#------------------------------------------------------------------------------
#$Date: 2016-11-08 09:11:19 +0200 (Tue, 08 Nov 2016) $
#$Revision: 188033 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/70/7227017.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7227017
loop_
_publ_author_name
'Jia, Jiage'
'Zhang, Yanhui'
'Zhang, Panpan'
'Ma, Pengtao'
'Zhang, Dongdi'
'Wang, Jingping'
'Niu, Jingyang'
_publ_section_title
;
 Synthesis and characterization of a series of novel
 polyoxometalate-supported carbonyl manganese derivatives
;
_journal_name_full               'RSC Adv.'
_journal_paper_doi               10.1039/C6RA23547F
_journal_year                    2016
_chemical_formula_moiety         'Bi2 C6 Mn6 O82 W18, 3(N), 31(O)'
_chemical_formula_sum            'C6 H94 Bi2 Mn6 N3 O113 W18'
_chemical_formula_weight         6073.74
_chemical_name_systematic
;
 ?
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           12
_space_group_name_Hall           '-C 2y'
_space_group_name_H-M_alt        'C 1 2/m 1'
_symmetry_space_group_name_Hall  '-C 2y'
_symmetry_space_group_name_H-M   'C 1 2/m 1'
_atom_sites_solution_primary     direct
_audit_creation_date             2016-04-04
_audit_creation_method
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_audit_update_record
;
2016-09-21 deposited with the CCDC.
2016-11-07 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 105.016(10)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   25.879(16)
_cell_length_b                   14.409(8)
_cell_length_c                   16.235(10)
_cell_measurement_reflns_used    1522
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.06
_cell_measurement_theta_min      2.21
_cell_volume                     5847(6)
_computing_cell_refinement       'SAINT v7.34A (Bruker, 200?)'
_computing_data_collection       'Bruker SMART'
_computing_data_reduction        'SAINT v7.34A (Bruker, 200?)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS-1997 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296.15
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0933
_diffrn_reflns_av_unetI/netI     0.1113
_diffrn_reflns_Laue_measured_fraction_full 0.995
_diffrn_reflns_Laue_measured_fraction_max 0.995
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            14810
_diffrn_reflns_point_group_measured_fraction_full 0.995
_diffrn_reflns_point_group_measured_fraction_max 0.995
_diffrn_reflns_theta_full        25.096
_diffrn_reflns_theta_max         25.096
_diffrn_reflns_theta_min         1.949
_exptl_absorpt_coefficient_mu    21.357
_exptl_absorpt_correction_T_max  0.2022
_exptl_absorpt_correction_T_min  0.058
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2004/1 (Bruker,2004) was used for absorption correction.
R(int) was 0.1629 before and 0.0527 after correction.
The Ratio of minimum to maximum transmission is 0.4223.
The λ/2 correction factor is 0.0015.
;
_exptl_crystal_colour            yellow
_exptl_crystal_colour_primary    yellow
_exptl_crystal_density_diffrn    3.450
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             5406
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.11
_refine_diff_density_max         2.329
_refine_diff_density_min         -2.022
_refine_diff_density_rms         0.386
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.010
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     346
_refine_ls_number_reflns         5406
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.011
_refine_ls_R_factor_all          0.0998
_refine_ls_R_factor_gt           0.0516
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0555P)²+16.6513P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1156
_refine_ls_wR_factor_ref         0.1385
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3406
_reflns_number_total             5406
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c6ra23547f2.cif
_cod_data_source_block           njy1
_cod_database_code               7227017
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.202
_shelx_estimated_absorpt_t_min   0.058
_olex2_refinement_description
;
1. Uiso/Uaniso restraints and constraints
Uanis(O1W) \\sim Ueq, : with sigma of 0.01 and sigma for terminal atoms of 0.02
2. Others
 Fixed Sof: N1(0.5) N2(0.25) O13W(0.5) O14W(0.25)
;
_shelx_shelxl_version_number     2014/7
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
W1 W 0.18624(3) 0.37077(7) 0.34702(5) 0.0332(3) Uani 1 1 d . . .
W2 W 0.05915(3) 0.37442(7) 0.35895(5) 0.0383(3) Uani 1 1 d . . .
W3 W 0.09213(3) 0.25794(6) 0.20694(5) 0.0324(2) Uani 1 1 d . . .
W4 W 0.18993(3) 0.38275(6) 0.11879(5) 0.0268(2) Uani 1 1 d . . .
W5 W 0.09644(4) 0.5000 -0.02819(7) 0.0279(3) Uani 1 2 d S T P
Bi1 Bi 0.06342(4) 0.5000 0.16907(6) 0.0256(3) Uani 1 2 d S T P
Mn1 Mn 0.0000 0.3067(3) 0.0000 0.0296(11) Uani 1 2 d S T P
Mn2 Mn 0.06590(17) 0.5000 -0.2708(3) 0.0424(13) Uani 1 2 d S T P
Mn3 Mn 0.27116(16) 0.5000 0.2552(3) 0.0352(12) Uani 1 2 d S T P
O1 O 0.1902(7) 0.5000 0.3719(11) 0.032(5) Uani 1 2 d S T P
O2 O 0.2456(5) 0.3332(10) 0.4132(8) 0.039(4) Uiso 1 1 d . . .
O3 O 0.1400(5) 0.3520(10) 0.4168(8) 0.040(4) Uani 1 1 d . . .
O4 O 0.1653(5) 0.2555(10) 0.2922(8) 0.037(4) Uani 1 1 d . . .
O5 O 0.2100(4) 0.4029(9) 0.2459(8) 0.028(3) Uani 1 1 d . . .
O6 O 0.1042(5) 0.4012(10) 0.2607(8) 0.034(4) Uani 1 1 d . . .
O7 O 0.0382(6) 0.3302(13) 0.4437(9) 0.056(5) Uani 1 1 d . . .
O8 O 0.0725(7) 0.5000 0.3937(11) 0.032(5) Uani 1 2 d S T P
O9 O -0.0006(5) 0.4047(11) 0.2812(9) 0.044(4) Uani 1 1 d . . .
O10 O 0.0633(5) 0.2536(10) 0.3022(8) 0.037(4) Uani 1 1 d . . .
O11 O 0.0880(6) 0.1411(10) 0.1815(10) 0.047(4) Uani 1 1 d . . .
O12 O 0.1379(5) 0.3038(9) 0.1336(8) 0.031(3) Uani 1 1 d . . .
O13 O 0.0376(5) 0.3086(11) 0.1326(8) 0.040(4) Uani 1 1 d . . .
O14 O 0.2405(5) 0.3099(10) 0.1132(8) 0.035(4) Uani 1 1 d . . .
O15 O 0.1625(5) 0.4058(8) 0.0059(7) 0.024(3) Uani 1 1 d . . .
O16 O 0.2309(6) 0.5000 0.1292(10) 0.025(4) Uani 1 2 d S T P
O17 O 0.1283(6) 0.5000 0.1111(10) 0.022(4) Uani 1 2 d S T P
O18 O 0.0549(5) 0.4099(12) -0.0157(9) 0.050(4) Uani 1 1 d . . .
O19 O 0.0931(7) 0.5000 -0.1379(10) 0.036(5) Uani 1 2 d S T P
O20 O 0.3247(8) 0.5000 0.4386(15) 0.069(8) Uani 1 2 d S T P
O21 O 0.3511(8) 0.3568(15) 0.2497(12) 0.090(7) Uani 1 1 d . . .
C1 C 0.3014(13) 0.5000 0.3638(19) 0.049(9) Uani 1 2 d S T P
C2 C 0.3179(8) 0.4141(17) 0.2501(14) 0.042(6) Uani 1 1 d . . .
O1W O 0.0566(10) 0.2019(16) -0.0258(14) 0.116(8) Uani 1 1 d . U .
O2W O 0.1224(6) 0.3893(16) -0.2792(12) 0.091(7) Uani 1 1 d . . .
O3W O 0.0542(9) 0.5000 -0.4176(12) 0.069(8) Uani 1 2 d S T P
N1 N 0.9344(16) 0.234(3) 0.395(3) 0.060(12) Uiso 0.5 1 d . U .
N2 N 0.3218(17) 0.5000 0.978(3) 0.032(11) Uiso 0.5 2 d S TU P
O4W O 0.3697(7) 0.5000 0.5840(11) 0.036(5) Uani 1 2 d S T P
O5W O 0.1583(10) 0.2730(19) 0.5757(16) 0.128(9) Uiso 1 1 d . . .
O6W O 0.0592(8) 0.2325(17) 0.8111(13) 0.101(8) Uani 1 1 d . . .
O7W O 0.1704(8) 0.3072(14) 0.8708(12) 0.084(6) Uiso 1 1 d . . .
O8W O 0.2384(8) 0.0000 0.3422(14) 0.054(6) Uani 1 2 d S T P
O9W O 0.2001(9) 0.1101(14) 0.4179(13) 0.099(7) Uani 1 1 d . . .
O10W O 0.3321(10) 0.0000 0.435(2) 0.115(12) Uani 1 2 d S T P
O11W O 0.3639(15) 0.5000 0.722(2) 0.120(13) Uani 1 2 d S T P
O12W O 0.2488(11) 0.137(2) 0.2614(18) 0.154(11) Uani 1 1 d . . .
O13W O 0.4356(13) 0.395(2) 0.579(2) 0.063(10) Uiso 0.5 1 d . . .
O14W O 1.0000 0.226(4) 0.5000 0.071(15) Uani 0.5 2 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Bi Bi -4.1077 10.2566 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
W W -0.8490 6.8722 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 W1 O5 86.3(7) . .
O1 W1 O6 86.1(6) . .
O2 W1 O1 100.6(7) . .
O2 W1 O3 100.7(6) . .
O2 W1 O4 96.8(6) . .
O2 W1 O5 100.1(6) . .
O2 W1 O6 172.6(6) . .
O3 W1 O1 91.2(7) . .
O3 W1 O4 90.4(6) . .
O3 W1 O5 159.2(5) . .
O3 W1 O6 76.0(5) . .
O4 W1 O1 161.9(6) . .
O4 W1 O5 85.8(5) . .
O4 W1 O6 76.7(5) . .
O5 W1 O6 83.2(5) . .
O3 W2 O6 72.6(5) . .
O7 W2 O3 94.0(6) . .
O7 W2 O6 163.8(6) . .
O7 W2 O8 100.7(8) . .
O7 W2 O9 105.2(7) . .
O7 W2 O10 96.5(7) . .
O8 W2 O3 86.0(7) . .
O8 W2 O6 87.7(7) . .
O8 W2 O10 161.0(7) . .
O9 W2 O3 160.8(6) . .
O9 W2 O6 88.3(5) . .
O9 W2 O8 92.0(7) . .
O9 W2 O10 91.5(6) . .
O10 W2 O3 84.5(6) . .
O10 W2 O6 73.7(5) . .
O4 W3 O6 74.8(5) . .
O10 W3 O4 86.4(5) . .
O10 W3 O6 75.8(5) . .
O10 W3 O12 157.3(6) . .
O11 W3 O4 97.7(6) . .
O11 W3 O6 170.8(6) . .
O11 W3 O10 98.7(7) . .
O11 W3 O12 100.9(6) . .
O11 W3 O13 104.6(7) . .
O12 W3 O4 79.7(5) . .
O12 W3 O6 83.3(5) . .
O13 W3 O4 155.9(6) . .
O13 W3 O6 83.8(6) . .
O13 W3 O10 99.2(6) . .
O13 W3 O12 87.0(6) . .
O5 W4 Mn3 41.3(4) . .
O5 W4 O17 86.6(5) . .
O12 W4 Mn3 128.8(4) . .
O12 W4 O5 87.6(5) . .
O12 W4 O16 156.7(6) . .
O12 W4 O17 86.6(5) . .
O14 W4 Mn3 89.2(5) . .
O14 W4 O5 98.4(6) . .
O14 W4 O12 103.1(6) . .
O14 W4 O15 99.4(6) . .
O14 W4 O16 97.4(6) . .
O14 W4 O17 169.2(6) . .
O15 W4 Mn3 129.1(4) . .
O15 W4 O5 159.6(5) . .
O15 W4 O12 98.0(5) . .
O15 W4 O16 89.5(6) . .
O15 W4 O17 74.2(5) . .
O16 W4 Mn3 39.7(5) . .
O16 W4 O5 78.4(6) . .
O16 W4 O17 74.1(5) . .
O17 W4 Mn3 88.3(3) . .
O15 W5 O15 78.7(7) . 6_565
O15 W5 O17 70.8(4) . .
O15 W5 O17 70.8(4) 6_565 .
O18 W5 O15 157.5(6) 6_565 .
O18 W5 O15 88.5(6) 6_565 6_565
O18 W5 O15 88.5(6) . .
O18 W5 O15 157.6(6) . 6_565
O18 W5 O17 87.6(5) . .
O18 W5 O17 87.6(5) 6_565 .
O18 W5 O18 97.2(11) . 6_565
O18 W5 O19 104.5(6) 6_565 .
O18 W5 O19 104.4(6) . .
O19 W5 O15 95.0(5) . .
O19 W5 O15 95.0(5) . 6_565
O19 W5 O17 161.4(7) . .
O6 Bi1 O6 83.8(7) . 6_565
O17 Bi1 O6 90.2(5) . 6_565
O17 Bi1 O6 90.2(5) . .
O13 Mn1 O13 178.5(9) . 2
O13 Mn1 O1W 92.8(7) 2 2
O13 Mn1 O1W 88.2(7) . 2
O13 Mn1 O1W 88.2(7) 2 .
O13 Mn1 O1W 92.8(7) . .
O18 Mn1 O13 90.8(5) . 2
O18 Mn1 O13 88.1(5) 2 2
O18 Mn1 O13 88.1(5) . .
O18 Mn1 O13 90.8(5) 2 .
O18 Mn1 O18 90.7(9) 2 .
O18 Mn1 O1W 87.7(9) . .
O18 Mn1 O1W 176.0(7) 2 .
O18 Mn1 O1W 176.0(7) . 2
O18 Mn1 O1W 87.7(9) 2 2
O1W Mn1 O1W 94.2(15) 2 .
O9 Mn2 O9 79.4(8) 2 5_565
O9 Mn2 O2W 169.5(7) 5_565 .
O9 Mn2 O2W 93.1(7) 2 .
O9 Mn2 O2W 93.1(7) 5_565 6_565
O9 Mn2 O2W 169.5(7) 2 6_565
O9 Mn2 O3W 91.6(6) 2 .
O9 Mn2 O3W 91.6(6) 5_565 .
O19 Mn2 O9 97.4(6) . 5_565
O19 Mn2 O9 97.4(6) . 2
O19 Mn2 O2W 90.7(6) . 6_565
O19 Mn2 O2W 90.7(6) . .
O19 Mn2 O3W 168.2(8) . .
O2W Mn2 O2W 93.3(11) . 6_565
O2W Mn2 O3W 81.2(7) 6_565 .
O2W Mn2 O3W 81.2(7) . .
W4 Mn3 W4 65.46(10) . 6_565
O5 Mn3 W4 87.3(4) 6_565 .
O5 Mn3 W4 87.3(4) . 6_565
O5 Mn3 W4 39.5(4) . .
O5 Mn3 W4 39.5(4) 6_565 6_565
O5 Mn3 O5 84.1(7) 6_565 .
O16 Mn3 W4 38.3(2) . 6_565
O16 Mn3 W4 38.3(2) . .
O16 Mn3 O5 75.3(5) . .
O16 Mn3 O5 75.3(5) . 6_565
C1 Mn3 W4 139.9(6) . 6_565
C1 Mn3 W4 139.9(6) . .
C1 Mn3 O5 102.0(9) . .
C1 Mn3 O5 102.0(9) . 6_565
C1 Mn3 O16 176.4(13) . .
C1 Mn3 C2 85.0(11) . 6_565
C1 Mn3 C2 85.0(11) . .
C2 Mn3 W4 134.1(8) . 6_565
C2 Mn3 W4 134.1(8) 6_565 .
C2 Mn3 W4 86.0(7) . .
C2 Mn3 W4 86.0(7) 6_565 6_565
C2 Mn3 O5 172.7(8) . 6_565
C2 Mn3 O5 172.7(8) 6_565 .
C2 Mn3 O5 92.4(8) . .
C2 Mn3 O5 92.4(8) 6_565 6_565
C2 Mn3 O16 97.6(8) 6_565 .
C2 Mn3 O16 97.6(8) . .
C2 Mn3 C2 90.3(14) . 6_565
W1 O1 W1 156.3(10) 6_565 .
W1 O3 W2 115.5(6) . .
W1 O4 W3 114.0(7) . .
W1 O5 W4 140.7(6) . .
W1 O5 Mn3 119.7(6) . .
W4 O5 Mn3 99.2(6) . .
W2 O6 W1 96.0(5) . .
W3 O6 W1 94.4(5) . .
W3 O6 W2 94.2(5) . .
Bi1 O6 W1 141.0(7) . .
Bi1 O6 W2 110.9(5) . .
Bi1 O6 W3 110.5(5) . .
W2 O8 W2 144.4(10) . 6_565
W2 O9 Mn2 137.2(8) . 5_565
W3 O10 W2 115.6(7) . .
W4 O12 W3 148.9(7) . .
W3 O13 Mn1 140.1(8) . .
W4 O15 W5 117.0(6) . .
W4 O16 W4 117.2(8) . 6_565
W4 O16 Mn3 102.0(5) . .
W4 O16 Mn3 102.0(5) 6_565 .
W4 O17 W4 94.3(6) 6_565 .
W5 O17 W4 97.2(5) . .
W5 O17 W4 97.2(5) . 6_565
Bi1 O17 W4 126.2(4) . 6_565
Bi1 O17 W4 126.2(4) . .
Bi1 O17 W5 109.0(7) . .
W5 O18 Mn1 176.0(10) . .
W5 O19 Mn2 163.7(11) . .
O20 C1 Mn3 177(3) . .
O21 C2 Mn3 177(2) . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
W1 O1 1.903(4) .
W1 O2 1.719(13) .
W1 O3 1.868(13) .
W1 O4 1.896(14) .
W1 O5 1.953(13) .
W1 O6 2.262(12) .
W2 O3 2.085(13) .
W2 O6 2.240(13) .
W2 O7 1.727(13) .
W2 O8 1.900(5) .
W2 O9 1.778(13) .
W2 O10 1.985(15) .
W3 O4 2.036(13) .
W3 O6 2.232(14) .
W3 O10 1.884(13) .
W3 O11 1.730(14) .
W3 O12 1.997(12) .
W3 O13 1.760(13) .
W4 Mn3 3.125(4) .
W4 O5 2.013(13) .
W4 O12 1.826(12) .
W4 O14 1.698(12) .
W4 O15 1.816(12) .
W4 O16 1.979(8) .
W4 O17 2.304(10) .
W5 O15 2.141(12) 6_565
W5 O15 2.141(12) .
W5 O17 2.198(16) .
W5 O18 1.731(14) .
W5 O18 1.731(14) 6_565
W5 O19 1.761(16) .
Bi1 O6 2.131(13) 6_565
Bi1 O6 2.131(13) .
Bi1 O17 2.127(16) .
Mn1 O13 2.120(13) 2
Mn1 O13 2.120(13) .
Mn1 O18 2.117(15) .
Mn1 O18 2.117(15) 2
Mn1 O1W 2.217(19) 2
Mn1 O1W 2.217(19) .
Mn2 O9 2.150(14) 2
Mn2 O9 2.150(14) 5_565
Mn2 O19 2.088(17) .
Mn2 O2W 2.193(17) 6_565
Mn2 O2W 2.193(17) .
Mn2 O3W 2.32(2) .
Mn3 W4 3.125(4) 6_565
Mn3 O5 2.089(12) 6_565
Mn3 O5 2.089(12) .
Mn3 O16 2.041(17) .
Mn3 C1 1.73(3) .
Mn3 C2 1.75(2) .
Mn3 C2 1.75(2) 6_565
O1 W1 1.903(4) 6_565
O8 W2 1.900(5) 6_565
O9 Mn2 2.150(14) 5_565
O16 W4 1.979(8) 6_565
O17 W4 2.304(10) 6_565
O20 C1 1.21(3) .
O21 C2 1.19(3) .
