#------------------------------------------------------------------------------
#$Date: 2017-08-10 07:53:52 +0300 (Thu, 10 Aug 2017) $
#$Revision: 199696 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/22/88/7228888.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7228888
loop_
_publ_author_name
'Lv, Xue-Hui'
'Yang, Shuai-Liang'
'Li, Yuan-Xia'
'Zhang, Chen-Xi'
'Wang, Qing-Lun'
_publ_section_title
;
 A family of lanthanide compounds based on nitronyl nitroxide radicals:
 synthesis, structure, magnetic and fluorescence properties
;
_journal_issue                   61
_journal_name_full               'RSC Adv.'
_journal_page_first              38179
_journal_paper_doi               10.1039/C7RA05764D
_journal_volume                  7
_journal_year                    2017
_chemical_formula_sum            'C149 H173 Eu3 F54 N18 O30'
_chemical_formula_weight         4177.93
_chemical_name_systematic
; 
 ? 
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_audit_update_record
;
2015-05-08 deposited with the CCDC.
2017-07-27 downloaded from the CCDC.
;
_cell_angle_alpha                90.00
_cell_angle_beta                 101.271(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   50.142(5)
_cell_length_b                   12.6433(12)
_cell_length_c                   28.692(2)
_cell_measurement_reflns_used    23209
_cell_measurement_temperature    113(2)
_cell_measurement_theta_max      27.9
_cell_measurement_theta_min      1.2
_cell_volume                     17839(3)
_computing_cell_refinement       CrystalClear
_computing_data_collection       CrystalClear
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'CrystalStructure 3.8'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      113(2)
_diffrn_detector_area_resol_mean 14.22
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Rigaku Saturn724 CCD'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  multilayer
_diffrn_radiation_source         'rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0381
_diffrn_reflns_av_sigmaI/netI    0.0314
_diffrn_reflns_limit_h_max       59
_diffrn_reflns_limit_h_min       -59
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       34
_diffrn_reflns_limit_l_min       -33
_diffrn_reflns_number            68008
_diffrn_reflns_theta_full        25.02
_diffrn_reflns_theta_max         25.02
_diffrn_reflns_theta_min         1.45
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.169
_exptl_absorpt_correction_T_max  0.7830
_exptl_absorpt_correction_T_min  0.7667
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   CrystalClear
_exptl_crystal_colour            Colorless
_exptl_crystal_density_diffrn    1.556
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             8432
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.829
_refine_diff_density_min         -0.913
_refine_diff_density_rms         0.072
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.118
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1244
_refine_ls_number_reflns         15737
_refine_ls_number_restraints     295
_refine_ls_restrained_S_all      1.184
_refine_ls_R_factor_all          0.0407
_refine_ls_R_factor_gt           0.0388
_refine_ls_shift/su_max          0.007
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0296P)²+68.3786P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0887
_refine_ls_wR_factor_ref         0.0898
_reflns_number_gt                15101
_reflns_number_total             15737
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c7ra05764d2.cif
_cod_data_source_block           shelx_CCDC1
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_absorpt_correction_type' value 'MULTI-SCAN' changed to
'multi-scan' according to
/home/data/users/saulius/crontab/automatic-downloads/rss-feeds/RSC/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

Automatic conversion script
Id: cif_fix_values 4973 2017-02-22 13:04:09Z antanas 
;
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               7228888
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.142065(3) 0.326931(13) 0.080452(6) 0.02198(6) Uani 1 1 d . . .
Eu2 Eu 0.0000 0.819585(18) 0.2500 0.02076(7) Uani 1 2 d S . .
F1 F 0.18506(6) -0.0254(2) 0.04084(15) 0.0874(11) Uani 1 1 d U . .
F2 F 0.20099(11) 0.0042(3) 0.11195(14) 0.1227(17) Uani 1 1 d U . .
F3 F 0.22568(6) 0.0212(2) 0.06183(15) 0.0832(11) Uani 1 1 d U . .
F4 F 0.23811(5) 0.4501(2) 0.07066(9) 0.0484(6) Uani 1 1 d U . .
F5 F 0.24089(5) 0.3620(2) 0.00815(10) 0.0558(7) Uani 1 1 d U . .
F6 F 0.21223(5) 0.4893(2) 0.00440(9) 0.0470(6) Uani 1 1 d U . .
F7 F 0.11266(9) 0.6308(2) -0.03650(12) 0.1017(14) Uani 1 1 d U . .
F8 F 0.10956(7) 0.4922(2) -0.07915(9) 0.0693(9) Uani 1 1 d U . .
F9 F 0.07413(6) 0.5712(3) -0.06814(10) 0.0686(9) Uani 1 1 d U . .
F10 F 0.02725(5) 0.4299(3) 0.04127(12) 0.0682(9) Uani 1 1 d U . .
F11 F 0.04062(6) 0.2754(2) 0.06210(15) 0.0824(11) Uani 1 1 d U . .
F12 F 0.04781(6) 0.4026(3) 0.11142(11) 0.0840(11) Uani 1 1 d U . .
F13 F 0.13405(7) -0.0229(2) 0.16496(13) 0.0787(10) Uani 1 1 d U . .
F14 F 0.10395(6) 0.0772(2) 0.18362(11) 0.0653(8) Uani 1 1 d U . .
F15 F 0.13942(8) 0.0425(3) 0.23511(11) 0.0918(12) Uani 1 1 d U . .
F16 F 0.22795(11) 0.1978(5) 0.2248(3) 0.092(3) Uani 0.652(10) 1 d PU A 1
F17 F 0.21431(17) 0.3487(8) 0.2458(3) 0.087(3) Uani 0.652(10) 1 d PU A 1
F18 F 0.23125(9) 0.3329(5) 0.18443(18) 0.0558(16) Uani 0.652(10) 1 d PU A 1
F16' F 0.2166(2) 0.2409(11) 0.2585(4) 0.080(4) Uani 0.348(10) 1 d PU A 2
F17' F 0.2154(3) 0.3913(11) 0.2290(6) 0.077(4) Uani 0.348(10) 1 d PU A 2
F18' F 0.2321(2) 0.2630(16) 0.1969(5) 0.098(5) Uani 0.348(10) 1 d PU A 2
C61 C 0.0362(2) 0.4775(10) 0.2392(4) 0.032(4) Uani 0.369(6) 1 d PDU B 1
F19 F 0.01952(16) 0.4279(6) 0.2632(3) 0.067(3) Uani 0.369(6) 1 d PDU B 1
F20 F 0.0406(4) 0.408(2) 0.2058(6) 0.045(4) Uani 0.369(6) 1 d PDU B 1
F21 F 0.05982(17) 0.4885(9) 0.2694(4) 0.073(4) Uani 0.369(6) 1 d PDU B 1
C61' C 0.04496(17) 0.4994(8) 0.2342(3) 0.047(3) Uani 0.631(6) 1 d PDU B 2
F19' F 0.07001(8) 0.5213(4) 0.22808(19) 0.0665(17) Uani 0.631(6) 1 d PDU B 2
F20' F 0.0370(2) 0.4101(12) 0.2114(4) 0.065(3) Uani 0.631(6) 1 d PDU B 2
F21' F 0.04659(14) 0.4812(5) 0.2804(2) 0.063(2) Uani 0.631(6) 1 d PDU B 2
F22 F 0.04580(5) 0.6384(3) 0.40324(9) 0.0640(8) Uani 1 1 d U . .
F23 F 0.01924(6) 0.7486(2) 0.42471(10) 0.0680(8) Uani 1 1 d U . .
F24 F 0.00953(7) 0.5855(3) 0.42458(9) 0.0769(10) Uani 1 1 d U . .
F25 F 0.02775(10) 1.1154(4) 0.36806(15) 0.139(2) Uani 1 1 d U . .
F26 F -0.01361(10) 1.1194(3) 0.36065(15) 0.1240(18) Uani 1 1 d U . .
F27 F 0.00609(9) 1.2398(2) 0.33257(11) 0.0952(13) Uani 1 1 d U . .
O1 O 0.14101(5) 0.49181(19) 0.11743(8) 0.0267(5) Uani 1 1 d . . .
O2 O 0.18345(6) 0.6197(2) 0.26497(10) 0.0470(8) Uani 1 1 d . . .
O3 O 0.11691(5) 0.22910(18) 0.01687(9) 0.0262(5) Uani 1 1 d . . .
O4 O 0.13430(6) -0.0578(2) -0.07333(10) 0.0366(6) Uani 1 1 d . . .
O5 O 0.16829(5) 0.16811(19) 0.07217(9) 0.0292(6) Uani 1 1 d . . .
O6 O 0.18043(5) 0.37740(19) 0.04899(9) 0.0267(5) Uani 1 1 d . . .
O7 O 0.12382(5) 0.44763(18) 0.01688(8) 0.0257(5) Uani 1 1 d . . .
O8 O 0.09474(5) 0.35569(19) 0.08255(9) 0.0271(5) Uani 1 1 d . . .
O9 O 0.13151(5) 0.2015(2) 0.13545(9) 0.0311(6) Uani 1 1 d . . .
O10 O 0.17933(5) 0.3269(2) 0.14771(9) 0.0318(6) Uani 1 1 d . . .
O11 O 0.04592(5) 0.87382(19) 0.25552(9) 0.0267(5) Uani 1 1 d . . .
O12 O 0.12192(5) 0.7157(3) 0.21580(10) 0.0413(7) Uani 1 1 d . . .
O13 O 0.02738(5) 0.66351(19) 0.24682(9) 0.0280(6) Uani 1 1 d . B .
O14 O 0.00890(5) 0.75697(19) 0.32983(9) 0.0270(5) Uani 1 1 d . . .
O15 O 0.00346(5) 0.97507(18) 0.29968(9) 0.0267(5) Uani 1 1 d . . .
N1 N 0.15670(6) 0.5465(2) 0.15110(10) 0.0256(6) Uani 1 1 d . . .
N2 N 0.17663(6) 0.6068(3) 0.21986(11) 0.0335(7) Uani 1 1 d . . .
N3 N 0.10249(10) 0.2362(3) 0.29138(15) 0.0594(12) Uani 1 1 d . . .
N4 N 0.11663(6) 0.1343(2) -0.00175(10) 0.0238(6) Uani 1 1 d . . .
N5 N 0.12472(6) -0.0008(2) -0.04377(11) 0.0269(7) Uani 1 1 d . . .
N6 N 0.20795(7) 0.3401(3) -0.11102(12) 0.0372(8) Uani 1 1 d . . .
N7 N 0.06987(6) 0.8287(2) 0.25871(10) 0.0234(6) Uani 1 1 d . . .
N8 N 0.10569(6) 0.7548(3) 0.24028(11) 0.0293(7) Uani 1 1 d . . .
N9 N 0.03447(7) 0.7995(3) 0.02569(11) 0.0320(7) Uani 1 1 d . . .
C1 C 0.15882(7) 0.5323(3) 0.19762(13) 0.0289(8) Uani 1 1 d . . .
C2 C 0.17102(8) 0.6433(3) 0.13791(14) 0.0315(8) Uani 1 1 d . . .
C3 C 0.18557(10) 0.6153(4) 0.09777(17) 0.0535(13) Uani 1 1 d . . .
H3A H 0.1969 0.5526 0.1066 0.080 Uiso 1 1 calc R . .
H3B H 0.1971 0.6747 0.0920 0.080 Uiso 1 1 calc R . .
H3C H 0.1721 0.6006 0.0688 0.080 Uiso 1 1 calc R . .
C4 C 0.14914(9) 0.7257(3) 0.12123(16) 0.0409(10) Uani 1 1 d . . .
H4A H 0.1355 0.6964 0.0953 0.061 Uiso 1 1 calc R . .
H4B H 0.1574 0.7885 0.1099 0.061 Uiso 1 1 calc R . .
H4C H 0.1404 0.7454 0.1477 0.061 Uiso 1 1 calc R . .
C5 C 0.18999(8) 0.6684(3) 0.18638(16) 0.0387(10) Uani 1 1 d . . .
C6 C 0.21863(9) 0.6225(5) 0.1913(2) 0.0681(16) Uani 1 1 d . . .
H6A H 0.2284 0.6305 0.2242 0.102 Uiso 1 1 calc R . .
H6B H 0.2284 0.6602 0.1700 0.102 Uiso 1 1 calc R . .
H6C H 0.2174 0.5473 0.1829 0.102 Uiso 1 1 calc R . .
C7 C 0.19099(12) 0.7845(4) 0.20059(18) 0.0615(14) Uani 1 1 d . . .
H7A H 0.1726 0.8089 0.2020 0.092 Uiso 1 1 calc R . .
H7B H 0.1982 0.8263 0.1771 0.092 Uiso 1 1 calc R . .
H7C H 0.2028 0.7929 0.2319 0.092 Uiso 1 1 calc R . .
C8 C 0.14477(8) 0.4541(3) 0.22113(13) 0.0299(8) Uani 1 1 d . . .
C9 C 0.15580(10) 0.4187(3) 0.26714(14) 0.0410(10) Uani 1 1 d . . .
H9 H 0.1731 0.4440 0.2829 0.049 Uiso 1 1 calc R . .
C10 C 0.14175(11) 0.3472(3) 0.28980(15) 0.0470(12) Uani 1 1 d . . .
H10 H 0.1496 0.3250 0.3211 0.056 Uiso 1 1 calc R . .
C11 C 0.11649(10) 0.3065(3) 0.26808(16) 0.0454(11) Uani 1 1 d . . .
C12 C 0.10593(9) 0.3398(3) 0.22140(16) 0.0398(10) Uani 1 1 d . . .
H12 H 0.0891 0.3120 0.2051 0.048 Uiso 1 1 calc R . .
C13 C 0.11962(8) 0.4122(3) 0.19886(14) 0.0329(9) Uani 1 1 d . . .
H13 H 0.1118 0.4343 0.1675 0.039 Uiso 1 1 calc R . .
C14 C 0.11255(16) 0.2164(5) 0.34136(19) 0.087(2) Uani 1 1 d . . .
H14A H 0.1308 0.1853 0.3458 0.131 Uiso 1 1 calc R . .
H14B H 0.1003 0.1674 0.3532 0.131 Uiso 1 1 calc R . .
H14C H 0.1134 0.2832 0.3589 0.131 Uiso 1 1 calc R . .
C15 C 0.07480(11) 0.2058(4) 0.2710(2) 0.076(2) Uani 1 1 d . . .
H15A H 0.0629 0.2675 0.2698 0.113 Uiso 1 1 calc R . .
H15B H 0.0688 0.1507 0.2906 0.113 Uiso 1 1 calc R . .
H15C H 0.0740 0.1787 0.2387 0.113 Uiso 1 1 calc R . .
C16 C 0.13214(7) 0.1015(3) -0.03155(12) 0.0232(7) Uani 1 1 d . . .
C17 C 0.09389(7) 0.0599(3) 0.00243(13) 0.0272(8) Uani 1 1 d . . .
C18 C 0.06856(8) 0.1047(3) -0.03031(16) 0.0388(10) Uani 1 1 d . . .
H18A H 0.0651 0.1767 -0.0202 0.058 Uiso 1 1 calc R . .
H18B H 0.0528 0.0599 -0.0286 0.058 Uiso 1 1 calc R . .
H18C H 0.0715 0.1062 -0.0631 0.058 Uiso 1 1 calc R . .
C19 C 0.08967(9) 0.0568(3) 0.05308(15) 0.0402(10) Uani 1 1 d . . .
H19A H 0.1070 0.0408 0.0744 0.060 Uiso 1 1 calc R . .
H19B H 0.0763 0.0020 0.0562 0.060 Uiso 1 1 calc R . .
H19C H 0.0830 0.1257 0.0615 0.060 Uiso 1 1 calc R . .
C20 C 0.10487(8) -0.0441(3) -0.01582(13) 0.0287(8) Uani 1 1 d . . .
C21 C 0.12115(9) -0.1127(3) 0.02360(16) 0.0435(10) Uani 1 1 d . . .
H21A H 0.1302 -0.1695 0.0095 0.065 Uiso 1 1 calc R . .
H21B H 0.1088 -0.1434 0.0426 0.065 Uiso 1 1 calc R . .
H21C H 0.1348 -0.0691 0.0440 0.065 Uiso 1 1 calc R . .
C22 C 0.08355(9) -0.1098(3) -0.04851(16) 0.0424(10) Uani 1 1 d . . .
H22A H 0.0755 -0.0677 -0.0763 0.064 Uiso 1 1 calc R . .
H22B H 0.0693 -0.1312 -0.0314 0.064 Uiso 1 1 calc R . .
H22C H 0.0921 -0.1730 -0.0588 0.064 Uiso 1 1 calc R . .
C23 C 0.15239(7) 0.1624(3) -0.05016(12) 0.0241(7) Uani 1 1 d . . .
C24 C 0.17432(7) 0.1136(3) -0.06535(13) 0.0275(8) Uani 1 1 d . . .
H24 H 0.1765 0.0391 -0.0624 0.033 Uiso 1 1 calc R . .
C25 C 0.19283(7) 0.1718(3) -0.08456(13) 0.0294(8) Uani 1 1 d . . .
H25 H 0.2076 0.1366 -0.0942 0.035 Uiso 1 1 calc R . .
C26 C 0.19029(7) 0.2825(3) -0.09012(13) 0.0275(8) Uani 1 1 d . . .
C27 C 0.16871(8) 0.3309(3) -0.07341(13) 0.0280(8) Uani 1 1 d . . .
H27 H 0.1668 0.4055 -0.0755 0.034 Uiso 1 1 calc R . .
C28 C 0.15036(7) 0.2728(3) -0.05408(12) 0.0259(8) Uani 1 1 d . . .
H28 H 0.1360 0.3082 -0.0432 0.031 Uiso 1 1 calc R . .
C29 C 0.22559(8) 0.2872(4) -0.13825(15) 0.0413(10) Uani 1 1 d . . .
H29A H 0.2370 0.2354 -0.1180 0.062 Uiso 1 1 calc R . .
H29B H 0.2372 0.3395 -0.1496 0.062 Uiso 1 1 calc R . .
H29C H 0.2145 0.2509 -0.1655 0.062 Uiso 1 1 calc R . .
C30 C 0.20309(9) 0.4525(3) -0.11979(16) 0.0434(10) Uani 1 1 d . . .
H30A H 0.1853 0.4624 -0.1407 0.065 Uiso 1 1 calc R . .
H30B H 0.2173 0.4817 -0.1350 0.065 Uiso 1 1 calc R . .
H30C H 0.2033 0.4889 -0.0896 0.065 Uiso 1 1 calc R . .
C31 C 0.20123(8) 0.0382(3) 0.06976(16) 0.0397(10) Uani 1 1 d . . .
C32 C 0.19160(7) 0.1534(3) 0.06379(13) 0.0285(8) Uani 1 1 d . . .
C33 C 0.20909(7) 0.2265(3) 0.04965(13) 0.0286(8) Uani 1 1 d . . .
H33 H 0.2262 0.2035 0.0440 0.034 Uiso 1 1 calc R . .
C34 C 0.20200(7) 0.3332(3) 0.04362(12) 0.0258(8) Uani 1 1 d . . .
C35 C 0.22345(8) 0.4088(3) 0.03091(14) 0.0326(9) Uani 1 1 d . . .
C36 C 0.09883(9) 0.5419(3) -0.04723(15) 0.0388(10) Uani 1 1 d . . .
C37 C 0.10021(8) 0.4745(3) -0.00210(13) 0.0281(8) Uani 1 1 d . . .
C38 C 0.07584(7) 0.4518(3) 0.01228(13) 0.0293(8) Uani 1 1 d . . .
H38 H 0.0592 0.4755 -0.0067 0.035 Uiso 1 1 calc R . .
C39 C 0.07524(7) 0.3952(3) 0.05370(13) 0.0267(8) Uani 1 1 d . . .
C40 C 0.04743(8) 0.3754(3) 0.06735(15) 0.0373(9) Uani 1 1 d . . .
C41 C 0.13041(10) 0.0633(4) 0.18938(17) 0.0494(12) Uani 1 1 d . . .
C42 C 0.14480(8) 0.1581(3) 0.17169(14) 0.0348(9) Uani 1 1 d . . .
C43 C 0.17094(9) 0.1833(3) 0.19627(15) 0.0420(10) Uani 1 1 d . . .
H43 H 0.1787 0.1429 0.2235 0.050 Uiso 1 1 calc R . .
C44 C 0.18593(8) 0.2660(3) 0.18207(15) 0.0366(9) Uani 1 1 d . A .
C45 C 0.21424(10) 0.2877(4) 0.21206(19) 0.0550(13) Uani 1 1 d . . .
C46 C 0.08003(7) 0.7918(3) 0.22235(13) 0.0244(7) Uani 1 1 d . . .
C47 C 0.08949(7) 0.8278(3) 0.30541(13) 0.0282(8) Uani 1 1 d . . .
C48 C 0.07555(8) 0.7800(4) 0.34287(14) 0.0432(11) Uani 1 1 d . . .
H48A H 0.0606 0.8260 0.3476 0.065 Uiso 1 1 calc R . .
H48B H 0.0887 0.7730 0.3728 0.065 Uiso 1 1 calc R . .
H48C H 0.0684 0.7101 0.3323 0.065 Uiso 1 1 calc R . .
C49 C 0.09700(9) 0.9428(3) 0.31750(17) 0.0436(11) Uani 1 1 d . . .
H49A H 0.1045 0.9746 0.2917 0.065 Uiso 1 1 calc R . .
H49B H 0.1106 0.9458 0.3471 0.065 Uiso 1 1 calc R . .
H49C H 0.0807 0.9819 0.3215 0.065 Uiso 1 1 calc R . .
C50 C 0.11331(7) 0.7587(3) 0.29350(13) 0.0272(8) Uani 1 1 d . . .
C51 C 0.14154(8) 0.8074(3) 0.30750(14) 0.0349(9) Uani 1 1 d . . .
H51A H 0.1549 0.7614 0.2969 0.052 Uiso 1 1 calc R . .
H51B H 0.1462 0.8153 0.3421 0.052 Uiso 1 1 calc R . .
H51C H 0.1417 0.8770 0.2925 0.052 Uiso 1 1 calc R . .
C52 C 0.11402(10) 0.6441(3) 0.31096(16) 0.0432(10) Uani 1 1 d . . .
H52A H 0.0961 0.6118 0.3005 0.065 Uiso 1 1 calc R . .
H52B H 0.1188 0.6429 0.3457 0.065 Uiso 1 1 calc R . .
H52C H 0.1276 0.6043 0.2978 0.065 Uiso 1 1 calc R . .
C53 C 0.06757(7) 0.7924(3) 0.17241(12) 0.0230(7) Uani 1 1 d . . .
C54 C 0.07311(7) 0.7114(3) 0.14206(13) 0.0274(8) Uani 1 1 d . . .
H54 H 0.0848 0.6549 0.1547 0.033 Uiso 1 1 calc R . .
C55 C 0.06190(7) 0.7128(3) 0.09427(13) 0.0284(8) Uani 1 1 d . . .
H55 H 0.0658 0.6566 0.0746 0.034 Uiso 1 1 calc R . .
C56 C 0.04479(7) 0.7958(3) 0.07400(13) 0.0254(8) Uani 1 1 d . . .
C57 C 0.03906(7) 0.8753(3) 0.10485(13) 0.0280(8) Uani 1 1 d . . .
H57 H 0.0273 0.9317 0.0924 0.034 Uiso 1 1 calc R . .
C58 C 0.05005(7) 0.8736(3) 0.15255(13) 0.0262(8) Uani 1 1 d . . .
H58 H 0.0457 0.9284 0.1724 0.031 Uiso 1 1 calc R . .
C59 C 0.01460(8) 0.8791(3) 0.00668(14) 0.0370(9) Uani 1 1 d . . .
H59A H -0.0021 0.8672 0.0188 0.055 Uiso 1 1 calc R . .
H59B H 0.0106 0.8748 -0.0281 0.055 Uiso 1 1 calc R . .
H59C H 0.0219 0.9494 0.0165 0.055 Uiso 1 1 calc R . .
C60 C 0.03529(9) 0.7045(3) -0.00292(14) 0.0371(9) Uani 1 1 d . . .
H60A H 0.0542 0.6829 -0.0011 0.056 Uiso 1 1 calc R . .
H60B H 0.0269 0.7194 -0.0361 0.056 Uiso 1 1 calc R . .
H60C H 0.0253 0.6474 0.0092 0.056 Uiso 1 1 calc R . .
C62 C 0.02523(7) 0.5888(3) 0.21769(14) 0.0298(8) Uani 1 1 d . . .
C64 C 0.01976(8) 0.6592(3) 0.40076(15) 0.0361(9) Uani 1 1 d . . .
C65 C 0.00480(7) 0.6707(3) 0.34881(13) 0.0275(8) Uani 1 1 d . . .
C66 C -0.01070(8) 0.5853(3) 0.32859(14) 0.0333(9) Uani 1 1 d . . .
H66 H -0.0113 0.5231 0.3469 0.040 Uiso 1 1 calc R . .
C67 C 0.00588(10) 1.1384(3) 0.33830(16) 0.0420(10) Uani 1 1 d . . .
C68 C 0.00292(7) 1.0730(3) 0.29277(13) 0.0283(8) Uani 1 1 d . . .
C69 C 0.0000 1.1263(4) 0.2500 0.0325(12) Uani 1 2 d S . .
H69 H 0.0000 1.2015 0.2500 0.039 Uiso 1 2 calc SR . .
C70 C 0.20663(15) 0.0017(5) 0.3054(3) 0.090(2) Uani 1 1 d . . .
H70A H 0.2145 0.0310 0.2794 0.135 Uiso 1 1 calc R . .
H70B H 0.1910 -0.0430 0.2921 0.135 Uiso 1 1 calc R . .
H70C H 0.2204 -0.0407 0.3263 0.135 Uiso 1 1 calc R . .
C71 C 0.1973(2) 0.0918(7) 0.3337(3) 0.145(4) Uani 1 1 d D C .
H71A H 0.1871 0.1429 0.3108 0.174 Uiso 1 1 calc R . .
H71B H 0.1844 0.0622 0.3523 0.174 Uiso 1 1 calc R . .
C72 C 0.21727(19) 0.1482(7) 0.3652(3) 0.143(4) Uani 1 1 d D . .
H72A H 0.2308 0.1728 0.3481 0.171 Uiso 0.441(7) 1 d PR C 1
H72B H 0.2261 0.0971 0.3879 0.171 Uiso 0.441(7) 1 d PR C 1
H72C H 0.2303 0.1763 0.3478 0.171 Uiso 0.559(7) 1 d PR C 2
H72D H 0.2268 0.0968 0.3871 0.171 Uiso 0.559(7) 1 d PR C 2
C73 C 0.2103(4) 0.2386(13) 0.3944(5) 0.127(3) Uani 0.441(7) 1 d PDU C 1
H73A H 0.1926 0.2236 0.4033 0.153 Uiso 0.441(7) 1 calc PR C 1
H73B H 0.2080 0.3031 0.3744 0.153 Uiso 0.441(7) 1 calc PR C 1
C74 C 0.2313(3) 0.2612(12) 0.4396(4) 0.105(3) Uani 0.441(7) 1 d PDU C 1
H74A H 0.2482 0.2220 0.4385 0.126 Uiso 0.441(7) 1 calc PR C 1
H74B H 0.2356 0.3377 0.4413 0.126 Uiso 0.441(7) 1 calc PR C 1
C75 C 0.2207(4) 0.229(2) 0.4838(6) 0.191(9) Uani 0.441(7) 1 d PDU C 1
H75A H 0.2306 0.2680 0.5117 0.229 Uiso 0.441(7) 1 calc PR C 1
H75B H 0.2238 0.1522 0.4897 0.229 Uiso 0.441(7) 1 calc PR C 1
C76 C 0.1901(3) 0.2537(15) 0.4762(6) 0.087(3) Uani 0.441(7) 1 d PDU C 1
H76A H 0.1872 0.3145 0.4959 0.130 Uiso 0.441(7) 1 calc PR C 1
H76B H 0.1804 0.1921 0.4853 0.130 Uiso 0.441(7) 1 calc PR C 1
H76C H 0.1832 0.2703 0.4427 0.130 Uiso 0.441(7) 1 calc PR C 1
C73' C 0.2091(4) 0.2357(9) 0.3951(4) 0.127(3) Uani 0.559(7) 1 d PDU C 2
H73C H 0.1932 0.2743 0.3769 0.153 Uiso 0.559(7) 1 calc PR C 2
H73D H 0.2243 0.2865 0.4041 0.153 Uiso 0.559(7) 1 calc PR C 2
C74' C 0.2018(3) 0.1861(9) 0.4397(4) 0.105(3) Uani 0.559(7) 1 d PDU C 2
H74C H 0.1856 0.1405 0.4306 0.126 Uiso 0.559(7) 1 calc PR C 2
H74D H 0.2171 0.1412 0.4557 0.126 Uiso 0.559(7) 1 calc PR C 2
C75' C 0.1961(4) 0.2708(17) 0.4737(5) 0.191(9) Uani 0.559(7) 1 d PDU C 2
H75C H 0.2111 0.3232 0.4787 0.229 Uiso 0.559(7) 1 calc PR C 2
H75D H 0.1953 0.2383 0.5048 0.229 Uiso 0.559(7) 1 calc PR C 2
C76' C 0.1690(2) 0.3272(8) 0.4541(5) 0.087(3) Uani 0.559(7) 1 d PDU C 2
H76D H 0.1704 0.3652 0.4249 0.130 Uiso 0.559(7) 1 calc PR C 2
H76E H 0.1650 0.3775 0.4778 0.130 Uiso 0.559(7) 1 calc PR C 2
H76F H 0.1544 0.2747 0.4472 0.130 Uiso 0.559(7) 1 calc PR C 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O1 Eu1 O3 139.59(8) . .
O1 Eu1 O6 91.42(8) . .
O3 Eu1 O6 101.43(8) . .
O1 Eu1 O9 105.42(9) . .
O3 Eu1 O9 90.52(9) . .
O6 Eu1 O9 137.61(8) . .
O1 Eu1 O10 73.76(8) . .
O3 Eu1 O10 146.51(8) . .
O6 Eu1 O10 75.21(9) . .
O9 Eu1 O10 72.86(9) . .
O1 Eu1 O8 75.25(8) . .
O3 Eu1 O8 73.64(8) . .
O6 Eu1 O8 147.72(8) . .
O9 Eu1 O8 74.66(8) . .
O10 Eu1 O8 126.33(8) . .
O1 Eu1 O7 75.02(8) . .
O3 Eu1 O7 71.37(8) . .
O6 Eu1 O7 75.99(8) . .
O9 Eu1 O7 145.55(8) . .
O10 Eu1 O7 136.44(8) . .
O8 Eu1 O7 72.22(8) . .
O1 Eu1 O5 146.83(8) . .
O3 Eu1 O5 73.09(8) . .
O6 Eu1 O5 71.98(8) . .
O9 Eu1 O5 73.05(8) . .
O10 Eu1 O5 74.28(9) . .
O8 Eu1 O5 132.73(8) . .
O7 Eu1 O5 125.35(8) . .
O11 Eu2 O11 146.48(12) 2 .
O11 Eu2 O14 91.99(8) 2 2
O11 Eu2 O14 99.03(8) . 2
O11 Eu2 O14 99.03(8) 2 .
O11 Eu2 O14 91.99(8) . .
O14 Eu2 O14 141.17(12) 2 .
O11 Eu2 O15 76.65(8) 2 2
O11 Eu2 O15 76.20(8) . 2
O14 Eu2 O15 74.01(8) 2 2
O14 Eu2 O15 144.76(8) . 2
O11 Eu2 O15 76.20(8) 2 .
O11 Eu2 O15 76.65(8) . .
O14 Eu2 O15 144.76(8) 2 .
O14 Eu2 O15 74.01(8) . .
O15 Eu2 O15 70.99(12) 2 .
O11 Eu2 O13 71.82(8) 2 2
O11 Eu2 O13 141.54(8) . 2
O14 Eu2 O13 76.34(8) 2 2
O14 Eu2 O13 72.13(8) . 2
O15 Eu2 O13 135.37(8) 2 2
O15 Eu2 O13 128.20(8) . 2
O11 Eu2 O13 141.55(8) 2 .
O11 Eu2 O13 71.82(8) . .
O14 Eu2 O13 72.13(8) 2 .
O14 Eu2 O13 76.33(8) . .
O15 Eu2 O13 128.20(8) 2 .
O15 Eu2 O13 135.36(8) . .
O13 Eu2 O13 70.47(12) 2 .
F21 C61 F19 106.1(8) . .
F21 C61 F20 106.4(9) . .
F19 C61 F20 105.6(9) . .
F21 C61 C62 110.9(9) . .
F19 C61 C62 114.2(9) . .
F20 C61 C62 113.1(16) . .
F20' C61' F19' 108.1(7) . .
F20' C61' F21' 107.3(7) . .
F19' C61' F21' 107.0(7) . .
F20' C61' C62 111.5(10) . .
F19' C61' C62 112.3(7) . .
F21' C61' C62 110.4(7) . .
N1 O1 Eu1 137.4(2) . .
N4 O3 Eu1 139.2(2) . .
C32 O5 Eu1 133.0(2) . .
C34 O6 Eu1 135.4(2) . .
C37 O7 Eu1 133.4(2) . .
C39 O8 Eu1 133.4(2) . .
C42 O9 Eu1 134.2(3) . .
C44 O10 Eu1 132.8(3) . .
N7 O11 Eu2 137.5(2) . .
C62 O13 Eu2 131.8(2) . .
C65 O14 Eu2 133.7(2) . .
C68 O15 Eu2 135.6(2) . .
O1 N1 C1 125.8(3) . .
O1 N1 C2 119.3(3) . .
C1 N1 C2 114.4(3) . .
O2 N2 C1 125.4(3) . .
O2 N2 C5 121.2(3) . .
C1 N2 C5 113.2(3) . .
C11 N3 C14 118.6(5) . .
C11 N3 C15 120.8(4) . .
C14 N3 C15 118.4(5) . .
O3 N4 C16 125.9(3) . .
O3 N4 C17 119.2(3) . .
C16 N4 C17 113.9(3) . .
O4 N5 C16 125.7(3) . .
O4 N5 C20 121.7(3) . .
C16 N5 C20 112.5(3) . .
C26 N6 C29 120.2(3) . .
C26 N6 C30 119.5(3) . .
C29 N6 C30 117.1(3) . .
O11 N7 C46 125.5(3) . .
O11 N7 C47 119.7(3) . .
C46 N7 C47 114.4(3) . .
O12 N8 C46 125.4(3) . .
O12 N8 C50 120.7(3) . .
C46 N8 C50 113.8(3) . .
C56 N9 C59 119.8(3) . .
C56 N9 C60 119.4(3) . .
C59 N9 C60 117.0(3) . .
N1 C1 N2 107.0(3) . .
N1 C1 C8 127.3(3) . .
N2 C1 C8 125.7(3) . .
N1 C2 C4 106.6(3) . .
N1 C2 C3 108.9(3) . .
C4 C2 C3 110.2(4) . .
N1 C2 C5 100.3(3) . .
C4 C2 C5 114.8(3) . .
C3 C2 C5 115.1(4) . .
C2 C3 H3A 109.5 . .
C2 C3 H3B 109.5 . .
H3A C3 H3B 109.5 . .
C2 C3 H3C 109.5 . .
H3A C3 H3C 109.5 . .
H3B C3 H3C 109.5 . .
C2 C4 H4A 109.5 . .
C2 C4 H4B 109.5 . .
H4A C4 H4B 109.5 . .
C2 C4 H4C 109.5 . .
H4A C4 H4C 109.5 . .
H4B C4 H4C 109.5 . .
N2 C5 C7 109.1(4) . .
N2 C5 C6 105.8(4) . .
C7 C5 C6 111.1(4) . .
N2 C5 C2 101.3(3) . .
C7 C5 C2 114.7(4) . .
C6 C5 C2 113.9(4) . .
C5 C6 H6A 109.5 . .
C5 C6 H6B 109.5 . .
H6A C6 H6B 109.5 . .
C5 C6 H6C 109.5 . .
H6A C6 H6C 109.5 . .
H6B C6 H6C 109.5 . .
C5 C7 H7A 109.5 . .
C5 C7 H7B 109.5 . .
H7A C7 H7B 109.5 . .
C5 C7 H7C 109.5 . .
H7A C7 H7C 109.5 . .
H7B C7 H7C 109.5 . .
C9 C8 C13 117.6(4) . .
C9 C8 C1 121.1(4) . .
C13 C8 C1 121.3(3) . .
C10 C9 C8 120.5(4) . .
C10 C9 H9 119.7 . .
C8 C9 H9 119.7 . .
C9 C10 C11 122.1(4) . .
C9 C10 H10 118.9 . .
C11 C10 H10 118.9 . .
N3 C11 C10 121.5(4) . .
N3 C11 C12 121.4(5) . .
C10 C11 C12 117.1(4) . .
C13 C12 C11 121.1(4) . .
C13 C12 H12 119.4 . .
C11 C12 H12 119.4 . .
C12 C13 C8 121.5(4) . .
C12 C13 H13 119.2 . .
C8 C13 H13 119.2 . .
N3 C14 H14A 109.5 . .
N3 C14 H14B 109.5 . .
H14A C14 H14B 109.5 . .
N3 C14 H14C 109.5 . .
H14A C14 H14C 109.5 . .
H14B C14 H14C 109.5 . .
N3 C15 H15A 109.5 . .
N3 C15 H15B 109.5 . .
H15A C15 H15B 109.5 . .
N3 C15 H15C 109.5 . .
H15A C15 H15C 109.5 . .
H15B C15 H15C 109.5 . .
N4 C16 N5 107.1(3) . .
N4 C16 C23 127.5(3) . .
N5 C16 C23 125.3(3) . .
N4 C17 C19 110.2(3) . .
N4 C17 C18 105.8(3) . .
C19 C17 C18 110.2(3) . .
N4 C17 C20 100.2(3) . .
C19 C17 C20 115.3(3) . .
C18 C17 C20 114.3(3) . .
C17 C18 H18A 109.5 . .
C17 C18 H18B 109.5 . .
H18A C18 H18B 109.5 . .
C17 C18 H18C 109.5 . .
H18A C18 H18C 109.5 . .
H18B C18 H18C 109.5 . .
C17 C19 H19A 109.5 . .
C17 C19 H19B 109.5 . .
H19A C19 H19B 109.5 . .
C17 C19 H19C 109.5 . .
H19A C19 H19C 109.5 . .
H19B C19 H19C 109.5 . .
N5 C20 C22 109.2(3) . .
N5 C20 C21 106.8(3) . .
C22 C20 C21 110.8(3) . .
N5 C20 C17 100.8(3) . .
C22 C20 C17 114.6(3) . .
C21 C20 C17 113.8(3) . .
C20 C21 H21A 109.5 . .
C20 C21 H21B 109.5 . .
H21A C21 H21B 109.5 . .
C20 C21 H21C 109.5 . .
H21A C21 H21C 109.5 . .
H21B C21 H21C 109.5 . .
C20 C22 H22A 109.5 . .
C20 C22 H22B 109.5 . .
H22A C22 H22B 109.5 . .
C20 C22 H22C 109.5 . .
H22A C22 H22C 109.5 . .
H22B C22 H22C 109.5 . .
C28 C23 C24 117.5(3) . .
C28 C23 C16 120.7(3) . .
C24 C23 C16 121.8(3) . .
C25 C24 C23 121.2(3) . .
C25 C24 H24 119.4 . .
C23 C24 H24 119.4 . .
C24 C25 C26 121.4(3) . .
C24 C25 H25 119.3 . .
C26 C25 H25 119.3 . .
N6 C26 C27 121.6(3) . .
N6 C26 C25 121.6(3) . .
C27 C26 C25 116.8(3) . .
C28 C27 C26 121.7(3) . .
C28 C27 H27 119.1 . .
C26 C27 H27 119.1 . .
C27 C28 C23 121.3(3) . .
C27 C28 H28 119.3 . .
C23 C28 H28 119.3 . .
N6 C29 H29A 109.5 . .
N6 C29 H29B 109.5 . .
H29A C29 H29B 109.5 . .
N6 C29 H29C 109.5 . .
H29A C29 H29C 109.5 . .
H29B C29 H29C 109.5 . .
N6 C30 H30A 109.5 . .
N6 C30 H30B 109.5 . .
H30A C30 H30B 109.5 . .
N6 C30 H30C 109.5 . .
H30A C30 H30C 109.5 . .
H30B C30 H30C 109.5 . .
F2 C31 F3 106.9(4) . .
F2 C31 F1 105.7(4) . .
F3 C31 F1 105.9(4) . .
F2 C31 C32 111.2(4) . .
F3 C31 C32 114.9(4) . .
F1 C31 C32 111.7(3) . .
O5 C32 C33 128.6(3) . .
O5 C32 C31 113.9(3) . .
C33 C32 C31 117.5(3) . .
C32 C33 C34 121.3(3) . .
C32 C33 H33 119.4 . .
C34 C33 H33 119.4 . .
O6 C34 C33 128.3(3) . .
O6 C34 C35 114.4(3) . .
C33 C34 C35 117.2(3) . .
F5 C35 F6 107.8(3) . .
F5 C35 F4 106.7(3) . .
F6 C35 F4 106.8(3) . .
F5 C35 C34 113.5(3) . .
F6 C35 C34 112.0(3) . .
F4 C35 C34 109.6(3) . .
F8 C36 F9 107.1(4) . .
F8 C36 F7 107.6(4) . .
F9 C36 F7 105.6(4) . .
F8 C36 C37 111.4(3) . .
F9 C36 C37 114.9(4) . .
F7 C36 C37 109.8(3) . .
O7 C37 C38 128.7(3) . .
O7 C37 C36 113.6(3) . .
C38 C37 C36 117.7(3) . .
C39 C38 C37 121.7(3) . .
C39 C38 H38 119.2 . .
C37 C38 H38 119.2 . .
O8 C39 C38 128.6(3) . .
O8 C39 C40 113.2(3) . .
C38 C39 C40 118.2(3) . .
F12 C40 F11 108.6(4) . .
F12 C40 F10 105.9(3) . .
F11 C40 F10 106.5(4) . .
F12 C40 C39 111.1(3) . .
F11 C40 C39 110.9(3) . .
F10 C40 C39 113.6(4) . .
F14 C41 F13 106.4(4) . .
F14 C41 F15 106.9(4) . .
F13 C41 F15 107.7(4) . .
F14 C41 C42 112.4(4) . .
F13 C41 C42 110.1(4) . .
F15 C41 C42 112.9(4) . .
O9 C42 C43 128.0(4) . .
O9 C42 C41 114.2(4) . .
C43 C42 C41 117.8(4) . .
C44 C43 C42 121.9(4) . .
C44 C43 H43 119.0 . .
C42 C43 H43 119.0 . .
O10 C44 C43 128.4(4) . .
O10 C44 C45 114.0(4) . .
C43 C44 C45 117.6(4) . .
F18' C45 F17 127.0(9) . .
F18' C45 F16 57.4(10) . .
F17 C45 F16 113.1(7) . .
F18' C45 F17' 114.7(13) . .
F17 C45 F17' 31.6(7) . .
F16 C45 F17' 135.8(8) . .
F18' C45 F18 42.7(11) . .
F17 C45 F18 106.3(6) . .
F16 C45 F18 99.4(5) . .
F17' C45 F18 79.9(8) . .
F18' C45 F16' 108.7(11) . .
F17 C45 F16' 63.0(7) . .
F16 C45 F16' 57.0(6) . .
F17' C45 F16' 94.3(9) . .
F18 C45 F16' 138.2(6) . .
F18' C45 C44 117.1(8) . .
F17 C45 C44 114.3(6) . .
F16 C45 C44 111.7(5) . .
F17' C45 C44 109.6(7) . .
F18 C45 C44 110.9(4) . .
F16' C45 C44 110.1(6) . .
N7 C46 N8 107.5(3) . .
N7 C46 C53 128.1(3) . .
N8 C46 C53 124.4(3) . .
N7 C47 C48 108.9(3) . .
N7 C47 C49 106.6(3) . .
C48 C47 C49 110.2(4) . .
N7 C47 C50 101.8(3) . .
C48 C47 C50 114.1(3) . .
C49 C47 C50 114.5(3) . .
C47 C48 H48A 109.5 . .
C47 C48 H48B 109.5 . .
H48A C48 H48B 109.5 . .
C47 C48 H48C 109.5 . .
H48A C48 H48C 109.5 . .
H48B C48 H48C 109.5 . .
C47 C49 H49A 109.5 . .
C47 C49 H49B 109.5 . .
H49A C49 H49B 109.5 . .
C47 C49 H49C 109.5 . .
H49A C49 H49C 109.5 . .
H49B C49 H49C 109.5 . .
N8 C50 C51 108.7(3) . .
N8 C50 C52 106.7(3) . .
C51 C50 C52 109.6(3) . .
N8 C50 C47 100.8(3) . .
C51 C50 C47 115.1(3) . .
C52 C50 C47 115.2(3) . .
C50 C51 H51A 109.5 . .
C50 C51 H51B 109.5 . .
H51A C51 H51B 109.5 . .
C50 C51 H51C 109.5 . .
H51A C51 H51C 109.5 . .
H51B C51 H51C 109.5 . .
C50 C52 H52A 109.5 . .
C50 C52 H52B 109.5 . .
H52A C52 H52B 109.5 . .
C50 C52 H52C 109.5 . .
H52A C52 H52C 109.5 . .
H52B C52 H52C 109.5 . .
C58 C53 C54 117.8(3) . .
C58 C53 C46 121.5(3) . .
C54 C53 C46 120.7(3) . .
C55 C54 C53 121.1(3) . .
C55 C54 H54 119.5 . .
C53 C54 H54 119.5 . .
C54 C55 C56 121.2(3) . .
C54 C55 H55 119.4 . .
C56 C55 H55 119.4 . .
N9 C56 C57 121.7(3) . .
N9 C56 C55 121.1(3) . .
C57 C56 C55 117.2(3) . .
C58 C57 C56 121.7(3) . .
C58 C57 H57 119.2 . .
C56 C57 H57 119.2 . .
C57 C58 C53 121.1(3) . .
C57 C58 H58 119.5 . .
C53 C58 H58 119.5 . .
N9 C59 H59A 109.5 . .
N9 C59 H59B 109.5 . .
H59A C59 H59B 109.5 . .
N9 C59 H59C 109.5 . .
H59A C59 H59C 109.5 . .
H59B C59 H59C 109.5 . .
N9 C60 H60A 109.5 . .
N9 C60 H60B 109.5 . .
H60A C60 H60B 109.5 . .
N9 C60 H60C 109.5 . .
H60A C60 H60C 109.5 . .
H60B C60 H60C 109.5 . .
O13 C62 C66 128.7(4) . 2
O13 C62 C61' 112.8(4) . .
C66 C62 C61' 117.7(4) 2 .
O13 C62 C61 115.5(5) . .
C66 C62 C61 114.9(5) 2 .
C61' C62 C61 20.6(4) . .
F24 C64 F22 108.2(4) . .
F24 C64 F23 106.6(4) . .
F22 C64 F23 105.1(4) . .
F24 C64 C65 113.8(3) . .
F22 C64 C65 111.1(3) . .
F23 C64 C65 111.4(3) . .
O14 C65 C66 128.4(4) . .
O14 C65 C64 114.4(3) . .
C66 C65 C64 117.2(3) . .
C62 C66 C65 121.4(4) 2 .
C62 C66 H66 119.3 2 .
C65 C66 H66 119.3 . .
F25 C67 F26 105.0(5) . .
F25 C67 F27 106.4(4) . .
F26 C67 F27 105.8(4) . .
F25 C67 C68 111.9(4) . .
F26 C67 C68 111.6(4) . .
F27 C67 C68 115.4(4) . .
O15 C68 C69 128.1(4) . .
O15 C68 C67 113.8(3) . .
C69 C68 C67 118.1(3) . .
C68 C69 C68 121.7(5) . 2
C68 C69 H69 119.2 . .
C68 C69 H69 119.2 2 .
C71 C70 H70A 109.5 . .
C71 C70 H70B 109.5 . .
H70A C70 H70B 109.5 . .
C71 C70 H70C 109.5 . .
H70A C70 H70C 109.5 . .
H70B C70 H70C 109.5 . .
C72 C71 C70 118.0(8) . .
C72 C71 H71A 107.8 . .
C70 C71 H71A 107.8 . .
C72 C71 H71B 107.8 . .
C70 C71 H71B 107.8 . .
H71A C71 H71B 107.1 . .
C71 C72 C73 122.2(10) . .
C71 C72 C73' 120.1(10) . .
C73 C72 C73' 2.9(13) . .
C71 C72 H72A 108.5 . .
C73 C72 H72A 107.7 . .
C73' C72 H72A 110.5 . .
C71 C72 H72B 105.6 . .
C73 C72 H72B 105.2 . .
C73' C72 H72B 104.5 . .
H72A C72 H72B 106.7 . .
C71 C72 H72C 108.8 . .
C73 C72 H72C 105.3 . .
C73' C72 H72C 108.1 . .
H72A C72 H72C 3.0 . .
H72B C72 H72C 109.3 . .
C71 C72 H72D 106.0 . .
C73 C72 H72D 106.9 . .
C73' C72 H72D 106.3 . .
H72A C72 H72D 104.2 . .
H72B C72 H72D 2.6 . .
H72C C72 H72D 106.8 . .
C72 C73 C74 114.8(11) . .
C72 C73 H73A 108.6 . .
C74 C73 H73A 108.6 . .
C72 C73 H73B 108.6 . .
C74 C73 H73B 108.6 . .
H73A C73 H73B 107.5 . .
C75 C74 C73 111.3(9) . .
C75 C74 H74A 109.4 . .
C73 C74 H74A 109.4 . .
C75 C74 H74B 109.4 . .
C73 C74 H74B 109.4 . .
H74A C74 H74B 108.0 . .
C74 C75 C76 109.1(9) . .
C74 C75 H75A 109.9 . .
C76 C75 H75A 109.9 . .
C74 C75 H75B 109.9 . .
C76 C75 H75B 109.9 . .
H75A C75 H75B 108.3 . .
C72 C73' C74' 108.1(8) . .
C72 C73' H73C 110.1 . .
C74' C73' H73C 110.1 . .
C72 C73' H73D 110.1 . .
C74' C73' H73D 110.1 . .
H73C C73' H73D 108.4 . .
C75' C74' C73' 110.8(9) . .
C75' C74' H74C 109.5 . .
C73' C74' H74C 109.5 . .
C75' C74' H74D 109.5 . .
C73' C74' H74D 109.5 . .
H74C C74' H74D 108.1 . .
C74' C75' C76' 110.9(9) . .
C74' C75' H75C 109.5 . .
C76' C75' H75C 109.5 . .
C74' C75' H75D 109.5 . .
C76' C75' H75D 109.5 . .
H75C C75' H75D 108.0 . .
C75' C76' H76D 109.5 . .
C75' C76' H76E 109.5 . .
H76D C76' H76E 109.5 . .
C75' C76' H76F 109.5 . .
H76D C76' H76F 109.5 . .
H76E C76' H76F 109.5 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 O1 2.344(2) .
Eu1 O3 2.356(2) .
Eu1 O6 2.367(2) .
Eu1 O9 2.369(2) .
Eu1 O10 2.409(3) .
Eu1 O8 2.413(2) .
Eu1 O7 2.417(2) .
Eu1 O5 2.437(2) .
Eu2 O11 2.378(2) 2
Eu2 O11 2.378(2) .
Eu2 O14 2.382(2) 2
Eu2 O14 2.382(2) .
Eu2 O15 2.415(2) 2
Eu2 O15 2.415(2) .
Eu2 O13 2.416(2) 2
Eu2 O13 2.416(2) .
F1 C31 1.315(5) .
F2 C31 1.287(5) .
F3 C31 1.307(5) .
F4 C35 1.337(4) .
F5 C35 1.328(4) .
F6 C35 1.329(5) .
F7 C36 1.325(5) .
F8 C36 1.310(5) .
F9 C36 1.319(5) .
F10 C40 1.328(5) .
F11 C40 1.311(5) .
F12 C40 1.307(5) .
F13 C41 1.327(6) .
F14 C41 1.316(5) .
F15 C41 1.328(5) .
F16 C45 1.342(7) .
F17 C45 1.236(9) .
F18 C45 1.395(8) .
F16' C45 1.442(11) .
F17' C45 1.394(15) .
F18' C45 1.114(12) .
C61 F21 1.331(9) .
C61 F19 1.341(9) .
C61 F20 1.345(9) .
C61 C62 1.590(13) .
C61' F20' 1.326(8) .
C61' F19' 1.331(8) .
C61' F21' 1.333(8) .
C61' C62 1.516(11) .
F22 C64 1.320(5) .
F23 C64 1.327(5) .
F24 C64 1.317(5) .
F25 C67 1.285(6) .
F26 C67 1.292(6) .
F27 C67 1.294(5) .
O1 N1 1.316(4) .
O2 N2 1.283(4) .
O3 N4 1.311(4) .
O4 N5 1.276(4) .
O5 C32 1.253(4) .
O6 C34 1.253(4) .
O7 C37 1.250(4) .
O8 C39 1.255(4) .
O9 C42 1.247(5) .
O10 C44 1.244(5) .
O11 N7 1.317(4) .
O12 N8 1.274(4) .
O13 C62 1.252(4) .
O14 C65 1.254(4) .
O15 C68 1.254(4) .
N1 C1 1.331(5) .
N1 C2 1.505(5) .
N2 C1 1.367(5) .
N2 C5 1.493(6) .
N3 C11 1.384(6) .
N3 C14 1.446(7) .
N3 C15 1.449(7) .
N4 C16 1.330(4) .
N4 C17 1.500(4) .
N5 C16 1.372(4) .
N5 C20 1.498(5) .
N6 C26 1.372(5) .
N6 C29 1.453(5) .
N6 C30 1.455(5) .
N7 C46 1.331(5) .
N7 C47 1.500(5) .
N8 C46 1.371(4) .
N8 C50 1.501(5) .
N9 C56 1.382(5) .
N9 C59 1.447(5) .
N9 C60 1.459(5) .
C1 C8 1.454(5) .
C2 C4 1.521(6) .
C2 C3 1.521(5) .
C2 C5 1.556(6) .
C3 H3A 0.9800 .
C3 H3B 0.9800 .
C3 H3C 0.9800 .
C4 H4A 0.9800 .
C4 H4B 0.9800 .
C4 H4C 0.9800 .
C5 C7 1.521(6) .
C5 C6 1.530(6) .
C6 H6A 0.9800 .
C6 H6B 0.9800 .
C6 H6C 0.9800 .
C7 H7A 0.9800 .
C7 H7B 0.9800 .
C7 H7C 0.9800 .
C8 C9 1.401(5) .
C8 C13 1.402(5) .
C9 C10 1.384(6) .
C9 H9 0.9500 .
C10 C11 1.396(7) .
C10 H10 0.9500 .
C11 C12 1.405(6) .
C12 C13 1.379(6) .
C12 H12 0.9500 .
C13 H13 0.9500 .
C14 H14A 0.9800 .
C14 H14B 0.9800 .
C14 H14C 0.9800 .
C15 H15A 0.9800 .
C15 H15B 0.9800 .
C15 H15C 0.9800 .
C16 C23 1.456(5) .
C17 C19 1.509(5) .
C17 C18 1.533(5) .
C17 C20 1.555(5) .
C18 H18A 0.9800 .
C18 H18B 0.9800 .
C18 H18C 0.9800 .
C19 H19A 0.9800 .
C19 H19B 0.9800 .
C19 H19C 0.9800 .
C20 C22 1.524(5) .
C20 C21 1.529(5) .
C21 H21A 0.9800 .
C21 H21B 0.9800 .
C21 H21C 0.9800 .
C22 H22A 0.9800 .
C22 H22B 0.9800 .
C22 H22C 0.9800 .
C23 C28 1.402(5) .
C23 C24 1.403(5) .
C24 C25 1.381(5) .
C24 H24 0.9500 .
C25 C26 1.412(5) .
C25 H25 0.9500 .
C26 C27 1.406(5) .
C27 C28 1.376(5) .
C27 H27 0.9500 .
C28 H28 0.9500 .
C29 H29A 0.9800 .
C29 H29B 0.9800 .
C29 H29C 0.9800 .
C30 H30A 0.9800 .
C30 H30B 0.9800 .
C30 H30C 0.9800 .
C31 C32 1.534(5) .
C32 C33 1.388(5) .
C33 C34 1.398(5) .
C33 H33 0.9500 .
C34 C35 1.535(5) .
C36 C37 1.540(5) .
C37 C38 1.394(5) .
C38 C39 1.392(5) .
C38 H38 0.9500 .
C39 C40 1.541(5) .
C41 C42 1.536(6) .
C42 C43 1.398(6) .
C43 C44 1.394(6) .
C43 H43 0.9500 .
C44 C45 1.534(6) .
C46 C53 1.447(5) .
C47 C48 1.517(5) .
C47 C49 1.525(5) .
C47 C50 1.570(5) .
C48 H48A 0.9800 .
C48 H48B 0.9800 .
C48 H48C 0.9800 .
C49 H49A 0.9800 .
C49 H49B 0.9800 .
C49 H49C 0.9800 .
C50 C51 1.524(5) .
C50 C52 1.531(5) .
C51 H51A 0.9800 .
C51 H51B 0.9800 .
C51 H51C 0.9800 .
C52 H52A 0.9800 .
C52 H52B 0.9800 .
C52 H52C 0.9800 .
C53 C58 1.398(5) .
C53 C54 1.406(5) .
C54 C55 1.377(5) .
C54 H54 0.9500 .
C55 C56 1.408(5) .
C55 H55 0.9500 .
C56 C57 1.406(5) .
C57 C58 1.372(5) .
C57 H57 0.9500 .
C58 H58 0.9500 .
C59 H59A 0.9800 .
C59 H59B 0.9800 .
C59 H59C 0.9800 .
C60 H60A 0.9800 .
C60 H60B 0.9800 .
C60 H60C 0.9800 .
C62 C66 1.385(5) 2
C64 C65 1.539(6) .
C65 C66 1.390(5) .
C66 C62 1.385(5) 2
C66 H66 0.9500 .
C67 C68 1.528(5) .
C68 C69 1.382(5) .
C69 C68 1.382(5) 2
C69 H69 0.9500 .
C70 C71 1.525(9) .
C70 H70A 0.9800 .
C70 H70B 0.9800 .
C70 H70C 0.9800 .
C71 C72 1.404(10) .
C71 H71A 0.9900 .
C71 H71B 0.9900 .
C72 C73 1.497(10) .
C72 C73' 1.504(9) .
C72 H72A 0.9627 .
C72 H72B 0.9628 .
C72 H72C 0.9627 .
C72 H72D 0.9630 .
C73 C74 1.529(10) .
C73 H73A 0.9900 .
C73 H73B 0.9900 .
C74 C75 1.521(10) .
C74 H74A 0.9900 .
C74 H74B 0.9900 .
C75 C76 1.541(10) .
C75 H75A 0.9900 .
C75 H75B 0.9900 .
C76 H76A 0.9800 .
C76 H76B 0.9800 .
C76 H76C 0.9800 .
C73' C74' 1.533(10) .
C73' H73C 0.9900 .
C73' H73D 0.9900 .
C74' C75' 1.513(10) .
C74' H74C 0.9900 .
C74' H74D 0.9900 .
C75' C76' 1.540(10) .
C75' H75C 0.9900 .
C75' H75D 0.9900 .
C76' H76D 0.9800 .
C76' H76E 0.9800 .
C76' H76F 0.9800 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O3 Eu1 O1 N1 -173.9(3) . .
O6 Eu1 O1 N1 -64.3(3) . .
O9 Eu1 O1 N1 76.4(3) . .
O10 Eu1 O1 N1 9.9(3) . .
O8 Eu1 O1 N1 145.5(3) . .
O7 Eu1 O1 N1 -139.4(3) . .
O5 Eu1 O1 N1 -6.1(4) . .
O1 Eu1 O3 N4 -174.2(3) . .
O6 Eu1 O3 N4 79.8(3) . .
O9 Eu1 O3 N4 -59.3(3) . .
O10 Eu1 O3 N4 -0.7(4) . .
O8 Eu1 O3 N4 -133.1(3) . .
O7 Eu1 O3 N4 150.6(3) . .
O5 Eu1 O3 N4 12.8(3) . .
O1 Eu1 O5 C32 -51.6(4) . .
O3 Eu1 O5 C32 120.1(3) . .
O6 Eu1 O5 C32 11.6(3) . .
O9 Eu1 O5 C32 -144.0(3) . .
O10 Eu1 O5 C32 -67.6(3) . .
O8 Eu1 O5 C32 167.1(3) . .
O7 Eu1 O5 C32 68.7(3) . .
O1 Eu1 O6 C34 139.1(3) . .
O3 Eu1 O6 C34 -79.4(3) . .
O9 Eu1 O6 C34 24.2(4) . .
O10 Eu1 O6 C34 66.3(3) . .
O8 Eu1 O6 C34 -156.8(3) . .
O7 Eu1 O6 C34 -146.7(3) . .
O5 Eu1 O6 C34 -11.6(3) . .
O1 Eu1 O7 C37 -92.4(3) . .
O3 Eu1 O7 C37 64.8(3) . .
O6 Eu1 O7 C37 172.2(3) . .
O9 Eu1 O7 C37 3.1(4) . .
O10 Eu1 O7 C37 -137.9(3) . .
O8 Eu1 O7 C37 -13.4(3) . .
O5 Eu1 O7 C37 116.8(3) . .
O1 Eu1 O8 C39 92.9(3) . .
O3 Eu1 O8 C39 -61.0(3) . .
O6 Eu1 O8 C39 24.5(4) . .
O9 Eu1 O8 C39 -156.2(3) . .
O10 Eu1 O8 C39 149.4(3) . .
O7 Eu1 O8 C39 14.2(3) . .
O5 Eu1 O8 C39 -107.8(3) . .
O1 Eu1 O9 C42 -80.3(3) . .
O3 Eu1 O9 C42 137.2(3) . .
O6 Eu1 O9 C42 29.6(4) . .
O10 Eu1 O9 C42 -13.2(3) . .
O8 Eu1 O9 C42 -149.9(4) . .
O7 Eu1 O9 C42 -166.2(3) . .
O5 Eu1 O9 C42 65.1(3) . .
O1 Eu1 O10 C44 125.4(3) . .
O3 Eu1 O10 C44 -50.2(4) . .
O6 Eu1 O10 C44 -138.7(3) . .
O9 Eu1 O10 C44 13.1(3) . .
O8 Eu1 O10 C44 68.3(3) . .
O7 Eu1 O10 C44 171.2(3) . .
O5 Eu1 O10 C44 -63.6(3) . .
O11 Eu2 O11 N7 179.4(3) 2 .
O14 Eu2 O11 N7 -72.9(3) 2 .
O14 Eu2 O11 N7 69.8(3) . .
O15 Eu2 O11 N7 -143.8(3) 2 .
O15 Eu2 O11 N7 142.8(3) . .
O13 Eu2 O11 N7 6.5(4) 2 .
O13 Eu2 O11 N7 -5.2(3) . .
O11 Eu2 O13 C62 48.9(4) 2 .
O11 Eu2 O13 C62 -127.0(3) . .
O14 Eu2 O13 C62 -20.7(3) 2 .
O14 Eu2 O13 C62 136.3(3) . .
O15 Eu2 O13 C62 -72.3(3) 2 .
O15 Eu2 O13 C62 -174.2(3) . .
O13 Eu2 O13 C62 60.7(3) 2 .
O11 Eu2 O14 C65 84.5(3) 2 .
O11 Eu2 O14 C65 -127.2(3) . .
O14 Eu2 O14 C65 -20.2(3) 2 .
O15 Eu2 O14 C65 164.2(3) 2 .
O15 Eu2 O14 C65 157.3(3) . .
O13 Eu2 O14 C65 17.1(3) 2 .
O13 Eu2 O14 C65 -56.5(3) . .
O11 Eu2 O15 C68 -80.2(3) 2 .
O11 Eu2 O15 C68 80.0(3) . .
O14 Eu2 O15 C68 -6.8(4) 2 .
O14 Eu2 O15 C68 176.0(3) . .
O15 Eu2 O15 C68 0.2(3) 2 .
O13 Eu2 O15 C68 -133.2(3) 2 .
O13 Eu2 O15 C68 125.8(3) . .
Eu1 O1 N1 C1 -79.5(4) . .
Eu1 O1 N1 C2 109.4(3) . .
Eu1 O3 N4 C16 -82.0(4) . .
Eu1 O3 N4 C17 110.3(3) . .
Eu2 O11 N7 C46 82.9(4) . .
Eu2 O11 N7 C47 -104.8(3) . .
O1 N1 C1 N2 -178.5(3) . .
C2 N1 C1 N2 -6.9(4) . .
O1 N1 C1 C8 0.7(6) . .
C2 N1 C1 C8 172.2(3) . .
O2 N2 C1 N1 178.4(3) . .
C5 N2 C1 N1 -6.9(4) . .
O2 N2 C1 C8 -0.8(6) . .
C5 N2 C1 C8 174.0(3) . .
O1 N1 C2 C4 68.8(4) . .
C1 N1 C2 C4 -103.3(4) . .
O1 N1 C2 C3 -50.0(4) . .
C1 N1 C2 C3 137.8(4) . .
O1 N1 C2 C5 -171.3(3) . .
C1 N1 C2 C5 16.6(4) . .
O2 N2 C5 C7 -47.1(5) . .
C1 N2 C5 C7 138.0(4) . .
O2 N2 C5 C6 72.6(4) . .
C1 N2 C5 C6 -102.4(4) . .
O2 N2 C5 C2 -168.4(3) . .
C1 N2 C5 C2 16.6(4) . .
N1 C2 C5 N2 -18.0(3) . .
C4 C2 C5 N2 95.9(4) . .
C3 C2 C5 N2 -134.7(4) . .
N1 C2 C5 C7 -135.3(4) . .
C4 C2 C5 C7 -21.4(5) . .
C3 C2 C5 C7 108.0(5) . .
N1 C2 C5 C6 95.1(4) . .
C4 C2 C5 C6 -151.0(4) . .
C3 C2 C5 C6 -21.6(5) . .
N1 C1 C8 C9 154.5(4) . .
N2 C1 C8 C9 -26.5(5) . .
N1 C1 C8 C13 -26.1(6) . .
N2 C1 C8 C13 152.9(4) . .
C13 C8 C9 C10 -1.8(6) . .
C1 C8 C9 C10 177.6(4) . .
C8 C9 C10 C11 0.8(6) . .
C14 N3 C11 C10 8.8(7) . .
C15 N3 C11 C10 171.6(4) . .
C14 N3 C11 C12 -171.5(4) . .
C15 N3 C11 C12 -8.7(7) . .
C9 C10 C11 N3 -179.1(4) . .
C9 C10 C11 C12 1.2(6) . .
N3 C11 C12 C13 178.1(4) . .
C10 C11 C12 C13 -2.1(6) . .
C11 C12 C13 C8 1.2(6) . .
C9 C8 C13 C12 0.8(5) . .
C1 C8 C13 C12 -178.6(3) . .
O3 N4 C16 N5 -177.7(3) . .
C17 N4 C16 N5 -9.5(4) . .
O3 N4 C16 C23 -0.5(6) . .
C17 N4 C16 C23 167.8(3) . .
O4 N5 C16 N4 177.0(3) . .
C20 N5 C16 N4 -6.9(4) . .
O4 N5 C16 C23 -0.3(6) . .
C20 N5 C16 C23 175.7(3) . .
O3 N4 C17 C19 -48.4(4) . .
C16 N4 C17 C19 142.5(3) . .
O3 N4 C17 C18 70.6(4) . .
C16 N4 C17 C18 -98.5(4) . .
O3 N4 C17 C20 -170.3(3) . .
C16 N4 C17 C20 20.6(4) . .
O4 N5 C20 C22 -43.8(4) . .
C16 N5 C20 C22 140.0(3) . .
O4 N5 C20 C21 76.1(4) . .
C16 N5 C20 C21 -100.2(4) . .
O4 N5 C20 C17 -164.8(3) . .
C16 N5 C20 C17 19.0(4) . .
N4 C17 C20 N5 -21.5(3) . .
C19 C17 C20 N5 -139.7(3) . .
C18 C17 C20 N5 91.1(3) . .
N4 C17 C20 C22 -138.6(3) . .
C19 C17 C20 C22 103.1(4) . .
C18 C17 C20 C22 -26.0(4) . .
N4 C17 C20 C21 92.5(3) . .
C19 C17 C20 C21 -25.8(5) . .
C18 C17 C20 C21 -155.0(3) . .
N4 C16 C23 C28 -26.3(5) . .
N5 C16 C23 C28 150.5(3) . .
N4 C16 C23 C24 154.6(4) . .
N5 C16 C23 C24 -28.7(5) . .
C28 C23 C24 C25 -1.6(5) . .
C16 C23 C24 C25 177.6(3) . .
C23 C24 C25 C26 -0.6(6) . .
C29 N6 C26 C27 -164.7(4) . .
C30 N6 C26 C27 -5.2(6) . .
C29 N6 C26 C25 15.0(6) . .
C30 N6 C26 C25 174.5(4) . .
C24 C25 C26 N6 -177.2(3) . .
C24 C25 C26 C27 2.5(5) . .
N6 C26 C27 C28 177.5(3) . .
C25 C26 C27 C28 -2.2(5) . .
C26 C27 C28 C23 0.0(6) . .
C24 C23 C28 C27 1.9(5) . .
C16 C23 C28 C27 -177.3(3) . .
Eu1 O5 C32 C33 -10.1(6) . .
Eu1 O5 C32 C31 170.7(2) . .
F2 C31 C32 O5 -57.5(5) . .
F3 C31 C32 O5 -179.1(4) . .
F1 C31 C32 O5 60.3(5) . .
F2 C31 C32 C33 123.2(5) . .
F3 C31 C32 C33 1.6(6) . .
F1 C31 C32 C33 -119.0(4) . .
O5 C32 C33 C34 1.2(6) . .
C31 C32 C33 C34 -179.6(4) . .
Eu1 O6 C34 C33 9.8(6) . .
Eu1 O6 C34 C35 -167.3(2) . .
C32 C33 C34 O6 -0.7(6) . .
C32 C33 C34 C35 176.3(3) . .
O6 C34 C35 F5 -155.7(3) . .
C33 C34 C35 F5 26.9(5) . .
O6 C34 C35 F6 -33.3(4) . .
C33 C34 C35 F6 149.2(3) . .
O6 C34 C35 F4 85.1(4) . .
C33 C34 C35 F4 -92.4(4) . .
Eu1 O7 C37 C38 9.4(6) . .
Eu1 O7 C37 C36 -170.8(2) . .
F8 C36 C37 O7 57.7(5) . .
F9 C36 C37 O7 179.8(3) . .
F7 C36 C37 O7 -61.3(5) . .
F8 C36 C37 C38 -122.4(4) . .
F9 C36 C37 C38 -0.4(5) . .
F7 C36 C37 C38 118.5(4) . .
O7 C37 C38 C39 2.6(6) . .
C36 C37 C38 C39 -177.3(3) . .
Eu1 O8 C39 C38 -11.1(6) . .
Eu1 O8 C39 C40 168.3(2) . .
C37 C38 C39 O8 -1.7(6) . .
C37 C38 C39 C40 178.9(3) . .
O8 C39 C40 F12 51.1(5) . .
C38 C39 C40 F12 -129.4(4) . .
O8 C39 C40 F11 -69.8(4) . .
C38 C39 C40 F11 109.7(4) . .
O8 C39 C40 F10 170.4(3) . .
C38 C39 C40 F10 -10.1(5) . .
Eu1 O9 C42 C43 10.5(6) . .
Eu1 O9 C42 C41 -167.1(3) . .
F14 C41 C42 O9 -36.1(5) . .
F13 C41 C42 O9 82.4(5) . .
F15 C41 C42 O9 -157.2(4) . .
F14 C41 C42 C43 145.9(4) . .
F13 C41 C42 C43 -95.6(5) . .
F15 C41 C42 C43 24.9(6) . .
O9 C42 C43 C44 0.5(7) . .
C41 C42 C43 C44 178.1(4) . .
Eu1 O10 C44 C43 -10.5(6) . .
Eu1 O10 C44 C45 170.1(3) . .
C42 C43 C44 O10 -0.3(7) . .
C42 C43 C44 C45 179.1(4) . .
O10 C44 C45 F18' -74.8(14) . .
C43 C44 C45 F18' 105.7(14) . .
O10 C44 C45 F17 91.8(8) . .
C43 C44 C45 F17 -87.7(8) . .
O10 C44 C45 F16 -138.2(6) . .
C43 C44 C45 F16 42.3(8) . .
O10 C44 C45 F17' 58.0(9) . .
C43 C44 C45 F17' -121.5(9) . .
O10 C44 C45 F18 -28.3(6) . .
C43 C44 C45 F18 152.2(5) . .
O10 C44 C45 F16' 160.4(8) . .
C43 C44 C45 F16' -19.1(9) . .
O11 N7 C46 N8 177.8(3) . .
C47 N7 C46 N8 5.0(4) . .
O11 N7 C46 C53 -0.1(6) . .
C47 N7 C46 C53 -172.8(3) . .
O12 N8 C46 N7 -178.3(3) . .
C50 N8 C46 N7 4.6(4) . .
O12 N8 C46 C53 -0.3(6) . .
C50 N8 C46 C53 -177.5(3) . .
O11 N7 C47 C48 54.4(4) . .
C46 N7 C47 C48 -132.4(3) . .
O11 N7 C47 C49 -64.6(4) . .
C46 N7 C47 C49 108.6(3) . .
O11 N7 C47 C50 175.1(3) . .
C46 N7 C47 C50 -11.7(4) . .
O12 N8 C50 C51 50.1(4) . .
C46 N8 C50 C51 -132.6(3) . .
O12 N8 C50 C52 -68.0(4) . .
C46 N8 C50 C52 109.3(4) . .
O12 N8 C50 C47 171.5(3) . .
C46 N8 C50 C47 -11.2(4) . .
N7 C47 C50 N8 12.4(3) . .
C48 C47 C50 N8 129.5(3) . .
C49 C47 C50 N8 -102.1(4) . .
N7 C47 C50 C51 129.1(3) . .
C48 C47 C50 C51 -113.8(4) . .
C49 C47 C50 C51 14.6(5) . .
N7 C47 C50 C52 -101.9(3) . .
C48 C47 C50 C52 15.2(5) . .
C49 C47 C50 C52 143.6(4) . .
N7 C46 C53 C58 32.4(5) . .
N8 C46 C53 C58 -145.1(4) . .
N7 C46 C53 C54 -148.6(4) . .
N8 C46 C53 C54 33.9(5) . .
C58 C53 C54 C55 0.7(5) . .
C46 C53 C54 C55 -178.3(3) . .
C53 C54 C55 C56 0.8(6) . .
C59 N9 C56 C57 -7.9(5) . .
C60 N9 C56 C57 -165.0(3) . .
C59 N9 C56 C55 173.2(3) . .
C60 N9 C56 C55 16.0(5) . .
C54 C55 C56 N9 177.2(3) . .
C54 C55 C56 C57 -1.8(5) . .
N9 C56 C57 C58 -177.7(3) . .
C55 C56 C57 C58 1.3(5) . .
C56 C57 C58 C53 0.3(5) . .
C54 C53 C58 C57 -1.3(5) . .
C46 C53 C58 C57 177.8(3) . .
Eu2 O13 C62 C66 19.2(6) . 2
Eu2 O13 C62 C61' -171.5(4) . .
Eu2 O13 C62 C61 -149.1(4) . .
F20' C61' C62 O13 160.4(6) . .
F19' C61' C62 O13 -78.1(7) . .
F21' C61' C62 O13 41.2(8) . .
F20' C61' C62 C66 -28.9(8) . 2
F19' C61' C62 C66 92.6(7) . 2
F21' C61' C62 C66 -148.2(6) . 2
F20' C61' C62 C61 58.4(17) . .
F19' C61' C62 C61 180(100) . .
F21' C61' C62 C61 -60.8(17) . .
F21 C61 C62 O13 -42.9(10) . .
F19 C61 C62 O13 77.0(9) . .
F20 C61 C62 O13 -162.3(7) . .
F21 C61 C62 C66 147.2(8) . 2
F19 C61 C62 C66 -92.9(9) . 2
F20 C61 C62 C66 27.8(9) . 2
F21 C61 C62 C61' 44.4(16) . .
F19 C61 C62 C61' 164(2) . .
F20 C61 C62 C61' -75.1(19) . .
Eu2 O14 C65 C66 -11.0(6) . .
Eu2 O14 C65 C64 167.2(2) . .
F24 C64 C65 O14 160.9(4) . .
F22 C64 C65 O14 -76.6(4) . .
F23 C64 C65 O14 40.3(5) . .
F24 C64 C65 C66 -20.7(5) . .
F22 C64 C65 C66 101.8(4) . .
F23 C64 C65 C66 -141.3(4) . .
O14 C65 C66 C62 -2.9(6) . 2
C64 C65 C66 C62 179.0(3) . 2
Eu2 O15 C68 C69 -0.4(6) . .
Eu2 O15 C68 C67 179.5(2) . .
F25 C67 C68 O15 56.5(6) . .
F26 C67 C68 O15 -60.8(5) . .
F27 C67 C68 O15 178.3(4) . .
F25 C67 C68 C69 -123.6(5) . .
F26 C67 C68 C69 119.1(4) . .
F27 C67 C68 C69 -1.7(6) . .
O15 C68 C69 C68 0.2(3) . 2
C67 C68 C69 C68 -179.7(4) . 2
C70 C71 C72 C73 179.4(12) . .
C70 C71 C72 C73' -178.2(9) . .
C71 C72 C73 C74 156.1(12) . .
C73' C72 C73 C74 112(23) . .
C72 C73 C74 C75 -108(2) . .
C73 C74 C75 C76 -37(2) . .
C71 C72 C73' C74' 84.3(15) . .
C73 C72 C73' C74' -139(23) . .
C72 C73' C74' C75' 174.3(11) . .
C73' C74' C75' C76' 71.0(19) . .
