#------------------------------------------------------------------------------
#$Date: 2019-11-14 12:44:39 +0200 (Thu, 14 Nov 2019) $
#$Revision: 227778 $
#$URL: file:///home/coder/svn-repositories/cod/cif/7/23/50/7235069.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7235069
loop_
_publ_author_name
'Csaba Jobbagy'
'Peter Baranyai'
'Gabor Marsi'
'Barbara Racz'
'Liang Li'
'Pance Naumov'
'Andrea Deak'
_publ_section_title
;
 Novel gold(i) diphosphine-based dimers with aurophilicity triggered
 multistimuli light-emitting properties
;
_journal_name_full               'Journal of Materials Chemistry C'
_journal_page_first              10253
_journal_page_last               10264
_journal_paper_doi               10.1039/C6TC01427E
_journal_volume                  4
_journal_year                    2016
_chemical_formula_moiety         'C72 H56 Au2 O2 P4, 2(F6 Sb), C H2 Cl2'
_chemical_formula_sum            'C73 H58 Au2 Cl2 F12 O2 P4 Sb2'
_chemical_formula_weight         2027.40
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_cell_angle_alpha                90
_cell_angle_beta                 105.2300(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   22.6394(16)
_cell_length_b                   16.3498(11)
_cell_length_c                   20.1213(14)
_cell_measurement_reflns_used    9110
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      28.364
_cell_measurement_theta_min      2.243
_cell_volume                     7186.3(9)
_computing_cell_refinement       'SAINT v8.34A (Bruker, 2013)'
_computing_data_reduction        'SAINT v8.34A (Bruker, 2013)'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'XT (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0413
_diffrn_reflns_av_unetI/netI     0.0242
_diffrn_reflns_Laue_measured_fraction_full 1.000
_diffrn_reflns_Laue_measured_fraction_max 0.997
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       21
_diffrn_reflns_limit_k_min       -21
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            170498
_diffrn_reflns_point_group_measured_fraction_full 1.000
_diffrn_reflns_point_group_measured_fraction_max 0.997
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.395
_diffrn_reflns_theta_min         0.932
_exptl_absorpt_coefficient_mu    5.054
_exptl_absorpt_correction_T_max  0.576
_exptl_absorpt_correction_T_min  0.332
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2014/4 (Bruker,2014) was used for absorption correction.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.874
_exptl_crystal_description       block
_exptl_crystal_F_000             3896
_exptl_crystal_size_max          0.270
_exptl_crystal_size_mid          0.140
_exptl_crystal_size_min          0.110
_refine_diff_density_max         3.787
_refine_diff_density_min         -2.838
_refine_diff_density_rms         0.134
_refine_ls_extinction_coef       .
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     884
_refine_ls_number_reflns         17976
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.026
_refine_ls_R_factor_all          0.0421
_refine_ls_R_factor_gt           0.0302
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0342P)²+27.8667P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0699
_refine_ls_wR_factor_ref         0.0767
_reflns_Friedel_coverage         0.000
_reflns_Friedel_fraction_full    .
_reflns_Friedel_fraction_max     .
_reflns_number_gt                15013
_reflns_number_total             17976
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            1000005.cif
_cod_data_source_block           PCOD1000005
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               7235069
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.342
_shelx_estimated_absorpt_t_max   0.606
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.21290(2) 0.34995(2) 0.79435(2) 0.01622(4) Uani 1 1 d . . . . .
Au2 Au 0.25901(2) 0.45270(2) 0.65047(2) 0.01836(4) Uani 1 1 d . . . . .
P1 P 0.18443(5) 0.22263(6) 0.74254(5) 0.01563(18) Uani 1 1 d . . . . .
P2 P 0.15711(5) 0.47363(6) 0.59414(5) 0.01631(19) Uani 1 1 d . . . . .
P3 P 0.24335(5) 0.45877(6) 0.87097(5) 0.01620(19) Uani 1 1 d . . . . .
P4 P 0.36403(5) 0.44098(6) 0.69114(5) 0.0203(2) Uani 1 1 d . . . . .
C1 C 0.22760(19) 0.1915(2) 0.68204(19) 0.0177(7) Uani 1 1 d . . . . .
C2 C 0.2711(2) 0.1286(3) 0.6965(2) 0.0218(8) Uani 1 1 d . . . . .
H2 H 0.2753 0.0960 0.7366 0.026 Uiso 1 1 calc R U . . .
C3 C 0.3083(2) 0.1136(3) 0.6529(2) 0.0275(9) Uani 1 1 d . . . . .
H3 H 0.3370 0.0700 0.6625 0.033 Uiso 1 1 calc R U . . .
C4 C 0.3036(2) 0.1620(3) 0.5954(2) 0.0291(10) Uani 1 1 d . . . . .
H4 H 0.3303 0.1529 0.5668 0.035 Uiso 1 1 calc R U . . .
C5 C 0.2602(2) 0.2237(3) 0.5790(2) 0.0250(9) Uani 1 1 d . . . . .
H5 H 0.2570 0.2566 0.5393 0.030 Uiso 1 1 calc R U . . .
C6 C 0.22125(18) 0.2369(2) 0.62135(19) 0.0183(8) Uani 1 1 d . . . . .
C7 C 0.14576(19) 0.3160(2) 0.54204(19) 0.0194(8) Uani 1 1 d . . . . .
C8 C 0.13118(19) 0.3981(2) 0.52693(19) 0.0181(8) Uani 1 1 d . . . . .
C9 C 0.09586(19) 0.4181(3) 0.4609(2) 0.0217(8) Uani 1 1 d . . . . .
H9 H 0.0858 0.4737 0.4493 0.026 Uiso 1 1 calc R U . . .
C10 C 0.0754(2) 0.3574(3) 0.4123(2) 0.0267(9) Uani 1 1 d . . . . .
H10 H 0.0515 0.3716 0.3675 0.032 Uiso 1 1 calc R U . . .
C11 C 0.0895(2) 0.2759(3) 0.4285(2) 0.0263(9) Uani 1 1 d . . . . .
H11 H 0.0748 0.2346 0.3951 0.032 Uiso 1 1 calc R U . . .
C12 C 0.1252(2) 0.2549(3) 0.4936(2) 0.0234(8) Uani 1 1 d . . . . .
H12 H 0.1355 0.1993 0.5048 0.028 Uiso 1 1 calc R U . . .
O1 O 0.17812(14) 0.29851(16) 0.60977(13) 0.0200(6) Uani 1 1 d . . . . .
C13 C 0.23668(18) 0.5624(2) 0.83756(19) 0.0179(8) Uani 1 1 d . . . . .
C14 C 0.1923(2) 0.6166(2) 0.8480(2) 0.0219(8) Uani 1 1 d . . . . .
H14 H 0.1669 0.6006 0.8766 0.026 Uiso 1 1 calc R U . . .
C15 C 0.1846(2) 0.6932(3) 0.8175(2) 0.0274(9) Uani 1 1 d . . . . .
H15 H 0.1551 0.7301 0.8263 0.033 Uiso 1 1 calc R U . . .
C16 C 0.2205(2) 0.7160(3) 0.7738(2) 0.0328(10) Uani 1 1 d . . . . .
H16 H 0.2140 0.7674 0.7510 0.039 Uiso 1 1 calc R U . . .
C17 C 0.2654(2) 0.6640(3) 0.7636(2) 0.0291(10) Uani 1 1 d . . . . .
H17 H 0.2900 0.6795 0.7340 0.035 Uiso 1 1 calc R U . . .
C18 C 0.2744(2) 0.5893(3) 0.7969(2) 0.0227(8) Uani 1 1 d . . . . .
C19 C 0.3741(2) 0.5690(3) 0.7820(2) 0.0247(9) Uani 1 1 d . . . . .
C20 C 0.3994(2) 0.5328(3) 0.7336(2) 0.0238(9) Uani 1 1 d . . . . .
C21 C 0.4546(2) 0.5640(3) 0.7250(3) 0.0358(11) Uani 1 1 d . . . . .
H21 H 0.4724 0.5407 0.6915 0.043 Uiso 1 1 calc R U . . .
C22 C 0.4831(3) 0.6287(4) 0.7651(3) 0.0478(15) Uani 1 1 d . . . . .
H22 H 0.5201 0.6505 0.7586 0.057 Uiso 1 1 calc R U . . .
C23 C 0.4576(3) 0.6619(4) 0.8147(3) 0.0467(15) Uani 1 1 d . . . . .
H23 H 0.4782 0.7049 0.8434 0.056 Uiso 1 1 calc R U . . .
C24 C 0.4024(2) 0.6329(3) 0.8229(3) 0.0362(11) Uani 1 1 d . . . . .
H24 H 0.3844 0.6567 0.8560 0.043 Uiso 1 1 calc R U . . .
O2 O 0.32002(14) 0.53522(18) 0.79008(15) 0.0236(6) Uani 1 1 d . . . . .
C1A C 0.20220(19) 0.1448(2) 0.80962(19) 0.0186(8) Uani 1 1 d . . . . .
C2A C 0.2419(2) 0.1627(3) 0.8735(2) 0.0237(9) Uani 1 1 d . . . . .
H2A H 0.2575 0.2166 0.8831 0.028 Uiso 1 1 calc R U . . .
C3A C 0.2590(2) 0.1021(3) 0.9234(2) 0.0306(10) Uani 1 1 d . . . . .
H3A H 0.2864 0.1143 0.9668 0.037 Uiso 1 1 calc R U . . .
C4A C 0.2358(2) 0.0240(3) 0.9094(2) 0.0313(10) Uani 1 1 d . . . . .
H4A H 0.2475 -0.0175 0.9434 0.038 Uiso 1 1 calc R U . . .
C5A C 0.1959(2) 0.0056(3) 0.8467(2) 0.0303(10) Uani 1 1 d . . . . .
H5A H 0.1802 -0.0484 0.8377 0.036 Uiso 1 1 calc R U . . .
C6A C 0.1784(2) 0.0661(3) 0.7962(2) 0.0244(9) Uani 1 1 d . . . . .
H6A H 0.1506 0.0536 0.7532 0.029 Uiso 1 1 calc R U . . .
C1B C 0.10466(18) 0.2074(2) 0.69902(19) 0.0168(7) Uani 1 1 d . . . . .
C2B C 0.06085(19) 0.2380(3) 0.7301(2) 0.0224(8) Uani 1 1 d . . . . .
H2B H 0.0731 0.2703 0.7706 0.027 Uiso 1 1 calc R U . . .
C3B C -0.0007(2) 0.2209(3) 0.7014(2) 0.0265(9) Uani 1 1 d . . . . .
H3B H -0.0304 0.2400 0.7234 0.032 Uiso 1 1 calc R U . . .
C4B C -0.0190(2) 0.1762(3) 0.6413(2) 0.0236(8) Uani 1 1 d . . . . .
H4B H -0.0612 0.1652 0.6217 0.028 Uiso 1 1 calc R U . . .
C5B C 0.0244(2) 0.1471(3) 0.6091(2) 0.0235(8) Uani 1 1 d . . . . .
H5B H 0.0119 0.1174 0.5672 0.028 Uiso 1 1 calc R U . . .
C6B C 0.08599(19) 0.1619(2) 0.6387(2) 0.0198(8) Uani 1 1 d . . . . .
H6B H 0.1157 0.1407 0.6177 0.024 Uiso 1 1 calc R U . . .
C1C C 0.14489(19) 0.5741(2) 0.5542(2) 0.0193(8) Uani 1 1 d . . . . .
C2C C 0.0865(2) 0.6082(3) 0.5350(2) 0.0243(9) Uani 1 1 d . . . . .
H2C H 0.0522 0.5775 0.5396 0.029 Uiso 1 1 calc R U . . .
C3C C 0.0786(2) 0.6870(3) 0.5090(2) 0.0278(9) Uani 1 1 d . . . . .
H3C H 0.0387 0.7103 0.4955 0.033 Uiso 1 1 calc R U . . .
C4C C 0.1282(2) 0.7317(3) 0.5027(3) 0.0339(11) Uani 1 1 d . . . . .
H4C H 0.1226 0.7863 0.4862 0.041 Uiso 1 1 calc R U . . .
C5C C 0.1863(3) 0.6979(3) 0.5201(3) 0.0392(12) Uani 1 1 d . . . . .
H5C H 0.2202 0.7286 0.5143 0.047 Uiso 1 1 calc R U . . .
C6C C 0.1946(2) 0.6185(3) 0.5462(2) 0.0280(9) Uani 1 1 d . . . . .
H6C H 0.2343 0.5950 0.5584 0.034 Uiso 1 1 calc R U . . .
C1D C 0.10129(18) 0.4712(2) 0.64452(19) 0.0186(8) Uani 1 1 d . . . . .
C2D C 0.1072(2) 0.5305(3) 0.6957(2) 0.0259(9) Uani 1 1 d . . . . .
H2D H 0.1420 0.5654 0.7068 0.031 Uiso 1 1 calc R U . . .
C3D C 0.0618(2) 0.5381(3) 0.7306(2) 0.0294(10) Uani 1 1 d . . . . .
H3D H 0.0657 0.5781 0.7657 0.035 Uiso 1 1 calc R U . . .
C4D C 0.0111(2) 0.4876(3) 0.7141(2) 0.0272(9) Uani 1 1 d . . . . .
H4D H -0.0200 0.4936 0.7376 0.033 Uiso 1 1 calc R U . . .
C5D C 0.0055(2) 0.4287(3) 0.6639(3) 0.0309(10) Uani 1 1 d . . . . .
H5D H -0.0294 0.3940 0.6530 0.037 Uiso 1 1 calc R U . . .
C6D C 0.0506(2) 0.4197(3) 0.6289(2) 0.0258(9) Uani 1 1 d . . . . .
H6D H 0.0468 0.3786 0.5946 0.031 Uiso 1 1 calc R U . . .
C1E C 0.32101(19) 0.4485(3) 0.9248(2) 0.0201(8) Uani 1 1 d . . . . .
C2E C 0.3504(2) 0.3732(3) 0.9302(2) 0.0241(9) Uani 1 1 d . . . . .
H2E H 0.3306 0.3279 0.9040 0.029 Uiso 1 1 calc R U . . .
C3E C 0.4091(2) 0.3642(3) 0.9742(2) 0.0340(11) Uani 1 1 d . . . . .
H3E H 0.4293 0.3128 0.9778 0.041 Uiso 1 1 calc R U . . .
C4E C 0.4375(2) 0.4295(4) 1.0121(3) 0.0379(12) Uani 1 1 d . . . . .
H4E H 0.4773 0.4229 1.0421 0.045 Uiso 1 1 calc R U . . .
C5E C 0.4091(2) 0.5046(4) 1.0073(3) 0.0413(12) Uani 1 1 d . . . . .
H5E H 0.4291 0.5493 1.0342 0.050 Uiso 1 1 calc R U . . .
C6E C 0.3507(2) 0.5147(3) 0.9626(2) 0.0308(10) Uani 1 1 d . . . . .
H6E H 0.3313 0.5667 0.9582 0.037 Uiso 1 1 calc R U . . .
C1F C 0.19355(19) 0.4613(2) 0.9284(2) 0.0189(8) Uani 1 1 d . . . . .
C2F C 0.2144(2) 0.4878(3) 0.9966(2) 0.0278(9) Uani 1 1 d . . . . .
H2F H 0.2568 0.4974 1.0161 0.033 Uiso 1 1 calc R U . . .
C3F C 0.1729(2) 0.5000(3) 1.0359(2) 0.0341(11) Uani 1 1 d . . . . .
H3F H 0.1872 0.5176 1.0824 0.041 Uiso 1 1 calc R U . . .
C4F C 0.1112(2) 0.4869(3) 1.0080(2) 0.0311(10) Uani 1 1 d . . . . .
H4F H 0.0832 0.4966 1.0349 0.037 Uiso 1 1 calc R U . . .
C5F C 0.0899(2) 0.4596(3) 0.9408(2) 0.0274(9) Uani 1 1 d . . . . .
H5F H 0.0474 0.4505 0.9218 0.033 Uiso 1 1 calc R U . . .
C6F C 0.1310(2) 0.4456(2) 0.9009(2) 0.0229(8) Uani 1 1 d . . . . .
H6F H 0.1165 0.4255 0.8553 0.028 Uiso 1 1 calc R U . . .
C1G C 0.3942(2) 0.3625(3) 0.7543(2) 0.0256(9) Uani 1 1 d . . . . .
C2G C 0.3587(2) 0.2955(3) 0.7606(2) 0.0239(9) Uani 1 1 d . . . . .
H2G H 0.3177 0.2918 0.7329 0.029 Uiso 1 1 calc R U . . .
C3G C 0.3827(2) 0.2337(3) 0.8073(2) 0.0283(9) Uani 1 1 d . . . . .
H3G H 0.3578 0.1882 0.8118 0.034 Uiso 1 1 calc R U . . .
C4G C 0.4422(2) 0.2379(3) 0.8472(2) 0.0362(11) Uani 1 1 d . . . . .
H4G H 0.4587 0.1953 0.8787 0.043 Uiso 1 1 calc R U . . .
C5G C 0.4781(3) 0.3050(4) 0.8409(3) 0.0501(15) Uani 1 1 d . . . . .
H5G H 0.5192 0.3080 0.8683 0.060 Uiso 1 1 calc R U . . .
C6G C 0.4545(2) 0.3675(4) 0.7954(3) 0.0442(14) Uani 1 1 d . . . . .
H6G H 0.4791 0.4135 0.7919 0.053 Uiso 1 1 calc R U . . .
C1H C 0.39869(19) 0.4239(3) 0.6204(2) 0.0207(8) Uani 1 1 d . . . . .
C2H C 0.3859(2) 0.4807(3) 0.5668(2) 0.0287(9) Uani 1 1 d . . . . .
H2H H 0.3593 0.5253 0.5676 0.034 Uiso 1 1 calc R U . . .
C3H C 0.4122(2) 0.4720(3) 0.5123(2) 0.0306(10) Uani 1 1 d . . . . .
H3H H 0.4037 0.5107 0.4759 0.037 Uiso 1 1 calc R U . . .
C4H C 0.4508(2) 0.4068(3) 0.5110(3) 0.0329(10) Uani 1 1 d . . . . .
H4H H 0.4696 0.4015 0.4742 0.040 Uiso 1 1 calc R U . . .
C5H C 0.4620(3) 0.3494(3) 0.5630(3) 0.0410(12) Uani 1 1 d . . . . .
H5H H 0.4877 0.3040 0.5614 0.049 Uiso 1 1 calc R U . . .
C6H C 0.4357(2) 0.3576(3) 0.6180(3) 0.0358(11) Uani 1 1 d . . . . .
H6H H 0.4432 0.3178 0.6536 0.043 Uiso 1 1 calc R U . . .
Sb1 Sb 0.07783(2) 0.85483(2) 0.66298(2) 0.02430(6) Uani 1 1 d . . . . .
F1 F 0.07805(15) 0.74066(15) 0.66595(14) 0.0388(7) Uani 1 1 d . . . . .
F2 F 0.11013(13) 0.85803(16) 0.75941(13) 0.0298(6) Uani 1 1 d . . . . .
F3 F 0.07666(13) 0.96999(15) 0.66185(14) 0.0323(6) Uani 1 1 d . . . . .
F4 F 0.04319(15) 0.85564(16) 0.56716(13) 0.0363(7) Uani 1 1 d . . . . .
F5 F 0.15703(15) 0.8566(2) 0.65113(18) 0.0481(8) Uani 1 1 d . . . . .
F6 F -0.00128(12) 0.85497(16) 0.67648(13) 0.0290(6) Uani 1 1 d . . . . .
Sb2 Sb 0.62461(2) 0.22344(2) 1.00253(2) 0.03198(7) Uani 1 1 d . . . . .
F7 F 0.6134(3) 0.1592(4) 1.0758(3) 0.111(2) Uani 1 1 d . . . . .
F8 F 0.68502(19) 0.2853(2) 1.0603(3) 0.0886(17) Uani 1 1 d . . . . .
F9 F 0.6296(2) 0.2900(4) 0.9318(2) 0.106(2) Uani 1 1 d . . . . .
F10 F 0.56246(13) 0.16302(18) 0.94400(18) 0.0441(8) Uani 1 1 d . . . . .
F11 F 0.68188(17) 0.1497(3) 0.9922(4) 0.121(3) Uani 1 1 d . . . . .
F12 F 0.56356(18) 0.2931(3) 1.0177(3) 0.0804(14) Uani 1 1 d . . . . .
C25 C 0.6487(7) 0.4233(8) 0.7434(10) 0.290(15) Uani 1 1 d . . . A 1
H25A H 0.6663 0.3907 0.7117 0.348 Uiso 1 1 calc R U . A 1
H25B H 0.6836 0.4571 0.7690 0.348 Uiso 1 1 calc R U . A 1
Cl1 Cl 0.6512(3) 0.3628(3) 0.7939(3) 0.228(3) Uani 1 1 d . . . A 1
Cl2A Cl 0.61190(18) 0.4968(2) 0.68519(16) 0.0883(14) Uani 0.687(8) 1 d . . P A
1
Cl2B Cl 0.5874(7) 0.4388(12) 0.7138(11) 0.231(10) Uani 0.313(8) 1 d . . P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
P3 Au1 P1 165.87(3) . .
P4 Au2 P2 170.76(4) . .
C1B P1 C1A 105.16(18) . .
C1B P1 C1 106.34(18) . .
C1A P1 C1 104.32(18) . .
C1B P1 Au1 117.49(13) . .
C1A P1 Au1 108.04(13) . .
C1 P1 Au1 114.34(13) . .
C8 P2 C1D 105.36(19) . .
C8 P2 C1C 107.74(18) . .
C1D P2 C1C 102.67(18) . .
C8 P2 Au2 110.53(14) . .
C1D P2 Au2 118.27(13) . .
C1C P2 Au2 111.52(14) . .
C1E P3 C13 106.30(19) . .
C1E P3 C1F 106.80(18) . .
C13 P3 C1F 102.10(18) . .
C1E P3 Au1 113.26(14) . .
C13 P3 Au1 119.03(12) . .
C1F P3 Au1 108.21(14) . .
C20 P4 C1G 102.6(2) . .
C20 P4 C1H 105.62(19) . .
C1G P4 C1H 106.3(2) . .
C20 P4 Au2 112.69(15) . .
C1G P4 Au2 118.12(15) . .
C1H P4 Au2 110.54(14) . .
C2 C1 C6 118.3(4) . .
C2 C1 P1 122.5(3) . .
C6 C1 P1 118.9(3) . .
C3 C2 C1 120.5(4) . .
C3 C2 H2 119.7 . .
C1 C2 H2 119.7 . .
C4 C3 C2 120.1(4) . .
C4 C3 H3 119.9 . .
C2 C3 H3 119.9 . .
C3 C4 C5 120.6(4) . .
C3 C4 H4 119.7 . .
C5 C4 H4 119.7 . .
C4 C5 C6 119.3(4) . .
C4 C5 H5 120.4 . .
C6 C5 H5 120.4 . .
O1 C6 C5 122.9(4) . .
O1 C6 C1 116.1(3) . .
C5 C6 C1 120.9(4) . .
C12 C7 C8 121.5(4) . .
C12 C7 O1 122.0(4) . .
C8 C7 O1 116.3(3) . .
C7 C8 C9 118.4(4) . .
C7 C8 P2 118.8(3) . .
C9 C8 P2 122.8(3) . .
C10 C9 C8 120.3(4) . .
C10 C9 H9 119.8 . .
C8 C9 H9 119.8 . .
C9 C10 C11 120.5(4) . .
C9 C10 H10 119.8 . .
C11 C10 H10 119.8 . .
C12 C11 C10 120.0(4) . .
C12 C11 H11 120.0 . .
C10 C11 H11 120.0 . .
C7 C12 C11 119.2(4) . .
C7 C12 H12 120.4 . .
C11 C12 H12 120.4 . .
C6 O1 C7 118.8(3) . .
C14 C13 C18 117.6(4) . .
C14 C13 P3 122.0(3) . .
C18 C13 P3 120.4(3) . .
C15 C14 C13 121.2(4) . .
C15 C14 H14 119.4 . .
C13 C14 H14 119.4 . .
C14 C15 C16 119.6(4) . .
C14 C15 H15 120.2 . .
C16 C15 H15 120.2 . .
C17 C16 C15 120.2(4) . .
C17 C16 H16 119.9 . .
C15 C16 H16 119.9 . .
C18 C17 C16 119.5(4) . .
C18 C17 H17 120.3 . .
C16 C17 H17 120.3 . .
C17 C18 O2 122.2(4) . .
C17 C18 C13 121.7(4) . .
O2 C18 C13 116.1(4) . .
C24 C19 C20 122.0(4) . .
C24 C19 O2 121.1(4) . .
C20 C19 O2 116.9(4) . .
C19 C20 C21 118.6(4) . .
C19 C20 P4 118.3(3) . .
C21 C20 P4 122.8(3) . .
C22 C21 C20 120.0(4) . .
C22 C21 H21 120.0 . .
C20 C21 H21 120.0 . .
C21 C22 C23 120.0(5) . .
C21 C22 H22 120.0 . .
C23 C22 H22 120.0 . .
C24 C23 C22 120.6(5) . .
C24 C23 H23 119.7 . .
C22 C23 H23 119.7 . .
C19 C24 C23 118.7(5) . .
C19 C24 H24 120.6 . .
C23 C24 H24 120.6 . .
C19 O2 C18 117.2(3) . .
C2A C1A C6A 119.7(4) . .
C2A C1A P1 120.1(3) . .
C6A C1A P1 120.2(3) . .
C3A C2A C1A 120.4(4) . .
C3A C2A H2A 119.8 . .
C1A C2A H2A 119.8 . .
C4A C3A C2A 119.6(4) . .
C4A C3A H3A 120.2 . .
C2A C3A H3A 120.2 . .
C5A C4A C3A 120.7(4) . .
C5A C4A H4A 119.6 . .
C3A C4A H4A 119.6 . .
C4A C5A C6A 120.2(4) . .
C4A C5A H5A 119.9 . .
C6A C5A H5A 119.9 . .
C1A C6A C5A 119.5(4) . .
C1A C6A H6A 120.3 . .
C5A C6A H6A 120.3 . .
C6B C1B C2B 119.5(4) . .
C6B C1B P1 122.2(3) . .
C2B C1B P1 118.1(3) . .
C3B C2B C1B 119.7(4) . .
C3B C2B H2B 120.2 . .
C1B C2B H2B 120.2 . .
C4B C3B C2B 120.5(4) . .
C4B C3B H3B 119.8 . .
C2B C3B H3B 119.8 . .
C3B C4B C5B 120.1(4) . .
C3B C4B H4B 119.9 . .
C5B C4B H4B 119.9 . .
C6B C5B C4B 119.5(4) . .
C6B C5B H5B 120.2 . .
C4B C5B H5B 120.2 . .
C5B C6B C1B 120.6(4) . .
C5B C6B H6B 119.7 . .
C1B C6B H6B 119.7 . .
C6C C1C C2C 119.8(4) . .
C6C C1C P2 119.5(3) . .
C2C C1C P2 120.6(3) . .
C3C C2C C1C 119.9(4) . .
C3C C2C H2C 120.1 . .
C1C C2C H2C 120.1 . .
C4C C3C C2C 120.1(4) . .
C4C C3C H3C 120.0 . .
C2C C3C H3C 120.0 . .
C3C C4C C5C 120.7(4) . .
C3C C4C H4C 119.6 . .
C5C C4C H4C 119.6 . .
C4C C5C C6C 119.4(5) . .
C4C C5C H5C 120.3 . .
C6C C5C H5C 120.3 . .
C1C C6C C5C 120.0(4) . .
C1C C6C H6C 120.0 . .
C5C C6C H6C 120.0 . .
C6D C1D C2D 120.0(4) . .
C6D C1D P2 122.8(3) . .
C2D C1D P2 116.8(3) . .
C3D C2D C1D 119.5(4) . .
C3D C2D H2D 120.2 . .
C1D C2D H2D 120.2 . .
C4D C3D C2D 120.2(4) . .
C4D C3D H3D 119.9 . .
C2D C3D H3D 119.9 . .
C5D C4D C3D 120.3(4) . .
C5D C4D H4D 119.8 . .
C3D C4D H4D 119.8 . .
C4D C5D C6D 120.4(4) . .
C4D C5D H5D 119.8 . .
C6D C5D H5D 119.8 . .
C1D C6D C5D 119.6(4) . .
C1D C6D H6D 120.2 . .
C5D C6D H6D 120.2 . .
C2E C1E C6E 119.6(4) . .
C2E C1E P3 119.9(3) . .
C6E C1E P3 120.5(3) . .
C1E C2E C3E 120.0(4) . .
C1E C2E H2E 120.0 . .
C3E C2E H2E 120.0 . .
C4E C3E C2E 119.9(5) . .
C4E C3E H3E 120.0 . .
C2E C3E H3E 120.0 . .
C3E C4E C5E 120.9(5) . .
C3E C4E H4E 119.5 . .
C5E C4E H4E 119.5 . .
C4E C5E C6E 119.6(5) . .
C4E C5E H5E 120.2 . .
C6E C5E H5E 120.2 . .
C1E C6E C5E 120.0(5) . .
C1E C6E H6E 120.0 . .
C5E C6E H6E 120.0 . .
C2F C1F C6F 119.3(4) . .
C2F C1F P3 121.7(3) . .
C6F C1F P3 118.5(3) . .
C3F C2F C1F 119.9(4) . .
C3F C2F H2F 120.1 . .
C1F C2F H2F 120.1 . .
C4F C3F C2F 120.6(4) . .
C4F C3F H3F 119.7 . .
C2F C3F H3F 119.7 . .
C3F C4F C5F 120.2(4) . .
C3F C4F H4F 119.9 . .
C5F C4F H4F 119.9 . .
C4F C5F C6F 120.0(4) . .
C4F C5F H5F 120.0 . .
C6F C5F H5F 120.0 . .
C5F C6F C1F 120.0(4) . .
C5F C6F H6F 120.0 . .
C1F C6F H6F 120.0 . .
C2G C1G C6G 119.5(4) . .
C2G C1G P4 120.3(3) . .
C6G C1G P4 120.2(3) . .
C1G C2G C3G 120.3(4) . .
C1G C2G H2G 119.9 . .
C3G C2G H2G 119.9 . .
C4G C3G C2G 120.4(4) . .
C4G C3G H3G 119.8 . .
C2G C3G H3G 119.8 . .
C3G C4G C5G 119.5(4) . .
C3G C4G H4G 120.2 . .
C5G C4G H4G 120.2 . .
C6G C5G C4G 120.7(5) . .
C6G C5G H5G 119.7 . .
C4G C5G H5G 119.7 . .
C5G C6G C1G 119.7(5) . .
C5G C6G H6G 120.2 . .
C1G C6G H6G 120.2 . .
C6H C1H C2H 120.1(4) . .
C6H C1H P4 122.6(3) . .
C2H C1H P4 117.3(3) . .
C3H C2H C1H 119.9(4) . .
C3H C2H H2H 120.0 . .
C1H C2H H2H 120.0 . .
C4H C3H C2H 120.0(4) . .
C4H C3H H3H 120.0 . .
C2H C3H H3H 120.0 . .
C5H C4H C3H 120.0(4) . .
C5H C4H H4H 120.0 . .
C3H C4H H4H 120.0 . .
C4H C5H C6H 120.4(4) . .
C4H C5H H5H 119.8 . .
C6H C5H H5H 119.8 . .
C1H C6H C5H 119.5(4) . .
C1H C6H H6H 120.2 . .
C5H C6H H6H 120.2 . .
F1 Sb1 F5 91.42(14) . .
F1 Sb1 F6 89.50(13) . .
F5 Sb1 F6 178.67(14) . .
F1 Sb1 F4 92.11(12) . .
F5 Sb1 F4 91.42(14) . .
F6 Sb1 F4 89.52(12) . .
F1 Sb1 F3 178.54(12) . .
F5 Sb1 F3 89.66(13) . .
F6 Sb1 F3 89.40(12) . .
F4 Sb1 F3 88.84(12) . .
F1 Sb1 F2 89.87(12) . .
F5 Sb1 F2 90.29(14) . .
F6 Sb1 F2 88.74(11) . .
F4 Sb1 F2 177.35(12) . .
F3 Sb1 F2 89.15(12) . .
F9 Sb2 F11 96.6(3) . .
F9 Sb2 F8 88.7(2) . .
F11 Sb2 F8 90.13(18) . .
F9 Sb2 F10 90.82(18) . .
F11 Sb2 F10 91.09(16) . .
F8 Sb2 F10 178.73(15) . .
F9 Sb2 F12 87.9(3) . .
F11 Sb2 F12 175.3(3) . .
F8 Sb2 F12 91.19(18) . .
F10 Sb2 F12 87.62(16) . .
F9 Sb2 F7 175.2(3) . .
F11 Sb2 F7 88.1(3) . .
F8 Sb2 F7 92.5(2) . .
F10 Sb2 F7 88.0(2) . .
F12 Sb2 F7 87.4(3) . .
Cl1 C25 Cl2A 153.6(15) . .
Cl1 C25 H25A 98.1 . .
Cl2A C25 H25A 98.1 . .
Cl1 C25 H25B 98.1 . .
Cl2A C25 H25B 98.1 . .
H25A C25 H25B 103.7 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Au1 P3 2.3366(10) .
Au1 P1 2.3414(10) .
Au2 P4 2.3103(11) .
Au2 P2 2.3131(10) .
P1 C1B 1.805(4) .
P1 C1A 1.821(4) .
P1 C1 1.822(4) .
P2 C8 1.812(4) .
P2 C1D 1.816(4) .
P2 C1C 1.817(4) .
P3 C1E 1.814(4) .
P3 C13 1.814(4) .
P3 C1F 1.815(4) .
P4 C20 1.807(4) .
P4 C1G 1.809(4) .
P4 C1H 1.819(4) .
C1 C2 1.401(6) .
C1 C6 1.404(5) .
C2 C3 1.388(6) .
C2 H2 0.9500 .
C3 C4 1.382(6) .
C3 H3 0.9500 .
C4 C5 1.386(6) .
C4 H4 0.9500 .
C5 C6 1.395(6) .
C5 H5 0.9500 .
C6 O1 1.379(5) .
C7 C12 1.389(5) .
C7 C8 1.396(5) .
C7 O1 1.397(4) .
C8 C9 1.398(5) .
C9 C10 1.385(6) .
C9 H9 0.9500 .
C10 C11 1.389(6) .
C10 H10 0.9500 .
C11 C12 1.389(6) .
C11 H11 0.9500 .
C12 H12 0.9500 .
C13 C14 1.396(6) .
C13 C18 1.401(6) .
C14 C15 1.387(6) .
C14 H14 0.9500 .
C15 C16 1.395(7) .
C15 H15 0.9500 .
C16 C17 1.382(7) .
C16 H16 0.9500 .
C17 C18 1.381(6) .
C17 H17 0.9500 .
C18 O2 1.393(5) .
C19 C24 1.380(6) .
C19 C20 1.385(6) .
C19 O2 1.391(5) .
C20 C21 1.402(6) .
C21 C22 1.384(7) .
C21 H21 0.9500 .
C22 C23 1.389(7) .
C22 H22 0.9500 .
C23 C24 1.386(7) .
C23 H23 0.9500 .
C24 H24 0.9500 .
C1A C2A 1.393(6) .
C1A C6A 1.394(6) .
C2A C3A 1.391(6) .
C2A H2A 0.9500 .
C3A C4A 1.381(7) .
C3A H3A 0.9500 .
C4A C5A 1.380(7) .
C4A H4A 0.9500 .
C5A C6A 1.398(6) .
C5A H5A 0.9500 .
C6A H6A 0.9500 .
C1B C6B 1.391(5) .
C1B C2B 1.396(5) .
C2B C3B 1.389(6) .
C2B H2B 0.9500 .
C3B C4B 1.381(6) .
C3B H3B 0.9500 .
C4B C5B 1.393(6) .
C4B H4B 0.9500 .
C5B C6B 1.386(6) .
C5B H5B 0.9500 .
C6B H6B 0.9500 .
C1C C6C 1.385(6) .
C1C C2C 1.393(6) .
C2C C3C 1.385(6) .
C2C H2C 0.9500 .
C3C C4C 1.374(7) .
C3C H3C 0.9500 .
C4C C5C 1.384(7) .
C4C H4C 0.9500 .
C5C C6C 1.394(6) .
C5C H5C 0.9500 .
C6C H6C 0.9500 .
C1D C6D 1.391(6) .
C1D C2D 1.396(6) .
C2D C3D 1.394(6) .
C2D H2D 0.9500 .
C3D C4D 1.381(7) .
C3D H3D 0.9500 .
C4D C5D 1.378(7) .
C4D H4D 0.9500 .
C5D C6D 1.392(6) .
C5D H5D 0.9500 .
C6D H6D 0.9500 .
C1E C2E 1.390(6) .
C1E C6E 1.390(6) .
C2E C3E 1.397(6) .
C2E H2E 0.9500 .
C3E C4E 1.370(8) .
C3E H3E 0.9500 .
C4E C5E 1.378(8) .
C4E H4E 0.9500 .
C5E C6E 1.400(7) .
C5E H5E 0.9500 .
C6E H6E 0.9500 .
C1F C2F 1.398(6) .
C1F C6F 1.402(6) .
C2F C3F 1.392(6) .
C2F H2F 0.9500 .
C3F C4F 1.379(7) .
C3F H3F 0.9500 .
C4F C5F 1.384(7) .
C4F H4F 0.9500 .
C5F C6F 1.397(6) .
C5F H5F 0.9500 .
C6F H6F 0.9500 .
C1G C2G 1.384(6) .
C1G C6G 1.400(7) .
C2G C3G 1.390(6) .
C2G H2G 0.9500 .
C3G C4G 1.378(7) .
C3G H3G 0.9500 .
C4G C5G 1.390(8) .
C4G H4G 0.9500 .
C5G C6G 1.383(7) .
C5G H5G 0.9500 .
C6G H6G 0.9500 .
C1H C6H 1.378(6) .
C1H C2H 1.394(6) .
C2H C3H 1.385(6) .
C2H H2H 0.9500 .
C3H C4H 1.383(7) .
C3H H3H 0.9500 .
C4H C5H 1.379(7) .
C4H H4H 0.9500 .
C5H C6H 1.394(7) .
C5H H5H 0.9500 .
C6H H6H 0.9500 .
Sb1 F1 1.868(3) .
Sb1 F5 1.870(3) .
Sb1 F6 1.881(3) .
Sb1 F4 1.881(3) .
Sb1 F3 1.883(2) .
Sb1 F2 1.886(3) .
Sb2 F9 1.819(4) .
Sb2 F11 1.822(4) .
Sb2 F8 1.846(3) .
Sb2 F10 1.863(3) .
Sb2 F12 1.877(4) .
Sb2 F7 1.880(5) .
C25 Cl1 1.409(12) .
C25 Cl2A 1.731(10) .
C25 H25A 0.9900 .
C25 H25B 0.9900 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
C1B P1 C1 C2 -120.3(3) . . . .
C1A P1 C1 C2 -9.4(4) . . . .
Au1 P1 C1 C2 108.4(3) . . . .
C1B P1 C1 C6 65.7(3) . . . .
C1A P1 C1 C6 176.5(3) . . . .
Au1 P1 C1 C6 -65.7(3) . . . .
C6 C1 C2 C3 2.0(6) . . . .
P1 C1 C2 C3 -172.0(3) . . . .
C1 C2 C3 C4 1.5(7) . . . .
C2 C3 C4 C5 -2.7(7) . . . .
C3 C4 C5 C6 0.3(7) . . . .
C4 C5 C6 O1 178.0(4) . . . .
C4 C5 C6 C1 3.4(6) . . . .
C2 C1 C6 O1 -179.5(3) . . . .
P1 C1 C6 O1 -5.2(5) . . . .
C2 C1 C6 C5 -4.5(6) . . . .
P1 C1 C6 C5 169.8(3) . . . .
C12 C7 C8 C9 -1.0(6) . . . .
O1 C7 C8 C9 -176.5(4) . . . .
C12 C7 C8 P2 177.5(3) . . . .
O1 C7 C8 P2 2.0(5) . . . .
C1D P2 C8 C7 -82.4(4) . . . .
C1C P2 C8 C7 168.5(3) . . . .
Au2 P2 C8 C7 46.4(3) . . . .
C1D P2 C8 C9 96.0(4) . . . .
C1C P2 C8 C9 -13.1(4) . . . .
Au2 P2 C8 C9 -135.2(3) . . . .
C7 C8 C9 C10 0.8(6) . . . .
P2 C8 C9 C10 -177.6(3) . . . .
C8 C9 C10 C11 0.2(7) . . . .
C9 C10 C11 C12 -1.0(7) . . . .
C8 C7 C12 C11 0.2(6) . . . .
O1 C7 C12 C11 175.4(4) . . . .
C10 C11 C12 C7 0.9(7) . . . .
C5 C6 O1 C7 39.0(5) . . . .
C1 C6 O1 C7 -146.1(4) . . . .
C12 C7 O1 C6 39.8(5) . . . .
C8 C7 O1 C6 -144.8(4) . . . .
C1E P3 C13 C14 -123.0(3) . . . .
C1F P3 C13 C14 -11.2(4) . . . .
Au1 P3 C13 C14 107.8(3) . . . .
C1E P3 C13 C18 60.4(4) . . . .
C1F P3 C13 C18 172.2(3) . . . .
Au1 P3 C13 C18 -68.8(3) . . . .
C18 C13 C14 C15 2.0(6) . . . .
P3 C13 C14 C15 -174.7(3) . . . .
C13 C14 C15 C16 2.0(7) . . . .
C14 C15 C16 C17 -3.1(7) . . . .
C15 C16 C17 C18 0.2(7) . . . .
C16 C17 C18 O2 -178.3(4) . . . .
C16 C17 C18 C13 4.0(7) . . . .
C14 C13 C18 C17 -5.0(6) . . . .
P3 C13 C18 C17 171.8(3) . . . .
C14 C13 C18 O2 177.2(3) . . . .
P3 C13 C18 O2 -6.1(5) . . . .
C24 C19 C20 C21 -1.8(7) . . . .
O2 C19 C20 C21 -178.7(4) . . . .
C24 C19 C20 P4 171.8(4) . . . .
O2 C19 C20 P4 -5.1(6) . . . .
C1G P4 C20 C19 -80.3(4) . . . .
C1H P4 C20 C19 168.5(4) . . . .
Au2 P4 C20 C19 47.8(4) . . . .
C1G P4 C20 C21 93.0(4) . . . .
C1H P4 C20 C21 -18.1(5) . . . .
Au2 P4 C20 C21 -138.9(4) . . . .
C19 C20 C21 C22 1.0(8) . . . .
P4 C20 C21 C22 -172.3(5) . . . .
C20 C21 C22 C23 1.1(10) . . . .
C21 C22 C23 C24 -2.5(10) . . . .
C20 C19 C24 C23 0.4(8) . . . .
O2 C19 C24 C23 177.2(5) . . . .
C22 C23 C24 C19 1.8(9) . . . .
C24 C19 O2 C18 45.3(6) . . . .
C20 C19 O2 C18 -137.8(4) . . . .
C17 C18 O2 C19 33.4(6) . . . .
C13 C18 O2 C19 -148.7(4) . . . .
C1B P1 C1A C2A -142.9(3) . . . .
C1 P1 C1A C2A 105.3(3) . . . .
Au1 P1 C1A C2A -16.7(4) . . . .
C1B P1 C1A C6A 40.0(4) . . . .
C1 P1 C1A C6A -71.7(4) . . . .
Au1 P1 C1A C6A 166.3(3) . . . .
C6A C1A C2A C3A 1.4(6) . . . .
P1 C1A C2A C3A -175.6(3) . . . .
C1A C2A C3A C4A -0.6(7) . . . .
C2A C3A C4A C5A -0.1(7) . . . .
C3A C4A C5A C6A 0.1(8) . . . .
C2A C1A C6A C5A -1.4(6) . . . .
P1 C1A C6A C5A 175.6(3) . . . .
C4A C5A C6A C1A 0.7(7) . . . .
C1A P1 C1B C6B -96.4(3) . . . .
C1 P1 C1B C6B 13.9(4) . . . .
Au1 P1 C1B C6B 143.5(3) . . . .
C1A P1 C1B C2B 79.1(3) . . . .
C1 P1 C1B C2B -170.6(3) . . . .
Au1 P1 C1B C2B -41.0(3) . . . .
C6B C1B C2B C3B 1.6(6) . . . .
P1 C1B C2B C3B -174.0(3) . . . .
C1B C2B C3B C4B -2.1(6) . . . .
C2B C3B C4B C5B 0.7(7) . . . .
C3B C4B C5B C6B 1.4(6) . . . .
C4B C5B C6B C1B -1.9(6) . . . .
C2B C1B C6B C5B 0.4(6) . . . .
P1 C1B C6B C5B 175.9(3) . . . .
C8 P2 C1C C6C -106.4(4) . . . .
C1D P2 C1C C6C 142.7(3) . . . .
Au2 P2 C1C C6C 15.0(4) . . . .
C8 P2 C1C C2C 76.8(4) . . . .
C1D P2 C1C C2C -34.1(4) . . . .
Au2 P2 C1C C2C -161.7(3) . . . .
C6C C1C C2C C3C -1.2(6) . . . .
P2 C1C C2C C3C 175.6(3) . . . .
C1C C2C C3C C4C -0.5(6) . . . .
C2C C3C C4C C5C 2.0(7) . . . .
C3C C4C C5C C6C -1.8(8) . . . .
C2C C1C C6C C5C 1.3(7) . . . .
P2 C1C C6C C5C -175.5(4) . . . .
C4C C5C C6C C1C 0.2(8) . . . .
C8 P2 C1D C6D -0.7(4) . . . .
C1C P2 C1D C6D 112.0(4) . . . .
Au2 P2 C1D C6D -124.8(3) . . . .
C8 P2 C1D C2D -173.4(3) . . . .
C1C P2 C1D C2D -60.7(4) . . . .
Au2 P2 C1D C2D 62.5(3) . . . .
C6D C1D C2D C3D -0.6(6) . . . .
P2 C1D C2D C3D 172.3(3) . . . .
C1D C2D C3D C4D -0.4(7) . . . .
C2D C3D C4D C5D 0.9(7) . . . .
C3D C4D C5D C6D -0.3(7) . . . .
C2D C1D C6D C5D 1.1(6) . . . .
P2 C1D C6D C5D -171.4(3) . . . .
C4D C5D C6D C1D -0.6(7) . . . .
C13 P3 C1E C2E -148.3(3) . . . .
C1F P3 C1E C2E 103.3(3) . . . .
Au1 P3 C1E C2E -15.7(4) . . . .
C13 P3 C1E C6E 34.1(4) . . . .
C1F P3 C1E C6E -74.4(4) . . . .
Au1 P3 C1E C6E 166.6(3) . . . .
C6E C1E C2E C3E 0.8(6) . . . .
P3 C1E C2E C3E -176.9(3) . . . .
C1E C2E C3E C4E 0.3(7) . . . .
C2E C3E C4E C5E -0.3(8) . . . .
C3E C4E C5E C6E -0.6(8) . . . .
C2E C1E C6E C5E -1.8(7) . . . .
P3 C1E C6E C5E 175.9(4) . . . .
C4E C5E C6E C1E 1.7(8) . . . .
C1E P3 C1F C2F 25.7(4) . . . .
C13 P3 C1F C2F -85.7(4) . . . .
Au1 P3 C1F C2F 147.9(3) . . . .
C1E P3 C1F C6F -162.1(3) . . . .
C13 P3 C1F C6F 86.5(3) . . . .
Au1 P3 C1F C6F -39.9(3) . . . .
C6F C1F C2F C3F -1.4(6) . . . .
P3 C1F C2F C3F 170.7(4) . . . .
C1F C2F C3F C4F -0.5(7) . . . .
C2F C3F C4F C5F 1.4(7) . . . .
C3F C4F C5F C6F -0.2(7) . . . .
C4F C5F C6F C1F -1.7(6) . . . .
C2F C1F C6F C5F 2.5(6) . . . .
P3 C1F C6F C5F -169.9(3) . . . .
C20 P4 C1G C2G 146.1(4) . . . .
C1H P4 C1G C2G -103.2(4) . . . .
Au2 P4 C1G C2G 21.5(4) . . . .
C20 P4 C1G C6G -36.3(5) . . . .
C1H P4 C1G C6G 74.3(5) . . . .
Au2 P4 C1G C6G -160.9(4) . . . .
C6G C1G C2G C3G 0.0(7) . . . .
P4 C1G C2G C3G 177.5(3) . . . .
C1G C2G C3G C4G -0.8(7) . . . .
C2G C3G C4G C5G 0.7(8) . . . .
C3G C4G C5G C6G 0.2(9) . . . .
C4G C5G C6G C1G -1.0(10) . . . .
C2G C1G C6G C5G 0.9(9) . . . .
P4 C1G C6G C5G -176.7(5) . . . .
C20 P4 C1H C6H 113.8(4) . . . .
C1G P4 C1H C6H 5.2(5) . . . .
Au2 P4 C1H C6H -124.1(4) . . . .
C20 P4 C1H C2H -67.0(4) . . . .
C1G P4 C1H C2H -175.5(3) . . . .
Au2 P4 C1H C2H 55.2(4) . . . .
C6H C1H C2H C3H -2.3(7) . . . .
P4 C1H C2H C3H 178.4(4) . . . .
C1H C2H C3H C4H 0.3(7) . . . .
C2H C3H C4H C5H 1.6(8) . . . .
C3H C4H C5H C6H -1.5(8) . . . .
C2H C1H C6H C5H 2.3(8) . . . .
P4 C1H C6H C5H -178.4(4) . . . .
C4H C5H C6H C1H -0.5(8) . . . .
