H16 0.9300 .
C16 C12 1.362(13) .
C14 H14 0.9300 .
C23 H23 0.9300 .
C23 C22 1.402(15) .
C22 H22 0.9300 .
C22 C21 1.385(13) .
C7 H7 0.9300 .
C7 C6 1.341(19) .
C6 H6 0.9300 .
C6 C5 1.356(17) .
C4 C8 1.380(12) .
C4 C5 1.390(15) .
C8 H8 0.9300 .
C12 C11 1.468(12) .
C9 C10 1.487(12) .
C10 H10 0.9300 .
C10 C11 1.308(12) .
C11 H11 0.9300 .
C1 O4 1.235(9) 2_766
C5 H5 0.9300 .
C20 C21 1.372(13) .
C20 C24 1.403(12) .
C21 H21 0.9300 .
C24 H24 0.9300 .
O6 Gd1 2.319(6) 1_444
